1.

(1) Positional isomer

(2) Chain isomer
(3) Geometrical isomer
(4) Functional isomer
2. Including cyclic structures, how many structural isomers
are possible for the formula C4H8 :

(1) 3
(2) 5
(3) 2
(4) 4
3. The number of isomeric aldehydes and ketones with
formula C5H10O are (structural isomers)

(1) 7
(2) 6
(3) 5
(4) 8
4. Minimum number of carbon atom required by a
Hydrocarbon alkane alkene an alkyne to show chain
isomerism respectively are:

(1) 1,4,4
(2) 4,3,3
(3) 4,4,3
(4) 4,4,5
5. How many structural formula are possible when one of the
hydrogen is replaced by a chlorine atom in anthracene and
phenanthracene:

(1) 3,5
(2) 7,3
(3) 3,3
(4) 6,2
6. Which of the following compound is isomeric with
propanoic acid:

The equality relationship between

7. Compound

(1) Functional isomers

(2) Position isomers
(3) Metamers
(4) All of these
8. Which of the following compound will show geometrical
isomers?
9. The geometrical isomerism is shown by:
10.

Incorrect statement is:

(1) (a) is Z, (b) is E
(2) (a) and (b) are geometrical isomers
(3) (a) and (b) are structural isomers
(4) (a) and (b) have different connectivity of atoms
11. Which of the following statement is true regarding
following structures?

(1) I, II and III are identical

(2) I and II are identical, while I and III are enantiomers
(3) I and III are identical, while I and II are enantiomers
(4) II and III are identical, while I and II are enantiomers
12. The two compounds given below are :

(1) Enantiomers
(2) Identical
(3) Optically inactive
(4) Diastereomers
13. Which of the following combination amongst the four
fischer projections represents the same absolute
configuration.

(1) II and III

(2) I and IV
(3) II and IV
(4) III and IV
14. Which of the following are diastereomers?

(1) I and III

(2) II and IV
(3) I and II
(4) None of these
15. Following molecules are:

(1) Enantiomer
(2) Identical
(3) Diastereomer
(4) Structural isomers
16. :
17. Which of the following show stable or major form of enol?
18. Which structure is most stable:
19. What is the activation energy for a reaction it its rate
doubles when the temperature is raised from 200 to 350C :

(1) 342 kJ mol-1

(2) 269 kJ mol-1
(3) 34.7 kJ mol-1
(4) 15.1 kJ mol-1
20. For the chemical reaction
N2 (g) + 3H2 (g) 2NH3 (g)

the correct option is:

1 d[H2 ] 1 d[NH3 ] d[N2 ] d[NH3 ]

(1)   (2)  2
3 dt 2 dt dt dt
d[N2 ] 1 d[NH3 ] d[H2 ] d[NH3 ]
(3)   (4) 3 2
dt 2 dt dt dt
21. A first order reaction has a specific reaction rate of 10-2
sec-1. How much time will it take for 20g of the reactant to
reduce to 5g:

(1) 138.6 sec

(2) 346. 5 sec
(3) 693.0 sec
(4) 238.6 sec
22. The addition of a catalyst during a chemical reaction alters
which of the following quantities:

(1) Entropy
(2) Internal energy
(3) Enthalpy
(4) Activation energy
23. Identify the incorrect statement:

(1) For zero order reaction t1/2  [R0]

(2) For first order reaction t1/2 is independent of [R0]
(3) For a chemical reaction with rise in temperature by
100, the rate constant is nearly increases three to
four times
(4) The number of collisions per second per unit volume
of the reaction mixture is known as collision
frequently
24. For an exothermic reaction, the energy of activation of the
reactants is:

(1) equal to the energy of activation of products

(2) less than the energy of activation of products
(3) greater than the energy of activation of products
(4) some times greater and sometimes less than that of
the products
25. Rate of a reaction can be expressed by arrhenius equation
as k = Ae-E/RT
In this equation, E represents:

(1) The energy above which all the colliding molecules will
react
(2) The energy below which colliding molecules will not
react
(3) The total energy of the reacting molecules at a
temperature T
(4) The fraction of molecules with energy greater than the
activation energy of the reaction
26. A reactant (A) form two products
A 
k1
 B, Activation energy Ea1
A 
k2
 C, Activation energy Ea2

If Ea2 = 2Ea1 then k1 and k2 are related as:

(1) k1  2k 2 eEa2 /RT (2) k1  k 2 eEa1 /RT

(3) k 2  k1eEa2 /RT (4) k1  Ak 2 eEa1 /RT
27. The activation energy for a simple chemical reaction
A  B is Ea in forward direction. The activation energy
for the reverse reaction:
(1) is negative of Ea
(2) is always less than Ea
(3) can be less than or more than Ea
(4) is always double of Ea
28. Consider the endothermic reaction X- y with the activation
energies E0 and Ef backward and forward reactions,
respectively in general:

(1) Eb < Ef
(2) Eb > Ef
(3) Eb = Ef
(4) these is no definite relation between Ef and Eb
29. Rate constant, k of the first order reaction when initial
concentration (C0) and concentration (Cr) at time t,is given
by equation kt = log C0 – log Ct. Graph is a straight line if
we plot:

(1) t vs log C0
(2) t vs log Ct
(3) t-1 vs log Ct
(4) log C0 vs log Ct
30. For a first order reaction A  B the reaction rate at reactant
concentration of 0.01 M is found to be 2.0 × 10-5 mol lit-1
sec-1. The half life period of the reaction is:

(1) 220 s
(2) 30 s
(3) 300 s
(4) 347 s
31. In a first order reaction A  B if k is rate constant and initial
concentration of the reactant A is 0.5 M, then the half-life
is:

log2 log2
(1) (2)
k k 0.5
ln 2 0.693
(3) (4)
k 0.5k
32. The half lie of a substance in a certain enzyme catalysed
reaction is 138s. The time required for the concentration of
the substance to fall from 1.28 mg L-1 to 0.04 mg L-1 is:

(1) 690 s
(2) 276 s
(3) 414 s
(4) 552 s
33. A first order reaction takes 40 minutes for 30%. It’s half life
 10 
period log  0.1549 
 7 

(1) 99.9 min

(2) 88.8 min
(3) 77.7 min
(4) 66.6 min
34. For a first order A  B the reaction rate at reactant
concentration of 0.01 M is found to be 2.0 ×10-5 mol lit-1
sec-1. The half life period of the reaction is:

(1) 220s
(2) 30s
(3) 300s
(4) 347 s
35. In a first –order reaction A  B if k is rate constant and
initial concentration of the reactant A is 0.5 M, then the
half-life is:

log2 log 2
(1) (2)
k k 0.5
ln 2 0.693
3) (4)
k 0.5k
21. [A] [B] Rate of reaction
0.1 M 0.1 M 0.002
0.2 M 0.1 M 0.002
0.3 M 0.2 M 0.008
0.4 M 0.3 M 0.018
The rate equation will be:

(1) Rate = k [B]2

(2) Rate = k [A][B]2
(3) Rate =k[A]2[B]
(4) Rate = k [A][B]
22. The rate constant of the reaction A  B is 0.6 ×10-3
mole per second. If the concentration of A is 5M, then
concentration of B after 20 minutes is:

(1) 0.36 M
(2) 0.72 M
(3) 1.08 M
(4) 3.60 M
23. The correct difference between first and second order
reactions is that:

(1) A first order reaction can catalyzed; a second-order

reaction cannot be catalyzed
(2) The half-life of a first order reaction does not depend on
[A]0 ; the half-life of a second-order reaction does
depend on [A]0
(3) The rate of a first-order reaction does not depend on
reactant concentrations, the rate of a second order
reaction does depend on reactant concentrations
(4) The rate of a first order reaction does depend on reactant
concentrations; the rate of a second-order reaction does
not depend on reactant concentration
24. When initial concentration of the reactant is doubled, the
half-life period of a zero order reaction:

(1) Is tripled
(2) Is doubled
(3) Is halved
(4) Remains unchanged
25. If the rate constant for a first order reaction is k, the time
(t) required for the completion of 99% of the reaction is
given by:

(1) t = 0.639 /k
(2) t = 6.909/k
(3) t = 4.606/k
(4) t = 2.303/k