Mixing of the same solutions with different molar concentrations.

MOLARITY AND MOLALITY PRACTICE PROBLEMS

1.

(1.33 M, 19.45 g, 0.5 L)

2.

(a-0.00176 M, b- 0.668M)

3.

(Fe+3 = 0.7 M, Cr2O7-2 = 0.105 M)

4.
 (5.4 x 1024 ions)

5.

6.

7.

[PO4-3] < [NO3-] < [Na+]

8.

9.
 A

10.

11- The density of a 70 % by weight HClO4 solution is given as 1.66 g/mL. What is the
molarity of this concentrated perchloric acid? HClO4 has a molar mass of 100.46 g/mol.

(11.568 M)

12- To prepare a 100 mL solution of 8.00 M HNO 3, how many milliliters of concentrated
HNO3 should be taken if it has a 70 % w/w concentration and a density of 1.42 g/mL? The
molar mass of HNO3 is 63.0 g/mol.

(50.7 mL)
13- When mixing 100 mL of 0.1 M CaCl 2 solution with 50 mL of 0.2 M CaCl 2 solution and
diluting it to a total volume of 250 mL with water, what are the concentrations of CaCl 2, Ca+2,
and Cl- ions in the final solution?

(0.08 M CaCl2, 0.08 M Ca+2, 0.16 M Cl-)

14- What is the molality of a 1 M HCl solution with a density 1.0585 g/mL. (H: 1g/mol, Cl:
35.5 g/mol).

(0.9785 m)

15. Calculate the molality of 25.0 grams of KBr dissolved in 750.0 mL of pure water. ( K:39
g/mol, Br: 80 g/mol).

(0.28 m)

16. A solution of H2SO4 with a molal concentration of 8.010 m has a density of 1.354 g/mL.
What is the molar concentration of this solution?

(6.074 M)
17. What is the molality of a 3.75 M H2SO4 solution with a density of 1.230 g/mL?

(4.34 m)

18. What is the molality of a solution consisting of 1.34 mL of carbon tetrachloride (CCl 4,
density= 1.59 g/mL) in 65.0 mL of methylene chloride (CH2Cl2, density = 1.33 g/mL)?

(0.16 m)

19. An aqueous solution of urea containing 18g urea in 1500 cm 3 of the solution has a density
equal to 1.052. If the molecular weight of urea is 60, find the molality of the solution.

(0.192 m)
20. 560 g of 2 m aqueous solution of urea is mixed with 2480 g of 4 m aqueous solution of urea.
Find the molality of the resulting solution.

(3.6 m)

21. A solution is prepared by dissolving 10.2 g of glucose, C6H12O6, in 405g of water.

The final volume of the solution is 414mL. Find the concentration of the solution in units of
molality and the density of the solution.

(0.14 m, 1.003 g/mL)

22.

23.

24.

25.
26. An aqueous solution is prepared by diluting 3.30 mL acetone (d = 0.789 g/mL) with water
to a final volume of 75.0 mL. The density of the solution is 0.993 g/mL. What is the molarity,
molality of this solution? (M =58.0794 g/mol).

(M= 0.624 M, m= 0.598 m)

27. A 0.391 m solution of the solute hexane dissolved in the solvent benzene is available.
Calculate the mass (g) of the solution that must be taken to obtain 247 g of hexane (C6H14).

(7592.5 g)

28. Calculate the mass of the solute C6H6 and the mass of the solvent tetrahydrofuran that
should be added to prepare 1.63 kg of a solution that is 1.42 m.

(162.53 g hexane, 1467.47 g tetrahydrofuran)

29. Calculate the molality (m) of a 7.55 kg sample of a solution of the solute CH 2Cl2 (molar
mass = 84.93 g/mol) dissolved in the solvent acetone (CH 3COH3C) if the sample contains 929
g of methylene chloride.

(m= 1.652 m)

30. Determine concentration of a solution that contains 825 mg of Na2HPO4 dissolved in

450.0 mL of water in (a) molarity, (b) molality, (c) mass %, and (d) ppm. Assume the density
of the solution is the same as water (1.00 g/mL). Assume no volume change upon the addition
of the solute.
31. You are given 450.0 g of a 0.7500 molal solution of acetone dissolved in water. How
many grams of acetone are in this amount of solution?

(18.78 g)