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2. Resonance effect

1. Resonance
structures
 It is also called as
NO BOND RESONANCE
 Resonance of
sigma e-,
C C due to a nearby
empty p-orbital
or unsaturated
system
 𝛂-hydrogen
H H
𝛂-Hydrogen
𝛂
+ C C OH stabilizes the
H H
𝛂-hydrogen
carbocation

𝞼C-H - punhybrid
 H H
H H
𝛂
+ C C OH + C C OH
H H
H H
+
H
H
Formation of OH 𝞼C-H - punhybrid
𝝿-bond, C C
stabilizing C+ H H
More 𝛂-Hydrogens = Better stability
Decreasing order of Carbocation stabilization

9 𝛂-H 6 𝛂-H 3 𝛂-H

 Similar to
carbocation.
C C
C But,
interaction is
b/w 𝞂C-H - 𝝿 C-C
*
Unhybrid
p-orbitals
 CH3 rotates
(single bond)
Same orientation
as p-orbital
 No Bond
resonance

Bond order
reduces
 No Bond
resonance
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