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MATERIAL SAFETY DATA SHEET

According to Global Harmonized System (GHS)


Product Name : Kiwadye Red SX-13 Issue Date : July 31, 2018
Product Use Description : Textile Indusrty Revision Date : July 17, 2019
1. COMPANY IDENTIFICATION
Name : Thai Kiwa Chemical Co., Ltd (Manufacture)
Address : 178 Soi Chan 16, Thungwatdon, Sathon, Bangkok 10120 Thailand.
Telphone : (662) 676-1115 e-mail : thaikiwa@hotmail.com

Name : Chemsol Tech Co.,Ltd. (Overseas Agency)


Address : 1/21 Moo 3, Tambon Thakharm, Amphur Bangpakong
Chachongsao 24130 Thailand.
Telphone : 66) 33 020 441 e-mail : chemsolbang@gmail.com

2. MAIN COMPOSITION
INGREDIENTS CAS NO. (%)
Pigment Red : 68016-06-7 7-8
Pigment Red 6041-97-7 45-53
Surfactant : 99734-09-6 7-9
1,2-Benzisothizoline-3-one : 2634-33-5 0.05-0.07
Water : 7732-18-5 x

3. CLASSIFICATION OF HAZARDOUS
3.1 Hazard Symbol: Xi, Irritant
3.2Risk and Safety Phrases
R22 – Harmful if
swallowed
R36/R38 – Irritating to eyes/Irritating to
skin R43 – May cause sensitization by skin
contact H316 – Causes mild skin irritation
H320 – Causes eye irritation
Comply to Oekotex, REACH and EN 71.

4. FIRST AID PROCEDURES


Eyes : Wash the eyes with running water for at least
15 minutes and seek for medical attention.
Skin : Wash material off skin with plenty of water and soap.
Inhalation : Rinse the mouth well and seek for medical attention.
Ingestion : Induce vomiting and seek for medical attention.

5. PHYSICAL AND CHEMICAL CHARACTERISTICS


Boiling Point (approx.) : >100˚C
Vapor Pressure (mm Hg) : 18 (at 68 ̊ F)
Vapor Density (Air = 1) : 0.63
Specific Gravity (H₂O = 1) : 1.1~1.2 g/cm3
Solid Content : 44~50%
pH Value : 6~8
Viscosity : < 400 cPs
Pigment Content : 22 ± 1 %
Melting Point : Not determined.
Evaporation Rate : Same as water.
Solubility in Water : Not soluble in water. But miscible with water.
Appearance and Odor : Red colored pigment liquid / No odor.
6. FIRE AND EXPLOSION HAZARD DATA
Flash Point : None.
Flammable Limit : None.
Extinguish Media : Non-flammable.
Special Fire Fighting Procedure : None.
Unusual Fire and Explosion Hazards : None.
Autoignition temperature : N/A
7. REACTIVITY DATA
Stability : Stable.
Incompatibility (Materials to Avoid) : None.
Hazardous Decomposition or by Product : None.
Hazardous Polymerization : Occur.

8. HEALTH HAZARD DATA


Self – Reactivity : None
Explosion : None
Flammability : Flammable after evaporated moisture
Oxidation : None
Stability : Stable in normal condition
: None (Annex V method. COMMISSION DIRECTIVE 93/21/EEC of EU)
Skin Irritation
: No Data available concerning this Pigment in
Eye Irritation RTECS₂ Issued by NIOSH₃
Acute Toxicity : LD ≥ 5000 mg/Kg (Oral, Rat)
(Data of this Pigment
component)⁴
Degradability : None (Data of this Pigment component)
Fish Toxicity : No Data available
Others : Apply to the New German Regulation of July 15,1994.⁵
Manufacturing and import will be prohibited from April 1,
1998. And selling will be prohibited from October 1, 1998.
Emergency and First Aid Procedures
Steps to Be Taken in Case Material is : Collect in container for disposal. Use protective Released or Spilled
9. PRECAUTIONS FOR SAFE HANDLING AND USE
equipments such as rubber gloves and safety glasses.
Waste Disposal Method : In accordance with local and official regulations, pass on to an appropriate
incinerating plant of depository, but not to streams or waterways.
Precautions to Be Taken in Handling : Avoid contact with skin and
eyes. and Storing

10. CONTROL MEASURES


Respiratory Protection : Not required if used in well-ventilated place.
Local Exhaust : Should be well-ventilated.
Special : Not necessary.
Machanical : Not necessary.
Other : Not necessary.
Protective Gloves : Needed (Rubber gloves).
Eye Protection : Needed (Safety glasses).
Other Protective Clothing or Equipment : Not necessary.

11. DOT SHIPPING INFORMATION


Proper Shipping Name : Kiwadye Red P-84S
DOT Class : Not applicable.
DOT ID Number : Not applicable.
Reportable Quantity : Not applicable.
Local Requirements : Not applicable.
Other Information : Not applicable.

Air monitoring for acrylonitrile is recommended where the product is heated in areas without adequate ventilation.
12. ADDITIONAL INFORMATION
Degradability : N/A
13. ENVIRONMENTAL INFORMATION
Concentrativity : N/A

14. DISPOSAL CONSIDERATION


Product : if utilization or recycling pf product is not possible, if should be disposed of according to the
local regulations and lows.

15. TRANSPORTATION
See “SECTION VIII - Precaution for Handing and Storage”.

16. APPLICATION OF LAW


This is not restricted by any of laws listed as follows;
Chemical Substances Control Act, The Industrial Safety and Health Law, The Fire Service Act,
Regulation of Poison and Toxicant, The Safety of Vessel’s Law. Apply to the New German Regulation of July 15, 1994.
Read well the section of PRECAUTION OF HANDLING AND STORAGE,
MEASURES FOR EXPOSURE PREVENTION, FIRST AID PROCEDURES, etc. and be careful for handing.
Thai Kiwa Chemical Co., Ltd (Manufacture) Chemsol Tech Co.,Ltd. (Overseas Agency)
78 Soi Chan 16, Thungwatdon, Sathon, 1/21 Moo 3, Tambon Thakharm, Amphur Bangpakong,
Bangkok 10120 Thailand. Chachongsao 24130 Thailand.
Tel :(662) 676-1115, e-mail : thaikiwa@hotmail.com (66) 33 020 441, e-mail : chemsolbang@gmail.com
All information and statements given in the Product information are belived to be accurate at the time of publication, but Thai Kiwa Chemicals and an of their affiliates make no
representation or warranty with respect thereto, including, but not limited to, any results obtained or the infringement of any proprietary right.
1 and statements are intented for persons having the required skill and know-how and do not relieve the user form verifying the suitability of the information and
All information
statements given for a specific purpose prior to use. Use or application of such information or statements is at the user's sole discretion and risk, without any liability on the
part of Thai Kiwa Chemicals or any of their affiliates. Nothing herein shall be construed a licence to or a recommendation for use of the any proprietary rights.

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