Replica 27th January-JEE Main 2024 - 240115 - 221129

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Ashwani Tyagi

LIVE MOCK TEST (With Topic Details)


REPLICA 27th JANUARY JEE Main-2024

PHYSICAL ORGANIC INORGANIC


1. Limiting Reagent 1. GOC 1. Atomic radius
2. Bohr’s Model 2. Ozonolysis 2. MOT
3. Redox Reactions 3. SN1,SN2,E1,E2 3. Hybridisation
4. Adiabatic Process 4. Reactions Of Alkynes 4. Crystal Field Theory
5. Le-chatelier’s Principle 5. Phenols 5. K2Cr2O7 & KMnO4
6. Solubility and Ksp 6. Nucleophilic Addition 6. Nitrogen Family
7. Energy Of Activation 7. Name Reactions 7. Group-14
8. Colligative Properties 8. Geometrical Isomerism 8. Acidic Radicals
9. Nernst Equation 9. Test Of Amines
10. Kohlrausch’s Law 10. Duma’s & Kjeldahl
11. First Order Reactions 11. Vitamins
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Which of the following disease is not caused by the deficiency of a water


soluble vitamin?

A. Beri-beri
B. Cheilosis
C. Pernicious Anaemia
D. Xerophthalmia

D
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Identify the incorrect statement among the following?

A. Ionisation Energy of Mn+ is lesser than Cr+ due to no loss in exchange


energy.
B. Tl2+ , V2+ and Cr2+ are strong reducing agents and liberate H2 from acids
C. Decrease in pH breaks Cr-O-Cr bonds in dichromates.
D. Order of oxidising power : VO2+ < Cr2O72- < MnO4-

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

4 gm of a mixture of CaCO3 and sand is treated with an excess of HCl, and 0.88
gm of CO2 is produced. % of CaCO3 in the original mixture will be:

A. 20%
B. 50%
C. 25%
D. 38%

B
REPLICA 27th JANUARY SECTION-A JEE Main-2024

For H-atom if Tn = Time period of revolution in nth


orbit and Tn2/Tn1= 8, then n1 and n2 will be :

A. n1 = 1, n2 = 2
B. n1 = 2, n2 = 4
C. n1 = 3, n2 = 4
D. n1 = 2, n2 = 3

A
REPLICA 27th JANUARY SECTION-A JEE Main-2024

For the decomposition of ammonia in a closed vessel at 300K, if an inert gas is


added to the container under isochoric conditions , equilibrium will?
2NH3 ⇌ N2 + 3H2

A. Shift in forward direction.


B. Shift in backward direction.
C. shift in either direction.
D. Remain unaffected.

D
REPLICA 27th JANUARY SECTION-A JEE Main-2024

In the reversible adiabatic expansion of an ideal monoatomic gas,


the final volume is 8 times the initial volume. The ratio of final
temperature to initial temperature is

A. 8:1
B. 1:4
C. 1:2
D. 4:1

B
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Kc for the reaction : [Ag(CN)2]- ⇌Ag++2CN-, the equilibrium constant


at 25°C is 4.0 × 10-19, then the silver ion concentration in a solution
which was originally 0.1 molar in KCN and 0.03 molar in AgNO3 is :
A. 7.5 10 18
B. 7.5 × 10-18
C. 7.5 × 1019
D. 7.5 × 10-19

B
REPLICA 27th JANUARY SECTION-A JEE Main-2024

A. B.

C. D.

A
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Product A will be:

A. B. C. D. None of these

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

4-Bromocyclohexene is treated with KOH in alcoholic medium to form ‘X’


(minor product). When this product is treated with O3/H2O/Heat , it gave a
final product ‘Y’. Y is

A. Malonic acid
B. Glutaric Acid
C. Succinic Acid
D. Acetic Acid

D
REPLICA 27th JANUARY SECTION-A JEE Main-2024

SP is equal to?
A. PQ + RS
B. PQ + QR + RS
C. SR + SQ
D. PQ + QR

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Which of the following pairs of solutions can be expected to be


isotonic at the same temperature?
A. 0.1 M urea and 0.1 M NaCl
B. 0.1 M urea and 0.2 M MgCl2
C. 0.1 M NaCl and 0.1 M Na2SO4
D. 0.1 M Ca(NO3)2 and 0.1 M Na2SO4

D
REPLICA 27th JANUARY SECTION-A JEE Main-2024

A hydrogen electrode placed in a buffer solution of CH3COONa and


CH3COOH in the ratios x:y and y:x has electrode potential values
E1 and E2 volts, respectively, at 25°C. The pKa value of acetic acid
is
A. (E1 + E2)/ 0.118
B. (E2 - E1)/ 0.118
C. −(E1 + E2)/ 0.118
D. (E1 - E2)/ 0.118

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

A. B.

C. D.

D
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Calculate the half-life of the first-order reaction


C2H4Og → CH4g + COg
if the initial pressure of C2H4O is 80 mm and the total pressure at the end
of 20 minutes is 120 mm.
A. 40 min
B. 120 min
C. 20 min
D. 80 min

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Identify structure of Y:

A. B.

C. D.

D
REPLICA 27th JANUARY SECTION-A JEE Main-2024

Arrange the compounds in order of decreasing reactivity for nucleophilic


addition reaction:

A. I > IV > II > III

B. I > II > III > IV

C. II > III > I > IV

D. II > I > III > IV

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

The oxidation number of the central atom in the compound K3CrO8 is

A. +5
B. +6
C. +13
D. +4

C
REPLICA 27th JANUARY SECTION-A JEE Main-2024

In which of the following all bond lengths are same

A. PF5
B. B2H6
C. Al2Cl6
D. PCl5

A
REPLICA 27th JANUARY SECTION-A JEE Main-2024

The correct order of increasing radius of the elements Si, Al, Na and P is
A. Si, Al, P, Na
B. P, Si, Al, Na
C. Al, Si, P, Na
D. Al, P, Si, Na

B
REPLICA 27th JANUARY SECTION-B JEE Main-2024

In redox reaction, Ba(MnO4)2 oxidizes K4[Fe(CN)6] into K+, Fe+3, CO3–2 and NO3–
ions in acidic medium, where Ba(MnO4)2 itself reduces into Mn+2, than how
many moles of Ba(MnO4)2 will react with 1 mole of K4[Fe(CN)6]??

6
REPLICA 27th JANUARY SECTION-B JEE Main-2024

A reaction is carried out in two different conditions where it follows zero


order and first order mechanisms with half lives t1 and t2 respectively .
Assuming initial concentration taken to be 6.93 moles per litre ,find the
value of t1/t2?

5
REPLICA 27th JANUARY SECTION-B JEE Main-2024

In the hydrolysis of ester according to the reaction, in acidic medium


CH3COOC2H5 + H2O → CH3COOH + C2H5OH, How many steps are involved?

C
REPLICA 27th JANUARY SECTION-B JEE Main-2024

Find the total number specie(s) among the following, containing 3c−2e
bond.
[ Be2H4, (BeH2)n, Be2Cl4, Al2(CH3)6, Al2Cl6, I2Cl6, B2H6, B2H2 (CH3)4 ]

5
REPLICA 27th JANUARY SECTION-B JEE Main-2024

What will be the number of products that are formed on monochlorination


of C5H12?

11

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