Professional Documents
Culture Documents
Mallinckrodt Jersey City Site
Mallinckrodt Jersey City Site
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1'1.1 . j t .. {1
~ :.. ~I'-l: 11~ oil
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Mr. Scott A.
Weinel'. CommlssJoner
New Jerse)' Department of Env!ronmental Protection and Energ)'
401 Eagt S~ateStreett 7th Floor
Trenton, Nrw Jersey 08625
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Re: N!qEPE VoluntBlYSite Remediation ProgflDl
M~. Holclli1p,Inc.
223 est Side Avenue
J ,, City, NJ CY7305
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Oelll' Mr.1e1ner:
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The purpos. of thiS letter fs two fold, 1) To enthusiastically report to you that the NJDEPE
I voluntary BIte remediation program Is 8 succt".8S and 2) To seek your guidance, given thIs
success, as !to
how we mIght now proceed with a more streamlined ECRA review submittal
80 as to avqld the possibIUty of and duplicate efforts and costly delays, given the negative
historical ~ceptiC1n oC ECRA as a site remediatIon process.
I
M.I. Holdln¥s executed B Memorandum of Agreement (MOA) with NJDEPE in October, 1'992
to begin N~DEPE oversight of the cleanup of M.I. lIo1dlngs' Jersey Crty, New Jersey
facUlty. ok
proJjeTtles are comprised of 11.65 acres of land which are divided into three
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N]DEPE's tevtew of that report, as well as the oversight of on-going remedial activities
for the western portion of the facility, has been conducted by NJDEPE's West Orange, New
Jersey flel4 offlce. The support from the West Orange offlce has been excellent. The
NJDEPE o~rs!ght manager Is Mr. Gary Greulich, s Senior Environmental Specialist in the
West Orange office. Mr. Greulich's responsiveness to our needs has kept the projeCt on
i schedule and a lette!" o! no further action (for the ellstern portion of the facl1ltjr) was
i lssued by N~DEPE to M.1. Holdings, Inc. an May 17, 1993 (copy attached).
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TIERRA-B-014883
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. ,.0. FROM iOGD1AliD-CLYDE WAYNE 70 !609177~2B5 P005iC06
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i W. Fred Ro Inson
i Vice Preatd t and General Manager
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cc: G. Gf.'euHch (NJDEPE, West Orange)
B. V Fossen (NJDEPE, West Orange)
W. Ii" on
J. KIrk
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TIERRA-B-014884
Document No. 5
• 4 Confidential Business Information
Report
=
Volume 1
Prepared for
Prepared by
10 December 1987
AWD
BAF000001
TIERRA-B-014885
AWDTechnologles, Inc.
TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1
2.0 BACKGROUND INFORMATION
2.1 Geology 1
2.2 Hydrogeology 2
3.0 FIELD INVESTIGATIONS 2
3.1 Soil Borings and Monitoring Well Insta 11at ion 2
3.2 Monitoring Well Development 4
3.3 Groundwater Sampling 5
NJIOlTC ii
TIERRA-B-014886
AWO Tedtnologles, Inc.
LIST OF TABLES
Table Title
1 SUMMARY OF MONITORING WELL CONSTRUCTION
2 FIELD PARAMETER MEASUREMENTS ON JUlY 27 AND 28, 1987
3 GROUNDWATER ANALYSIS - ORGANIC COMPOUNDS
4 GROUNDWATER ANALYSIS - METALS
5 SOIL ANALYSIS, METALS
6 SOIL ANALYSIS, ORGANIC COMPOUNDS
LIST OF FIGURES
Figure Title
1 WELL LOCATION AND WATER LEVEL
2 TYPICAL CLUSTERED WELL INSTALLATION
lIST OF APPENDICES
Appendix Title
A BORING lOGS
B MONITORING WELL INSTALLATION REPORTS
C LABORATORY REPORTS (Bound Separately)
NJIOITC iii
TIERRA-B-014887
AWD Technologies. Inc.
1.0 INTRODUCTION
2.1 Geology
The bedrock beneath the M.I. Holdings site is the Triassic Newark
formation which consists of red sandstones and shale with occasional
layers of conglomerate. To the east of the property, the Triassic
Palisade Diabase forms a linear hill that extends the entire length of
Jersey City and eventually emerges to the north along the Hudson
River.
NJIOI -1-
TIERRA-B-014888
AWDTechnologies, Inc.
2.2 Hydrogeology
NJI01
TIERRA-B-014889
AWDTechnologies, Inc.
Throughout the drill ing, air qual ity was monitored with an HNU
(11.7 EV probe) and a mercury vapor analyzer both at the borehole and
in the breathing zone.
NJ101 -3~
TIERRA-B-014890
AWD Technologies. Inc.
NJIOI -4-
TIERRA-B-014891
AWU Technologies, Inc.
NJ10l -5-
TIERRA-B-014892
AWD Technologies, Inc.
The three deep wells (MW-IB, MW-2B and MW-3B) were purged of a
minimum three casing volumes of water using a submersible pump.
Alconox and potable water were used to wash the pump. Approximately
30 gallons of potable water were flushed through the pump after
purging each monitor well.
The three shallow wells (MW-IA, MW·2A and MW-3A} were purged
using a centrifugal pump and dedicated black PVC hose. The shallow
wells were pumped dry and allowed to recharge for 2 hours, and then
pumped dry a second time before sampling.
NJIOl
TIERRA-B-014893
AWDTechnologles, Inc.
NJ101 -7-
TIERRA-B-014894
AWDTechnofogles, Inc.
NJIOI -8-
TIERRA-B-014895
AWD Tecbnologies, Inc.
NJIOI ~9-
TIERRA-B-014896
AWD Technologies, Inc.
5.1 Conclusjons
NJIOI -10-
TIERRA-B-014897
AWD Technologies. Inc.
5.2 Recommendations
NJI01 -11-
TIERRA-B-014898
AWDTechnoJogies, Inc.
TABLE 1
SUMMARY OF MONITORING WELL CONSTRUCTION
length Elevation
Screen of Ri ser (ft) Top of
Depth Length (Including Casing
MW (ft) (ft) stickup) (ft)
NJIOITl
TIERRA-B-014899
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TABLE 2 5'
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FIELD PARAMETER MEASUREMENTS ON JULY 27 AND 28, 1987
HNU
Background/
Elevation Cft} Condo Well
Well Top of Water Quality Temp. (umhos/ Sample
Humber Water Casing Smell, Color Time pH oC cm) (ppm)
... __ .- .. __ ._- " ..
NJI01T42
TIERRA-B-014900
AWn Technologies, Inc.
TABLE 3
GROUNDWATER ANALYSIS - ORGANIC COMPOUNDS
Well ; MW lA
w
MW-IB MW-2A MW-2B MW 3A
w MW 3B
w
Base/Neutral Compounds
1,2-Dichlorobenzene U U U U U 6J
Naphthalene U U U IJ U 3J
Fluoranthene U U U U U U
pyrene U U U U U U
TIERRA-B-014901
TABLE 4
GROUNDWATER ANALYSIS - METALS ~
Cl
Parameter: Antimony Arsenic Beryllium Chromium Copper Lead Mercury Nickel Selenium Zinc
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...
0
~
MW-IA: ~
7/27/87
unfiltered <60 <10 <5.0 46 36 48 4.6 <40 <5.0 84
9/23/87
filtered <60 <10 <5.0 14 <25 <5.0 1 <40 <5.0 112
10/16/87
filtered 101 <10 <9 <10 <25 <5.0 0.45 <40 8.6 30
MW-18:
7/27/87
unfiltered <60 <10 <5.0 <10 <25 <5.0 <0.2 <40 5.6 <20
9/23/87
filtered <60 <10 <5.0 <10 <25 <5.0 <0.2 <40 <5.0 60
10/16/87
filtered <60 <10 <5 <10 <25 <5.0 <0.2 90 6.0 39
TIERRA-B-014902
TABLE 4, CONTINUED
GROUNDWATER ANALYSIS - METALS
i
Parameter: ~
Antimony Arsenic Beryllium Chromium Copper Lead Mercury Ni ck.e1 Selenium Zinc ::s
2.
co
MW-2A:
J
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7/27/87
unfiltered <60 46 <5.0 202 <25 21 45.6 <40 <5.0 64
9/23/87
filtered <60 4 <5.0 11 <25 <5.0 <0.2 <40 <5.0 81
10/16/87
filtered 102 21 <5 <10 <25 <5.0 <0.2 <40 <5.0 <20
MW-2B:
7/27/87
unfiltered <60 <10 <5.0 <10 <25 5.2 3.6 <40 <20 <20
9/23/87
filtered <60 <10 <5.0 <10 <25 <5.0 <0.2 <40 <5.0 58
10/16/87
f11 tered 8.3 <10 <5 <10 <25 <5.0 <0.2 <40 <5.0 37
TIERRA-B-014903
TABLE 4, CONCLUDED
GROUNDWATER ANALYSIS - METALS
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Parameter: Antimony Arsenic Beryll ium Chromium Copper Lead Mercury Nickel Selenium Zinc
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MW-3A: S"
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7/27/87
unfiltered 151 37 <5.0 2.240 113 193 240 206 <5.0 306
9/23/87
filtered <60 21 <5.0 1,970 <25 <5.0 9.3 <40 <5.0 114
10/16/87
filtered 133 42 <5 2,000 <25 <5.0 15.1 K40 K5.0 24
MW-3B:
7/27/87
unfiltered <60 45 <5.0 1,000 48 5.2 22 <40 <5.0 41
9/23/87
filtered <60 6.2 K5.0 <10 <25 <5.0 0.27 <40 <5.0 SO
10/16/87
filtered <60 <10 <5 <10 <25 <5.0 <0.2 <40 <5.0 30
TIERRA-B-014904
AWD Tedlnologles. Inc.
TABLE 5
SOIL ANALYSIS, METALS
Parameter:
Antimony <12 <12 728
Arsenic <2.0 <2.0 5.3
Beryllium <1.0 <5.0 1.3
Copper <5.0 10 45
NJ10lT6
TIERRA-B-014905
AWDTechnologles,lnc.
TABLE 6
SOIL ANALYSIS, ORGANIC COMPOUNDS
Base/Neutral Compounds:
1,2-Dichlorobenzene U U U
Naphthalene U U U
Fluoranthene 73 J U U
pyrene 88 J U U
Cyanide
(aqueous, ug/l) <0.10 <0.1 <0.10
Cyanide
(dry weight, mg/kg)
Phenols
(aqueous, ug/l) <0.5 <0.5 1.05
Phenols
(dry weight, mg/kg)
Petroleum Hydrocarbons
(mg/l) NT NT NT
TIERRA-B-014906
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TIERRA-B-014907
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TIERRA-B-014908
OFFSHORE INVESTIGATION
RESULTS SUMMARY REPORT
STUDY AREA 7
JERSEY CITY, NEW JERSEY
Prepared For:
Prepared By:
Parsons
200 Cottontail Lane
Somerset, NJ 08873
BASOOOOOI
TIERRA-B-014909
S
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TIERRA-B-014910
OFFSHORE INVESTIGATION
RESULTS SUMMARY REPORT
STUDY AREA 7
JERSEY CITY, NEW JERSEY
Prepared For:
Prepared By:
Parsons
200 Cottontail Lane
Somerset, NJ 08873
TIERRA-B-014911
TABLE OF CONTENTS
1.0 INTRODUCTION I
1.1 Purpose............................................................................... 1
12 Site Description....................... .. 1
1.3 Overview of Offshore Investigation Results.............................................. .. .. 2
2.0 RESULTS OF BATHYMETRIC, GEOPHYSICAL, AND HYDRODYNAMIC
FIELD SURVEyS 4
2.1 Bathymetric Surveys............................................. 4
3.4.1 TotaiChromiumandChromium VI 9
3. 7. I Polychlorinated Biphenyls II
TIERRA-B-014912
TABLE OF CONTENTS (continued)
TIERRA-B-014913
LIST OF TABLES
Table 6 Acid Volatile Sulfide and Simultaneously Extracted Metals Results in Sediment
TIERRA-B-014914
LIST OF FIGURES
Figure 3 Locations of Sediment Grab Samples and Water Column Samples in the
Reference Areas
Figure 4 Study Area 7 Cross-Section Location Map
Figure 5A Cross-Section A-A', Hackensack River Near Study Area 7
Figure 6B Total Chromium Results in Sediment from 0.5 to 1.0 ft Below Mudline
Figure 6C Total Chromium Results in Sediment from I to 2 ft Below Mudline
Figure 6D Total Chromium Results in Sediment from 2 to 3 ft Below Mudline
TIERRA-B-014915
LIST OF FIGURES (continued)
TIERRA-B-014916
LIST OF FIGURES (continued)
TIERRA-B-014917
LIST OF FIGURES (continued)
Figure llA Mercury Results in Sediment from 0.0 to 0.5 ft Below Mudline
Figure liB Mercury Results in Sediment from 1 to 2 ft Below Mudline
Figure IIC Mercury Results in Sediment from 3 to 4 ft Below MudJine
Figure 12A Total Polycyclic Aromatic Hydrocarbon Results in Sediment from 0.0 to 0.5 ft
Below Mudline
Figure 12B Total Polycyclic Aromatic Hydrocarbon Results in Sediment from I to 2 ft Below
Mudline
Figure 12C Total Polycyclic Aromatic Hydrocarbon Results in Sediment from 3 to 4 ft Below
Mudline
Figure 13A PCB TEQ from 0.0 to 0.5 ft Below Mudline
Figure 13B PCB TEQ from 1.5 to 2.0 ft Below Mudline
Figure l3C PCB TEQ from 3.5 to 4.0 ft Below Mudline
Figure 14A DioxinJFur1m TEQ from 0.0 to 0.5 ft Below Mudline
Figure 14B Dioxin/Furan TEQ from 1.5 to 2.0 ft Below Mudline
Figure I4C Dioxin/Furan TEQ from 3.5 to 4.0 ft Below Mudline
TIERRA-B-014918
1.0 INTRODUCTION
1.1 Purpose
the results of sediment chemistry and physical testing of sediments performed as pan of
the offshore investigation activities conducted between October 2003 and January 2004
in the Hackensack River in the vicinity of Study Area 7 (hereafter referred to as "SA 1',
or the "Site") located in Jersey City, New Jersey. Offshore investigation activities
included sediment sampling, field surveys, pore water characterization, water column
discussed herein was implemented in compliance vvith two stipulated Immediate Action
Orders entered into by the parties pursuant to the judgment entered by the United States
District Court of New Jersey in Interfaith CommWlity Organization, et. aI. v. Honeywell
International et aI (Civil Action No. 95-2097 DMC, May IS, 2003). In particular, the
field activities summarized herein were specified in the Sediment Sampling Plan
(Immediate Action Stipulation Item 13) and the Bathymetric and Waterside Geophysical
Survey Plan (Immediate Action Stipulation Item 20) contained in the court order.
The chemical data included in this report have been independently reviewed and
validated by V ALIDAT A, LLC under contract to Honeywell. All chemical data collected
during the offshore investigation was evaluated and validated according to the Standard
Protection (NJDEP 2001), The data presented in this report supersede the preliminary
results reported periodically by Honeywell to The Louis Berger Group previously. The
procedures used during implementation of the field work are summarized in the Offshore
Investigation Post - Field Sampling Report October 2003 To January 2004 Activities,
Study Area 7, Jersey City, New Jersey (Parsons and ENVIRON 2004).
TIERRA-B-014919
• Roosevelt Dnve-In SIte (NJDEP SIte 115),
The Site is primarily a vacant [at, although the Trader Horn facility is still in
operation. All portions of the site have some form of cover: the eastern portion of the site
is paved with asphalt; the western portion was capped with a PVC cover and overlain
with gravel as an Interim Remedial Measure (IRM); and the middle of the site still
contains a concrete slab that was fonnerly the foundation for the Valley Fair department
store. With the exception of Trader Horn, no buildings exist on the property.
The site is bordered on the north by the Jersey City Incineration Authority
(NJDEP Site 087), the Jersey City Incineration Authority Well (NJDEP Site 088); on the
east by Route 440; on the south by the Roosevelt Bowling Lanes (NJDEP Site 124),
Delphic Consolidated (NIDEP Site 125), ABF Trucking (NJDEP Site 140), Old
Dominion (NJDEP Site 134), and Degen Oil (NIDEP Site 073); and on the west by the
Hackensack River. The Site is currently vacant but was formerly used for commercial
bulkhead along the waterfront adjoining the Hackensack River. Surrounding land use is
industrial and commerci aL
The offshore field work activities completed as part of the October 2003 to
January 2004 field investigation included the following;
TIERRA-B-014920
• Sediment Collection for Sedi ment Toxicity and Bioaccumulation Testing and
Benthic Infaunal Survey
TIERRA-B-014921
2.0 RESVL TS OF BATHYMETRIC, GEOPHYSICAL, AND HYDRODYNAMIC
FIELD SURVEYS
A two-person field team of Ocean Surveys, Inc. (OSI), operating under the
direction of an American Congress on Surveying and Mapping (ACSM) certified
hydrographer, conducted the bathymetric surveys. The surveys were performed in
accordance with the United States Army Corps of Engineers' (ACOE) Engineering
Manual EM 1110-2-1003 for Hydrographic Surveys (EM 1110-2-1003) for navigation
and dredging support in soft bottom materials. Bathymetric survey data were co fleeted
from the vicinity of the Site and surrounding offshore areas between October 17 and 22,
2003. The results of the bathymetric survey are presented in the Honeywell SA 7 Sediment
Program Bathymetric Survey, Jersey City, New Jersey report prepared by OSI (2004a).
The geophysical survey was conducted between October 22 and 28, 2003. The
geophysical field team used remote sensing technology to collect sub-bottom
stratigraphy, magnetic field intensity, and geomorphology information. Geophysical
survey data were collected from the vicinity of the Site and surrounding offshore areas.
The geophysical field survey consisted of an integrated suite of remote sensing
technologies including sub-bottom profiling, magnetic field intensity mapping, and side
scan sonar imaging. The results of the geophysical survey are presented in the Honeywell
SA 7 Sediment Program Geophysical Survey, Jersey City, New Jersey report prepared by
OSI (2004b).
Oceanographic and hydrodynamic survey data were collected from the vicinity of
the Site and surrounding offshore areas to collect water level, current velocity, and basic
water quality data for input to a sediment transport study and for evaluation and design of
sediment remediation options. The survey consisted of both an in situ program and a real-
time boat-mounted program using specialized field instrumentation. The in situ
instrument program consisted of measurement of current velocities, riverbed current
TIERRA-B-014922
velocities, sediment bed elevation, in situ river conductivity and temperature
measurements versus depth (CTD), and tidal variation around the Site As an adj unct to
the longer-term In situ instrument program, the oceanographic field team conducted a
pair of real-time boat-mounted current velocity and CTD-Turbidity profiling surveys over
nominal l3-hour tidal cycles along four cross-river transects. The results of the
OSI (2004c).
The groWldwater upwelling study was conducted to obtain supporting data for the
groundwater investigations being conducted onshore at the Site. Specifically, the purpose
was to obtain data on potential areas of groundwater to surface water seepage in the
riverbed was not possible, the investigation utilized a Trident Probe system to collect
areas of groundwater upwelling. In addition, hand penetrometers were inserted into the
sediments to evaluate the bearing capacity of the sediments and vane shear tests were
conducted to evaluate the undrained shear strength of the sediments in the vicinity of the
Site. The results of the groundwater upwelling study and in situ testing are presented in
TIERRA-B-014923
3.0 SEDIMENT CHEMICAL CHARACTERIZATION RESULTS
Sediment grab and core sampling was conducted from the vicinity of the Site and
surrounding offshore areas (Figures 2A, 28, and 3). The field sampling procedures used
are documented in the Offshore Investigation Post - Field Sampling Report October 2003
To January 2004 Activities, Study Area 7, Jersey City, New Jersey (parsons and
ENVIRON 2004). A total of 1,429 surface and subsurface sediment samples were
collected and analyzed for 212 chemicals and 8 physical parameters, including:
Chemicals
• Pesticides
• Ammonia and pH
Physical Parameters
• Bulk density, water content, percent solids and total organic carbon
YALIDA TA, LLC evaluated and validated the analytical data according to the
Standard Operating Procedure (SOP) established by the New Jersey Department of
TIERRA-B-014924
Environmental ProtectIOn. During the data validation process, the laboratory reports were
reviewed and quality assurance/quality control parameters were evaluated (where
applicable) as described in the data validation SOP (NJDEP 2001). The following
qualifiers were used where applicable:
• "R" indicates that the reporting limit or sample result has been determined to be
Wlusable due to a major deficiency in the data generation process. The data should
not be used for any qualitative or quantitative purposes.
• "ur' indicates that the sample-specific reporting limit for the analyte in this
sample should be considered approximate. This qualifier is used when the data
validation process identifies a deficiency in the data generation process.
• "B" indicates that detectable levels of the analyte were found in the associated
method blank.
range, and the average detected concentration in sediment. In addition to the summary
statistics, the frequency of exceedance of chemical screening criteria established by New
Jersey Department of Environmental Protection and the National Oceanic and
Atmospheric Administration (NJDEPfNOAA) are also shown. Table I presents a
summary of chemicals detected in sediment samples collected at all depths of sampling in
the vicinity of SA7. Table 2 presents a summary of chemicals detected in sediment
samples from 0 to 0.5 feet below the sediment surface in the vicinity of SA7. Table 3
presents a summary of chemicals detected in sediment samples collected from the
reference areas.
TIERRA-B-014925
3.3 Cross-Sections of Sediment Depths in the Hackensack River Adjacent to SA 7
Offshore sediment borings were drilled between November and December 2003
at a total of 41 locations in the vicinity of Study Area 7 for physical and chemical
characterization of river sediments. Sediment cores were collected using piston and
vibracoring methods at 33 of the 41 locations and deep geotechnical borings were drilled
using rotary drilling techniques at the remaining eight locations. Of the 33 sediment
coring locations, 26 were completed to a nominal depth of 10 feet below the sediment
surface (or "mudline") and seven were completed to depths greater than 10 feet (i.e., as
great as 17 feet) below the mudline. The deep gootechnical borings were typically drilled
approximately 20 feet into bedrock (i.e., a total depth of approximately 120 feet below
the mudline) The boring locations are shown on Figure 4.
• Stratum D, Grey to Black Peat and Organic Clay: Typically dark grey organic
clay and clayey silt, scattered fine sand laminations, very loose to loose.
• Stratum SI, Grey Sand: Typically light to medium grey fine to medium-grained
sand, trace coarse sand and gravel, trace organic material, scattered laminations of
fine sand or silt, generally dense.
• Stratum RC, Reddish Brown Silty Clay/Clayey Silt: Typically reddish bro\Vll silty
clay and clayey silt, trace silty sand, dense to very dense.
TIERRA-B-014926
shows the locations of the cross-sections offshore from the Site. Sediment cross-sections
extending parallel to the waterfront bulkhead at the Site are shovm in Figures 5A through
3.4 Metals
Columbia Analytical Services, Inc. (Columbia), Total chromium was analyzed using
analyses were conducted by two analytical methods, EPA Methods 7l96A and 7199,
folloVving extraction by two different methods (NIDEP and EPA). Table 4 presents the
concentration range of 3.9 milligrams per kilogram (mg/kg) to 33,500 mglkg and an
collected, 280 samples exceeded the NJDEPtNOAA Effects Range Low (ERL) screening
Medium (ERM) screening criterion of 370 mg/kg, and 288 samples exceeded the NOAA
figures show the offshore areas where total chromium concentrations are below the
Chromium VI was detected in 218 samples, with a concentration range of 0.5 mglkg to
57 mg/kg.
TIERRA-B-014927
342 Target Analyte List Metals
New Jersey (STL-Edison) using EPA Methods 60lOB and 7471. Table 5 presents the
analytical results of TAL metals in sedi ment. Summaries of TAL metals concentrations
in sediment and their screening criteria exceedances are also presented In Tables 1, 2 and
3. All TAL metals with the exception of thallium were detected in sediment samples. To
illustrate the presence of other metals in sediment, concentration profiles of arsenic, lead,
and mercury, are shown in Figures 9A through 9C, IDA through IOD, and 11A through
11 C, respectively.
EPA Draft Method A VS/SEM. Table 7 presents the analytical results of A VS/SEM in
than 1.
SVOC analyses were conducted by STL-Edison using EPA Method 8270C Table
concentrations in sediment and their NOAA AET screening criteria exceedances are
presented in Tables 1,2 and 3. PAH analyses were conducted by STL-Edison using EPA
Method SW8270. Table 9 presents the PAHs results and total PAHs concentrations in
sediment. In the calculation of total PARs, one-half of the detection limit was used for
non-detect samples. Total PAHs concentrations in sediment are also shown in Figures
12A through 12C. Summaries of detected PARs and total PAHs concentrations III
sediment and their screening criteria exceedances are presented in Tables 1,2 and 3.
TIERRA-B-014928
presented in Tables I, 2 and 3. Organotin analyses were conducted by STL·VT using
Method OR560. Table 6 shows the analytical results of organotin concentrations in
sediment and surrunaries of organotins are shown in Tables I, 2, and 3. Dibutyltin.
tributyltin, and tetrabutytin were detected in sediment samples with a concentration range
of 1.9 micrograms per kilogram (ug/kg) to 16 uglkg.
Total PCB analyses were conducted by Alta usmg EPA Method 8081 and
coplanar PCB analyses using EPA Method 1668. Table I I presents the analytical results
of PCBs in sediment. Summaries of PCB concentrations in sediment and their screening
criteria exceedances are presented in Tables I, 2 and 3. TEQ concentrations of PCBs
were calculated and are shown in Figures I3A through 13C.
PCDD and PCDP analyses were conducted by Alta using EPA Method 8290.
Table 12 presents the analytical results of PCDDs and PCDFs in sediment Summaries of
TIERRA-B-014929
PCDDIF concentrations in sediment are presented in Tables l, 2 and 3, TEQ
concentrations of PCDDs and PCDFs were calculated and are shown In Figures 14A
through 14C
PBDE analyses were conducted by Aha using EPA Method 8290. Table 13
Nitrogen ammonia, total organic carbon (TOC), and pH analyses were conducted
by STL-Edison using EPA Method 350.1-350,2, modified ASTM Method D 2579, and
EPA Method 9040B, respectively. Bulk density and percent solids analyses were
results of nitrogen ammonia, total organic carbon (TOC), bulk density, solids, and pH in
sediment.
Pore water, the water occupying the space between sediment or soil particles, was
extracted from sediment of the nine stations sampled for toxicity and bioaccumulation
testing. The isolation of pore water from these sediments occurred at the Site between
November II and 13, 2003, Total suspended solids (TSS), chromium, and metals in pore
water were analyzed by MEC Analytical Systems (MEC) in Calsbad, California and
STL-Edison. TSS results are presented in the Offshore Investigation, Sediment Toxicity
Characterization Report for November 2003 Sampling Activities, Honeywell Study Area
7, Jersey City, New Jersey prepared by MEC (2004). Table IS presents the analytical
results of total chromium and chromium VI in pore water. Table 16 presents the
TIERRA-B-014930
4.0 WATER COLUMN CHARACTERIZATION RESULTS
Water column samples for TSS analysis were collected in November and
December 2003 during the oceanographiclhydrodynamic survey operations. The results
of TSS in the water column are included in the oceanographic-hydrodynamic
characterization report entitled Honeywell SA 7 Sediment Program Oceanographic
Survey, Jersey City, New Jersey report prepared by OSI (2004c).
4.2 Chromium
A water column sampling event was also implemented to evaluate the potential
presence of chromium in surface water adjacent to the Site and in the identified reference
areas. On October 16, 2003, shallow surface water samples were collected for chromium
analysis from three locations near SA7 and from two locations in each of the three
targeted reference areas. figures 2 and 3 show the locations of water column samples in
the vicinity of Study Area 7 and the reference areas. All chromium grab water column
samples were submitted to Columbia for analysis of total chromium and chromium VI.
Total chromium was analyzed using EPA Method 60 lOB and chromium VI was analyzed
using EPA Method 7199. Table 17 presents the analytical results of total chromium and
chromium VI in water column samples.
TIERRA-B-014931
5.0 GEOTECHNICAL CHARACTERIZATION RESULTS
Core sediment samples were also obtained for standard oedometer (consolidation) and
permeability testing. The sediment samples were collected widl piston cores during November
and December 2003. However, these samples appeared to have been disturbed either as a result
of the coring, storage, or transportation procedures, and were considered too disturbed to obtain
meaningful consolidation and permeability results. MRCE has undisturbed sediment core
samples collected with a fixed piston from the shallow portions of the deep borings, GEO-l
through GEO-S, which can be used to run these tests. The locations of these borings are shown in
Figure 2B. ENVIRON requested the results of standard oedometer and permeability testing of
sediment borings (GEO-2. GEO-4, GEO-S, GEO-7, and GEO-8) from IvlRCE. The results of the
standard oedometer and permeability testing are shown in Table 19.
In addition to the geotechnical samples, surface sediment was sampled from three
locations for self-weight consolidation and column settling tests on November 22, 2003. The
self-weight consolidation/column settling test samples were submitted to Trident Tech Services,
Inc. (Trident) of Chesterton, Indiana for analysis. The results of the self-weight consolidation-
colulTU1settling tests are presented in the Sediment Testing Report - SA 7, Jersey City, New
Jersey report dated February 20, 2004 prepared by Trident (2004).
TIERRA-B-014932
5.3 Radiodating Analysis
To age-date different sediment depth intervals, sediment samples were collected from
certain sediment cores during the offshore sediment coring program for isotopic radiodating
testing and evaluating the depositional history of the offshore area near the Site and the stability
of the sediments. The radiodating samples were analyzed by Flett Research, Ltd. (Flett) of
Winnipeg, Manitoba. Canada for isotopic constituents using lead-210 (Ph-2l0) and cesium-137
(es-137) as indicator elements. Sediments to a depth of 10 em were also analyzed for bery IIium-
7 (Be-7), and a very limited subset of sample intervals was analyzed for radium-226 (Ra-226)
The radiochemistry results are presented in the Radiodating Analytical Report dated April 25.
2004 prepared by Flett (2004)
TIERRA-B-014933
6.0 ECOLOGICAL TOXICITY STUDIES
Composite sediment samples for the analysis of toxicity were collected between
November 7 and II, 2003 A description of the sampling process was discussed in Section
3.7.2.1 of the Offshore Investigation Post - Field Sampling Report October 2003 To JanuQlY
2004 Activities, Study Area 7, Jersey City, New Jersey (Parsons and ENVIRON 2004). The
composite sediment toxicity samples were analyzed for total chromium, chromium VI, TAL
metals, AVS/SEM, sVOCs, PARs, pesticides, PCBs, PCDDlFs , PBDEs, and other parameters.
Results were compared to those from similar testing performed concurrently at three locations
elsewhere in the Hackensack River and upper Newark Bay. Bioassays were performed in
accordance with USEPA and us. Army Corps of Engineer test methods. The methods and
more detailed results of the sediment toxicity study are presented in the Offshore Investigation,
Sediment Toxicity and Benthic Injaunal Characterization Report jor November 2003 Sampling
Activities, Honeywell Study Area 7, Jersey City, New Jersey prepared by MEC (2004). Results
of the sediment toxicity samples were validated using the data validation method described in
Section 3.1 of this report and are shown in Tables 4 through 14.
Sediment samples were collected offshore from SA 7 and in three reference locations to
determine the abundance and diversity of the benthic infaunal community in the sediment. The
benthic infaunal survey was performed in accordance with EPA methods. The methods and
results of the benthic infaunal survey are presented in the Offshore Investigation, Sediment
Toxicity Characterization Reponjor November 2003 Sampling Activities, HoneyweJl Study Area
7, Jersey City, New Jersey prepared by Iv.lliC (2004).
TIERRA-B-014934
7.0 REFERENCES
Flett Research Ltd. (Flett). 2004. Results of Hackensack RiverlNewark Bay Radiochemistry
Measurements. Letter from R.J. Flett to C. Stubbs, Environ. April 25.
MEC Analytical Systems, Inc (MEC). 2004. Offshore Investigation Sediment Toxicity and
Benthic InfalUlal Characterization Report for November 2003 Sample Activities;
Honeywell Study Area 7; Jersey City, New Jersey.
Mueser Rutledge Consulting Engineers (MRCE). 2004. Subsurface Investigation, Study Area _.
7, (Daylin-Grace Site), Jersey City, New Jersey. April 15,
Ocean Surveys, Inc. (OSI). 2004a. Honeywell SA7 Sediment Program Bathymetric Survey;
Jersey City, New Jersey.
Ocean Surveys, Inc. (OSI). 2004b Honeywell SA7 Sediment Program Geophysical Survey;
Jersey City, New Jersey,
Ocean Surveys, Inc. (OSI). 2004c. HoneyweIl SA 7 Sediment Program Oceanographic Survey;
Jersey City, New Jersey.
Ocean Surveys, Inc. (OSI). 2004d. Honeywell SA7 Sediment Program Vibratory Coring, Trident
Probing, Hand Penetrometer and Vane Shear Investigation; Hackensack River, Jersey
City, New Jersey.
Parsons and ENVIRON International Corporation (parsons and ENVIRON). 2004. Offshore
Investigation Post-Field Sampling Report October 2003 to Janu;uy 2004 Activities; Study
Area 7; Jersey City. New Jersey. Febru;uy 27.
Trident Tech Services, Inc. (Trident). 2004. Sediment Testing Report - SA 7; Jersey City. New
Jersey. February 20.
Van den Berg, et al. (1998). Toxic Equivalency Factors (TEFs) for PCBs, PCDDs, PCDFs for
Humans and for Wildlife, Environmental Health Perspectives 106, 775,
TIERRA-B-014935
Tobl. t
Summar)" ofChemir3h. in Sediment S:lilmple~ in ~he Vldnity ofSA7
DfI'hl('ted
S'ud,. Area 7; Jrruy Clt)'. New Jersey
M~(al:l m«l/kp):
--
---
-_. 9.3
---
OiJ
Bal'"ium
BerylliulTl
60/53
53/53
L3 -ID
l5·638
19
137
8.2
... _.
39/50 70
...
3160
...
3l
48
71liO
48/53
62153 0.11 - I O.S --. ... ... --- ... ..-
Cfldmium 54/68
C.lcium
Chromium
63/63
0.14·10.1
34l- 37000
1.7
6,213
l.2
... _
28/5"
.
9.6
...
1154
---
3
...
7/14
---
411/421 39·33500 534 81 280/421 370 137/421 52 288/411
Hcxavalenl Chromium NJDEP 7196A 7/304 5.49·2J.1 10 ... ... ..- ... ---
H<xavolenl Chromium NJDEP 7199 2181304 '"
0.. 78·40.9 3.7 -'- ... --- ... ._ .
Hexa ....alent Chromium EPA 71%A
Hexavalent Chromium EPA 7199
1/304
144/304
l85·5,86 19 ...
_.
-. _. ... ._ .
---
.-.
0516·56.5 4.4 --. '" -- ... .-.
Cobalt 63/63 2.1·21 7.6 ... ... --- ...
Copper 64/68 4.5·715 10 18/63
129 34 48164 270 7/64
Iron 63/63 390 3/64
5310·38900 21,373 - ... -.. ... ... ._-
lead 641207 2.1 - l20 137
Magne.'lium 5J/63 1160·9390 5,051
47
-_.
_.
50/64
... _.
218 13/64
--
400
...
2164
... !
Ma."g~ncsc:
MC"rcury
63/63
601203
45.3 • 623 298 ... _. -. 260 40/63
0.041 ·64 6.8 0.15 53/60
Nickel 0.71 45/60 0.41 48160 !
POlA$$ium
64/68
63/53
1.5 - 120
298·2500
28
1,411
21
..- _.
37/64
_
_.
52 3/64 110
...
1/54
Selenium
Silver
3/63
51/63
2.7·3.7 3.2 ... .
-. _.
--.
I
._-
313
0.44·8.8
_.
I
2.4
Sodium 63/63 ~5I - L0900 4,290 _.
1 39/51 3.7
...
6/51
...
3.1 10/51
Thallium 0/63 .- .- _. _. _. ...
--
_.- _....
V.Rn.Adilim
Zinc
63/63
64/68
5.8·98.5
14.2 - 842
28 .-. ... _. ._- 57 3163
252 150 40/64 410 13164 410 13/64
IO ...... otlns (uP/kpi,
Dlbutyllio 21/63 1.9·14 5.1 ... -- -.. ... ...
M.onQ-butyllin
Tc-Ir~butyhin
7/63 12·2.3 1.7 ..- ... .-- ... ... ...
7/63 26-5.4 3.4 ... ..- ... ...
Triburyhin --- ---
19/63 1.9·19 H ._- -. ... -'. --- ...
,
Parson!
Page I of7
f: 1'<' , RON
TIERRA-B-014936
Tohle 1
SUJhmltl")' of Chem 1l'8b: Detf'(,'I'td III Sediment S:a.mpl"!I; in the: Vi(ini~' of SA ,
St .. dy Aru ;; ,JCr1It"y Ci1')', Nf''W Jenr~
1
!
Oetntlon
Rang.
Ave-rag-t D.tected
ERL ERL ERM ERM NOAAAET
Ch("mi('~l! of NOAA
Frtqurnc)' (NJDEP/ E.x(,f'f'danC"f' (NJDEP/ E:u'Il!l"donef' Exc-trdanc-l'
Conc~ntntlol1: AET
o.te~tion NOAA) Frrquf'oq NOAA) , Froeque-nc)' Foreqt.ch(",J
.- 8
_.--
I
2-Mclhylphenol OIM -- .-- I ... -_. - ..
2-NilrOAtlilim: 0164 --- .- -. I _ .. ...
8
...
.-
--
2 - Nilrophenol 0/64 ... -_ .... --... --- ... --- ...
3,3'·Di(;1; IOfobenzldinc 0164
---- 00-
... -- I
._-
...
--. --.
I
_.
-- - ..
_00
...
00-
4·Chloroaniline
4·Chloropher'lyl ph~hyl c,J,cr
21164
0164
12 - J80
...
III
...
--... 00.
'-' ---
4·Methylphctlo! _
""-
.. I .00
... ... ---
45164 8.8 - 230
.-
75 --- --. --. 100 10/45
4·Nitroanihne 0164
-- _.
00-
---... -. --. -- _ ..
4·Nitrop!tcnol
bi,(2 -Ch loro<thoxy)m clh.tle
0/64
0164
--- "-
--
---
...
h i5(2 -EIh y Ih" YI)pl1tl\.I .. e 4'164 80· 3JOOO 4,370 ... ... ..- ! ! -_. ...
...
00-
--- 140
98
.- ... _.
00-
,
..-
...
, --
00.
!
6
6
5!~
...
!
,
Di-n-butyl
Di-n·o<;"lohlh.I."
phthal.'e 11M
0164
140·
---
140
'-'
---
---
--
... --
---
-..
... I 58
61
1/1
I
---
Pag-e 2 of7
TIERRA-B-014937
T.blet
SummaI")' of Chemin I. D<I«led In Sediment S.mpl.,In the VklnlfJ ofSA7
Study A.... 7; Jeney Cll)', NowJon.y
_.
1.3 ..-
0/64
'- ... -- --
.-
Hc-XfIr;hlorodhane
hC)phoronc:
0/64
1/64 420 - 420
... ...
_. _.... ---
...
...
--- I
73
...
._.
.- .
Nilroben;rene 5/64 26 • 2~0
420
123 -- _. -- ...
I
I
N- Ni'lro"lo-ili ~l'l-propy lflmi n e 0/64 .- --- _ ..
-- ... ...
21
..-
5/~
---
N ·Nit rosodiphen yl am i n e 7/64 18·440 -. i
--- ...
Pel11achloropneflo( 0/64 ._.
171
-- _. '"
-- :
-- _ ..
28
17
617
.-.
Pflcnof 0/64 ..- -- ._. --. I
--. --- J 30 ...
:1 I
Pulv[v,l!, Arom.t1,""""ij;dro,arbom no/l, ;
1-Chloron.apl1thalenc
2·Moclhylnaph:hnlcllc
0/64
51164
...
12·4900
.-
316
_ ..
70
..-
3D/51
I
!
--.
670
._.
I
--- --- !
I
5/51 64 3}J51
Ac(:nephlhene 5~J64 8.9·11000 873 16
I !
~3J55 500 IS/55 130 26/55 I
Acenaphthylene ,
57/64 8.6 • 4700 480 44 53/57 I 640 12/57 71 52/57
Anthracene 57/64 28· 10000 1,~56 8~ 53/57 ! 1,100 17J~7 280 37/57
Ben~o{:J,)n.nlhrll.cene 59164 34· 16000 2,362 261 53/59 1,600 22159 960 34/59
Benz.o(a)pyrene 58/64 30·8800 1,574
Benzo(b)nooronlflcn< 58/64 19·5200 1,212
430
...
48/58
... _.
1,600 19/58
--
1,100
1,800
24/58
13/58
Benzo(8,fl,i)pc'Ylene
BcnzQ(k)nuClrflnlhent::
58/64
58/64
16·2600
27 - 6900
641
1,511
170'
240'
51158
53/58
-.
._-
---- 670
1.800
19/58
16/58
Cnrysene 59/64 <10• 20000 2,780 384 52/59 2,800 17/59 950 39/59
Dibenzo(n,h ),flnlhr8ct::nc 49/64 20·880 266 63 45/49 260 18/49
Fluorantl1ent:: 230 19/49
58/64 34 - 18000 3,837 600 471~8 5,100 14/58 l.3oo 32/58
fll,lorene 48/64 8 6 . 4600 5t4 19 47/48 540 10/48 12lJ 21148
'ndcno{ 1 ,2.3-cd)pyrem: 58/64 l3 • 2300 596 200' 48/58 ... ... 600 20158
Napfl'h.lene 54/64 18 - 10000 1,310 160 42/54 2,100 9/54 230
Phen.nthr~ne )5/5~
51164 2\ - 18000 2,219 240 ,
42/57 1,500 IS/57 660 24/57
Pyn:n~ 58164 65 • 28000 5,lt~ I
665 ~IJ58 2,600 27/58 2,400 29158
Df:&f!;cl-ili" 'jj,,/k·,"';.; I
4,4'-DDD
4,4'-DIJE
521136 11 ·76000 16,964 ... _. 20 48/52 16 49152
70/136 12· 820000 42,088 2.2 69no 27 63no 9
4,4'-DDT 69no
121136 13 - 110000 18,972 I 12112 7 12112 12 12112
Aldrin 0/94 .- ... 2' _ .. .-. ..-
alnh.·RHC I 9.5 ---
5/94 12·38 2J 6' 515 ! -.. ... I
I --- ...
Page 3 of7
EN"IRON
TIERRA-B-014938
Tabl. t
Sumnulry or Chenlka:1.s 1le-lecC'~cI in Sediment SAmples in the Vidnity o-fSA 7
Study AN'A 7; Jf'n~)' Cit" NrwJene)'
Parson:!
Paso 4 of7
TIERRA-B-014939
T.bl.1
Sumrt1a~' afChemlC'ah: D.trl"totd in &:d;ment Samples tn the \1dnffJ urSA 7
Study A5'ea 7; J~rsIl!J City. N~w Jen.~
OCDF 5g;68 _.
15.5·25560 1,559
_. --- _...
. ... ---...
Tol.1 TCDF 53/68 41·11800 1,188 ... _.
Tol.1 PeCDF 55/68 1.6.1· 9180 756
_.
... _. _. ...
...
... ...
Tol.1 fi,CDF 56/68 2.54· R780 ... _. ... ... ...
Tol.1 HpCDF 61/68 1.57·22510
678
1,196 _. -- _. ... ... ...
Fol '-chlorinated 0' llen ....ls (.-..1 .......
PCB·156
PCB·Il7
43164 37 I ·23300 2,Til --- _. .-- ... I ... ...
37164 9.24·5190 599 ... ... -- ... I --. ...
PCB·167 41164 15.3·89l0 aS4 ... -. ... -_. ... -..
PCB·J69 7164 1/.1J6 -1/7.3 27 --_. ... --. ... -- . ...
PCB·l70
PCB·IRO
45164
49164
915 - 43100
7.85 . 103000
4,950
11,723 --. _.--. ..-
... '--
...
...
'--
--
.-.
.
PCR·1S9 341M 10.2 - 1600 257 ... ... --. ... ... ._-
Totol monoCB 47155 )2) ·11500 1,653 ... -.. _ .. ... ... .--
Totol diCS 48115 R.4 . 208000 20,351 .-- '" ... ... ... ...
T"l'!oPIIIMCB 47/55 5.-16· 1910000 117,257 ... ... -- . ... ... ...
Tol.RIldrRCB 491S5 )0.4·4010000 211,514 ... ... ... ...
Tota! pel'1lll;CB 43155 75.2·2320000 161,466 ... ...
'"
..- ... - ..
---
Tola! I1cxaCB 41155 2~.4 . 1010000 9.1,DI0 ... ... ... ... ... _ ..
TOI.I '"pl.CB 4015l l3.1 . 3891100 44,466 ... ... ._- ... -.. .-.
Total actaCB 36115 104. 101DOO 19,237 ... _. '" ... ... ...
To-tarnonaCB
Totnt decRCB
36155 nl·11400o 10,082 ... .-- -.. ... --. .-.
38155 59.2 . 42000 5.013 ... ... ..- _._- ... .. -
'"
P.ge 5 or?
f. N \ I I< () N
TIERRA-B-014940
Table'
SUtnmAry ofChemk"l, D("tr-c.~d In Sedim!'llt Samples Intlull Vldntl)' ofSA1
Study Ate'll 7~ Jeney City, N-ew J.crny
I
RJonge ERL ERL ERM
Chrm't"ol!l
Drte-efron A v~Ntgl" DIPtrlL"tfd ERM NOAAAET
of (NJDEPI E~('r'!dM(t (N.IDErl NOAA
Frt'qut",y Con.('l!'nrnU~nn E:s::ctedanc-e Exned;l,n('1!
Ol;!fl'ctlon NOAA) Frrqu-tnC'y I AET
NOAA) F~qth"f1(} Fre'luf'n('y
Arodor rm!tk..l
Arcx.11.lI'·IOI6 0172 --- --. _. ._- --- --. --- _ ..
Aroc lor-I 221 0172 --... --. --- --- -_. ... ... -_.
Arrx:.lor-1232 0172 --- -- ... ... -- _. ---
II.roclor-1242 0172 ... --- ... ... ... --. ._-
A.roclor-124R
Aroclor·1254
37m 46·960 260 ---
'"
-.. _. ... - .. .--
20n2 48-no 289 ... --- --. --. -..
""-oclor·1260 Isn2 46·420 191 -- ... ._- -_ . ---
--- ---
Pl:Ji"fDNlmillltlte-a Oinntn'l'l th .... 1",,191
BDE·I
BDE-2
221M 17.5·693 193 ---_. _. -. --- -.. ...
17164 _ ..
1l.2 - 439
--.
_....
148 ---
BDE-3 31164 ...
BOE·7 42164
9.n·1380 ]~5 --- ..- -.
_ ..
"- ---
1j5·1160 242 --- ... ---
BOE-IO 14164 103·14.8 4.9 ... ... --- ---
BDE·D --- --- ._. - ..
32164 ._. -_.
BDE·15 53164
0.646·283
0585.4QOO
54
351 .-- _.--- --
---
--.
--- ...
BDE·I? 40164 273·1['10 31Q ... _. _._. ---
.--
.--
8DE-25 7164 3.34 • 45_2 12 -.
_. _._. --
... ...
---
---
BDE·28
80E-35
44/64 3.2 - ]16 85 _. -.. --- ...
BDE·47
15/64 1.27 ·107 ]5 --
_. ..- ... --- ... ---
I
I
BOE-49
64/64 343 . 6460 630 ... _. ... _ ..
---...
,
4]/64 2.9·3070 634 .-. ..- '" --- ...
BDE·66
8DE-75
31/64 HI ·234 67 --. ... _.- -.. --- ---
28/64 l.Ol - 501 --.
BDE·n
134 --- -.. --- ! --- ---
80E·85
7164 O.63~ - 896 2.7 ... ... --- '" --- '--
_.--.
32/64 3.56·189
BDE-99
34 --- '" _.- -.. -..
64/64 31~·6550 597 ... --- ... ...
BDE·]00
8DE-116
62/64
7164
727·1480
682·29.6
j 12 _ .. ..- _. ...
---
-.. ---
13 --. ... .-- ... ... ...
BDE·126
BDE·138
7/64 2.13 ·9.97 4.1 --- ..- --. ... .-- ---
BDIO-IS3
10/64 5.49 ·120 37 .-- •.. -.- ... --- .--
BDE·IS4
36164
36/64
IU -1120 273
_.... ... ... ._. ... --.
7.52 - 936 --. _.
BDE-155 19/64
210
...
... --. ---
BDE·IS6
BDE-ISI
7164
338·107
3.74 - 42.9
42
10 _. _.
'" ...
--.
..-
...
---
_ ..
--.
---
7164 4.57· ~l 16 ... -- . --- --. --. --.
Page 6 of7
EN\!RON
TIERRA-B-014941
Tablel
Summary of Chfo..nl<'Rls Dthchd In Sediment S.mple-s In !he Vicinity of SA'7
Stud)' Ar~a 7;. Jeney Ch;y, New Jrr.sey
80E-183
80E-197
38/64 10.4 ·4940 803 ..- _.-. -. _. .. _ ..
_....
.
33/64 7.l;S • <930 676 ...
BOE-~03 ... ... ...
32/64 1l.l·1910 609 _. ..- ... ...
RI'lE·207 ... _. ...
8DE·209
36/64
~2164
28 . 6980
178·291000
2,U17
59,384 ... _. _.
'" ... ... ...
Tolal Mono-8DE _. .-
_. ...
_.--.
'-'
32/64
TOlal Di·BDE ~3/54
12.1 • 1550
0.936.4190
~40
... -. ... ...
TOlal Tri·BOE 45154
832
... _. _.... --. ..- .--
Tot.1 r'ITa·SDE
3.25 . 3780 1,005 ... ..- ...
64/54 34.3·11500 1,890 ...
_. -- .
_. -. ... ... _.
Tolal PenlA·ODE
Total HexA.BDE
64/54
35/64
387. 8520 806
_.
... _. ... ...
19.6·2950 775 --. --. .--
T".I Hopl.·BDE 38/64 _. ...
... --.
r".] OeIA'SDE 34164
IOA·6580
931 - 8930
1,178
2,212
_ ..
-. _. _. ...
...
-- . ...
._-
TOlal NonA-BDE 36/54 zg • 13500 4034 --. _. _. ...
---
... ._-
~
New Jeney Dep.artmcM.1 of Ern:uonme-Illal ProLcction (NJDEP). 1998, GuidRl1ce [c)r Sedimcr11 Qunlity EVIl!uilIliQns. November.
Buchman, t\ltF" 1999. NOAA ~t:n:cniJl8 Quick ReferCDit~ Tablc~. NOAA HAL MAT Report 99-1 .. Seanle: WAf C08:5l..ldProteclion
IInd RestotAtion Di"i~ion. Nallon,l O<:eanic and Atmospheric AdminislriItion, I Z pllgt::.~
Note"
An .anlll)'~es Are ba,~d on V.fl:lid.aLll:d dota from rnc October 2003 Lhroug.h JOfllla.ry 2()04 field sampilnB evc::nb and from the 2002 Rc:mc:dial Invcslisstion .Report pl'"l:pnred by Tetl1l- Tc:t;h.
HeXIIYfldent r;;.f'lromium 8nalY'5-l:s were cDnducted by 1wo analytical mcthod.~(1196A and 1199) following ex.lfa.clioo by !\l,IO rntlhods (NJDEP and EPA).
ERL ~ Elfocll Ronge Low.
ERM • ElfeclS Range Medium
NIDEP New )c!'1ey Department of Em'ironmC'nral Protcction.
:>::
P."-on. ...
Page 70f7
TIERRA-B-014942
Tabl.2
Summ3ry orChemh:als Doete'Ct~din SrolnH~f\t frum 0 to O.!i rt Bfllo'W Mudline-
Stud)' Arl"l 1; Je-rsc)' City, N~'W Jerw)'
I
Rgnge
Det(lctlon A "tra~e Dl@:tt'cled
Ch~mlC:lI~ ERL (N.lDE?1 ERL E~c~edal1ce ERM(NJDEPI NOAAAET
Frequency
of ERM EUf'rdance NOAA
ConcenlralJon NOAA) Frequehcy F.:lc('ed3nr-1"
Delt:dlon NOAA) FrE!CJuency AET
Fr~qll'l'f1-('j
.... t.I~-~ m~k"'
AI\.Irruoum 40140 2380·\4700 7,~4S -- -- ... ...
Anlimony
Ar'\cnic
1140
40/40
2.3 - 2.3 2.3 ._- - -- _. ...
9.3
.- .
WI
Barium 40140
lA - 113
9.1 • 3~5
17 8.2
- _.
24140 70
... _.
2140 3S 4140
BCl"yTlium
Cadmium
39140 0.11 • 0.97
112
O.S _. -- - -.
4g
...
31140
---
38145 0.14-8.1 J.5
Calcium
1.2 15138 9.6 0138
40/40 34S·37OO0 .. 3 4138
Chromium 115149 7.4 - 14200
6,643
824
_
- - -. ... .-.
81 10011\5
Hc;uvdcJlI Chromium NIDEP 11%A
Chromhln'l NJDEP 7199
0145 - -.. -- -..
370
._-
SO/Ill
... _.
62 1041llS
...
Hcx~vllenl
H,,, .. I.n' Chromium EPA 71% A
30/45
0/4l
0593-
-
11.3 3.7
.- _'--. .-
.-
.- - ... -
Hexav.llenl Chromium EPA 7199 3414S n ... ... - '" ... --.
0.744·12.4
... ._ . ... ---
Cobal,
Copp.r
40140 2.4·21 7..1 .- -. .- - 10
41145 6140
Imn
L••d
40140
6.4-715
5310 - n900
119
20,051
34
... _.
32141 270
...
3/41
-
390
..-
2141
...
411130 7· 476 122 47
M.l,gne.~il.lm HI41 2U 6141 400 1/41
Manganne
40/40 1250- 9190 4,825 - -- ._- ._. ... ...
Mc:rcliry
40140 l16·520 269 ... ... ... -. 260
411\26 0.041·64 6.2 24140
0.15 35/41 0.71
Nick<:] 41/45 29141 041 3214\
16·120 26 21
PQI .... sium 22141 S~ 1/41
40140 ~9S. 2600 ... 110 1/41
S-clcnlum 3140 2.7 - 3.7
1,349
_ .. --
...
--- -. ... ...
Si~ver 35/40
3.~ ..- ... 1 31)
0.44·8.8 2.3 I
Sodium 25135 3.7 41H
40140 3.1 7/35
Thallium
HI·9360
-_.
4,243 --- -.. .-. -.. - ..
0/40 ... ...
'"
.-
Vanadium
Zinc
40140 5.8 - 98.5 26 _. .-
...
...
...
._-
...
S7
.-.
41145 19.2-842 231 2140
150 24/41 410 6141 41 D 6/41
~nntj"'~ u-/ko"
LL
Dibulyllin 17140 19· 14 ... -- -- - -. ..-
MQnoburyllin
Te'r~bl,Jtj'l1in
5140
5/40
1.2 -2
2.6 ·S.4
1.6
B
--
...
~
._.
-..
...
.- ... ...
Tribu'l'hin [6140 1.9· 19 ... .- --- ._-
I 6.3 --- ... .- -.. -..
'I
Page 1 cf7
TIERRA-B-014943
Tabl.2
Summary orCheml"ab Delectocd In Sf'dlrnent from 0 loO.S n Be-low Mudllne
Study Aru 1~ Jersey City, Norl'l'Jrr~)'
Chemll'Bls
Detection
Freq.u'C'nq
RAnge
.r
Detfctlon
A yerage D~tectl!d
Conuntratlon
ERL(NJDEPI
NOAA)
ERL E:toCwibnc-e
Frequency
ERM(NJDEP/
NOAA)
ERM. Enroedancc:
FreqQ~nC"y
l-=;l
I
NOAA
AET i
NOAA AET
EH'I:,:dancc
Fr-equenry
Di'n-buryl pht""I"<
0141
1141 140· 140 140
_.
_. .-
--.
--
'-
6
,
511
...
[)j·n-o<",loh'hal.'e 0141 - -. -- ... .-
18
61 i
III
---
Page 2 of7
£N \"1 H 0 N
TIERRA-B-014944
Tobie 1
Sumrnuy orCh.emkal!§: Deote<:te-d Ih S~dimenl rr-ll'm 0 (0 Q..S n. Bflow MlJdUne
Study Area 1; Juse-y City, N("w J,crsty
DetecUon
Range
Chemical!! Av-enge Detec(ed ERl.{I'IJDEP/ NOAAAET
FrE:qul;"ncy
or ERL EJ:teedlnce ERM(NJDEPI Emf Enttdlncl' NOAA
DeilecUcm
COr'lcentrltloh NOAA) Frequency NOAA) Fr-equllnc)' ExclN'dancc
AET
}o"rrqueon(')"
I
I
Hexachlofobenzc::m:: - .-
0/41
._- -- - - --..- 6 ..-
I-Ic:-r.a(;hlorobulildi",C' 0/41 - "- - -- ._-
Hc.'( a..:hl orocyd open
J Ie;\; Jeld orocth~ nc
tadic:ne 0141 -
---
-- .-. -- -- -
13
... ---
0141
'-- --- -- .- --
I$QphofOnc
NilfDbe:nz.cne
0141 -- -- ---- - - ...
73
---
---
...
N· Nitroso-di -fl- "propyl .:limine
3141
0141
26·250
..-
142
- ... -_ . ---- ._-
.-.- 21
..-
]13
Plilr~ORS
Page 30f1
TIERRA-B-014945
Tabid
Summ.lry .,rChemlulll O-ettl::ted in Sediment from 0 to 0.5 n Btlow Mudline
St.udy Area?; Jer!licy City, N~w JeI'H~·
Range
Dt'teclhm A verBse D~ttcted ERL (NIDEPI NOAAAET
Chemical'!i
Fr~qurnt'y
or ERL E".edance ERM(NIDEPI ERM E.x:c:,.~d .. n-ce-
Concentration NOAA) Frequency NOAA) Exce-edBnu
DdtUion Frt:'quency AET
FrNlupnry
~
bela·BHC 1/71 20 - 20 20 S" III ... - - ._-
Chlordane 0141 - '- 1l.5 - _ ..
del.a-BHC 0/71 ... .- - -
6
- .'
-
---
2.8
_. ._.
Dicltlrin sm 14 -20 17 om SIS 8 SIS 1.9 SJS
~ndosul(an t 11171 3200·37000 12.382 - .- --- -- _ .. ._-
Endosulfa.n II 0/71 - ... - - ... _.-
Endosulfiilfl ~ulrnc 1/71 4900· 4900 4,900 _. - .-
--
- ...
_.-
...
E"drirt 6171 19·24000 12.003 3"
._-
616 .- .- ... ...
Efldrin aldehyde:
Endnn ketone
4111 19· 140 Sl
...
.- .- .- ... ...
11171 8.2·64
_. 29 ..- ... ... ...
samma·BHC
Hcpla<:Wor
eLinda"e) 0171
- 3"
...
.- - -
"
4.8
.
---
Hepl.ad\lorcpoxidc
2/71
2/71
13 ·62 38 ...
- - 0.3 212
Methoxychlor 7m
IS·140 78 S·
_.
212
- - _. .-.
TO~llIphcnc 0/11
13 - 210000
-
35,874
... -
- -
-'- ...
...
... --.
...
".
;
iO~'IU .nd l"tJran I [nrlJ~\
Di<:lxins and Fur.;)n~ TEQ"'''' 37137 1.3·82 16 .-. _. .•. ... 3.6 24137
:
i
2,3,7,8·TCDD 36139 2.47 - 13S0 127 -. - ... ... ...
I.2,3,7.8·P,COO
1,2,3,4,7,8·H.'CDD
17/39
IBI39
0,9S3 • %.2
0,965·40.5
93
8.•
-
...
_.
...
...
-
.-
...
...
...
... I
l,2,3,7,8,9·fhCDD 22139 0.451·75.2 14 _. _. '" -
.
...
_- ...
1,2,3,6,7,8-H.'CDD ...
00.
l, 2,3,4,6, 7 ,K.HpeDD
25139
37139
0.773 ·In
10.5 ·139ll
25
...
00-
... -
...
... ... I .. '
279 ... ._- ...
OCDD
1'0,.1 TCDD
38139 90.1·12370 2,738 - - ... ... .- I _ ..
To'al PeCDD
36/39 2.47·1520 IS3 -
...
- .- ... ... I
_.
..-
26139 9.61·304 54 - ... -.. ... !'
Toll' f{,COD 35/39 5,09· llGO 176 ... ... ". ... --- i -_.
T o,alllpCDD
2,3,7,8-TCDF
37/39 24.4·4IS0 706 - - --. ... ... I --.
J.2.3,7,8,PeCDF
31139 0.906, 491 36 - -
_. ... -- ... ,
'"
30139 0.993·31 S 35 - ... ... - .. :
2,3,4,7.8,PeCDF 30139 1.53·421 52 --. ... _. ..- ...
---
...
1,2,3.4.7,8·!1xCOF 36139 S.99· H2O 356 -. ... ... .-- .-.
...
00-
Page 4 of?
EN \ l RON
TIERRA-B-014946
T.bl~ 2
Summary ofCh"mi-cah. Dl't-ec:ted In Sedi",~l1t from 0 loO.S n l)oe~o", MucJlioe
Stud)' Aru 7, Jct3i'f)" City, New Jer:!'eY
Range
Deh:t"tlon Avpr.g~ De-tKh·(j1 ERL(NJDEPI ERL E~cetdan(e NOAAAET
Chemicals of EAA1(NJDEPI ERM E:needllnc~ NOAA
Fr-rque-ncy Corll;~ntrallon 1'IOAA) Frequency EHf('d;lOn~
Dett'ctiun NOAA) Ff('q\.i~IlCY AET
Frpqll('n-C'~'
Copl.n.r
PCB-77
PCB, TEQ"" 37/l7 6.9·1110 IS< 22,700 ... 180,000 ... 130,000 ---
35/39 635·28700 l,002 ... - ... --
_. .- ---
PCB-II 29139 5.22 - 2150 310 - _.- - --- _.
PCB-IDS 36139 14J·528oo 1,041 - - _.- - --
PCB-I06/lll
PCB. I 14
31139 62,9· B3000 18,910 - - --- _ .. _.---
30139 6.69 - 3640 110 '" -- - .- .-- ...
PCB·123
PCB·IIG
30139 7.18·3150 411 - -- _.- -- ... -
PCB-ISo
22139 10,2 - 512 156 - - _.
'- ---
34/39 37.1 ·23800 1,412 - -- ... ... .-- _.-
PCB·IS7 29/39 9.24 -1060 4iO .- ..- - ..- ... ---
PCB-167 33/39 1S.8 • 3590 781 --- -. - -- ... _ ..
PCB-169 7/39 9.06 - 97,3 27 - ... .-- --- ..- ...
_.-- _._.
Pell·PO
PCB·Uo
35/39
36/39
91.5 -18200
242·42700
4,106
--
--. -
...
--- ---
PCB-lX9 26/39 10,2 - 678
10,391
2IK _. ... ... ---
---
_ ..
---
..-
TOlal monoCB 2&/36 J2,J. iSIO 1,722 ... ... ... .- -- --.
Total diCB -_. -
Tolal triCB
21/36
28136
174-187000 20.165
... .-
- ... --... ---
TOial r.erraCB
212 - 1160000 98,S19
_. -- .- ...
To"l penlaCE
28/36 760 - 2030000 l81,026 - ... .-- ... ...
28)36 321·1050000 126,136 "0
--- -- ... ---.. --
Total h ... CB 28)36 126· 411000 74,727 _ .. _.
0--
--- _
...
To"l hoplaell 27/36 263- 163000 37,524 -. - - ---
TOT.!l oc!.lCB 27/36 104·46900 13.nO ... - -_.
.0.
_ .. ---
...
Total non.CB
Total del.:.CB
27136 97.1 - 53000 6,408 --
...
- --- --- -..
27/36 592·42000 4 l42
--. 0.-
Pagel of7
EN \' l R ON
TIERRA-B-014947
Table 2
Summary QrChemlc:::.ls Ddectnl in: ~dilnen{ from 0 lolLS rt Below !\1udline
Stud)' Aru 7; Jer!€!y City, N~w Je.r5oeY
[)e1.cUen
Range
Chemful5 A¥''t'r-agt! Drtrt'tl:'d ERL(NJDEPI ERL [:[ceedante ERM(NJDEPI ERM Excc-edan(f' NOAA AET
of NOAA
Fr~qufnC"y C'On.centration NOAA) . Frrqut!"ncy NOAA) EHl!pd,ul ....
e
Detectlun Frt'qu~'1C-Y AET
Frequ-fo-ry
.'oclor ""Ik.'
_-.
Arodor-l0 16 0150 - -- ... . .- ... --. ...
Aroclor·1221 0150 -- ... .- --. ... _.
Aroclor·1232
Aro<lor·1242
0150 -
_. •..
...
...
...
- - ... ...
---
...
0150
.- - _. ... ...
Aro<l or· 1248 25150 59·720 ... ... ... ...
Arocl~r·1254 12150 48·420
215
232 .- ... _. _.
---
..-
...
...
Arocl.r·1260 15/50 67 - 370 174 ._- ... .- ... ... -.
"~I·br~ .. I".I.d Dlnh •• ol "[he" 'n.I.'
BDE·l Im7 27.8 • 693 203 -
_. _. -
BOE-2 11137 17.S·255 S7 .- _.--- ... -_ ..
-- ...
BDE·) 23131 15.6· 812 2S0 - - -
_. _. .- _.
BOE-7 )4137 ),77·1160 233 - - .- .- ...
BOE-IO 12137 1.03 '14.8 5.4 - _.- - ... .-
BOE·I] 25m 0.646 -160 37
- - .- ...
'--
-.
BOE-IS
BOE·17
36/37
33/37
3.4)·2580
4.42·1190
306
297
_.- -
.-
-
~ -
...
...
...
...
BOE·2S 5/37 ... -
---
BOE·28 34137
3.34 - 45.2
3.39·301
IJ
19 _. .-
-
- _.- ...
...
...
BDE·JS 13137 1.21· 107 39 - i - ... _._ . ...
--
...
BOE·H
BOE·49
37137 90.1 ·6460 869 .- - ... --. ...
34137 5.S • 2540 568 - - ..• ... ..-
BOE·66
BOE·75
24137
23137
4.11· 234
1.01· 389
66
117
-
-
.-
.-
.-
...
...
_. ...
...
---
---
...
BOE·n 5137 0.635·8.96 2.S -. - .- .- ... _.-
BOE·~5
BOE·99
24/37 6.44· 189 )7
- -- .- .- ... ...
BDE·IOO
37137 94.8 ·6550 842 - - .- '- ..- ...
37137 2J.I -1480 203 - - .- '" ... ..-
BOE·116 5/37 7.1I ·296 13 - .- .- .- _ ..
.-.
BOE·126 5137 2.26 - 9.97
- - - _ ..
BDE-D8 7/37 S.49·78.9
4.2
34 -- .- -
-
.- ...
._.
...
llDE·ljJ 28/37 [7.3 - 1120 262 - _.- .- .- -- --.
BDE-1S4
BDE·lI5
28137 11.3·936 206 -- _. _.- .- ... ...
14137 3.81·107 44 - _. .- ... ---
BDE·l56 5137 3.74 ·42.9 13 - - .- ... .-.
BOE-li[ 5,37 7.36· 51 21 -- ... ... '"
Pas·60f1
TIERRA-B-014948
Tabid
Summary of Chemicals Detee-led tn Sediment from 0 (0 0.5 n Bi:low MudUne
Study Area 7; Jersey City, New JerleY
Range
DetE."dioll A veta@e Df'leded ERL(NJDEP/ NOAAAET
Chemical' or ERL EuredarlCof ERM(NJOEP/ ERM ElCt~anc-(' NOAA
FU'qufncy COl1ci;"ntrlHon NOAA) Frequeru;y E:t:e~!!danc:t"
D~tectlon NOAA) Frt'qlll1ncy AET
Fr-cqbtflCY
BOE-183
BOE-197
30/37
26137
18.3 - 4940
12.5 - 2780
640
574
-
--'- -
---
-
-_. -- ---
---
---
---
OOE-203
OOE-207
25/37 11.l-15~0 536
---- -
---- - --- ---
60£·209
29m
35/37
7004.5740
2070 - 291000
1,793
65,442
- --
-- ----- ---
TOI,d Mono~DDE 24/31
---- - -
-- --
To.al Di·BDE
19.2 - J650 437
_. - -- ---
36/37 3,43 - 2830 828
-- - -- ---
T 01.1 T ri·BOE 34/37 4.42·3360 914 -- - _..- - --- ---
TOlal Tetra-BDE
Toeal Pc:nt.l·BDE
31/31
37/37
100·11500 2,398 ---
_. - _.- -- ---
Tot.IIl".-60E
118 ·8520 1.120
_. - - -- -- --
TOlal Bcpta-BDE
28137 19,6 - 2S20 70S
- -- -
_. -- .-
30/37 18.3 - 6450 922 --- - ._-
--
_.--
To .. 1 (kla-BDE -"
To"'l Nona-ODE
27/37
29/37
14,5 -7080
70,4 - InDO
1.852
3SSJ
-
_. - --- -.- '-
- '- I .-
Sources:
New Jeney Dcpanmcnt ofEIll,-irQM1cnlal Prorecllon (NJDEP). 1998. GuiWincc fOT Sediment QWiljty Evaluations. No ...ember.
Buchman. M.F., 1999, NOAA Sc~ning Quick Refete:nc-c Tables, NOAA IIllZ.MAT Report 99~11 Scaule WA, COUlaJ Profeclion
;a.,d RUCor:iIJonDivi.sion, National ate,amic and Almospheric Administration, 12 page"
NOlot1:
AlI..Inalyscs are based on validilled dar, frorn Ihe Ottober 2003 lhro-ugh J.anua.ry 2004 field sampling e'toi~rs illDdfront the:: 2002 Rcmr::cli.aI Invc- .. tigation Rcp-or1 prepared by Te-ln. Tec::h.
Heuv:dcnl chromium analys¢., were f;Qnduf;tcd by two an,IYlit,l1 melhods (7196A and 7199) following extraction by two method" (N"IDEP and EPA).
ElU. • Elf"" Range low
ERM ... Effe(;tJ Range Medium.
NIDEP'" New JCf!lc)' Dep.arrmenl ofEnvironmcntaJ Proleclinn
NOAA = N.ation.:d OcurUc .Ind Almospheric Adrninhllration.
AfT - Apparenl Eff-t.;ts TIu-C'shold.
EPA -= UhJ.lcd StalC5 EnvironmenlaT Prolection Ag=-n-cy.
mglkg .. Miligram!l: per kilogram.
uglkg ~{i<:ro&ram~ pet kLiogr.ilm.
1:t
PatwlI~
Page 7 on
f:NI'J fH)N
TIERRA-B-014949
Tablo 3
Summ • ...,. ofChemlt'ah Ddrded in Scdlmtnt from ch.e Rrrrrence Are&!.
Su'ldyAr~~ 7; Jenry City. Nnv Jenr)'
M~!ah (mp/Lp':
Aluminum
AntLmony
6/6
0/6 _.
8500·14600 10.642
.-
...
.-
.-
.-
.- '-
...
... ...
~enic 6/6
'"
9.3 ...
8·24.8 14 8.2 5/6 70 0/6
Barium 35 016
6/6 98.6·127 113 ..- .- .- .- 48 616
Beryllium
Cadmiu'ITI
6/6
5/6
062·0.93 0.7 .- .- _ .. .- ... ---
0.27· 4.5 2.0 1.2 3/5 9.6
I 015 3 115
Calcium
Chromium
6/6
616
2680·6930
122·227
4,732 -- .- .- --- ... _ ..
167 81 6/6 370 016 62
Hc:<ava!cnl Chromium NJDEP 71%A 0/6 ... .- .- .
_. ... ... ...
6/6
H«a ..alcnl Cnmmium NJDEP7199 4/6 1.09-11 4.6 -.. ... ... ... ...
.--
...
...
Hexa ... lenl Chromium EPA 7196A
Hex.valent Chromium EPA 7199
0/6
6/6 0.903·5.9
.--
2.5
...
... --
.-
.-
...
---
.--
...
...
.-.
...
Cob.lt 6/6 7.6· 11.3 9.2 .- ... ... ... 10 216
Copper 6/6 90.1 - 176 132 34 6/6 270
Iron
Lead
6/6
6/6
20600·31700
99.6·225
24,667
158
.-
47
.- .-
0/6
0/6
390
.-
016
..-
6/6 218 1/6 400 0/6
Magnesium 6/6 4700.8\00 6,050 .- ... _ .. .- ... ...
Manganese 6/6 263·516 356 -_. -- .- .- 260 6/6
Mercury 6/6 1.2·5.5 2.7 0.£5 6/6 0.71 6/6 0.41
Nickel 616
6/6 22.7·44.2 33 21 6/6 52 0/6
Potas;sium 6/6
_.
1540·2340 1,843 ... ... I
I ..- --
liU
. - 0/6
...
Selenium 0/6 .- ... '- .- .- 1
Silver .1/6 0.6.1·33 2.3 1 4/5 3.7 0/5 3.1
'--
S"dium
nallium
6/6
0/6
4040·10800
...
6.917
.- .-
.-
.-
...
._-
...
...
...
"-
2/5
...
... --.
... .-
V.:nadium 6/6 22.9· 38.7
Zine
29 -.- ... 57 0/6
6/6 200·4fi6 333 ISO 6/6 410 3/6 410 316
n_$I;'lcti .. " 'u"Jk"':
l1JlL
Dibulyllin
Monobutyltin
4/6
.- -- ... --. ...
Tetr.butyllin
0/6
0/6
.- .- .- _ .. ...
... ... -_.
I -.-
'"
Tribut)'hin 4/6 .- --- ... ._- ...
Pag-e I of?
EN\lRON
TIERRA-B-014950
•
Tabl.3
Summary oFChemicaIs Dete('ted In ~dirrlfnt from «hot Rder~n('e Are-a
Study Ar~1l7~Jenty C'ry, New Jeru'y
1,4·Dichlorobenz~nc
2,4.5- Trichlorophcnol
3/6
316
19-35
33·100
_.
26
75 .- -_.
.-
---
---- ..-
110
---
0/5
-.
.-
_.-
.- ..- _.- ..- J
0/5
---
2~4~(j.Tricl1lorophenol 016 .- _. -_. I
---- ...
2,4-0iehlorophonol 01. -- ... ... .- --.-
6
...
2,4-Dimelhylphenol 015 ... ... -- 5
2r4~Di",itrophcI1Qt
----. -.. .- .- IS ---
0/6 .- .- .- ..- ...
2,4-Di.il(otoluene
2.6 ...Di:nilr-olol1.u::nc
015
0/. _. .-
-- ---- ._- ... ._. ---
... --.
2-Chlorophenol _. --
...
...
-- --- --- ...
2·Methylphenol
0/5
0/5 _. --
... -- --
_ ..
---
_ ..
8 .-
2.Nilro",nili.nc 0/. _. -- ---
.-
--- --. ...
8 --.
2·Nilrophenol ... .- ... .-- --.
0/.
.- .- ... - ..
3,3'· Diehl OT'Obcnzidinc
3-NLlro8nil~c
0/. -.
-.
.- .- .- _ .. !
.-
'"
--- --.
4,6- Di n;I,o-2-methyl pheno I
0/6
-.
-- -- ... -- ... ... --.
0/.
...
.- -- -- -- -- .-
4-Ch loro-3 .mclhylphcnol 0/6
- -- .- .- --- .-
._-
...
4--Chlorotlnilinl:
4-Chlorophcnyl pbonyl olber
4/6
016
_.
57 - 280 127
...
--
.- .-
--
._- .- .- --.
.-
.. -.. ... ...
4·Methylphcnol
4-Nitroanilinc
616 52- 1I0
...
74
.--
---
...
.- _
... 100 1/6
015
..-
.- .- ... ... ...
4·Nitrophenol
hi. (2 -Ch Iorocl h oxy )mel h 'no
0/6
_. ... -- -_. "- ... ._- ---
._---. ...
0/6
his (2 -Ck Ioroclh yl loth., ... '- .- ... --- ...
0/6
-- ... ... --- ._- - ..
bi. (2·Ch loroi,opropy I)elher 0/6 ... .- .- ...
bi, (2· Elh ylhexyl Jphth .181c 6/. --.... --- '" --- --.
Bulylbenzyl phlh811te 015
250·
_. 5800 2.130 .--
-..
...
.-
. - -.. - ..
Carbazole 616
'"
.-
,
.- ... -- 53
S8·390
--
'--
194
Dibcnzo[unn
... --- -..
.---
5/. 42·2100 709 --
.- -"-..
Diethyl phlhll.te 0/5 --- ... --
110 216
Dimethyl phlh81lte 016 _. --. ... I
... _ .. 6 --
Oi·n-'utyl
Di-n-octvl
phlb81a1e
ph/h.llle
0/. ... -- .-
I
-..
--
-- -- •
53
._-
---
0/. o..
--- --- .- --. 51 ._.
P8se 2 of?
TIERRA-B-014951
Tobl.3
Summary ofChfmie-ah D'te('1edIh S4!-d'ment f:rom (tit Rc:frnmoC'l' Ar-t1U
Study A... 7; J .... y CIl], N... J .... ;,.
I
D-t'teetiDn ERL ERM ERM NOAA AET
Chp-mlC"ot!l- NOAA
Fl"'t'quc:ncy
of D....... d (NJDEPf E;I;Ce'l!:dllnco£ (NJDEPI Ex("udancf' Ex("c't'danc-('
DrtediQn ConC'enl:nttlon NOAA) Frequency AET
NOAA) Fr-tquen"y F"'Clut'f\(')"
!
HC;\.oCh~orobenz.c[\e 0/6 --
...
.- ... -- --. --._- 6 ..-
Hcxllch lorobul8dienc 0/6 -- ..- ..- -- ---
Hexach lorocyc lopcntad icnc: 0/6 --- -- ... -- '- _ ..
J.)
- .. ._-
Hexlllchloroethane
lsophorone
0/6
0/6 _.-
.. .-
.-
-.. --.
--
...
.-
.-
...
7~
._ .
---
Nitrobenzene 0/. _. .-
'"
... .- ---
... ..-
N·N itro,o~di-t1·propylam In c
N ..Nilmsodi phc:nyllmi no(!
0/6
0/6
--... --
_ ..
... -- -- .-
21
.-
"-
...
--- '- -- .-- _.-
Pent;l'lch!(jrophc:noJ 0/6 -- -- .- -- -.. - ..
28
n ...
1'1101101 Of6
-- - -- -- .- -- 130 '"
Pc!"t>"rlk .. io".:i'io: P·-dfv("Yrbons
"' 'u!"/k
2~Cnlorontphlh.!cnc 0/6 _. .- ..- .-
2-Melhylnophthol.n,
Acen8lphlhcne
616 '2·3100 819 10 '/6
--
610
--
216
.•. ...
6/6 81·12000 04 5/6
3,035 i6 6/6 500
Ae.nophthylene 6/6 216 DO 416
150·2400 9S0 44 6/.
Anthrl'~e-ne 640 216 71 ./6
616 260·7900 2.883 85
Benzo(R)ailthracenc 6/6 1,100 216 280
6/6 590·12000 4,4~8 SI6
261 6/6 1,600 3/6
Ben<o(')pyren. 6/6 660 - 11000 960 41(j
4,081 430 6/. 1,600 4/6
..-
Benzo(b)fluonmlhcn. 6/6 i,iOO 4/6
Benzo(8,h,i)p.rylen. 6/6
660 ·7900
400·5300
3,123 -- .- .- i,800 2/6
Bonzo(k)f)uomnlh.ne 6/6
2,002 170- 6/6 .- .- 610 416
Chl] •• n. 6/6
7.0·9300
870· 13000
3,593
5,028
240- 6/6 .- .- 1,800 2/6
384 6f6 2,800 216
Dibc=n:zo( R,h)anthrDCC lie 6/6 130 - 1900 950 S/6
713 63 4/6 260
Auonlntht:rn::: 6/6 2/6 230 2/6
1800·2'000 9,917 600 616
Fluorene 5,100 2f6 i,300 6/6
6/6 7~ • 2000 674 19
lJ\deno(I,2,3-edJpyr.ne 6/6 S40 2/6 120
6/6 4/6
Naphthah:ne 6/.
340·4900
95·14000
1,863
3,814
200-
160
6/6
416 ,
--
2,100
--
216
600 4/6
Phenanthn:ne 6/6 690.9\00 , 230 4/6
2,918 240 616 I,SOO
Pyren. 6/6 2/6 660 6/6
i4oo·200oo 8,000 665 6/6
I
2,.00 4/6 2,400 4/6
4,4'·DDD
4,4'·DDI:
0/6
i/6 20·20
- .- 2 .- 20 -_. 16 -_.
20 2.2 IIi 27 0/1
4,4'·DDT 0/6 -. --.- I -- 1 .-
9 ...
._-
Aldrin 0/6 ... 2- .- ... ...
12
olph.-BKe 5/6 17 -40 27 6- i ... ...
9.5
...
--.
~/~
...
P'AMOflS
Poge 3 of1
ENVIRON
TIERRA-B-014952
T.bl.3
Summary ofChel11iub Del~('ted In Swimel1t from Ihe Refert'nC't Al"'ru
Slud) Ar'rlil7; Jeruy Ch".. Ne-wJt'rsorJ
bc.. ·BHC _. i
0/6 ... 5" --- .- ... ._ . ---
Chl",d.n.
dell.·BHC
0/6
0/6
_.
-. -.-
...
O.~
.-
. 6 ...
I
28 ...
Dieldrin 0/6 _. .- 0-02
.-
.-
.-
8
--
.-
,
... --.
...
Endo-sulra:n I _. .- 19
0/6
_. - .- -.. ... ...
Endos.lran II
Endo5ulfa" !u~f'tl::
End,;n
0/6
0/6 -.
_._.
...
.- -
.-
.-
'-
'-
.-
.-
...
...
...
._ .
_.-
...
0/6 .- 3' ... ... .-
&loon aldehyde
f..ndrin ketone:
0/6 .- ... .-
---
-_. .- ...
...
1/6 38·38 38 ... ... .- ...
'"
_ ..
gamm.-BHC (Lindane) 0/6 ..- .- 3' .- ...
---
'-
Heptachlor 016 -.
_. --
.-
... - ... ...
48
03
'"
._.
HeptJIohlor epoxide
MelllOxyohlor
016
1/6
S" .- ... ... ._ . ...
_.
26·26 26 -- ... .- --.- ... ...
To•• phene 0/6 .- .- - -- .- ...
DhH:I~·Pinel F'ul-.ii:i (poe;J~)
Dioxins snd FUl'"af1:!I TEQ'"
2,J,7,8·TCDD
6/6
5/6
66 - 3769
1.31 ·207
1,72S
%
--
...
...
.-
...
...
'" 3,6 6/6
. ... ._-
1,2,3.7.8-PeCDD
1,Z,3.4.7,S·lhCDD
S/5
6/6
0.561 - 7,04 3.6 .-
...
.-
...
_ ..
"
.- _.. ...
1,2,3.7.8,9-~L,C"DD
0.S·5,11 3_1
-- ... ... ..-
6/5 0.98· 24,1 9.1 ...
1,Z,3,6.7,8·HxCDD 6/6 ...
"-
...
--- .- --- ...
1,2,3,4,6,7,8· HpC"DD
1.01·51.9 17 ... ... ... _.-
6/6 20.3.702 299 ... ... ... _ .. ...
OCDD 616 793·6140 ... '"
T"",ITCDD
3,284 '" --- ... ... --.
To,.1 PeCDD
6/6
6/6
12.3·249
6.77'40.4
129
22
--
...
-.- ...
...
-.- ..- ...
J"lal H,CDD ... .- ... -..
JolalHpCDD
515
6/6
24,S·488 157
.-
-- ...
... '- ... ...
2,3,7,8·TCDF
53.9·1450 542 ...
... .- ._- ...
1.2,3.7,8-PeCDF
516
616
3.23·29,2
2.48·23
14 .-
.-
.- ... ... ...
2.3,4.7.8·PoCDF 616 2.44·47.9
II
.-
.-
...
...
...
.- .- ._-
1,2),4,7,8·HxCDF 6/6 535·219
21
... ... .- ,-- ...
98 ... ..- ... ...
1,2),7,8,9·HxCDF 6/6 0748·11,2 4.6 ... .- -- .- ... ...
1,2,3,6,7,8·HxCDF
2,3,4,6,7,8·H,CDF
6/6 3.39· 146 68 .-
...
.- ... .- ._- ...
J 2.3 4.6 78-HpCDr
6/6 1.57·24.6 12 ... ... ... ... - ..
6/6 235·1570 700 .- .- i
'" ... --- ...
Page. 4 of7
tN'IRON
TIERRA-B-014953
T.bld
Slimmal)' OrChf"ml-£"al5 Detuted if1 Sedimenc from thr Rl!'fnrnc~ Aroeu
Studr Are. 7: J'''''r Cll)', N.w J..... r
DetpC'tion
RAng' Avc:ntge ERL ERL ERM ERM
C"rn1-l('a.I~ NOAA Af.T
Frequen-cy
or Oe£f('t,d (NJDEP/ EXl"eedllniC"t! (NJDEP/ Exce'rd9lnc:-t
NOAA
Exr"rdBioce
Dele-crion ConCf'nfratJon NOAA) Frl:quent."y AET
NOAA) Frrquro<'}' Fl"cqutnc-y
.~~
[II
1.2,3.4.7.8,9·HpCDF 6/6 l.OS - 25.3 11 ._- .- -- -- .
OCDF
Total TCDF
6/6 32 - 1700 694 -- -- -.. -- --- ---
Tot.1 P,CDF
6/6 50.9-1790 809 -- -- ._- .-
Tot.1 H,CDF
6/6
6/6
39,3·1660
34,8 - 1660
7H
766
--
--
'" --- .--
Totsl HpCDF 6/6 347-1840 83;
--- --- ---
--- --- -- --
PciychiorjnSded Binhen'l'h: ([)2:/~~
Coplanar PCB!l TEQu
PCB·77
6/6 20·645 238 22,700 -- 180,000 .-- DO,OOO ---
PCB-81
6/6 78 ·6410 2.888 -- -- .- -- --- ---
616 9.71 ·366 203 -- -- -- ... --- _ ..
PCB·IOS 616 134·20300 7,024 --- -- -- ... --- -.-
PCB·l06/liB
PCB·114
6/6
616
398·51500
9.71 • 1330
18,171
447
.--
-- ---- .-
-_. ---
...
.-- --.
--- --
PCB-I23
PCB·126
616
5/6
9.71 - 792
9,71 ·248
272 ---
.-
---- .--
.-
-- --- ---
PCB-I 56
110 -- --- ---
PCB-IS?
6/6 38.1 - 6550 2,132 - -- _.- --- I ... ---
6/6 10.6·1080 412 -- .- -- .- --- .--
PCB-167 6/6 16_5·2700 904 .- - -..- --- --- ---
PCB-I69
PCB-I 70
416
6/6
8.79- 59,6
956·31900
29
8,207
--
--
--
.- --.
-- .-- -..
PCB-ISO 6/6 277·81900 ... --- ..-
-- -- ---
21.058
-- --- ---
PCB-189
Total monoCB
6/6
...
97.1- 1220
--
345
--
---
-- --
.-
--- '- --. --
Tot.1 diCB -- --. -- ---
--- -- --. ---
-- - .. -.. --.
Tol.llriCB ---
-_.
--
--
---- .-
'"
_.-- -- ...
Tol.1 hexaCB
TOllil heptaCB -- -.. ---
-- ... -- .- --- I
TolliloolaCB ... _. -- --
...
.- -- --. -- ---
--. --. -.. --- -- ...
Tol.1 """.CB
_.--- ...
--. - .. _ ... --- ---
To.. 1doc.CS --- -- -- --- --. --. _ ..
Pase 1 of1
TIERRA-B-014954
T.ble 3
SummAry of Chemical", Dr-Ire-trod in Sediment rrom Ihf' Rrfn~nc-e AruL5
Study Arts 7; Jer.s!'y City, New Jtrse,y
80E·4?
4/6
6/6
43.1-153
201-?09O
99
2,413
.-
--
--
.-
.- --
._-
..- --- "
BOE-49 -- -- ._-
6/6 42.3 - 3800 1,293 .- - .- -- ---
BOE-66 3/6 71.9 - 300 188 ._- -- .- ---. _ .. "- j
_ ..
SOB-n ._.
316
_.
3.71 - 383 13S .- .- - .. ...
BOE·??
BOE·85
0/6 .- .- .- -- -.. ... -.-
BOE-99
4/6
6/6
29.8 - 209
230·7240
106 ._-
--
--.- --.- ._- _ ..
'"
BOE-IOO
2,449
.- I -- . ... ...
BOE-116
6/6 59.7 - 1880 636
--
--.-- .- -- ... -.-
BDE·I26
1/6
0/6 _.
76.8 - 76.8 71
.- - ---- -- .- .-
80E-138 3/6 80.2 - 104 9) -.-
.-
.- I '-
j .-
...
.--.. ..-
BOE·153 -,-
BDE·154
4/6 378·1260 802 -- .- I
.- -- --- ._-
BOE·155
5/6
4/6
54.4·1120 545 --
--
-- .- '.- ._- .-.
BOE·Is6 0/6 _.
40.6 - 122 70
.- ---
--
--
.-.
...
-- -_.
._-
.-
_ ..
BDE.IBI 0/6 --- "-
-- -- .-
"-
-- ... '"
r~n:on~
Pas" 6 of?
ENVIRON
TIERRA-B-014955
T.bl.3
Summary of Chemic-. Is Ooelected In Srdlmrnl rrunl .he Rerertl1("f: AreM
Stud,. Are. 7; .hney Clt)', New Je1"!P]
De-lto ....tion
!Un:. Ave-rag€! ERL ERL ERM ERlVI
CI1~mk..l~ NOAA AET
of D-elnted {NJOErl EX"'f'~dRm·-t (NJnEr/ NOAA
Frt"quf'nc)' Exreotdlalnce EXCl"f'dllMce
Drlrl'tion Ccn~("ntnUhHi NOAA) FM""'Ilf~r1CY NOAA) Frequent)'
AET
Froequ{'~'I"J
80E·] g) 5/6 j9, I .4930 1,918 .- ... ..- ..- ... ---
BOE-I97 4/6 763· 4S80 2,503 ._- ... .- -_. _ .. ...
BOE·2m 4/6 755-4170 ...
2,166 --- '- ... ... ...
BOE·207
BOE·209
4/6
616
3760·23600
3jgO·470000
12,333 .-
.-
.- _.- -_. --- ...
TQ1RI MQno.BDE
226,225 ...
'- _ .. ._- ...
TOlAlDi·BDE
4/6
6/6
340· 1000
8.4 - 2460
651 -.-
..-
-- .- _.- ._. ..-
1,079 .- .- --- ... ...
ToI,1 Tri-BDE 616 33,9·3220 1,517 -- -_. .- -- . -.. ...
To'al Telra-8DE 6/6 24) • 13600 6,537 ..- ... ... ... ._- ...
Total Penla·BDE
TOl.l Hex.-BDE
6/6
5/6
290 - 9110 3,359 --.
-_.
-- ._- --. -_. ._-
l4.4·3550 2,081 --- -- _.- ..- ...
Total Hopta·BOE
T"'aIOeI.-BDE
516 59.1 .8230 3,176 ._.
.•. ----- .- .-
..
._- - ..
TOI&I NoM-BOE
416
4/6
2840· 1gSOO
7360·41800
9.275
22115 -_. .- --... _
..-
...
...
..-
---
Sources:
N~w Jl:n.ey DepArtment of Environment aT Protection (NJDEP). 1998. Guidance fOl" Sediment QUftlily EvalUlI.lioo:'l. NQvember
Buohman, M,P" 1999, NOAA So~e"i"S QUick Referenoe Tabl"", NOAA HAZMAT Report 99-1, ScBttie WA, Co.,t>] Proleolion
end Rc:~tornlion Division. NfltiOfl.\l1Occ:at1ic and Atmospheric Administration, 12 page!!.
NOle,'
All Bnalys.e$ ore: based On va!idaled data from the: Ol;;lobcr 2003 through J8nllftry 2004 field sampling evenU and frum the 2002 RemediAl II:lVc:sligalion RC'port prepared by Tetra Tech,
Hcx.elvalcllt chromium 8n81)'~es were conducted by two Bnslytieal rtIc:LhoW (7196A and 7199) following elC.lraction by two methods: (N'JDEP Rnd EPA).
ERL Effeots Ranse Low.
=
ERM = Effecta Range Mediulll
NJDEP", New Jcney Dr;portmenl ofEnvirol'1mcnlal Protection.
NOAA = NationAl O:eanic and Atmospheric AdmillistratlQn
AET ~ Apparent Elfeols Thre.hold.
EPA • United Stat=s EnvironmentA~ Protection Agency.
mglks = Miligram, pe' kilosram.
uglkg • Microgram' pcr kilogram,
pg/g = picOR11Im! per gram .
..... :IE" Value n-ot s....II;i1.eble for lhu chcmicat.
• = MarinelEstultine 'edfmettl
screening -criteria nol avoilablc, the: frc!hwatcf !.edimen~ ICI"e(ning criteria was llsed.
.* TEQ - Toxio;ity Equivalency Quotien[; TEQ c8Icula~lOf'l!J do nOl mclude dita from the 2002 Reme;.diallnv'C:srigation Report
PnnOH'1
PAse 7 of7
EN '.! AOI\
TIERRA-B-014956
T,ble 4
Analylic,1 RC5WtS ofTol,1 Chromium and He.,.,len, Chromium in Sediment
Study Area 7; Je~ey City, New Je~ey
TIERRA-B-014957
Table .I
Allalytical Results of Tolal Chromium and Hel"'alenl Chromium in Sediment
Study Area 7; Jersey City, New Jersey
TIERRA-B-014958
Tobie 4
An.ly,ic.1 Results of Tot.1 Chromium and He .... I'nl Chromium in Sedimenl
Study Are. 7; Je"ey City, Ne .. Jersey
I I I
320 7.63 VI 0:95 UJ 7.63 UJ 1.59IB
SDOOD--ISO-00OO05-103 1011612003 O· 0,5 1,400 I J.7 UJ 1.46 UJ 11 ,7 VJ
Soo j WoOl 0-065070.2UJ
3.79 J 1/
IIIIS/2003 6.5·7 299 6.55 UJ 1.75 J 6.55 U 9,18 J
SDOIW·OIO-115120-203 1111512003 11.5 - 12 6.6 4.68 UJ 0.987 JB 4.68 U 0.468 V
SD02C-0IO-06S070-203 1111312003 6.5· 7 430 87 VJ 2.17 JB 8.7 VJ 0.87 UJ
S002C-01O·115120-203 )111312003 11.5 - 12 7.3 4,69 UJ 0.50J B 4.69 UJ 0.469 UJ
Sa02C-OJ 0·165170-203 1J113/2003 165 - 17 7.8 4.68 UJ 0.468 VJ 4,68 UJ 0.468 UJ
SD02E-O i0-065070-203 ii/l ~/2003 6.5 - 7 285 5.87 VJ 0.75IB
I 5.87 U 3,45 J
SD02E-01O-1I5120-20) 11115/2003 II,5 - 12 7.6 4.56 VJ 0.456 OJ 4,56 U 0.456 U
SD02E-010·165110-203 11115/2003 16.5.17 68 4.&5 UJ 0.60118 485 U 0.485 U
~D02E-025-000005·203 1112112003 0.0.5 216 937 UJ 0,937 UJ 9.37 UJ 5.41 J
SOO2E·025·0050 10·203 1112112003 0.5 . I 271 941 UJ 0.941 UJ 9.41 UJ 3.44J
S002E·025.0IS020·203 1112112003 1.5 - 2 208 825 UJ 0825 UJ 8.25 UJ 0.825 UJ
S002£·025·025030·203 11121/200) 2,5 - ) 207 6,45 VJ 0&4 J 6.45 UJ 3.15 J
SD02E·025-035040·203 1112112003 3.5 - 4 S60 7.09 UJ 2.18 J 7D9 UJ 0.709 UJ
SD02E-025·06~Q70-203 11/21/2003 6.5 - 7 406 8.26 UJ
- 1.9J 826 VI 6,71 J
TIERRA-B-014959
Taule ~
AnalJlinl Results of Totol Chl'omium .nu He .. ,·.lenl Chromium in Sedimenl
Study Area 7; Jcrsey City. Nen Jersey
PDl'S()nS
Page 4 of7 ENVIRON
TIERRA-B-014960
Table ~
Analytic,1 Results orTolal Chl'omilUll and Hexavalenl Chromium in Seulment
Study Area 7; Jersey City, :-if"' .Jerse~'
Field Sample ID
Date
Sampled
Depth
IkJow
Mudline
TOlal
Chrmniw10
(mglkg)
Hexavalent
Chrorniwn
r'JJDEP
Euraction
Hexavalent
Chromium
NJDEP
EXlraclion
lIeu"alent
Chromium
EPA
Extnlction
""'-".,
Chromium
ErA
Extl'llclion
]
(reel) 7196,\ 7199 7196.1. 7199
.. . _ . (rnglkgJ (~J (mglkg) (mgi~)
,
SD03W·200-Q0000l·203 I1124/200] 0-0.5 53,8 UUJ 3,16 4.& UJ 33 J8
SD03W·200-Q0501O-20] 1ll24i20OJ 0.5 - I 25 H8Ul 5.45 4.8& UJ 1]91B
SDmW·200-005010-20] 1112412003 0.5 - j- 13,7 5.0~ UJ 3.93 5.08 UJ 0635 U
SD03W·2oo-o15020-203 1112412003 1.5 - 2 5.8 4.72 UJ 0,478 13 4.72 UJ 0.59 U
S003W.2oo-Q25030-20] 1112412003 2,5·3 71 4,82 UJ 0.96618 4,82 Ul 0.602 U
SD03W-2oo-o35040-203 Il124/2003 ]5 - 4 7 4.9 Ul 0,49U 4.9 VI 0.613 li
SD03W·200-o65070·20] 111241200] 65 -7 66 4.8 UI 0,92918 4.8 UI 0.6 U
SD03 W·200-085090·203 111241200] 85-9 5.5 J 4.85 UJ 075! 1 4.85 UJ O.607lH
SD I3E-005·0oo005-203 11117/2003 0-0,5 2.850 I 7.26 VI 0.726 UJ 7.26 UJ 0.726 UJ
SO 13E-005-OO50 10-203 1111712003 0.5· I 2.190 J 9.64 UJ 0,964 UI 9.64 UJ 3.01 I
S013E·005-015020-203 1111712003 L5 - 2 5371 7.63 UJ 16.21 7.63 UJ 2,4 J
SD13E-005·0250]0·203 11117/2003 2,5·3 298 J 7.45 UJ 1.36 J 7,45 UJ ].28 J
SOI3£-OO5·035040-203 1lll7/2oo3 35 - 4 898 J 7,97 Ul 0.797 Ul 7.97 UJ 0.797 UJ
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SOI3E-050-065070·203 11113/2003 6.5 -7- 4.9 4.72 UJ 0.472 U1 4,72 VJ 0.472 VI
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TIERRA-B-014961
T.ble 4
Analytical Results of Total Chromiwn and Hex.nltnl Chromium in Sediment
Study A rea 7; Jers')' City, New Jersey
TIERRA-B-014962
Table 4
Analytical Resuhs of Total Chl'omium and Hex.avalenr Chromium in Sellimelll
Study Area 7; Jersey City, New J,,"Sey
NOles:
Chromium ....d hel<Avalent chromium analyses condueled by Columbi. Analytical Services, Inc. (Roell .. ter, New York).
Hex.avalent chromium analyses were conducted by TWo analytical methods (7196A and 7199)
following extrac~on by two methods (NJDEP and EPA).
• - The Mmple is a field duplicate.
J w The associaled .. Iue is an estimated quantity.
R - The result is unuseable.
U = The sample was analyzed for, but was not detected above the sample quantitation or detection limit.
UJ - The sample was analyzed for, but was not detected. The associ.led quantit.hon or detection limil is an eslimale.
B = The parameter was delected in the Blank sample(sl.
BJ = The parameter was detected in the BI.nk s.mple(s). The associated value is an estim.red quantity
-- = Not Bnalyzed.
TIERRA-B-014963
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ENVIltON
TIERRA-B-014965
Table 6
Acid Volatile Sulfide and Simulf.neously EUraeted Metals Results in Sedimenl
Study Area 7; .Jersey City, New Jersey
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145 J I J 60.7 108
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00-0.5 101 J 0.6 J
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1011012003 00-0.5 89.9 0.78
361 J 015 J 42.2 91.8
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00 - 05 1940 J IJ
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3.6 J
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V.ol.fO K
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Area 7 Samples; 038
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00·0.5 225 0.78 67.6 J
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11/2]12003 00 - 0.5 1230 1.09
096 J 54.2 J 140 J Oe}18 B
SDODA-025·000005·203 1112312003 25. I J 367 J 020
0.0-0.5' 435 l.lJ 71.7 J
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PI\P~ONS
Pa~e lof2
ENVIRON
"
TIERRA-B-014966
Table 6
Acid Volatile Sulfide and Simultaneously Estracleu Metals Results in Sediment
Study Area 7; Jersey City, Ne" Jersey
Notes:
• ~ The sample is a field duplicate.
I ; SEMIA VS is the <urn oflhe concenlrations of each meMI in urnole/g reported for a given 'ample, diVided by the acid volatile sulfide concentration in umolclg.
J ~ The associated value is an estimated quantity.
R ~ Th' result is "nus.,ble.
U ~ The Sam pic was analyzed for, but was not detected above the sample quantilalion or detection limi!.
U.I ~ The sample was analyzed for. but was nnt detected. The associated quantitatlon or detection limit is an estimate.
B ~ The paramoter WBs delceted in the Blank sample(s)
BJ ~ The parnmeler was detected in the Blank s.mplc(s). The associated value is all estimated quanlity.
NA= The r.atio could not be cBlculated because one or more of Ihe component concentrations was: not delected.
PAR;>ONS
Page 2 of2 ENVIRON
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TIERRA-B-014975
Table 10
Organa!in. Results in Sedimenl
Sludy A"ea 7; Jersey City, New Jersey
IL
SlUdv Area 7 Samnles:
SDOOI-2oo-DOOO05-203 1 11/25/2003 1 0.0- 0.5 I 1.7U 1 IJU
-/ 2.2 U r 1.9 U
SDOO4-200-oooo05-203 1112212003 0.0- 0.5 1.5 U 1.2 U 2U I.8U
SDD04-200-D15020-203 11/2212003 1.5 - 2.0 8.8 1.3 UJ 2.2 UJ 2.8
SDD04-200-035040-203 11/22/2003 3.5 - 4.0 2.4 U 1.9U 3.2 U 28 U
SDOOA·005-0oo00S·203 121112003 0.0·0.5 2.9 J IJU 2.2 U 1.9U
SDOOA-025-000ooS-203 11/2312003 0.0 - 0.5 4.6 J J.5J 2.6 J 48J
SDOOA-025·0()()()OS-203 !lI2312003 0.0 - 0.5" 4.8J 1.5J 2.6 J 2.8 J
SDOOA·050-o00005·203 1112312003 0.0 - 0.5 7.lJ 2J 3.4 J 9.2 J
SOOOA-050-D 15020-203 11/23/2003 1.5 - 2.0 3J 2.3 J 3.9 J 3.4 J
SOOOA-050-o35040-203 11123/2003 3.5 - 4.0 2.3 J 1.8 J 3J 2.6 J
SOOOA·loo-OOOOO5-203 11/24/2003 0.0 - 0.5 27 U 2.1 UJ 3.5 U 3.1 U
SooOA-2oo-oo0005-203 121112003 0.0 - 0.5 3.4 U 26U 4.5 U 3.9 U
SDOOB-005-ooooo5-;W3 121112003 0.0 - 0.5 I.5U I.lV 1.9 U 1.7 V
5OO0B-025-ooooo5-203 11/2512003 0.0 - 0.5 2.3 1.3 V 22V 1.9 U
SooOB-025-oo0005·203 11/2512003 0.0·0.5" 1.6 U 12U 2.1 U 1.8 U
SoooB-025-015020-203 11/2512003 L5 - 2.0 1.9 V 1.5 U 2.5 U 22U
SooOB-025-035040-203 11/25/2003 3.5 - 4.0 2.2 U I.7U 2.9U 25 U
5OO0B-050-0oo005-203 11/23/2003 0.0 - 0.5 2.4 J I.2J 5.4 J 1.9 ]
SooD8-05O-OO0005-203 11/23/2003 0.0·0.5· 2J 1.6 J 26J 2.3 J
Soo08-100-ooooo5-203 11/2212003 0.0 - 0.5 1.9 J 1.3 UJ 2.3 UJ 2 UJ
50008-100-015020-203 1 [/2212003 1.5 - 2.0 1.6 V 1.2U 2U 1.8U
SOooB-200-000oo5-203 11/22/2003 0.0 - 0.5 I.7U UU 2.2 U 1.9 U
I
S OOOC-005-000005-203 11120/2003 0.0·0.5 4J 2.6 U 4.4 U 5J
I
SOOOC-005-D15020-203 11/20/2003 15 - 2.0 3.2 U 2.4 U 4.1 V 3.6U
SDOOC-005-035040-203 1112012003 3.5 - 4.0 4J 2.4 U 4.1 U
, 3.7 U
SDOOC-025-OO0005-103 101 l612003 0.0 - 0.5 5.8 J 2.5 V 4.2U 6.4 J
SDOOC·025-00ooo5·203 !111912003 0.0·0.5 49J 2.9U 4.9U 6.6
I
SOOOC-050-OO0005-203 11119/2003 00 -0.5 2.5 U 2U 3.3 U 2.9U
S DOOC-I 00-000005-103 10116/2003 0.0 - 0.5 3.9 J 1.8U 3.1 U 5.7 J
SDODC- too-000005-103 1011612003 0.0 - 0.5· 4.9 J 1.8 U 31 U 5J
500OC-IOO-000005-203 11/21/2003 0.0 - 0.5 2UJ I5UJ 2.6 UJ 2.3 UJ
SDODC· 100-000005·203 11/2112003 0.0 - 0.5· 2U ISU 2.6 U 2.3 U
5OOOC·200-000005-203 1112112003 00-0.5 1.9 U 15 U 2.5 V 2.2 U
80000-050-000005-103
50000-150-000005-103
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S002E-075-oo0oo5-103 10/16/2003 0.0 - 0.5 14 J 2.4 U 4U 12 J
'-
Parsons Page:: I of2 ENVIRON
TIERRA-B-014976
Table 10
Organotins Results ;n Sediment
Study Area 7; Jersey City. New Jersey
Notes:
• = The sample is a field duplicate.
J = The associated value is an estimated quantity.
R = The result is unuseable.
U = The sample was analyzed for, but was not detected above the sample quantilation or detection limit.
VJ ~ The sample was analyzed for, but was nol detected. The associated quantitation or detection limit is an estimate.
B = The parameter was detected in the Blank .ample(s).
BJ = The parameter was detected in the Blank sample(s). The associated value is an estimated quantity.
TIERRA-B-014977
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EN '·1 RON
TIERRA-B-014985
Table 1~
Other Parameters Result. in Sediment
Study Area 1; Jersey City, New Jersey
---
---
53.7
)4 6
44 7
763J
7.041
& IJ
8 24 J
-_.
---
--
IIStudy Area 1Samples;
SOOO 1-200-000005·203 11/2512003 0.0 - 0.5 24.5 1.68
SooO 1·200-D05010·203 [ 1/2512003 05 - 1.0 --- 1.17 _.7& 8.26 J
8.39 J
15,400
15,300
SOOO 1-200-il 15020·203 11125/2003 15 - 2.0 .- 1.23 -. 7.931 59,400
SDOO 1-200-025030-203 11I25/2003 2.5 - 3.0 -_. 083 ._- 7.42J 53.100
SOOO 1-200-035040-203 . - 1112512003 3.5 - 4.0 -- --- ... 756J 23,600
Soo04-200·0ooo05·203 11/22/2003 0.0 - 0.5 8U 1.79 85.3 7.93 2,410
S0004-200·0050 10-203 1112212003 0.5· 1.0 ._- 1.73 _. 8.55 4.060
SOOO4-200-0 15020-203 1112212003 1.5 • 2.0 -_. 1.48 76 8.51 11,900
SD004·200·025030·203 1112212003 2.5 - 3.0 - 0.8 .-. 751 5J,200
SOO04-200-035040-203 1112212003 3.5 -4.0 --- 068 53.1 7.8 49.600
SDOOA-005·00oo05-203 W1I2003 0.0-0.5 52.4 138 78.2 8.56 J 17.500 ,
SOOOA-il05-il0501O-203 121112003 0.5 - 1.0 --- 0.96 --- 887 J 38.600
SOOOA-005-0 15020·203 121112003 1.5 - 2.0 --- 1.38 .- , 8.96 J 107.000
SDOOA-005·025030·203 121112003 2.5 - 3.0 - 0.67 ... 8.89 J 64,&00
S DOOA-005 ..{}J 5040·203 1211/2003 3.5 - 4.0 ... --- .... 914 J 65.800
S DOOA-025-DOOOO5-203 1112312003 0.0 .. 0.5 45 1.15 64.9 8.02 J 17,700
SooDA -025-ilOOO05·203 1112312003 0.0·0.5' 31.4 --- 65 &27J 21.&00
SDOOA·025-D050 10·203 . 1112312003 0,5 - 1.0 --. 0.96 -- 8.52 J 46,200
SDOOA-il25-il 15020·203 111231200J 1.5 - 2.0 --
i
0.5 ..- 8.15 J 160.000
SDOOA·025-<J25030·203 11123.'200J 2.5·3.0 - 0.73 -. 7.51 J 43.100
8DOOA-025-035040·203 IJJ23f2oo3 35 -4.0 ... 0_75 --- 7.65 J 38,700
SDOOA-il50-OOOOO5-203 11123/2003 0.0·05 39.5 0.9 502 &.13 J 24.400
SDOOA-{)50-D050 10-203 11/2312003 0.5 - 1.0 ---
_ ..
061 -- 1122 J 33.900
SDOOA-il50-0 15020·203 1112312003 1.5 - 2.0 0.6 43.6 7.97 J 62,700
SooOA·050-025030·203 1112312003 25·3.0 --- 084 --- 7.53 J 46,500
SooOA-05Q..035040-203 1I1231200J 35 -4.0 .-- 0.86 57 7.78 J 33,100
SOOOA-100..()()0005-203 [ !/2412003 00 - 0.5 69 0.78 47.7 7.97 J 75.\00
SDOOA-IOO-005010-203 11124/2003 0.5 - 10 --- 0.74 --- 8.05 J 77,400
SDOOA-IOO-O I5020-203 11124(2003 1.5 • 2.0 --- 0.76 -- 7.3 J 42.700
SDOOA-100-{)25030-203 1112412003 2.5·3.0 ... 081 --- 7.72 J 25.700
SooOA-IOO-03S040-203 11124/2003 35.4.0 -- 0.73 --- 7.36 J 49.300
SooOA-200-00000S·203 121112003 0.0·0.5 80.4 0.63 37.7 7.14J 74,900
SDOOA·200·005010·203 12/112003 0.5 - 1.0 --- 0.87 --- 8.16J 54,500
SDOOA·200·0 15020·203 121112003 1.5-2.0 ..- 0,73 _ .. 7.7 J 30,300
SOOOA-2oo-025030-203 121112003 2.5 - 3.0 -- 0.&9 ._- 8.04 J 26.200
SooOA-200-il35040·203 1211/2003 3.5 - 4.0 -- 093 -.. 7.85 J 33,000
S LiOO I:J-005-DOoOO5- 203 121112003 0.0·0.5 83.1 188 88.7 &.53 J 8,270
SDOOB-005..()()50 10-203 121112003 0.5·1.0 ... 172 -_. 8.85 J 9.670
80008·005-015020·203 12/112003 1.5 ·2.0 --- 1.55 ._. 8.9 J 11,900
TIERRA·B·014986
Table I~
Other Param"ers Results in Sediment
Study Area 7; Jersey City, New Jersey
TIERRA-B-014987
Table 1-1
Other Parameters Results in S"diment
Study Area i; Jersey City, New Jersey
TIERRA-B-014988
T.ble 14
Other Por.meters Results in Sedimenl
Srudy Area 7; Jersey City, New Jersey
TIERRA-B-014989
Table 15
Total Chromium Results in Pore Water
Study Aru 7; Jersey City, New Jersey
Noles:
Total chromium in pore waler a".IFed by Columbia Analytical Services, Inc. (Rochester, New York)
using EPA Method 60108.
• = The s.~mple is a [leld duplicate.
J - The associated value is an estimated quantiI)'.
U - The sample was onalyzed for, but was not deteoted above the sample quantitation or deteClionlimit.
Parsons
Page 1 of 1
ENVIRON
TIERRA-B-014990
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TIERRA-B-014991
Table 17
Total Chromium and Hexavalent Chromium Results in Surface Water
Study Area 7; Jersey Cil)', New Jersey
Hexavalent
Depth Chromium
Field Sample lD Date Sampled Chromi~m
(feet) (uglL)
(ugfL)
Referenee SamBles (Filtered):
SWOOI-RFI-DOOSUR-103 10/16/2003 00 -0.5 IOU 10 UJ
SWOOI-RF2-DOOSUR-103 IOf16/2003 00·0.5 IOU IOUJ
SWOOI-RF3-000SlJR-103 IOfl612003 0.0 - 0.5 IOU IOUJ
SW002-RFI-oOOSUR-I03 1011612003 0.0·0.5 IOU IOUJ
SW002-RF2-DOOSlJR-103 1011612003 00 -0.5 IOU IOUJ
SWOO2 -RF3 -DOOSUR -103 10/1612003 0.0 - 0.5 IOU 10 UJ
Study Area 7 Samnles (Filteredl:
SW02W-D50-DOOSUR-103 I 01 1 6f2003 0.0 - 0.5 IOU 1001
SW03 W-D25-DOOSUR-103 IOfl6/2003 0.0·0.5 IOU 1001
SWD3W-D25-DOOSUR-I03 10/16/2003 0.0 - 0.5' IOU 10 UJ
SWI3W-100-oOOSUR-J03 10/16/2003 00 - 0.5 IOU IOUl
Reference Samoles Ilfnfiltered):
SWOOI-RF1-G00SUR-I03 10/16/2003 0.0 - 0.5 lOU !O 01
SWOOI-RF2-G00SUR-103 10/1612003 0.0 -05 IOU 1001
SWOO l-RF3-D00SUR-l 03 IOfl 6/2003 0.0 - 0.5 10 U 1001
SW002-RFl-DOOSlIR-l03 1O!l6f2003 0.0 - 0.5 IOU 10 UJ
SW002-RF2-DOOSUR-! 03 10/1612003 0.0 - 0.5 IOU IOUl
SWOO2-RF3-000SUR-I03 10116/2003 0.0 -0.5 IOU IOUJ
Study Area 7 Samnles fTJnfiltered1:
SW02W-D50-D00SUR-103 1011612003 0.0 - 0.5 IOU 10 UJ
SWOJ W-025-DOOSUR.103 10/16/2003 0.0 - 0.5 IOU 1001
SWD3 W -D25 -DOOSUR -103 1011612003 00 - 0.5' IOU IOUJ
SWI JW-100-OO0SUR-IDJ IOf16/2003 0.0 - 0.5 IOU 10 UJ
Notes:
Total chromium in SUlfaee water analyzed by Columbia Analytical Services, Inc. (Rochester, New York)
using EP A Method 60 JOB.
Hexavalent chromium in surface water analyzed by Columbia Analytical Services, Inc. (Rochester, New York)
using EP A Method 7199.
, = The sample is a field duplicate.
J = The associated value is an estimated quantity.
UJ = The sample was analyzed for, but was nOI detected.
The associated quantitation or detection limit is an estimate.
TIERRA-B-014992
Table 18
Summary of Sediment ~(}Ie<:hnic.1 D.ta
Study Area 7; Jersey City, Ncw Jef5ey
i
ATTERBERG LiMitS
eRADAHON
Depth Average NalUral
N.tura:l Natural Water
&ring USCS Natural Uquid Plasticity
Below Wafer Water
Group Water 8./0 Coarse % Content of Organic
Number Mudline Limit Index Content of 0/0 Fine Specific
Content % Gravel Medium % Fines
Symbol Content ("!o) (%) Sand S.nd Gradation Content Gravity
(feet) ("!o) UmitSlll1lpll,
S8Jld Sample ("!o)
(%) of Solids
mr
("!o)
CV~j
I1
8000'-200 00·0.5 8C 32 29 37 19 31
5Dool-2oo 0.5-LO SC 17.9 43.4 26.7 33
41 41 39 18 41 2.71
80001-200 1.5-2.0 0.1 1.6 14.3 53.8
8C 47 5! 44 30.2 41 2.5 272
23 47 00 0.6
SOool-200 2.5-3.0 8C 48 14.6 45.1 39.7 44
49 37 13 45 3.4 272
SOool-2oo 3.5-4.0 0.0 0.9 16.0 55.0
CH 78 81 68 40 78
281 49 2.8 264
·•·
f\f\
··
nl'\
SDOO4·200 v.y U.V 0.5
0.0-0.5 SP-8M 20 20 • 1.7 97.8 76 4.1 274
8 D004-2oo
S0004-200
S0004-200
05-10
1.5-2.0
2.5-3.0
SP-SM
8M
CH
20
33
91
21
34
92 77
·· •
0.1
0.0
0.3
0.5
0.8
1.1
i
29.6
245
9.3
62.7
64.7
65.6
7.1
JO.t
23.8
19
20
33
0.7
08
1.3
275
246
270
48 91 3.6 1.1
8D004-200 3.5-4.0 CH 114 12.1 14.3 68.9 91
tIS 90 63
·· ··
56 114 2.69
··
SDOOA-005 0.0-0.5 0.0 0.2 [.2 9.6 on"
Sivl 29 30 I O:1',V i 14 7.2 265
8DooA-005 05-1.0 9.6 8.5 I 23.5 42.8
8M 46 46 15.7 29 3.3 2.78
•·
8DooA-005 7.8 6.6 18.!
l.5-2.0 8M 63 64 • *
38.4 29.0 46 4.0 2.66
··
5DooA·005 4.6 9.8 21.9
2.5-3.0 8M 52 54 • 39.[ 24.6 62 8.0 2.56
SDooA-005
SDOOA-025
SDOOA·025
35-4.0
0.5-1.0
1.5-2.0
8M
SM
SC
84
65
t52
86
69 47
· •
17 66
9.6
7.5
0.7
14.7
12.9
4.9
24.3
19.1
6.0
32.0
29.9
41.1
19.4
30.7
47.4
50
83
7.9
10.2
2.72
2.65
154 84 34 147 63 6.2 2.64
SDooA-025 2.5-3.0 1.3 6.4 13.1 386
CH 84 S2 55 27 89
40.5 154 21.3 2.43
SOooA-025 B-4.0 0.0 0.1 0.4 22.1
CH 90 93 67 37
774 82 5.4 2.71
80ooA-050 82 1.7 J.7 1.3
00-0.5 CL 76 79 49 27
12.0 83.4 93 68
SOOOA·050 0.5-1.0 CH
77 0.0 0.5 1.0 27.7 70.8
""-
82 92 55 30 75 2.9 2.74
SOOOA-050 84 0.0 03 12
15·2.0 CH 152 [52 24.0 74.5 77
92 57 151 0.0 5.1 2.74
SOOOA·050 25-3.0 CH 0.1 0.3 8.9
III 117 75 44 90.7 152 8.1 263
112 0.0 0.0 0.2
SOOOA·050 3.5-4.0 CH 77 5.0 948 108
30 67 39 96 7.3 264
SDOOA-100 0.0 0.0 0.1
0.0-0.5 CH t02 104 59 33
16 98.2 91 4.8 2.75
$ DooA· 100 102 0.0 0.3
05-10 CH 94 1.5 25.6 72.6 102
95 60 31 94 00 O.l
55 2.64
Sl)ooA-IOO 1.5-2.0 CH 105 0.6 17.4 81.9
106 7J 44 105 95 5.8 2.68
5 DooA· 100 2.5-3.0 CH 95
0.0 0.0 0.0 3.1 96.9
96 65 37 95 0.0
105 48 2.79
SDooA·IOO 0.0 0.2
3.5-4.0 CH 104 105 98
I.l 98.S 95 4.4
SOOOA-200
59 104 00 0.0 0.1
280
00-0.5 CH 164 170 1.4 985 104
104 65 J62 0.0 7.2 276
50ooA-200 0.5-10 0.0 0.1 61
CH 118 130 79 48 114
93.8 152 101 2 (,.j
0.0 0.0 0.4 89 90.7 114 7.1 267
=
P91"SOnS
Page [ of 5
Er-IVIRO"
TIERRA-B-014993
Table 18
Summary of Sediment c;.,ote<:hnical Data
Study Are. 7; .Jersey C;I)', New .1ersey
Natural Water
Boring
Contenlof Orgflnic Sped lie
Number
Gradation Contenl Gravity
Sample (%) of Solids
£0,1. \
\ 'v,
SOOOA.200
SDOOA·200 90.8 74 ~~
/ SOOOA-200
SOOOB-005
98.4
97.3
92
85
~.~ I 2~~ i
4.2 2.77
SDOOB-005 4.1 19 0.6 271
5000B-005 6.9 24 1.4 279
5000B-005 33.3 23 12 2.70
5D008·005 79.4 34 2.5 270
5D008-025 93.8 83 49 2.67
50008·025 8.7 19 0.9
50008-025 44.9 19 1.6 2.75
S0008-025 83.8 29 1.7 272
50008-025 97.4 104 53 2.71
S0008·050 98.0 84 4.5 270
SD008-050 10.6 66 3.4 270
SD008·050 89.2 68 4.0 2.80
SD008·050 91.7 31 21 278
5D008-050 76.7 32 IJ 2.77
SD008·JOO 24.5 28 1.8 26B
50008-100 30.3 40 19 270
50008-100 HO 44 24 273
50000·100 209
5DOOB-100 38 266
5D008-200 1.8 +
5 D008-200 26.7 26 271
50008-200 40.1 272
50008-200 19.3 34 2.71
S0008-200 43.9 50 2.70
5DOOC-Q05 46.6 47 272
5DooC-005
SOooC-005
J 98.2
99.6
+ 2.28
265
98.2 261
Pal'sons
Page 2 of 5
ENViRON
TIERRA-B-014994
Table 18
Summary of Sediment GeoledmJe.1 Dala
Stud)· Area 7; Jersey Cli)', New Jersey
Averal;e
A""""OUMn. ~ GRA.DATION
Del'lh Natural Natural
uses Natunl Natural Water
%"",r=
Boring Be!o", Water U~Ujd P1a"licit)· Water % Co.rs~
Groul~ Wat ... % Conlenlof
Number Mud'in" Limit Index Content of % Grave~ S d Organic Specific
Symbol Conlent Medium
(feet) Conlen,t (%) (%) Lirnil Sam 1'1" an Sand V. Finrs Gradation Content Gravir:\"
("!o) Sand
(%j San,ple (%) of Solid.
(%)
SDOOC-005 ("!oj
2.5-3.0 OH 132 121 117 66 144 0.0
SDOOC-005 3.5-40 OH 116 121 97 52
0.0 0.0 1.0 99.0 .,. 7.2 2.61
SDOOC-025 III 0.0 0.0 0.0
0.0-05 CH 126 78 57 34 78
0.5 99.5 ... 2.1 2.6&
SDOOC-025 0.5- [.0 00 0.0 0.2 2.9
OH 157 160 121 968 173 2.7
61 I53 0.0 2.64
SDOOC-025 l.5-2.0 OH 0.0 0.0 3.1 96.9 ...
141 138 1/3 61 6.6 2.61
I43 0.0
SDOOC-025 2.5-3.0 OH 142 142 112 62 142
0.0 0.0 , J.l n.9 ... 66 2.62
SDOOC-025 3.5-4.0 0.0 0,0 0.0 14
OH I31 125 98.6 7.5
SDOOC-050 00·0.5 OH 137
109 57 136 0.0 0.0 0.0 1.0 99.0
'"
+
2.65
137 87 46 137 5.2 2.72
SDOOC-050 05·1.0 0.0 0.0 0.7
OH 124 127 94 12.6 86.7 138 2.2
50 121 0.6 1.8 2.60
SDOOC-050 15-2.0 OB 137 6.9 9.7 80.9 +
131 102 56 142 65 270
SDOOC-050 0.0 0.0 0.0 3.2 I .,.
25·3.0 OH 105 100 96.8
84 39 110 0.7 04 i 6.3 261
SDOOC-050 3.5-4.0 OH 74 75 63 27 74
1.8 13.7 83.3 ... 5.0 2.76
SDOOC-IOO 0.0-2.0 0.0 0.5 0.6 12.1 .,.
CH 84 84 74 41 86.8 4.4 2.66
SDOOC·IOO
84 0.0 0.0 0.8
0.0-0.5 CL 27.2 72.1 ...
SDOOC·IOO 0.5-1.0 SC
64 64 42 17 64 0.1 0.2
I
1.3 47.8 505
'-- 265
47 46 33 10 4&
64 1.4 2.72
SOooC-IOO 0.0 0.2 5.4 .,.
1.5-2.0 CH 59 66 56 29 52
63.0 3\.4 2.5 2.60
SDOOC-lOO 0.0 0.1 1.1 42.6
25-30 CH 81 80 68 35 82
56.2 + ..- 2.65
.
SDOOC-JOO 0.0 0.0 0.0
3.5-4.0 OH 83 &4 2.3 97.7 + 4.9
68 34 82 2.66
SDOOC-200 0.0·05 SC 35 35 * *
0.5
0.5
0.8 4.1 17.7 no + ._- 2.64
SDOOC·200 0.5-1.0 SM 25 -- -_. 0.6 22.4 52.5 24.1 .,.
SDOOC·200 1.5-2.0 SC 63
25
68 59
-- 0.0 i 0.1 19.9 61.2 18.8 +
1.6 267
32 57 0.0 I.I 2.68
SOooC-200 2.5-30 OH 0.8 12.2 38.1 48.9 ...
129 129 III 57 129 14 2.67
SDOOC-200 3.5-40 0.0 0.0 0.0
OH 112 112 110 59 112
6.9 93.1 ... 4.2 2.55
SD02E·025 0.0 0.0
0.0-0.5 OH 139 139 !Q2 53 ,or, 0.3 57 94.1 ... 3.5 2.5S
$002E·025 0.5-1.0
U7 0.0 0.0 00 0.9
OH 123 123 94 43 99.1 + 64
123 3.3 263
S002E-025
S002E-025
l.5-2.0
25-3.0
OH
OH
83
76
80 78 39
I
86 I 0.0
1.7
0.4
4.9
1.1
[07
4.0
79.4
94.5
'" 81 2.63
78 74 39 73 + 54 270
SD02E-025 0.0 0.0
15-40 CH 56 57 61 36 56
0.0 7.7 923 ... 6.4 2.63
.
0.0 0.0
SD02£-075 00-2.0 OH 120 120 91 38 120
0.0 0.2 99.8 ... 4.1 270
SD02E·075 0.0-0.5 0.0 0.0 0.2 10.2
CH 141 141 95 59 89.7 --.
I: 141 0.3 01 2.65
S002E-075 0.5-10 OH 129 0.4 4.7 94.5 141
127 111 63 130 1.8 2.65
0.0 0.0 0.3 4.4 95.3 + J.3 2.60
Pa"sons
Page 3 of 5
fN\IHON
TIERRA-B-014995
Table 18
S"mmary of Sediment Geotechnical Dala
Study Area 7; ,Jersey City, New Jersey
P<lr~ons
Page4of5
FNVlr~ON
TIERRA-B-014996
Table 18
Summary of Sediment c;.,ole<:hnie.1 Data
Shirl)' Area 7; Jersey City, New Jersey
A TTERHERG LIMITS
GRADATION
Average N.hlr81
Depth Nahlrol Natural Water
Boring USCS Nahlrol Liquid Pla.tidly Water
Below Water % Content of
Group War.r °/. C09r5e G/o Fine Organic Spedfi<
Nwnber Mudl;n. Limit Index Content of 11/0 Gravel
Cootent Medium 0/. Fines Gradation Content
Symbol Conlenl (%) (%) SAnd Sand GrAvi!)'
(feel) (%) Limit Sam pie Sand
(%) Sample ("!o) of Solids
(%)
(%)
SDI3£·050 0.5-1.0 CH 59 59 57 29 59 0,0 1.5 0,0
5D I 3£·050 1.5·2.0 1.8 96.7 + 3.1 2,77
OH 85 83 81 42 88 0,0 0.0 0.0 13 98.7 +
5013E-050 2.5-3.0 OH 92 91 85 55 2,74
46 92 0,0 00 0.0
5013£-050 35-4.0 2,5 97.5 + 5.5 2,63
OH 78 82 76 40 74 0,0 0.0 0.0 0,8 99.2
SO I3E-I00 0,0-0.5 CH 102 79 107
i
4.5 2.75
68 174 00 0.6
SO I3E-IOO 0,5-1.0 8.8 37.9 52.7 79 2.1
CH 82 74 2.61
.
58 31 89 1.3 0.3
50I3E·IOO 15-2.0 3.2 17.6 77.S + 4.1
CH 93 92 81 47 94 2.63
0,0 0.0 0.0 2.1 97.9
5013E-IOO 25·30 OH 96 100 4.6 2.93
95 53 91 0.0 0.0
S013E-IOO 3,5·4,0 0.0 l.l 98.9 + 4.9
CH ll8 106 107 2.6&
·• ·•
70 130 0,0 0.1
5DI3W·200
5013W-200
0.0-0.5
0.5-1.0
SM
8M
21
17
21
17 ·· 0.3 0.9
l.l
23.9
9.0
59,6
89.8
15.3
+
+
6.5
---
2.58
2.68
··· ··· ·
1.5 2.8 251
SDI3W-200 1.5-2.0 se 14 14 10,1 0.7
52.9 17,7 + --- 2.70
sp-se 18.3 54.5 16.4
SD13W-200 2.5-3.0 13 13 • + --- 2.68
·
0.0 0.3 19.0 71.7
SD13W·200 3.5·4.0 sp-se 15 15 4.1
9.0 + OJ 2.65
1.3 26.7 5&.9 9.0 + --. 272
Notes:
All lests summarized were performed in a Mueser Rutledge Consulting Engineers laboralory,
• Average natllral waler content" is a weighted average of all material tesled .
• • Soil non plastic,
+ ~Natllral water Conlen! not laken,
-- ~ Nol enollgh soil in jar to 11m tes\'
Panon:s
Page 5 of 5
ENVIRON
TIERRA-B-014997
....
Tab-lit 19
Sr. "Hhlll-d OI'dQ-me~~r .nod Perltl-.blltty T a-Un-g Resulbi
Stud,. Aru 1: j~l~l Ctt)r. Nom'Jt'Tlq"
,.
S:trft!'
GEO-2 iU --6,) OH 10 ,~ '''''
19.9- t 1~
(%1 (%~ (II. ~
~... \
R.t'" R.tlo
<1S1'1
Sitess
rrSF1
In-dc); In-del {("mIlK)
rars:ftnJ
~~lorl
TIERRA-B-014998
JERSEY CITY
Honey\\'ell NEW JERSEY
STUDY AREA 7
SITE MAP
PARSONS
OCEAN SURVEYS, INC. MECbm:;.;""'._ ...... UmncrTech, Inc.
PRIVEL£GED AND CONFIDENTIAl. PREPARED AT n-H~ REQUEST OF COUNSEL
TIERRA-B-014999
! It) o
~
125
EXPLANATION
Sediment Sample
iii No Sample'
'NOTE.:
ATTHA:EE U:X:ATlONS.$,t.MPUNG
WAS ATTEJJ:f7TED; HOWEVER
SAMPLES COULD NOT BE COUECT"ED
BECA1.JSE COARSE SEO!MENTS WERE
FOJNO. ROC-K FfUG~Et>rTS WERE
ENCOUNTCFrWAllOCATrON$
00&-02.'5 AND OOS-D50. CO~
SAND AND SHELL ffMGMfN"f$
INERE ENCOUNTERED AT LOCATJiJN
t3:Y/~200.
FIGURE 2A
JEASEYCITY
Honeywell NEW JERSEY
STUDY AREA 7
LOCATIONS OF SEDIMENT
GRAB SAMPLES AND WATER
COLUMN SAMPLES NEAR SA?
TIERRA-B-015000
II~ EXPLANATION
o
~
125
A 10' Core
A 20' Core
0,_<, , __... ".
Radiodating Core
'"
FIGURE 28
JERSEY CITY
Honeywell NEW JERSEY
STUDY AREA 7
LOCATIONS OF SEDIMENT
BORINGS FOR CHEMICAL
AND GEOTECHNICAL
CHARACTERIZATION
TIERRA-B-015001
FIGURE 3
JERSEY CITY
NEW JERSEY
STUDY AREA 7
LOCATIONS OF SEDIMENT
GRAB SAMPLES AND WATER
COLUMN SAMPLES IN
REFERENCE AREAS
TIERRA-B-015002
r 16 :-
EXPLANATION
125
. :::".' ~
,.., .. '.-.
I
.A 10' Core
Radjodaling Core
FIGURE 4
JERSEY CITY
I-loneyv,'ell NEW JERSEY
STUDY AREA 7
CROSS-SECTION
LOCA TION MAP
TIERRA-B-015003
SUPPLEMENTAL REMEDIAL INVESTIGATION REPORT
REMEDIAL ACTION SELECTION REPORT
REMEDIAL ACTION WORK PLAN
5
NEW JERSEY CITY UNIVERSITY PROPERTIES
Site 090
'~o/~;.,
~' ..
' -"-,,-,,-,,,".,.~._ .... _ ~
I •• ·--<.C:_~.'
BBA000004
TIERRA-B-015004
SUPPLEMENTAL REMEDIAL INVESTIGATION REpORT/
REMEDIAL ACTION SELECTION REpORT/
REMEDIAL ACTION WORK PLAN
STUDY AREAS
NEW JERSEY CITY UNIVERSITY PROPERTIES
JERSEY CITY, NJ
Prepared for:
Honeywell
Honeywell
101 Columbia Road
Morristown, NJ 07962
Prepared by:
,MACTEC
MACTEC Engineering and Consulting. Inc.
200 American Metro Boulevard, Suite 113
Hamilton, New Jersey 08619
JUNE 2007
TIERRA-B-015005
Table of Contents
Executive Summary
1.0 Introduction 1
1.1 Purpose and Scope I
1.2 Report Organization , 4
TIERRA-B-015006
Table of Contents
4.5.3 Compliance with Applicable Federal, State, and Local Regulations , .40
4.5.4 Potential Impacts on the Local Community 40
4.5.5 Potential for Remedial Action to Cause Natural Resource Injury 41
4.5.6 Criteria for Restricted Use Remedial Action 41
7.0 References 66
TABLES
ii
TIERRA-B-015007
Table of Contents
FIGURES
APPENDICES (Volume 2)
111
TIERRA-B-015008
EXECUTIVE SUMMARY
Honeywell International Inc. (Honeywell) has completed an evaluation of remedial action alternatives to
address chromium contamination for the portion of Study Area 5 proposed for redevelopment by New
Jersey City University (NJCU or University). This portion of Study Area 5 is comprised of the following
sites:
These sites are collectively referred to herein as the "Site", and encompass a total of approximately 14
acres located in Jersey City, Hudson County, New Jersey (see Illustration I).
This combined Supplemental Remedial Investigation Report (SRIR), Remedial Action Selection Report
(RASR), and Remedial Action Work Plan (RA WP) reflects Honeywell's concerted efforts to produce an
integrated remedial approach to the New Jersey City University site (a portion of Study Area 5),
developed in close cooperation with and supported by the University. The approach selects a remedial
technology based on the specific uses anticipated for the chromium impacted portions of the Site,
consistent with the guidance in the Department's recently issued Chromium Directive (Policy). These
uses fall into both the Residential and Commercial categories that are discussed in the Policy. Honeywell
and NJCU have met numerous times to coordinate the remediation with the redevelopment, and have
recently formed ajoint team to continue this coordination through the life of the project.
This cooperative effort has resulted in a comprehensive approach to chromium remediation. This RA WP
applies a combination of remedial technologies that will fully protect human health and the environment
and effectively integrate the remediation with the redevelopment. This proactive approach 1) is
encouraged by New Jersey's Brownfields Legislation, 2) fully meets both the spirit and intent of the
Policy, and 3) complies with the Technical Requirements for Site Remediation. We strongly believe that
this approach is a model that demonstrates what can be achieved under the new Policy.
·---------·--~---_··---------------7
e~o-tllVol:l
N
t
LEGEND
( 81te Boundary
RESlOEHTlAl. AOC SITE 114 : Rni<J.,.,li.IAOC
I . Commerei'" AOC
:
.,_...._-. "-"1 ~
~
c::J
Proposl'd e.c...v
Proposed ClIP A'....
P,oposed 8ulldltl9l'
lon .Ar~_
S~IO ,
I
- Impermeilble Barner
J!
________ -
BioBa"ie, (PRS)
Chromium Imp.acted Soil.
o..\in •• ';on line 120mo/lllli
ES-I
TIERRA-B-015009
Working with the property owner, Honeywell has developed a viable and protective remedy for
contamination associated with both chromite ore processing residue (COPR) and sodium chromate. The
CaPR was likely used as fin on the Site and the sodium chromate likely resulted from housekeeping
practices associated with the adjacent, former Mutual Chemical site. The remedy supports the aggressive
Site redevelopment plan and schedule envisioned by NJCU.
The remedial approach presented herein was developed to align remediation solutions with NJCU's plans
for the property and is fuJly protective of human health and the environment. NJCU's redevelopment of the
Site will result in both residential and commercial uses. Honeywell, following the guidance of the Policy
and Technical Requirements for Site Remediation, has selected remedies that support the site uses. For
residential uses, defined by the Residential Area of Concern (RAOq, excavation will be applied. For
commercial uses, similarly defined by the Commercial Area of Concern (CAOq, both state of the art
engineering controls and an innovative reactive wall (or permeable reactive barrier) will be applied (see
lllustration 1). The combination of remedial approaches described in this document will ensure that:
NJCU fully supports Honeywell's approach and is ready to proceed with the Site development pending
review fPld approval of this RA WP by the NJDEP. NJCU intends to request funding for their
redevelopment through the Environmental Infrastructure Trust Fund. Their goal is to submit an application
to the Trust Fund in August, 2007 and that funding application requires an approved RA WP.
• Excavation of soils containing hexavalent chromium above 20 mglkg to a depth of 20 feet (20/20) in
the Residential AOe. The Residential AOC extends to the nearest physical feature of the adjoining
Commercial AOC.
• Additional focused soil excavation in the Commercial AOC to provide clean utility corridors and to
coordinate the proposed capping system with proposed Site development features along Route 440.
• Engineering controls (cap) for the Commercial AOC where soils exceed 20 mglkg hexavalent
chromium.
ES-2
TIERRA-B-015010
• Installation of an in-situ permeable reactive barrier (PRB) using a biological medium for the treatment
of residual impacted groundwater across the western portion of the Site.
• In-situ groundwater treatment system to reduce source concentrations on the adjacent Home Depot site,
which is contributing to the deep aquifer contamination.
• Impermeable barrier and backfill liner systems to prevent recontamination of excavated areas from
potential upgradient sources.
• Institutional Controls (Deed Notice) for soils remaining with hexavalent chromium above 20 mg/kg.
The remedial approach described herein goes beyond what is required in the Policy for the RAGC by
providing for full excavation to 20/20. Treatment of the chromium impacted soils is allowed under the
Policy, but Honeywell has chosen to excavate all of the RAGC to 20/20, primarily to meet NJCU's schedule
requirements. The remedial approach also provides an added measure of protection for the CAGC by
including a redundant groundwater protection system as a "belt and suspenders" approach. In addition to
the PRB, Honeywell will be installing piping that will enable a pump and treat system to be activated, if
necessary.
The NJCU West Side Campus Expansion will serve to broaden the physical resources of the University
and enable them to provide expanded learning opportunities for New Jersey residents, primarily from
Hudson County. It will also provide attractive retail outlets and market rate housing that will help to
continue the revitalization of Jersey City's west side. Honeywell's remediation plan will enable this
redevelopment to move forward quickly and with a fully protective remedy.
ES-3
TIERRA-B-015011
1.0 INTRODUCTION
This combined Supplemental Remedial Investigation Report (SRIR), Remedial Action Selection Report
(RASR) and Remedial Action Work Plan (RA WP) was prepared by MACTEC Engineering and
Consulting, Inc. (MACTEC) on behalf of Honeywell International Inc. (Honeywell) to address chromium
contamination on the portion of Study Area 5 (SA-5) proposed for redevelopment by New Jersey City
University (NJCU). This portion of SA-5 is comprised of sites designated as Baldwin Steel (NJDEP Site
090), M.1. Holdings (NJDEP Site 184), and a portion of the Former Morris Canal Site (NJDEP Site 153)
abutting Sites 090 and 184 (collectively referred to herein as the "Site"). This document addresses
remedial investigation (Rl) requirements and proposes remedial actions for the Site in accordance with
the requirements of the Administrative Consent Order (ACO) and the New Jersey Technical
Requirements for Site Remediation (Technical Requirements) (NJDEP, 2003).
Honeywell (formerly Allied Signal, Inc.) entered into an ACO with the New Jersey Department of
Environmental Protection (NJDEP) on June 17, 1993, to investigate and, if necessary, remediate
chromium contamination at twenty-one (21) Sites referred to by the NJDEP as the Hudson County
Chromium Sites. The Sites are located in Jersey City, New Jersey, and are grouped into seven (7) Study
Areas. SA- 5 is comprised of five (5) contiguous Sites identified as follows:
A Remedial Action (RA) for soils has already been completed at the former Ryerson Steel site (Site 117
but now conunonly referred to as the Home Depot site). This action was part of the redevelopment of the
property as a retail shopping center. Previous investigations and remedial actions have also been
conducted on portions of Site 184 (MI Holdings). Previous investigation and remedial action activities
on the eastern portion of Site 184 were reported to NJDEP on December 1, 1992, and additional Site
characterization and remediation was completed in the western portion of Site 184, including excavation
and off-site disposal of contaminated soils. These activities were documented in a report prepared by
Woodward-Clyde Consultants dated August 30,1993.
RI activities have been substantially completed on the remaining Sites comprising SA-5. A report
entitled Draft Remedial Investigation Report (RIR) - Study Area 5, dated November 1999, prepared by
TetraTech, Inc., documented the results of previous RI field activities on the five (5) sites comprising
SA-5 (TetraTech, 1999). The NJDEP provided comments on the RIR in a letter dated October 9, 2001,
and Honeywell provided responses to the NJDEP review comments in a letter dated December 19,2001.
An RIR Addendum with results of additional soil sampling performed on Site 090 (Baldwin Stee!) and
Site 184 (MI Holdings) was submitted to the NJDEP in October 2004 (TetraTech, 2004).
A Remedial Investigation Work Plan (RIWP) Addendum for Shallow Groundwater was prepared by
MACTEC and submitted to the NJDEP in March 2005. The results of the additional RI field activities
are presented in this report. The additional RI activities were conducted to address NJDEP requirements
for shallow groundwater in response to the NJDEP comment letter dated December 21,2004 on the RIR
TIERRA-B-015012
Addendum, and subsequent discussions including a meeting held on February 3, 2005 between
representatives of Honeywell and the NJDEP. Honeywell provided responses to the NJDEP comments
on the RIR Addendum in a letter dated February 15,2005. Prior to field mobilization for the additional
Rl activities in April 2005, a conference call was held between representatives of Honeywell and the
NJDEP to discuss the proposed supplemental field activities. NJDEP provided preliminary verbal
comments on the RIWP during the conference call on April 8, 2005, and subsequently provided written
comments in a letter dated June 3, 2005. Honeywell transmitted a letter dated July 1,2005, with
responses to the NJDEP review comments.
The RI has included a total of over 80 soil borings and analysis of over 700 samples for total and
hexavalent chromium on the Site. Based on the RI soil data, the horizontal and vertical extent of
hexavalent chromium above the most stringent NJDEP Soil Cleanup Criteria of20 mglkg has been
characterized and delineated.
This RASR/RA WP presents an evaluation of remedial alternatives and selected remedial actions to
address chromium contamination, to be implemented as part of the Site redevelopment activities.
Working with NJCU, Honeywell has developed a viable and protective remedy to address contamination
associated with the historical placement of chromium-containing fill at the Site. Currently, an interim
remedial measure (IRM) consisting of pavement and existing floor slabs serve as a cap to prevent direct
contact with contaminated soils. NJCU plans to redevelop the land into a mixed-use facility, referred to as
the NJCU West Campus Development, consisting of student housing, retail, and other educational facilities.
Under the current redevelopment plan, it is anticipated the existing pavement and building foundations will
be removed, and a remedy to address chromium contamination will be implemented.
The remedial approach takes into consideration the recently issued Chromium Policy (NJDEP
Memorandum dated 2/8/07) and NJCU's redevelopment plan, which includes residential and commercial
uses. Honeywell, following the guidance ofthe Chromium Policy, has selected remedies that address the
site uses. The components of the proposed remedial actions for chromium include:
• Pre~remediation activities including obtaining property access agreements; remedial design; and
regulatory approvals including soil reuse plan approval (if necessary), soil erosion sediment control plan
(SESCP) certification, and local construction permit approvals.
• Excavation of chromium-impacted soils in the Residential AGC (RAOC). Soils containing hexavalent
chromium above 20 mg/kg in the RAOC will be excavated to a maximum depth of20 feet. As a
conservative measure, Honeywell has extended the RAGC out from the footprint of residential use
buildings to the nearest physical feature of the adjoining commercial area (CAGC).
• Engineering controls for soils exceeding 20 mgikg in the CAGe. The engineering controls include a
capping barrier with impervious geo-membrane liner, geo-composite drainage layer, and minimum
two fect clean soil cover, or minimum I-foot clean soil and pavement cover.
• Additional focused soil excavation may be performed to provide clean utility corridors in connection
with the proposed Site development and to coordinate the proposed capping system with proposed
Site development features along Route 440. Soils excavated for utility corridors and grading for cap
installation will be re-used by consolidation and capping on-site.
TIERRA-B-015013
• Installation of an in-situ permeable reactive barrier (PRE) that will use biologically mediated reduction
for treatment of hexavalent chromium. The PRE will run primarily along the western border of the Site.
• Implementation of an in-situ groundwater treatment system to address residual source material on the
Home Depot property (Site 117), which is contributing to the deep groundwater chromium plume. An
impermeable hydraulic barrier will be installed along the southern property line of the Site to
hydraulically isolate remediated areas on the Site from "source area" groundwater on Home Depot.
• Institutional Controls (Deed Notice) for soils above 20 mg/kg hexavalent chromium, including
maintenance of existing engineering controls (e.g., concrete, pavement) and newly installed controls
during the remedial action and Site redevelopment (e.g., engineered barrier, clean fill, paving).
This RASRJRA WP addresses soils and shallow groundwater impacted by chromium contamination
above applicable remediation criteria, and satisfies the Technical Requirements for Site Remediation
while incorporating the objectives of New Jersey's Brownfields Program. While the NJCU final design
and development work progresses, Honeywell will proceed with final engineering design activities. The
remedy for soils takes into consideration the current NJDEP chromium policy and current redevelopment
plans by NJCU. NJCU is in agreement with deed notice restrictions for the remedial approach in this
RAWP.
The proposed remedial actions for the portion of Site 153 (Former Morris Canal) abutting Sites 090/184
(NJCU Property) include limited soil excavation as may be required for cap installation and for providing
clean utility corridors to support the proposed Site development by NJCU. Honeywell has proposed to
buy this portion of the former Morris Canal from the Bayonne Municipal Utilities Authority (BMUA),
and anticipates successful completion of this purchase in the next several months. At that point, as the
property owner, Honeywell would agree to deed notice and institutional controls for this property.
The R1 data for the Site and data from the regional groundwater investigation being conducted under the
oversight of a court-appointed Special Master for Study Area 7, demonstrate that shallow groundwater
conditions at the Site are not a source of the groundwater impacts in the deep groundwater zone. Further
investigations and remedial actions for the deep groundwater zone are being addressed under separate work
plan(s) subject to review/approval by the Special Master for Study Area 7. The Final Groundwater
Investigation Report (GIR), for the regional investigation, was submitted to the Special Master and NJDEP
on February 2, 2007 (HydroQual, Inc., 2007).
Based on the Final GlR and additional data collected at Site 117 (adjacent to Site 090), an in-situ
groundwater treatment system is proposed by Honeywell to address the residual source on Site 117
contributing to the regional groundwater contamination. The proposed groundwater treatment system is
included with this RA WP for NJDEP review and approvaL
TIERRA-B-015014
1.2 REPORT ORGANIZATION
This RASR/RA WP has been prepared to meet the provisions specified in the New Jersey Technical
Requirements for Site Remediation, NJ.A.C. 7:26E-5.2 and 6.2, and contains the following sections:
1. Introduction. This section contains background infonnation and describes the report
organization.
2. Site Description. This section contains information on Site location, history, soils, geology,
hydrogeology, topography and surface water bodies, previous remedial investigations, and
remedial actions.
3. Summary of Remedial Investigation Activities. This section contains a summary of RI soil and
groundwater investigation results, including a summary of previous investigations and the
supplemental Rl activities completed during 2005.
4. Remedial Action Selection Report. This section identifies remediation objectives and includes
information pertaining to remedial action selection pursuant to N.J.A.C 7:25E-5.2.
5. Remedial Action Work Plan. This section describes the work elements of the proposed remedial
action pursuant to N.J.A.C 7:26E-6.2.
6. Remedial Action Report. This section describes the items to be included in a report documenting
the completion of the remedial action activities.
7. References. This section presents a list of selected references used in preparing this document.
8. List of Acronyms/Abbreviations. This section includes a list of acronyms used in this document.
TIERRA-B-015015
2.0 SITE DESCRIPTION
This section presents a Site description and background information for the portion of SA-5 that is the
subject of this document: Baldwin Steel (Site 090), M.L Holdings (Site 184), and the northern portion of
the Former Morris Canal (Site 153) next to the Baldwin Steel and M.L Holdings Sites. The property
comprising Sites 090 and 184 is owned by NJCU. The portion of Site 153 abutting Sites 090 and 184 is
owned by the City of Bayonne Municipal Utilities Authority (BMUA) and is in the process of being
acquired by Honeywell.
The property consists of a rectangular parcel (approximately 1,000 feet long and about 300 feet wide)
bordered on the north by M.L Holdings (Site 184), on the east by an inactive rail spur line and property
occupied by NJCU, on the south by a retail shopping center (Site 117; Former Ryerson Steel or Home
Depot site), and on the west by the Former Morris Canal (Site 153) and Route 440. With the exception
of paved parking areas bordering Route 440 and a paved corridor along the south side of the property
(between the former Baldwin Steel building and aforementioned retail shopping center), the property is
covered by the former building slab (estimated 650 feet long by 250 feet wide or 162,000 square feet).
The Baldwin Steel Site was previously used for storage, cutting and rolling of various types of steel (e.g.,
aluminized, galvanized, cold-rolled, etc.), typically used for fabrication into ductwork. Tractor trailers
delivered raw materials via access from West Side Avenue and exited the facility at the western end onto
Route 440. A rectangular office space was located at the rear of the plant and connected the ,plant to an
irregularly-shaped storage building. The building was a large structure constructed of a concrete
foundation, steel colunms, steel and wooden trusses, and corrugated steel siding. The office and storage
buildings were constructed of con'crete foundations and brick. The office building was a one-story
structure, while the storage building was two stories. No sub-grade floors or basements existed in the
building structures, with the exception of press pits located beneath some ofthe heavy equipment used
for cutting and rolling. It is believed that the buildings were constructed prior to 1930.
Site utilities include electrical service, water, sanitary sewer, storm sewer, and fuel oil lines. All utilities
are located underground with the exception of the electrical lines, which include both overhead and
underground lines. An underground water line which provides water to three hydrants on-Site is also
TIERRA-B-015016
located along the roadway on the south side of the former Baldwin Steel building. Potable and non-
potable water entered the former office/storage building and the plant via lines from West Side Avenue
in the northeast comer of the property. The sanitary sewer line ran along the interior of the plant
building and tied into a sanitary sewer line along Route 440.
The Baldwin Steel Site is surrounded by a chain-link fence ranging from four to eight feet in height.
Access to the property is from three gates, one located at the rear of the facility which allows access from
West Side Avenue and two located at the front of the property for access from Route 440. The entire
property is either occupied by building floor slabs or is covered with paving. All areas on the site were
paved as a result of remedial action upgrades during an Interim Remedial Measure (IRM) completed in
1990 by a contractor for Honeywell (formerly Allied Signal). The pavement on the east and south side
(along the Former Ryerson Steel property boundary) of the building is uneven, possibly due to placement
of underlying fill material in this area.
The M.l. Holdings Site is bordered by Carbon Place to the north, Route 440 to the west, Baldwin Steel
(Site 090) to the south, and property occupied by NJCU to the east. The majority of the property is
paved, with several small lawn areas and a chain-link fence around the perimeter of the property. The
Site contains three (3) buildings and paved parlGng lot areas. In 1993, Woodward-Clyde Associates
completed a remedial action at the Site, which included excavation of mercury/chromium-impacted soils,
building demolition, and asphalt capping. The paved areas are in good condition, with no evidence of
cracks or potholes leading to exposure to underlying fill soils. The property is surrounded by a chain link
fence approximately IO-feet in height, with access to the property from several entrance gates along
Carbon Place and from the eastern side of the property along West Side Avenue. Site physical features
also include overhead utilities (electrical lines) and underground utilities (gas, water, and sewer lines).
TIERRA-B-015017
2.2 SITE HISTORY
The operating history for the properties comprising the Site was documented in the Remedial Investigation
Report (RJR) dated November 1999 (TetraTech, 1999). Site history for the Baldwin Steel and M.L
Holdings Sites are summarized below.
No detailed historical information regarding the placement of Chromium Ore Processing Residue
(COPR) on this property is available. It is believed that chromite ore was stored on a portion of Lot 6D
by the Mutual Chemical Company during approximately 60 years of operation.
Prior to 1940, Mallinclcrodt produced inorganic chemicals such as salts or oxides of iron and mercmy.
During the 1940s, Mallinckrodt participated in the Manhattan Project under contract with the U.S.
Government for the testing of uranium trioxide. Mter World War II, the plant continued to produce
mercury compounds and other inorganic chemicals such as zinc acetate, potassium sulfate, potassium
chloride, ferrous sulfate, ferric chloride, and sodium nitrate. Production of mercury compounds ended
around 1974, when general facility improvements were made including demolition of the mercury
production equipment and various buildings. The majority of the open areas on the property were paved
at that time.
From thc 1940s to approximately 1980, Mallinckrodt also conducted packaging operations (both wet and
dry operations) at the facility for a variety of both organic and inorganic chemicals. Some of the liquid
packaging operations included preparation of bottles of alcohols, acetone, xylenes, benzene and toluene.
Organic liquids were received by railroad or truck in drums and carboys before packaging in bottles. The
bottled liquids were stored in various warehouses at the facility. Mineral acids and ethers were also
received by railroad for packaging operations. In the late 1970s, most ofMallinckrodt's operations
decreased to the production or packaging of the chemicals noted above as a result of the transfer of
material handling and sub-division (packaging) operations to a new plant in Kentucky. In the early
1980s, Mallinckrodt's production of chemicals was primarily limited to calcium and zinc stearate
dispersions. All other production operations (packaging of organic and inorganic chemicals) ceased by
1982. Zinc stearate dispersion production ceased in the late 1980s. More recent operations by M.I.
Holdings were limited to the production of calcium stearate dispersions. As previously noted, a remedial
TIERRA-B-015018
action was conducted on behalf ofM.I. Holdings by Woodward-Clyde Associates during 1993. The
remedial action consisted of excavation of mercury/chromium-impacted soil, building demolition and
asphalt paving as a cap. A deed notice and classification exception area (CEA) was also established for
the western portion of the site.
Regional Geology
Jersey City is located within the upper portion of the drainage basin for Newark Bay, and lies within the
glaciated section of the Piedmont Province. The bedrock in most of the region is comprised of Lower
Jurassic to Upper Triassic age sedimentary rock units known as the Newark Supergroup, and was formed
from sediments deposited within a northeast-southwest trending structural basin known as the Newark
Basin. The sedimentary rocks of the Newark Supergroup in New Jersey are composed of reddish-brown
arkosic sandstone, mudstone, siltstone, conglomerate, and dark gray argillite. These sedimentary rock
units have been intruded by igneous rock units (primarily diabase) in the form of sills and dikes, which
now generally form ridges such as the Palisades and the Heights in Jersey City.
The Newark Supergroup has been divided into three formations on the basis of distinctive lithology: (1) a
lower unit identified as the Stockton Formation; (2) a middle unit identified as the Lockatong Fonnation;
and (3) an upper unit identified as the Brunswick Group. Based on geologic mapping performed across
northern New Jersey, including Study Area 5 (Drake, Jr., et aI., 1996), it is anticipated that SA-5 overlies
a contact between the predominantly mudstone units of the Lockatong Formation and the north-northeast
trending diabase dike to the east. Regional mapping also indicates a north-northeast trending, southeast
dipping normal fault lies approximately one-half mile east of the Site. Additional geologic information is
currently being collected as part of the SA-7 investigation.
The beds of the Newark Supergroup generally strike to the northeast in the Hackensack River basin and
dip at approximately 16 degrees to the west-northwest. A prominent set of vertical joints strike N 45° E,
approximately parallel to the strike of the beds. A less prominent set of nearly vertical joints strike north
75 degrees west, sub-parallel to the dip of the bedding (Anderson, 1968). Faults, where present, typically
strike northeastward and are parallel to or intersect the strike of the beds at low angles. The bedrock
surface is irregular, shaped by pre-glacial and interglacial streams and further modified by glacial scour.
TIERRA-B-015019
The bedrock surface is overlain by glacial till/stratified lacustrine deposits, and alluvialliacustrine
deposits laid down by several glacial advances across the area, principally during the Wisconsin glacial
period. The glacial till is generally described as an unsorted mix of sand, gravel, silt and clay in a
continuous layer overlying bedrock, as well as in discontinuous lenses within the stratified lacustrine
deposits. The lacustrine deposits generally consist of very fine sand, silt and clay with noticeable
layering and varves characteristic of alluvial deposition. The alluviaVlacustrine deposits are typically
characterized as a fine to medium sand with some silt that appear to coarsen to the east.
The various glacial deposits are typically overlain by Holocene age alluvium deposited within the
floodplains of present day streams. Meadow mat, consisting of decaying marsh deposits, is also found in
many low lyin g areas and much of the region has been artificially filled with material of varying
composition in an effort to raise the ground surface above the surrounding surface water features.
Site Geology
Fill Material
The majority of the ground surface at the Site is covered with asphalt pavement (parking lots, roads) or
buildings, which overlie a continuous layer of man-emplaced fill material. The fill ranges in thickness
from approximately 5 to 17 feet, with an average thickness of 10 to 12 feet, and generally consists of silty
sand with miscellaneous construction debris such as gravel, brick, glass, wood, and concrete. Slug test
results for the fill zone indicate generally low permeability on the order of approximately 0.5 feet/day.
Meadow Mat
Meadow mat consists of a highly organic deposit of peat and fine-grained sediments that occurs in a thin
layer in the western portion of the Site. Meadow mat is generally not present beneath the majority of the
Site further east from the fonner Moms Canal.
Lacustrine Sand
The Lacustrine Sand has generally been described as a fine to medium sand with some silt that directly
underlies the fill material and meadow mat (where present). Occasional discontinuous layers of brown-
gray sand are present near the top of the unit as are fine-grained silt lenses throughout. This unit
correlates to the S-2 Sand identified beneath SA-7. The thickness of this unit general1y increases from
east to west and from north to south and is bifurcated beneath SA-7 by a red clay unit. Three (3) slug
tests conducted in the Lacustrine Sand during the Rl suggest hydraulic conductivity values on the order
of 0.5 feet/day, whereas eleven slug tests constructed in wells screened within this stratum beneath SA-7
suggest hydraulic conductivity values on the order of 5.0 feet/day.
Bedrock
The bedrock consists of the Triassic age Lockatong formation of the Newark Supergroup and may be
underlain in the eastern most area by Diabase. The bedding planes dip generally to the northwest at
approximately 15 degrees while the bedrock surface generally slopes to the southwest. The bedrock is
approximately 110 ft below ground surface in the vicinity of the SA-5 (HydroQual, February, 2007).
TIERRA-B-015020
2.3.2 Regional and Site Hydrogeology
Regional Hydrogeology
The Site is located in a broad area of low relief near Newark Bay, with expected low groundwater
gradients. Close to the bay, shallow groundwater is influenced by tidal fluctuations, with low-lying and
marshy areas being only slightly above high tide. Regionally, groundwater flow is generally toward the
major water bodies in the area, including the Hackensack River, Passaic River, and Newark Bay. These
major water bodies serve as regional groundwater discharge points and hydrogeologic boundaries. The
size and influence of these water bodies is such that groundwater will not migrate across them, but will
discharge to the rivers and the bay.
The groundwater underlying the Hudson County Chromium Sites can be characterized as a multi-aquifer
system. In general, there are two water-bearing zones/systems underlying the study area: (I) a surficial
water-bearing zone within unconsolidated materials consisting of man-deposited fill, glacial drift
(composed of clay, silt, sand, gravel, and boulders), fluvial fine- to medium-grained sand, and (2) the
underlying water-bearing zone within fractured bedrock.
Groundwater in the shallow, unconfined to semi-confined water-bearing zone is recharged through direct
infiltration of precipitation. Groundwater movement within this zone is through pore spaces between
sediment grains. Depths to groundwater vary from less than one foot to 10 feet bgs or more. The
direction of shallow groundwater flow is toward local surface waters that serve as groundwater discharge
points, including small, unnamed drainages, the nearby rivers, and Newark Bay. Close to the rivers and
the bay, shallow groundwater is tidally influenced.
Site Hydrogeology
Groundwater beneath the Site occurs within the fill material and underlying lacustrine sand deposits
under unconfined conditions, and within the underlying bedrock under confined or semi-confined
conditions. A layer of meadow mat in the western portion of the Site, separates the fill material from the
underlying natural formations. Where the meadow mat is absent, the two units may be in contact.
Existing data shows that the upper (fill) and deeper (natural) groundwater bearing zones are distinct,
where separated by the meadow mat. Groundwater flow pattern and direction are different in the two
units. Contaminant distribution profiles in the two units are also distinct. Chromium is the only
contaminant detected in the deeper zone, while a suite of contaminants has been detected in the shallow
zone. The SA-7 investigation has shown that, where the meadow mat is present, chromium has not
migrated vertically from the shallow to the deeper zones. Based on these data, it has been concluded that
contamination in the shallow zone above the meadow mat is associated with chromium-impacted fill,
while contamination in the deeper units is related to historical discharges at the former Mutual Chemical
facility located south of the Site.
Groundwater flow in the area of the Site has been mapped as part of the comprehensive SA-7
investigation, which has identified four hydrostratigraphic zones as follows:
Shallow Zone - above the meadow mat and generally in fill material
Intermediate Zone - just below the meadow mat (generally not present beneath SA-5)
Deep Zone - within the lacustrine deposits just above the glacial till/ice contact deposits
Upper Bedrock Zone - Just below the top of bedrock
10
TIERRA-B-015021
Regional groundwater contour maps for the Shallow and Deep Zones are presented on figures in
Appendix A. The groundwater contour maps indicate that groundwater flow in the fill material (Shallow
Zone) is generally to the west or northwest and is strongly influenced by near surface features such as the
stonn sewer along Route 440. Groundwater flow in the lacustrine deposits (Deep Zone) is similarly to
the west-northwest, with little or no influence from near surface features, thus groundwater flow
continues west and northwest to the Hackensack River. Groundwater flow within the Upper Bedrock
Zone beneath SA-7 is to the northwest, and similar conditions are expected beneath the Site.
As previously indicated, slug test data for the Shallow Zone (Fill) indicate a relatively low permeability
for the fill material of approximately 0.5 feet/day, with an estimated flow velocity of 3 feet/year based on
average gradient of 0.005 and porosity of 30% (TetraTech, 1999). Slug test data for the Deep Zone
(Lacustrine Sand) indicate hydraulic conductivity values on the order of 5.0 feet/day, with an estimated
flow velocity on the order of 18 feet/year based on an average hydraulic gradient of 0.003 and porosity of
30%. Limited data available for the glacial till/ice contact deposits suggest hydraulic conductivities on
the order of 0.1 feet/day.
Based on information from the RIR, there are no public water supply wells located in Hudson County. A
previous file search was conducted during 1999 at the NJDEP Department of Water Allocation Division
office in Trenton, NJ. Coordinates of the study area were supplied, and microfilm records of wells
within one mile of the study area were obtained. A review of the information indicates that there are no
industrial or public water supply wells down-gradient from the Site.
The Fonner Morris Canal runs north-south along the western boundary of the Site along Route 440. The
portion ofthe canal through Jersey City opened in 1836 and was filled with salt water, and this section of
the canal was equipped with tide locks at both ends that prevented the water from flowing out at low tide
(http://www.jerseycityonline.comlmorris_cana1.htm). The canal was closed and drained in 1924. The
canal was subsequently filled in and no visual evidence of the former canal exists. The majority of the
former canal area is now covered with pavement, and the portion of the former canal next to the Site
contains a sewer line.
No surface waters are present at or adjacent to the Site. The principal water bodies in the vicinity of the
subject Site include the Hackensack River, Passaic River, and Newark Bay. The nearest surface water
body is the Newark Bay, located approximately 4,000 feet to the west. The Site is located within the
Hackensack River basin, which extends northward from Newark Bay into southeastern New York State.
The Hackensack River is used for water supply in the upper reaches of the basin; however, in the vicinity
of the Site, the river is classified as SE-3 (saline estuarine waters) with the following designated uses:
II
TIERRA-B-015022
3. Migration of diadromous fish;
4. Maintenance of wildlife; and
S. Any other reasonable uses
Several municipalities draw water from the river during the summer months, resulting in very little net
flow in the lower reaches of the river during the time periods of water diversion from the river. This
results in poor flushing of the lower reaches (tidal portion) of the river during these time periods.
The Hackensack River is tidally influenced along the reach adjacent to Jersey City. According to
National Oceanic and Atmospheric Administration (NOAA) records, the mean tide level of the
Hackensack River in the area of Jersey City is approximately 2.84 feet above MSL and the mean tide
range is approximately 5 feet. Water quality in the Hackensack River is affected by industrial discharges
(over 100 permitted discharges into the river) and by the tides. Low dissolved oxygen levels are common
in the river during the summer, and total dissolved solids levels are slightly to moderately saline.
Previous investigations and remedial actions conducted at Site 090 (Baldwin Steel) and Site 184 (M.l.
Holdings) prior to the Rl are summarized in this section, along with information on Site 153 (Fonner
Morris Canal) located along the western boundary of Sites 090 and 184. R1 results based on the findings
from the RlR and RIR Addendum are presented in Section 3.0.
A contractor for Allied Signal, Inc. completed an Interim Remedial Measure (asphalt cap) at the Baldwin
Steel Site in 1990. Capping of areas of exposed soil was completed during the Interim Remedial
Measure. This remedial measure was completed to prevent direct contact exposures, control potential
fugitive dust emissions, reduce percolation of precipitation, and prevent overland runoff of chromium
containing materials. A contractor for Allied Signal, Inc. also upgraded the asphalt cap by placement and
rolling of additional asphalt along the southern fence line in October 1994.
12
TIERRA-B-015023
M.1. Holdings (Site 184)
SamplIng and analysis of soil and groundwater were conducted by A WD Technologies and Woodward-
Clyde Consultants. A WD Technologies installed six (6) monitoring wells at the Site in 1987 (three
shallow and deep clusters) and sampled these wells on three occasions in 1987 and once in 1988. In
addition, three (3) soil samples were collected during the installation of these wells. In 1993, Woodward-
Clyde collected surface and subsurface soil samples at 17 locations in the southwestern comer of the
property and subsequently collected eight (8) post-excavation sidewall samples. Woodward-Clyde also
completed one round of monitoring well sampling and analysis in 1993. Total chromium concentrations
were detected in soil samples up to 36,000 mglkg. Total chromium concentrations were detected in
unfiltered and filtered groundwater samples up to 2.24 mg/I and 2.0 mg/I, respectively.
A remedial action was conducted at the M.l. Holdings Site by Woodward-Clyde in 1993. The remedial
action was conducted to remediate (remove) soil containing mercury. Based on a summary report
prepared by Woodward-Clyde, approximately 900 cubic yards of sail/fill were excavated from three
areas located in the southwestern comer of the property. Excavation depths ranged from two to
three feet. A narrow strip of land along the western boundary of the Site was not remediated. This
portion of the Site was investigated during the RI for soils.
TetraTech, Inc. on behalf of New Jersey City University (NJCU) performed additional RI activities on
the Site during 2004-2006 to address non-chromium contaminants under a Memorandum of Agreement
with the NJDEP. The additional RI activities included geophysical survey, test pit investigation, soil and
groundwater sampling, and baseline ecological evaluation (BEE). The results of these activities were
documented in a Remedial Investigation ReportlRemedial Action Work Plan (RIRIRA WP) (TetraTech,
February 2006), which is currently under review by the NJDEP. The recommendations proposed in the
RIRJRA WP include pre-design investigations, investigation of catch basins and sewer lines, investigation
of sub-slab areas following removal of building slabs, and further delineation of chlorinated VOCs (e.g.,
carbon tetrachloride) in groundwater. The recommended remedy includes extension of the existing cap
and deed notice area to cover the entire Site, and maintaining the existing CEA for residual groundwater
contamination. A figure illustrating the proposed remedial actions is included in Appendix A-5.
13
TIERRA-B-015024
3.0 SUMMARY OF REMEDIAL INVESTIGATION RESULTS
This section presents a summary of the RI results for Baldwin Steel, M.L Holdings, and the northern
portion of the Fonner Morris Canal based on information presented in the RIR and RIR Addendum
(TetraTech. 1999; 2004). A more detailed discussion of the RI data including results for other sites
comprising SA-5 is presented in the RIR dated November 1999. Additional soil delineation data for
Baldwin Steel and M.l. Holdings is presented in the RIR Addendum dated September 2004. Relevant
data summary tables and figures from the RlR Addendum are included for reference in Appendix A.
Comprehensive soil analytical data for hexavalent chromium (including the extent of soils containing
hexavalent chromium above 20 mglkg) is presented on Figure 3.
This section also presents results of additional Rl activities completed during 2005, as specified in the
March 2005 RIWP Addendum for Shallow Groundwater submitted to the NJDEP. The additional Rl
activities were conducted to collect additional data for evaluation of remedial actions for chromium
contaminated fill that may be acting as a potential source of shallow groundwater impacts at the Site, and
included additional soil borings and monitoring wells. Copies of well permits are provided in Appendix B.
A total of nine (9) soil borings were advanced using hollow-stem auger (HSA) drilling methods and/or
direct-push sampling equipment. The borings included seven (7) locations in the western portion of Site
90 (Baldwin Steel) and two (2) locations on Site 184 (M.!. Holdings), designated as follows:
Soil borings were advanced to a maximum depth of approximately 20 feet bgs, and soil samples were
collected using split-spoon samplers. Soil samples were visually inspected for the presence of COPR
(e.g., yellow-green or colored staining or nodules), and field screened for the presence of organic vapors
using a photo-ionization detector (PID). Soil boring logs are included in Appendix C.
Soil samples were collected from three (3) locations (090-S8-003, 004,005) and submitted for laboratory
analysis for total chromium and hexavalent chromium to provide additional data for delineation beneath
the existing building. Selected soil samples were also submitted for laboratory analysis for Synthetic
Precipitation Leaching Procedure (SPLP), total and hexavalent chromium. Selected samples were also
collected and submitted for grain size analysis. Sample depth intervals for SPLP analysis corresponded
14
TIERRA-B-015025
to depths with elevated hexavalent chromium based on previous soil data. A surrunary of the soil and
SPLP sample results is presented in Table lA and grain size analysis results are included in Table IB.
Laboratory analytical parameters and methods for the soil sampling program included:
SPLP by USEP A Method 1312 with totaVhexavalent chromium analysis on the leachate
Total Chromium by USEPA Method 3050B/601GB
Hexavalent Chromium by USEPA Method 3060AJ7l96A
Grain Size by ASTM Method D422
Data validation was performed by Validata, LLC of Seattle, W A. Data validation procedures included
validation of all samples analyzed for chromium and hexavalent chromium. Based on the data validation
results, the laboratory analytical data were determined to be acceptable, with minor qualifications. Soil
sample laboratory reports and data validation summary reports are included in Appendix F. Electronic
data deliverables are provided in Appendix M.
AIL soil sampling locations were surveyed for horizontal coordinates and surface elevations by Keller &
Kirkpatrick of Parsippany, NJ. The horizontal datum was established to within 0.10 foot using the New
Jersey System of Plane Coordinates (NAD 83). Vertical elevations were established to within 0.01 foot
using the North American Vertical Datum (NA VD 88).
Four (4) shallow monitoring wells were installed during April 2005 to depths ranging from 12 to 16 feet
bgs. The monitoring wells are identified as follows:
090-MW-OlO: within area of chromium-impacted soils in southwest portion of property
090-MW-011: perimeter of chromium-impacted area, upgradient of existing well MW-090-EOI
184-MW-001 : upgradient of chromium-impacted soils
184-MW-002: within the area of chromium-impacted soils in the northwest portion of the property
Monitoring wells were installed using HSA drilling methods and constructed of 2-inch diameter schedule
40 PVC well materials, with flush mount protective casing.· Following installation, each monitoring well
was developed in accordance with NJDEP requirements to remove drill cuttings and/or formation fines
from the well screen. Monitoring wells were screened across the water table to provide groundwater
quality data for the shallow water-bearing zone (fill). Monitoring well records and construction diagrams
are provided in Appendix D. A surrunary of the construction details is provided below.
15
TIERRA-B-015026
Two (2) rounds of groundwater sampling were completed during 2005 including one round on April 28,
2005 and a second round on May 31, 2005. Three (3) rounds of groundwater sampling were completed
during 2006 as follows: May 10,2006, August to, 2006, and December 13, 2006. Groundwater
monitoring well sampling procedures included low flow purge/sample methods. Field sampling included
water level measurements and the collection of field parameters including pH, temperature, conductivity,
dissolved oxygen (DO), and reduction-oxidation potential (Redox). Groundwater sampling field data
sheets and groundwater contour map reporting forms are included in Appendix E.
HydroPunch groundwater samples were also collected during soil boring activities from two soil borings
(SB-003 and SB-005) and analyzed for total and hexavalent chromium (unfiltered and filtered) to provide
additional data on shallow groundwater for the southern portion of the Site beneath the existing building.
Groundwater grab sample 090-PZ-OOl was collected from 090-SB-003 borehole, and sample 090-PZ-002
was collected from 090-SB-005 borehole. The screened interval at both locations was from 3 to 13 ft bgs.
Groundwater samples were submitted for laboratory analysis for total and hexavalent chromium
(unfiltered and filtered). The first round of sampling also included the following additional watcr quality
parameters to provide additional data for evaluation of natural attenuation and groundwater treatment
options: pH, alkalinity, calcium, iron, magnesium, ferrous iron, sulfate, and total organic carbon (TOC).
Groundwater sampling results for samples collected during 2005 and 2006 are summarized on Tables 3
and 4, respectively.
The groundwater sampling completed during May 2006 included analysis of additional parameters
including Target Analyte List (TAL) metals, chlorides, hardness, nitrates, salinity, specific conductance,
sulfides and total dissolved solids (TDS). Data validation was performed by Validata, LLC of Seattle,
W A Data validation procedures included validation of all samples analyzed for chromium and
hexavalent chromium, and approximately ten (10) percent of samples analyzed for other parameters
following NJDEP standard operating procedures for validatlon of analytical data. Based on the data
validation results, the laboratory analytical data were determined to be acceptable, with some
qualifications. Two (2) groundwater grab samples (filtered samples) (90-PZ-00IF and 90-PZ-002F)
submitted for hexavalent chromium analysis were rejected because the samples exceeded the required
holding time; however total chromium results were acceptable for these locations. Groundwater sample
laboratory reports and data validation summary reports are included in Appendix G. Electronic data
deliverables are provided in Appendix M. Groundwater elevation data are presented in Table 5.
Groundwater contour mapss are included as Figures 4A through 4E. Groundwater contour reporting
forms are contained in Appendix E-2.
16
TIERRA-B-015027
3.3 SOIL INVESTIGATION RESULTS
The Rl soil investigation activities were conducted in several phases, with results summarized below.
The RI soil investigation was conducted in several phases during 1997 to 1999 and reported in the Draft
RIR (Tetra Tech NUS, Nov, 1999). A total of 47 soil borings (up to 8 feet bgs) were completed on the
subject Sites, including 15 borings at Baldwin Steel, 12 borings at M.I. Holdings, and 20 borings within the
Former Moms Canal. Samples were collected from selected depth intervals for submittal for laboratory
analysis for total and hexavalent chromium. Approximately ten percent of the soil samples were also
analyzed for Target Compound List (TCL) volatile organic compounds (VOCs), semi volatile organic
compounds (SVOCs), and pesticide/polychlorinated biphenyls (PCBs); TAL metals; and total petroleum
hydrocarbons (TPH).
Subsurface Soil: Chromium (total) was detected in all of the 82 subsurface soil samples, with the
maximum concentration (36,800 mg/kg) detected at sample location 090-5B-808 collected from a depth
interval of 12 to 14 feet bgs near the southern boundary. Hexavalent chromium was detected in 61 of 82
subsurface soil samples at concentrations ranging from 2.6 mg/kg to 8,210 mg/kg, with maximum
concentration (8,210 mg/kg) in sample 090-SB-EOl, collected from a depth interval of 8 to 10 feet bgs in
the western portion of the Site. No other anatytes were detected above the NJDEP sec, with the
exception of arsenic in two samples (samples 090-8B-B02, 2-4 ft bgs: 42 mg/kg and 090-SB-C03 10-12
ft bgs: 39 mglkg) above the sce of20 mg/kg.
Subsurface Soil: Chromium (total) was detected in all of the 56 subsurface soil samples at concentrations
ranging from 3,5 mg/kg to 35,000 mg/kg. Hexavalent chromium was detected in 26 of 56 subsurface soil
samples at concentrations ranging from 2.6 mglkg to 8,080 mg/kg. The maximum concentration of total
and hexavalent chromium was detected at I 84-SB-A03, collected from a depth interval of 4 to 6 feet bgs
along the northwest comer of the Site.
Other constituents detected in subsurface soil samples included several VOCs (benzene, chloroform,
methylene chloride, dichlorobenzene, ethylbenzene) at low concentrations (less than 1-2 mg/kg) below
17
TIERRA-B-015028
the sec. PAHs and metals were also detected at concentrations below the sec, with the exception of
copper (Sample 184-SB-A02-0406: 659 mg/kg) detected slightly above the SCC of 600 mglkg.
Surface Soils: Chromium (total) was detected in all five surface soil samples at concentrations ranging
from 59.3 mglkg to 11,200 mglkg (153-SB-05). Hexavalent chromium was detected in all five surface
soil samples at concentrations ranging from 5.4 mglkg to 624 mglkg. The maximum detection of total
and hexavalent chromium (total) was at sample location 153-SB-A05 (0-2 fi bgs), collected near the
southwest corner of Site 090. Surface soil samples were not analyzed for any other parameters.
Subsurface Soil: Chromium (total) was detected in all of the subsurface soil samples at concentrations
ranging from 9.8 mglkg to 39,800 mg/kg. Hexavalent chromium was also detected in all of the
subsurface soil samples at concentrations ranging from 2.5 mg/kg to 9,150 mg/kg. The maximum
concentrations of both total and hexavalent chromium were detected in sample 153-SB-A05, collected
from a depth interval of 6-8 ft bgs near the southwest corner of Site 090.
Benzene was detected in sample 153-SB-A03 (1.3 mg/kg; 8-10 ft bgs) slightly above the NJDEP Impact
to Groundwater Soil Cleanup Criteria of 1 mglkg near the western boundary of Sites 090 and 184.
The RIR Addendum (Tetra Tech NUS, Oct. 2004) presents results of additional soil borings and
sampling conducted during 2003 on the properties subject to redevelopment by NJCU, including 34
borings at Site 090 (Baldwin Steel) and 12 borings at Site 184 (M.L Holdings). Approximately 440
samples were analyzed for total and hexavalent chromium. The report also includes sampling results for
the portion of the Former Morris Canal adjacent to the Baldwin Steel and M.I. Holdings Sites.
Total chromium concentration ranged from 1.9 to 69,600 mg/kg, with the highest concentration detected
at090-SB-20 (8-10 ft bgs) in the southwestern portion of Site 090 (Baldwin Steel). Hexavalent
chromium concentration ranged from less than 2 mglkg to 28,400 mg/kg in sample 090-88-114, which
was collected at a depth of 6 to 8 feet bgs in the southwestern portion of Site 090 (Baldwin Steel).
Three (3) additional borings (184-SB-13, 184-SB-14, and 090-SB-37) were completed by Tetratech in
February 2005 to provide additional data in the eastern portion of the Site. A total of30 soil samples
were collected and analyzed for total and hexavalent chromium from various depth intevals, and results
indicated that hexavalent chromium was detected above 20 mg/kg in one sample (090-SB-13; 88.4 mg/kg
at 0-2 ft bgs). All other samples contained less than 20 mg/kg of hexavalent chromium.
The RI soil data indicate that the horizontal and vertical extent of hexavalent chromium above the
NJDEP soil cleanup criteria of 20 mg/kg was delineated (Figure 3). The portion of the proposed
redevelopment area impacted by hexavalent chromium concentrations is along the western and
southwestern boundaries (estimated at approximately 4.5 acres). The impacted area is bounded by the
Baldwin Steel (Site 090) boundary to the south (adjacent Site 1 17 has already been capped by
Honeywell), the Morris Canal Site to the west (where RI efforts are ongoing), and clean borings (no
exceedances of 20 mglkg) to the north and east within the Baldwin Steel and M.L Holdings property
18
TIERRA-B-015029
boundaries. Hexavalent chromium concentrations slightly above 20 mglkg were detected in shallow soils
beneath existing pavement at a few isolated locations outside the main chromium-impacted fill area.
Hexavalent chromium results exceeding the NJDEP soil cleanup criteria are indicated on Figure 3. The
RIR and RIR Addendum text and tables with soil sample results for total and hexavalent chromium are
included in Appendix A for reference.
Soil samples were collected from three (3) locations (090-SB-003, 090-SB-004, 090-SB-005) to provide
additional data for horizontal delineation in the southern portion of Site 090 beneath the existing building
(as indicated on Table 1 and Figure 3). Total chromium concentrations ranged from 4.1 mg/kg to 555
mglkg, with the maximum concentration of total chromium detected in sample 090-SB-003 (12-14 feet
bgs). Total chromium did not exceed the NIDEP sce of 120,000 mglkg for trivalent chromium.
Hexavalent chromium concentrations were less than 20 mglkg, with the exception of one sample: 090-
SB-003 (91.3 mglkg at 12-14 ft bgs). Grain size analysis was performed on samples obtained from
locations 090-SB-00l, 090-SB-002, 090-8B-003, 090-MW-OI0, 090-MW-Ol1 and 184-MW-002. A
majority ofthe samples were described as a fine to medium sand (Table IB).
Additional soil sampling was performed during November 2006 to provide further soil delineation under
proposed building footprints (Buildings 5 and 7) in the southwest portion of the Site, and to evaluate soil
pH data with respect to sources of chromium impacts (i.e. COPR fill versus dichromate sources). Soil
samples were collected at 2-foot intervals from 14 sampling locations (090-SB-006 through 090-SB-O 19)
to the top of the peat stratum (maximum 16 feet bgs). Results are summarized on Table 2 and Figure 3.
Analytical data packages and electronic data deliverables are contained in Appendices F and M,
respectively. Boring logs are contained in Appendix C.
Analytical results were used to confirm chromium-impacted soils beneath proposed Buildings 5 and 7.
Field observations of eOPR-impacted fill and elevated hexavalent chromium results (> 1,000 mglkg)
were noted at seven locations (090-8B-007, 090-SB-008, 090-SB-OI5 through 090-SB-019). Hexavalent
chromium concentrations were slightly above 20 mg/kg at four locations (090-8B-009, 090-SB-OI0, 090-
88-012, 090-SB-0 14). The remaining samples did not contain hexavalent concentrations in excess of 20
mg/kg (090-SB-006, 090-SB-Oll, 090-88-013).
Soil samples were also analyzed for pH to evaluate the source of hexavalent chromium. High pH values
(>11) were detected in samples with hexavalent chromium levels above 1,000 mglkg and field
observations ofCOPR-impacted fill. Samples containing low levels of hexavalent chromium above 20
mglkg showed relatively neutral pH results.
19
TIERRA-B-015030
3.4 GROUNDWATER INVESTIGATION RESULTS
Groundwater investigations at the Site were conducted in several phases during the previous RI for SA-S,
the supplemental RI activities conducted during 2005-2006, and as part of the regional groundwater
investigation under the oversight of a court-appointed Special Master for Study Area 7.
Previous groundwater investigations included sampling of monitoring wells installed within SA-S as part
of the RI, the SA-7 investigation, and other investigations completed on behalf of the property owner
(NJCU). The RI activities for SA-5 included installation of 16 monitoring wells, including two (2) wells
at Baldwin Steel (Site 090) and three (3) wells at M.l. Holdings (Site 184). Groundwater investigation
results are sununarized in this section, with reference infonnation provided in Appendix A. A summary
overview of previous groundwater investigation results by cae is provided below:
VOCs/SVOCs
Five (5) monitoring wells were sampled for VOCs and SVOCs as part of an investigation on Site 184
(MI Holdings) during September 1992 and March 1993. The following VOCs were detected above the
GWQS in MW-3B: benzene (88-230 ug/L), xylene (200-220 ugIL), trichloroethylene (640-5,200 ug/L),
1,2-dichloroethenes (total) (330-560 ug/L), and vinyl chloride (13-24 ug/L). The lower concentrations
were detected during the March 1993 sampling round, indicating declining concentrations. No SVOCs
were detected above the GWQS. MW-3B, formerly located near the western boundary ofM.!. Holdings
(Site 184), was screened from approximately 35 ft to 45 ft bgs, at the base of the Lacustrine Sand.
Inorganics
The majority of groundwater sampling completed within SA-S has been for inorganics. Sampling
completed as part ofthe SA-5 and SA-7 regional groundwater investigations primarily focused on
chromium and major cation/anions with some additional analyses for several anions/cations and
miscellaneous parameters. Work completed on the Site 184 (M.I. Holdings) focused on mercury but also
included chromium and other Priority Pollutant List metals.
Chromium (total and hexavalent) was the most frequently detected metal with reported concentrations
above the GWQS in both filtered and unfiltered samples. Other metals reported above the GWQS in
filtered samples collected from Site 184 (M! Holdings) included cadmium (well MW-2B), mercury (well
MW-2A) and thallium (well MW-3B). Arsenic, lead, mercury, and thallium were also reported above the
GWQS in groundwater samples collected from HydroPunch borings on Site 90 (Baldwin Steel).
Additionally, the following inorganics were occasionally detected in groundwater above the GWQS
during the RI: aluminum, iron, sodium, ammonia, sulfate, chloride and total dissolved solids (IDS).
Groundwater samples collected using low-flow sampling techniques typically have lower metals
concentrations than either HydroPunch samples or samples collected using conventional sampling
techniques, which were likely used during the 1992 and 1993 sampling rounds.
Groundwater data collected during previous investigations associated with SA-5 indicate that
groundwater impacts at Site 090 (Baldwin Steel) and Site 184 (M.l. Holdings) include total and
hexavalent chromium above the GWQS. Chromium concentrations above the GWQS are present within
the Shallow Zone (contained within the fill material) beneath most of Site 117 (Ryerson SteelfHome
Depot) and Site 153 (Morris Canal) adjacent to Route 440. As previously indicated, a thin layer of
meadow mat is present in the western portion of SA-5, and a downward hydraulic gradient was identified
20
TIERRA-B-015031
between the fill material and the underlying lacustrine deposits. Where the meadow mat is not present,
the shallow and deep zones are in hydraulic communication.
HydroQual, Inc. prepared a draft report during October 2004 focusing on groundwater conditions at SA-5
to support the development of a RASRJRA WP for Baldwin Steel (Site 090) and M.l. Holdings (Site 184).
The report indicated that groundwater flow direction in the Shallow Zone at SA-S is generally toward the
west and north, and is influenced by near surface features including storm sewers along Route 440.
Hexavalent chromium concentrations detected in the shallow groundwater zone were generally below the
GWQS (70 ug/L) in the majority of monitoring wells at Sites 90 and 184 within SA-5. Groundwater
sample results for monitoring well 090-MW-EO 1 (located in the western portion of the Site near Route
440) indicated total and filtered hexavalent chromium concentrations of770 ugIL and 583 ug/L,
respectively. The report also contains results of groundwater grab (HydroPunch) samples collected by
others, indicating elevated chromium concentrations in the southwest portion of the property.
Vertical aquifer screening sample results obtained during installation of deep monitoring wells (090-
MW-090, 90-MW-7BR) located in the southwestern portion of the Site indicate that hexavalent
chromium was detected in 090-MW-090 above the GWQS (70 ug/L) near the bottom of the fill unit (12-
14 feet bgs) and at various depths greater than 25 feet bgs, with the highest concentrations detected at
depths below 60 feet bgs. There were no detections in the interval between the bottom of the fill and the
deeper natural deposits. Vertical screening results for 090-MW -7BR indicate that hexavalent chromium
concentrations above the GWQS were limited to samples collected from depths below 25 feet bgs. The
vertical aquifer screening results indicate that the chromium levels detected in the deep groundwater zone
are several orders of magnitude greater than the Shallow Zone. The groundwater data indicate that the
highest hexavalent chromium concentrations in the shallow groundwater zone have been detected at SA-
7 (Sites 87 and 115) on the opposite (west) side of Route 440, and other nearby Sites associated with SA-
5 (Sites 117 and 153) south of the subject Site.
3.4.3 Deep Overburden Groundwater Report for Study Area 7 (February 2007)
As part of the Regional Groundwater study for SA-7, HydroQual, Inc. on behalf of Honeywell prepared a
Final Groundwater Investigation Report dated February 2, 2007 to describe the hydrogeology of the deep
overburden deposits in the vicinity of Study Areas 5,6, and 7, and to characterize the deep overburden
groundwater chromium plume (HydroQual, 2007). This study included both the landward portion of the
plume and the portion that extends beneath the Hackensack River. The term "deep overburden" refers to
the deposits between the meadow mat and the bedrock surface. Groundwater occurs within the fill
material above the meadow mat under unconfined conditions, and within the lacustrine sand and bedrock
under semi-confined and confined conditions, respectively. The report indicates that groundwater flow
in the intermediate zone below the meadow mat is toward the Hackensack River. Groundwater flow in
the deep zone is to the west-northwest beneath SA-5. but then turns to the north-northwest beneath SA-7
and SA-6 North. A coarse-grained sand deposit (beneath the eastern portion of SA-7) and the low
permeability red clay (beneath the western portion of SA- 7) control groundwater flow in the deep zone.
Two independent chromium plumes have been identified; one in the fill and shallow overburden above
the meadow mat, and one in the deep overburden. Chromium in the shallow overburden plume is a result
of groundwater in direct contact with COPR, and COPR-impacted soil, and is unrelated to the deep
plume, which has its origin at the former Mutual Chemical Company production facility east of Route
21
TIERRA-B-015032
440 (Site 117; current location of the Home Depot facility). The report indicates that the source of the
deep plume is from the historic vertical migration of chromium through the lacustrine sands into the deep
overburden. The deep plume then travels through the deep, highly penneahle, coarse-grained sand layer
where it travels horizontally to the north-northwest where it moves back up through the lacustrine sands
ultimately discharging to the Hackensack River.
In contrast to the COPR-related sources of the shallow plume, the deep overburden plume was likely
caused by historic releases of chromate solutions from the various processes at the fanner Mutual
Chemical Company production plant. Based on the historical information provided in the Final
Groundwater Investigation Report, the most likely location of process-related discharges is in the vicinity
of Building F, in the northwest comer of the fonner plant, where the "wet" operations took place. The
vertical profile of hexavalent chromium concentrations in pore water adjacent to the wet operations area
supports the conceptual model of process-related discharges. Pore water quality data collected from
borings 090-MW-07, I 17-MW-I4, and 090-MW-07BR located within close proximity to the wet
operations indicate that hexavalent chromium is present throughout the entire vertical column from the
Shallow Zone to the top of bedrock. Concentrations range from a low of 1.5 mgIL to a high of 6,920
mg/L. This was the only location within the project area in which such a vertical continuum was
identified. The highest concentrations noted in these borings are at a depth of approximately 65 feet and
in contact with the 5-3 Sand. The fact that the Shallow and Intermediate Zones in this source area
continue to exhibit hexavalent chromium in concentrations in excess of 10 ppm, indicates that residue
from past housekeeping practices may still be present in the subsurface. Although a relatively thin layer
ofCOPR-Iike material was identified in boring 117-MW-I4, it is unlikely that this small volume could be
solely responsible for the persistence of these elevated concentrations decades after plant operations have
ceased. It is more likely that some form of solid-phase residual of the historical sodium chromate
discharges is present within the fill and/or underlying lacustrine deposits.
Hexavalent chromium was detected in the deep overburden at concentrations greater than 1,000 mglL in
three wells: 090-MW-09 had 2,460 mg/L in the unfiltered sample collected in April 2004; 117-MW-14
had 6,920 mg/L in the unfiltered sample collected in December 2006; and 115-MW-19 had 2,250 mgIL
in filtered sample collected in September 2004. These wells are located within the Site property,
adjacent to the Site property, and approximately 400 feet west of the Site, respectively. Vertical aquifer
sampling results indicate that the chromium levels detected in the deep groundwater zone are several
orders of magnitude greater than the Shallow Zone. Vertical aquifer sampling results and relevant
figures from the reglOnal investigation illustrating the regional extent of chromium impacts and vertical
gradients are included in Appendix A.
Hexavalent chromium was a(so detected beneath the riverbed sediments at concentrations ranging from
0.732 mg/L to 218 mg/L. The report indicates that the plume is believed to have attained a largely
steady-state position beneath the river with ongoing discharge upward through the relatively thin
sediments in a topographic depression area beneath the river, with little or no further lateral migration of
the plume. Hexavalent chromium was not detected above the detection limit of 5 ugll in any of the 26
pore water sample locations beneath the river. (HydroQual, Inc., 2007).
22
TIERRA-B-015033
adjacent to the Hackensack River, with piping to and treatment at the existing SA-7 wastewater treatment
plant. A Court Order dated 10/6106 approved the DORAA Report and the selection of Alternative No.3,
Groundwater sample results for two rounds of sampling performed during 2005 (April and May) are
indicated on Table 3 and Figure 5. Monitoring wells sampled include 090-MW-EOl, MW-090-010,
090-MW-Oll, l84-MW-OOl, I84-MW-002 and 090-MW-8A. Groundwater field parameter
measurements are indicated on the groundwater sampling field data sheets in Appendix E. Groundwater
elevation data are presented in Table 5. Groundwater contours are included as Figures 4A and 4B.
Total cltromium was detected in the following monitoring wens above the GWQS (70 ugIL) with maximum
concentrations shown in parenthesis: 090-MW-EOI (117 ugIL); 090-MW-OlO (5,280 ug/L); 184-MW-D02
(245 ug/L) and 090-MW-8A (514 ugIL). Elevated total cltromium concentrations were also detected in
groundwater grab samples 090-PZ-00I (7,220 ugIL) and 090-PZ-002 (2,640 ugIL). Groundwater grab
sample 090-PZ~001 was collected from 090-SB-003 borehole, and sample 090-PZ-002 was collected from
090-SB-005 borehole. The screened interval at both locations was from 3 to 13 ft bgs. These results are
likely biased high due to the groundwater grab sampling method. Hexavalent chromium was detected
above the GWQS in two wells as follows: 090-MW-OIO (5,220 ug/L) and 90-MW-8A (497 ugIL). Both of
these wells are located within the area of chromium-impacted soils in the southwest portion of the Site.
Field measurements indicate that elevated pH levels were detected at 090-MW-01O (pH > 12), whereas
neutral pH conditions were detected at other wells including 090-MW -8A (pH of 6.44). Groundwater field
data indicate relatively neutral pH values (ranging between pH 6 to 9), with the exception of 090-MW-O 10
in the southwest portion of the Site.
Groundwater sampling included other water quality parameters (selected metals, alkalinity, ferrous iron,
sulfate, TOC) and field measurements (DO, oxidation-reduction potential [ORP]) to provide additional
data for evaluation of natural attenuation and potential groundwater treatment options. Alkalinity values
ranged from 46 mg/I to 789 mgll, with the highest alkalinity values detected in 184-MW -002 and 090-
MW-OIO. Ferrous iron, sulfate, and TOe values ranged from 0.15 to 0.24 mg/I; 9.8 to 45.5 mg/I; and 2.5
to 20 mg/I, respectively. DO results ranging between I to 10 mgll were detected in the majority of
monitoring wells, with the exception of090-MW-0IO and 090-MW-Ol I which had DO values below I
mglkg or non-detect. ORP results indicated negative values in the majority of wells, with the lowest
values detected in 090-MW-OIO. Data for 090-MW-OIO include a lack of DO along with negative ORP
values, indicating anaerobic reducing conditions where the highest chromium concentrations were
detected in the southwest portion of the Site. The results indicate subsurface conditions favorable
for chromium reduction (Cr -6 to Cr~3) in groundwater beneath the Site.
Groundwater sample results for sampling performed during May, August and December 2006 are
indicated on Table 4 and Figure 5, Monitoring wells sampled include 090-MW-OlO, 090-MW-ll, 090-
MW-8A, 090-MW-E01, l84-MW-OOI, 184-MW-002. Monitoring well 090-MW-8A was not sampled in
August 2006 as it could not be located following building demolition activities. Groundwater field
parameter measurements are indicated on the groundwater sampling field data sheets in Appendix E.
Groundwater contour maps are included as Figures 4C through 4E.
Total chromium was detected in the foiIowing monitoring wells above the GWQS (70 ug/L) with
maximum concentrations shown in parenthesis: 090-MW-OIO (3,500 ugIL), 090-MW-8A (380 ug/L), and
184-MW -002 (222 ug/L). Hexavalent chromium was detected above the chromium GWQS (70 ugll) in
23
TIERRA-B-015034
90-MW-8A (345 ugIL), and below the GWQS in 090-MW-010 (64 ug/L). These wells are located within
the area of chromiurp-impacted soils in the southwest portion of the Site. The most recent round of
sampling (December 2006) indicates hexavalent chromium detected in only one well: 90-MW-8A (332
uglL). Laboratory analysis shows elevated pH levels at 090-MW -010 (pH 12.08), whereas near neutral
pH conditions were detected at the remaining wells. Groundwater field data also indicate relatively
neutral pH values (ranging between pH 6 to 9), with the exception of090-MW-OIO in the southwest
portion of the Site.
Groundwater sampling included other water quality parameters (TAL metals, natural attenuation
parameters) to provide additional data tor evaluation of natural attenuation and potential groundwater
treatment options. Alkalinity values ranged from 23 mg/l to 784 mgll, with the highest alkalinity values
detected in 184-MW-002. Ferrous iron, sulfate, and TOC values ranged from <0.1 to 4.9 mg/I; <5 to 328
mgll; and 1.6 to 47.2 mg/I, respectively. Sulfide results ranged from <1 to 32.4 mgIL. DO results ranged
between 0 and 6 mg/l, with DO not detected in 090-MW-OIO, 090-MW-Oll, 184-MW-OOl, and 184-
MW-002. ORP results indicated negative values in the majority of wells, with the lowest values
detected in 090-MW-OIO. Monitoring wells 090-MW-8A and 090-MW-011 (located outside the zone of
highest hexavalent soil impact) show positive ORP values. Data for 090-MW-OIO include a lack of DO
along with negative ORP values, indicating anaerobic reducing conditions where the highest chromium
concentrations were detected in the southwest portion of the Site. The results indicate subsurface
conditions favorable for chromium reduction (Cr+6 to Cr+3) in groundwater beneath the Site.
Other metals detected above the GWQS included aluminum, arsenic, iron, lead, manganese, mercury, and
sodium. The greatest number of metals above the GWQS were detected in 090-MW-OIO, including
aluminum (2,920 ug/L), arsenic (58.7 ug/L), iron (12,000 ug/L), lead (80.7 uglL), mercury (28.8 ug!L),
and sodium (292,000 ug/L). Elevated mercury (22.6 ugIL) was also detected above the GWQS in 184-
MW-OOI. TDS and chloride concentrations ranged from 220 to 1,140 mg/l and 18 to 109 mg/l,
respectively.
Honeywell has conducted a treatability assessment of source area material on the Home Depot site (see
Appendix N). Laboratory tests were conducted on soil obtained within the footprint of the former
Mutual Chemical Company facility (source of Study Area 7 deep overburden groundwater
contamination) to provide a direct measure of the leachability of soil-associated hexavalent chromium
(Cr(VI)) and to assess the performance of an abiotic reductant for Cr (VI). The major objectives of this
study were to (i) use kinetic leaching tests to determine the leaching characteristics ofCr(VI) from
representative soil samples from within the source area defined by the prior wet operations on SA-5, (ii)
evaluate possible Cr(VI)·mineral and/or chemical mechanisms that may be responsible for Cr(VI)
retention in the soil, and (lii) evaluate the reductant dosing requirements for reduction of Cr(VI).
A full description of the studies, including the field collection, laboratory methodology and analyses, and
results is presented in Appendix N (Treatability Study - Source Area Study Area 7, HydroQual Inc.) The
results of the studies are briefly summarized as follows:
At hydraulic gradients ranging from approximately 14 to over 70, multiple pore volume exchanges
(up to 40 or more) were required to sufficiently leach Cr(VI) so that effluent concentrations were
below the New Jersey groundwater quality criterion of70 ppb.
The large number of pore volume exchanges, both within fine sand samples as well as silty clay
samples, indicates that Cr(VI) is not leached within the typical 3-5 pore volume exchanges expected
if only dissolved phase chromium were present and readily leachable from the pore spaces.
24
TIERRA-B-015035
• The leaching curve response (Le., a slow, relatively steady decline) could be indicative of diffusion
of Cr(VI) from within the sample, which could be accounted for by the presence of Cr(VI) in
micropores, or a combination of diffusion, sorbed material, and solid phase material.
• The fill sample that appeared to exhibit visual evidence of solid phase chromium at the time it was
collected, did not contain COPR, but did contain a chromite phase (trivalent chromium) indicating
that the formation of solid phase material did indeed occur. Apart from this conclusion, chromium
was detected in three of the five samples tested.
• The addition of calcium polysulfide at two times the stoichiometric ratio based on total extractable
Cr(VI) by alkaline digestion resulted in concentrations of Cr(VI) in effluent samples below the
GWQS without indication of a return to higher levels for the sample tested with more than one dose
(i.e., fine sand sample). Calcium polysulfide dose ratios for treatment should range from two to three
times the stoichiometric ratio, based on the overall results of the testing.
Soil Investigation
• The RI included over 80 borings and analysis of over 700 samples for total and hexavalent chromium
on Site 090 (Baldwin Steel), Site 184 (M.!. Holdings), and the northern portion of Site 153 (Former
Morris Canal) next to Sites 090 and 184 during the RI. The horizontal and vertical extent of
hexavalent chromium above the NJDEP Soil Cleanup Criteria has been characterized and delineated.
• The portion of the Site and proposed redevelopment area impacted by hexavalent chromium
concentrations greater than the NJDEP soil criteria (20 mg/kg per the NJDEP chromium policy) is
along the western and southern boundaries of the Site (estimated at approximately 4.5 acres). The
impacted area is bounded by the Site 090 (Baldwin Steel) boundary to the south (adjacent Site 117 to
the south has already been capped by Honeywell), Site 153 (Former Morris Canal) boundary to the
west (where additional RI efforts are ongoing), and clean borings (no exceedances of20 mg/kg) to
the north and east within Site 090 (Baldwin Steel) and Site 184 (M.I. Holdings). Hexavalent
chromium concentrations slightly above 20 mg/kg were detected in shallow soils beneath existing
pavement at a few isolated locations outside the main chromium-impacted fill area.
• A one to two foot thick layer of meadow mat (peat) is present in the western portion of the Site. The
highest hexavalent chromium concentrations occur in saturated fill material above the meadow mat,
at depths between approximately 6 to 14 feet bgs. RI results indicate good correlation between field
observations of possible COPR impacted soils and laboratory data indicating elevated hexavalent
chromium concentrations. Field observations of possible COPR and/or COPR contaminated fill were
noted in some of the borings as relatively thin layers (e.g., yellow-green colored streaks or nodules)
mainly at the bottom of the fill. Typically, the hexavalent chromium concentrations are one to two
orders of magnitude less in the underlying samples collected from (and below) the meadow mat,
which appears to be acting as a confining layer that prevents downward migration of hexavalent
chromium into the deeper groundwater zone.
• SPLP data for soil samples collected at SA-5 is limited and indicates high variability and uncertainty
with respect to correlation of hexavalent chromium concentrations in soils with SPLP leachate
results. The high variability of the SPLP results indicates that the SPLP test cannot be used to
predict groundwater impacts at this Site. Groundwater data provides more conclusive evidence
regarding actual source impact to groundwater.
25
TIERRA-B-015036
Groundwater Investigation
• Two independent chromium contamination plumes have been identified in groundwater; one in the
shallow fill and overburden zone above the meadow mat (where present) and one in the deep
overburden zone. Vertical aquifer sampling data indicate that the chromium levels in the deep
overburden groundwater zone (below the meadow mat) are several orders of magnitude greater than
the Shallow Zone, indicating that shallow groundwater conditions at the Site are not a source of the
groundwater contamination present in the deep overburden zone.
Total and hexavalent chromium concentrations in groundwater within the Shallow Zone beneath the
majority of the Site are below the GWQS or not detected. Elevated chromium concentrations above
the GWQS ono ugIL were detected in the southwest portion of the Site (090-MW-01O, 090-MW-
8A) and the northwest corner of the Site (I84-MW -002). The presence of elevated hexavalent
chromium in the Shallow Zone groundwater is associated with chromium-impacted fill soils,
particularly in areas with high pH levels (e.g., 090-MW-OIO; pH >10).
• Total and hexavalent chromium concentrations detected in the Shallow Zone were lower during 2006
as compared to data collected during 2005. Groundwater sample results for 090-MW-OI0 indicate
that total chromium levels decreased from 5,200 ugiL (May 2005) to 3,500 uglL (December 2006),
and hexavalent chromium levels decreased from 5,170 ugIL (May 2005) to 64 ugIL (May 2006) to
non-detect (December 2006). In 090-MW-8A, total and hexavalent chromium concentrations
decreased from 514 ugll and 496 ugll (May 2005), respectively, to 356 ugll and 332 ugll (December
2006), respectively. In 184-MW-002, total chromium levels decreased from 180 ug/l (May 2005) to
83 ugIL (December 2006). Hexavalent chromium results during 2006 were non-detect or below the
GWQS in all monitoring wells, with the exception of 090-MW -8A. The presence of elevated
hexavalent chromium in 90-MW-8A with neutral pH conditions indicates that hexavalent chromium
at this location may be associated with dichromate rather than COPR-impacted fill.
• Groundwater results indicating initial elevated total and hexavalent chromium concentrations may be
associated, at least in part, with suspension/dissolution of contaminants from physical disturbance of
chromium-impacted fill during well installation. This pattern of initial elevated concentrations near
the time of well installation followed by substantially lower concentrations has been observed at
other chromium-impacted fill sites.
• The regional groundwater investigation for SA-7 indicates that elevated chromium is present in the
Deep Overburden Zone near the boundaries of Site 117 (Ryerson Steel), Site 153(Former Morris
Canal) and Site 90 (Baldwin Steel), and extends west of Route 440 in the area of SA-6 and SA-7.
The source of the deep groundwater plume is believed to be from past operations at the fanner
production plant (Site 117; Ryerson Steel; currently occupied by Home Depot), likely associated
with historical discharges or spills of materials used at the plant (e.g., sodium dichromate) and
vertical migration of chromium through the lacustrine sands into the deep overburden where it mixes
with groundwater moving through the deep, more permeable, coarse-grained sand layer.
• Other constituents detected in groundwater above the GWQS during the most recent sampling
completed during 2006 included aluminum, arsenic, iron, lead, manganese, mercury, and sodium.
• Other constituents detected in groundwater above the GWQS in connection with investigations by
others include VOCs (benzene, xylene, TCE, DCE, vinyl chloride) and metals (cadmium, mercury,
thallium) at Site 184 (MI Holdings).
26
TIERRA-B-015037
• Groundwater measurements indicate strong reducing conditions, as evidenced by lack of dissolved
6 H
oxygen and negative ORP values. These conditions favor the natural reduction of Cr+ to Cr
• R1 data for the Site and nearby sites within Study Areas 5, 6 and 7 include groundwater results for
chloride and TDS. Over 300 chloride and TDS sample analyses have been completed over a nine-
year period, with results indicating that groundwater exceeds the GWQS for these compounds on a
regional basis. In some cases, the concentrations exceed the criteria for Class IIIB groundwater
designation, suggesting impacts from saline surface water (Newark Bay). The exceedances of the
GWQS (or Class UIB threshold values) are not bounded by property lines or location of historical
operations, thus they are ubiquitous and regional. The level and extent of the impact varies by
stratigraphic unit and is likely a function of the history and properties of each unit. In the Shallow
Zone (above the meadow mat), impacts are likely related to the filling of the estuarine marshes and
subsequent interconnection of the bay with the fill zone. The intermediate and deep glacial zones
and the bedrock are likely impacted from historic pumping operations. The level and extent are
governed by geologic properties of these units (e.g. permeable zones in the glacial sediments and
fracture zones in the bedrock).
Recommendations
Soil and groundwater impacts have been adequately characterized and delineated, and sufficient data
exist to proceed with remedial action selection to address chromium contamination detected in soils and
groundwater at the Site. A Remedial Action Selection Report and Remedial Action Work Plan are
presented in Sections 4 and 5, respectively.
27
TIERRA-B-015038
-,'
PERMIT TO DISCHARGE
BCJ000008
TIERRA-B-015039
PBr:~ 'of 28 pages
,NJ0027022
A. G~liHAL CONDl'l'ION~:
1. All d.i scharges authorized herein s~lall be con si stent. ..... i th the te rms
and conditions of this pernit. The di~charee of any pol1ut~~t more
freq'Uently tr l!,,'1, or at a level, in excess of, that identified. and
authorized by this permit shall consti tute a violation of the terms
a~i conditicns of this ?ermit. Such 0 violation may result i~ the
i~position of civil ani/or criminal penalties as provided for in
Section 309 of the Act. Facility modifications, additions, and/or
expansions that increase the plant capacity must be reportei to the
per~itting authcrity ani this ?ermit then nodified or re-iss~el to
reflect such changes. Any o.nticipa::'e.i
change in the facili ty ,iischarge,
incluiinf, a~y new significant in1ustrial discharge Or significant
changes in t~~ quantity or quality of existing indus~riGl iisc~~rges
to t!~e treet~ent Sj'stE:::: that will result in :-Jewor increasei :..iscr.arges
of pollu-::'ants::ru.st· be re:;?or:'ed.
to the ;{egicnal Ad.:ninis':ratcr. ::odificn.tic:s
to the per~~t ~ay ~hen be Dade to reflect any necessary chanses in
perrr~t condi::'ions, inclUding any necessary effluent linitatic~s for
any 90l1uta~ts net 'identified. ani li::1i. ted. herein. In no case ere any
ney: connections, increased. flows, or significant chal'';2s in in:'':'uen t
quality ?er::~tte1 that will cause Violation of the effluent li~tatio~s
specified. herein.
2. !,:ter Iiotic!'::
E::.rJl o;.'rJortunit:,r
fer ::l h€:,ri~lg, this [)tr::,J.::' ma:r 'be ~od.ifie'i,
suspen::e·i, or revo~ed in whole or in port dmine its term for cause
incl~jinr, but not li~~ted to, the ~01lo~~ng:
4. The per~ttee shall allow the hea:!.of the state water ~ollutic~
control agency, the Recional A'1~~~nistTatcr, and/or their authorized
representatives, upon the ~rc~entatic~ of crede~tials:
TIERRA-B-015040
Page 3 ~ 28 pages
NJ0027022
TIERRA-B-015041
Page 4 of ,-ages
,.oN.l0027022
9. If for any reason the permittee does not comply with or will be
unable to comply with any effluent limitation specified in this permit,
or should any unusual or extrordinary discharge of wastes occur from
the facilities herein permitted, the permittee shall immediately
notify the Regional Administrator and appropriate State agency by
telephone and provide the same authorities with the following infor-
mation in writing within five days of such notification:
a. A description of the non-complying discharge including its
impact upon the receiving waters.
b. Cause of non-compliance.
c. Anticipated time the condition of non-compl iance is expected
to continue, or if such condition has been corrected, the
duration of the period of non-compliance.
d. Steps taken by the permittee reduce and eliminate the non-
complying discharge.
e. Steps to be taken by the permittee to prevent recurrence of
the condition of non-compliance.
10. Permittee shall take all reasonable steps to minimize any adverse
impact to navigable waters resulting from non-compliance with any
effluent limitation specified in this permit. The permittee will
also provide accelerted or additional monitoring as necessary to
determine the nature and impact of the non-complying discharge.
11. Except as provided in permit condition 8 on bypassing, nothing in
this per~it shall be construed to relieve the permittee from civil
or criminal penalties for non-complying discharge.
12. Nothing in this permit shall be construed to preclude the institution
of any legal action nor relieve the permittee from any responsibilities,
liabilities, or penalties established pursuant to any applicable
State law or regulation under authority preserved by Section 510
of the Act.
", '
TIERRA-B-015042
Pnr.c 5 ..,f "-28- pages
NJ0027022
16. ~he pel~ttee shall require 2ny iniustrial user o~ such trea~me~~
~orks tc comply ~~th the require~ents of section 204(b), 307, ar.i
303 of the Act. 1.:1.-:" industrial Ilser subject to the rcq,uirt:!mem.s of
section 207 of tho:: ;·.ctshall be required. by the per::.i
ttee to rr~?nre
an1 trQn~,,~t to the Regionol A·ir~~istrator ?eriodic notice (ever
in~ervals not. to exceed. 9 r:lonths) of prct;ress tower:! full conplianc,,",
¥ith secti~n 307 reQuireaents.
17. ?~~ ?er"ttee shall req~re &ny injustrial user of stor~ s~~ers ~o
cO:1ply "i. th :'he rec;,uirer:.entcf section :;03 of the Ar;:.t.
TIERRA-B-015043
Page 6 of 28 page s
NJ0027022
c. S~e Table I _
TIERRA-B-015044
,Enge '7 of28 Pages
NJ0027022
2. Fac11ity QPeration and Quality Control
TIERRA-B-015045
t'n[~c 8 ....Pl" - -28 ,;a~es
NJ002?022.
Director
Division of I-laterResources
New Jersey Department of
Environmental Protection
Labor & Industry Building
P. O. Box 1390
Trenton, New Jersey 08625
::ee T<3ble I
The analytical and $ompling ~ethods us~d shall confor~ to the latest
edition of the refere.l\ce r.lethod:; listed. belo.... (These are
interim
references to be rC!placed by See. 304( [J £Uidel.incswhen a.vaila.ble).
Huwever, different but equivaJ.ent r.Jethods are n.1.lowable if they
receive the prior written a.pproval of the perrnittinC authority.
TIERRA-B-015046
~age :> of ."28 _.pages
NJ0027022
4. Recordin&
The permittee shall record for all samples the date and time of
sampling, the sampling method used, the date analyses were performed,
the identity of the analysts, and the results of all required analyses
and measurements.
5. Solids Disposal
TIERRA-B-015047
\
Page 10 or 28 pages
-·~:l\'tJ002
7022
Ta.ble II - Gclf-t·~oni taring Requirements y
Hinimum Honitoring Requirements
?arwneter )·1eo.sUTc:T:lent .F'recucnc Sa:n 1 e
, I
::J -~.,- .......- .... -_.- _.. :ec, i:,:flue~t and effluent
measurement and testin~ are reQuired.
TIERRA-B-015048
Pag .... ,110'£.28 Pages
NJ0027022
Section C -
II Special. Conditions"
TIERRA-B-015049
I'uge I~ or l~ pG~.F~s
NJ00270'>4\
~ ~ct~on
. C- I
Schedule of Compliance 11
TIERRA-B-015050
" ... Page 13 of 2"8 pages
NJO_027022
i) a statemen"'~lS to the pel'dttee's ir:tent . 'file for
a federal .....IIS tr:.Jction Grc:nt or to COflStru .. C the ncc~ssary
facilities \-/;thout Federal aid.
I..n2
'.L.l.f
U Le I..ne p~rii1'\,.
r.ee
""",. """'1
i~11I
1
COil:PY
\'Jith the elapsed schedule i2q'Ji1'eif.2.'1't ;:nd en _
ass2ssr.:ent of th2 prababiiitv that D2ij'.~itt22 ~Iil]
meet the next schedule requi~e~ent ~n time.
TIERRA-B-015051
,-,
Section C-II "I
r P \ 14 of 28 pages
N.)vu27022
A. General Requirements
B. Preliminary Requirements
TIERRA-B-015052
~ .
.Pas 5 of 28 pages
NJ0027022
c. Operational Plan
TIERRA-B-015053
Page 16 of 28 pages
NJ0027022
A. General Requirements
TIERRA-B-015054
Page 17 of 28 pages
NJ0027022
B. Sampling
3. Type 1 Discharges:
a. Description
TIERRA-B-015055
P~ge 18.0£ 28 pages
NJ0027022'
4. Type 2 Discharges:
a. Description
A. Interim Reports
B. Final Report
- TIERRA-B-015056
Page 19 of 28 pages
NJ0027022
TIERRA-B-015057
Q~sr.r:;pt;ve Li:Jj!b-2..Uj_~churJJ~ Points
HHh in the :~9m~);11 e<i $(;'..1<:)" Sys torn
Discharge Discharge
r~~Htbci" ;!:~!:~-;
:".:~ lJ I <.I1.v"
TIERRA-B-015058
Discharge Discharg~ Di~churge Point
Nurr:bcT' Nume Latitude Longitude Receiving Water~al
014 Claremont
Regulutor
Ave. 40°43'05" 74°05'41" Hackensack River .
015 Fisk Street 40°42'55" 74°05'4]1' Hackersack River
Regu1 i1tor
Discharge No. 001 is obt?ined in the Jersey City S.A. Eastside Treatment Plant NPDES permit
'(No. NJ0027014).
N
<Xl
TIERRA-B-015059
,.,'
.__ ...~.
--- ",
\
Page ,of 28Page
NJ0027022
SCHEDULE OF COMPLIANCE FOR INDUSTRIAL
DIsCHARGE n~roRMATlon
Not later then 180 days following issuance of this permit, the
permittee Ehall have prooulgated an enforceable industrial waste
ordinance. This ordina.'1ceshould aJJ.O'lf' the pert:litteeto enforce
all pre-treatment requirements necessary to ensure compliance with
the terms ond ccndi tions of this :perm!t, as "ell as to ensure com-
pliance by all major contributir.g industries* with the pre-treatment
standards and any other applicable require~ents promulgated pursuant
to Section 307.of the Act. A copy of this c~dinance is to be submitted
for approval by the permit issuing authority, such approval being
an enforceable provision of this :~D~Spercit. ThiG ordinance shall
require each major contributing industry to sub~t to the permittee
periodic notice (at intervals net to exceed 9 months) regarding
sp-ecific actions taken to achieve i'ull compliance ".riththe requireme:lts
of Section 307. On the last day of the !!lor:ths cf Septenber
and I-larch , the p'er::-~i
tte~ shall submit to "t.nepermit
issuing authority 8. report sU:'Tt"43.rizine;
th·~progress of all 1<.,'10',,'11
major contributing ir;ciust.ries ,,0
s"J.'Dject the requirer.ientsof Section
307 tm:ards full compliance 10. th sucn requirements. Such reports
shall include at least the follOWing information:
TIERRA-B-015060
-:-'\
Pl 23 oE28 pages
NJ0027022
Pursuant to Section 307 (0) (1) of the Federal Hater Pollution Control
Act Amendments of 1972, the Administrator published "Pretreatment
Standards" for pollutants introduced into a publicly o~~ed treatnent
works in the Federal Register, Volume 38, 215 on Thursday, :Xovember 8,
1973. Nothing in this permit shall be construed to relieve any major
industrial contributor from their ob1ieations to co:!\ply"lith these
standards.
TIERRA-B-015061
'\
APPEh''DTX I
TIERRA-B-015062
---.....
TIERRA-B-015063
FOR.., APFRO~·£t
OMS No, 158-ROlt
Page 2~-~f 28 pages
NJ002~ , FOR AGENCY USE
Submit a description 01 each major Industrial faci lity diSChargingto the mu nlcipa, system, using a separate Section IV for each facility deocrlp--
tlon. Indicate the 4 digit Standard Industrial crassificaUon (SIC) Code for the industry, the maJor product or raw material. the flow (In tho",-
sand gallons per day). and the cnaracteristlcs 01 the wastewater diocharged from the industrial lacHity into the municipal system. Consult Table
"\ for standard measures of prOducts or raw materialS. (see Instructions)
City 40tc
County 401d
State 401e
Parar;;et(>(
,jame
Pa(~~eter
4060
Number
406b Value .
TIERRA-B-015064
Page 27 of 28 pag€s
NJ0027022
Sampling Schedule I
TIERRA-B-015065
Page 28.of 28 pages
NJ0027022
By authority of
(Date)
TIERRA-B-015066
~SEWAGE
CONTINUED fROM PAGE 1
1~--~-- ~------~
"'These results show that the Alan MytBlkaj- diredvf of the In since the study ~gan, said Man"
city has a $l!:'riQus problem with te-r3tate Sanitation Commission, roo adding that the study will be
maintenance I,)f its sewerage tn- s,n autonomous agli!Ocycharged romplete when .each pi~ ha.s
fra!:ltrutttlr~T" Manz.o said, with monit.oi"ingwater quality been sampled three times,
'They (city offici.l.) are going to in the trist.ate area. At each of the outfall pipes,
be very embarraased by what we . Mytdka said he would do Ma.mo said, inves-tigatora- have
turn out". ' "whatever it t.akes" to stop .cop· found fee.a] (oliform levels far
,., Manzo, an outspoken health firil"i-ed vioiatkms, including lak- :exc"*,,ding aHowed' .etandarde.
code enfora::er, h9.s- publicly ing the city to CQurt. Fee"l ooliform, a bacteria f"und
dashed 'with city officials "nd' A spok""man for tbe state De, in human feces, was fQund at
ma.jor developers:· Manm's de- partmenl t)f Environmentai Pnr 2,400 paW. per 100 millilitero at
partment undertook the study in iection said that if the city ea-ch {)f the outfaH 81ie3. Water
July, anti p]STI5 to release it in Health Department had found dist;harged from sewage t~at·
lat.e October_ any vi-olaUons, the state depart.- ment plant must have feea.l col.
City officials reacted mm-fl ment would like to know al:xmi iform 1••• 1. below 200 parts per
with ~nger than embarrassment
tv M(U~zo>scha-rg-es. Mayor An-
thony R. -Cucd, acknowledging
them, Lns-t m{loth,
Hsckenser;;k had been fme-d:
rnQl'e than $400.00-0 for dis-
h:e ·eaidt lOG mmUlte"", a .tate d.!,art~
ment spokesman
Manw said
said.
that because it
'l
defitienc-e8 in the rntmicipat
s-ew'?r .system, :Raid the dty was
~hea:n~:~. raW sewage during d~ rained gO litU-e in July and Au,
gust. the "ve.t mejodty" of the
8pend~f.lg $102 milhon over five Like many o.th..e-r Hudson Il8ml'l•• were taken during dry
yenrn lo bring the 10Q·year.otd County municipa.lities, this! weather,
pipe c(lmplex into good condi· city's system -c-ombihe$ its storm, The findings .how the regu· o
HO-I'L . water a.nd sanitary aewage "')la-· laLor-a arfl maJfunctlQn-ing. Msn~
louis M. -Malllzo#chlef i-~S~ge-tO., '0' tb6~~~;ey
~itl H.ahh D-eparim_8ot, &;li.smlns"S theelen-denn)' • "We a~e not lurning Q-urbatks tern. On rainy d.eys. storm water w said. R..egulatoTS aTe- devices
"\verm-e:S8WIM oU1'hdi pipe yu-stard3y, A !liudy befng Utldeiiakl'1ln b~htS d8va'tm-en~ a::;.rGc manunoC~ii;)t':H1g tin the problem/I he said. "'But overl()eds the city'a tWI'J sewage ntled into the main sewersge
ouUaUs ar-e releasing niW 'Sewago into the HtiH:;'kef1.$~IM:::~
lu\~ud'8-gn dvsn. - I, ~t'5- not something YVl.r'Van put a treatm-e:nt plants and the excess pipes that are d-esigne.d to aHow
f '. • i' I: ' .. \ :
>'
J""'''''
,t
USA
'-
-S"'>1&0 il'fE ;'lj~!I¢N t;l1SltATCl-l
$ancla~~ un and 1!l:ake it go, a rnixtur~ of B€Wage s,·nd freah
j
aste,f·oul's~.r·ivers
~ , ~: J. ~ ";_ -- . .;"'-,_ _:'.' ,":, . ". J'. ,! '
a:w!':\y. water, is p=er-roitted tn be. re~ into the rivers only when the
h~l~se{l through the outf.aUs. sewerage system backs up.
REPRESENTATIVES OF The city department launched Mithael Barnes, the dt:-/!!'
atate and regionai poHutiulJ (:{m· lL,,>invest.igation of the city's out" chief engiuE!ier, rf!:ojJKlns.ibl~ for
trol agerH::!.t;oS sa.d while they faHa tm <July 19, aet:(l-rding W m.n-intai.n~ng-the sewage Gutflo-w
Study:outf~ns releasingunireated sewage
~ • 1 ',.' , - '
were unaw.Qr'E! of M8nw\s find-
. 'inge, if they .founa them to be
Ma-n::w,and haa since found that
wst-er leaving and surrQumEng
most of the 20 outfall pipe.
syst~rn, :a-ccuse-dMsn2'£ of sding
irreBponaibly by. not infotming
th-e city of biB pr€Hminary find·
substantiated, the city could be
By JONATHAN BfUNC:KMAN jng th-e lnvp.$tlgatiLln. Bald the uncompleted study heavily fined.' ' being: studie<:!is highly I"'Huted in~.,
The Hurls-on DIspatch . lEi fin(Hng that most of lh~ city's Jl{JUtfaH plp-es·' "If you have 24 houTS of dry with sewage, even during dry j If heis fQund s malfunction-
JERSEY CITY -Large amounts of' untr-eated :rel-e-asing raw sewage ~nto th-e rivers
aTe -dudng w-eather und there's still Taw weather. ing l"€gulator. he should have
sewag-e ate f10wtng dkectJy into the Hudson ' dry weal-heL The dty's- 26 outfall pipes are de· sewag-e coming (Jut 'Of the out· MOST OF the pip.shave tcld us immediately," .aid
Ha-ckensack rivers bec~use of malftindiQns in sign{ld, to discharge diluted Wl:ls.te into the -dvers faUs.. that's a v.aolaU(ln,'" said bee~ sampled on tWiJ (JC(;aS10I18
Barne:5.
city sewage system, according L(l stu.dy be:in_g om. only whe.n h~avy rutn overloads the :,:;ewerage ~Y5'
dueled by the Health DBpartmeqt here, tern.
Chief Health l!1speetor Louis M. Manw, head· Plea~- ~ee SEWAGE Page-a
SCIOllflO18
TIERRA-B-015067