Professional Documents
Culture Documents
Jee-Main Electro Chemistry
Jee-Main Electro Chemistry
(1) 0.816 amp (2) 1.632 amp (3) 2.448 amp (4) 3.264 amp
−1
2. The conductivity of 0.1 N NaOH solution is 0.022 S 𝑐𝑚 . To this solution equal volume of 0.1 N HCl solution is
added which results into decrease of conductivity of solution to 0.0055 S 𝑐𝑚 −1 . The equivalent conductivity of
NaCl solution in S 𝑐𝑚 2 𝑒𝑞𝑢𝑖𝑣 − is :
(1) increase in both the solution (2) decrease in both the solution
(3) increase in A and decrease in B (4) decrease in A and increase in B
4. What is the time (in sec.) required for depositing all the silver present in 125 mL of 1 M AgNO 3 solution by
passing a current of 241.25 A? (1 F = 96500 C).
(1) Na and Br2 (2) Na and O2 (3) H2, Br2 and NaOH (4) H2 and O2
0 −33
6. 𝐸𝐴𝑙3+/𝐴𝑙 = −1.66 𝑉 and KSP of 𝐴𝑙 (𝑂𝐻)3 = 1.0 × 10 . Reduction potential of the above couple at pH = 14 is:
(1) 0.66 volt (2) 0.80 volt (3) 1.08 volt (4) 0.94 volt
2+ 2+ +
8. The standard reduction potential of 𝐶𝑢 /𝐶𝑢 and 𝐶𝑢 /𝐶𝑢 are 0.337 and 0.153 respectively. The standard
electrode potential of 𝐶𝑢 + /𝐶𝑢 half-cell is
(1) +0.44 V, yes (2) – 0.44 V, No (3) +0.44 V, No (4) – 0.44 V, yes
10. 𝐸 for 𝐹2 + 2𝑒 ⇌ 2𝐹 is 2.8 V, 𝐸 for ½ 𝐹2 + 𝑒 − ⇌ 𝐹 − is
0 − − 0
T = 298 K
(1) nearly 10−19 𝑀 (2) 10−12 𝑀 (3) 10−8 𝑀 (4) nearly 10−16 𝑀
0 0
16. Consider the potentials 𝐸𝑀𝑔 2+ /𝑀𝑔 = −2.37 𝑉 and 𝐸𝐹𝑒 3+ /𝐹𝑒 = −0.04 𝑉.
(1) 𝐸𝐶0− |𝐶2 > 𝐸𝐵0− |𝐵2 > 𝐸𝐴0−|𝐴2 > 𝐸𝐷0 −|𝐷2 (2) 𝐸𝐶0−|𝐶2 < 𝐸𝐵0−|𝐵2 < 𝐸𝐴0−|𝐴2 < 𝐸𝐷0 −|𝐷2
(3) 𝐸𝐶0− |𝐶2 < 𝐸𝐵0− |𝐵2 > 𝐸𝐴0−|𝐴2 > 𝐸𝐷0 −|𝐷2 (4) 𝐸𝐶0−|𝐶2 > 𝐸𝐵0−|𝐵2 < 𝐸𝐴0−|𝐴2 < 𝐸𝐷0 −|𝐷2
24. 𝐸𝐻0 +/𝐻2 = 0.00 𝑉 ; 𝑡ℎ𝑒𝑛 𝐸𝐷0 +/𝐷2 at 250C will be
(1) 0.00 V (2) more than zero V (3) less than zero V (4) cannot be predicted
25. When an electric current is passed through acidified water, 112 ml of H 2 gas at NTP is collected at the cathode
in 965 seconds. The current passed in amperes is
Am AB Am AB Am Am AB
AD AB
AD AD AD
(1) C (2) C (3) C (4) C
−3
27. Number of electrons lost during electrolysis of 0.14 g of 𝑁 is (N0 = Avagadro number)
0.01
(1) 0.03 (2) 0.03 N0 (3) 0.015 N0 (4) 2𝑁
0
28. Aqueous solution of NaCl containing a small amount of MeOH (methyl orange) is electrolysed using Pt-
electrodes. The colour of the solution after some time will
0 0
𝐸𝐻𝑔 ++ /𝐻𝑔 = 0.85 𝑉 𝐸𝐻𝑔 ++ /𝐻𝑔 ++ = 0.92 𝑉
2 2
0 0
𝐸𝐴𝑔𝐶𝑙/𝐴𝑔 = 0.22 𝑉 𝐸𝑁𝑂 −
3 /𝑁𝑂
= 0.96 𝑉
+ 0
+ 2H + 2e , E = 1.30 V
OH O
At pH = 2, electrode potential is :
(1) 6.203 × 1023 (2) 1.64 × 10−24 (3) 6.24 × 1018 (4) 6.24 × 10−24
36. Electrolysis can be used to determine atomic masses. A current of 0.550 A deposits 0.55 g of a certain metal in
100 minutes. Calculate the atomic mass of the metal if n = 3 :
with increasing voltage, the sequence of deposition of metals on the cathode will be :
(1) Li, Cu, Ag, Au (2) Cu, Ag, Au (3) Au, Ag, Cu (4) Au, Ag, Cu, Li
39. Based on the following information arrange four metals A, B, C and D in order of decreasing ability to act as
reducing agents :
(I) Only A, B and C react with 1 M HCl to give H2(g)
(II) When C is added to solutions of the other metal ions, metallic B and D are formed
(III) Metal C does not reduce 𝐴𝑛+ .
(1) C > A > B > D (2) C > A > D > B (3) A > C > D > B (4) A > C > B > D
40. The standard electrode potential for the following reaction is + 1.33 V. What is the potentials at pH = 2.0 ?
𝐶𝑟2 𝑂72− (𝑎𝑞. 1 𝑀) + 14 𝐻 + (𝑎𝑞. ) + 6𝑒 − → 2𝐶𝑟 3+ (𝑎𝑞. 1 𝑀) + 7𝐻2 𝑂(ℓ)
(1) 𝐶1 = 𝐶2 (2) 𝐶1 > 𝐶2 (3) 𝐶2 > 𝐶1 (4) Both (1) and (3)
42. Resistance of a decimolar solution between two electrodes 0.02 meter apart and 0.0004 m 2 in area was found
to be 50 ohm. Specific conductance (k) is :
(1) 0.1 𝑆-𝑚 −1 (2) 1 𝑆-𝑚 −1 (3) 10 𝑆-𝑚 −1 (4) 4 × 10−4 𝑆-𝑚 −1
43. Equivalent conductivity of 𝐹𝑒2 (𝑆𝑂4 )3 is related to molar conductivity by the expression :
(1) 7.77 min (2) 9.44 min (3) 5.24 min (4) 11.39 min
48. Find the thickness of the electro deposited silver if the surface area over which deposition occurred was 100
cm2 and a current of 0.2 A flowed for 1 hr with the cathodic efficiency of 80%. Density of Ag = 10 g/cc
(Ag = 108).
(1) 6.4 × 10−5 𝑐𝑚 (2) 6.4 × 10−4 𝑐𝑚 (3) 6.4 × 10−7 𝑐𝑚 (4) 6.4 × 10−8 𝑐𝑚
49. In the given figure the electrolytic cell contains 1 L of an aqueous 1 M Copper (II) sulphate solution. If 0.4 mole
of electrons passed through of cell, the concentration of copper ion after passage of the charge will be
+
e e
Cu Cu
CuSO4
53. Match List –I with List-II and select the correct answer using the code given below the lists :
List – I List – II
(a) Concentration cell (p) O OH
+
+ 2H + 2e
O OH
(b) Electrode reversible with respect to anion (q) 𝑃𝑡|𝐶𝑒 +4 , 𝐶𝑒 +3
(c) Quin hydrone electrode (r) 𝐻𝑔|𝐻𝑔2 𝐶𝑙2 , 𝐾𝐶𝑙
(d) Redox-electrode (s) 𝑁𝑎(𝐻𝑔)|𝑁𝑎𝐶𝑙 |𝑁𝑎(𝐻𝑔)
ANSWER
1. 3 28. 2
2. 2 29. 1
3. 4 30. 1
4. 2 31. 4
5. 3 32. 4
6. 1 33. 3
7. 4 34. 3
8. 3 35. 3
9. 1 36. 3
10. 1 37. 3
11. 2 38. 3
12. 4 39. 3
13. 1 40. 4
14. 1 41. 4
15. 1 42. 3
16. 3 43. 2
17. 3 44. 4
18. 1 45. 4
19. 3 46. 1
20. 2 47. 2
21. 4 48. 1
22. 1 49. 2
23. 3 50. 3
24. 2 51. 1
25. 3 52. 2
26. 2 53. 1
27. 2 54. 1