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Yakeen NEET 2.0 (Legend)

Chemical Kinetics DPP-03

1. The graph of t1/2 versus initial concentration ‘a’ is 6. A first order reaction completes 60% in 20 minutes.
for: The time required for the completion of 90% of the
reaction is approx.
(1) 30 minutes
(2) 40 minutes
(3) 50 minutes
(1) First order (4) 60 minutes
(2) Second order
(3) Zero order 7. A first order reaction is 50% completed in
(4) Can’t predict 1.26 × 1014 s. How much time would it take for
100% completion?
2. A first order reaction has a specific reaction rate of (1) 1.26 × 1015 s
10–2 sec–1. How much time will it take for 20 g of the (2) 2.52 × 1014 s
reactant to reduce to 5 g? (3) 2.52 × 1028 s
(1) 138.6 sec (4) Infinite
(2) 346.5 sec
(3) 693.0 sec 8. For a first-order reaction, the half-life period is
(4) 238.6 sec independent of:
(1) First power of final concentration
3. If initial concentration of the reactants is doubled, (2) Cube root of initial concentration
the time for half reaction is also doubled, the order (3) Initial concentration
of the reaction is: (4) Square root of final concentration
(1) Zero (2) One
(3) Two (4) Three 9. The rate constant for a first order reaction is
4.606 × 10–3 s–1. The time required to reduce 2.0 g of
4. Consider the following in respect of zero order the reactant to 0.2 g is:
reaction. (1) 100 s (2) 200 s
I. t1/2 is directly proportional to the initial (3) 500 s (4) 1000 s
concentration.
II. Time taken for the completion of the reaction is 10. A reaction is found to have the rate constant x sec–1
twice its t1/2 by what factor the rate is increased, if initial conc. of
III. Concentration of the reactant decreases linearly A is tripled.
with time (1) 3
Which of the statements given above are correct? (2) 9
(1) I & II only (2) I & III only (3) x
(3) II & III only (4) I, II & III (4) Remains same

5. 99% of a first order reaction, was completed in 32 11. The rate constant for a first order reaction whose
minutes. When will 99.9% of the reaction complete? half-life is 480 sec:
(1) 50 minutes (1) 1.44 × 10–3 sec–1
(2) 46 minutes (2) 1.44 sec–1
(3) 49 minutes (3) 0.72 × 10–3 sec–1
(4) 48 minutes (4) 2.88 × 10–3 sec–1
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12. Which of the following curves represents a 1st order 13. Which of the following represents the expression for
reaction? 3
th life of first order reaction?
4
(1) k 4
(1) log
2.303 3
2.303 3
(2) log
k 4
2.303
(3) log 4
k
(2) 2.303
(4) log 3
k

14. 75% of a first order reaction was found to complete

in 32 min. When will 50% of the same reaction
complete?
(3) (1) 24 min
(2) 16 min
(3) 8 min
(4) 4 min
(4) 1 and 3 both
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (1) 8. (3)
2. (1) 9. (3)
3. (1) 10. (1)
4. (4) 11. (1)
5. (4) 12. (4)
6. (3) 13. (3)
7. (4) 14. (2)

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