Decarbonising The Aviation Industry

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Decarbonising the aviation

industry
The future of sustainable aviation fuels is driven by a commitment to
ambitious decarbonisation targets and continuous innovation

Yvon Bernard, Carine Leclercq and Nicolas Simon


Axens

T
o address the array of climate targets set megatons of CO₂ emitted in 2022. For
by national and international authorities this reason, the International Civil Aviation
worldwide, industries in every sector must Organization has set ambitious goals to
seek efficient and dependable solutions in the reduce net CO₂ emissions by half by 2050, in
transition from fossil fuels. These heightened comparison to 2005 levels. Furthermore, the
demands, driven by environmental concerns global air transport industry, through the Air
and sustainability regulations, have created Transport Action Group, has embraced a long-
the complex challenge of finding cost-effective term climate goal of net-zero emissions by
solutions to reduce reliance on fossil fuel 2050. This confirms the commitment of global
resources. airlines, airports, air traffic management, and
Achieving these ambitious targets – as outlined manufacturers of aircraft and jet engines to
by the Intergovernmental Panel on Climate reduce their CO₂ emissions in line with the Paris
Change and various national pathways toward Agreement’s goal of limiting global warming to
achieving net-zero emissions – will require 1.5°C by 2100 (UNFCC, 2015).
behavioural changes, efficiency gains, and the
leverage of renewable or low-carbon energy Main regulatory frameworks for SAF
sources available around the world, including SAF will be essential to achieving the aviation
solar energy, wind energy, biomass, and more. industry’s ambitious decarbonisation targets.
Regulations will play a large part in increasing
Rising sustainability standards in the the share of SAF used in aviation and defining
aviation industry the products that will qualify as SAF. Currently,
Sustainable aviation fuel (SAF) is one of the there is no global consensus on these
solutions to decarbonise the aviation industry. regulations. However, two main approaches
Just as SAF must be combined with other currently exist in the industry.
decarbonisation solutions, experts do not expect In the US, many fuel purchasers are
that one single SAF production technology will be considering carbon-intensity-based metrics
able to meet the increasing demand for this fuel. to evaluate fuel sustainability, commonly
For this reason, government agencies, refining utilising tools such as the Greenhouse Gases,
companies, and aviation industry stakeholders Regulated Emissions, and Energy Use in
are collectively investigating the full range of Transportation (GREET) model developed by
technology pathways to substitute fossil-based Argonne National Laboratory. Such models
jet fuel with SAF based on renewable sources. do not group feedstocks or processes by
These sources include agricultural and forestry category, but rather they scientifically calculate
residues, alcohols, wastes, and energy crops, as a given feedstock’s overall greenhouse gas
well as CO₂ and renewable hydrogen. emission profile considering its production,
Today, aviation accounts for 3% of global transportation, processing, and use. The
greenhouse gas emissions, including 890 outcome is a scientifically based and quantified

www.decarbonisationtechnology.com 45
requires e-SAF to increase from 1.2% of
What is SAF? aviation fuels in 2030 to 35% in 2050. European
regulations promote advanced biofuels sourced
SAF is an alternative to traditional fossil from feedstocks that are not in direct or indirect
jet fuel and a promising solution to reduce competition with food resources. These include
carbon emissions in the aviation sector. It recycled carbon fuels (potentially using waste
can be produced from two major sources: from non-renewable sources) and low-carbon
• Renewable or waste-derived bio- fuels (possibly including hydrogen produced
based resources that meet sustainability from nuclear power). These options all share
criteria depending on their origins, such the goal of achieving at least a 70% reduction in
as renewable oils and fats, lignocellulosic greenhouse gas emissions.
biomass, wastes, sugars, and low carbon In addition to these two major regulatory
intensity inedible starches. frameworks, several other countries (such
• Captured CO₂ combined with renewable as China, India, and Thailand) are currently
hydrogen (produced via water electrolysis preparing their SAF regulations. These will be
using electricity from renewable sources) released shortly so the industry can prepare for
or low-carbon hydrogen (generated using the first milestones.
either nuclear power or fossil natural gas
with CO₂ sequestration). Depending on Expanding the global supply of SAF
regulations, some traditional hydrogen may To align with all regulations, the aviation industry
or may not be used. This synthetic aviation must significantly ramp up its adoption of SAF
fuel is known as e-SAF (also known as in the coming years. The industry will have to
Power-to-X, synthetic fuels or e-fuels). expand the range and increase the production
SAF is considered a drop-in fuel, meaning of available feedstock for this to be possible.
it can be blended with traditional jet Today, most of the world’s SAF comes from
kerosene. It can currently be blended up vegetable oils such as rapeseed and palm oil.
to 50% by volume maximum for the main Some regulations, such as the revised European
pathways (FT-SPK, ATJ-SOK, and HEFA-SPK Renewable Energy Directive, ban the use of soy
certified by ASTM) without requiring any and palm oils for biofuels because the feedstock
equipment changes, special infrastructure or is in competition with the food industry (EUR-
modification of the supply chain, which helps Lex, 2023). As a result, lipidic second-generation
limit the overall supply chain investments. feedstocks, including animal fats, used cooking
oil, and palm oil mill effluent, are taking over.
These feedstocks will only allow the industry
Carbon Intensity (CI) score. The CI score then to meet the first milestone with few percent of
determines the sustainability of a given fuel SAF incorporation. To move beyond this plateau
compared to fossil fuel baselines. Additionally, caused by the limited volume of lipidic second-
it provides a foundation for regulatory and generation feedstock, the second phase will
credit structures to incentivise CI reductions require constructing industrial plants to produce
throughout the entire SAF value chain. SAF from other feedstocks.
A different approach is taken in Europe, where
the European Union has committed to reducing Three major feedstocks for the future of SAF
its overall emissions by 55% by 2030. To reach In collaboration with its partners, Axens has
this goal, the European Commission introduced already developed expertise to utilise the next
its ‘Fit for 55’ package of legislative proposals. generation of feedstocks for the production of
Among them, 11 initiatives have a direct impact SAF and e-SAF. These include biomass, which
on transport, and ‘ReFuelEU’ is the initiative are typically residues from agriculture, forestry,
dedicated to aviation. Under this initiative, the and other waste products that do not compete
SAF requirement will rise from 2% of aviation with food crops. CO₂ captured from sources
fuels in 2025 to 6% by 2030 and then 70% in such as flue gas, cement or steel factories and
2050. A sub-obligation of this SAF mandate power plants or biogenic CO2 (produced from

46 www.decarbonisationtechnology.com
Water
Electrolysis
E H2

O2

O2 H2
Biomass SAF / e-SAF / e-biofuels
CO2
H2 H2

H2S CO H2O CO
1 2 3 4
Pretreatment Gasification Conditioning FT & Upgrading

Figure 1 Gasification and the FT pathway for SAF and e-SAF production

biomass) combined with green H2 (produced same infrastructure and units are shared, and
with low-carbon electricity) are the feedstocks the biogenic carbon source is concentrated
for e-SAF (dedicated to aviation fuels) or and cost-free.
e-biofuels (generic name). In both cases, the
feedstocks are combined with hydrogen to Ambition to operate Europe’s largest SAF
produce e-fuels or SAF. production unit
Together with its partners (Avril, IFP Energies
Expertise in biofuel production: nouvelles, TotalEnergies, ThyssenKrupp-Uhde,
The biomass pathway CEA, and other local and financial partners),
The ASTM D7566 standard for aviation fuels Axens has proven the value of the BioTfueL
allows for several technological pathways for technology on two large-scale demonstration
the production of synthetic kerosene. Axens plants processing a broad spectrum of
offers commercial solutions for some of these, lignocellulosic biomasses for the production of
such as HEFA-SPK, ATJ-SPK, and FT-SPK, SAF and byproducts such as renewable naphtha.
which can be extended to both SAF and e-SAF Axens is now involved with its partners Elyse
(whenever green H2 is added) production. Energy, Avril, IFP Investissements, and Bionext
Under the FT-SPK pathway, the BioTfueL in the BioTJet project. This project, which aims
(biomass-to-fuel) technology can combine to build and operate the largest hydrogen and
lignocellulosic biomass and renewable hydrogen lignocellulosic biomass-based SAF production
to create high-quality SAF. Biomass feedstocks unit in Europe, aligns with the European
are diverse, and it is possible to use energy energy transition strategy and the aviation
crops (such as miscanthus), agricultural waste sector’s ambitious decarbonisation objectives.
(such as bagasse, rice straw, and wheat straw) Recognising its potential, the French Agency for
and forestry residues. Ideally suited to farmers Ecological Transition (ADEME) gave the project
and industrial players with access to large support as part of the France 2030 Investments
volumes of these natural residual products, the for the Future Program under the call for
FT-SPK pathway involves heating the biomass proposals for the ‘Development of a French
(torrefaction) and converting it into a gas Sustainable Aviation Fuel production sector’.
(gasification). Renewable hydrogen becomes Axens is supporting the development of the
important to improve carbon efficiency during BioTJet project beyond the conventional role of a
syngas conditioning. It is combined with syngas licensor and equipment, catalyst, and adsorbent
to meet proper conditions to create hydrocarbon supplier by becoming a shareholder and partner
products through Fischer-Tropsch (FT) synthesis. of the BioTJet project company. This equity
Combining biomass and renewable hydrogen investment represents a significant milestone
in a refinery can create valuable synergies. The for the commercial development of BioTfueL.

www.decarbonisationtechnology.com 47
DMX
AdvAmine Gasel
Carbon CO2 Reverse water Fischer-Tropsch
capture conditioning gas shift and upgrading
CO2
H2

Electrolysis H2 purification
H2
Water
O2 Tail gas
treatment

Figure 2 CO₂ capture pathways

Expertise in e-fuel production: CO₂ pathway (DAC) or oxy-fuel combustion, are currently less
The pathway for e-SAF production involves the mature and have lower technology readiness
combination of CO₂ with renewable hydrogen. levels compared to the more established post-
Axens has an extensive e-SAF offer, which combustion and pre-combustion pathways.
includes the reverse water gas shift (RWGS) However, because DAC will likely be able to
technology, carbon capture solutions DMX and effectively capture the CO₂ directly from the
AdvAmine, catalysts and adsorbent materials, atmosphere, it has the potential to drastically
along with its Fischer-Tropsch solution Gasel. reduce greenhouse gas emissions in the long term.
As renewable hydrogen remains costly and
CO₂ resources are limited until direct capture Take Kair: Capturing carbon to produce SAF
technologies become more mature, Axens In 2023, Axens signed a memorandum of
has developed an integrated e-fuel complex understanding with EDF, Holcim, and IFPEN for
with near-full carbon recovery and optimised the ‘Take Kair’ project to develop an industrial
hydrogen consumption. Maximising resource e-SAF facility in the west of France.
utilisation is a key condition for the widespread This project illustrates the key role played by
deployment of e-SAF. consortiums in this emerging field. Holcim will
capture biogenic CO₂ at its cement plant in the
CO₂ capture pathways Mayenne department, and EDF will contribute
CO₂ capture consists of extracting the CO₂ expertise in hydrogen production. At the same
produced by various industries. Two main time, Axens and IFPEN will jointly develop
carbon capture pathways are available: and integrate the low-carbon fuel synthesis
• The post-combustion pathway focuses on the processes, including Fischer-Tropsch synthesis.
treatment of CO₂-containing flue gases at close Air France-KLM will be the main off-taker of the
to atmospheric pressure. One effective solution product to be used in its planes.
for this is chemical absorption, which involves If the necessary financing is obtained, the aim
separating the CO₂ from other gases through is to start the construction of the unit in 2026,
absorption in a chemical solvent to produce a with a first phase of production in 2028. One
clean flue gas. This solution is licensed under of the first industrial e-fuel production projects
the commercial name DMX by Axens. Solvent- in France, Take Kair will save more than one
based processes are generally considered to be hundred kilotons of CO₂ emissions per year
more mature than other technologies, such as compared to the fossil equivalent.
physical absorption.
• The pre-combustion pathway involves Comprehensive solutions from a reliable
capturing CO₂ before fuel combustion, typically partner
on syngas. This solution is licensed under the With more than 40 years of experience in the
commercial name AdvAmine by Axens. In this fields of biofuels and biotechnologies, refining,
case, the fuel is processed with steam or oxygen and petrochemicals, Axens has been at the
to create syngas. forefront of developing the core technologies
Other solutions, such as direct air capture that underpin all major e-fuel production

48 www.decarbonisationtechnology.com
pathways. The company’s expertise enables one-and-a-half times as much as bio- or waste-
close collaboration with customers, tailoring based SAF, but with a lower carbon footprint
solutions to meet the specific requirements which is ultimately the goal of reducing the
of each situation. This flexibility is particularly aviation sector impact. As H₂ and CO₂ prices
valuable for e-SAF and SAF projects, as they decrease, coupled with advancements in process
often necessitate integration with existing technologies and the establishment of larger-scale
infrastructure, facilities, and equipment. plants, the production cost of e-SAF is expected
to decrease significantly. While SAF remains
SAF and e-SAF: Increasingly competitive more expensive than traditional fossil fuels,
fuel sources the future of sustainable aviation fuels appears
In the realm of e-SAF processes, electrolytic promising, driven by a commitment to ambitious
hydrogen and CO₂ are pivotal feedstocks which decarbonisation targets and continuous innovation
influence both the cost and sustainability of for a more sustainable aviation industry.
e-SAF. The cost of hydrogen is tied to the
price of renewable electricity, which is on a AdvAmine, BioTfuel, DMX, and Gasel are trademarks of
Axens.
downward trajectory with expanding production
capacities. At the same time, the price of CO₂
is linked to the development of carbon capture LINKS
technologies and ongoing industrial projects.
More articles from: Axens
Considering no incentives on investment
nor on offtakes, with low carbon electrolytic More articles from the following categories:
Alternative Fuels
H₂ priced at €5,000 per ton, a litre of e-SAF
Emissions Reduction
costs between four and seven times as much
Marine, Aviation & Transportation Fuels
as conventional fossil-based jet fuel and about

www.decarbonisationtechnology.com 49

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