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Specimen 2
Specimen 2
Specimen 2
Cambridge IGCSE™
*4926358439*
CHEMISTRY 0620/32
Paper 3 Theory (Core) February/March 2023
1 hour 15 minutes
INSTRUCTIONS
● Answer all questions.
● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
● Write your name, centre number and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid.
● Do not write on any bar codes.
● You may use a calculator.
● You should show all your working and use appropriate units.
INFORMATION
● The total mark for this paper is 80.
● The number of marks for each question or part question is shown in brackets [ ].
● The Periodic Table is printed in the question paper.
IB23 03_0620_32/2RP
© UCLES 2023 [Turn over
PMT
Br2
CH4
C 2H 4
Cl –
CO2
Cr3+
Cu2+
H2
K+
N2
N3–
O2
SO42–
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
(d) an ion which forms a green precipitate when a few drops of aqueous sodium hydroxide are
added to it
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
[Total: 6]
Draw a diagram to show the filtration apparatus used to separate the soil from the solution
obtained by shaking the soil with distilled water.
[3]
(b) Table 2.1 shows the masses of some of the ions in 1000 cm3 of the solution obtained by filtering
a sample of soil with distilled water.
Table 2.1
(i) Name the negative ion that has the lowest concentration.
....................................................................................................................................... [1]
....................................................................................................................................... [1]
(iii) Calculate the mass of phosphate ions in 200 cm3 of the solution.
......
Na
Fig. 2.1
[2]
Choose from the list the gas which is essential for aquatic life.
sewage ......................................................................................................................................
nitrates .......................................................................................................................................
[2]
[Total: 11]
H N H
Fig. 3.1
[2]
....................................................................................................................................... [1]
....................................................................................................................................... [1]
....................................................................................................................................................
.............................................................................................................................................. [1]
[Total: 5]
Table 4.1
Give two reasons for your answer using only the information in Table 4.1.
reason 1 .....................................................................................................................................
reason 2 .....................................................................................................................................
[3]
magnesium chloride
potassium chloride
silver chloride
sodium chloride
[1]
Mg + Cl 2 → MgCl 2
Fig. 4.1 shows an incomplete reaction pathway diagram for this reaction.
energy
progress of reaction
Fig. 4.1
(ii) Explain how Fig. 4.1 shows that the reaction is exothermic.
.............................................................................................................................................
....................................................................................................................................... [1]
(d) Table 4.2 shows the reactions of four different metals with steam.
Table 4.2
[2]
Table 4.3
relative
atom number of atoms
atomic mass
fluorine 12 19 12 × 19 = 228
nickel 59
phosphorus 31
[Total: 10]
1 .................................................................................................................................................
2 .................................................................................................................................................
[2]
(i) Name the products formed at the positive and negative electrodes.
....................................................................................................................................... [1]
(c) Deduce the number of protons and neutrons in the iodide ion shown.
53I
127 –
(ii) Choose from the list the name of this type of reaction.
(iii) State the colour of chlorine gas at room temperature and pressure.
....................................................................................................................................... [1]
[Total: 11]
10
6 (a) Fig. 6.1 shows the displayed formula of a molecule of crotyl alcohol.
H H H
H C C C C O H
H H H
Fig. 6.1
(i) On Fig. 6.1 draw a circle around the alcohol functional group. [1]
(ii) Describe the feature of crotyl alcohol that shows it is an unsaturated compound.
....................................................................................................................................... [1]
....................................................................................................................................... [1]
Suggest how fractional distillation can be used to separate a mixture of crotyl alcohol and
water.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
Describe two conditions for the manufacture of ethanol by the fermentation of aqueous glucose.
1 .................................................................................................................................................
2 .................................................................................................................................................
[2]
Choose from the list the general formula for the homologous series to which ethene belongs.
11
....................................................................................................................................... [1]
[1]
............................ . [1]
(iv) Complete the symbol equation for the complete combustion of methane.
[Total: 13]
12
....................................................................................................................................... [1]
Describe the extraction of iron from iron ore in the blast furnace.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
[4]
arrangement .......................................................................................................................
.............................................................................................................................................
motion .................................................................................................................................
.............................................................................................................................................
[2]
13
(b) The equation for the reaction of iron with steam is shown.
.............................................................................................................................................. [1]
.............................................................................................................................................
....................................................................................................................................... [1]
(d) Crystals of iron(II) chloride can be prepared by adding excess iron to dilute hydrochloric acid.
(i) Suggest how the unreacted iron is removed from the reaction mixture.
....................................................................................................................................... [1]
(ii) Describe how dry crystals of iron(II) chloride are made from a dilute solution of
iron(II) chloride.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
[Total: 14]
14
8 A student investigates the reaction of iron powder with dilute hydrochloric acid at 20 °C. The
hydrochloric acid is in excess.
(a) Fig. 8.1 shows the volume of hydrogen gas released as the reaction proceeds.
60
50
40
volume of
hydrogen gas
/ cm3
30
20
10
0
0 1 2 3 4 5 6 7
time / min
Fig. 8.1
(ii) The student repeats the experiment using dilute hydrochloric acid of a higher concentration.
Draw a line on the grid in Fig. 8.1 to predict how the volume of hydrogen gas changes
when dilute hydrochloric acid of a higher concentration is used. [2]
15
(b) (i) The student repeats the experiment with large pieces of iron.
Describe how the rate of reaction differs when large pieces of iron are used.
....................................................................................................................................... [1]
(ii) The student repeats the experiment with iron powder at a temperature of 15 °C.
....................................................................................................................................... [1]
[2]
....................................................................................................................................... [1]
(iii) Choose from the list a possible pH value of aqueous sodium hydroxide.
pH 2 pH 4 pH 7 pH 13 [1]
....................................................................................................................................... [1]
[Total: 10]
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.
Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.
© UCLES 2023
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
16
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
0620/32/F/M/23
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium nihonium flerovium moscovium livermorium tennessine oganesson
– – – – – – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT