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CHEMISTRY

CLASS 11

Formula
Sheet
NCERT Kaksha
38 Ohe

Velocity
Distance
-
Acceleration =
Velocity 1 = 1.66056x10-24 gram
time time

atomic mass unit
Mass Force

density= ressure

NCERT
=

Area
volume

of Forenheit
=

()
"F 32k 0 + 273.13
o
+ Celsius
= =

Temperature
=

=
Kelvin

Weight (in grams


Number of grams of atoms =

gram atomic mass


X

KAKSHA
Multiply
=

Molecular Mass
(AxB(y) xx)Atomic =
mass of Al+[Atomic mass of B) +
yx (Atomic mass
of C]

OR

Molecular Mass =
Actual mass of a molecule
of matter

"atom
X mass of one

Mass (in grams


Gram Molecular No. =

Molecular
weight
atomic weight of the element
Equivalent weight of the element =

valency
formula weight of salt
Equivalent weight of common salt=
total cationic
charge on the part

Equivalent weight of acidic salt -

formulaweight ofsatintent in salt

Equivalent weight of acid -

weight ofacidrule
secular
Equivalent weight of Base:
weightof Basein
ecular molecule

assin
gramsan
Molecular weight 2X vapour density
=

quam Equivalent weight

A =
atomic weight Molecular formula weight
A EXY x
=

Equivalent
=
E =

weight
v
Empirical formula weight
valency
=

n Integer (1, 2, 3, 4....)


=

NcertkakshalUmesh
· Saini Vaishali saini
formula mass of AB: Atomic mass of At Atomic mass of B

Mass of the element in the compound


Percentage composition -

X 100
Molar mass of the compound

Mass of solute
Mass
percentage X 100
=

Mass of solution

Mole fraction Mole fraction of A =

moles
ofnation
NO. of
=
HA

MA+ MB

of
molesofbilation
NB
mole fraction ofB - =

MA+ MB

The sum
of the mole fractions of all the components of a solution 1
MA+ Mp
=

is always the unit.

in
No. of Moles
- weight Mass

of
molesofsolute
a

Molarity (M) -

liters

Molality (m) -

of
molesof solutebest

NcertkakshalUmesh
· Saini Vaishali saini
BB******
"
kg-
e
1.750028x1
change to mass Ratio of electron x
= -

e Magnitude of the
change the electron, me: Mass of the electron
=
on

.
absolute

Relative changeMasooooooootati
OCo23nspd
change(es

&· ret

NCERT
Electrone-1.6x 18-19 L
+-n
-

Proton p + 1.6x18-19 + 1
-

Neutron R O

Ac Mass number

Atomic (2)
No. of Protons in the =No. of electrons in a

2X
no. =

nucleas of an atom neutral atom


-Nuclear symbol
>

KAKSHA
Atomic Number

Mass number (A) =


No. of protons (2) + No. of Neutrons (n)

c velocity of light
=

Relation between
wavelength and
frequency c =
0 X v
frequency
=

x:
wavelength
(6.626
3*
Plank's sec)
function constant
n x 10 J-
work
:

Wo =

GU Uo:threshold frequency v velocity


=

Energy of Photon E= ho

hw+tMeU"
E
Kinetic
energy of Electron
De-Broglie wavelength x
*
=
=

Ci
line spectra of Hydrogen j -
R p
momentum
=

wave number 2

GE Ez-E
Bohn's rule
frequency v of highly allowed state
=

Ez=Energy energy
=

Energy of lower allowed state


energy
=

1,2,3,....
merr=
n
Angular of Electron
=

momentum
r =
radius

do 52.9 pm
Radii of the
stationary states H"a
=

rn
=

n 1,2,5....
=

Energy of stationary
=-Rn/)
states En Rn Rydberg
=

constant

xx
uncertainty in position
=

Heisenberg Uncertainty principle A1XUP- Op: uncertainty in momentum

Schrodinger Equation 7 "x + 0T"m(E -V. N


12
0
=

T 0 jj2
E= Total energy of system
=

Mathematical operator + +
V =
Potential energy of system xx by 823

Total no. of nodes Angular node+ Radial node =


1 + (n -1- 1) n- 1
=

Autbau Principle of
Increasing order
energy of orbitals

Is, 23, 24, 3s, 3p, 4s, 3d, 4p, 35, 4d, 3p, 4f,3d, 6p, 7s...

NcertkakshalUmesh
· Saini Vaishali saini
(888NOO
% a

s-block p-block
-
..

NCERT
-
d-block
I

KAKSHA
↑ ↑

f"block

NcertkakshalUmesh
· Saini Vaishali saini
Bog ****** 585****

Formal
charge

I FormalChangeC a) (totalinaofouvalence
E

on an atom in -
-

I totalno.of nonbonding- I totalnumberintothe I


Dipole moment 0XM
D,
x =

0
-

change, r =
distance of separation

Debye (1D 3.33564x1030c. m)


=

sum and difference of wave functions 4mo" Ya*No

Bond
order=t(Nb-Na) No -No.of electronsoccupyingbondingorbitalinstals

NcertkakshalUmesh
· Saini Vaishali saini
358*r
Boyel's law
(Atconstant
PC + and x) P kc
= =

(pressure- volume
Relationship r

H tr
Proportionality
k1 constant
Temperature
P1Vc Pc Ve T
=

OR
=

is
=
+
=

v =
volume m Mass
=

NCERT
p= Pressure

From boyel's lawd


Density d= (51) p
=

Charle's law

k Ea
v x T (Atconstant P and n) ] V kzT
=

OR =

(Temperature -

Volume Relationship
kc constant
=

KAKSHA
Avagadro's law
v
n n o. of moles
y n- kyn
=

=
a
(volume -
amount Relationship

Ideal equation PV=nRT constant (8.20578 x 10-L-atm-Mol "k")


gas R: gas

law
combined Say Lussac's PXT

=
law
gas (Pressure -

Temperature Relationship
*
= constant =

ks
T

molar of gaseous substance M

tR
mass M Molecular mass
=
=

d =

density

Dalton's law of partial pressure Ptotal -

P, +P2+Pst.... (At constant + and V.

Pressure of dry gas p


Ptotal aqueous density
-
-

dry gas

Partial Pressure in terms of mole fraction


Pi= x, Ptotal P. "Partial Pressure
"Mole fraction
x;

Average of M,+Uzt..... Un
Uar-
speed molecules
Hav= oR

Root mean square velocity Unms= = ..... un


0 + on Uems
-
Urms?Mav> Ump n of molecules
=
no.

U., U2, My.... Un= individual speeds

Urms: root mean square speed


Ump: Uav: Urms: 1: 1,128: 1.224 uav
-average speed
Ump: most probable speed

=/RT
n cofficient of viscocity
viscosity F
YA
Probable
Ump
=

= Most speed
A Area
=
of contact

All velocity gradient


I

compressibility factor
= ed
For ideal and z
in
2
z gas 1
= =

NcertkakshalUmesh
· Saini Vaishali saini
--
r =
speed of diffusion
Graham's diffusion law
thee d

M
=

density of
Molecular
=
gas
mass of gas
p Pressure of gas
=

v volume of gas
tmnc
=

Kinetic gas Equation PV =

m
weight of single molecule of
=

gas
n number of molecules present
= in the volume

=volume
Kinetic
energy of one molecule of gas
Ex=EKT. n Root velocity of molecules
=
mean square
k
(Boltzmann's constant)
=

Vanderwaals
(P ac)(v
+ b) RT
=

Equation for
-

n 1
=

of
12-Mc/2RT dedn.
The number molecules who e

4T/*
=

Maxwell
velocity distribution
duo =

T =
speed
Absolute
is between

temperature
c and c+d

fludity=1
H

NcertkakshalUmesh
· Saini Vaishali saini
***
in XV W (first thermodynamics)
Change inertial
energy g + of
=
law

work
Weer =-") Pexav Weer =-2.303 nRT
log to
Vi

NCERT
Heat
9:
Free Expansion &V g PexOU
= =

Pex
=
external force

Enthalpy UH
QV+UngRT
=

Meat
Capacity 9: COT C :
Heat
capacity

KAKSHA
(m
Capacity =
Molar Heat

"Heat Pressure
Cp capacity at constant

Relation between Cp and Cr (p-Cy =


R =Heat at
Cv Capacity constant volume

Enthalpy Change

WnH =
(sum of enthalpies of products) -

(sum of anthalpies of reactants


OR

UrH =

Ea; M
product
-

zbiH Rectants

standard bond
Relationship between
enthalpy to
anthalpy

UrHE= I Bond enthalpy reactants


-

I Bond enthalpy products

anthalpy of Solution
(sol NO
=
U NO + Δ HO
lattice hyd

US 9 nev
entropy change for reversable
=

process
T

Total
Entropy Change US
total
=
US
system
+ US suer> O

Gibbs function G =
H -

TS

Gibbs Energy 4G0=- RTLnk OR


UrGO=-2.303RTlogK

NcertkakshalUmesh
· Saini Vaishali saini
Ea
Equilibrium Equation Kc= (CTID kc =

Equilibrium constant

SAT (B]

Equilibrium constant for a


general reaction (c=(C)'(D7*
SAYY(B)
*

kc
Tc

NCERT
Equilibrium
=

constant for the reverse reaction in the inverse reactions

Kp=(CTID7*(RT)
*" *
Equilibrium constant in
gaseous state OR Kp k, (RT)
=

SAYY(B)
*

Reaction quotient Qc=(CT'ID7*


SAYY(B)
*

KAKSHA
Relation between Equilibrium constant K. Reaction quotient & and Gibbs G
Energy

0G0+ NG0=- RTIn UGO/RT


RT In Q
-

5G =
K k e
=

log(HT) }
UG=standard gibbs energy
pH =

-log an+=
-

Molc

Acid Solution has pH L F

Basic solution has pH - 7

Neutral Solution has pH =


f
Ka-capacity of acid
Relation between Ka and Ko kaxkb =

Kw ko: capacity of base


ionic product of water
Kw
=

Mendesson -

hall equation
pH=pKa+ [Conjugate base, A-T
log
[ acid
MAT
[A]
Ratio
of conjugate base (cation) and solution in acid
=

CHAT

NcertkakshalUmesh
· Saini Vaishali saini
*****

Based on the ancient concept

Addition of oxygen/ electronegative element


Oxidation =
OR
Removal of hydrogen/ electropositive element

NCERT
Reduction:
Addition of hydrogen/electropositive element

OR

Removal of oxygen/ electronegative element

Redox Reaction Oxidation =

+ Reduction

KAKSHA
Based on new concepts

Oxidation electron
-

ejection
Reduction =
gain of electrons

N.= Normality of Solution 1, Nc= Normality of solution 2

Normality Relation NLVI=NaVa Vs= volume of solution 1 Vc-volume of solution 2

M1 =

Molarity of Reducing solution

MaVe =
Relation Vi solution
Molarity
volume of Reducing
=

Mc Molarity of oxidized solution


=

volume of oxidized solution


Ve:

NcertkakshalUmesh
· Saini Vaishali saini
-

Some Chemical compounds names & Molecular Formulas

Molecular Molecular
compound Name
Formula compound Name
Formula

Acetic acid Potassium Nitrate KNO3


CH3COOH

Hydrochloric acid MCL


Ammonium chloride NH4CL

NCERT
sulfuric acid Ammonium hydroxide NH4OH
H2SO4

Acetate
CH3COO
calcium nitrate
Ca(NOsI2
Peroxide H2Oz
Ammonia
NHz Hydrogen

KAKSHA
Nitric acid silver chloride AgCI
HNO3
Barium sulphate BaSO4
Phosphoric acid My PO4

Sodium Phosphate NazPO4 Magnesium sulphate Mg5O4

calcium carbonate
CaCO3
sodium sulphite NagSO3

Sodium Bicarbonate 0 xalic acid MgCgOU


NaMCOS
Sodium potassium dichromate KgCMg07
Hydroxide NaOH

Zinc chloride 2nC12


Calcium
Mydroxide ca (OH)2
Ethanol CaMsOH
Zinc
hydroxide InCOHCe
NitrOUS Acid HNOG
Zinc sulphate InS04

Potassium Hydroxide KOH Phosphorus Pentachloride PC13


-

sodium nitrite
5) Iver nitrate
AgNOz NaNOg

Potassiune
sodium carbonate NagCO3 Permagnate KMnO4

Boric acid NgBOg


Magnesium Hydroxide MgCONc
potassium nitrite KNOg
Methane CHy

Sodium chloride NaCL Tartaric acid C4M60g

carban tetra chloride CCly


Aluminium Hydroxide Al (OH)

sodium Iron oxide FegOS


sulphate NazSO4

NcertKaksha/Umesh
· Saini Vaishali saini
Dogs
Properties of Hydrogen

Relative abundance (%) gg.985

NCERT
Relative atomic mass 1.008

Melting point 13.96

Boiling point 20.39

KAKSHA
Density 0.09

Internuclear
enthalpy 74.17

Covalent Radius 37

Zonic Radius 20y

Properties of Mat

I 11
Molecular Mass 18.0151

Melting point 273.8

Boiling point 373.8

Density 1.0000

0.8903
Viscocity
ielectric
D) constant 78.39

conductivity, 3.7x18%,
I

NcertkakshalUmesh
· Saini Vaishali saini
Yes (Does -

Group 1 Elements · Alkali Metals

#
symbol (
Electronic configuration
is was,

NCERT
sodium NC 15 "25-2p63s'

potassium Kis"2s"2p63s "3p6 Us'

Rubidium Rb is 2s-2p63s"3p3d10 us"Up65s'

KAKSHA
Us-Upond'035-36b
p63s23p63d10
-
caesium CS is25 2
OR

Francium Fr [Rn] 7S'

Group 2 Elements: Alkaline Earth Metals

# interes
an.somar Erectronicconciano
Beryllium Be

Calcium

"
Strontium Sr is 2s"2p63s"3p3d10 us"Up65s

Barium Ba is2s-2p63s-3p'3d10 us"Upoud"5s "5666s


OR (x2) 632

Radium ·Ra [RN] 752

NcertkakshalUmesh
· Saini Vaishali saini
*Rep (b***s=

General Electronic Configuration and Oxidation States

i
a ro
#the ni n NCERT
group electronic oxidation

13 ns-upF B (Boron) +3

14 ns "up" c (carbon) +4

KAKSHA
3
15 ns-Up N (Nitrogen) +5

16 ns-up4 0 Coxygen) + 6

IF ns-ups (Flourine)
F + 7

ns-up6

NcertkakshalUmesh
· Saini Vaishali saini
⑱-- S*4
#Boas
IUPAC Names of Some Common names of
Unbranched Saturated
Hydrocarbons some
Organic compounds

NCERT
on


compound Molecular Name
Name
Formula

CH4 Methane
Methane CH4
MyCCHzCHgCH3 n-butane

KAKSHA
Ethane CeH8
(MSC), CHCH3 sobutane
I

P
ropane (3Hg
(MzC)pC Neopantane
Butane C4H1O
HzCCHgCHgOH
Pentane (5M12
HCHO
Hexane CH14
(HzC)2C8 Acetone
Meptane C=H16
CHCI
Octane CyM18
CHICOOH Acetic acid
Nonane CqMco
CHG Benzene
Decane CoH22
CoNzOCHs Anisole

CoNzNHz Aniline

sAcetophenone

CMgOCHICH3 fthyl Methyl Ether

NcertkakshalUmesh
· Saini Vaishali said i
Some functionalgeoups & Classes of Dompounds

I
IUPAC

ran
Functional
class of
compounds group
structure grOUETC group
suffixe

Alkanes

NCERT
Alkenes xC C
=

CE) yne
Alkynes
-
- -

Arenes

KAKSHA
Halides
(IFF,c,Br,t) nalo =

Alcohols OL
OM
hydroxy-
-
-

Aldehydes CMO
forenyl, OXO al
-
-

Ketones x =0 OX0- -

One

Nitriles CEN nitrile


cyano
-

R 0-R-
Ethers
alkoxy
- -

--

Carboxylic oic acid


COOH
carboxy
-
-

acids.

Carboxylic -

200% -

Oate
ions

Esters COOR Oate


alkoxycarbonyl
- -

COX
Acyl nalides
halocarbonyl oyl Halide
-

(X =
F,(1, Br, 1)

Amines -NH2 c
amino- -

amine
> NH, > N

CONHz,
A mides carbonyl amide
-

CONHR
-

CONR2
-

Nitro
nitro
-NOg
compounds

sulphonic sulphonic
sulpho
t acids acid

NcertkakshalUmesh
· Saini Vaishali saini

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