Preparation method of high proportion mixed oil cocamide DEA (diethanolamine)

CN102755856A
China
Abstract
The invention relates to a preparation method for raw material of detergent, in particular to the
preparation method for high proportion mixed oil cocamide DEA (diethanolamine). The high
proportion mixed oil cocamide DEA comprises, by mass percent, 45-50% of coconut oil, 5-7%
of palm kernel oil, 45-50% of diethanol amine. Free amine value of prepared cocamide DEA is
120-150. The prepared cocamide DEA is light yellow transparent liquid with high viscosity. The
preparation method is simple, low in cost, and applicable to large-scale production in detergent
industries. In addition, industrialized production is easy to implement.
Description
A kind of production method of the Ninol of miscella at high proportion
[technical field]
The present invention relates to a kind of production method of novel surfactant, specifically is
the surface-active agent and process for producing same that is used to make washing agent.
[background technology]
Ninol belongs to non-ionic surface active agent, does not have cloud point.Proterties be faint
yellow to amber thick liquid, soluble in water, have functions such as good foaming, steady
bubble, infiltration decontamination, anti-hard water.Belong to non-ionic surface active agent,
the compatibility thickening effect is obvious especially with it when anion surfactant is acidity,
can with kinds of surface activating agent compatibility.Can strengthen cleaning effect, can be
used as additive, foam stabilization agent, foaming aids, be mainly used in the manufacturing of
shampoo and liquid detergent.In water, form a kind of opaque vaporific solution, can be
transparent fully under certain stirring, under finite concentration, can be dissolved in fully in
different types of surfactant, in low-carbon (LC) and high-carbon, also can dissolve fully.The
production method of the Ninol of miscella at high proportion involved in the present invention
has higher consistence, is prone to processing and lower cost.
[summary of the invention]
The objective of the invention is to overcome the deficiency of prior art, a kind of production
method of the Ninol of miscella at high proportion is provided.The present invention realizes
through following technical scheme: the Ninol of miscella at high proportion involved in the
present invention, component and mass percentage content are: coconut oil 45%-50%, palm
kernel oil 5%-7%, diethanol amine 45%～50%.The unhindered amina value of the Ninol of
producing is 120～150, is light yellow transparency liquid, has very high viscosity.The
production method of miscella Ninol at high proportion is characterized in that processing step
is:
Step 1 is with coconut oil, palm kernel oil with put into retort;
Step 2 is slowly poured diethanol amine and constantly stirring into, adds the sodium chloride of
gross mass about 1% simultaneously;
Step 3 in 130 ℃～180 ℃ reactions down of temperature, after treating to react completion in 5
～10 hours, is taken out liquid.Whether with the hydrochloric acid solution check of 0.01mol/l, it
is qualified to check.
In the step 1, the mass percent of said coconut oil is 30%～40%, and the palm kernel oil mass
percent is 35%-50%.
In the step 2, said diethanol amine addition is 45%～50% of a gross mass.

In the step 3, described reaction should be reacted under 0.1～0.2Mpa.

In the step 3, described unhindered amina value both had been qualified between 120～150.
The present invention has following beneficial effect: the viscosity of its product is high, and
consistence is good, and water absorbing capacity is strong, has good foaming and steady bubble
effect, has littler ammonia taste, and human body skin etc. is had littler spread effect.Preparation
method of the present invention is simple, and cost is low, is prone to realize industrialization
production.
[specific embodiment]
Below in conjunction with embodiment the present invention is described further.Production
technology of the present invention is to implement easily to this professional people.The
experimental technique of unreceipted actual conditions in the following example, usually
according to normal condition, or the condition of advising according to manufacturer.
Embodiment 1
With gross weight is that the coconut oil of 65.2g and the palm kernel oil of 10.1g add in the
retort of 200ml, slowly adds diethanol amine 64.7g, does not stop to stir.Add 1.4g sodium
chloride.Send in the autoclave, reaction is 6 hours under 0.2MPa, 135 ℃ condition, and
constantly stirs.Use 0.01mol/L salt acidometric titration then, find that the unhindered amina
value is 123, promptly obtain miscella Ninol at high proportion.
Embodiment 2
With gross weight is that the coconut oil of 59.3g and the palm kernel oil of 9.2g add in the retort
of 200ml, slowly adds diethanol amine 59.4g, does not stop to stir.Add 0.13g sodium
chloride.Send in the autoclave, reaction is 6 hours under 0.2MPa, 135 ℃ condition, and
constantly stirs.Use 0.01mol/L salt acidometric titration then, find that the unhindered amina
value is 128, promptly obtain miscella Ninol at high proportion.
Utilize said method can make miscella Ninol at high proportion, and reach its distinctive
beneficial effect.
Claims (6)
1. the production method of a kind of miscella at high proportion of the present invention Ninol
is characterized in that the described Ninol of producing is light yellow transparency liquid, has
very high viscosity.
2. the production method of a kind of Ninol of miscella at high proportion according to claim 1
comprises the steps:
Step 1 is with coconut oil, palm kernel oil with put into retort;
Step 2 is slowly poured diethanol amine and constantly stirring into, adds the sodium chloride of
gross mass about 1% simultaneously;
Step 3 in 130 ℃～180 ℃ reactions down of temperature, after treating to react completion in 5
～10 hours, is taken out liquid.Whether with the hydrochloric acid solution check of 0.01mol/l, it
is qualified to check.
3. the production method of a kind of Ninol of miscella at high proportion according to claim 2 is
characterized in that in the step 1, and in the step 1, the mass percent of said coconut oil is 30%
～40%, and the palm kernel oil mass percent is 5%-7%.
4. the production method of a kind of Ninol of miscella at high proportion according to claim 2 is
characterized in that in the step 2, and said diethanol amine addition is 45%～50% of a gross
mass.
5. the production method of a kind of Ninol of miscella at high proportion according to claim 2 is
characterized in that in the step 3, and described reaction should be reacted under 0.1～0.2Mpa.
6. the production method of a kind of Ninol of miscella at high proportion according to claim 2 is
characterized in that in the step 3, and described unhindered amina value both had been qualified
between 120～150.