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Fundamentals of Smart Materials
Fundamentals of Smart Materials
Edited by
Mohsen Shahinpoor
University of Maine, USA
Email: shah@maine.edu
Print ISBN: 978-1-78262-645-9
EPUB ISBN: 978-1-78801-946-0
A catalogue record for this book is available from the British Library
Apart from fair dealing for the purposes of research for non-commercial purposes
or for private study, criticism or review, as permitted under the Copyright, Designs
and Patents Act 1988 and the Copyright and Related Rights Regulations 2003, this
publication may not be reproduced, stored or transmitted, in any form or by any
means, without the prior permission in writing of The Royal Society of Chemistry
or the copyright owner, or in the case of reproduction in accordance with the
terms of licences issued by the Copyright Licensing Agency in the UK, or in
accordance with the terms of the licences issued by the appropriate Reproduction
Rights Organization outside the UK. Enquiries concerning reproduction outside the
terms stated here should be sent to The Royal Society of Chemistry at the address
printed on this page.
Whilst this material has been produced with all due care, The Royal Society of
Chemistry cannot be held responsible or liable for its accuracy and completeness,
nor for any consequences arising from any errors or the use of the information
contained in this publication. The publication of advertisements does not
constitute any endorsement by The Royal Society of Chemistry or Authors of any
products advertised. The views and opinions advanced by contributors do not
necessarily reflect those of The Royal Society of Chemistry which shall not be
liable for any resulting loss or damage arising as a result of reliance upon this
material.
Printed in the United Kingdom by CPI Group (UK) Ltd, Croydon, CR0 4YY, UK
Preface
Mohsen Shahinpoor
University of Maine
Acknowledgements
Mohsen Shahinpoor
Contents
1.1 Introduction
Homework Problems
Abbreviations and Acronyms
2.1 Introduction
2.2 Piezoelectric Ceramic Actuators, Energy-harvesters, and
Sensors
2.3 Constitutive Modeling of Piezoelectric Materials
2.4 Applications
Homework Problems
References
4.1 Introduction
4.2 Constitutive Equations and Electrostrictive Properties
4.3 PMN Impedance Mismatch
4.4 PMN Suppliers
4.5 Electrostrictive Materials Compared to Piezoelectric
Materials
4.6 Conclusions
Homework Problems
References
5.1 Introduction
5.2 Ionic PAN Fibers in General
5.3 Preparation of C-PAN
5.4 Force–Strain Variations in Active PAN Fibers
5.5 Variations in the Length of Modified PAN Fibers versus the
pH Variations of the Solutions in Which they are Contained
5.6 Effect of Different Anions on the Generative Force
Characteristics
5.7 Generative Force Characteristics: Effect of Acidity
5.8 Performance of a PAN Bundle Artificial Muscle
5.9 Electrical Activation of Conductive PAN (C-PAN) Muscles
5.10 Electric Current Effect on Force Generation
5.11 Mathematical Modeling of the Contraction and Swelling of
Active PAN Muscles
5.12 Modeling of the Expansion and Contraction of PAN Muscles
Based on Electrocapillary Effects
5.13 Conclusions
Homework Problems
References
6.1 Introduction
6.2 Various Magnetostrictive Effects
6.3 Terfenol-D Availability
6.4 Properties of Terfenol-D
6.5 GMS Constitutive Equations
6.6 Conclusions
Homework Problems
References
7 Review of Giant Magnetoresistive (GMR)
Materials
Mohsen Shahinpoor
7.1 Introduction
7.2 Ordinary Magnetoresistance (OMR)
7.3 Spintronics and GMR Effect
7.4 Applications of GMR
7.5 Modeling
7.6 Role of Electron Spin in GMR
7.7 GMR in Granular Structures
7.8 GMRs as Smart Sensors
7.9 Hard Disk Drives
7.10 Conclusions
Homework Problems
References
8.1 Introduction
8.2 Magnetoviscoelasticity of Ferrogels
8.3 Constitutive Equations for Ferrogels
8.4 Analysis of Dynamics of Magnetic Gel Actuators in a
Magnetic Field
8.5 Nonhomogeneous Deformation of Ferrogels
8.6 Concluding Remarks
Homework Problems
References
9 Review of Electrorheological Fluids (ERFs)
as Smart Material
Mohsen Shahinpoor
9.1 Introduction
9.2 Giant Electrorheological Effects (GERF)
9.3 Modeling of ERFs
9.4 The Bingham Model
9.5 Krieger–Dougherty
9.6 Kinetic Chain Model
9.7 Applications
9.8 Automatic Transmission and ERFs
9.9 Conclusion
Homework Problems
References
12.1 Introduction
12.2 Shape Memory Effect (SME)
12.3 Stress–Strain–Temperature Dependence of SMAs
12.4 SME Variations
12.5 One-way SME (OWSME)
12.6 Two-way SME (TWSME)
12.7 Constitutive Equations for SMAs
12.8 Tanaka Model
12.9 The Liang and Roger Model
12.10The Brinson Model–
12.11Cardiovascular Superelastic Stents
12.12Medical Applications
12.13SMA Engineering and Industrial Applications
12.14Conclusions
Homework Problems
References
13 Review of Magnetic Shape Memory Smart
Materials
Mohsen Shahinpoor
13.1 Introduction
13.2 MSMA Actuators
13.3 Sensing and Multi-functional Properties of MSMMs
13.4 Typical MSMA Materials
13.5 Manufacturing of MSMAs
13.6 MSM Mechanism
13.7 Magneto–Mechanical Constitutive Modeling of MSMs
13.8 Some Additional Applications of MSMs
13.9 Conclusions
Homework Problems
References
14.1 Introduction
14.2 Shape Memory Polymers (SMPs) in Temperature Fields
14.3 Thermoplastic SMPs
14.4 SMP Product Development
14.5 Thermomechanical Constitutive Equations for SMPs
14.6 Conclusion and Outlook
Homework Problems
References
15 Review of Smart Materials for Controlled
Drug Release
Carmen Alvarez-Lorenzo and Angel Concheiro
15.1 Introduction
15.2 Drug Dosage Forms and Drug Delivery Systems
15.3 Interest of Smart Materials for Controlled Drug Release
15.4 Stimuli to Be Exploited and Applications
15.5 Conclusions and Future Aspects
Homework Problems
References
16.1 Introduction
16.2 Introduction to Mechanochromic Materials
16.3 Some Examples of Mechanochromic Polymers
16.4 Mechanochromic Devices Based on Marine Biological
Systems
16.5 Introduction to Mechanical Metamaterials
16.6 Background to Metamaterials
16.7 Electromagnetic Metamaterials
16.8 Elastic Metamaterials
16.9 Acoustic Metamaterials
16.10Structural Metamaterials
16.11Nonlinear Metamaterials
16.12Cloaking Devices
16.13Seismic Protection
16.14Antennas
16.15Absorber
pre-programmed drug release systems, formulations that provide
discontinuous release as a function of specific signals (stimuli) are
advantageous in many situations. The when, where and how drug
release triggering occur require detailed knowledge of the changes
that the illness causes, in terms of physiological parameters. These
changes can be characterized in terms of biomarkers (e.g., glucose,
specific enzymes, or quorum sensing signals in the case of infection)
and physicochemical parameters (pH, ions, temperature,
glutathione) that may be exploited as internal stimuli. When the
physio-pathological changes are too weak or non-specific, the
application of external stimuli may be an alternative. External
sources of temperature, ultrasound, light, and magnetic or electric
fields may allow for the focal switch on/off of drug release.
Mechanochromic smart materials, as well as mechanical
metamaterials, are then reviewed. In particular, two recent families
of smart materials, namely mechanochromic materials and
mechanical metamaterials, respectively, are described.
Mechanochromic materials change their optical properties, and in
particular, photoluminescence characteristics, if subjected to
mechanical loading. Metamaterials are materials that are not
ordinarily produced in nature. Smaller units rather than the
properties of the host material play a fundamental role in materials
behavior. Metamaterials are nanocomposite materials made up of
periodically repeated micro or nano units of metals, alloys, and
plastics that exhibit properties different from the natural properties
of the participating materials.
Ionic polymer–metal composites (IPMCs) are then reviewed. Ionic
polymeric networks contain conjugated ions that can be
redistributed by an imposed electric field and consequently act as
distributed nano actuators, nanosensors, and energy harvesters.
This chapter briefly presents the manufacturing methodologies and
fundamental properties and characteristics of ionic polymers such as
IPMCs. Gel-based and chitosan-based conductor composites have
also been considered as electrically active composite smart materials
similar to IPMCs. Following the description of IPMCs, a review of
smart ionic liquids is then presented. Ionic solids such as sodium
Another random document with
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The Project Gutenberg eBook of A year in
Russia
This ebook is for the use of anyone anywhere in the United
States and most other parts of the world at no cost and with
almost no restrictions whatsoever. You may copy it, give it away
or re-use it under the terms of the Project Gutenberg License
included with this ebook or online at www.gutenberg.org. If you
are not located in the United States, you will have to check the
laws of the country where you are located before using this
eBook.
Language: English
BY
MAURICE BARING
AUTHOR OF “WITH THE RUSSIANS IN MANCHURIA,” ETC.
DEDICATED
TO
Dr. Johnson
PREFACE
St. Petersburg
CONTENTS
PAGE
PREFACE ix
INTRODUCTION xiii
CHAPTER
I. ST. PETERSBURG TO GODZIADAN 1
II. JEN-TZEN-TUNG 11
III. THE STRIKE AND THE MANIFESTO OF OCTOBER 21
(30TH) 17TH
IV. MOSCOW AFTER THE MANIFESTO 31
V. ST. PETERSBURG BEFORE THE SECOND STRIKE 39
VI. MOSCOW—THE DECEMBER RISING 43
VII. MOSCOW—AFTER THE RISING 63
VIII. THE “INTELLIGENZIA” 75
IX. THE BEGINNING OF THE REACTION 84
X. CURRENT IDEAS IN ST. PETERSBURG 97
XI. DOSTOIEVSKI’S ANNIVERSARY 121
XII. THE POLITICAL PARTIES 128
XIII. IN THE COUNTRY 137
XIV. THE ELECTIONS 152
XV. EASTER AT MOSCOW—THE FOREIGN LOAN 162
XVI. THE AGRARIAN QUESTION—ON THE EVE OF THE 178
DUMA
XVII. THE OPENING OF THE DUMA 191
XVIII. FURTHER IMPRESSIONS OF THE DUMA 202
XIX. THE DEADLOCK 212
XX. CURRENT IDEAS ON THE DUMA 225
XXI. THE BEGINNING OF DISORDER 233
XXII. PRINCE URUSSOFF’S SPEECH 250
XXIII. NAZARENKO, AND OTHER PEASANT MEMBERS 258
XXIV. THE DISSOLUTION OF THE DUMA 281
XXV. IN THE COUNTRY AFTER THE DISSOLUTION 288
INDEX 309
INTRODUCTION
August 8, 1905.
I left St. Petersburg this evening for Manchuria. The one absorbing
discussion in St. Petersburg is the question of the peace negotiations.
Will there be peace or not?
August 11th.
I started for Irkutsk on the 9th from Moscow. The train is crowded
with people—officers going to the war, men of business going to
Siberia, women and children. It is exceedingly hot. The last time I
travelled in this Trans-Siberian express the winter had just given way
to the leafless and bare aspect of early spring. Now we travel through
great stretches of green plains, past huge fir-woods which are burnt
and browned by the heat. The topic of the peace negotiations
continues to prevail above all other topics. I am constantly asked my
opinion. We have just received the latest telegrams from Portsmouth.
A man of business asked me if I thought there would be peace. I said
“Yes.” “There won’t be,” he replied. The railway line is fringed all the
way with pink flowers, which, not being a botanist, I take to be
ragged robin. At night the full moon shines spectral and large over
the dark trees and marshes, and every now and then over stretches of
shining water. The officers discuss the war from morning till night.
They abuse their generals mercilessly. They say that it is impossible
for Russians to look foreigners in the face. In my compartment there
is an army doctor. He assisted at the battle of Mukden and is now
returning for the second time to the war. He tells me that he wrote a
diary of his experiences during the battle and that he is unable to re-
read it now, so poignantly painful is the record. He trusts there will
not be peace. He is sanguine as to the future. He loathes the liberal
tendencies in Russia and detests Maxim Gorki. Yet he is no Jingo.
A gentleman from Moscow, and his wife, on the contrary, inveigh
bitterly against the Government and the war. (I saw these same
people again at Moscow after the December rising. Their house was
situated in a street where the firing had been heavy and abundant.
They had had enough of revolution and blamed the revolutionaries
as severely then as they now blamed the Government.) We
constantly pass trains full of troops going to the war. The men all ask
the same question: “When is peace going to be?” They ask for
newspapers and cigarettes. I gave some of them some bottles of
whisky, which they drank off then and there out of the bottle. An
amusing incident happened last evening. We had stopped at a siding.
Everybody had got out of the train. I was walking up and down the
platform with one of the passengers. We saw a soldier throwing big
stones at the window of the washing compartment.
“What are you doing that for?” we asked.
“I want to speak to his Honour,” the soldier said; “he is washing
his face in the washing-room.” And through the window of the
compartment, lit by electric light, we could see the silhouette of an
officer washing his face.
“Why don’t you go and knock at the door?” we asked.
“They are” (to speak of a person in the third person plural is
respectful in Russian, and is always done by inferiors of their
superiors)—“they are ‘having taken drink’ (Oni Vipimshi),” he
replied, and then he added, lest we should receive a false impression,
“His Honour is very good.”
As we passed train after train of troops I reflected on the rashness
of prophecy. How often I had heard it said in London, when the war
broke out, that the line would break down immediately. Even when I
reached Mukden I heard people say that the line could not possibly
last through the summer, and here it is supporting gaily train after
train in the second year of the war.
We arrived at Irkutsk on the morning of the 17th and took the train
for Baikal. At Irkutsk station there was a train of sick soldiers
returning from the war. They begged for newspapers. The tedium of
their long journey is, they say, intolerable. They say there has been a
good deal of typhus in Manchuria.
We crossed the lake in the steamer. Its summer aspect is far less
striking than the strange glory which it wears when it is frozen, and
the distant mountains seem like “a sunny pleasure dome with caves
of ice.” In summer the waters are blue, the nearer hills grey and the
distant mountains blue, but with nothing strange or unreal about
them. Yet when the sunset silvered the grey tints and spread a ragged
golden banner in the sky, the lake was extremely beautiful in another
way. At Baikal station there was the usual struggle for places in the
train. How well I remembered the desperate struggle I had gone
through to get a seat in a third-class carriage at this same place last
year! This time it was in the first-class carriage that the conflict took
place. An engineer got into the same carriage as I did. He occupied
one of the lower berths and I the other. Presently a lady arrived,
bound for Chita, and looking for a place. She came into our carriage
and asked to be allowed to have one of the lower berths. The
engineer flatly refused and said that he had occupied his seat and
had a right to keep it. I told her I would let her have mine with
pleasure. She occupied it and went out. I moved my things into the
upper berth. “Why on earth did you give up your seat?” the engineer
asked. “You had a right to keep it.” When the lady came back she
said to me: “Ah! you are evidently not a Russian; no Russian would
have given up his place.” The engineer turned out to be quite a good-
natured sort of person, but there is something about trains which
makes people who are by nature mild and good-natured turn into
savages, and instils into them a passionate determination to cleave to
their rights. The next morning another man arrived in our carriage,
with a large basket and a second-class ticket. This upset the engineer,
who complained to the “Controller” of the train, and the poor man
was turned out. The engineer snorted and said: “There’s an insolent
fellow for you.” The lady was the wife of an engineer who was
employed at Chita; and she told me much about life in Chita: how
hard times were, owing to the war, how scarce food was getting—
“Und wie so teuer der Kaffee,
Und wie so rar das Geld!”