Data and formulae sheet

Important IR stretching frequencies

Those above 1650 cm–1 are most important.

Equations

Kw = 1.0 × 10-14
pKa + pKb = 14
Kw = Ka × Kb
pH = -log[H3O+]
Kw = [H3O+][OH-]

−𝑏𝑏 ± √𝑏𝑏 2 − 4𝑎𝑎𝑎𝑎

𝑥𝑥 =
2𝑎𝑎

Zero First Second

rate = k rate = k[A] rate = k[A]2

[A]t = –kt + [A]o ln[A]t = –kt + ln[A]o

𝒍𝒍𝒍𝒍 𝟐𝟐
𝒕𝒕𝟏𝟏 =
𝟐𝟐 𝒌𝒌

𝑬𝑬𝒂𝒂 𝑬𝑬𝒂𝒂 𝟏𝟏 𝒌𝒌𝟐𝟐 −𝑬𝑬𝒂𝒂 𝟏𝟏 𝟏𝟏

𝒌𝒌 = 𝑨𝑨𝒆𝒆−𝑹𝑹𝑹𝑹 𝒍𝒍𝒍𝒍𝒍𝒍 = − � � + 𝒍𝒍𝒍𝒍𝒍𝒍 𝒍𝒍𝒍𝒍 = ( − )
𝑹𝑹 𝑻𝑻 𝒌𝒌𝟏𝟏 𝑹𝑹 𝑻𝑻𝟐𝟐 𝑻𝑻𝟏𝟏

Constants Conversions
R = 8.314 J K–1 mol–1 p° = 105 Pa
NA = 6.022 × 1023 mol–1 1 bar = 105 Pa
F = 96487 C mol–1 T(K) = T(°C) + 273.15