1

ARJUNA (JEE)
Percentage of Free SO3 in Oleum DPP-15
Density of Gaseous Substances
Dulong & Petit Law
1. The density of nitrogen gas is maximum at: 6. Find %age of free SO3 in 50 g of oleum if
(A) STP label of oleum 110%:
(B) 273 K and 1 atm (A) 44.44 (B) 54.44
(C) 546 K and 2 atm (C) 22.22 (D) 11.11
(D) 546 K and 4 atm
7. Which of following label of oleum is not
possible?
2. A gas has a density of 1.25 g L–1 at 1 atm (A) 115% (B) 120%
and 273 K. Identify it:
(C) 122% (D) 123%
(A) NO2 (B) O2
(C) N2 (D) SO2
8. If mass of free SO3 is 80 g in a 100 g of
oleum. Find %age label of oleum?
3. 11.35 L of a gas at STP weighs 14 g. The (A) 110% (B) 112%
gas could be:
(C) 118% (D) 120%
(A) N2O (B) N2
(C) CO (D) Both B and C
9. If specific heat of element is 3.2 cal/g. Find
atomic mass of element?
4. What is the molar mass of a gas that has a (A) 1 g (B) 2 g
density of 5.66 g L–1 at 35C and 745 mm
(C) 3 g (D) 4 g
Hg?
(A) 127 (B) 141
10. What is the molar mass of a gas that has a
(C) 143 (D) 146
density of 5.66 g L–1 at 35C and 745 mm
Hg?
5. Find %age of free SO3 in a bottle of oleum (A) 127 (B) 141
labeled 110%:
(C) 143 (D) 146
(A) 44.44 (B) 54.44
(C) 34.44 (D) 24.44
 2

ANSWERSKEY
1. (D)
2. (C)
3. (D)
4. (D)
5. (A)
6. (A)
7. (D)
8. (C)
9. (B)
10. (D)

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ARJUNA (JEE)
Molarity of mixtures of solutions DPP-14
Cannizaro method
1. 5 mL of NHCl, 20 mL of N/2 H2SO4 and 30 (A) 6 (B) 10
mL of N/3 HNO3 are mixed together and (C) 8 (D) 4
volume made one litre. The normality of
the resulting solution is : 7. 100 mL of 0.3 N HCl solution were mixed
(A) N/5 (B) N/10 with 200 mL of 0.6 N H2SO4 solution. The
(C) N/20 (D) N/40 final acidic normality is :
(A) 0.9 N (B) 0.6 N
2. The normality of 0.3 M phosphorus acid (C) 0.5 N (D) 0.4 N
(H3PO3) is :
(A) 0.1 (B) 0.9 8. Equal volumes of 0.1 M AgNO3 and 0.2 M
(C) 0.3 (D) 0.6 NaCl are mixed. The concentration of NO3−
ions in the mixture will be :
3. What will be the normality of a solution (A) 0.1 M (B) 0.05 M
obtained by mixing 0.45 N and 0.60 N (C) 0.2 M (D) 0.15 M
NaOH in the ratio 2 : 1 by volume :
(A) 0.4 N (B) 0.5 N 9. A substance contains 7% by mass of N and
(C) 1.05 N (D) 0.15 N 4% by mass of oxygen. Calculate minimum
possible molar mass of the substance.
4. 25 mL of 3.0 M HNO3 are mixed with 75 (A) 200 (B) 300
mL of 4.0 M HNO3. If the volumes are (C) 400 (D) 600
additive, the molarity of the final mixture
would be : 10. Find minimum molar mass of compound if
(A) 3.25 M (B) 4.0 M it has 6% carbon
(C) 3.75 M (D) 3.50 M (A) 100 (B) 200
(C) 400 (D) 300
5. The solution A and B are 0.1 and 0.2 molar
in a substance. If 100 mL of A are mixed
with 25 mL of B and there is no change in
volume, then the final molarity of the
solution is :
(A) 0.15 M (B) 0.18 M
(C) 0.12 M (D) 0.30 M

6. 1.5 litre of a solution of normality N and

2.5 litre of 2M HCl are mixed together. The
resultant solution had a normality 5. The
value of N is :

ANSWERS KEY
 2

1. (D)
2. (D)
3. (B)
4. (C)
5. (C)
6. (B)
7. (C)
8. (B)
9. (C)
10. (B)

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 1

ARJUNA (JEE)
Law of equivalence DPP-13

1. If metal carbonate has 60%. Carbonate ion 7. A metal carbonate on heating is converted
( CO32 ). Find equivalent mass of metal. to metal oxide and is reduced to 60% of its
original weight. The equivalent weight of
(A) 10 g (B) 20 g
the metal is
(C) 30 g (D) 40 g
(A) 5 (B) 25
(C) 60 (D) 70
2. If 10 g H2 react with 142 g of Cl2. Find
8. The oxide of a metal contains 52.91% of
mass of HCl formed if molar mass of H2,
the metal. If the formula of the metal oxide
Cl2 and HCl are 2g, 71g and 36.5g
is M2O3, then what is the atomic mass of
(A) 73 g (B) 146 g the metal?
(C) 36.5 g (D) 142 g (A) 8.99 (B) 26.96
(C) 17.97 (D) 53.93
3. A 100 ml solution was made by adding
1.43g of Na2CO3·10H2O. Find Normality of
9. Equivalent mass of the bivalent metal is
solution if Molar mass of Na2CO3·10H2O =
32.7. Molecular mass of its chloride is
286 g.
(A) 68.2 (B) 103.7
(A) 0.4 N (B) 0.3 N
(C) 136.4 (D) 166.3
(C) 0.2 N (D) 0.1 N

10. An element (X) having equivalent mass E

4. If 500 ml of 0.1M HCl is added to 250 ml
forms an oxide XmOn. The atomic mass of
of 0.01 NaOH the resulting solution is
element should be
(Hint whichever has higher gram
2En
equivalent) (A) (B) 2mEn
m
(A) Acidic (B) Basic E
(C) (D) En
(C) Neutral (D) None of these n

5. If 1L of 0.1 M H2SO4 is added to 2L of

0.1M Ca(OH)2 the resulting solution is
(Hint whichever has higher gram
equivalent)

(A) Acidic (B) Basic

(C) Neutral (D) None of these

6. An oxide of metal have 20% oxygen, then

equivalent weight of oxide is
(A) 32 (B) 48
(C) 40 (D) 52
 2

ANSWERS KEY
1. (B)
2. (B)
3. (D)
4. (A)
5. (B)
6. (C)
7. (B)
8. (B)
9. (C)
10. (A)

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ARJUNA (JEE)
Parts per million (ppm); Equivalent mass DPP-12

Law of equivalence
1. What is equivalent mass of propane (C3H8) 8. Find equivalent mass of CH4 in following
in following reaction reaction: 1CH4 + 4HCl → 1CCl4 + 4HCl.
C3H8 + 5O2 → 3CO2 + 4 H2O Molar mass of CH4, Cl2 are 16g and 71g:
(A) 2.2 g (B) 4.4 g (A) 2 g (B) 3 g
(C) 6.6 g (D) 8.8 g (C) 4 g (D) 16 g

2. Find n-factor if B(OH)3 9. Find equivalent mass of N2 in following

(A) 1 (B) 2 reaction: 1N2(g) + 3H2(g) → 2NH3(g)
14 15
(C) 3 (D) None of these (A) g (B) g
3 6
14 13
(C) g (D) g
3. Find equivalent mass of NaOH Molar mass 6 3
of NaOH = 40 g
(A) 20 g (B) 10 g 10. What is equivalent mass of C in following
(C) 40 g (D) 60 g reaction:
1 C + 1 O2 → 1 CO2
4. Find equivalent mass of Ca2+ ion, if atomic (A) 3 g (B) 6 g
mass of Ca = 40g: (C) 9 g (D) 12 g
(A) 40 g (B) 20 g
(C) 10 g (D) None of these

5. If 15 g of Ca is present in 1000 g of
solution, find ppm of Ca.
(A) 1500 (B) 15000
(C) 15 (D) 150

6. Find equivalent mass of H3PO3, if molar

mass of H3PO3 = 82g:
(A) 82 g (B) 164 g
(C) 123 g (D) 41 g

7. Find equivalent mass of SO24−

(A) 96 g (B) 48 g
(C) 24 g (D) 22 g
 2

ANSWERS KEY
1. (A)
2. (A)
3. (C)
4. (B)
5. (B)
6. (D)
7. (B)
8. (A)
9. (A)
10. (A)

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 1

ARJUNA (JEE)
CONCENTRATION TERMS DPP-11

1. Molality is expressed in units of 8. How much of NaOH is required to

(A) mol kg–1 (B) mol L–1 neutralize 1500 cm3 of 0.1 M HCl?
(C) mol L s–1 –1
(D) mol1 g–1 s–1 (A) 40 g (B) 4 g
(C) 6 g (D) 60 g
2. Which of the following is correct?
(A) The sum of mole fractions of all the 9. Which of the following concentration terms
components in a solution is always is temperature dependent?
unity
(B) Mole fraction depends upon (A) % by mass
temperature (B) % by volume
(C) Mole fraction is always negative (C) Molality
(D) Mole fraction is independent of content (D) Mole fraction
of solute in solution
10. Which of the following concentration terms
3. Which of the following methods of is temperature dependent?
expressing concentration varies with (A) % by mass
temperature?
(B) Mole fraction
(A) Molality (B) Weight percent
(C) Mass/volume ratio
(C) Molarity (D) Mole fraction
(D) Molality

4. Concentrated aqueous sulphuric acid is

98% H2SO4 (w/w) and has a density of 1.80
gmL–1. Molarity of solution
(A) 1 M (B) 18 M
(C) 10 M (D) 15 M

5. Mole fraction of solvent in aqueous

solution of NaOH having molality of 3 is
(A) 0.3 (B) 0.05
(C) 0.7 (D) 0.95

6. Molarity of H2SO4 is 18 M. Its density is

1.8 g/cm3, hence molality is :
(A) 18 (B) 100
(C) 36 (D) 500

7. Mole fraction of A in H2O is 0.2. The

molality of A in H2O is :
(A) 13.9 (B) 15.5
(C) 14.5 (D) 16.8
 2

ANSWERS KEY
1. (A)
2. (A)
3. (C)
4. (B)
5. (D)
6. (D)
7. (A)
8. (C)
9. (B)
10. (C)

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 1

ARJUNA (JEE)
CONCENTRATION TERMS DPP-10

1. The amount of H2SO4 present in 400 mL of 8. A solution contains one mole of alcohol and
0.1 M solution of the acid is: four moles of water. What are the mole
(A) 2.45 g (B) 3.92 g fractions of water and alcohol?
(C) 9.80 g (D) 4.9 g (A) 1/4, 4/1 (B) 4/1, 1/4
(C) 4/5, 1/5 (D) 1/5, 4/5
2. 50 mL of an aqueous solution of glucose
contains 6.02 × 1022 molecules. The 9. 40% NaOH solution has a density of
concentration of solution is: 1.110 g/mL. The molarity of the solution is:
(A) 0.1 M (B) 1.0 M (A) 1.11 (B) 11.1
(C) 0.2 M (D) 2.0 M (C) 3.64 (D) 3.0504

3. The number of mole KCl in 1000 mL of 3 10. Density of 31.5% solution of HNO3 in water
molar solution is: is 1.02 g/mL. The molarity of same solution
(A) 1.5 (B) 3.0 is :
(C) 1.0 (D) 4.0 (A) 5.1 M (B) 3.28 M
(C) 2.28 M (D) 0.44 M
4. How many g of NaOH will be needed to
prepare 250 mL of 0.1 M solution:
(A) 1 g (B) 10 g
(C) 4 g (D) 6 g

5. 5.85 g of NaCl are dissolved in 90 g of

water. The mole fraction of NaCl is :
(A) 0.1 (B) 0.01
(C) 0.2 (D) 0.0196

6. The density (in g mL–1) of a 3.60 M sulphuric

acid solution that is 29% H2SO4 (molar mass
= 98 g mol–1) by mass will be:
(A) 1.64 (B) 1.88
(C) 1.22 (D) 1.45

7. The mole fraction of NaCl in a solution

containing 1 mole of NaCl in 1000 g of water
is:
(A) 0.0177 (B) 0.001
(C) 0.5 (D) 0.244
 2

ANSWERS KEY
1. (B)
2. (D)
3. (B)
4. (A)
5. (D)
6. (C)
7. (A)
8. (C)
9. (B)
10. (A)

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 1

ARJUNA (JEE)
Law of reciprocal proportions,
Gay lussac law DPP-9

Empirical formula and molecular formula

1. The empirical formula of a compound is 6. What percentage of oxygen is present in the
CH2O. Its molecular weight is 180. The compound CaCO3.3Ca3(PO4)2?
molecular formula of compound is (A) 23.3% (B) 45.36%
(C) 41.94% (D) 17.08%
(A) C4HO4 (B) C3H6O3
(C) C6H12O6 (D) C5H10O5 7. Which of the following series of compounds
have same mass percentage of carbon?
(A) CO2, CO
2. Which one of the following combinations (B) CH4, C6H6, C2H2
illustrate law of reciprocal properties? (C) C2H2, C6H6, C10H8
(A) N2O3, N2O4, N2O5 (D) HCHO, CH3COOH, C6H12O6
(B) NaCl, NaBr, NaI
8. The empirical formula of a compound of
(C) CS2, CO2, SO2 molecular mass 120 is CH2O. The molecular
formula of the compound is:
(D) PH3, P2O3, P2O5
(A) C2H4O2 (B) C4H8O4
(C) C3H6O (D) al of these
3. What is the empirical formula of vanadium
oxide, if 2.74 g of the metla oxide contains 9. The crystalline salt Na2SO4.xH2O on heating
1.53g of metal? loses 55.9% of its weight. The formula of the
crystalline salt is
(A) V2O3 (B) VO (A) Na2SO4.5H2O (B) Na2SO4.7H2O
(C) V2O5 (D) V2O7 (C) Na2SO4.2H2O (D) Na2SO4.10H2O

4. Determine the empirical formula of Kelvar, 10. 0.1 mole of a carbohydrate with empirical
used in making bullet proof vests, is 70.6% formula CH2O contains 1 g of hydrogen.
C, 4.2%H, 11.8% N and 13.4% O: What is its molecular formula?
(A) C7H5NO2 (B) C7H5N2O
(A) C5H10O5 (B) C6H12O6
(C) C7H9NO (D) C7H5NO
(C) C4H8O4 (D) C3H6O3
5. The hydrated salt Na2CO3.xH2O undergoes
63% loss in mass on heating and becomes
anhydrous. The value of x is:
(A) 10 (B) 12
(C) 8 (D) 18
 2

ANSWERS KEY
1. (C)
2. (C)
3. (C)
4. (D)
5. (A)
6. (C)
7. (D)
8. (B)
9. (D)
10. (A)

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 1

ARJUNA (JEE)
Dalton's Atomic theory
DPP-08
Laws of chemical combination

1. A quantity of 10 g of a hydrocarbon exactly 4. Some bottles of colourless liquids were

requires 40 g oxygen for complete being labelled when the technicians
combustion. The products formed are CO2 accidentally mixed them up and lost track of
and water. When CO2 gas formed is their contents. A 15.0 ml sample withdrawn
absorbed completely in lime water, the mass from one bottle weighed 22.3 g. The
of solution increases by 27.5 g. What is the technicians knew that the liquid was either
mass of water formed simultaneously in the acetone, benzene, chloroform or carbon
combustion? tetrachloride (which have densities of 0.792
g/cm3, 0.899 g/cm3, 1.489 g/cm3, and 1.595
(A) 22.5 g (B) 27.5 g g/cm3, respectively). What was the identity
(C) 50 g (D) 10 g of the liquid?
(A) Carbon tetrachloride
(B) Acetone
2. Zinc ore (zinc sulphide) is treated with (C) Chloroform
sulphuric acid, leaving a solution with some (D) Benzene
undissolved bits of material and releasing
hydrogen sulphide gas. If 10.8 g of zinc ore 5. Law of multiple proportions is not
is treated with 50.0 ml of sulphuric acid applicable for the oxide(s) of
(density 1.2 g/ml), 65.2 g of solution and (A) carbon (B) iron
undissolved material remains. In addition, (C) nitrogen (D) aluminium
hydrogen sulphide (density 1.4 g/L) is
evolved. What is the volume (in litres) of this
6. If total mass of reactants is 48 g and mass of
gas?
one of the products is 40 g. Find mass of the
(A) 4.0 (B) 5.6 other product.
(C) 7.84 (D) 4.4 (A) 24 (B) 56
(C) 28 (D) 8

3. When a mixture of aluminium powder and 7. The gravimetric composition of water as

iron (III) oxide is ignited, it produces molten H : O is:
iron and aluminium oxide. In an experiment, (A) 1 : 1 (B) 1 : 2
5.4 g of aluminium was mixed with 18.5 g of (C) 1 : 8 (D) 1 : 16
iron (III) oxide. At the end of the reaction,
the mixture contained 11.2 g of iron, 10.2 g 8. Mass of oxygen in Fe2O3 and FeO is in the
of aluminium oxide, and an undetermined simple ratio of:
amount of unreacted iron (III) oxide. No (A) 3 : 2 (B) 1 : 2
aluminium was left. What is the mass of the (C) 2 : 1 (D) 3 : 1
iron (III) oxide left?
(A) 2.5 g (B) 7.3 g 9. Two oxides of a metal contain 36.4% and
53.4% of oxygen by mass respectively. If the
(C) 8.3 g (D) 2.9 g
formula of first oxide is M2O, then that of the
second is
 2

(A) M2O3 (B) MO (A) P2O3, PH3 (B) P2O5, NH3,

(C) MO2 (D) M2O5 (C) N2O5, NH3 (D) H2O, H2O2

10. Which one of the following sets of

compounds correctly illustrates the law of
multiple proportions ?

ANSWERS KEY
1. (A)
2. (A)
3. (A)
4. (C)
5. (D)
6. (D)
7. (C)
8. (D)
9. (B)
10. (D)

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 1

ARJUNA (JEE)
Mole Concept Continued DPP-07

1. Based on the following consecutive 6. If we start from 500 g of CaCO3 and treated
reactions with series of reagents to give C5H10, find
2KClO3  2KCl + 3O2 mass of C5H10 formed if molar mass of
4Al + 3O2  2Al2O3 CaCO3 is 100g and C5H10 is 58 g
2 moles of KClO3 of 50% purity on strong (A) 58 g (B) 116 g
heating and then with excess of Al, Al2O3 (C) 168 g (D) 224 g
formed is
(A) 2 mol (B) 1 mol 7. For sequential reaction:
(C) 3 mol (D) 1.5 mol A  B + C …..(i)
2B  C + 2D ….(ii)
If % yield of (i) and (ii) reactions are 90%
2. In the following set of reactions,
and 80% respectively, then the overall %
CaCO3  
 CaO  CO 2  75% yield  yield is expected to be:
CO 2  C 
 2CO  50% yield  (A) 90% (B) 80%
CO formed at STP from 10 g of CaCO3 is (C) 72% (D) 10%
(A) 2.24 L (B) 11.2 L
8. NX is produced by the following step of
(C) 1.12 L (D) 1.68 L
reactions:
M + X2  MX2
3. NH3 is formed in the following step:
3MX2 + X2  M3X8
I. Ca + 2C  CaC2 (50% yield)
M3X8 + N2CO3  NX + CO2 + M3O4
II. CaC2 + N2  CaCN2 + C (100% yield) How much M (metal) is consumed to
III. CaCN2 + 3H2O  2NH3 + CaCO3 (50% produces 206 gm of NX? (Take at. Wt. of M
yield) = 56, N = 23, X = 80)
2 moles of NH3 are formed if we take (A) 42 gm (B) 56 gm
(A) 1 mol Ca (B) 2 mol Ca (C) 14/3 gm (D) 7/4 gm
(C) 3 mol Ca (D) 4 mol Ca
9. 5 moles of A, 6 moles of Z are mixed with
4. What weights of P4O6 and P4O10 will be sufficient amount of C to finally produce F.
produced by the combustion of 31 g of P4 in Then find the maximum moles of F which
32 g of oxygen leaving no P4 and O2? can be produced. Assuming that the product
(A) 2.75 g, 219.5 g (B) 27.5 g, 35.5 g formed can also be reused. Reactions are:
(C) 55 g, 71 g (D) 17.5 g, 190.5 g A + 2Z  B …..(i)
B + C  Z + F ….(ii)
5. How many moles of P4O6 and P4O10 will be (A) 3 moles (B) 4.5 moles
produced by the combustion of 12.4 gm of (C) 5 moles (D) 6 moles
phosphorus in 12.8 gm of O2, leaving no P4
or O2? 10. Human lungs can absorb 8 gm O2 per hour
[Atomic wt. P = 31] by respiration. If all oxygen atoms are
(A) 0.11 mol and 0.3 mol converted to carbohydrates (C6H12O6) how
(B) 0.15 mol and 0.25 mol long will it take to produce 180 gm C6H12O6?
(A) 8 hours (B) 12 hours
(C) 0.05 mol each
(C) 10 hours (D) 6 hours
(D) 0.1 mol each
 2

ANSWERS KEY
1. (B)
2. (D)
3. (D)
4. (B)
5. (C)
6. (A)
7. (C)
8. (A)
9. (A)
10. (B)

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 1

ARJUNA (JEE)
Volume Contraction and Percentage Yield DPP-06

1. Find the volume contraction if 10L of 6. Fe2O3 reacts with excess CO at a high
Butane (C4H10) under combustion with temperature according to the equation
sufficient amount of oxygen? below: Fe2O3 + 3CO  2Fe + 3CO2
(A) 35 L (B) 25 L If 6.50 g of Fe2O3 yields 3.85 g of Fe, what
(C) 15 L (D) 3.5 L is the percentage yield of the reaction?
(A) 59.2% (B) 69.9%
2. Find the mass of 50% CaCO3 which will
(C) 76.3% (D) 84.7%
produce 136 g of CaSO4? (Molar mass of
CaCO3 = 100 g; Molar mass of CaSO4 = 136
g) 7. When 10 g of 90% pure lime stone (Calcium
CaCO3 + H2SO4  CaSO4 + H2O + CO2 carbonate) is heated completely, the volume
(A) 100 g (B) 200 g (in litres) of CO2 is liberated at STP is
(C) 300 g (D) 400 g (A)22.4 (B) 2.24
(C) 20.16 (D) 2.016
3. If 300 g of CaCO3 on reaction with excess of
H2SO4 gives 272 g of CaSO4. Find the % age 8. The volume of oxygen necessary for the
yield of product? complete combustion of 20 L of propane is
(A) 66.66% (B) 33.33%
(C) 50% (D) 25% (A) 40 L (B) 60 L
(C) 80 L (D) 100 L
4. Find maximum moles of CCl4 formed when
10 moles of CH4 undergoes chlorination 9. If 0.5 mole of BaCl2 is mixed with 0.2 mole
with excess of chlorine: of Na3 PO4 the maximum number of mole of
1CH4 + 4Cl2  1CCl4 + 4HCl Ba3 (PO4) 2 that can be formed is:
(A) 2 moles (B) 5 moles (A) 0.7 (B) 0.5
(C) 8 moles (D) 10 moles (C) 0.30 (D) 0.1

5. For the reaction: 2X + 3Y  3Z, the

10. 10 g of hydrogen and 64 g of oxygen were
combination of 2.00 moles of X with 3.00
filled in a steel vessel and exploded. Amount
moles of Y produces 3.00 moles of Z. What
is the percent yield of this reaction? of water produced in this reaction will be:
(A) 100% (B) 58.3% (A) 1 mole (B) 2moles
(C) 66.7% (D) 90% (C) 3 moles (D) 4 moles
 2

ANSWERS KEY
1. (A)
2. (B)
3. (A)
4. (D)
5. (A)
6. (D)
7. (D)
8. (D)
9. (D)
10. (D)

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 1

ARJUNA (JEE)
Mole Concept Continued DPP-05

1. According to the equation, 7. A gaseous mixture contains 70% N2 and 30

N2O3(g) + 6H2(g) → 2NH3(g) + 3H2O(g) % unknown gas by volume. If the average
how many moles of NH3(g) could be formed mass of gaseous mixture is 37.60. Find
from the reaction of 0.22 mol of N2O3 (g) molecular mass of unknown gas if molar
with 0.87 mol of H2(g)? mass of N2 = 28 gm
(A) 0.29 mol (B) 0.44 mol (A) 42.2 (B) 60
(C) 0.73 mol (D) 1.1 mol (C) 40 (D) 50
2. Enzymes convert glucose (M = 180.2) to
ethanol (M = 46.1) according to the equation 8. The mass composition of universe may be
C6H12O6 → 2C2H5OH + 2CO2 90% 11 H , and 10% 42 He . The average
What is the maximum mass of ethanol that molecular of universe should be
can be made from 15.5 kg of glucose? (A) 2.20 (B) 2.10
(A) 0.256 kg (B) 0.512 kg (C) 3.80 (D) 3.64
(C) 3.96 kg (D) 7.93 kg

3. According to following reaction: 9. The vapour density of a gas A is twice that

A + BO3 → A3O4 + B2O3 of a gas B. If the molecular weight of B is M,
The number of moles of A3O4 produced if 1 the molecular weight of A will be :
mole of A is mixed with 1 mole of BO3 is : (A) M (B) 2M
(A) 3 (B) 1 (C) 3M (D) M/2
(C) 1/3 (D) 2/3
10. The number of moles of C and D produced
4. For the reaction 2P + Q → R , 8 mol of P on mixing 5 moles of A and 7 moles of B are
and 5 mol of Q will produce : respectively :
(A) 8 mol of R (B) 5 mol of R (3A + 5B →7C + 9D)
(C) 4 mol of R (D) 13 mol of R
(A) 9 moles and 11 moles
5. 5 mol of VO and 6 mol of Fe2O3 are allowed (B) 11.66 moles and 15 moles
to react completely according to the reaction (C) 9.8 moles and 12.6 moles
VO + Fe2O3 → FeO + V2O5 (D) 1 moles and 13 moles
The number of moles of V2O5 formed is :
(A) 6 (B) 2
(C) 3 (D) 5

6. For the reaction

7A + 13 B + 15C → 17P
If 15 moles of A , 26 mole of B and 30.5
moles of C are taken initially, then limiting
reactant is :
(A) A (B) B
(C) C (D) none of these
 2

ANSWERS KEY
1. (A)
2. (D)
3. (C)
4. (C)
5. (B)
6. (B)
7. (D)
8. (B)
9. (B)
10. (C)

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 1

ARJUNA (JEE)
Mole Concept continued DPP-04

1. Find mass of 18.066 × 1023 molecules of 6. Find number of moles of oxygen require for
NH3? complete combustion of 1 mole of propane?
(If atomic mass of N and H are 14 and 1) (A) 1 (B) 3
(A) 51 g (B) 34 g (C) 5 (D) 7
(C) 17 g (D) None of these
7. Find mass of oxygen require for complete
2. Find mass of CO2 which have same combustion of 90 g of C2H6? If
12 1 16
molecules as present in 68 g of NH3? 6 C, 1H and 8 O
(A) 88 g (B) 176 g (A) 136 g (B) 236 g
(C) 44 g (D) 132 g (C) 336 g (D) 436 g

3. Find volume of CO2 (g) at STP if it weighs 8. Find volume of C3H8 Which will react with
88 g? 30 L of O2
(Atomic mass of C and O are 12g and 32g) (A) 3 L (B) 6 L
(A) 44.8 L (B) 67.2 L (C) 9 L (D) None of these
(C) 22.4 L (D) 89.6 L
9. How many moles of electrons weigh one
4. Find total number of electrons in 51 g of kilogram?
7 N and 1 H if Avogadro’s No. = NA
NH3? If 14 1
(A) 6.023 × 1023
(A) 20 NA (B) 30 NA 1
(B)  1031
(C) 10 NA (D) 5 NA 9.108
6.023
(C)  1054
5. Find total number of neutrons in 56 g of CO? 9.108
6 C and 8 O if Avogadro’s No. = NA
If 12 16
1
(D)  108
(A) 28 NA (B) 22 NA 9.108  6.023
(C) 11 NA (D) None of these
10. Twenty molecules of SO3 will weigh as
much as ….. molecules of oxygen
(A) 100 (B) 50
(C) 15 (D) 8
 2

ANSWERS KEY
1. (A)
2. (B)
3. (A)
4. (B)
5. (A)
6. (C)
7. (C)
8. (B)
9. (D)
10. (B)

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 ARJUNA (JEE)
SOME BASIS CONCEPT OF CHEMISTRY DPP - 03
1. 1 amu is equal to : 9. Boron has two isotopes boron-10 and boron-11
(A) 1.00758 g (B) 0.000549 g whose percentage abundances are 19.6% and
(C) 1.66 × 10–24 g (D) 6.02 × 10–23 g 80.4% resectively. What is the average atomic mass
of boron?
2. Atomic mass of chlorineis 35.5. It has two isotopesof (A) 10.8 (B) 10.6
atomic mass 35 and 37. The percentageof heavier (C) 9.6 (D) None of these
isotope is :
(A) 10 (B) 15 10. Calculate the mass of 2.5 gram atoms of oxygen.
(C) 20 (D) 25 (A) 50.0 g (B) 70.0 g
(C) 20.0 g (D) 40.0 g
3. Atomic mass of boron is 10.81. It has two isotopes
with 80% and 20% abundance respectively. The
11. Calculate the gram atoms in 2.3 g of sodium.
atomic mass of the isotope having 80% abundance
(A) 0.2 (B) 0.5
is 11.01. The atomic mass of the other isotope is:
(A) 10.80 (B) 11.01 (C) 0.1 (D) 0.8
(C) 10.01 (D) 21.82
12. Calculate the mass of 1.5 gram molecule of sulphuric
4. The mass of an atom of carbon is : acid.
(A) 1 g (B) 1.99 × 10–23 g (A) 147.0 g (B) 146.0 g
(C) 1/12 g (D) 1.99 × 1023 g (C) 149.0 g (D) 148.0 g

5. An element, X hasthe following isotopic composition,

200
X : 90%
199
X : 8%
202
X : 2%
the weighted average atomic mass of the naturally-
occuring element 'X' is closest to :
(A) 201 amu (B) 202 amu
(C) 199 amu (D) 200 amu

6. What is the average molecular weight of a gas

containg 20% of N2 (molecular weight 28) and 80%
of SO2 (molecular weight 64)?
(A) 52 (B) 53
(C) 50 (D) None of these

7. Naturally occuring chlorine is 75% Cl35 which has

an atomic mass of 35 amu and 25% Cl37 which
has a mass of 37 amu. Calculate the average atomic
mass of chlorine -
(A) 35.5 amu (B) 36.5 amu
(C) 71 amu (D) 72 amu

8. Carbon occur in nature as a mixture of C 12 and C

13. Average atomic mass of carbon is 12.011 what
is the % aboundance of C12 in nature ?
(A) 99.8% (B) 98.9%
(C) 97.6% (D) 98.5%
 [ANSWERS]
1. (C)
2. (D)
3. (C)
4. (B)
5. (D)
6. (C)
7. (A)
8. (B)
9. (A)
10. (D)
11. (C)
12. (A)

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 1

ARJUNA (JEE)
Different Types of Particles and Relative DPP-02

Atomic Mass
1. 1 amu is equal to 6. If NA is Avogadro’s number, the 10 amu
(A) 6.023 × 1023 g will be equal to _________ gram
(B) 1.67 × 10–24 g (A) 10 NA
1 NA
(C) g (B)
1.67  10−24 10
(D) 1 g 10
(C)
NA
2. Number of neutrons in 1 molecule of CO2
(D) NA
are
(A) 22
7. The mass of a sodium atom is 23 times
(B) 20
(C) 12 1
greater than of the mass of C-12 atom.
(D) 16 12
What is relative atomic mass of sodium?
3. Mass of magnesium is 24 amu it means that (A) 23
an atom of magnesium is _________ times (B) 12
heavier than one-twelfth of mass of C-12 23
(C)
atom 12
1 12
(A) (D)
24 23
(B) 12
(C) 24 8. Sum of proton, electron and neutron in 1
1 molecule of H2S2O8
(D)
12 (A) 290
(B) 292
4. Number of electrons in 10 molecules of (C) 294
CaCO3 (D) 296
(A) 50
(B) 500 9. Number of protons in 1 H1 , 2 H1 and 3H1
(C) 100 isotopes of hydrogen, respectively are :
(D) 1000 (A) 1, 2 and 3
(B) 2, 4 and 6
5. Which of the following has highest mass in (C) 1, 1 and 1
amu? (D) 0, 1 and 2
(A) 1 molecule of H2SO4
(B) 1 molecule of H3PO4 1
(C) 1 molecule of CO2 10. mass of 1 atom of C-12 is equal to
12
(D) 1 molecule of CaCO3
(A) 1 g
(B) 1 amu
(C) 12 g
(D) 12 amu
 2

ANSWERS
1. (B)
2. (A)
3. (C)
4. (B)
5. (D)
6. (C)
7. (A)
8. (B)
9. (C)
10. (B)

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 1

ARJUNA (JEE)
Some Basis Concept of Chemistry DPP-01

1. An average adult has 5.2 L of blood. 6. The largest volume of the following group
Volume of blood in m3 is is that of
(A) 5.2 × 103 m3 (B) 5.2 × 10–3 m3 (A) 445 g of water at 4°C (d = 1g cm–3)
–6 3
(C) 5.2 × 10 m (D) 5.2 × 10–2 m3 (B) 600 g of chloroform at 20°C (d = 15 g
cm–3)
2. 10.5 g cm–3 in SI unit will be (C) 155 cm3 of steel
(A) 10.5 × 10–3 kg m–3 (D) 0.50 L of milk
(B) 10.5 x 10–1 kg m–3
(C) 10.5 kg m–3 7. Of the following substance, the greatest
(D) 10.5 × 103 kg m–3 density is that of
(A) 1000 g of water at 4°C
3. Solder is an alloy of tin and lead that is (B) 100.0 cm3 of chloroform weighing
used in electronic circuits. It has melting 198.9 g
point of 225°C. It is ............. °F. (C) 10.0 cm3 piece of wood weighing 7.72
(A) 498 °F (B) –437 °F g
(C) 437 °F (D) 400 °F (D) an ethyl alcohol-water mixture of
density 0.83 g cm–3
4. At what temperature will a Fahrenheit
thermometer give a reading that is twice on 8. SI unit and metric unit of volume are
the Celsius thermometer? (A) m3, L (B) m3, m3
(A) 53.3° (b) –123° (C) L, m3 (D) dm3, m3
(C) 30.0° (D) 160.0°
9. Which one of the following is not a
5. Which choice best describes the degree of mixture?
uncertainty in the measurement of 4.0032 (A) Brass (B) Air
g? (C) 22 carat gold (D) Water
(A) The measurement is between 4.0031
and 4.0033 10. Which one of the following represents
(B) The measurement is between 4.002 smallest quantity ?
and 4.004 (A) 1850 ng (B) 1.85 × 10–4 g
(C) The quantity is exact (C) 1.85 × 103 µ g (D) 1.85 × 10–6 kg
(D) The uncertainty cannot be determined
with given information
 2

ANSWERS
1. (B)
2. (D)
3. (C)
4. (D)
5. (A)
6. (D)
7. (B)
8. (A)
9. (D)
10. (A)

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