Safety Data Sheet

CAUSTIC SODA
Section 1: Chemical Product and Company Identification

Product Name: Caustic Soda Contact Information:

CAS#: 1310-73-2 OVA CHEM SDN. BHD.
No 6, Jalan Tasik Utama 7
Medan Niaga Tasik Damai
RTECS: Not available. 57000 Sungai Besi, Kuala Lumpur.
Tel/Fax: +603 9054 1203
TSCA: TSCA 8(b) inventory: All components are listed or
exempted.
For emergency assistance, call: +6012 368 3559
CI#: Not available.
Synonym: Sodium hydrate
Chemical Name: Sodium Hydroxide
Chemical Formula: NaOH

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sodium Hydroxide 1310-73-2 99 %

Toxicological Data on Ingredients: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects

Main Hazard: May cause eye, skin respiratory and respiratory irritation.

Eyes: Eye contact will cause irritation and inflammation with possible corneal damage if prompt action is not taken.

Skin: Skin contact can produce irritation and inflammation.

Inhalation: Inhalation of dust particles will produce irritation to respiratory tract, characterized by sneezing and coughing.

Ingestion: Dust particles will cause irritation and possible damage to mouth, throat & gastro intestinal tract if prompt action is not
taken.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of clean water or saline
fluid for at least 15 minutes. Get medical attention immediately.

Skin Contact: Wash with soap and water at least 15 minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Get medical attention if irritation develops.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Loosen tight
clothing such as a collar, tie, belt or waistband. Get medical attention.
Ingestion:
Wash out mouth with water. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical attention if symptoms appear.

Section 5: Fire and Explosion Data

Flammability of the Product: Not flammable.

Combustion hazard: Not hazardous combustion product but irritating fumes may be released.
Flash Points: Not combustible.

Flammable Limits: Not available.

Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not available.

Explosion Hazards in Presence of Various Substances: None.

Fire Fighting Media and Instructions: Raise the alarm and then tackle the fire if safe to do so. Use an extinguishing agent
suitable for the surrounding fire. Water may be ineffective. Prevent spillage from entering sewers, drains or watercourses.

Personal Protection: Standard fire fighting protective equipment with approved self contained breathing apparatus.
Special Exposure Hazards: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products: Not available

Section 6: Accidental Release Measures

Personal Precautions: If specialized clothing is required to deal with the spillage, take note of any information in section
8 on suitable and unsuitable materials.

Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.

Spillages: Sweep or shovel up spillages and place in suitable waste container for disposal in accordance with regional
procedures and regulations. Flush away any residual spillage materials with water.

Section 7: Handling and Storage

Precautions: Put on appropriate personal protective equipment. Eating, drinking and smoking should be prohibited in areas where
this material is handled stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not
ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Empty
containers retain residue and can be hazardous. Do not reuse container.

Storage: Store in accordance with local regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials.
Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
 Section 8: Exposure Controls/Personal Protection

Exposure controls: Use in a well-ventilated area and minimized airborne dust. An eye wash station and safety shower should
be located in the mixing and storage area.

Eye and Face Protection: Wear approved chemical safety googles and face shield for protection against splashes.

Hand Protection: Use chemical resistant gloves to prevent contact with skin.

Body protection: Standard cover are usually sufficient. Use a chemical apron or chemical over suit for prolonged contact.

Respiratory protection: A standard dust mask may be adequate. Use an approved respirator fitted with a dust filter for high
dust levels or if dust is a nuisance.

Additional Comments: Care is required when handling used sacks as they will contain residual product which is alkaline.
Contaminated waste (e.g disposable chemical over suit) must be processed in accordance with site procedures.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid, crystalline, highly hygroscopic, flakes, blocks, microgranules
Odor: Odourless.
Taste: Not available.
Molecular Weight: 40.01 g/mol
Color: White.
pH : > 13

Flash Point: Not Applicable.

Boiling Point: 1,388 ˚C, Pressure: 101.3kPa

Melting Point: 318.4 0C, Pressure: 101.3kPa

Specific Gravity : 1.14 kg/m3

Relative density: 2.13 at 20 0C

Critical Temperature: Not available.

Vapor Pressure: 1 hPa at 739 0C
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Soluble, Alcohol (Glycerol)
 Section 10: Stability and Reactivity Data

Stability: The product is stable.

Possibility of hazardous reactions: Potential exothermic hazard when react with strong acids. May be corrosive to metals.
Risk of violent reaction. Risk of explosion. Reacts violently with water.
Hazardous polymerization: under normal conditions of storage and use, hazardous reactions will not occur.

Conditions of Instability: Do not expose to direct sunlight. Do not overheat to prevent thermal decomposition. Do not expose to
moisture and freezing condition.

Materials to avoid: Avoid contact with acids, metals, water, aluminium, alloys and oxidizing agents.

Hazardous decomposition products: Hydrogen

Section 11: Toxicological Information

Toxicity: Product is an irritant and corrosive due to alkalinity.

Acute Toxicity Data: LD 50 Oral (Rat) 4200 mg/kg

Carcinogenicity: Not identified as Carcinogen by the following bodies: IARC ( International Agency for Research on Cancer)
NTP (National Toxicology Program OSHA (Occupational Safety and Health Administration).

Section 12: Ecological Information

Mobility: Airborne Dust particles and in solution.

Biodegradibility: Material is inorganic and is not biodegradable.

Persistence: Material is alkaline and may raise the pH of surface water.

Bio Accumulation: Not known

Eco Toxicity: High Alkalinity is a potential hazard to plant and marine life. High pH values and sodium content can damage soil
structure. Concentration above 1 ppm or pH values above 10.5 may be fatal to fish and other marine life.

Section 13: Disposal Considerations

Product Disposal
Dispose of waste material in accordance with regional procedures and regulations.

Packaging Disposal
Empty packaging may contain residual material that could be harmful if misused by those unfamiliar with the product. Dispose in
accordance with regional procedures and regulations.

Section 14: Transport Information

Summary: Dangerous Cargo

UN/ID nr: 1824
Hazchem Code: 2R

ADR / RID – Road / Rail: 8 (42b)

Hazard Class: 8

Packing Group: II
 Section 15: Regulatory Information

European Labeling In Accordance with EC Directives:

Hazard Statements : Causes serious eye irritation

May be harmful if swallowed
Causes skin irritation
May be harmful if inhaled.

Precautionary statements : Avoid breathing dust

Do not get in eyes , on skin or on clothing
Wash hands thoroughly after handling.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Last Updated: January 2013

NFPA Rating Section:

The information above is believed to be accurate and represents the best information currently available to us. However, we make
no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their
particular purposes. In no event shall OVA Chem be liable for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if OVA Chem has been advised
of the possibility of such damage.