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(@bohring - Bot) Adv Paper 2 (07.05.2024)
(@bohring - Bot) Adv Paper 2 (07.05.2024)
(@bohring - Bot) Adv Paper 2 (07.05.2024)
JEE (Advanced)
(07.05.2024)
PAPER – 2
Each Section is further divided into Two Parts: Part-A & Part-B.
1. Part-A (01 – 08) contains 8 multiple choice questions which have one or more than one
correct answer. Each question carries +4 marks for all correct answer.
Full Marks : +4 If only (all) the four option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
Part-A (09 – 12) contains 2 List-Match sets with 4 questions (each set has 2 questions). Each
question has 4 statements in LIST-I & 4, 5 or 6 statements in LIST-II. The codes for Lists have
choices (A), (B), (C), (D) out of which only one is correct.
Each question has only one correct answer and carries +3 marks for correct answer and –1 mark
for wrong answer.
2. Part-B (01 – 06) contains 6 Numerical answer type questions with answer XXXXX.XX and each
question carries +3 marks for correct answer. There is no negative marking.
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Physics SECTION – I
PART – A
(One or More than one correct type)
This part contains 08 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
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C
(A) It will be maximum at A
(B) It will be minimum at A
(C) It will be equal at B and C and that value will be maximum.
M2
(D) It will be more at O than A by an amount 2 .
R
TA TB T
=300 K =900 K
(A) The heat absorbed by the gas during the process AB is 3000 R.
(B) The heat absorbed by the gas during the process BC is 1200 R.
(C) The heat rejected by the gas during the process BC is 600 R.
(D) The efficiency of the cycle is 36%.
I
x
z
Dotted (imaginary) lines form a cube of side a. I: current
Then, regarding this loop :
60i ˆ ˆ
(A) Magnetic field at centre of cube is (i j)
4 3 a
3 0 i ˆ ˆ
(B) Magnetic field at centre of cube is (i j)
6a
3 0 i ˆ ˆ
(C) Magnetic field at centre of cube is + (i j)
6a
(D) Magnetic moment of the loop has no z-component.
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7. A positive charge (having charge q0)is thrown from orgin with velocity v0 ( ˆj k)
ˆ in a gravity-free
space. Everywhere in space, there exists a uniform & constant magnetic field B =B0 k̂ . Two
infinite, rigid, perfectly elastic planar walls are kept at z = z0. Taking mass of the particle to be
m0 & assuming v0> 0, z0 > 0, choose the correct option(s) :
4z0
(A) The motion is periodic with period , for any value of z0.
v0
4z0 2m0 v 0
(B) The motion is periodic with period , if z0 is of the form of n , n I+
v0 B0 q0
4z0 2n 1 2m0 v 0
(C) The motion is periodic with period , if z0 is of the form of B q ,, n I
+
v0 4 0 0
(D) The motion is periodic & the particle crosses origin only once every cycle, if z 0 is of the
2n 1 2m0 v 0
form , n I+
4 B0 q0
This whole arrangement is in a gravity –free space & take the mass of the triangular loop to be
M0. Then (initially), regarding the triangular loop:
(A) There is no acceleration of centre of mass
(B) There is no angular acceleration of centre of mass
3 3 B 0R
(C) There is angular acceleration = anticlockwise
2 M0
9 3 B 0R
(D) There is angular acceleration = anticlockwise
2 M0
This part contains TWO (02) List-Match Sets. Each List-Match set has TWO(02) Multiple Choice
Questions. Each List-Match set has two lists: List-I and List-II. List-I has Four entries (I), (II), (III) and
(IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U). FOUR options are given in each Multiple
Choice Question based On List-I and List-II and ONLY ONE of these four options satisfies the condition
asked in the Multiple Choice Question.
Answer the following by appropriately matching the list based on the information given in the
paragraph.
Now the container is given possible accelerations as in List-I. Some numbers are given in List-II.
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List-I List-II
(I) (P) 2
a0
(II) g (Q) 1
a
2
(III) a g (R) 0
(IV) a g (S) 3
2
(T) 1
2
(U) 3
9. If the experiment is done on earth (acceleration due to gravity : g), then match the
tension(magnitude) in rod
ratio . Here, weight of ball on earth means mass x acceleration
weight (magnitude)of ball on earth
due to gravity.
Options
(A) I S, II Q, III P, IV T
(B) I Q, II T, III R, IV P
(C) I T, II P, III R, IV S
(D) I T, II R, III S, IV P
10. Imagine now that the experiment is repeated on a different planet whose density is same as that
of earth but radius is twice as that of earth. Then match the ratio
tension(magnitude) in rod
.
weight (magnitude)of ball on earth
Options
(A) I T, II U, III P, IV S
(B) I P, II S, III Q, IV U
(C) I Q, II P, III S, IV T
(D) I T, II Q, III R, IV S
Answer the following by appropriately matching the list based on the information given in the
paragraph
E1, E2, E3, E4, E5 are five circuit elements such that E1, E2,
E3 and E4 are of same nature (resistive or capacitive) and E1 E2 = nE1
corresponding E5 is capacitive or resistive respectively for a E5
given experiment. Four value of n(= 1, 2, 3, 4) give rise to E3 = nE4 E4 n: positive
four possible circuits: Circuit-1 (n = 1), circuit -2(n = 2), integer
circuit -3(n = 3) and circuit -4 (n = 4). List I gives the possible
four circuit and List II gives some numbers.
V0
.
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List-I List-II
4
(I) Circuit-1 (P)
3
3
(II) Circuit-2 (Q)
2
5
(IV) Circuit-4 (S)
2
8
(T)
5
(U) 2
11. If E1 = E4 = R0 (resistive) and E5 = C0(capacitive), then the correct match for the time constant of
the voltage acorss the capacitor, as a factor of R0C0, is:
Options
(A) I R, II Q, III T, IV P
(B) I S, II P, III R, IV T
(C) I P, II Q, III R, IV S
(D) I R, II P, III Q, IV T
12. If E1 = E4 = C0 (capacitive) and E5 = R0 (resistive), then the correct match for the time constant of
the voltage across the resistor, as a factor of R0C0, is:
Options
(A) I R, II Q, III U, IV S
(B) I S, II P, III R, IV U
(C) I R, II P, III Q, IV T
(D) I P, II Q, III R, IV S
PART – B
(Numerical Answer Type)
This part contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
1. Two identical discs (each of radius r) are arranged such that one is made to fall freely & the other
is tied to a string of length (>>r) as shown:
O
A B
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Initially, both discs are at same level (with the string horizontal and disc A just left to the point of
suspension (of disc B) O. Now, disc B is released and A is released at such a moment such that
following situation arises just before collision (at the lowest point of B):
B
Assuming collision to be perfectly elastic, find the max height in cm, to which B rises (from its
lowest position) after the collision. Take 3 =1.73. L = 2 m and truncate the final answer to two
decimal places.
Inductor
100
t=0 12 V
The inductor has an inductance of 0.5 mH & resistance of 100 . The bulb stops glowing if
current passing through it becomes any less than 50 mA. Then for what time interval (in s),
after closing the switch, will the bulb glow for. (Take n 2 = 0.69)
C
L = 0.1 H
~
250 V, 100 rad/s
4. A container consists of a sample of hydrogen like ions of the same element & in the same state.
In this state, the ionization energy of an ion in the above sample is 36% of a hydrogen atom. This
sample is now allowed to reach its most stable configuration, thereby resulting in 10 distinct types
of photons. The most energetic Paschen – line photons from this sample are made to incident on
a metal. The stopping potential of the ejected photoelectrons is observed to be 4V. Find the work
function (in eV) of the metal. (Take ionisation energy of a hydrogen atom= 13.6 eV and truncate
your final answer to two decimal places)
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S2
1 2
D = 720 cm
A parallel beam of light (inclined at 10 to the horizontal) is incident on the setup as shown. Find
(in cm) the separation between the point O (which is the geometrically symmetric point of the
YDSE) & the closest point on the screen where intensity is half the maximum possible.
(Take = 3.14, sin = = tan for small angles)
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Chemistry SECTION – II
PART – A
(One or More than one correct type)
This part contains 08 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
2. In Baeyer’s process (extraction for aluminium metal), bauxite ore is first digested with reagent ‘Q’
to form ‘R’. The solution of ‘R’ is then neutralized by passing gas ‘S’ and ‘T’ is precipitated out.
Choose the correct option(s)
(A) ‘Q’ is NaOH
(B) ‘R’ is Na[Al(OH)4]
(C) Bauxite ore is Al(OH)3
(D) ‘S’ is CO2 gas
4. Each of the following options contains a set of four molecules. Identify the option(s) where all
bond lengths in a molecules are equal in all four molecules in an option
(A) OF2, SF4, XeF2, ClF3
NO3 ,O3 ,SF5 , ClF4
(B)
(C) NO3 ,BF3 ,SiF4 ,SH2
(D) XeF2 ,P4 ,I3 ,SO 24
O
3. Zn / Hg,HCl,
(A) The compound ‘P’ gives 2,4-DNP test.
(B) The compound ‘Q’ gives effervescence of CO2 with NaHCO3.
(C) The conversion of ‘P’ to ‘Q’ is a type of electrophilic substitution reaction.
(D) The compound ‘P’ is soluble in NaOH.
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6. Which of the following reaction (s) do not/does not give aniline as major product?
(A)
C
NH2 Br2 NaOH
O
(B) O
1 KOH
NH
2 Cl
O 3 NaOH aq
(C)
Br NH3
(D)
C i NH3 ,
OH
ii LiAlH4
iii H2 O/H
O
2 2
i SO Cl /h i HIO
ii NaOC2H5 / C2H5 OH 'P ' 4
ii OH /
' Q'
iii Cold dil./aq.KMnO4 /OH
CH3
(A) The compound ‘P’ is OH
OH
CH3
(B) Total ‘P’ products formed are two.
CH3
O
(D) Compound ‘P’ on reaction with excess of HI gives I
H2 /Ni
Y C6H14 O
Optically inactive
(A) Only ‘X’ gives yellow solid with NaOH/I2
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(B) Both X and Y form immediate turbidity with HCl in the presence of anh. ZnCl2.
(C) Only ‘X’ decolourises the colour of acidic solution KMnO 4.
(D) Dehydrogenation takes place when ‘Y’ is heated with Cu at 300 oC.
Answer the following by appropriately matching the lists based on the information given in
the paragraph.
List-I includes starting materials and reagents of selected chemical reactions. List-II gives
structures of compounds that may be formed as intermediate products and/or final products from
the reactions of List-I.
LIST–I LIST–II
(I) O (P) CN
CH3
i NaOHI2
ii Conc. H2 SO4
OH
(II) COOC2H5 (Q) CHO
i LiAl O Bu
t
H/ 78 Co
ii H O
3
CH3
3
iii Ac 2 O/ AcONa
iv Conc.H2 SO4 O
(III) H (R) O
O
i aq. KOH OH
ii Cu/500o C
O
iii CH3MgBr /C2H5 OC2H5
iv H3 O
v OH /
CH2 Cl
(IV) CH CH2 (S)
i HBr /H2 O2
ii KCN alc.
iii H3 O
iv Br2 / O
v KOH alc.
(T)
O O
(U) O
OH
OH
9. Which of the following options has correct combination considering List-I and List-II?
(A) (III), (T), (U)
(B) (IV), (R), (T)
(C) (IV), (P), (S)
(D) (III), (Q), (S)
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Answer the following by appropriately matching the lists based on the information given in
the paragraph.
List-I includes starting materials and reagents of selected chemical reactions. List-II gives
structures of compounds that may be formed as intermediate products and/or final products from
the reactions of List-I.
LIST–I LIST–II
(I) O (P) CN
CH3
i NaOHI2
ii Conc. H2 SO4
OH
(II) COOC2H5 (Q) CHO
i LiAl Ot Bu 3 H/ 78o C
ii H3 O
CH3
iii Ac 2 O/ AcONa
iv Conc.H2 SO4 O
(III) H (R) O
O
i aq. KOH OH
ii Cu/500o C
O
iii CH3MgBr /C2H5 OC2H5
iv H3 O
v OH /
CH2 Cl
(IV) CH CH2 (S)
i HBr /H2 O2
ii KCN alc.
iii H3 O
iv Br2 / O
v KOH alc.
(T)
O O
(U) O
OH
OH
10. Which of the following options has correct combination considering List-I and List-II?
(A) (I), (U), (S)
(B) (II), (R), (T)
(C) (I), (U), (T)
(D) (II), (P), (T)
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Answer the following by appropriately matching the lists based on the information given in
the paragraph.
In the following List-I contains equation of state of a gas in different conditions of pressure and
List-II contains properties of that gas (P = pressure of gas, Vm = molar volume of gas, T =
temperature of gas, Z = compressibility factor, Urms = root mean square velocity of gas, M = molar
mass of gas, a and b are van der Waals constant, R = gas constant)
LIST–I LIST–II
(I) P (Vm – b) = RT (P) At constant temperature the value
of PVm does not change by
changing pressure
(II) a (Q) Z < 1
PVm RT
Vm
(III) 1 (R) Z is independent of P and T
PVm 2
MUrms
3
(IV) PM = dRT (S) Attractive forces are dominant
between gas molecules
(T) Z increases with increasing P.
(U) Z=0
11. Which of the following options has correct combination considering List-I and List-II?
(A) (II), (P)
(B) (III), (T)
(C) (III), (Q)
(D) (II), (S)
Answer the following by appropriately matching the lists based on the information given in
the paragraph.
In the following List-I contains equation of state of a gas in different conditions of pressure and
List-II contains properties of that gas (P = pressure of gas, Vm = molar volume of gas, T =
temperature of gas, Z = compressibility factor, Urms = root mean square velocity of gas, M = molar
mass of gas, a and b are van der Waals constant, R = gas constant)
LIST–I LIST–II
(I) P (Vm – b) = RT (P) At constant temperature the value
of PVm does not change by
changing pressure
(II) a (Q) Z < 1
PVm RT
Vm
(III) 1 (R) Z is independent of P and T
PVm 2
MUrms
3
(IV) PM = dRT (S) Attractive forces are dominant
between gas molecules
(T) Z increases with increasing P.
(U) Z=0
12. Which of the following options has correct combination considering List-I and List-II?
(A) (IV), (U)
(B) (I), (R)
(C) (I), (T)
(D) (IV), (Q)
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PART – B
(Numerical Answer Type)
This part contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
1. A current strength of 9.65 A is passed for 10 seconds through 1 L of solution of 0.1 M aqueous
CuSO4. The pH of solution is…..(Assuming that during the process there is no change in volume).
2. AB2 dissociates in A2+ and B ions in an aqueous solution. What is depression of freezing point of
aqueous AB2 solution containing 0.65 mole fraction of AB2 in 930 gm of water, if the ratio of the
observed depression of freezing point of the aqueous solution to the value of the depression of
freezing point in the absence of ionic dissociation is 2. Given K f of water is 1.86 K kg mol-1.
4. The ammonia prepared by treating ammonium sulphate with NaOH is used by CuSO 4.5H2O to
form a stable coordination compound. If 330 g of pure ammonium sulphate and 499 g of pure
CuSO4.5H2O are used in preparation and NaOH is used the excess, the moles of
copper – ammonia coordination compound produced is
(Atomic weight in g mol-1 H = 1, N = 14, O = 16, S = 32, Na = 23, Cu = 63.5)
6. Based on VSEPR theory, the number of 180o F – Xe – F angles in a molecule of [XeF3]+ [SbF6]
is
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PART – A
(One or More than one correct type)
This part contains 08 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
1. If all the values of x which satisfies the inequality log1/3 x 2 2Px P2 1 0 also satisfy the
inequality kx2 – kx – k2 0 for all real values of k, then all possible values of p lies in the interval
(A) [–1, 1]
(B) [0, 1]
(C) [0, 2]
(D) [–2, 0]
3
m 3 n 1
2. The real root of the equation 8x3 – 3x2 – 3x – 1 = 0 can be written in the form where
P
m, n and P are the positive integers (m n P), then
(A) m + n + P = 98
(B) m + n + P = 97
(C) m + n = 90
(D) n + P = 17
3. If 5x – y, 2x + y, x + 2y are in A.P. and (x – 1)2, (xy + 1), (y + 1)2 are in G.P. x 0, then (x + y)
equals
3
(A)
4
(B) 3
(C) –5
(D) –6
4. If the equation |z|(z + 1)8 = z8|z + 1| where z is a complex number and z(z + 1) 0 has distinct
roots z1, z2, z3 ….. zn (where n N), then
(A) z1, z2, z3, ….. zn are cyclic points
(B) z1, z2, z3, ….. zn are collinear points
n
7
(C) Re z
r 1
r
2
m
(D) I
r 1
m zr 0
5. If 100 C50 can be prime factorized as 2 3 5 78 ….. where , , , are non negative integers,
then
(A) <
(B) <
(C) +=+–1
(D) +=0
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6. f x x 2 x 1 , x (0, 2), then f(x) is discontinuous at (where [.] denotes greatest integer
function)
1 2
(A)
2
1 3
(B)
2
1 5
(C)
2
(D) 1
7. Let (x + 1)(x + 2)(x + 3) ….. (x + 100) = a0 + a1x + a2x2 + ….. a100x100, then 100a0 + 99a1 + 98a2 +
….. a99 is equal to
(A) 101 ! 1 2 ..... 100
2 3 101
x2 2
t 5t 4
8. Let f x
0
2 et
, then f(x) has
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Answer the following by appropriately matching the lists based on the information given in the
paragraph.
MM-I. Match the following list(s)
LIST-I LIST-II
ˆ
If a j 3 kˆ , b ˆj 3 kˆ and c 2 3 kˆ from a triangle, then the
(I) (P)
internal angles of the triangle between a and b is 6
b
2
f x 3x dx a
2
(II) If b2 , then the value of f is (Q)
6 3
a
5/6
2
(III) The value of
ln3 sec x dx is
7/6
(R)
3
1
The maximum value of arg for |z| = 1, z 1 is approaching
(IV) 1 z (S)
to the value
(T)
2
(U)
4
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Answer the following by appropriately matching the lists based on the information given in the
paragraph.
1 tan 1
(II)
If f tan 1
1 tan 1
tan , then the set f , 0
2
is (Q) (–, 0) (0, )
8 3 x 2
(III) The domain of the function f x sin1
is (R) [2, )
1 32 x 1
(IV) If f(x) = x3/2(3x – 10), x 0, then f(x) is increasing in (S) (–, –1] [1, )
(T) (–, 0] [2, )
(U) (0, )
PART – B
(Numerical Answer Type)
This part contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
2 2 20
1 1 1
1. If an 1 1 1 1
n n
(n 1), then the value of a
i 1 i
is equal to
2. Sum of the coefficients in the expansion of (2x + y + z)37 which are divisible by 37 can be written
abc 2
as ap bp c where p is a prime number and a, b, c are even, then is equal to
2
3. A point P is randomly selected from the region described by 3 |z| 5 (where z is a complex
1
number). If the probability that argument of P lies in the interval , is , then N is
4 4 N
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4. Let f(x) = ax4 + 6x2 + 3x + 7 and f(–4) = 2286 and f(4) = N. Then the number of ways in which the
number N can be resolved as a product of two divisor which are relatively prime
5. If the distance of two points P and Q from the focus of a parabola y 2 = 4ax are 4 and 9
respectively, then the distance of the point of intersection of tangents at P and Q from the focus is
x x
6. Let f(x) be continuous function such that f(0) = 1, f(x) – f x R. The area of region
7 7
bounded by the curve y = f(x) and coordinate axes is
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FIITJEE MOCK TEST
Q. Q. Q.
PHYSICS CHEMISTRY MATHEMATICS
No. No. No.
1. D 1. BCD 1. ABC
2. AD 2. ABD 2. AC
3. B 3. AB 3. AD
4. B 4. CD 4. BCD
5. ACD 5. CD 5. ACD
6. AD 6. BCD 6. CD
7. BCD 7. CD 7. AD
8. AC 8. BC 8. AB
9. B 9. D 9. B
1. 1.69 1. 3 1. 7
2. 2.30 2. 2.60 2. 5
3. 500 3. 82 3. 4
4. 4.70 4. 1.25 4. 16
5. 0.40 5. 6 5. 6
6. 3.14 6. 0 6. 3
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(MOCK TEST)
JEE (Advanced)
(07.05.2024)
PAPER – 2
PART – A
1. D
m(v 0 sin 60)2 v0 sin 60
Sol. Looking at B with respect to A : 2T
A B
a= T/m a= T/m
2. A, D
Sol. For ring: (Nr)dt = I0 (Rotation)
(N cos + N sin )dt = m 2gH (translation)
For wedge : (N sin ) dt = ( N cos )dt
3. B
Sol. Net force on the element at depth y,
dy
dF(y) = gy rd cos sin
cos
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Top view
y force
force
[0, ]
r
F dF(y)
0
H
ydF(y)
0
and effective point of application = H
dF(y)
0
4. B
T|| + dT||
Sol. dT|| dm r2 sin
2 element
MR2 a= r2
T TA (1 cos ) /2 T||
2
/2
5. A, C, D
5R
Sol. Q AB nCP T 2 (900 300) 3000R
2
In the process BC, P = T2
PV2 = constant
Molar heat capacity in the process BC,
R 3R R
C CV
(1 x) 2 (1 2)
R
C
2
R
QBC nCT 2 (300 900) 600R
2
P 1
QCA WCA nRTn C 2R 300n 1200Rn(3)
P
A 9
QCA 1320R
Wcycle Qcycle 3000R 600R 1320R 1080R
Wcycle
Efficiency of cycle, 100
Q supplied
1080R
100 36%
3000R
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6. A, D
Sol. B due to body diagonal = 0
0i 1 1 ˆi ˆj i
B due to edge along (using the result 0 (sin sin )
4 a / 2 3 3 2 4r
0i 2 2 ˆi ˆj
B due to face diagonal = along
4(a / 2) 3 3 2
Also, magnetic moment iA .
7. B, C, D
Sol. The motion will be helical. Also, at each collision, the motion will be mirror image of the motion
that would have happened without collision (mirror being the wall).
8. A, C
B0 r
Sol. Einduced =
2
600
R R/2
2 sec
2
Net torque = 6 d E I
cos
0
R/2 E
9. B
10. B
Sol. (for Q.9-Q.10):
For any case, Buoyancy B Vliquidgeff
where geff g a and T B mg ma
11. D
Sol. Find time constant by shorting the battery finding Reff across C0. Then = Reff C0.
12. A
Sol. Find time constant by shorting the battery finding Ceff across R0. Then = R0 Ceff.
PART – B
1. 00001.69
Sol. Let A : v0 & B : v0 before collision
v
Let A :
& B : v after collision
v0/2
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1 3 v
e = 1 v0
2 v . . . (i)
2 2
v v 3
Conserving momentum horizontally mv0 = mv + m 0 . . . (ii)
2 4
Solve for v.
2. 00002.30
Sol. i(t) = imax(1 – e-t/)
here, imax = V/3R
= 2L/3R
V
ibulb(t) = (2 e 3Rt/2L )
6R i(t)
2L
t = ln 2 .
3R
12 V
3. 00500.00
Sol. XL = L = 100 0.1 = 10
1 1 1 1 1 1 i
Z R 2 XL i 10 10i 10
10 10
Z (1 i) 5(1 i)
(1 i) 2
Z 5(1 i)
250
Net impedance of the circuit, Z 25
10
Z (R1 XCi) Z (15 XCi) 5(1 i)
Z 20 (5 XC )i
5 XC (25)2 (20)2
5 XC 15
XC 5 15
XC = 20
1
20
C
1 1
C 500F
20 20 100
C = 500 F
4. 00004.70
13.6Z2
Sol. 36% of 13.6 . . . (i)
n2
Also, nC = 10
2 . . . (ii)
hc
and, eV0 = - . . . (iii)
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5. 00000.40
Sol. W(t) = N0e-4t . . . (i)
dZ
W(t) . . . (ii)
dt
dX
3W(t) 2X(t) . . . (iii)
dt
Solve the three equations.
6. 00003.14
Sol. After passing through prism, ray from upper prism becomes horizontal & ray from lower prism is
inclined at 20 to the horizontal.
x = d sin 10 + d sin . . . (i)
1
Also, I = 4I0 cos2 (4I0 ) 2I0
2 2
1
cos2 = 2 . . . (ii)
2
Solve (1) & (2).
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Chemistry SECTION – II
PART – A
1. B, C, D
Sol. Cu conc.HNO3 Cu NO3 2 NO2 H2O
'K ' 'L ' 'M'
Cu NO3 2 KCN excess
K 3 Cu CN4 CN 2 KNO3
'T' 'S'
2. A, B, D
Sol. Al2O3 .xH2O NaOH Na Al OH 4
'Q' 'R '
Na Al OH4 CO 2 Al2O3 .xH2O NaHCO3
'R ' ' S' 'T'
3. A, B
Sol. 3Cl2 NH3 NCl3 3HCl
Excess
4. C, D
5. C, D
Sol. O O
O
OH
O
H C C H
Re d hot Fe tube
Anhyd. AlCl3
O
Zn / Hg HCl
OH
Conc. H2 SO4
O
6. B, C, D
Sol.
C NH2 Br2 KOH NH2 KBr CO2 H2O
O
7. C, D
8. B, C
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9. D
10. C
Sol. (I) O
O
CH3
O
NaOH I2
H2 SO 4
OH
O O O
(II) O O
CHO
OC2H5 i LiAl Ot Bu 3 H OH
ii H3 O
Ac 2 O/ AcONa
Conc. H2 SO 4
(III) H H
O H
O O
O O
KOH aq. O
Cu/
CH2 Cl H
CH2 OH
O
i CH3MgBr
ii H3 O
H
O
OH
CH3
O O
(IV) CH CH2 CH2 CH2 Br CH2 CH2 CN
HBr /H2 O2
KCN
H3 O
Br
O
CH2 CH2 COOH COOH
Br2 /
OH
Alc. KOH
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11. D
12. C
PART – B
1. 00003.00
1
Sol. Cu2 2e Cu 2H
H2 O O2 2e
2
Q = 9.65 × 10 = 96.5 C
96.5
Moles of H2SO4 produced = moles of Cu2+ reduced 5.0 104
2 96500
5 10 4
Conc. of H2SO4 (M) = 5 10 4 mole / L
1
H 2 5 10 4 10 3 mole / L
pH = - log[H+] = 3
2. 00002.60
Sol. Tf iK f .m
0.65 1000 2 186 0.65
2 1.86 = 4 × 0.65 = 2.6
930 93
3. 00082.00
234 234
7 234 206
Sol. 238
92 X
90 Y
88 Z 89 L 75 M
7 + 75 = 82.00
4. 00001.25
Sol. NH4 2 SO4 2NaOH 2NH3 Na2SO4 2H2O
n 2.5 n5
CuSO 4 .5H2O 4NH3 Cu NH3 4 SO 4 5H2 O
n2 n5
limiting
5
Hence, moles of [Cu(NH3)4]SO4 = 1.25
4
5. 00006.00
Sol. XeF4 H2 O
Xe XeO3 HF O 2
'A' 'B '
Oxidation state of Xe = 0
Oxidation of Xe in XeO3 = +6
6. 00000.00
Sol.
F
Xe F
F 180o
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Mathematics SECTION – III
PART – A
1. A, B, C
Sol. We have log1/3 x 2 2Px P2 1 0 x2 + 2Px + P2 + 1 1
(x + P)2 0 x = –P. Now x = –P satisfy kx2 + kx – k2 0
kP2 – kP – k2 0 k2 + kP – k P2 0 k2 – k(P2 – P) 0
Apply D < 0, (P2 – P)2 0 P2 – P = 0 P = 0 or 1
2. A, C
Sol. 8x3 = 3x2 + 3x + 1 9x3 = x3 + 3x2 + 3x + 1
9x3 = (x + 1)3, x + 1 = 3 9x
1 92/3 91/3 1
x
3
9 1 9 1
3
81 3 9 1
=
8
3. A, D
Sol. (5x – y) + x + 2y = 2(2x + y) 2x = y
(x – 1)2(y + 1)2 = (xy + 1)2 (x – 1)(y + 1) = (xy + 1) –x – 1 = 1
1 1
x = –2, y = –4 and 2x2 – x – 1 = –2x2 – 1 x = , y =
4 2
4. B, C, D
Sol. |z|(z + 1)8 = z8|z + 1| |z| |z + 1|8 = |z|8 |z + 1| |z + 1|7 = |z|7 |z| = |z + 1|
5. A, C, D
100 100!
Sol. C50
50!50!
Exponent of 2 in 100! = 97
Exponent of 2 in 50! = 47
6. C, D
Sol. x2 – x + 1 = 2, x2 – x – 1 = 0
1 1 4 5 1
x x , (since x > 0)
2 2
x2 – x + 1 = 1 x2 – x = 0 x = 0, x = 1 since x (0, 2)
7. A, D
1
Sol. Replace x by and differentiate and put x = 1
x
8. A, B
2x x 4 5x 2 4
Sol. f x 0 2x(x2 – 4)(x2 – 1) = 0 2x(x – 2)(x + 2)(x – 1)(x + 1) = 0
2 ex
9. B
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10. D
Sol. (for Q.9-Q.10):
4 4 12 1 2
AB c 2 3 , AC b 2 , BC a 2 , cos
222 2 3
A
c b
B C
a
b b
1
(I) (Q) f x 3x dx a2 b2 f x dx b2 a2 f(x) = x f
2 6 6
a a
(II) (P)
3 1 1
ln sec x tan x 7/6 =
5/6
(III) (S) I ln 3 ln
ln3 ln3 3
1 u 1
(IV) Let u z , |z| = 1 |u – 1| = |u|
1 z u
1
Locus of u is x maximum argument of u is approaches towards
2 2
1
x
2
11. A
12. D
Sol. (for Q.11-Q.12):
2iz 2i 1
(I) (S) Re 2
sin if z = cos + i sin , since |z| = 1
1
1 z z
z
1
Range of is (–, –1] [1, )
sin
(II) (R) R1 R1 + R3
0 0 2
f tan 1 tan 2 1 tan2 = 2 sec2 Range (2, )
1 tan 1
8 3 x2
(III) (T) 1 2x 2
1 x (–, 0] (2, )
1 3
3 1/2 15 1/2
(IV) (R) f(x) = x3/2(3x – 10), x 0 f(x) = x 3x 10 3x3/2 = x x 2 0 x 2
2 2
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PART – B
1. 00007.00
2 2
n2 n 1 n2 n 1 4
Sol. an =
n 2 2
n2 n 1 n 1 n2
20
a
1
1
202 212 1 7
n 1 n 4
2. 00005.00
abc 2
Sol. Total sum = 437 , 437 237 2 = sum of coefficients divisible by 37 =5
2
3. 00004.00
1
Sol. Given in the figure, P
4
arg z =
4
arg z =
4
4. 00016.00
Sol. f(x) – f(–x) = 6x, f(4) – f(–4) = 24 N = f(4) = 24 + 2286 = 2310 = 2.3.5.7.11
Number of divisors = 2n – 1 = 16
5. 00006.00
Sol. If tangent of P and Q meet at T, then ST2 = SP SQ ST2 = 36, ST = 6
6. 00003.00
x x x x x x x 1 1 1
Sol. f x f f n1 f n n = f x f n 1 2 n1
7 7 7 7 7 7 7 7 7 7
6
x x
Taking x , f(x) – f(0) = . Area =
6 1 6 dx 3
0
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