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9

sQUAR
ES 4-5 Question →
16-200
hiuingceu →
All carbon
containing
NCERT
-

compound in living system !


a
.

1)
Ctnemalttnalysis ORGANIC molecules
sample thieving Tissues
Retentalt / Add ↓

insoluble pool/

lysis
TEHERAN'd of a cell

↓/↓ Biomacoo
molecules

gamy
-

Polysaccharide

Protein Nucleic acid →

:f£kerate traction Acid soluble pool/


.

:-. :
-

Biomieromolecules

④ 80%5

→ ironing Nucleotide
milna
filtrate Amino acid
-


Mirta -

Retentive !

Inorganic elements

88¥88 →

Aggregates →
size ↑ →
found in R.tentate.cl#'M94--

I
Ash
= Analysis
=

Sample (wet weight 7 E tog →


cost

weieghHgo→
↓ Evaporation
water
Tissue (dry vapour
↓ Burn

As ( Ash weight
Ashes →
inorganic
Ca 2-1

By
-

Micrometres : -

Monomers

mw →
less than
-

telecoms .

Masques →
Polymers

MY Merchan Eeoc daltons

pyo →
Lipids → Not
polymers .

800 dalton .

Lipids strictly BMO macromolecule !



are not
Cell composition
-
-

'

I
'

hipid Bilayer → Lipids -3%


@
.


.

Nickle acid 5-7-1→


.


water
-5704%
÷ :-) protein
.

10
-15%

.

Carbohydrates -2%
PID abundant element in
living
most
,
cell i.
Oxygen
-
.

'

Compound
" →
11
in 11 " Water .

in Mat
C,a,tÉn
i
ECF
present

, , i,
ICF →
Kt
PIC
PRIMARY SECONDARY METABOLITE


Substance which Substance not involved in
directly involved
life processes Instead
are
.

tin
life processes .

they are produced for defense !


They affect growth
→ .

→ ✗
grown

They are universe
-
.


unique
Eg : -

Chlorophyll
-
.

Prokaryotes
G↳wcose ,
etc
!
Category Example
.
Painkiller
1- Alkaloids →
Mo codeine -

cough syrup !
2.
Terpenes →
Diterpene ,
Mono
terpene water soluble

A% -eno→u↑ᵗA
.

3-
Pigment → →

Main such .

no
Drugs
-

Yin,cwi@mv%%k¥n amorous

s Toxins -
Absin & Ricin →
Anti
depressant
.

. -

G.
Polymeric →
substances
Gm Cellulose etc
- .

,
_

Rubber
conaanavalin A
Pyg& Essential oil →
Lemongrass oil .
CARBOHYDRATES
mum

-

Hydrates of Casson ketone


-

Instant
Energy source •
-
- -


Aldehydic chain -50

pehangtestlbenediatttesttdfoeefancton.at -
cha ,n→⇐
Ignatian Grab _

'

&
'
Types ↓ is
forget sugar ☆ colour
change

tee
④osacahasidewias-wh-oitltgosacchaoi.de
- -

Polysaccharide
Tew

unit my
single

of sugar →
,
many
2-9 unit
Sweetin taste .

of → • no units of
' monosaccharide
single → free
- → sweet / Non -

sweet
monosaccharide
I Non sweet
I
-
.

tuefehhng Test
"e

test

¥7 -

¥
?⃝
② Monosaccharide → 3-7-01sbon

CnHg④
-
→ G. f-

⑨ Tnes : -


CHO
Hz f OH
-
-

A-
d-⑨ Right -

on

i grasp 9=0
No optical
c- on
HIC OH µ
- -
.

activity
,
.

D-
Glyceraldehyde
-
DÑEE ANOMERS

Hexoses 868)

:¥i¥
-

"

amore .

µ
-

g on 1
-

H
-


g- ,
.
no
-

on
H -

f- on n n


Glucopgranose
D
H c- on
B- D- GIUCO
-
-
-

{ Hoon bysranose
Ketonic
Fouctose
sugar /

Fruit
sugar
→ .

② 0LÉRDE : -

2 units
P¥ Disaccharides →
of monosaccharide .

⑨ Maltose
÷-
→ Glucose + Glucose


24,4
glycosidic Linkage .

the
Fehring Test - →
Reducing
⑥ trade →
MiÉagae

Galactose + Glucose
poky glycosidic linkage
84¥ → we
felling Test Reducing . -1


⑤→
Invent
sugar →
Glucose
d- I >
+

B- 2
fructose

glycosidic Linkage

iiwfuningntesr
-

- Non -

Reducing .
② P¥c : _
Non -

reducing sugar
-

ve
Rehling Test '

ideal osmotically
for storage Inactive
-
a
-

⑨ Starch
Atnyloplast (Plastid

-
-

plant cell) toe


-
Iztest
I ↓

Amylose fAm t①
HOMONYM# water
-

Water soluble
I insoluble
10 -15% Glucose
-

so -85%

Branched
2g
→ Unbranched .

Ink
* Homo
polymer →
Glucose Branching tikage -

→ ✗-1,4
glycosidic linkage . 2-1,6
Linear
linkage -2%4 .
⑧ Glycogen ( Animal stanch ) . →
flomopolymor of
lyc¥•sis Glucose

Glycogen Iz Test
Glucose
-
-


Branched
genaj / -
Linear Branching

store →
musique 2-1,4 ✗ -116

pyo
CHITIN ⑨ CELLULOSE

It
→ Homo
polymer N
acetyl Homo
polymer B-Glucose
hinearz
→ -
→ .

Glucosamine
NAO helices
Linkage B-lil B- 1,4
glycosidic

glycosidic
-


Abundance 2nd in Biosphere Most _"eI-

Biosphere

→ -

→ Location → Exoskeleton of → Plant cell wall


Arthropods &
Cell
wanoffangi → unbranched

unbranched
.
-
2.AM/N0AciDm
chemical &
✓ Substituted methane
- ⑨ -
physical
-

property decide
-
-

∅ peng
Types my
-

⑧ Cook Chiral Carbon


F - ÷

'

n
optical activity
]

Essential Arg
Exception →
GIne
: not produced in body diet Eat
-

,
Lysine
-
- .

⑥⑥⑨ Tryptophan-①fm↳knaʰc
_

④ ④ Lt dourine >

-
Valine
Threonine
↓ I ↓

phenylalanine Methionine Arginine


Histidine

y
semi -

essential
✗ Mon
;¥EaLAA

produces -

body
∅ Neutral AA →
Gly → Alanine → Valine -

hell -

Isoleucine
-

a Aromatic'AA→
- Phenylalanine Tyrosine Tryptophan , . .

SEETA → Methionine ,
Cystine Cysteine ,
.

✗ Basic AA
-

Lysine +
Arginine :

+
Acidic
-
AA →
Aspartate & Glutamate .


Abc AA→ .
Serine + Threonine .

TNWITEER ION
/ Bipolar / Dipolar
R
r

+
*
a
Netcharge :O ↑
µ N
G COOH
Hgtv
-

C COO CE -

HY COO
-
- - - -
-

3 • a
"
µ H

'

⑨ H

PH acidic P> →
the Phat which
pn→ Basic
-

we
AA -
Basic get zwiiterieon .

AA -5
Acidic
In a solution of different pH

behauesdifferenky.in
AA
formation
of
Peptide Bond
-

HY § COOH
-
-

my Coon
- -

H -

H,
h

I Peptide (
Bond covalent

my F-
r Bond)
i É -
n coon
µ
- -

,
'
n


Hetero polymers
Retentah PR#

41cal → monomer Amino acids
↳gm-_
→ .

CIassifec-atioisonthibasi-ofsbuctui.IO
Primary
E -
structure
I N

N~¥-n⑦_"A④-c

peptide Bond
First AA -

N -
Terminal close

Last AA -
C - 11 "


No
'

AA & Location
of of AA .
② 2° Stonehill
%B°nd

_ I
Hzlinkage .

Fateh
d- helix p pleated
polypeptide
-

-
-

ni Inna
n-EE.in
3g
-

i
,
polypeptide ; i h
.

hvB°ⁿᵈ ,
cÑMN
÷
③Carry structures Necessary for biological

activities
☆ ↓

"☆f⑥hVC
Enzymes !
Activists Woollen Ball like structure
C@-

Bond → Me → Vanderwaal
covalent bond
-

peptide

Hydrophobic
-

disulphide → Hz Bonds .

_Io - -
- -
-
-
⑨ Quaternary structure :
Eye
-

.
-
HI -

b⑨ Adult
✗-88 BE ✗
foetal

B-

Rp
Functions
-
PLO → Hormones -
AM ,
oxytocin .


Transporter → GLUT II -


defense → Antibodies .


Receptors →
insulin
→ inhibitors .
ʳʰᵗʰˢ"ᵗʰᵗ

(
hipolgsii LIPIDS Not
polymers
hydrophobic
✗ =
hipogenesis "" Soluble
inorganic
0 found """"ᵗʰᵗ

Esters of solvents like benzene


M "
"
• ◦ da "° " ,

& Alcohol
- t
Igm -9kcal
-
. chloroform , ether .

Fatty acid
-

↓ ↓
satuuatedf.AT UnsaturatedAAmfr
8- 8 →
deaiblekond

single Bond

↑ nap IFA PUFA


monounsaturated FA
-

→ Palmitic acid ( IG )
deltoid
Polyunsaturated AA
Eg : → Linoleic (a)
-

→ stearic acid F. A
( is)
a)
Arachidic acted

Linolenic AA (3)

Gog →
Arachidonic f. Ala )
② Meutralfats : -
Ester of f. A +
Glycerol .

Remove .

ref,
%
-444%3
-
◦ -

112-9 on
-

3- (9) Tycoon
" →

g-
☆ on
µ
g-
-

µ _
on
palmitic acid
c-on
Hz C oh Hj-
-

Mono
1 f. A '
Glycerol glyceride
-

☆ .

Diglyceride
-

+ "
2- F. A

Triglyceride
_
"
3. f- A *

② Waxes
-

_
Ester of fatty acid
-
-1 Alcohol other

than
Earwax /Cerumen glycerol
Beeswax abdominal
gland of worker Bees
-

.
conjugate Lipids →
t.ph#h.olipid

phosphatic
A }
hydrophilic \
Glycerides
/ Am#Patg
}
molecule
& } hydrophobia
.

Ri Ra
Bite '
-

emulsification
Eg : -

Lecithin (
phosphatidylcholine , y
surfactant
-


Lungs surface tension .
=3 Derived Lipids Liver
syntheses
-

Cholesterol = steroid
Eg : -

-
uit D

= Plasma membrane

good NIL
{NUCLEICAciDS.ME
Hetero
polymers Building

→ Block → Nucleotide .

→ Refentalt →
DNA ,
RNA

Nucleotide
I ↓ ↓

Nucleoside Bases
phosphate sugar
^ -o-~
DNA RNA
&
I
Purines
Pyrimidines
=
_

Adenine
deoxyribose Cytosine
'
2 Ribose
-

-
-

Guanine
-

sugar sugar -

Thymine
2
ring
-

Uracil
( RMA)

single ring
-

structure
Nucleotide
-

,ʳi%É;¥q ;÷
" ""

Purine → ☒
linkage

H Pyrimidine -

Nd

%ñbo→
on on

phoˢ%ᵈa↑tBase
Linkage
a
Nomenclature
Base Sugar Nucleoside phosphate Nucleotide .

Adenosine
Adenine Ribose
Adenyliraaid

" →

Guanosine
Guanine
Guanylicacid
" → →
a

Uracil " →
Uridine
Uoidyhiacid

,,

Thymine deoxyribose doeoxythymidin


deoiythymidyhi
-
'
. " →

acid
Cytosine Ribose
"

cytidine

cytidylicacid .
WATSON AND CRICK MODEL of DNA .

_⑨_°ⁿᵈ⑦-⑤≤p Ibp
-
.

¥ 1-

-


-
Both
antiparallel
strands

/ A=T

,

⑤ ⑨
"

# =
4=-0
-

⑤ ④⇐ ⑥ -


31 Human -

BDNA -

10b$ / turn

pitch of DNA =
No of bp/ turn
'

✗ distance b/w Zbb


=
to ×
0.34hm / °
34A

3.4hm / 34A
=
°

- -
?⃝
THEA : -

)
}
A = " "
" ᵗᵗʰ
=

B 10

g. hand , ,
C 9
gnt
.

£
=

D= 8

Z= lzbp/ turn .

Left
-

handed .
Purine
Chan Pyrimidine
-

gaff
-

rule
.


A -19 =
Ttc
a- -
ENZYMES Biocatalyst →

mm
3D structures

Mostly -

Enzyme
-

proteinaceous
Ribonuclease P
RNA based
Ribozyme

-

→ -

a
specific
HiքTbsbau- dependent
.

on PH , temp .


product / trim

☆Ñ[ c
active silt →
substrate

Protein
part
molecule

Non -
.

protein part
structure
Holoenzyme Apet¥ao
: -

=
-

Harem
of
Eg : "ᵗʰ↳ " "
"ᵗʰⁿʰ ""
-

" ""

firmly attached with


Apoenzyme
?⃝
⑤ K-Eyme : -

organic compound not


firmly
attached
Eg : NAD FAD
-

,
.

② Metal ion
- ←
! -

Psocarboxy peptidases -
Zn
"

Carbonic Zn "
anhydrase
-

salivary amylase -

a-

PEPcase
MGH
-

Mcminn of EnymIᵈtii4

8+7=-80-8 E-s
+ ☐
product


E-
^

me
Exothermic
⑤ with

potential
enigma
[S]↑-[t
[s]
GT↓-[P@
-

Energy
( P)

Exothermic (P) Endothermic
Reaction
-

progress of Rxn .

Activation
-
Energy
-

Energy required to initiate asrxn

(
enzyme reduces AE
!
?⃝
④ Temperature →
10°C ↑ → 2x
ME
• 104 ↓
%
→ →

Temp ↑↑
-

Denature
=

Temp ↓ d- Inactive
-

optimum Max
-

Human body 372


-

② PI m
#
p optimum
-

Trypsin →
alkaline
pepsin
→ →
acidic
② Substrate come
ÉBÉ
: -

-
-

constant .


Vmax
- - - -
-
-

s -9
As the come
offs]
: increases .
Rate of
of !
velocity ↑ ↑↑↑ ↓↓↓
Rin also increases .

⑨ Sissi
+
Vy
- -

Rxn
-

• cone

j
velocity
-

constant
,

i l ∅
t
i
kind 1-
p
- . - - -
'
-

↓④ km↑s ] '
affinity ofemyme
-

JnIbition

komyp.tn Non-competitive

2g ⑤ ②
@ ⑤ ②

u inhibitor shape same
Substrate & - -
→ ⑤ &⑦ shape diff
-


Competing for active silt of →
No -

comp for A 's

enzyme ! Km -

same
Km → ↑↑

Vmax -

constant Vmax -

D8 .

Eg :
Suphadrng a
cytochrome
-
-

=
-
Succinic
dehydrogenase cyanide
µÉ psteet ,

/ NOI
giveaway pm
- P
2:30 9:oopm_
-

Sunday YT

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