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Practice Numerical - Mole fraction, Molality &Molarity

1 What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL?
(a) 4 mol L–1
(b) 20 mol L–1
(c) 0.2 mol L–1
(d) 2 mol L–1
2 A solution of oxalic acid, (COOH)2.2H2O is prepared by dissolving 0.63g of the acid in 250
cm3 of the solution. Calculate the molarity of the solution.
3 A solution of glucose is labeled as 10 % w/w. What would be the molality and mole fraction
of each component in the solution? If the density of the solution is 1.2 g/ml, then what shall be the molarity of
the solution?
4 Antifreeze is prepared from 222.6 g of ethylene glycol C2H4(OH)2 and 200 g of water. Calculate
the molality and molarity of the solution. Given that the density of the solution is 1.072 g/ml.
5 Calculate the molarity of a solution containing 9.8 g of H2SO4 in 250 cm3 of the solution.
(Atomic masses: S=32, O=16, H=1).
6 Calculate the molarity of 9.8%(w/w) solution of H2SO4 if the density of the solution
is 1.02 g mL−1. [Molar mass of H2SO4=98 gmol−1].
7 Calculate the molality and mole fraction of the solute in an aqueous solution containing 6 g of
urea per 500 g of water (Mol. mass of urea = 60).
8 Calculate the molality and mole fraction of the solute in aqueous solution containing 3.0g of
urea per 250g of water?
9 Which aqueous solution has higher concentration 1M or 1m solution of the same solute?
10 Which out of molality or molality does not get effected by temperature and why?
11 Calculate the mass per cent of different elements present in sodium sulphate (Na2SO4 ).
12 Calculate the concentration of nitric acid in moles per litre in a sample which has a density,
1.41 g mL–1 and the mass per cent of nitric acid in it being 69%.
13 What will be the concentration of sugar C12H22O11 in mol/litre if 20 g are dissolved in enough
water to make a final volume upto 2 litres.
14 Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of 0.375 molar
aqueous solution. Molar mass of sodium acetate is 82.0245 g mol–1.
15 Calculate the molality of sulphuric acid solution in which the mole fraction of water is 0.85.

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