Neutron NEET 2024 Chemistry Sankalp

Solutions
DPP - 05
Abnormal Molar Mass
Q 1. Which of the following salt has the same value of Van't Hoff factor as that of K4[Fe(CN)6]
(a) Al2(SO4)3
(b) NaCl
(c) Na2SO4
(d) Al(NO3)3

Q 2. 0.5 molal aqueous solution of a weak acid (HX) is 20% ionized. If 𝐾𝑓 for water is 1.86 K kg
mol-1, the lowering in freezing point of the solution is
(a) −1.12 K
(b) 0.56 K
(c) 1.12 K
(d) −0.56 K

Q 3. The freezing point depression constant for water is −1.86° C m-1. If 5.00 g Na2SO4 is
dissolved in 45.0 g H2O, the freezing point is changed by −3.82°C. Calculate the van't Hoff
factor for Na2SO4
(a) 0.381
(b) 2.05
(c) 2.63
(d) 3.11

Q 4. The correct relationship between the boiling points of very dilute solutions of AlCl 3(t1) and
CaCl2(t2), having the same molar concentration is
(a) t1 = t2
(b) t1 > t2
(c) t2 > t1
(d) t2 ≥ t1

Q 5. Van't Hoff factor of Ca(NO3)2 is

(a) 1
(b) 2
(c) 3
(d) 4

Q 6. Four solutions of K2SO4 with the following concentration 0.1 m, 0.01 m, 0.001 m and 0.0001
m are available. The maximum value of van't Hoff factor, i, corresponds to
(a) 0.0001 m solution
(b) 0.001 m solution
(c) 0.01 m solution
(d) 0.1 m solution

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Neutron NEET 2024 Chemistry Sankalp
Solutions
DPP - 05
Q 7. If 𝑎 is the degree of dissociation of Na2SO4, the Vant Hoff's factor (𝑖) used for calculating the
molecular mass is
(a) 1 + 𝑎
(b) 1 − 𝑎
(c) 1 + 2𝑎
(d) 1 − 2𝑎

Q8. The Van't Hoff factor calculated from association data is always than calculated from
dissociation data
(a) Less
(b) More
(c) Same
(d) More or less

Q 9. Which one of the following aqueous solutions will exhibit the highest boiling point?
(a) 0.015 M urea
(b) 0.01 M KNO3
(c) 0.01 M Na2SO4
(d) 0.015 M glucose

Q 10. Which of the following aqueous solution has a minimum freezing point?
(a) 0.01 m NaCl
(b) 0.005 m C2H5OH
(c) 0.005 m MgI2
(d) 0.005 m MgSO4

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Neutron NEET 2024 Chemistry Sankalp
Solutions
DPP - 05
Answer Key

S 1. Ans. (a)

S 2. Ans. (c)

S 3. Ans. (c)

S 4. Ans. (b)

S 5. Ans. (c)

S 6. Ans. (a)

S 7. Ans. (c)

S 8. Ans. (a)

S 9. Ans. (c)

S 10. Ans. (a)

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