Alkali Boil Out Procedure

For

Waste Heat Recovery Power Plant

1 x 14 MW WHR BASED POWER GENERATION PLANT

End User

AMBUJA CEMENT LIMITED

MARWAR MUNDHWA, RAJASTHAN

thyssenkrupp Industries India Pvt. Ltd.

Pimpri, Pune – 411018.
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

CONTENTS
SR. NO. DESCRIPTION
SECTIONS

1.
ABSTRACT

2. OBJECTIVES

3. PRE-REQUISTIES

4. CHECK LIST

5. REQUIRED CHEMICALS

6. SAFETY PRECAUTIONS

7. REQUIRED INSTRUMENT SIGNALS IN DCS

8. REQUIRED EQUIPMENT/AUXILIARIES READINESS FOR ABO

9. PROCEDURE

10. COMPLETION CRITERIA

11. ALKALI BOIL OUT SCHEDULE

12. HOT RINSING

13. ABO BLOWDOWN SAMPLE ANALYSIS REPORT

14. BOILER EXPANSION LOG SHEET DURING ALKALI BOIL OUT

15. PROCEDURE COMPLETION SIGN OFF

16. SAMPLE TESTING PROCEDURE & MSDS

17. APPLICABLE P&IDs

Prepared By Checked By Verified By Approved By

Page 2 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

1. ABSTRACT
Alkali Boil out Procedure (ABO) is Common for CC HP & PH (HP & LP) circuit. Chemical concentration will
be changed depending on water holding capacity and operating pressure of boiler.

2. OBJECTIVE

The purpose of alkali boil out is to remove the deposits like oil, grease and mill scale etc., resulting out of
manufacturing, fabrication and erection procedures from boiler internals. Such deposits in the boiler tube
walls restrict the heat flow across the tube bundles resulting failure due to overheating.

3. PRE-REQUISITES

Ensure all the pre-commissioning checks are completed including trial runs and ensure proper
1
operation of all the accessories.
Completion of boiler hydro test and duct refractory dry out (Refractory dry out is applicable only for
2
CC HP Boiler).
Ensure availability of Utilities like cooling water for BFP, Blow down tank, Instrument air for Control
3
valves, plant/service air (if applicable), etc.
Ensure availability of drain and vent system from various parts of Boiler and their routing to trench /
4
safe location.
Clean the steam drum thoroughly and carryout joint inspection. Firmly box-up the steam drum
5
manhole (one side) with new gaskets.
6 Box up all the manholes in the flue gas path after joint internal inspection with all agencies involved.
Insulation of Boiler casing, steam drum, and necessary ducting should be completed. Provide
7 personal protection guards for hot areas where insulation is not feasible.

Ensure installation of expansion pointers for measurement of Boiler thermal expansion. Mark the
8
pointer location in cold condition.
Ensure that transportation locks for spring supports is removed and mark location of cold load
9
setting.
During Alkali boil out one drum level transmitter, pressure transmitter to be taken into service Ensure
and confirm whether all the necessary safety interlocks are implemented and tested for reliable
10
operation. Both the level gauges should be kept on line and level transmitter readings to be cross
checked with direct level gauge reading.
The following equipment’s should be made operational from DCS.
· Feed water control valves.
11
· Deaerator level control valve.
· Isolation valves in the Feed water line in the feed water control station on the BFW pump discharge.

Prepared By Checked By Verified By Approved By

Page 3 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

Line up all the instruments connected to Deaerator storage tank and Boiler Feed Water piping. Take
all the Instruments in the flue gas path on line and check for proper indications on DCS panel. Ensure
operation of all control / motorized valves as listed below are made available from DCS.
For details of instruments please refer the list below.
Tag no’s:
12
CC HP Boiler :(CC HP-01-MOV-001, CC HP-01-MOV-002, CC HP-01-FCV-001A, CC HP-01-FCV-
001B)
PH – HP Section: (PHHP-01-MOV-001, PHHP-01-MOV-002, PHHP-01-FCV-001A, PHHP-01-FCV-
001B)
PH-- LP Section: (PHLP-01-MOV-001, PHLP-01-MOV-002, PHLP-1-FCV-001A, PHLP-1-FCV-001B)
Ensure Flue gas isolation damper at the Boiler inlet & outlet along with bypass damper is made
13
operational from local & also from the DCS.
All BFPs (DEA-01-BFP-001, DEA-01-BFP-002) are commissioned and ready.
14
Note- Minimum 1 no’s of BFP should be available.
Ensure availability of required quantity of DM water(including rinsing), uninterrupted power supply
15 (UPS), Power supply for all drives and proper area & plant illumination.
16 Neutralizing pit is available along with adequate quantity of neutralizer (Preferably HCL).
Water and steam circuit all temperature, pressure readings to be made available in DCS and also in
17
local.
Main steam line up to MSSV all supports is erected. All spring support floated and temporary
18
supports were removed.
19 Fresh air blower is commissioned and operational from DCS.
Sampling point must be erected between water wall drain station and its outlet isolation valve to IBD
20 tank. (Samples to be collected from this sample point during blow down)
Ensure availability of sample bottles and plant laboratory is ready and below mentioned testing
instruments and requisite chemicals is available for testing.
21  PH
 Oil & grease
 Turbidity
 Phosphate (up to 5000ppm)
 M- alkalinity & P- alkalinity
22 Dust handling system is commissioned and operational from DCS.

23 All hoppers level switches are commissioned and indication available in DCS.

24 All scrap materials are removed from boiler platforms and walkways.
Insulation- Boiler Drum, All headers, Evaporator down comers, water and steam circuit drains,
25
casing.

Prepared By Checked By Verified By Approved By

Page 4 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

4. CHECK LIST BEFORE COMMENCEMENT OF ALKALI BOIL OUT

Signature
Sr.No. Description Status
& Date
All temporary supports must be removed and boiler is free for thermal expansion.
1

2 Alkali chemical available and shifted to drum level.

Drum one side manhole is boxed up and another side is open and boiler drum
3 Expansionexpansion.
gasket is available.
4 Boiler water filling is completed (level below 150mm of drum centre line).
5 Start-up vent valve and its isolation both valves must be in close condition.
All super heaters drain valves & vent valves are in open condition.
Tag no’s:
CC HP boiler
Vent Valves: (CC HP-02-GB-009, CC HP-02-GB-016)

6 Drain Valves: (CC HP-02-GB-010, CC HP-02-GB-017)

PH – HP Section
Vent Valves: (PHHP-02-GB-009) Drain Valves: (PHHP-02-GB-008)
PH – LP Section
Vent Valves: (PHLP-02-GB-009) Drain Valves: (PHLP-02-GB-008)
EBD (Emergency blow down) & CBD (Continues blow down) valves in closed condition.
Tag no’s:
CC HP Boiler
EBD Valves: (CCHP-12-GB-001, CCHP-12-GB-002, CCHP-12-GT-001, CCHP-12-GT-002)
CBD Valves: (CCHP-11-GB-002, CCHP-11-GB-003, CCHP-11-GT-001, CCHP-11-MOV-001)
PH – HP Section
7
EBD Valves: (PHHP-12-GB-001, PHHP-12-GB-002, PHHP-12-GT-001, PHHP-12-GT-002)
CBD Valves: (PHHP-11-GB-002, PHHP-11-GB-003, PHHP-11-GT-001, PHHP-11-MOV-001)
PH –LP Section
EBD Valves: (PHLP-12-GB-001, PHLP-12-GB-002, PHLP-12-GT-001, PHLP-12-GT-002)
CBD Valves: (PHLP-11-GB-002, PHLP-11-GB-003, PHLP-11-GT-001, PHLP-11-MOV-001)

8 Pressure gauges on drum and main steam line are installed and taken in line.

9 Plastic buckets for pre-mixing of chemicals with water is available.

10 Fire extinguisher and Fire tender is available.

Prepared By Checked By Verified By Approved By

Page 5 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

Drum vents must be in open condition.
Tag no’s:

11 AQC Drum: (CCHP-02 -GB-006)

PH – HP Drum: (PHHP-02 -GB-006)
PH – LP Drum: (PHLP-02 -GB-006)
Main steam stop valves along with bypass are in closed condition.
Tag no’s:
12 CC HP– Boiler MSSV: (CCHP-02-MOV-001, CCHP-02-MOV-001A)
PH – HP MSSV: (PHHP-02-MOV-001, PHHP-02-MOV-001A)
PH – LP MSSV: (PHHP-02-MOV-002, PHHP-02-MOV-002A)
13 Cooling water is available for quenching of blowdown water at IBD tank.

Keep all the isolation valves in attemperator spray water piping in open condition
14
and control valves in close condition

15 All the logic and interlocks of boiler and its accessories were checked.

All necessary parameters to be logged periodically in the log sheet as provided by

16
site commissioning team. Also important events to be recorded.
Deaerator pre-commissioning is completed and adequate water level is maintained
17
in Deaerator. (Preferable 70%)
BFP suction line flushing is completed and minimum recirculation and balance leak
18
off valves are opened for both the BFPs.

Prepared By Checked By Verified By Approved By

Page 6 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

5. REQUIRED CHEMICAL:
Boiler water holding capacity (upto drum centerline)-
 CC HP Section ~ 39 m3
 PH HP Section ~ 125 m3
 PH LP Section ~ 31 m3

Sr.No. Chemical Name Quantity Required

Crystalline Tri-sodium phosphate (Na3Po4,  CC HP Section ~ 195 Kg

1  PH HP Section ~ 625 Kg
12H2O)
 PH LP Section ~ 93 Kg
5 Kg for each AQC boiler drum
2 Detergent (For Foaming purpose only
4 Kg each for PH HP and PH LP drum

Total chemical required 940 kg and detergent 15 kg for foaming purpose.

Adequate quantity of HCL must be available for neutralizing.

Calculation of required Chemical quantity:

Total quantity of chemical required: - (Water holding capacity (m3) × required ppm)/1000
Quantity of chemicals is decided to maintain initial phosphate concentration For HP section 5000 ppm &
for LP section 3000 ppm in boiler along with the chemical total 15 kg normal good quality detergent/
Washing powder to be added in boiler drum for foaming purpose only.

6. SAFETY PRECAUTION
Before commencement of Alkali boil out please ensure below mentioned safety pre-cautions are available.
 Good quality rubber hand gloves for handling Tri-sodium phosphate.

 Safety goggles for eyes. (For chemical handling)

 Emergency eye wash station at drum elevation and near drainage station.
 Firefighting system is ready and adequate quantity of fire extinguisher is available.
 Adequate illumination is available.
 Neutralizing pit is ready and adequate quantity of lime (HCL) is available for neutralizing.
 Ensure while giving blow down bottom header area a properly cordoned off with barricade.

Prepared By Checked By Verified By Approved By

Page 7 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

7. REQUIRED INSTRUMENT SIGNAL IN DCS

Sr. No. Tag No. Service Description

1 DEA-01-TT-001 DEAERATOR STORAGE TANK TEMPERATURE
2 DEA-01-PT-001 DEAERATOR STORAGE TANK PRESSURE
3 DEA-01-LT-001A DEAERATOR STORAGE TANK LEVEL-1
4 DEA-01-LT-001B DEAERATOR STORAGE TANK LEVEL-2
5 DEA-01-LT-001C DEAERATOR STORAGE TANK LEVEL-3
6 DEA-01-TT-002 DEAERATOR OUTLET FEEDWATER TEMPERATURE
7 DEA-01-PT-002 BFP SUCTION HEADER PRESSURE
8 DEA-01-DPT-001 DIFFERENTIAL PRESSURE ACROSS INLET STRAINER OF BFP#1
9 DEA-01-DPT-002 DIFFERENTIAL PRESSURE ACROSS INLET STRAINER OF BFP#2
10 DEA-01-PT-003 FEEDWATER PRESSURE AT THE OUTLET OF BFP#1
11 DEA-01-PT-004 FEEDWATER PRESSURE AT THE OUTLET OF BFP#2
12 DEA-01-PT-005A BOILER FEED PUMP DISCHARGE HEADER PRESSURE
13 DEA-01-PT-005B BOILER FEED PUMP DISCHARGE HEADER PRESSURE
14 CCHP-01-PT-001 FEEDWATER PRESSURE BEFORE ECO.
15 CCHP-01-TT-001 FEEDWATER TEMPERATURE BEFORE ECO.
16 CCHP-01-TT-002 FEEDWATER TEMPERATURE AFTER ECO.
17 CCHP-01-PT-002 FEEDWATER PRESSURE AFTER ECO.
18 CCHP-01-FT-001A FEED WATER FLOW AFTER ECO.
19 CCHP-01-FT-001B FEED WATER FLOW AFTER ECO.
20 CCHP-01-FCV-001B-ZT BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - POSITION FEEDBACK
21 CCHP-01-FCV-001A-ZT (0-100%) FEED WATER FLOW CONTROL VALVE - POSITION FEEDBACK
22 CCHP-01-LT-001A AQC BOILER DRUM LEVEL

23 CCHP-01-LT-001B AQC BOILER DRUM LEVEL

24 CCHP-01-LT-001C AQC BOILER DRUM LEVEL

25 CCHP-02-PT-001A AQC BOILER DRUM PRESSURE

26 CCHP-02-PT-001B AQC BOILER DRUM PRESSURE
27 CCHP-02-TT-001 AQC BOILER DRUM TEMPERATURE
28 DEA-01-WTE-001A/B BFP#1 MOTOR WINDING TEMPERATURE - R
29 DEA-01-WTE-001C/D BFP#1 MOTOR WINDING TEMPERATURE - Y
30 DEA-01-WTE-001E/F BFP#1 MOTOR WINDING TEMPERATURE - B
31 DEA-01-BTE-002 BFP#1 MOTOR DRIVE END BEARING TEMPERATURE
32 DEA-01-BTE-001 BFP#1 MOTOR NON DRIVE END BEARING TEMPERATURE

Prepared By Checked By Verified By Approved By

Page 8 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

Sr. No. Tag No. Service Description
33 DEA-01-BTE-003 BFP#1 PUMP DRIVE END BEARING TEMPERATURE

34 DEA-01-BTE-004 BFP#1 PUMP NON DRIVE END BEARING TEMPERATURE

35 DEA-01-WTE-002A/B BFP#2 MOTOR WINDING TEMPERATURE - R

36 DEA-01-WTE-002C/D BFP#2 MOTOR WINDING TEMPERATURE - Y

37 DEA-01-WTE-002E/F BFP#2 MOTOR WINDING TEMPERATURE - B

38 DEA-01-BTE-006 BFP#2 MOTOR DRIVE END BEARING TEMPERATURE

39 DEA-01-BTE-005 BFP#2 MOTOR NON DRIVE END BEARING TEMPERATURE
40 DEA-01-BTE-007 BFP#2 PUMP DRIVE END BEARING TEMPERATURE
41 DEA-01-BTE-008 BFP#2 PUMP NON DRIVE END BEARING TEMPERATURE
42 CCHP-01-FCV-001B-EP BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - EP CONVERTOR
43 CCHP-01-FCV-001A-EP (0-100%) FEED WATER FLOW CONTROL VALVE - EP CONVERTOR
FEED WATER TEMPERATURE AT THE INLET OF HP BOILER FEED CONTROL
44 PHHP-02-TT-001
STATION
FEED WATER TEMPERATURE AT THE INLET OF HP BOILER FEED CONTROL
45 PHHP-02-PT-001
STATION
46 PHHP-01-FT-001A HP BOILER FEED WATER FLOW
47 PHHP-01-FT-001B HP BOILER FEED WATER FLOW
HP BOILER MAIN (0-100%) FEED WATER FLOW CONTROL VALVE - POSITION
48 PHHP-01-FCV-001A-ZT
FEEDBACK
HP BOILER BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - POSITION
49 PHHP-01-FCV-001B-ZT
FEEDBACK
50 PHHP-01-LT-001A PHHP BOILER DRUM LEVEL
51 PHHP-01-LT-001B PHHP BOILER DRUM LEVEL
52 PHHP-01-LT-001C PHHP BOILER DRUM LEVEL
53 PHHP-02-PT-001A PHHP BOILER DRUM PRESSURE
54 PHHP-02-PT-001B PHHP BOILER DRUM PRESSURE
55 PHHP-02-TT-001 PHHP BOILER DRUM TEMPERATURE
56 PHLP-01-FT-001A LP BOILER FEED WATER FLOW
57 PHLP-01-FT-001B LP BOILER FEED WATER FLOW
58 PHLP-02-TT-001 LP BOILER FEED WATER TEMPERATURE
59 PHLP-02-PT-001 LP BOILER FEED WATER PRESSURE
LP BOILER MAIN (0-100%) FEED WATER FLOW CONTROL VALVE - POSITION
60 PHLP-01-FCV-001A-ZT
FEEDBACK
LP BOILER BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - POSITION
61 PHLP-01-FCV-001B-ZT
FEEDBACK
62 PHLP-01-LT-001A PHLP BOILER DRUM LEVEL

Prepared By Checked By Verified By Approved By

Page 9 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

Sr. No. Tag No. Service Description
63 PHLP-01-LT-001B PHLP BOILER DRUM LEVEL
64 PHLP-01-LT-001C PHLP BOILER DRUM LEVEL
65 PHLP-02-PT-001A PHLP BOILER DRUM PRESSURE

66 PHLP-02-PT-001B PHLP BOILER DRUM PRESSURE

67 PHLP-02-TT-001 PHLP BOILER DRUM TEMPERATURE
68 PHHP-05-PT-001 HP BOILER - DOSING SYSTEM PRESSURE AT THE OUTLET OF DOSING PUMP
69 PHLP-05-PT-001 LP BOILER - DOSING SYSTEM PRESSURE AT THE OUTLET OF DOSING PUMP
PHHP-01-FCV-001A- HP BOILER MAIN (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
70
ZSC (OPEN)
PHHP-01-FCV-001A- HP BOILER MAIN (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
71
ZSO (OPEN)
PHHP-01-FCV-001B- HP BOILER BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
72
ZSC (OPEN)
PHHP-01-FCV-001B- HP BOILER BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
73
ZSO (CLOSE)
HP BOILER STARTUP VENT LINE PRESSURE CONTROL VALVE - END LIMIT
74 PHHP-02-PCV-001-ZSC
(OPEN)
HP BOILER STARTUP VENT LINE PRESSURE CONTROL VALVE - END LIMIT
75 PHHP-02-PCV-001-ZSO
(CLOSE)
PHLP-01-FCV-001A- LP BOILER MAIN (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
76
ZSC (OPEN)
PHLP-01-FCV-001A- LP BOILER MAIN (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
77
ZSO (CLOSE)
PHLP-01-FCV-001B- LP BOILER BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
78
ZSC (OPEN)
PHLP-01-FCV-001B- LP BOILER BYPASS (0-100%) FEED WATER FLOW CONTROL VALVE - END LIMIT
79
ZSO (CLOSE)
80 PHLP-02-PCV-002-ZSC LP BOILER STARTUP VENT LINE PRESSURE CONTROL VALVE - END LIMIT (OPEN)
LP BOILER STARTUP VENT LINE PRESSURE CONTROL VALVE - END LIMIT
81 PHLP-02-PCV-002-ZSO
(CLOSE)
82 CCHP-02-TT-002 STEAM TEMPERATURE AT THE OUTLET OF HP PSH

83 CCHP-02-PT-002 STEAM PRESSURE AT THE OUTLET OF HP PSH

84 CCHP-02-TT-003 STEAM TEMPERATURE AT THE INLET OF HP FSH
85 CCHP-02-TT-004A FINAL SUPERHEATED STEAM TEMPERATURE AT THE OUTLET OF HP FSH
86 CCHP-02-TT-004B FINAL SUPERHEATED STEAM TEMPERATURE AT THE OUTLET OF HP FSH
87 CCHP-02-PT-002A FINAL SUPERHEATED STEAM PRESSURE AT THE OUTLET OF HP FSH
88 CCHP-02-PT-002B FINAL SUPERHEATED STEAM PRESSURE AT THE OUTLET OF HP FSH
89 CCHP-02-TT-005 STEAM TEMPEARTURE FROM PH BOILER
90 CCHP-02-PT-003 STEAM PRESSURE FROM PH BOILER
91 CCHP-06-LT-001 BLOW DOWN WATER TRANSFER PUMP LEVEL

Prepared By Checked By Verified By Approved By

Page 10 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

Sr. No. Tag No. Service Description
92 CCHP-05-PT-001 DOSING SOLUTION PRESSURE AT THE OUTLET OF DOSING PUMP
93 CC-03-DT-001 FLUE GAS PRESSURE AFTER FRESH AIR BLOWER
94 CC-03-DT-004 FLUE GAS PRESSURE ABOVE HP FSH COIL
95 CC-03-TT-004 FLUE GAS TEMPERTURE ABOVE HP FSH COIL

96 CC-03-DT-005 FLUE GAS PRESSURE ABOVE HP PSH COIL

97 CC-03-TT-005 FLUE GAS PRESSURE ABOVE HP PSH COIL
98 CC-03-DT-006 FLUE GAS PRESSURE ABOVE EVAP. COIL
99 CC-03-TT-006 FLUE GAS TEMPERTURE ABOVE EVAP. COIL
100 CC-03-DT-007 FLUE GAS PRESSURE ABOVE ECO. COIL
101 CC-03-TT-007 FLUE GAS TEMPERTURE ABOVE ECO. COIL
102 CC-03-DT-008 FLUE GAS PRESSURE ABOVE AQC CPH#1
103 CC-03-TT-008 FLUE GAS TEMPERATURE ABOVE AQC CPH#1
104 CC-03-TT-009 FLUE GAS TEMPERATURE AT THE OUTLET OF AQC BOILER

105 CC-03-DT-009 FLUE GAS PRESSURE AT THE OUTLET OF AQC BOILER

106 PHHP-02-TT-002A PH HP SUPERHEATED STEAM TEMPERATURE AT THE OUTLET OF HP SH
107 PHHP-02-TT-002B PH HP SUPERHEATED STEAM TEMPERATURE AT THE OUTLET OF HP SH
108 PHHP-02-PT-002A PH HP SUPERHEATED STEAM PRESSURE AT THE OUTLET OF HP SH
109 PHHP-02-PT-002B PH HP SUPERHEATED STEAM PRESSURE AT THE OUTLET OF HP SH
110 PHHP-02-FT-001A PH HP SUPERHEATED STEAM FLOW
111 PHHP-02-FT-001B PH HP SUPERHEATED STEAM FLOW
112 PHLP-02-TT-002A PHLP SUPERHEATED STEAM TEMPERATURE AT THE OUTLET OF LP SH
113 PHLP-02-TT-002B PHLP SUPERHEATED STEAM TEMPERATURE AT THE OUTLET OF LP SH
114 PHLP-02-PT-002A PHLP SUPERHEATED STEAM PRESSURE AT THE OUTLET OF LP SH
115 PHLP-02-PT-002B PHLP SUPERHEATED STEAM PRESSURE AT THE OUTLET OF LP SH
116 PHLP-02-FT-001A PHLP SUPERHEATED STEAM FLOW
117 PHLP-02-FT-001B PHLP SUPERHEATED STEAM FLOW
LP BOILER STARTUP VENT LINE PRESSURE CONTROL VALVE - POSITION
118 PHLP-02-PCV-002-ZT
FEEDBACK
119 PH-06-LT-001 BLOW DOWN WATER TRANSFER PUMP LEVEL
120 PHHP-05-PT-001 HP BOILER - DOSING SYSTEM PRESSURE AT THE OUTLET OF DOSING PUMP
121 PHLP-05-PT-001 LP BOILER - DOSING SYSTEM PRESSURE AT THE OUTLET OF DOSING PUMP
122 PH-03-DT-001 FLUE GAS PRESSURE AT THE INLET OF PH BOILER
123 PH-03-TT-001 FLUE GAS TEMPERATURE AT THE INLET OF PH BOILER
124 PH-03-TT-002 FLUE GAS TEMPERATURE AT THE INLET OF HP SH
125 PH-03-DT-002 FLUE GAS PRESSURE AT THE INLET OF HP SH

Prepared By Checked By Verified By Approved By

Page 11 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

Sr. No. Tag No. Service Description
126 PH-03-TT-003 FLUE GAS TEMPERATURE AT THE OUTLET OF HP SH
127 PH-03-DT-003 FLUE GAS PRESSURE AT THE OUTLET OF HP SH
128 PH-03-TT-004/005/006 FLUE GAS TEMPERATURE AT THE OUTLET OF HP EVAP.
129 PH-03-DT-004 FLUE GAS PRESSURE AT THE OUTLET OF HP EVAP
130 PH-03-DT-010 FLUE GAS PRESSURE AT THE OUTLET OF PH BOILER
131 PH-03-TT-010 FLUE GAS TEMPERATURE AT THE OUTLET OF PH BOILER

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Page 12 of 22 Commissioning : Energy Dept.
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Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

8. REQUIRED EQUIPMENT/AUXILIARIES READINESS FOR ABO

EQUIPMENT TAG NO.
Deaerator DEA-01-DE-001
Boiler feed water pumps DEA-01-BFP-001, DEA-01-BFP-002
CC HP Boiler hopper RAVs CC-03-RAV-001, CC-03-RAV-002 & CC-03-RAV-003
CC HP Boiler bottom chain conveyor CC-03-CV-001
PH boiler hopper RAV PH-03-RAV-001 & PH-03-RAV-002
PH boiler bottom ash chain conveyor PH-03-CV-001

9. PROCEDURE:

After ensuring the above said checklist, alkali boil out can be started and according to start up procedure
mentioned below.
9.1 Boiler Filling
Start boiler initial filling pump and charge boiler initial filling line.
9.1.1 Boiler initial filling to be done from initial filling provided at Boiler Feed water line (applicable for both
HP and LP section).
9.1.2 As the water comes through economizer & evaporator vents, close the valves completely after
removing air in the system.
9.1.3 Before initial filling the boiler ensure below mentioned valves are in closed condition
Sr.No. Description
EBD and CBD line valves Tag no’s
Tag no’s:
CC HP Boiler
EBD Valves: (CCHP-12-GB-001, CCHP-12-GB-002, CCHP-12-GT-001, CCHP-12-GT-002)
CBD Valves: (CCHP-11-GB-002, CCHP-11-GB-003, CCHP-11-GT-001, CCHP-11-MOV-001)
1 PH – HP Section
EBD Valves: (PHHP-12-GB-001, PHHP-12-GB-002, PHHP-12-GT-001, PHHP-12-GT-002)
CBD Valves: (PHHP-11-GB-002, PHHP-11-GB-003, PHHP-11-GT-001, PHHP-11-MOV-001)
PH –LP Section
EBD Valves: (PHLP-12-GB-001, PHLP-12-GB-002, PHLP-12-GT-001, PHLP-12-GT-002)
CBD Valves: (PHLP-11-GB-002, PHLP-11-GB-003, PHLP-11-GT-001, PHLP-11-MOV-001)

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SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

All Header drain valves Tag no’s
Tag no’s:
2 CC HP – Evaporator – CCHP-02-GB-008
CC HP – Economiser – CCHP-01-GB-004
PH - HP Evaporator –PHHP-01-GB-030
PH - LP Evaporator – PHLP-01-GB-030

9.1.4 LEVEL-water to be filled below 150mm below the center line of drum. Level to be visually ensured
from other side which is open. Ensure drum vents are in open condition.

9.2 Boiler Light Up:

AQC boiler
After ensuring required drum level in boiler. Prepare for boiler light up; For boiler light up first gas to be
allowed from MID tap-1.the sequence should be followed first open Boiler inlet damper and after inlet
damper is fully opened open boiler outlet damper (Before opening boiler inlet and outlet damper please
ensure bypass damper is in full open condition). After opening both inlet and outlet damper start closing
bypass damper to establish gas flow through AQC boiler. Gas flow rate to be maintained to warm up the
drum water temperature to 60-70 deg.C.

PH boiler
After ensuring required drum level in boiler the startup sequence to be followed as first open Boiler inlet
damper and after inlet damper is fully opened open boiler outlet damper (Before opening boiler inlet and
outlet damper please ensure bypass damper is in full open condition). After opening both inlet and outlet
damper start closing bypass damper to establish gas flow through PH boiler. Gas flow rate to be maintained
to warm up the drum water temperature to 60-70 deg.C.

9.3 Filling the chemical in boiler drum:

When drum water temperature reaches above 60-80 deg.C. Take water from boiler drum into mixing drum
and dissolve required chemicals thoroughly into the solution tank. Mix the chemical properly in the tank by
normal stirrer and after mixing transfers the solution into the drum via manhole.
Do not pour the solution in empty boiler drum. Repeat the steps and by this method dose the total quantity
of Na3Po4, 12H2O into boiler drum. After mixing the chemical into boiler drum dosed the detergent into
boiler drum and box up drum manhole.

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Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

9.4 Boiler Pressure raising:

By controlling the bypass damper for PH and AQC boiler gas flow through both the boilers to be increased
and accordingly boiler pressure will start increasing. Required pressure to be maintained during ABO is
tabulated below.
Sr.no Boiler Pressure raising during ABO

1 AQC - Boiler 9 kg/cm2

3 PH - HP Boiler 9 kg/cm2
4 PH - LP Boiler 1.5 kg/cm2

Keep the system stable for 4 hours, then start opening the drain valves one by one for few seconds.
Check the quality of the blow down water. After every 2 hours blow down shall be given from all water side
header drains. No. of blow down will depend on blow down water quality which needs to be checked during
every blow down. When the oil & grease content comes below 5 ppm.
Keep it replenished with DM water and keeps draining the system and samples to be taken and checked.
Continue with the hot rinsing and draining process. After rinsing when the blow down water quality is as
same as the feed water quality.

9.5 Blow down sampling:

After completion of blow down from each header, crack open all drain line valves and collect sample from
sampling point located at drain line from drainage station to IBD tank & tested for.

 Phosphate concentration
 Alkalinity (Both M-alkalinity and P-alkalinity)
 Oil & Grease
 Turbidity
 PH & Conductivity

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Page 15 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

10. COMPLETION CRITERIA
When oil and grease in blow down water will come below 5 ppm in two Consecutive samples close both the
Inlet, Outlet dampers, left the boiler for natural cooling.
When pressure decreases around 6 kg/cm2 all drain lines including CBD and IBD valves shall be opened
simultaneously for hot blow down of boiler.

11. ALKALI BOIL OUT SCHEDULE:

Sr. No. Temperature range Time

1. Boiler initial filling
2. Water rising upto 80- 90 deg C
Chemical mixing in boiler drum and drum
3. 4 hours
box up
4. Pressure rising up to 8 kg/cm2 3 hours
5. Holding time at 8 kg/cm2 4 hours
6. First blow down at 8 kg/cm2 After 4 hours of attaining 9 kg/cm2
At every 2 hours interval till oil and
7. Consecutive blow downs at 8 kg/cm2 grease decreases below 5 ppm in blow
down
8. Boiler hot blow down At 5 kg/cm2

NOTE: When the boiler pressure is around 8 kg/cm2(g) note down the boiler expansion readings. Measure
and mark the boiler locations in hot condition. Also observe and mark the location of hot condition for spring
supports.

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Page 16 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

12. HOT RINSING:

OBJECTIVE

It is essential to carry out hot rinsing process after alkali boil out to remove residue phosphate, oil and
grease from boiler and also to ensure boiler blow down water quality matches with feed DM water.

SAFETY PRECAUTION

 Before commencement of hot rinsing process please ensure blow down sump is properly barricaded
with proper caution tag.
 While collecting samples all required PPE’s must be worn

PRE-REQUISITES

1. Alkali Boil out completed.

2. Post alkali boil out hot draining completed.

3. Boiler is cooled after alkali boil out and below screen temperature is below 70 deg c.

4. Sufficient quantity of DM water available.

5. DM transfer pump is ready and available.

6. Neutralizing pit is available along with adequate quantity of neutralizer.

CHECK LIST

Sr.No Description Status Signature & Date

1 Furnace temperature is below 70 deg c.

2 Drum, super heater vent is in open condition

3 Drum level gauge glass indication is available.

4 DM lab is available with all required testing chemicals

Main steam stop valve and by-pass valve is in closed
5
condition
6 All super heater drains are in close condition

7 EBD valves and CBD valves are in closed condition.

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Page 17 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

PROCEDURE:

After ensuring the above said checklist, hot rinsing process can be started
 Start boiler initial filling pump and charge boiler initial filling line up to boiler drain header inlet.
 Start boiler filling from boiler feed water line.
 Fill DM water up to drum center line.
 After filling water up to drum center line stop DM transfer pump/initial fill pump
 While filling boiler take DM water sample and test at lab for
a. PH
b. Oil and grease
c. Turbidity
d. Phosphate
e. M-alkalinity and P-alkalinity
 During blow down collect water sample and test below mentioned parameters at laboratory.
a. PH
b. Turbidity
c. Phosphate
d. M-alkalinity and P-alkalinity
 Hot rinsing procedure will continue till boiler blow down water quality matches with feed DM water
quality.
 After completion of Hot Rinsing Process Header Cleaning and Flushing to be carried out. For Header
Cleaning and Flushing Evaporator Header stub needs to be cut (List of headers to be provided at site)
and Flushing with Normal temperature DM water (Preferably from DM transfer pump) to be carried
out.

COOLING DOWN AND POST ABO INSPECTION:

1. Drain water from boiler. Open steam drum manholes. Open all the manholes in boiler inlet
duct/casing.
2. Carry out joint inspection of steam drum inside and the boiler inlet duct refractory lining. Also
check the condition of SH and Evaporator supporting arrangement.

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Page 18 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

13. ABO BLOWDOWN SAMPLE ANALYSIS REPORT

The alkali analysis is done from the blow down samples and the report is given in Table.1 and the
rinsing water analysis report is given in Table.2.
TABLE NO -01
Blow PO4 M ALK
Oil &
Date Time PH P ALK Grease
down no (ppm) (ppm) (ppm)
(ppm)

2
3
4
5
6
7
8
9
10
11

TABLE NO-02
Date Parameter Time DM Water Blow down water
pH
Conductivity
Oil and grease
phosphate

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Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

14. BOILER EXPANSION LOG SHEET DURING ALKALI BOIL OUT

Date Time Elevation Expansion readings in mm

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Page 20 of 22 Commissioning : Energy Dept.
SR SN SC ENERGY DIV
Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
Client:- AMBUJA CEMENT LIMITED, MARWAR MUNDHWA, RAJASTHAN
Consultant: - HOLTEC CONSULTING PVT LTD
Doc. No.:- COMM/SC/26M0004/002 Rev No. :- 00
Date:- 10/12/2021 Project No. :- 26M.0004

TITLE ALKALI BOIL OUT PROCEDURE

15. PROCEDURE COMPLETION SIGN OFF

Once this procedure is completed, it is to be signed by the Commissioning in-charge and End User
Representative.

Remarks: -

tkII Commissioning In-charge End user representative

Date Date

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Project:- 1 x 14 MW WHR BASED POWER GENERATION PLANT
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TITLE ALKALI BOIL OUT PROCEDURE

16. SAMPLE TESTING PROCEDURE & MSDS

17. APPLICABLE P&IDs

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 Procedure for testing of Oil and grease in Alkali Boil out samples .

Required Chemicals:
A. Petroleum Ether.
B. Concentrated sulphuric acid.
C. What man no.40 filter paper.

Required apparatus:
A. Separating funnel of 1 litre capacity.
B. Porcelain dish.
C. Desiccators.
D. Balance Weight (Upto three decimal).
E. Oven

Testing Procedure:
1 Place one liter of the sample in a suitable Separating funnel.
2 Add 2-3 ml of concentrated Sulphuric acid & shake well.
3 Add 15 ml. of Petroleum ether (40- 60 Degc C) & shake well for 5 minute.
4 After adding petroleum ether while shaking Open the stopper intermittently and let
the air out from the funnel.
5 Add further 25 ml petroleum ether to the funnel and shake vigorously for 5 minutes.
6 Drain the water.
7 Transfer the ether layer through a what man no.40 filter paper in to a clean dried
Previously weighed porcelain dish.
8 Two to three washings with petroleum ether about 10 ml is sufficient.
9 Keep the porcelain dish in oven maintained the temperature 60 degc c, ensure the
Complete evaporation of petroleum ether.
10 Cool in a desiccators and weigh.

11 Calculation:

Oil and Grease (In ppm) = Residue in the porcelain dish (mg) x 1000

Initial Sample Volume (ml)

 Procedure for testing of pH in Alkali Boil out samples
Required Chemicals/Reagents:
A. Buffer solutions

Required apparatus/Instruments:
B. Calibrated pH meter
C. Beaker

Testing Procedure
General procedure for p H measurement using any standard pH Meter is as follows.

1. Switch on and allow the instrument to warm up.

2. Take the temperature of the solution and set the temperature control this value.

3. Ensure that the p H Meter is calibrated using buffer solutions prior to the p H Measurement.
4. Pour approximately 50 ml. of sample into the beaker and insert cells and move the cell and down
for several times to wash off any solids present on the cell.
5. Discard the water from the beaker. Repeat the same and note down the p H reading on display in
numbers.

6. Remove the cell rinse in distilled water and leave standing in distilled water.

Procedure for testing of Conductivity in Alkali Boil out samples

Required Chemicals/Reagents:
A. Standard solutions

Required apparatus/Instruments:
B. Calibrated Conductivity meter
C. Beaker

Testing Procedure
1. Switch on the instrument wait for 10-15 minutes to stabilize.
2. Set the temperature compensation knob to the temperature of the sample.
3. Ensure that the Conductivity Meter is calibrated using standard solutions prior to the conductivity
measurement
4. Pour approximately 50 ml. of sample in to the beaker .Immerse cell and move up and down for
several times to ensure equilibrium.
 Procedure for testing of Turbidity in Alkali Boil out samples

Required apparatus/Instruments:
A. Calibrated Turbidity meter
B. Test tube

Testing Procedure
1. Switch on the instrument and allow 10-15 minutes warm up.
2. Calibrate the instrument prior testing the sample..

3. Insert test tube containing sample in cell holder.

4. Meter will measure turbidity directly and gives the reading in NTU.

Procedure for testing of p-alkalinity in Alkali Boil out samples

Required Chemicals/Reagents:
A. Phenolphthalein indicator
B. Burette for titration

Required apparatus/Instruments:
C. Conical flask
D. Test tube

Testing Procedure
1. Take 100 ml of sample in a conical flask.
2. Add 3 to 4 drops of Phenolphthalein indicator,
3. Mix well and titrate against 0.02 N Sulphuric acid.

4. End point : Pink to colorless

5. Calculation: Burette reading x10 ppm

Procedure for testing of m-alkalinity in Alkali Boil out samples

Required Chemicals/Reagents:
A. Mixed indicator
B. Burette for titration

Required apparatus/Instruments:
C. Conical flask
 D. Test tube

Testing Procedure
1. Take 100 ml of sample in a conical flask.
2. Add 3 to 4 drops of Mixed indicator,
3. Mix well and titrate against 0.02 N Sulphuric acid.

4. End point: Blue to Grayish Pink.

5. Calculation: Burette reading x10 ppm

Procedure for testing of phosphate in Alkali Boil out samples

Required Chemicals/Reagents:

A. Spectrophotometer

Reagents required for spectrophotometer for testing of phosphate as mentioned in the OEM
manual to be followed.
 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150
* * * Section 1 - Chemical Product and Company Identification * * *
Chemical Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade)
Product Use: For Commercial Use
Synonyms: Sodium phosphate tribasic, Tribasic sodium phosphate, Trisodium orthophosphate, Orthophosphate trisodique, TSP
Supplier Information
Chem One Ltd. Phone: (713) 896-9966
14140 Westfair East Drive Fax: (713) 896-7540
Houston, Texas 77041-1104 Emergency # 1-800-424-9300
General Comments
NOTE: Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire,
exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service.
* * * Section 2 - Composition / Information on Ingredients * * *

CAS # Component Percent

10101-89-0 Trisodium Phosphate Dodecahydrate 98-100
Component Related Regulatory Information
No information available.
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
* * * Section 3 - Hazards Identification * * *
Emergency Overview
This product is a colorless, odorless solid, in crystal form. This product is corrosive, and can cause moderate to severe irritation to
contaminated tissues which come in contact with dusts or particulates of this product. If ingested burns can occur to the digestive
system. This product is not flammable or reactive. Thermal decomposition of this product produces irritating vapors and toxic
gases (e.g. phosphorous oxides). Emergency responders should wear proper personal protective equipment for the releases to
which they are responding.
Hazard Statements
DANGER! MAY BE FATAL IF SWALLOWED. MAY CAUSE BURNS TO THE EYES AND SKIN. EYE CONTACT CAN
RESULT IN CORNEAL DAMAGE. MAY CAUSE DIFFICULT BREATHING AND RESPIRATORY TRACT IRRITATION.
Avoid contact with eyes and skin. Avoid breathing dusts. Keep containers closed. Use with adequate ventilation. Wash
thoroughly after handling. Use with adequate ventilation.
Potential Health Effects: Eyes
Exposure to particulates or solution of this product may cause moderate to severe irritation of the eyes, including burns, depending
on duration and concentration of contact. Severe contact with the eyes can cause corneal injury, including clouding and burns,
which could lead to blindness. Permanent damage (cloudiness of the cornea) has resulted from contact with Trisodium Phosphate,
Anhydrous solution in two case reports, one involving hot solution. Concentrations were not reported. In another case report,
injury occurred as a result of a splash of aqueous solution, but healed within 48 hours (concentration not reported).
Potential Health Effects: Skin
This product can cause moderate to severe irritation of the skin, depending on duration and concentration of exposure. Severe
exposure or contact in the presence of moisture, or if product is in solution can cause burns. Alkalies penetrate skin slowly. The
extent of damage therefore depends on duration of contact. Repeated skin contact to low levels may lead to dermatitis (red,
cracked skin).
Potential Health Effects: Ingestion
Ingestion of this product in large volumes may irritate or burn the tissues of the mouth, esophagus, and other tissues of the
digestive system. Symptoms of exposure can include vomiting, diarrhea, and nausea. In severe cases, death may result. The
estimated fatal dose of sodium phosphates is 50 g.
Potential Health Effects: Inhalation
Breathing dusts or particulates generated by this product or to mists if in solution, can lead to moderate to severe irritation of the
nose, throat or respiratory system, depending on duration and concentration of exposure. Symptoms of minor exposure could
include coughing, wheezing, and shortness of breath. According to one report, irritation of the nose and throat was caused by
exposure to 0.5 to 2.0 mg/m3 airborne dust for one hour. Irritation has also been reported after short exposures above 7-10 mg/m3.
Severe inhalation exposure can result in pulmonary edema (a condition of fluid in the lungs), which can be fatal.
HMIS Ratings: Health Hazard: 2 Fire : 0 Physical Hazard: 1
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
____________________________________________________________
Issue Date: 09/09/98 10:35:26 CLW --------- Page 1 of 7 Revision Date: 12/27/2010 4:00 PM SEP
 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150

* * * Section 4 - First Aid Measures * * *

First Aid: Eyes
In case of contact with eyes, rinse immediately with plenty of water for at least 20 minutes. Seek immediate medical attention.
First Aid: Skin
Remove all contaminated clothing. For skin contact, wash thoroughly with soap and water for at least 20 minutes. Seek immediate
medical attention if irritation develops or persists. Completely decontaminate clothing, shoes, and leather goods before reuse.
First Aid: Ingestion
Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Immediately give large amounts of water. If
vomiting occurs naturally, rinse mouth and repeat administration of water. Obtain medical advice immediately. Never give
anything by mouth to a victim who is unconscious or having convulsions.
First Aid: Inhalation
Remove source of contamination or move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Get
immediate medical attention.
First Aid: Notes to Physician
Provide general supportive measures and treat symptomatically.
* * * Section 5 - Fire Fighting Measures * * *
Flash Point: Not flammable Method Used: Not applicable
Upper Flammable Limit (UEL): Not applicable Lower Flammable Limit (LEL): Not applicable
Auto Ignition: Not applicable Flammability Classification: Not applicable
Rate of Burning: Not applicable
General Fire Hazards
Trisodium Phosphate Dodecahydrate is not combustible, and does not contribute to the intensity of a fire. Closed containers
exposed to heat may explode. When involved in a fire, this material may decompose and produce irritating vapors, acrid smoke
and toxic gases. Solutions can react with metals such as aluminum, zinc and galvanized iron to produce highly flammable
hydrogen gas, that may explode if ignited.
Hazardous Combustion Products
Oxides of phosphorous.
Extinguishing Media
Use methods for the surrounding fire and other materials involved in the fire.
Fire Fighting Equipment/Instructions
Firefighters should wear full protective clothing including self-contained breathing apparatus. If possible control runoff from fire
control or dilution water to prevent environmental contamination.
NFPA Ratings: Health: 2 Fire: 0 Instability: 1 Other:
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

* * * Section 6 - Accidental Release Measures * * *

Containment Procedures
Stop the flow of material, if this can be done without risk. Contain the discharged material. If sweeping of a contaminated area is
necessary use a dust suppressant agent, which does not react with product (see Section 10 for incompatibility information).
Clean-Up Procedures
Small releases can be cleaned-up wearing gloves, goggles and suitable body protection. In case of a large spill (in which excessive
dusts can be generated), clear the affected area, protect people, and respond with trained personnel. Do not allow the spilled
product to enter public drainage system or open water courses. Place all spill residues in an appropriate container and seal.
Thoroughly wash the area after a spill or leak clean-up. Prevent spill rinsate from contamination of storm drains, sewers, soil or
groundwater.
Evacuation Procedures
Evacuate the area promptly and keep upwind of the spilled material. Isolate the spill area to prevent people from entering. In case
of large spills, follow all facility emergency response procedures.
Special Procedures
Remove soiled clothing and launder before reuse. Avoid all skin contact with the spilled material. Have emergency equipment
readily available.

____________________________________________________________
Issue Date: 09/09/98 10:35:26 CLW --------- Page 2 of 7 Revision Date: 12/27/2010 4:00 PM SEP
 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150

* * * Section 7 - Handling and Storage * * *

Handling Procedures
All employees who handle this material should be trained to handle it safely. Do not breathe dust. Avoid all contact with skin and
eyes. Use this product only with adequate ventilation. Wash thoroughly after handling.
Storage Procedures
Keep container tightly closed when not in use. Store containers in a cool, dry location, away from direct sunlight, sources of
intense heat, or where freezing is possible. Material should be stored in secondary containers or in a diked area, as appropriate.
Store containers away from incompatible chemicals (see Section 10, Stability and Reactivity). Storage areas should be made of
corrosion- and fire-resistant materials. Post warning and “NO SMOKING” signs in storage and use areas, as appropriate. Use
corrosion-resistant structural materials, lighting, and ventilation systems in the storage area. Floors should be sealed to prevent
absorption of this material. Inspect all incoming containers before storage, to ensure containers are properly labeled and not
damaged. Have appropriate extinguishing equipment in the storage area (i.e., sprinkler system, portable fire extinguishers).
Empty containers may contain residual particulates; therefore, empty containers should be handled with care. Do not cut, grind,
weld, or drill near this container. Never store food, feed, or drinking water in containers that held this product. Keep this material
away from food, drink and animal feed. Do not store this material in open or unlabeled containers. Limit quantity of material
stored.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Exposure Guidelines
A: General Product Information
Follow the applicable exposure limits.
B: Component Exposure Limits
The exposure limits given are for Particulates Not Otherwise Classified.
ACGIH: 10 mg/m3 TWA (Inhalable fraction)
3 mg/m3 TWA (Respirable fraction)
OSHA: 15 mg/m3 TWA (Total dust)
5 mg/m3 TWA (Respirable fraction)
DFG MAKs 4 mg/m3 TWA (Inhalable fraction)
1.5 mg/m3 TWA (Respirable fraction)
Engineering Controls
Ventilation must be sufficient to effectively remove and prevent buildup of dust or fumes that may be generated during handling or
thermal processing. Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces.
PERSONAL PROTECTIVE EQUIPMENT
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA
regulations found in 29 CFR Subpart I (beginning at 1910.132). Please reference applicable regulations and standards for relevant
details.
Personal Protective Equipment: Eyes/Face
Wear safety glasses (or goggles). If necessary, refer to U.S. OSHA 29 CFR 1910.133.
Personal Protective Equipment: Skin
Use impervious gloves. Gloves should be tested to determine their suitability for prolonged contact with this material. If
necessary, refer to U.S. OSHA 29 CFR 1910.138.
Personal Protective Equipment: Respiratory
None required where adequate ventilation conditions exist. If airborne concentration is high, use an appropriate respirator or dust
mask. If airborne concentrations are above the applicable exposure limits, use NIOSH-approved respiratory protection. If
respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable
U.S. State regulations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece
pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under
OSHA’s Respiratory Protection Standard (1910.134-1998).
Personal Protective Equipment: General
Wash hands thoroughly after handling material. Do not eat, drink or smoke in work areas. Have a safety shower or eye-wash
fountain available.

____________________________________________________________
Issue Date: 09/09/98 10:35:26 CLW --------- Page 3 of 7 Revision Date: 12/27/2010 4:00 PM SEP
 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150

* * * Section 9 - Physical & Chemical Properties * * *

Physical Properties: Additional Information
The data provided in this section is to be used for product safety handling purposes. Please refer to Product Data Sheets, Certificates
of Conformity or Certificates of Analysis for chemical and physical data for determinations of quality and for formulation purposes.
Appearance: White crystals Odor: Odorless
Physical State: Solid pH: 12.0 (1% solution)
Vapor Pressure: Zero Vapor Density: Not applicable
Boiling Point: Not applicable Melting Point: 166 deg F (73 deg C)
Solubility (H2O): 28 g/100 ml water @ 15 deg C Specific Gravity: 1.62(H2O = 1)
Freezing Point: Not applicable Particle Size: Not determined
Softening Point: Not applicable Bulk Density: Not available
Molecular Weight: 380.13 Chemical Formula: Na3PO412H2O

* * * Section 10 - Chemical Stability & Reactivity Information * * *

Chemical Stability
Stable under conditions of standard temperature and pressure. Trisodium Phosphate can react with air to form disodium phosphate
and sodium carbonate. Trisodium phosphate forms strong caustic solution, similar to soda lye. Solutions can react with metals
such as aluminum, zinc and galvanized iron to produce highly flammable hydrogen gas, that may explode if ignited.
Chemical Stability: Conditions to Avoid
Avoid high temperatures, exposure to air and incompatible materials.
Incompatibility
Trisodium Phosphate is incompatible with strong acids and may react violently; in solution reaction may cause splattering. In
solution, Trisodium Phosphate will react with metals such as aluminum, zinc and galvanized iron to form flammable hydrogen gas.
Trisodium Phosphate may react violently with magnesium. Trisodium Phosphate can be corrosive with some metals, including
aluminum, zinc and tin. Trisodium Phosphate is corrosive to gray cast iron at high temperatures and may be corrosive to steel or
brass, if wet.
Hazardous Decomposition
Phosphorus oxides.
Hazardous Polymerization
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute and Chronic Toxicity
A: General Product Information
May cause moderate to severe eye, skin, nose, throat and respiratory tract irritation or burns. After 0.1 ml of Trisodium
Phosphate was placed in the eye of a rabbit, a corrosive effect was seen within 24 hours. After 14 days, eye regained normal
appearance. Moderate irritation was observed when 0.5 mg/L of Trisodium Phosphate was held in continuous contact with intact
skin of a rabbit and abraded skin for 24 hours.
Chronic: Long term skin overexposure to this product may lead to dermatitis (red, itchy skin).
B: Component Analysis - LD50/LC50
Trisodium Phosphate:
LD50 (Oral-Rat) 7400 mg/kg; LD50 (Intraperitoneal-Mouse) 430 mg/kg; LD50 (Skin-Rabbit) > 7940 mg/kg
C: Component Analysis - TDLo/LDLo
LDLo (Intravenous-Rabbit) 1580 mg/kg
Carcinogenicity
A: General Product Information
Trisodium Phosphate is not considered carcinogenic by ACGIH, IARC, NIOSH, NTP, or OSHA.
B: Component Carcinogenicity
No information available.
Epidemiology
No information available.
Neurotoxicity
No information available.
Mutagenicity
Sex Chromosome Loss and Non-Disjunction (Oral-Drosophila melanogaster) 11 pph
____________________________________________________________
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 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150

* * * Section 11 - Toxicological Information * * * (Continued)

Teratogenicity
No information available.
Other Toxicological Information
LD (Skin-Rabbit) > 300 mg/kg
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
Product can be dangerous to aquatic life in high concentrations as it will increase the pH of the aquatic environment.
B: Ecotoxicity
No information available.
Environmental Fate
Product is not expected to accumulate in the food chain.

* * * Section 13 - Disposal Considerations * * *

US EPA Waste Number & Descriptions
A: General Product Information
EPA waste code for corrosivity (D002) may be required. Wastes should be tested to determine applicability.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
All wastes must be handled in accordance with local, state and federal regulations. This product, if unaltered by use, may be
disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
* * * Section 14 - Transportation Information * * *
NOTE: The shipping classification information in this section (Section 14) is meant as a guide to the overall classification of the
product. However, transportation classifications may be subject to change with changes in package size. Consult shipper
requirements under I.M.O., I.C.A.O. (I.A.T.A.) and 49 CFR to assure regulatory compliance.
US DOT Information
UN/NA #: Not Applicable
Shipping Name: Not Regulated
Hazard Class: Not Applicable
Packing Group: Not Applicable
Required Label(s): Not Applicable
Additional Info.: For packagings equal to or greater than 5,000 pounds this product is REGULATED as a U.S. DOT hazardous
material as the following: RQ, UN 3077, Environmentally hazardous substances, solid, n.o.s. (sodium phosphate, tribasic), 9, PG
III, Label CLASS 9.
50th Edition International Air Transport Association (IATA):
For Shipments by Air transport: This information applies to air shipments both within the U.S. and for shipments originating
in the U.S., but being shipped to a different country.
UN/NA #: UN 3077
Proper Shipping Name: Environmentally Hazardous Substance, solid, n.o.s. (Trisodium Phosphate)
Hazard Class: 9 (Miscellaneous Dangerous Goods)
Packing Group: III
Passenger & Cargo Aircraft Packing Instruction: 911
Passenger & Cargo Aircraft Maximum Net Quantity: 400 kg
Limited Quantity Packing Instruction (Passenger & Cargo Aircraft): Y911
Limited Quantity Maximum Net Quantity (Passenger & Cargo Aircraft): 30 kg G
Cargo Aircraft Only Packing Instruction: 911
Cargo Aircraft Only Maximum Net Quantity: 400 kg
Excepted Quantities: E1
Special Provisions: A97, A158
ERG Code: 9L

____________________________________________________________
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 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150
Limited Quantity Shipments: Shipments for air must be marked with the Proper Shipping Name Environmentally Hazardous
Substance, solid, n.o.s. (Trisodium Phosphate) and shall be marked with the UN Number (3077) preceded by the letters "UN", placed
within a diamond. The width of the line forming the diamond shall be at least 2 mm; the number shall be at least 6 mm high. The
total weight of each outer packaging cannot exceed 30 kg.
Excepted Quantities: The maximum quantity of this material per inner receptacle is limited to 30 g per receptacle and the aggregate
quantity of this material per completed package does not exceed 1kg. The inner receptacles must be securely packed in an
intermediate packaging with cushioning material to prevent movement in the inner receptacles and packed in a strong outer box with a
gross mass not to exceed 29kg. The completed package must meet a drop test. The requirements are found in 2.7.6.1. The package
must not be opened or otherwise altered until it is no longer in commerce. For air transportation no shipping paper is required. The
package must be legibly marked with the following marking:

NOTE: The “*” must be replaced by the primary hazard class, or when assigned, the division of each of the hazardous materials contained in the package. The “**” must be
replaced by the name of the shipper or consignee if not shown elsewhere on the package. The symbol shall be not less than 100 mm x 100 mm and must be durable and
clearly visible.
International Maritime Organization (I.M.O.) Classification
I.M.O. Classification: Sodium Phosphate, Tribasic is not regulated under the I.M.D.G./I.M.O. regulations.

* * * Section 15 - Regulatory Information * * *

US Federal Regulations
A: General Product Information
Trisodium Phosphate Dodecahydrate (CSA # 10101-89-0) is not on the TSCA inventory. As a hydrate, Trisodium Phosphate
Dodecahydrate is excepted from TSCA Inventory requirements (per 40 CFR 720.3 (u) (2)).
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
SARA 302 There are no specific Threshold Planning Quantities for Trisodium Phosphate Dodecahydrate. The default Federal
(EHS TPQ) MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR
370.20.
Trisodium Phosphate Dodecahydrate (10101-89-0)
CERCLA: final RQ = 5000 pounds (2270 kg) (Listed under 'Sodium phosphate, tribasic')
The following identified ingredients are not on the TSCA Inventory:
10101-89-0 Trisodium Phosphate Dodecahydrate
C: Sara 311/312 Tier II Hazard Ratings:
Component CAS # Fire Reactivity Pressure Immediate Chronic
Hazard Hazard Hazard Health Hazard Health Hazard
Trisodium Phosphate Dodecahydrate 10101-89-0 No No No Yes No
State Regulations
A: General Product Information
California Proposition 65
Trisodium Phosphate Dodecahydrate is not on the California Proposition 65 chemical lists.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substance lists:
Component CAS # CA FL MA MN NJ PA
Trisodium Phosphate Dodecahydrate 10101-89-0 Y N Y N Y Y
Other Regulations
A: General Product Information
Trisodium Phosphate Anhydrous is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water
Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply

____________________________________________________________
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 Material Safety Data Sheet
Material Name: Trisodium Phosphate, 12 Hydrate Crystalline (Technical Grade) ID: C1-150
to discharges of this substance.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Trisodium Phosphate Dodecahydrate 10101-89-0 No No Unlisted

C: Component Information (Canada)

Trisodium Phosphate Dodecahydrate is not listed in the WHMIS IDL
ANSI LABELING (Z129.1):
DANGER! MAY BE FATAL IF SWALLOWED. CAUSES SKIN AND EYE BURNS. HARMFUL IF INHALED. Do not taste
or swallow. Do not get on skin or in eyes. Avoid breathing dusts or particulates. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling. Wear gloves, goggles, faceshields, suitable body protection, and NIOSH/MSHA-
approved respiratory protection, as appropriate. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of
water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, do not
induce vomiting. Get medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or “alcohol” foam. IN CASE
OF SPILL: Absorb spill with inert material or neutralizing agent for bases. Place residue in suitable container. Consult Material
Safety Data Sheet for additional information.

* * * Section 16 - Other Information * * *

Other Information
Chem One Ltd. ("Chem One") shall not be responsible for the use of any information, product, method, or apparatus herein
presented ("Information"), and you must make your own determination as to its suitability and completeness for your own use, for
the protection of the environment, and for health and safety purposes. You assume the entire risk of relying on this Information.
In no event shall Chem One be responsible for damages of any nature whatsoever resulting from the use of this product or
products, or reliance upon this Information. By providing this Information, Chem One neither can nor intends to control the
method or manner by which you use, handle, store, or transport Chem One products. If any materials are mentioned that are not
Chem One products, appropriate industrial hygiene and other safety precautions recommended by their manufacturers should be
observed. Chem One makes no representations or warranties, either express or implied of merchantability, fitness for a particular
purpose or of any other nature regarding this information, and nothing herein waives any of Chem One's conditions of sale. This
information could include technical inaccuracies or typographical errors. Chem One may make improvements and/or changes in
the product (s) and/or the program (s) described in this information at any time. If you have any questions, please contact us at
Tel. 713-896-9966 or E-mail us at Safety@chemone.com.
Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of
Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for
Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health
Administration

Contact: Sue Palmer-Koleman, PhD Contact Phone: (713) 896-9966

Revision Log
07/11/00 10:50AM SEP Company name revised, Sect 1 and 16, from Corporation to Ltd.; text in Sect 12 “will lower pH”,
changed to “will increase pH”.
06/02/01 9:31 AM HDF Checked exposure limits; made changes to Sect 9; overall review, add SARA 311/312 Haz
Ratings.
08/20/01 6:00 PM CLJ Add Shipments by Air information to Section 14, Changed contact to Sue, non-800 Chemtrec Num.
09/30/03: 11:10 AM HDF General review and up-date of entire MSDS. Up-date of HMIS categories. Up-date of Section 8.
Addition of Stability information, Section 10. Up-date of toxicity data, Section 11. Up-date of Section 14. Addition of Clean
Water Act information, Section 15.
06/22/05: 11:10 SEP Updated IATA, Section 14
10/23/07 2:31pm SEP Updated IATA Section 14
10/15/08 10:53 AM DLY Changed Chem One Physical Address, Section 1
12/27/2010 4:00 PM SEP Updated IATA
This is the end of MSDS # C1-150

____________________________________________________________
Issue Date: 09/09/98 10:35:26 CLW --------- Page 7 of 7 Revision Date: 12/27/2010 4:00 PM SEP
RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
 RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018
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RELEASED FOR CONSTRUCTION

thyssenkrupp Industries India Pvt. Ltd.

Pimpri Pune - 411 018