MATERIAL SAFETY DATA SHEET Revisi : 01/12/2020

Expose 55 SC

1. IDENTIFICATION OF THE SUBSTANCE AND COMPANY

Trade Name Expose 55 SC

Company Name PT. Kristalindo Karunia International
Company Address Jl. Kelapa Puan Raya Blok CA 24 No 15, Gading Serpong, Pakulonan
Barat Kelapa Dua
Telephone / Fax Number 021-22052845
Contact address in case of Jl. Kelapa Puan Raya Blok CA 24 No 15, Gading Serpong, Pakulonan
Emergency Barat Kelapa Dua
Emergency Telephone Number 021-22052845

2. COMPOSITION/INFORMATION OF INGREDIENT
Chemical Name (IUPAC (±)-5-amino-1-(2,6-dichloro- α , α , α -trifluoro-p-tolyl)-4-trifluoromethyl
sulfinyl pyrazole-3-carbonitrile
CAS Number 120068-37-3
Common Name Fipronil
Concentration 5,5%
Chemical Family Phenylpyrazole
Formula C12 H4 Cl2 F6 N4 OS
Molecular Mass 437,15
Use Insecticide

3. HAZARD IDENTIFICATION
Harmful if swallowed. May cause allergic skin reactions and organ damage through prolonged or repeated exposure.
Very toxic to aquatic life with lasting effects

4. FIRST AID MEASURES

Special instructions
Inhalation Move person to fresh air. If breathing is difficult, oxygen may be
administered under nursing or medical supervision.
Contact with skin Remove all contaminated clothing; wash off exposed skin with plenty
of soap and water. Seek medical advice if there is more than trivial
exposure.
Splashes in eyes Flush immediately with plenty of water for at least 15 minutes. Get
medical attention if irritation persists.
Ingestion Wash out mouth at least 200 - 300 ml. Get medical attention.
Information for doctor or other Berikan pertolongan secara simptomatik.

5. FIRE - FIGHTING MEASURES

Suitable extinguishing media
Unsuitable extinguishing media
Special protective equipment for
fire-fighting
Other instructions
Water spray, CO2, foam, dry powder
Carbon Monoxide, Hydrogen Chloride, Hydrogen Fluoride, Carbon
Dioxide, Nitrogen Oxides, Sulfur Oxides, Organochlorine Compounds.
Substances / functional groups from these substances can be released
in case of fire.
Wear a self contained respiratory apparatus. Wear protective
clothing.
Cool fire-exposed containers with water fog and avoid environmental
contamination with extinguishing water.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Environmental precautions
Methods for cleaning up
7. HANDLING AND STORAGE
Handling
Special protection measure
Storage
Special storage requirements
Storage conditions
Shelf life
Recommended packaging material
Supplier packaging
Packaging material to be avoided
Incompatible substances
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Limit values for workplace air
STEL/TWA/IDLH
Personal protective equipment
Respiratory protection
Hand protection
Eye protection
Skin protection
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Color
Smell
pH
Boiling point/boiling range
Melting point/melting range
Flash point
Flammability (solid/gas)
Auto flammability (ignition point)
Explosion hazard
Oxidizing properties
Relative density
Vapor pressure
Volatility
Solubility in water
Solubility inorganic solvents
Do not touch spilled material and avoid contact with skin. Do not
breathe flying dust
The material is toxic to fish and wildlife. Avoid soil and water
contamination.
Absorb using an absorbent material such as vermiculite, sand,
collected in a closed place to be destroyed. Clean the floor with water
and detergent until clean.
Avoid direct contact with ingredients. Avoid inhalation of dust / vapors
when working with this material. When using this product, do not eat,
drink or smoke. Hands and / or face should be cleaned after use
Separate from food and animal feed. Keep in tightly closed packages
and in a well-ventilated room and keep away from humid and hot
places.
Keep in dry and well ventilated place at low temperature.
At least 2 years if properly packed and stored.
Carton, packed with polyethylene bag.
Carton, packed with polyethylene bag.
No special material.
Sensitive to alkalis. Unstable in methyl and ethyl alcohol solution.
None established
Wear mask with filter (MSHA/NIOSH no TC-21C0 or NIOSH with a
respirator N, R, P or HE)
Wear suitable protective gloves.
Wear safety glasses or gaggles.
Wear suitable protective clothing (long sleeves and trousers and
shoes)
Suspension
White
Characteristics
6-8
± 100oC
0oC
Tidak mudah terbakar
-
Not auto flammable
Non explosive
-
1.06
-
± 800 - 1,200
soluble
-
10. STABILITY AND REACTIVITY
Hazardous reactions No hazardous reactions if stored and handled as recommended
Sensitivity to jolting None
Condition to avoid Avoid spark generation and flames
Material to avoid Bases, Strong alkali and acids
Hazardous decomposition product No hazardous decomposition products if stored and handled as
recommended

11. TOXICOLOGICAL INFORMATION

Acute toxicity
LD50 oral (rat) 1.999 mg/kg
LD50 dermal (rat) >2.000mg/kg
LC50 inhalation (rat, 4 h) > 1,7 mg/l
Irritancy
Eye irritancy slight irritant
Skin irritancy slight irritant
Sensitization
Skin sensitization weak sensitizer
Effects on humans -

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL HAZARDS
This pesticide is toxic to birds, fish and aquatic invertebrates. Do not apply directly to water or to areas where surface
waters present or to intertidal areas below the mean high water mark. Runoff from treated areas may be hazardous to
aquatic organisms in neighboring disposal of wastes. Do not contaminate water when disposing of equipment wash
waters

ECOTOXICOLOGICAL INFORMATION (data on Fipronil)

Bluegill sunfish (Lepomis macrochirus LC50 (96 h) – 0.083 mg/L Rainbow trout (Onchorhynchus mykiss) LC50 (96 h)
– 0.246 mg/L Sheephead minnow LC50 (96 h) – 0.13 mg/L Water flea (Daphnia magna) NOEL – 9.8 μg/L; LOEL - 20
μg/L Bobwhite quail LD50 - > 11.3 mg/kg

ENVIRONMENTAL FATE, PERSISTENCE AND DEGRADABILITY, MOBILITY : Not readily biodegradable (by OECD
criteria)

13. DISPOSAL CONSIDERATIONS

Product Wastes resulting from the use of this product may be disposed at an
approved waste disposal facility
Empty packing Disposal or incineration methods based on state or local codes of
practice and laws

14. TRANSPORT INFORMATION

UN NUMBER: 3082
UN proper shipping name: Pesticides, liquid, Toxic, N.O.S.
Transport hazard class: 9
Environmental hazards: Yes
Packaging group: III
Special precautions for user: /

15. REGULATORY INFORMATION

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event shall we be liable for any claims, losses, or
damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages,
however arising, even if we have been advised of the possibility of such damages.
16. OTHER INFORMATION
References : Not available.