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JEE – MAIN: ELECTRO CHEMISTRY 1

STRAIGHT OBJECTIVE TYPE


1. A very thin copper plate is electro-plated with gold using gold chloride in HCl. The current was passed for 20
min. and the increase in the weight of the plate was found to be 2g. [Au = 197]. The current passed was

(1) 0.816 amp (2) 1.632 amp (3) 2.448 amp (4) 3.264 amp
−1
2. The conductivity of 0.1 N NaOH solution is 0.022 S 𝑐𝑚 . To this solution equal volume of 0.1 N HCl solution is
added which results into decrease of conductivity of solution to 0.0055 S 𝑐𝑚 −1 . The equivalent conductivity of
NaCl solution in S 𝑐𝑚 2 𝑒𝑞𝑢𝑖𝑣 − is :

(1) 0.011 (2) 110 (3) 0.0055 (4) 55.0


3. Two aqueous solution A and B containing solute CuSO4 and NaBr respectively were electrolysed using platinum
electrodes. The pH of the resulting solutions will show a/an :

(1) increase in both the solution (2) decrease in both the solution
(3) increase in A and decrease in B (4) decrease in A and increase in B
4. What is the time (in sec.) required for depositing all the silver present in 125 mL of 1 M AgNO 3 solution by
passing a current of 241.25 A? (1 F = 96500 C).

(1) 10 (2) 50 (3) 1000 (4) 100


5. The products formed when an aqueous solution of NaBr is electrolysed in a cell having inert electrodes are :

(1) Na and Br2 (2) Na and O2 (3) H2, Br2 and NaOH (4) H2 and O2
0 −33
6. 𝐸𝐴𝑙3+/𝐴𝑙 = −1.66 𝑉 and KSP of 𝐴𝑙 (𝑂𝐻)3 = 1.0 × 10 . Reduction potential of the above couple at pH = 14 is:

(1) – 2.31 V (2) + 2.31 (3) – 1.01 V (4) + 1.01 V


7. The standard electrode potential for the reactions,
𝐴𝑔+ (𝑎𝑞) + 𝑒 − → 𝐴𝑔(𝑠)
𝑆𝑛2+ (𝑎𝑞) + 2𝑒 − → 𝑆𝑛(𝑠)
at 25 C are 0.80 volt and – 0.14 volt, respectively. The emf of the cell 𝑆𝑛|𝑆𝑛2+ (1 𝑀)‖𝐴𝑔+ (1 𝑀)|𝐴𝑔 is
0

(1) 0.66 volt (2) 0.80 volt (3) 1.08 volt (4) 0.94 volt
2+ 2+ +
8. The standard reduction potential of 𝐶𝑢 /𝐶𝑢 and 𝐶𝑢 /𝐶𝑢 are 0.337 and 0.153 respectively. The standard
electrode potential of 𝐶𝑢 + /𝐶𝑢 half-cell is

(1) 0.184 V (2) 0.827 V (3) 0.521 V (4) 0.490 V


0 0 0 +2
9. 𝐸𝐹𝑒 3+/𝐹𝑒 +2 = +0.77 𝑉 ; 𝐸𝐹𝑒 +3/𝐹𝑒 = 0.036 𝑉. What is 𝐸𝐹𝑒/𝐹𝑒 +2 and is 𝐹𝑒 stable to disproportionation in
aqueous solution under standard conditions

(1) +0.44 V, yes (2) – 0.44 V, No (3) +0.44 V, No (4) – 0.44 V, yes
10. 𝐸 for 𝐹2 + 2𝑒 ⇌ 2𝐹 is 2.8 V, 𝐸 for ½ 𝐹2 + 𝑒 − ⇌ 𝐹 − is
0 − − 0

(1) 2.8 V (2) 1.4 V (3) – 2.8 V (4) – 1.4 V


0 0 2+
11. Given that 𝐸𝐹𝑒 2+ /𝐹𝑒 = −0.44 𝑉 ; 𝐸𝐹𝑒 3+ /𝐹𝑒 2+ = 0.77 𝑉 if 𝐹𝑒 , 𝐹𝑒 3+ and Fe solid are kept together then

(1) 𝐹𝑒 3+ increases (2) 𝐹𝑒 3+ decreases


(3) 𝐹𝑒 2+ /𝐹𝑒 3+ remains unchanged (4) 𝐹𝑒 2+ decreases

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 2

12. Consider following sets :


Zn Ag Fe

CuSO 4 (I) CuSO 4 (II) CuSO 4 (III)


(blue)
Blue colour solution changes to colourless (or fades) in

(1) I, II, III (2) I, II (3) II, III (4) I, III


13. 0 ( )| +2 ‖ +2 |
The 𝐸𝐶𝑒𝑙𝑙 = 1.18 𝑉 for 𝑍𝑛 𝑠 𝑍𝑛 (1𝑀) 𝐶𝑢 (1𝑀) 𝐶𝑢(𝑠). The value of x if when excess granulated zinc is
2.303 𝑅𝑇
added to 1 M Cu+2 solution the [Cu+2]eq. Becomes 10−𝑥 M, is (𝑇 = 298 𝐾, = 0.059) 𝐹

(1) 40 (2) 30 (3) 20 (4) 10


++
14. 𝑍𝑛 (𝑎𝑞.) 𝐻𝐶𝑙(𝑎𝑞.) 𝐻2 (𝑔)
You are given the following cell at 298 K, 𝑍𝑛 | |‖ ‖ | 𝑃𝑡
0.01 𝑀 1.0 𝑙𝑖𝑡 1.0 𝑎𝑡𝑚
0
with 𝐸𝑐𝑒𝑙𝑙 = 0.701 and 𝐸𝑍𝑛 2+ /𝑍𝑛 = −0.76 𝑉. Which of the following amounts of NaOH (equivalent weight =

40) will just make the pH of cathodic compartment to be equal to 7.0 :

(1) 0.4 g (2) 4 g (3) 10 g (4) 2 g


15. What must be the concentration of Ag in an aqueous solution containing Cu2+ = 1.0 M so that both the metals
+
0 0
can be deposited on the cathode simultaneously. Given that 𝐸𝐶𝑢/𝐶𝑢 2+ = −0.34 𝑉 and 𝐸𝐴𝑔+ /𝐴𝑔 = 0.812 𝑉,

T = 298 K

(1) nearly 10−19 𝑀 (2) 10−12 𝑀 (3) 10−8 𝑀 (4) nearly 10−16 𝑀
0 0
16. Consider the potentials 𝐸𝑀𝑔 2+ /𝑀𝑔 = −2.37 𝑉 and 𝐸𝐹𝑒 3+ /𝐹𝑒 = −0.04 𝑉.

The best reducing agent would be

(1) 𝑀𝑔2+ (2) 𝐹𝑒 3+ (3) Mg (4) Fe


17. Use the standard potentials of the couples 𝐴𝑢 + /𝐴𝑢(+1.69 𝑉), 𝐴𝑢3+ /𝐴𝑢 (+1.40 𝑉), and 𝐹𝑒 3+ /
𝐹𝑒 2+ (+0.77 𝑉) to calculate the equilibrium constant for the reaction
2𝐹𝑒 2+ (𝑎𝑞) + 𝐴𝑢3+ (𝑎𝑞) ⟷ 2𝐹𝑒 3+ (𝑎𝑞) + 𝐴𝑢+ (𝑎𝑞)

(1) 4 × 1016 (2) 8 × 108 (3) 4 × 10−16 (4) 1 × 1014


18. Calculate molar conductivity of HCOOH at infinite dilution, if equivalent conductivity of
𝐻2 𝑆𝑂4 = 𝑥1 , 𝐴𝑙2 (𝑆𝑂4 )3 = 𝑥2 , (𝐻𝐶𝑂𝑂)3 𝐴𝑙 = 𝑥3

𝑥1−𝑥2+𝑥3 6𝑥1 −3𝑥2+6𝑥3


(1) 6𝑥1 − 3𝑥2 + 6𝑥3 (2) 6
(3) 𝑥1 − 𝑥2 + 𝑥3 (4) 6
19. Salts of A (atomic weight 7), B (atomic weight 27) and C (atomic weight 48) were electrolysed under identical
conditions using the same quantity of electricity. It was found that when 2.1 g of A was deposited, the weight
of B and C deposited were 2.7 g and 7.2 g. The valencies of A, B and C are respectively

(1) 3, 1 and 2 (2) 1, 3 and 2 (3) 3, 1 and 3 (4) 2, 3 and 2


0 0 0
20. Given that 𝐸𝐹𝑒 3+/𝐹𝑒 and 𝐸𝐹𝑒 2+/𝐹𝑒 are – 0.36 V and – 0.439 V, respectively. The value of 𝐸𝐹𝑒 3+ ,𝐹𝑒 2+ |𝑃𝑡 would be

(1) (−0.36 − 0.439) 𝑉 (2) (−0.36 + 0.439) 𝑉


(3) [3(−0.36) + 2(−0.439)]𝑉 (4) [3(−0.36) − 2(−0.439)]𝑉

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 3

21. −1.5𝑉 −1.0𝑉


The standard oxidation potentials for Mn3+ ion acid solution are 𝑀𝑛2+ → 𝑀𝑛3+ → 𝑀𝑛𝑂2 . Is the
reaction 2𝑀𝑛3+ + 2𝐻2 𝑂 → 𝑀𝑛2+ + 𝑀𝑛𝑂2 + 4𝐻 + spontaneous under conditions of unit activity? What is
the change in free energy?

(1) spontaneous, – 48250 J (2) spontaneous, + 48250 J


(3) no change in free energy (4) spontaneous, – 96500 J
0 2+
22. Fe is reacted with 1.0 M HCl. E for Fe/fe = + 0.34 volt. The correct observation(s) regarding this reaction
is/are:

(1) Fe will not oxidised to Fe2+


(2) Fe2+ will be reduced to Fe
(3) since e.m.f. is positive, the half cell reaction shall occur
(4) since e.m.f. is positive, the half cell reaction shall not occur
23. The following facts are available ;
2𝐴− + 𝐵2 → 2𝐵− + 𝐴2 ;
2𝐶 − + 𝐵2 → 𝑁𝑜 𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 ; 2𝐷− + 𝐴2 → 2𝐴− + 𝐷2
Which of the following statements is correct?

(1) 𝐸𝐶0− |𝐶2 > 𝐸𝐵0− |𝐵2 > 𝐸𝐴0−|𝐴2 > 𝐸𝐷0 −|𝐷2 (2) 𝐸𝐶0−|𝐶2 < 𝐸𝐵0−|𝐵2 < 𝐸𝐴0−|𝐴2 < 𝐸𝐷0 −|𝐷2
(3) 𝐸𝐶0− |𝐶2 < 𝐸𝐵0− |𝐵2 > 𝐸𝐴0−|𝐴2 > 𝐸𝐷0 −|𝐷2 (4) 𝐸𝐶0−|𝐶2 > 𝐸𝐵0−|𝐵2 < 𝐸𝐴0−|𝐴2 < 𝐸𝐷0 −|𝐷2
24. 𝐸𝐻0 +/𝐻2 = 0.00 𝑉 ; 𝑡ℎ𝑒𝑛 𝐸𝐷0 +/𝐷2 at 250C will be

(1) 0.00 V (2) more than zero V (3) less than zero V (4) cannot be predicted
25. When an electric current is passed through acidified water, 112 ml of H 2 gas at NTP is collected at the cathode
in 965 seconds. The current passed in amperes is

(1) 1 (2) 0.5 (3) 0.1 (4) 2


26. Which of the following graphs are correct for strong electrolyte AD and AB

Am AB Am AB Am Am AB
AD AB
AD AD AD
(1) C (2) C (3) C (4) C
−3
27. Number of electrons lost during electrolysis of 0.14 g of 𝑁 is (N0 = Avagadro number)

0.01
(1) 0.03 (2) 0.03 N0 (3) 0.015 N0 (4) 2𝑁
0
28. Aqueous solution of NaCl containing a small amount of MeOH (methyl orange) is electrolysed using Pt-
electrodes. The colour of the solution after some time will

(1) remains yellow (2) change from yellow to colourless


(3) change from yellow to red (4) remain red

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 4

29. The spontaneous redox reaction/s among the following is/are

(a) 2𝐹𝑒 3+ + 𝐹𝑒 → 3𝐹𝑒 ++


++ ++
(b) 𝐻𝑔2 → 𝐻𝑔 + 𝐻𝑔
(c) 3𝐴𝑔𝐶𝑙 + 𝑁𝑂 + 2𝐻2 𝑂 → 3𝐴𝑔 + 3𝐶𝑙 − + 𝑁𝑂3− + 4𝐻 +
Given that
0 0
𝐸𝐹𝑒 +++ /𝐹𝑒 ++ = 0.77 𝑉 𝐸𝐹𝑒 ++ /𝐹𝑒 = −0.44 𝑉

0 0
𝐸𝐻𝑔 ++ /𝐻𝑔 = 0.85 𝑉 𝐸𝐻𝑔 ++ /𝐻𝑔 ++ = 0.92 𝑉
2 2
0 0
𝐸𝐴𝑔𝐶𝑙/𝐴𝑔 = 0.22 𝑉 𝐸𝑁𝑂 −
3 /𝑁𝑂
= 0.96 𝑉

(1) a (2) a, b, c (3) a, b (4) a, c


30. When lead acid accumulator (battery) is discharged, following reaction takes place.
𝑃𝑏(𝑠) + 𝑃𝑏𝑂2 (𝑠) + 2𝐻2 𝑆𝑂4 (𝑎𝑞. ) → 2𝑃𝑏𝑆𝑂4 (𝑠) + 2𝐻2 𝑂
If 1.25 ampere current is drawn for a period of 1930 minutes, mass of H2SO4 consumed is:

(1) 196 g (2) 49 g (3) 98 g (4) 147 g


31. 0.196 gram of copper is deposited on the cathode by a current of 32 milliampere passing for 5 hours through a
solution of copper sulphate. Determine the current efficiency. [Atomic weight of Cu = 63.6]

(1) 98 % (2) 78 % (3) 69 % (4) 89 %


32. Using the standard electrode potential values given below, decide which of the statements, I, II, III and IV are
correct. Choose the right answer from (1) (2) (3) and (4)
𝐹𝑒 2+ + 2𝑒 − ⇌ 𝐹𝑒 ; 𝐸 0 = −0.44 𝑉
𝐶𝑢2+ + 2𝑒 − ⇌ 𝐶𝑢 ; 𝐸 0 = +0.34 𝑉
𝐴𝑔+ + 𝑒 − ⇌ 𝐴𝑔 ; 𝐸 0 = +0.80 𝑉
I. Copper can displace iron from FeSO4 solution.
II. Iron can displace copper from CuSO4 solution.
III. Silver can displace copper from CuSO4 solution.
IV. Iron can displace silver from AgNO3 solution.
(1) I and II (2) II and III (3) II and IV (4) I and IV
33. For the half cell
OH O

+ 0
+ 2H + 2e , E = 1.30 V

OH O
At pH = 2, electrode potential is :

(1) 1.36 V (2) 1.30 V (3) 1.42 V (4) 1.20 V


34. In the electrolysis of an aqueous potassium sulphate solution, the pH of the solution in the space near an
electrode increased. Which pole of the current source is the electrode connected to?

(1) The positive pole (2) Could be either pole


(3) The negative pole (4) Cannot be determined

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 5

35. How many electrons are there in one coulomb of electricity?

(1) 6.203 × 1023 (2) 1.64 × 10−24 (3) 6.24 × 1018 (4) 6.24 × 10−24
36. Electrolysis can be used to determine atomic masses. A current of 0.550 A deposits 0.55 g of a certain metal in
100 minutes. Calculate the atomic mass of the metal if n = 3 :

(1) 100 (2) 45.0 (3) 48.258 (4) 144.75


37. Calculate the current (in mA) required to deposit 0.195 g of platinum metal in 5.0 hours from a solution of
𝑃𝑡𝐶𝑙62− : (Atomic weight : pt = 195)

(1) 310 (2) 31 (3) 21.44 (4) 5.36


3+ + +
38. An aqueous solution containing 1 M each of 𝐴𝑢 , 𝐴𝑔 , 𝐿𝑖 is being electrolysed by using inert electrodes.
The value of standard potentials are:
0 0 0 0
𝐸𝐴𝑔 + /𝐴𝑔 = 0.80 𝑉, 𝐸𝐶𝑢+ /𝐶𝑢 = 0.34 𝑉 and 𝐸𝐴𝑢+3 /𝐴𝑢 = 1.50 𝑉, 𝐸𝐿𝑖 + /𝐿𝑖 = −3.03 𝑉

with increasing voltage, the sequence of deposition of metals on the cathode will be :

(1) Li, Cu, Ag, Au (2) Cu, Ag, Au (3) Au, Ag, Cu (4) Au, Ag, Cu, Li
39. Based on the following information arrange four metals A, B, C and D in order of decreasing ability to act as
reducing agents :
(I) Only A, B and C react with 1 M HCl to give H2(g)
(II) When C is added to solutions of the other metal ions, metallic B and D are formed
(III) Metal C does not reduce 𝐴𝑛+ .

(1) C > A > B > D (2) C > A > D > B (3) A > C > D > B (4) A > C > B > D
40. The standard electrode potential for the following reaction is + 1.33 V. What is the potentials at pH = 2.0 ?
𝐶𝑟2 𝑂72− (𝑎𝑞. 1 𝑀) + 14 𝐻 + (𝑎𝑞. ) + 6𝑒 − → 2𝐶𝑟 3+ (𝑎𝑞. 1 𝑀) + 7𝐻2 𝑂(ℓ)

(1) + 1.820 V (2) + 1.990 V (3) + 1.608 V (4) + 1.0542


41. 𝐴𝑔|𝐴𝑔𝐶𝑙 |𝐶𝑙 − (𝐶2 )‖𝐶𝑙 − (𝐶1 )|𝐴𝑔𝐶𝑙 |𝐴𝑔 for this cell ΔG is negative if :

(1) 𝐶1 = 𝐶2 (2) 𝐶1 > 𝐶2 (3) 𝐶2 > 𝐶1 (4) Both (1) and (3)
42. Resistance of a decimolar solution between two electrodes 0.02 meter apart and 0.0004 m 2 in area was found
to be 50 ohm. Specific conductance (k) is :

(1) 0.1 𝑆-𝑚 −1 (2) 1 𝑆-𝑚 −1 (3) 10 𝑆-𝑚 −1 (4) 4 × 10−4 𝑆-𝑚 −1
43. Equivalent conductivity of 𝐹𝑒2 (𝑆𝑂4 )3 is related to molar conductivity by the expression :

(1) Λ𝑒𝑞 = Λ𝑚 (2) Λ𝑒𝑞 = 𝜆𝑚 /3 (3) Λ𝑒𝑞 = 3Λ𝑚 (4) Λ𝑒𝑞 = Λ𝑚 /6


44. The limiting equivalent conductivity of NaCl, KCl and KBr are 126.5, 150.0 and 151.5 S 𝑐𝑚 2 𝑒𝑞−1 , respectively.
The limiting equivalent ionic conductance for 𝐵𝑟 − is 78 S 𝑐𝑚 2 𝑒𝑞−1 . The limiting equivalent ionic conductance
for Na+ ions would be :

(1) 128 (2) 125 (3) 49 (4) 50


45. The resistance of 0.1 N solution of formic acid is 200 ohm and cell constant is 2.0 𝑐𝑚 −1 . The equivalent
conductivity (in S 𝑐𝑚 2 𝑒𝑞−1 ) of 0.1 N formic acid is :

(1) 100 (2) 10 (3) 1 (4) none of these

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 6

46. Given that (in 𝑜ℎ𝑚−1 𝑐𝑚 2 𝑒𝑞−1) ; T = 298 K


𝜆∞
𝐸 𝑓𝑜𝑟 𝐵𝑎 (𝑂𝐻)2 = 228.8 𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 𝑐𝑜𝑛𝑑𝑢𝑐𝑡𝑎𝑛𝑐𝑒
𝜆∞
𝐸 𝑓𝑜𝑟 𝐵𝑎𝐶𝑙2 = 120.3| 𝑓𝑜𝑟 0.2 𝑁 𝑁𝐻4 𝑂𝐻 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝜆∞
𝐸 𝑓𝑜𝑟 𝑁𝐻 4 𝐶𝑙 = 129.8 𝑖𝑠 4.766 × 10−4 𝑜ℎ𝑚 −1 𝑐𝑚 −1
Then value of pH of the given solution of NH4OH will be nearly

(1) 9.2 (2) 11.3 (3) 12.1 (4) 7.9


47. Na-amalgam is prepared by electrolysis of NaCl solution using liquid Hg as cathode. How long should the
current of 10 amp. is passed to produce 10% Na – Hg on a cathode of 10 gm Hg. (atomic mass of Na = 23).

(1) 7.77 min (2) 9.44 min (3) 5.24 min (4) 11.39 min
48. Find the thickness of the electro deposited silver if the surface area over which deposition occurred was 100
cm2 and a current of 0.2 A flowed for 1 hr with the cathodic efficiency of 80%. Density of Ag = 10 g/cc
(Ag = 108).

(1) 6.4 × 10−5 𝑐𝑚 (2) 6.4 × 10−4 𝑐𝑚 (3) 6.4 × 10−7 𝑐𝑚 (4) 6.4 × 10−8 𝑐𝑚
49. In the given figure the electrolytic cell contains 1 L of an aqueous 1 M Copper (II) sulphate solution. If 0.4 mole
of electrons passed through of cell, the concentration of copper ion after passage of the charge will be
+
e e

Cu Cu
CuSO4

(1) 0.4 M (2) 0.8 M (3) 1.0 M (4) 1.2 M


50. ++ ( + 𝐶𝑢++
The equilibrium 𝐶𝑢 𝑎𝑞) + 𝐶𝑢(𝑠) ⇌ 2𝐶𝑢 established at 20 C corresponds to
0
[𝐶𝑢+]2
= 2.02 × 104+ . The
0 0
standard potential, 𝐸𝐶𝑢 ++ ,𝐶𝑢 = 0.33 volts at this temperature. What is the standard potential, 𝐸𝐶𝑢/𝐶𝑢+ ?

(1) – 0.457 V (2) – 0.125 V (3) – 0.66 V (4) – 0.250


51. What is cell entropy change of the following cell ?
𝑃𝑡(𝑠)|𝐻2 (𝑔)|𝐶𝐻3 𝐶𝑂𝑂𝐻, 𝐻𝐶𝑙 ‖𝐾𝐶𝑙(𝑎𝑞)|𝐻𝑔2 𝐶𝑙2 (𝑠)|𝐻𝑔
P = 1 atm 0.1 M 0.1 M
Emf of the cell is found to be 0.045 V at 298 K and temperature coefficient is 3.4 × 10−4 𝑉 𝐾 −1
Given 𝐾𝑎(𝐶𝐻3 𝐶𝑂𝑂𝐻) = 10−5 𝑀

(1) 60 (2) 65.2 (3) 69.2 (4) 63.5


∞ 0
52. Calculate the value of Λ𝑚 for SrCl2 in water at 25 C from the following data :
Conc. (mol/lt) 0.25 1
Λ𝑚 (Ω−1 𝑐𝑚 2 𝑚𝑜𝑙 −1 ) 260 250

(1) 270 (2) 260 (3) 250 (4) 255

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 7

53. Match List –I with List-II and select the correct answer using the code given below the lists :
List – I List – II
(a) Concentration cell (p) O OH

+
+ 2H + 2e

O OH
(b) Electrode reversible with respect to anion (q) 𝑃𝑡|𝐶𝑒 +4 , 𝐶𝑒 +3
(c) Quin hydrone electrode (r) 𝐻𝑔|𝐻𝑔2 𝐶𝑙2 , 𝐾𝐶𝑙
(d) Redox-electrode (s) 𝑁𝑎(𝐻𝑔)|𝑁𝑎𝐶𝑙 |𝑁𝑎(𝐻𝑔)

(a) (b) (c) (d) (a) (b) (c) (d)


1. s r p q 2. p q r s
3. q r s p 4. s p q r
54. Match List –I with List-II and select the correct answer using the code given below the lists :
List – I List – II
(a) 𝑍𝑛|𝑍𝑛2+ (0.01 𝑀)‖𝑍𝑛2+ (0.1 𝑀)|𝑍𝑛 (p) Primary cell
(b) 1 Coulomb (q) Secondary cell
(c) Dry cell (r) 6.24 × 1018 electrons
(d) Lead storage cell (s) Concentration cell

(a) (b) (c) (d) (a) (b) (c) (d)


1. s r p q 2. p q r s
3. q r s p 4. s p q r

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367


JEE – MAIN: ELECTRO CHEMISTRY 8

ANSWER
1. 3 28. 2
2. 2 29. 1
3. 4 30. 1
4. 2 31. 4
5. 3 32. 4
6. 1 33. 3
7. 4 34. 3
8. 3 35. 3
9. 1 36. 3
10. 1 37. 3
11. 2 38. 3
12. 4 39. 3
13. 1 40. 4
14. 1 41. 4
15. 1 42. 3
16. 3 43. 2
17. 3 44. 4
18. 1 45. 4
19. 3 46. 1
20. 2 47. 2
21. 4 48. 1
22. 1 49. 2
23. 3 50. 3
24. 2 51. 1
25. 3 52. 2
26. 2 53. 1
27. 2 54. 1

S. Bagchi Classes (School of Chemistry) | Salt Lake | Gariahat | 9830705367

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