Semester Genap 2023/2024 Prodi Sarjana Teknik Kimia Universitas Riau Papermaking Drying Types of water in web • Free water • Water held in pores, in between fibres, and in lumen • Held in place by capillary forces • 35-70% consistency is free water • Imbibed water • Water held in the swollen cell walls • Makes up the “fibre saturation point” • Web consistencies between 70% and 90% are imbibed • Chemically bound water • Water bound to cellulose. Zero vapour pressure Fibre Bonding • Water removal induces strong surface tension forces • Leads to • hydrogen bonding • Fibre straightening • Lumen collapse Fibre bonding • As water is removed strength increases due to improved bonding Drying process • Heat transfer to web • Mass transfer of vapour from the web Drying process • Stage 1 • Warm up stage • Stage 2 • Constant drying rate stage • Heat and mass transfer are not rate controlling steps • Stage 3 • Falling rate stage • Not sufficient water to completely fill the web • Water in contact with roll evaporates and diffuses outward … complex heat and mass transfer • Corresponds with removal of free to imbibed water Drying process Dryer configuration Dryer configuration • Reverse section to reduce 2-sidedness of paper Other types of dryers Yankee dryer: • 8mm diameter roll • jets of hot air blow on paper • used for tissue. Other types of dryers Flakt dryer • Hot air blown as paper passes through a number of tiers • Unconstrained drying • Lower temperature drying: inhibits darkening, embrittlement of paper Heat transfer Heat transfer • Condensate shape inside cylinder changes significantly as a function of amount and cylinder speed • Some estimates of the thickness have been made Heat transfer Heat transfer • Correlations for mass transfer coefficient Heat transfer calculations • Tappi TIS 0404-07 • Assumes constant drying rate • Gets drying rate from experimental measurements See you next lecture