CHAPTER-5OLUTJON

MULTILE CHOICE QUESTION

08-Wnich of the followng agueous soluton should
hase tie highest boiling point
) 10M NhOH b) 10M NazOy
C) 20M NHNO d).0M kN02
Song More the na of Solutes,more will be
elevation in boilng point and more ole
be boiling point
NaoH Nat+OH n=2
Na,SOy 2Not+So ) n=3
NHyNO3 NHttNO3 ) n=
KNO Kt+NO7
Solef NasS0y has
has highest boilin point
option (b) IS Correct

08- Theunit ebuliascopic Censtant is

a)tg mort 6)mol Kgk o gmor d) mol kg
Son8 we know,
kh = ATb

mol kg
Opt+on a) 1s correct
08- The talues of VantHoff factors for kCl,
NhCi nd bsOy respectioely 3are
a)2,2and2 b) 2,2 and 3
d) I,1 and
Son

NaceNat+ Ce- i=2

C,Sou 2rt+ So i=3

Option Cb) IS correct

8- Value e Henhy' b. Constont KH iS
a) Graater for gases wrth higher solubl
b) Gireaten for !ases wrth lesser B0lubility
C) Constant for all gases
c) Not relaled to the solubility o goses

Q8 A colligatise property of Soltren dependS

On the
a) No of Solute particies
b) No. átGms in Solute molecule
c) Total no e solute and Sol9eit molecules
)Mass of solute porlicles
Sol^8- Option (a) is correct
 08 Coligatiue property of a Solition cepends

a) Molarity b) No of moles of solte

CONo k moles of solvent d)Natie of solute
Sol8- Opion Cb) IS_Correct

08- which of the follouwing solution wl

the least freezing pont? nae
)o-M urea o)O.lM Acetic acid
c)oM Nace d)o-1r CalCIwn chlorice

Son8- Urea does not d1ssoCIatron , n01 mol

CHsCoOHHgco0 +H*yn=2xo-l =02mol
Nace Nat + Ce n=2OI=0:2mol
Cace,at22Q n=3x0|=0-3mol
Option d) IS Corret

08- A
A semipemeable membrone permts the

a) solution b) Solsent c) Solute )Nerthex

Solute nor Solsent
So8 ption b) |S COrnect
 Q The decreaSing OrceA of QBmottc preszu
-he t log cRucase)CP1), Iog wea CP) and
log suCrose" Pa) at 73, when d1ssolsed
in 400 mL of wcate seporately is
b) P2>P3>P2
c) P3>P2> P1 d) P2>pl> P3
Song We Cnow
and Cx
M

shere M= Molar mas

Maucnose >Mgucoe>Mrea
Aurea ^gucObe> AsucrQbe
PP>P3
Optien Cd) is Corect

08- Molarity of q0 pahe watar is

a) 50 M b) 555M c) 5M d)Nne

n= 90O =50 mols

f these
Sol8
18
A008 wata = 900
o0 mL wates
 We now
Molarity =hxlo0o
VCinmL)

500
55.5M
opttên b) Is cOsect
C& Mole fraction f Solute in 25m
a)ou3 b)O043 c)43
SoB- 25m ag: Son means 25 mol
Solute in
loo03 Sol bentwate)
nË=Smol n=\0O0 =G5-5mol

25 -25 =0-043
nitn2 55.5 +2-5 53

option (6)IS Corret

0F AHso,, son contin 0.0% by weght
tsQ4 and has a specific graorty of
its nor ma ty is approximalel?
b)8 C) 28-2 a)36
song go%o by seght H SOy meOns
SO Ht, SOu in

Wseu=S0}
58 82 m
Vson
nHgso= 80 0-2163 moL

Molarty nHsoyxI000
Vson

O163\00

Ncxmality - Basicíty zMoarty

24.6N
Option (o 1Scorrect
 0g Oon dissolon Cemrron Salt in waten ,
the
a) treeZing pOint of Hs0 incyrases
6) boiling point of H2O decreases
-C) boiling pont ef He0 incrQses
d) boiling point of H0 remain some
COhect

08- The nrt of

obullioscopic censtant
aEkgmo|- b molkg C) Emollg d) none
fthese
Sore option Ca) s Cosect
O8- An a9ueeus SOn of
methanol in
Sater has aps pres3se
a)eual to that ef of metfanol
b) egual to tat of ateA
C) mohe -thaan thcit f wate,
d) less than that of wate,
Sor8- Gon
show +e desiatGr
Methanol
Optron Cc) s corre ct
08 The molality of pwe water is
a) 55.5 b) 20 c) 13 d)lo
Soln8 Wto =
natos = Lo00 555 hmol

Molalty = hwate
Wwater
555
lo00

= 55 5 m

ption (a) s corect

Q8- The no. ef moles ef Nace in 3 ltre f3
SOIn
a)1 b)3 c)4 d)2
Soln8 3M Nacl Son means
Nace in 4L Son 3moles of
In 3L Sol ) there are q moles ot Nace
Option CC) 1s COrect

08-Theamunt f solute
IoL f decCimolar Solh (g reecl -to prepar
a)O-0lmol )O2 mol
c)O05 mol d) mol
 So1n8 Decimnolar SOn means O-lmol solte
1S present 1L Son
Solte In ToL S o = IOXO-l=îmol
Optien a) is COrect

8 One Eilogam of wate contains

NaoH The Conc entratien ofthe
Solution iS best pressed as
a)01 molal D) O-| mola
c) decinormal d) about O- | mol
Son8 Option Ca) IS Correct

O8- The n moles of Nacl in 3L sf

3M Solutien is
b)3 a)
CC) Is
Sorg Optren Co 1S Correcl

Q8- Molalty is expressec in

a) Guaml itre b) mole|litre
c) litreImnole d) mole l
Solg- Opton la) 1s Correct
 08- which of the not affected by
temperature?
a) Normality b) Molal ty c) Molarity
d) formalty
Sorg- Volwme tenpe
IS affectecl bynot
rature. So, molaity
affected by temp
optin (b) 1s Corret
O8 Isotönic Solution hase egual
a) Vaph pres8Ure b)OSmotic presswse
) boiln point d) freezing polnt
So1"8- option (b) s correct

98-The molal elesation COnstant

depords upen
natwre of Solute b) hatue of soleht
Solh
o Vapswr presswe of so" b) entthalpy
Change
or8 Option (6) is Correat
 8 Molaity s expressed as
a L/mol C) mol lcoo3
Solg Optien (b) IS c o r r e t

QS hhich of follong is coilgpte

property?
a)Vapr presswre
b) relatrie (owe in apr presswre
c) losering n opus pressure
a) all of these
SON8- option Cb) IS Correct

Q8-nich liquic
Ene f the -folowns binary lguid
mxtures exhibits negatrse desatron frem
Racult6 law?
a) h- Hexane and n-heptne
b) Chlorofom- Acetene
Car bôn dislphideAcetone
c)
d) Bromoethane- chloroethene
SOrg Option (b) S Correct
 O8 Constant boiling mcte areal
a) deal o|h b)Azeotropes
cIsotonic Soh d) Ngne of these
Option (b) is correct

Q8-resbhe COOfer educes CocCing time

becebe
a) heat s more esenly c1str1 buted
b)-the high pressuse tend to rises the foo
C)the balng point of food wnde
presswe is elevated
a)the boi ling pont ot water in cookes
(S depressed
So lh8 Opten CC) 1S correct

Q& Corm phr IS Gfton wbed in molel

-ar mass detemnotin because
a) it has hi8n coryoSCopi c Constant
c) it 1S GolÝent for orgonic ulstane
IS (0latile
d) it IS read1ly aUaulalole
Solne Opton Ca) |S Conrect
 2OR 3MARK NuMeRICAL QUESTI ONS
4A Commlally awalable samu eh slbhu'c ad u IS). Hso, by
calcutat maloity:
welght Cdanit 1-logml)H,s0,,
1Sgs H,S0, eans Iag o, în 854 oh Yatn
Msla mal o< H, SOu- IX2+32+16X4
2+32+64

To 4hd tte valume oB daution,

Mads lo0
V=

No. cmos = Given madl

Moleculos mad!
5_- O1530 moes
98

Mdaty Velume o selutien

X 1000

O:1530
-XID00 =1-68 M
90:90
2 ACemucally aualable damble o dulbhu actd 389. H by
’36 cf HL mtans 389 o7 Ha in 62g %
Molae mass o HO = l+35:5 =36-59
Derdity =1-19gmsl!
Given mad! 38 =|·041 molus
No-o molu Molo mad 36-S
To 4fnd vobun,
Vslumy = Mas lo0
=84"03
No-h
malu Denity
Helaity =vslume of dslut fon X1000
1·19

X 1000 = l2"38M
84-03
3 Calculat. te mole ation o massetharal and watin în the sampe el
Which comtah 95/. éthansl by ?
maans ethanol diunlved in Sg o Hatu
>95. a ethanel 95g
Molau maw o ethansl= G HçOH
=12X2.+ IXS+ 16+)

Glven mass 95 )-065 moud

H6
No mols= Mdok
MOlat m
=5
No- o7 mols ofwatn 18
Molar mad o wat = H,0
-IX2+ 16 -0"27moe
= 18 mels
2:065 -0-881H mols
Mcle faoctien of ettanal = 2-065 +0:277
0"277 =0.|18 moles
Mole frotfen at = 2065+0"277
diuolved in 30g e watir
gucae Cmslas mass =Po) is
4-2-82g e% tractien eh glucae and Hatu.
Cal culatmou
’Molau mas aue =l80g
Molo mass
282 -0-0156 mos
180

Molae mass of Natu = IBg

No oh mols= 30- l.6666 mals
18 0.01S6 -0"0093 moly
Mol fracton ob glucode = ·6666+ 0"0156

|·6666 E0.9906 molu

watu = |·6666+ Oic
TACs 0"0156
Mole 7roen of
 syup welgtt 2142
4"p Contains 34-24 dugak
CCotb):( eght
CCpthao) Caeulkt nelfacten'22X1augak
+|l X6
in ajp.
Molo mass o Get-12X12 +
= 342g mol
= lX2+ 6
=18gmol
Wg= 34-2g
Mg- 342gmol
Ws= 214:29

Wa = 242-34-2 =1809
WA - l80 lo mols
ngMA 34-2 =0"1 meles
342

Mole fracten of dugan in dyup,

= 0-01 mlu
O:l+10

þasal exetd by a sclution Prebaked by

6. The csmoti Pressuke in mas l85000 in 4so me afwata
dauoling l-o %Poyme mal
at 31c
’ Ma=185000

V= 4So 0-45L
T=3c
=213+37 = 3lo

Me V
 B.314X1o3 X310
185000
2577:34x l0 3 = 30-959Pa
83250

Calaulat the molal elwatton Constarnt e wátin, t is givenlo0-052'c

that th
O°1molhl agueous dolutlony af tu dubstanu boilsd 't
M= 0"l maal
Th= loo:052°c

ATh= loo 052- l00 = O-052

ATb= Km
m
0052 = 0-52Km-
0*1

8 Addition a 0- 643 o} acembeund to 50 ml < bn2ne Cdnitty= 0

benaue
5-12, dulat tte nala mas of tte Comband.
’ Wg= 0-643
HA=50 x8819 = 43-9SA
AT-551- 5"03 - 0.48
K¢-5-12.
WgX K¢X l000
WA X AT
O.613X S-l1211000 - 1s6- 05gmsl
43-95X0.48

i 353-23K -kHhn l-00g non- Voltil,

being Peit
9-The eniAton ah bennu
mon- ersatien delit Ha dilowed în 909 of benaane, te biiling
354-lk Calulati the molax mass al salt.
Point kaised to
toe beneene =2-53 Sg mal!]
IK
WA= 90
 ATh- 354-||-353- 23
=088K
K - 2:53 KKgmsl
WBx Kb Xl D00
M6 WA XATh
|·B0X2S3XIoo
90X0-80

Mg 57-5gmal
Point o< dolution CRy=l-8% Kkg maly
what the Auatng
WA 600
Me =12X2+1X6 + 16X2
- 628
Kf-1-86WKgmo!
Wex KfXl000
WAXMB
4SXI86 Xlb00
600 X62

Of= 23-)S- 2:25

ATf= 2lo 90k
 Mex TAEORY QUESTIOMS
1 Defire Coligalie ortontes?
- Colligatiye propotiek ane those,propeontes which dsberd
upon the, rurben of pariles cf he solute in a deferit
arnount o oolvert end doos not depend upon atwte

3 hat b motal elevation onstant o chullioseic cônbtan

- Ebullio lortont (Ks)’The elevation n bailing peind
when one moe of non- Velatle sclute ia added to ohe Kilagra
Cyosti (ontJort lhy)’ The depession in feezing poind
pioduced hen ore rote cf non-volatk bobitesdbsstnd
in Gre kilogram je locog of the aslvent Unit ef Kg - kKg mo
3 shat b sngis Gnd Atuion?

Jodutl corenbaton to highen solte tocentátio

Dttusion ’ The rmoVertnt c moltculk in a fluid from area
higho Corcentreion to aea o Aoey (onentaton.

h asiGion oh disaboiaton ofsoltes in bolution. t

is the Hatio c the noirnal ard bseved molan nasses
c the oolute.
5 write don he atons ading the soubily of a
sslid, in bquid?
ane denpmae, preswe , pelaity and mahute
6what ere the fatons efeding the oehbilty oo gas in
liguid'
The factonb aleating the solbikly dgas in tipuid a
lenbenatae,
of the
pYiessalbe , polauky as ell as the natune
solute And thesoent.
1why the vapwr Pessoe a bolutiondeveases when non
VolÅtile oute is added into it?
’ When e add a non-volatile solute to a sdvent, the vapot
preskee oh the bolution deoncases because the bvface areais
Cubed by nen- volatile holte olealebs and theest
by the oent mokcues.
88hat ave the conditions to get accuate Valve of Moarngss
trom colligatie probewties?
>The conditions for geting acaate molan masa ode solte fr
Celligatie propertics kolutionae:
Reletive Aouerirg c vapour prebsue.
Elevation f Bolling Peint.
5Debression c Ereing kint.
Definedegee of disoiation and association?
> Degree cdissöciation (a) >Jt is defincd as the fration
bolute ns(lamnying lwvert) disßoiate at speafegien
Tomperatwre.
Degnee o asbouistion (a) ># ib defined as the nunben o
rmoleb o7 epartuer substante askoiated perrrãt f the
substane dóken.

MO hih olligatie proferty k referred to meawe molarmes.

+The colligatie profenly is pefored to measure molar