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~ :.. ~I'-l: 11~ oil

;!f3 ~'Vf',;1 ~',:/" /11'1", ..:(:"5'('.' (:'1,.' Pld\' ,:'" ..-,~.t..',",;


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lune 171 Ij93

i
Mr. Scott A.
Weinel'. CommlssJoner
New Jerse)' Department of Env!ronmental Protection and Energ)'
401 Eagt S~ateStreett 7th Floor
Trenton, Nrw Jersey 08625
i
Re: N!qEPE VoluntBlYSite Remediation ProgflDl
M~. Holclli1p,Inc.
223 est Side Avenue
J ,, City, NJ CY7305
I
Oelll' Mr.1e1ner:
L

The purpos. of thiS letter fs two fold, 1) To enthusiastically report to you that the NJDEPE
I voluntary BIte remediation program Is 8 succt".8S and 2) To seek your guidance, given thIs
success, as !to
how we mIght now proceed with a more streamlined ECRA review submittal
80 as to avqld the possibIUty of and duplicate efforts and costly delays, given the negative
historical ~ceptiC1n oC ECRA as a site remediatIon process.
I
M.I. Holdln¥s executed B Memorandum of Agreement (MOA) with NJDEPE in October, 1'992
to begin N~DEPE oversight of the cleanup of M.I. lIo1dlngs' Jersey Crty, New Jersey
facUlty. ok
proJjeTtles are comprised of 11.65 acres of land which are divided into three
I

; the MOA "U 8


separBte p*cels of lend. Among the submittals to NIDEPE ahortly after the execution of
report on the cleanup (at risk) of the eastern portion of the above
referenced ifsclJ1ty. The cleanup acdvltle.~ on this portion of oW' properties included the
excavatlon'and off-site disposal or over 2,000 tons ot mercury contaminateo sons. As a
result, theSe properties have been rezoned by the City of Jersey City to accommodate
recreat!on~l activities and are presently leased to the Jersey Cit)o'State. College,
i
I ,

N]DEPE's tevtew of that report, as well as the oversight of on-going remedial activities
for the western portion of the facility, has been conducted by NJDEPE's West Orange, New
Jersey flel4 offlce. The support from the West Orange offlce has been excellent. The
NJDEPE o~rs!ght manager Is Mr. Gary Greulich, s Senior Environmental Specialist in the
West Orange office. Mr. Greulich's responsiveness to our needs has kept the projeCt on
i schedule and a lette!" o! no further action (for the ellstern portion of the facl1ltjr) was
i lssued by N~DEPE to M.1. Holdings, Inc. an May 17, 1993 (copy attached).
,, .I
I

BAA000008

TIERRA-B-014883
')-~1-Q3
!L.I.i '.
oJ IIJ''4~LM
. ,.0. FROM iOGD1AliD-CLYDE WAYNE 70 !609177~2B5 P005iC06

i
j
I ,

I Mr. Scott Weiner, CommIssioner .


i N]DEPE
I June 17, 1 3
I~P2 I .
I I
! CoDSlderinj the large amount of data to be reviewed, N]DEPE's timely decisIon on the
I cleanup ot hla afte fa a success story. The cooperation we received rroni'NJDEPE to bring
i this proJec to completion has allowed M.I. Holding, to now consider selling that portion
, ot the Jers~ City facility to the Jersey efty State College. It la my understandtn, that
i such 8 sale f former industrial property would trigger the ECRA process. A preliminary
: phone call 0 the ECRA In(ormatlon line in NJDEPE's Trenton office Indicated that the
sale of the property would necessitate the flUng or the ECRA Initial Notlce Review fonns.
The representative on the information line also indicated that additional sampling and/or
remedlatloq of the ,site Is not ne<.-"eSSarydue' to the successfUl completion of the voluntary
I cl~an\lp. i
i
I
I M.J. Holdtn s Is concerned that the tMigerlng of the ECRA process might lead to either
; mlscommu cation or dlaagreement within the Vtu"iOU8 NJDEPE elements on the
, completen and resulta of this voluntary cleanup. It that were to h8ppen~. It would
i significant] undermine the voluntary cleanup program. In many Instances, clients are
i deslro ... ot' cleantnS up property prior to sale in order to factor in the real price and
eUminate e uncertainties or cleanup cost. This thought is also contained in your June
, 1992 Oesa' ptlon of the Program at Page 2. We certainly hope that the NJDEPE'a
i voluntary 81 e remediation program. will be a way to further streamline the newly enacted
! ISRA leglal tloD which was signed by Governor Florio on June 16. This new legislation,
: which repla ECRA, is more COJ18!atent with other regulatory prOIl'BmS and clearly the
voluntary cleanup program Is far more responsIve that the former ECRA process has been.
ACCOrd1ngl~, I would appreciate your feedback on how we may now proceed in a manner
. that wUl aV~ldthe potential for dupllcation of efforts regarding the volu~~tarysite cleanup
! and the ne,ly enacted ISRA proceas.
I .
i Very truly ours, •

~
i W. Fred Ro Inson
i Vice Preatd t and General Manager
I,
cc: G. Gf.'euHch (NJDEPE, West Orange)
B. V Fossen (NJDEPE, West Orange)
W. Ii" on
J. KIrk
!
I

I
I
I

TIERRA-B-014884
Document No. 5
• 4 Confidential Business Information

Report
=

Preliminary Site Characterization


M-I. Holdings' Jersey City Facility

Volume 1

Prepared for

M.L Holdings, Inc.


223 Westside Avenue
Jersey City, New Jersey

Prepared by

AWD TECHNOLOGIES, INC.


710 Route 46 East Suite 401 .
Fairfield. New Jersey 07006

10 December 1987

AWD
BAF000001

TIERRA-B-014885
AWDTechnologles, Inc.

TABLE OF CONTENTS

Page
1.0 INTRODUCTION 1
2.0 BACKGROUND INFORMATION
2.1 Geology 1
2.2 Hydrogeology 2
3.0 FIELD INVESTIGATIONS 2
3.1 Soil Borings and Monitoring Well Insta 11at ion 2
3.2 Monitoring Well Development 4
3.3 Groundwater Sampling 5

4.0 DATA ANALYSIS AND RESULTS 7

4.1 Site Geology 7


4.2 Site Hydrology 7
4.3 Results of Chemical Analysis 9

5.0 CONCLUSIONS AND RECOMMENDATIONS 10


5.1 Conclusions 10
5.2 Recommendations 11

NJIOlTC ii

TIERRA-B-014886
AWO Tedtnologles, Inc.

LIST OF TABLES

Table Title
1 SUMMARY OF MONITORING WELL CONSTRUCTION
2 FIELD PARAMETER MEASUREMENTS ON JUlY 27 AND 28, 1987
3 GROUNDWATER ANALYSIS - ORGANIC COMPOUNDS
4 GROUNDWATER ANALYSIS - METALS
5 SOIL ANALYSIS, METALS
6 SOIL ANALYSIS, ORGANIC COMPOUNDS

LIST OF FIGURES

Figure Title
1 WELL LOCATION AND WATER LEVEL
2 TYPICAL CLUSTERED WELL INSTALLATION

lIST OF APPENDICES

Appendix Title
A BORING lOGS
B MONITORING WELL INSTALLATION REPORTS
C LABORATORY REPORTS (Bound Separately)

NJIOITC iii

TIERRA-B-014887
AWD Technologies. Inc.

1.0 INTRODUCTION

This report summarizes preliminary site characterization


activities performed by AWD Technologies, Inc. at M.I. Holdings'
facility in Jersey City, New Jersey. The objective of this
preliminary investigation was an initial evaluation of soil and
groundwater conditions at the site. Field investigations began on
June 29, 1987 and included the installation of monitoring wells. and
the chemical analysis of soil and groundwater samples.

2.0 BACKGROUND INFORMATION

The M.l. Holdings facility in Jersey City is located between


West Side Avenue and Route 440 near Carbon Place. The surrounding
area is a combination of industrial and mixed residential use. The
facility consists of 22 buildings that occupy approximately 11 acres.
A variety of chemical products were produced continuously at the site
for approximately 90 years.

Mercury products were manufactured at this facil ity until 1977.


In 1977 production of all products. except Flowco(R} (calcium
stearate). was discontinued.

2.1 Geology

The bedrock beneath the M.I. Holdings site is the Triassic Newark
formation which consists of red sandstones and shale with occasional
layers of conglomerate. To the east of the property, the Triassic
Palisade Diabase forms a linear hill that extends the entire length of
Jersey City and eventually emerges to the north along the Hudson
River.

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TIERRA-B-014888
AWDTechnologies, Inc.

The actual depth to bedrock at this site is unknown. Lovegreen


(1974) estimates that the depth to bedrock in this area is 160 ft to
200 ft. The slope of the bedrock surface beneath the site generally
dips from east to west.

Bedrock is overlain by stratified glacial drift and fluvial


deposits that consist of reddish brown silty sand.

2.2 Hydrogeology

Review of IDcaI geography suggests that groundwater probably


flows east to west across the site from the topographic high of the
Palisade Diabase towards the Hackensack Meadows.

3.0 FIELD INVESTIGATIONS

3.1 Soil Borings and Monitoring Well Installation

Three pairs of clustered monitor wells were installed between


June 29, 1987 and July 7, 1987. Each cluster consists of one shallow
and one deep 4-in. 0.0. PVC well. Shallow monitoring wells are
screened in the unconfined aquifer, and are generally completed 10 ft
below grade. Deep wells were installed to a maximum depth of 50 ft.
Well construction details are summarized on Table 1.

Figure 1 shows the location of the three well clusters installed


by AWD Technologies at the plant. MW-IA and MW~IB were installed in
the northeast corner of the property and were expected to be on the
upgradi ent side of the property. Clusters MW-2At MW-2B and MW-3At
MW-3B were installed along the western edge of the property and were
expected to be on the downgradient side of the property. The

NJI01

TIERRA-B-014889
AWDTechnologies, Inc.

elevation of the wells was surveyed to the nearest O.OI-ft by Howard


F. Greenspan Associates, a New Jersey licensed surveyor.

Drilling was performed by the E~stern Drilling Company of


Woodbury Heights, New Jersey using a George E. Failing 1250 Holemaster
rig. The drilling was inspected in the field by a geologist,
Mr. Paul Kareth, who also prepared the boring logs and monitor well
installation reports. Water rotary techniques and drag bits were used
to advance the boreholes, except where sediment characteristics
required the use of drilling mud to maintain an open hole.
Specifically, mud was used during the first 14 ft of drilling at MW-IB
and throughout the drilling of MW-3B where fluid loss dictated the use
of mud to maintain an open hole. Split-spoon soil samples were
collected during well installation. Continuous samples were collected
to the top of the water table, and at 5-ft intervals thereafter.

Throughout the drill ing, air qual ity was monitored with an HNU
(11.7 EV probe) and a mercury vapor analyzer both at the borehole and
in the breathing zone.

All monitor wells were completed using 4 in. diameter flush


threaded PVC casing and .020-in. machine-slotted. 4-in.-diameter PVC
screens. Five feet of screen was installed in shallow wells, and 10
feet in deep wells. A filter pack consisting of No.1 Jesse Marie
Sand and was placed 1 ft to 2 ft above the top of the screen. This
was followed by a 2-ft thick layer of bentonite pellets. The
remaining annular space was filled with a cement/bentonite slurry.
Monitor well details are shown on Figure 2.

A relatively impermeable soil layer was encountered 11 ft below


grade in MW-IB. This boring was reamed to 12-in.-diameter and an
8-in.-diameter steel outer casing was set to a depth of 14 ft (i.e.,

NJ101 -3~

TIERRA-B-014890
AWD Technologies. Inc.

3 ft below the top of the relatively impervious soil layer). The


annular space between the borehole and casing was filled with a
cement/bentonite slurry and allowed to set overnight before drilling
continued.

Split-spoon samples were collected during the drilling of monitor


wells MW-IB; MW-2B and MW~3A. The samples were collected continuously
to the top of the water table in the shallow wells and at 5-ft
intervals below the water table in the three deep monitor wells MW-IB;
MW-2B, MW-3B.

Soils were examined in the field for evidence of contamination by


visual inspection and head space analysis with an HNU and a mercury
vapor meter. There were no indications in the field that any of the
soils collected contained contaminants. In the absence of field
evidence, the soil sample collected from immediately above the water
table was selected for laboratory analysis.

Descriptions of the soils encountered during drilling are


presented on the boring logs included in Appendix A. Appendix B
contains monitoring well installation reports.

3.2 Monitoring Well Development

Monitoring wells were developed as each cluster was completed.


MW-IA and MW-IB were developed with air. whereas the other four wells
were developed using a submersible pump. A steady flow rate was
maintained in MW-2B and MW-3B during development. MW-2A and MW-3A
were pumped dry several times during development because the minimum
pump rate of 5 GPM resulted in evacuation of the casing.

NJIOI -4-

TIERRA-B-014891
AWU Technologies, Inc.

Each well was developed for 30 to 45 minutes or until a silt free


discharge was achieved. A silt·free discharge could not be obtained
from MW-3A due to the slow recharge of that well.

3.3 Groundwater Sampling

Groundwater samples were collected from all of the monitoring


wells on three occasions: July 27 and 28, 1987; September 23, 1987;
and October 16, 1987.

The first round of samples consisted of unfiltered samples


analyzed for priority pollutants plus a library search for 40
additional tentatively identified compounds. Filtered groundwater
samples were collected and analyzed for priority pollutant metals
during the next two rounds. Filtered samples were collected to
evaluate the influence of suspended particles on the analytical
results for metals.

laboratory analyses were performed by YWC, Inc. t of Monroe, CT


and Whippany, NJ. YWCI is a NJDEP certified laboratory.

The protocols used to collect soil and groundwater samples at


this site were consistent with NJDEP guidance contained in the Draft
ECRA Sampl ing Plan Guide dated 6 June 1986, and the field sampl ing
procedures manual of June 1986. laboratory analyses were reported at
NJDEP's Tier II QA level.

A decontamination area was established to clean purging eqUipment


between monitoring wells. Plastic sheeting was laid out to prevent
sampling equipment from contacting the ground. Alconox soap and
potable water were used to clean sampling equipment between wells.

NJ10l -5-

TIERRA-B-014892
AWD Technologies, Inc.

The three deep wells (MW-IB, MW-2B and MW-3B) were purged of a
minimum three casing volumes of water using a submersible pump.
Alconox and potable water were used to wash the pump. Approximately
30 gallons of potable water were flushed through the pump after
purging each monitor well.

The three shallow wells (MW-IA, MW·2A and MW-3A} were purged
using a centrifugal pump and dedicated black PVC hose. The shallow
wells were pumped dry and allowed to recharge for 2 hours, and then
pumped dry a second time before sampling.

Each well was sampled with a laboratory-cleaned, dedicated bailer


constructed of stainless steel tubing with teflon check valves.

The volatile organic vials were filled first. The remaining


containers were filled in rotation to avoid developing a stratified
sample. Samples were not filtered in the' field during the first.
samp 1 i n9 event. Consequent ly, the measured concentration of metals
included both dissolved metals and metals attached to particulates in
the sample. Subsequent samples submitted to the laboratory for metals
analysis were filtered in the field using a 40 micron millipore
filter.

A field blank was collected each day by pouring


laboratory-supplied distilled water into a clean bailer, and then
transferring the water to the appropriate containers. A trip blank
also accompanied each day's samples, when analysis included volatile
organic compounds (VDCs).

All samples were transported directly to York laboratories in


Whippany, New Jersey at the end of each day. Cha in -of-custody was

NJIOl

TIERRA-B-014893
AWDTechnologles, Inc.

maintained throughout the sampling period, and is documented in the


laboratory reports included in Appendix C. This Appendix is bound
separately, and divided into two parts, because of its size.

4.0 DATA ANALYSIS AND RESULTS

4.1 Site Geology

Information included on boring logs (Appendix A) indicates that


the site is underlain by approximately 10 ft of man-made fill which
overlies at least 50 ft of natural soil deposits. The fill consists
mainly of sand with some construction debris. The fill on the eastern
side of the site overlies reddish brown silty sands of glacial or
fluvial origin. A layer of peat and organic silt was encountered at a
depth of 8 ft to 10 ft, indicating that the Hackensack Meadows
probably extended onto the site along the western boundary of the
site. The eastern extent of the marshland is unknown. Reddish brown
silty sands were encountered below the marsh deposit.

The soil borings were terminated at a maximum depth of 50 ft.


Bedrock was not encountered in any of the borings.

4.2 Site Hydrology

Water level measurements (Table 2) were used to estimate


groundwater flow patterns at the site. Static water level
measurements from shallow and deep wells indicate that at least two
water beari ng zones are present beneath the site. The upper water
bearing zone is under water table conditions, and groundwater is
generally encountered within 10 ft of the ground surface. The deeper
water bearing zone occurs under confined or semi-confined conditions,
and at the western end of the property 1s separated from the shallow
zone by the marsh deposits.

NJ101 -7-

TIERRA-B-014894
AWDTechnofogles, Inc.

Groundwater elevations in shallow wells are uniformly higher than


the deeper wells (Figure I). The differences in water elevations
between shallow and deep wells indicate a potential for downward
vertical movement of groundwater.

Plant north is defined on Figure 1 and our discussions of flow


directions are referenced to plant north. The water level data are
insufficient to develop a contour map of the piezometric surface due
to the limited number of observation points. In general, water level
measurements from both the shallow and deep monitor wells indicate
that groundwater flows predominately from east to west across the
site. A maximum gradient was calculated based on water elevations "at
the three well cluster locations. TIlemaximum' calculated gradient for
the shallow water-bearing zone was 0.009 and the maximum gradient for
the deep zone was 0.007. The components of gradient in the
north-south and east-west directions, and the direction of flow are as
follows:

Gradient. F1ow Direct ion


fast-West North-South
Shallow wells .008W .003N
Deeper wells .006W .0025

It should be emphasized that these calculated gradients provide only a


general indication of the direction of groundwater flow. Water level
observations at three points are the minimum number required to define
the general direction of flow~ and assume that the water table is a
flat plane. This is most likely an oversimplification of actual
conditions in the field.

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TIERRA-B-014895
AWD Tecbnologies, Inc.

4.3 Results of Chemical AnalYais

Measurements of pH, electrical conductivity and temperature were


obtained in the field at the time of groundwater sampling. The
results of these measurements are shown in Table 2. The pH at monitor
well cluster 3 is quite high (about 10 and 11) in both the shallow and
deep wells. The pH at monitor well clusters 1 and 2 is about neutral
(6.5) in the shallow wells and quite high (about 10) in the deeper
well s.

Electrical conductivity is consistently higher in the deep wells.


MW-IA had the lowest conductivity (111 umhos/cm) and MW-IB had the
highest (SOO umhos/cm). HNU readings of the atmosphere in each
monitoring well indicate that only MW-3B contained va vapors above
background levels. The HNU reading of 7 ppm for MW-3B is .corroborated
by laboratory analysis of groundwater from this location.

laboratory analyses were performed on one soil sample from each


cluster location, and on groundwater samples collected from each well.
First round analyses included priority pollutants plus forward library
search for both soil and groundwater. SUbsequent analyses were
limited to priority pollutant metals on groundwater samples.
Analytical results for the last round of samples were received on
October 26, 1987.

Analytical results are summarized on Tables 3 through 6.


Complete laboratory reports are included in AppendiX C. Elevated
concentrations of volatile organic compounds and some metals were
detected in groundwater collected from MW-3B. Soil from MW-3A, which
is adjacent to MW-3B, contained chromium and nickel in significant
concentrations. Soils and groundwater analyzed from elsewhere at the
site showed little evidence of contamination.

NJIOI ~9-

TIERRA-B-014896
AWD Technologies, Inc.

The presence of high chromium and nickel concentrations in soil


at the site may be attributed to the use of contaminated fill, a
common problem in Jersey City.

The monitoring wells were sampled and analyzed for priority


pollutant metals on two occasions after the first sampling event.
Samples collected during events two and three were filtered in the
field to remove any suspended solids that might be present. Filtering
significantly reduced the observed concentration of metals in
groundwater.

The most significant concentrations of VOCs were detected in


groundwater collected from MW-3B. MW-3B is a deep well which contains
11 ppm of trichloroethylene. MW-3A, the companion shallow well,
contains several organic compounds but in the low ppb range. The high
concentrations of VOCs in deep well MW-3B, and their virtual absence
in other wells at the site suggest one of the following:

• a contaminant source exists at the site, and a pathway


exists between the shallow and deep water bearing
zones; or
• a contami nant source exists off site and it is bei ng
transported to M. I. Holdings' property by groundwater
flow.

5.0 CONCLUSIONS AND RECOMMENDATIONS

5.1 Conclusjons

The results of this investigation indicate that soil and


groundwater in the vicinity of the well cluster Number 3 are
contami nated with metal sand organi c compounds. The elevated

NJIOI -10-

TIERRA-B-014897
AWD Technologies. Inc.

concentrations of chrome and nickel in the soil may be attributed to


the use of contaminated fill at the site. a common problem in Jersey
City.

The source of vacs detected in MW-3B is not known at the present


time. This is due in part to open questions regarding the direction
of groundwater flow at the site.

5.2 Recommendations

AWD Technologies proposes the following activities be performed


at the site as the next step toward defining subsurface conditions,
hydrogeo logy. so i1 and groundwater contami nat ion. and contami nation
sources.

• Install two additional well c1usters on either side of .


MW-3. This will provide better definition of the
extent of vacs in groundwater. and may provide some
information on the direction of the source.

• Perform a soil gas survey to assess the possibil ity


that a source of vacs is present in soil at the site.

• Install a network of shallow and deep piezometers at


the site to better define vertical and horizontal
groundwater gradients and establish the pattern of
groundwater flow across the site.

We will prepare a work plan describing these work items in more


detail, when requested by M.l. Holdings.

NJI01 -11-

TIERRA-B-014898
AWDTechnoJogies, Inc.

TABLE 1
SUMMARY OF MONITORING WELL CONSTRUCTION

length Elevation
Screen of Ri ser (ft) Top of
Depth Length (Including Casing
MW (ft) (ft) stickup) (ft)

lA 13.5 5 8.94 23.98

IB 52.0 9.7 38.9 23.48

2A 9.0 5.1 2.2 7.79

28 47.0 10.1 35.0 7.77

3A 10.5 5.1 2.2 7.73

3B 47.0 10.0 35.0 7.25

NJIOITl

TIERRA-B-014899
I
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::ll

!
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TABLE 2 5'
p
FIELD PARAMETER MEASUREMENTS ON JULY 27 AND 28, 1987

HNU
Background/
Elevation Cft} Condo Well
Well Top of Water Quality Temp. (umhos/ Sample
Humber Water Casing Smell, Color Time pH oC cm) (ppm)
... __ .- .. __ ._- " ..

MW-IB 12.18 23.98 silty, cleared 14:15 8.6 22 500 .6/.6


after several
minutes
MW-2B 4.88 7.77 silty, cleared up 14:45 10.1 28 324 .4/.4
after several
MW-3B 4.65 7.25 silty, strong odor 15:30 10.2 26 240 .4/7.0
brown suds
MW-IA 13.47 23.98 pumped dry twice. 12:30 6.3 30 111 .6/.6
brownish color
MW-2A 5.37 7.79 dirty brown, sand 13:00 6.7 28 155 .6/.6
in bucket
MW-3A 4.08 7.73 silty, odor, pumped 13:30 10.9 23 191 .6/.6
dry twice

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TIERRA-B-014900
AWn Technologies, Inc.

TABLE 3
GROUNDWATER ANALYSIS - ORGANIC COMPOUNDS

Well ; MW lA
w
MW-IB MW-2A MW-2B MW 3A
w MW 3B
w

Volatile Organic Compounds


Methylene Chloride 2JB 2JB 3JB 3JB lOB 2,000B
Trichlorofluoromethane U U U 2J IJ U
Chloroform U 4J U U U U
1,1,1-Trichloroethane U U U IJB U lOOJB
1,lwDichloroethene U U U U U U
Trichloroethylene U U U U 3 11,000
Benzene U U U U 14 360J
Toluene IJB 2JB IJB 2JB 3JB 490JB
Ethyl benzene U IJ U U 6 200J
trans-l,2-Dichloroethane U U U U 2J U

Library Search 180B U 598 107 733 U

Base/Neutral Compounds
1,2-Dichlorobenzene U U U U U 6J
Naphthalene U U U IJ U 3J
Fluoranthene U U U U U U
pyrene U U U U U U

Acid Extractable Compounds


Phenol U U U 9J U 18J
2,4-Dimethylphenol U U U U U 2J
Library Search BNA 31 U 130 U 50 2,052
Pesticides/pCB's
Gamma BHe U U U U U 0.05
Cyanide (aqueous, ug/l) <5 <5 <5 <5 25 <5
Cyanide (dry weight, mg/kg)
Phenols (aqueous, ug/l) 55 6 40 18 9 82
Phenols (dry weight, mg/kg)
Petroleum Hydrocarbons (mg/l) 2 <1 <1 2 <1 <1

All values in ug/l unless otherwise indicated.


U = Compound was analyzed for but not detected.
J = Compound was detected but is below the specified minimum detection limits,
concentration listed is an estimated value.
B = Possible laboratory contamination.
NT • Not tested.
NJI0lT32

TIERRA-B-014901
TABLE 4
GROUNDWATER ANALYSIS - METALS ~
Cl

Parameter: Antimony Arsenic Beryllium Chromium Copper Lead Mercury Nickel Selenium Zinc
i
:::J
Ii.
...
0

~
MW-IA: ~
7/27/87
unfiltered <60 <10 <5.0 46 36 48 4.6 <40 <5.0 84
9/23/87
filtered <60 <10 <5.0 14 <25 <5.0 1 <40 <5.0 112
10/16/87
filtered 101 <10 <9 <10 <25 <5.0 0.45 <40 8.6 30

MW-18:
7/27/87
unfiltered <60 <10 <5.0 <10 <25 <5.0 <0.2 <40 5.6 <20
9/23/87
filtered <60 <10 <5.0 <10 <25 <5.0 <0.2 <40 <5.0 60
10/16/87
filtered <60 <10 <5 <10 <25 <5.0 <0.2 90 6.0 39

TIERRA-B-014902
TABLE 4, CONTINUED
GROUNDWATER ANALYSIS - METALS
i
Parameter: ~
Antimony Arsenic Beryllium Chromium Copper Lead Mercury Ni ck.e1 Selenium Zinc ::s
2.
co

MW-2A:
J
Ei
~
7/27/87
unfiltered <60 46 <5.0 202 <25 21 45.6 <40 <5.0 64
9/23/87
filtered <60 4 <5.0 11 <25 <5.0 <0.2 <40 <5.0 81
10/16/87
filtered 102 21 <5 <10 <25 <5.0 <0.2 <40 <5.0 <20

MW-2B:
7/27/87
unfiltered <60 <10 <5.0 <10 <25 5.2 3.6 <40 <20 <20
9/23/87
filtered <60 <10 <5.0 <10 <25 <5.0 <0.2 <40 <5.0 58
10/16/87
f11 tered 8.3 <10 <5 <10 <25 <5.0 <0.2 <40 <5.0 37

TIERRA-B-014903
TABLE 4, CONCLUDED
GROUNDWATER ANALYSIS - METALS
!
Parameter: Antimony Arsenic Beryll ium Chromium Copper Lead Mercury Nickel Selenium Zinc
I
:I
2.
0
oe.
1=
MW-3A: S"
~
7/27/87
unfiltered 151 37 <5.0 2.240 113 193 240 206 <5.0 306
9/23/87
filtered <60 21 <5.0 1,970 <25 <5.0 9.3 <40 <5.0 114
10/16/87
filtered 133 42 <5 2,000 <25 <5.0 15.1 K40 K5.0 24

MW-3B:
7/27/87
unfiltered <60 45 <5.0 1,000 48 5.2 22 <40 <5.0 41
9/23/87
filtered <60 6.2 K5.0 <10 <25 <5.0 0.27 <40 <5.0 SO
10/16/87
filtered <60 <10 <5 <10 <25 <5.0 <0.2 <40 <5.0 30

f = filtered groundwater sample.


unf • unfiltered groundwater sample.
All values in parts per billion exce~t where noted.
NJI0IT33

TIERRA-B-014904
AWD Tedlnologles. Inc.

TABLE 5
SOIL ANALYSIS, METALS

Soil Soil Soil


Well MW-1B MW-2B MW-3A

Parameter:
Antimony <12 <12 728
Arsenic <2.0 <2.0 5.3
Beryllium <1.0 <5.0 1.3

Chromium 9.2 14 36tOOO

Copper <5.0 10 45

Lead 3.3 14 8.3


Mercury <0.1 <0.1 0.62
Nickel <8.0 <8.0 950

Selenium <1.0 <1.0 296


Zinc 29 36 1.05

All values in parts per million.


Soil samples collected between June 29 and July 6, 1987.

NJ10lT6

TIERRA-B-014905
AWDTechnologles,lnc.

TABLE 6
SOIL ANALYSIS, ORGANIC COMPOUNDS

Soil Soil Soi 1


Well MW-IB MW-2B MW-3A

Volatile Organic Compounds:


Methylene Chloride 5 JB 32 B 17 B
Trichlorofluromethane 5 JB 4 J 7 J
Chloroform U U U
1,1,1-Trichloroethane 35 B 50 B 7 JB
l,l-Dichloroethene 2 JB U U
Trichloroethylene U U U
Benzene 3 JB 10 JB 6 JB
Toluene U U U
Ethyl benzene U U U
trans-I,2-Dichloroethane U U U
library Search U U U

Base/Neutral Compounds:
1,2-Dichlorobenzene U U U
Naphthalene U U U
Fluoranthene 73 J U U
pyrene 88 J U U

Acid Extractable Compounds:


Phenol U U U
2,4-Dimethylphenol U U U
library Search BNA 9270 B 12,960 B 11,060 B
Pesticides/PCB's
Gamma BHe U U U

Cyanide
(aqueous, ug/l) <0.10 <0.1 <0.10
Cyanide
(dry weight, mg/kg)
Phenols
(aqueous, ug/l) <0.5 <0.5 1.05
Phenols
(dry weight, mg/kg)
Petroleum Hydrocarbons
(mg/l) NT NT NT

All values in ug/l unless otherwise indicated.


U = Compound was analyzed for but not detected
J = Compound was detected by is below the specified minimum detection
limits, concentration listed is an estimated value.
B = Possible laboratory contamination.
NT - Not tested.
NJ10lT5

TIERRA-B-014906
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TIERRA-B-014907
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TIERRA-B-014908
OFFSHORE INVESTIGATION
RESULTS SUMMARY REPORT

OCTOBER 2003 TO JANUARY 2004 ACTIVITIES

STUDY AREA 7
JERSEY CITY, NEW JERSEY

Prepared For:

Honeywell International, Inc.


101 Columbia Road
Morristown, NJ 07962

Prepared By:

Parsons
200 Cottontail Lane
Somerset, NJ 08873

ENVIRON International Corporation


214 Carnegie Center
Princeton, NJ 08540-6284

April 29, 2004

BASOOOOOI

TIERRA-B-014909
S
I
I
I
i

TIERRA-B-014910
OFFSHORE INVESTIGATION
RESULTS SUMMARY REPORT

OCTOBER 2003 TO JANUARY 2004 ACTIVITIES

STUDY AREA 7
JERSEY CITY, NEW JERSEY

Prepared For:

Honeywell International, Inc.


101 Columbia Road
Morristo'W11, NJ 07962

Prepared By:

Parsons
200 Cottontail Lane
Somerset, NJ 08873

ENVIRON International Corporation


214 Carnegie Center
Princeton, NJ 08540-6284

April 29, 2004

TIERRA-B-014911
TABLE OF CONTENTS

1.0 INTRODUCTION I
1.1 Purpose............................................................................... 1
12 Site Description....................... .. 1
1.3 Overview of Offshore Investigation Results.............................................. .. .. 2
2.0 RESULTS OF BATHYMETRIC, GEOPHYSICAL, AND HYDRODYNAMIC
FIELD SURVEyS 4
2.1 Bathymetric Surveys............................................. 4

2,2 Geophysical Survey........................................ 4

2.3 OceanographiclHydrodynamic Characterization 4

2.4 Groundwater Upwelling Study and In Situ Testing............. .. 5


3.0 SEDIMENT CHEMICAL CHARACTERIZATION RESULTS 6

3,] Data Validation................................................................. ,6


32 Summary of Chemicals Detected...................... 7
3.3 Cross-Sections of Sediment Depths in the Hackensack River Adjacent to SA 7.8
3.4 Metals , ,.., 9

3.4.1 TotaiChromiumandChromium VI 9

3.4.2 Target Anaiyte ListMetals 10


3. 4. 3 Acid Volatile Sulfide and Simultaneously Extracted Metals 10
3.5 Semi-Volatile Organic Compolillds and Polycyclic Aromatic Hydrocarbons .. 10
3.6 Pesticides and OrganotiIls 10

3.7 Polychlorinated Biphenyls, Polychlorinated Dibenzodioxins and Dibenzofurans,


and Polybrominated Diphenyl Ethers............... II

3. 7. I Polychlorinated Biphenyls II

3.7.2 Polychlonnated Dibenzodioxins and Dihenzojurans II

3.7_3 Polyhrominated Diphenyl Ethers.............................................. 12


38 Other Parameters................................. . 12

3.9 Pore Water Characterization Results .. _............ .._ 12

PARSONS Pagei ENVIRON

TIERRA-B-014912
TABLE OF CONTENTS (continued)

4.0 WATER COLUMN CHARACfERIZATlON RESULTS .....................•.........•. l3


4.1 Total Suspended Solids 13
42 Chromium ." 13
5.0 GEOTECHNICAL CHARACTERIZATION RESULTS 14
5.1 Geotechnical Parameters 14
5.2 Self-Weight Consolidation/Column Settling.......................... 14
5.3 Radiodating Analysis 15

6.0 ECOLOGICAL TOXICITY STUDIES · · · 16


6.1 Sediment Toxicity and Bioaccumulation Samples 16
6.2 Benthic In faunal Survey · 16
7.0 REFERENCES 17

PARSONS Page ii ENVIRON

TIERRA-B-014913
LIST OF TABLES

Table 1 Summary of Chemicals Detected in Sediment in the Vicinity of SA 7

Table 2 Summary of Chemicals Detected in Sediment from 0 to 0.5 ft Below Mudline

Table 3 Summary of Chemicals Detected in Sediment from the Reference Areas

Table 4 Total Chromium and Hexavalent Chromium Results in Sediment

Table 5 TAL Metals Results in Sediment

Table 6 Acid Volatile Sulfide and Simultaneously Extracted Metals Results in Sediment

Table 7 Semi-Volatile Organic Compounds Results in Sediment

Table 8 Polycyclic Aromatic Hydrocarbons Results in Sediment

Table 9 Pesticides Results in Sediment

Table 10 Organotins Results in Sediment

Table 11 Polychlorinated Biphenyls Results in Sediment

Table 12 Polychlorinated Dibenzodioxins and Dibenzofurans Results in Sediment

Table 13 Polybrominated Diphenyl Ethers Results in Sediment

Table 14 Other Parameters Results in Sediment

Table 15 Tota! Chromium Results in Pore Water

Table 16 TAL Metals Results in Pore Water

Table 17 Total Chromium and Hexavalent Chromium Results in Surface Water

Table 18 Summary of Sediment Geotechnical Data

Table 19 Standard Oedometer and Permeability Testing Results

PARSONS Page Iii ENVIRON

TIERRA-B-014914
LIST OF FIGURES

Figure I Study Area 7 Site Map


Figure 2A Locations of Sediment Grab Samples and Water Column Samples Near Study
Area 7
Figure 2B Locations of Sediment Borings For Chemical and Geotechnical Characterization

Figure 3 Locations of Sediment Grab Samples and Water Column Samples in the
Reference Areas
Figure 4 Study Area 7 Cross-Section Location Map
Figure 5A Cross-Section A-A', Hackensack River Near Study Area 7

Figure 5B Cross-Section B-B', Hackensack River Near Study Area 7

Figure 5C Cross-Section C-C', Hackensack River Near Study Area 7


Figure 50 Cross-Section D-D', Hackensack River Near Study Area 7
Figure 5E Cross-Section E-E', Hackensack River Near Study Area 7
Figure 5F Cross-Section F-F', Hackensack River Near Study Area 7
Figure 5G Cross-Section G-G', Hackensack River Near Study Area 7

Figure 5H Cross-Section H-B', Hackensack River Near Study Area 7


Figure 51 Cross-Section 1-1',Hackensack River Near Study Area 7
Figure 5J Cross-Section J-1', Hackensack River Near Study Area 7
Figure 5K Cross-Section K-K', Hackensack River Near Study Area 7
Figure 6A Total Chromium Results in Sediment from 0.0 to 0.5 ft Below Mudline

Figure 6B Total Chromium Results in Sediment from 0.5 to 1.0 ft Below Mudline
Figure 6C Total Chromium Results in Sediment from I to 2 ft Below Mudline
Figure 6D Total Chromium Results in Sediment from 2 to 3 ft Below Mudline

Figure 6E Total Chromium Results in Sediment from 3 to 4 ft Below Mudline


Figure 6F Total Chromium Results in Sediment from 4 to 5 ft Below Mudline

Figure 6G Total Chromium Results in Sediment from 5 to 6 ft Below Mudline


Figure 6H Total Chromium Results in Sediment from 6 to 7 ft Below Mudline
Figure 61 Total Chromium Results In Sediment from 7 to 8 ft Below Mudline
Figure 6J Total Chromium Results in Sediment from 8 to 9 ft Below Mudline
Figure 6K Total Chromium Results in Sediment from 9 to 10 ft Below Mudline

PARSONS Pageiv EJ',VIRON

TIERRA-B-014915
LIST OF FIGURES (continued)

Figure 6L Total Chromium Results in Sediment from 10 to II ft Below Mudline


Figure 6M Total Chromium Results in Sediment from II to 12 ft Below Mudline
Figure 6N Total Chromium Results in Sediment from 12 to 13 ft Below Mudline
Figure 60 Total Chromium Results in Sediment from 13 to 14 ft Below Mudline
Figure 6P Total Chromium Results in Sediment from 14 to 15 ft Below Mudline
Figure 6Q Total Chromi urn Results in Sediment from 15 to 16 ft Below Mudline
Figure 6R Total Chromium Results in Sediment from 16 to 17 ft Below Mudline
Figure 65 Total Chromium Results in Sediment from 18 to 19 ft Below Mudline
Figure 6T Total Chromium Results in Sediment from 19 to 20 ft Below Mudline
Figure 6U Total Chromium Results in Sediment from 20 to 21 ft Below Mudline
Figure 6V Total Chromium Results in Sediment from 22 to 23 ft Below Mudline
Figure 6W Total Chromium Results in Sediment from 23 to 24 ft Below Mudline
Figure 6X Total Chromium Results in Sediment from 24 to 25 ft Below Mudline
Figure 7A Median Total Chromium Concentration in Sediments 0.0 to 05 ft Below Mudline
Figure 7B Median Total Chromium Concentration in Sediments from 6 to 12 ft Below
Mudline
Figure 7C Median Total Chromium Concentration in Sediments from 2.5 to 3.5 ft Below
Mudline
Figure 7D Median Total Chromium Concentration in Sediments from 5.5 to 6.5 ft Below
Mudline
Figure 7E Median Total Chromium Concentration in Sediments from 8.5 to 9.5 ft Below
Mudline
Figure 8A Hexavalent Chromium Results in Sediment from 0.0 to 0.5 ft Below Mudline
Figure 8B Hexavalent Chromium Results in Sediment from 0.5 to l.0 ft Below Mudline
Figure 8C Hexavalent Chromium Results in Sediment from I to 2 ft Below Mudline
Figure 8D Hexavalent Chromium Results in Sediment from 2 to 3 ft Below Mudline

PARSONS Page v ENVIRON

TIERRA-B-014916
LIST OF FIGURES (continued)

Figure 8E Hexavalent Chromium Results in Sediment from 3 to 4 ft Below Mudline


Figure 8F Hexavalent Chromium Results in SedIment from 4 to 5 ft Below Mudline
Figure 8G Hexavalent Chromium Results in Sediment from 5 to 6 ft Below Mudlme
Figure 8H Hexavalent Chromium Results in Sediment from 6 to 7 ft Below Mudline
Figure 81 Hexavalent Chromium Results in Sediment from 7 to 8 ft Below Mudline
Figure 81 Hexavalent Chromium Results in Sediment from 8 to 9 ft Below Mudline
Figure 8K Hexavalent Chromium Results in Sediment from 9 to 10 ft Below Mudline
Figure 8L Hexavalent Chromium Results in Sediment from 10 to II ft Below Mudline
Figure 8M Hexavalent Chromi urn Results in Sediment from II to 12 ft Below Mudline
Figure 8N Hexavalent Chromium Results in Sediment from 12 to 13 ft Below Mudline
Figure 80 Hexavalent Chromium Results in Sediment from 13 to 14 ft Below Mudline
Figure 8P Hexavalent Chromium Results in Sediment from 14 to 15 ft Below Mudline
Figure 8Q Hexavalent Chromium Results in Sediment from 15 to 16 ft Below Mudline
Figure 8R Hexavalent Chromium Results in Sedi ment from 16 to 17 ft Below Mudline
Figure 8S Hexavalent Chromium Results in Sediment from 18 to 19 ft Below Mudline
Figure 8T Hexavalent Chromium Results in Sediment from 19 to 20 ft Below Mudline
Figure 8U Hexavalent Chromium Results in Sediment from 20 to 21 ft Below Mudline
Figure 8Y Hexavalent Chromium Results in Sediment from 22 to 23 ft Below Mudline
Figure 8W Hexavalent Chromium Results in Sediment from 23 to 24 ft Below Mudline
Figure 8X Hexavalent Chromium Results in Sediment from 24 to 25 ft Below Mudlme
Figure 9A Arsenic Results in Sediment from 0.0 to 0.5 ft Below Mudline
Figure 9B Arsenic Results in Sediment from I to 2 ft Below Mudline
Figure 9C Arsenic Results in Sediment from 3 to 4 ft Below Mudline
Figure IDA Lead Results in Sediment from 00 to 0.5 ft Below Mudline
Figure lOB Lead Results in Sediment from 05 to 1.0 ft Below Mudline
Figure 10C Lead Results in Sediment from I to 2 ft Below Mudline
Figure 100 Lead Results in Sediment from 3 to 4 ft Below Mudline

PARSONS Page vi ENVIRON

TIERRA-B-014917
LIST OF FIGURES (continued)

Figure llA Mercury Results in Sediment from 0.0 to 0.5 ft Below Mudline
Figure liB Mercury Results in Sediment from 1 to 2 ft Below Mudline
Figure IIC Mercury Results in Sediment from 3 to 4 ft Below MudJine
Figure 12A Total Polycyclic Aromatic Hydrocarbon Results in Sediment from 0.0 to 0.5 ft
Below Mudline
Figure 12B Total Polycyclic Aromatic Hydrocarbon Results in Sediment from I to 2 ft Below
Mudline
Figure 12C Total Polycyclic Aromatic Hydrocarbon Results in Sediment from 3 to 4 ft Below
Mudline
Figure 13A PCB TEQ from 0.0 to 0.5 ft Below Mudline
Figure 13B PCB TEQ from 1.5 to 2.0 ft Below Mudline
Figure l3C PCB TEQ from 3.5 to 4.0 ft Below Mudline
Figure 14A DioxinJFur1m TEQ from 0.0 to 0.5 ft Below Mudline
Figure 14B Dioxin/Furan TEQ from 1.5 to 2.0 ft Below Mudline
Figure I4C Dioxin/Furan TEQ from 3.5 to 4.0 ft Below Mudline

PARSONS Page vii ENVIRON

TIERRA-B-014918
1.0 INTRODUCTION

1.1 Purpose

This Offshore Investigation Results SummaI)' Report represents a compilation of

the results of sediment chemistry and physical testing of sediments performed as pan of

the offshore investigation activities conducted between October 2003 and January 2004
in the Hackensack River in the vicinity of Study Area 7 (hereafter referred to as "SA 1',

or the "Site") located in Jersey City, New Jersey. Offshore investigation activities

included sediment sampling, field surveys, pore water characterization, water column

characterization, and geotechnical characterization of the sediment. The field work

discussed herein was implemented in compliance vvith two stipulated Immediate Action

Orders entered into by the parties pursuant to the judgment entered by the United States

District Court of New Jersey in Interfaith CommWlity Organization, et. aI. v. Honeywell

International et aI (Civil Action No. 95-2097 DMC, May IS, 2003). In particular, the

field activities summarized herein were specified in the Sediment Sampling Plan

(Immediate Action Stipulation Item 13) and the Bathymetric and Waterside Geophysical

Survey Plan (Immediate Action Stipulation Item 20) contained in the court order.

The chemical data included in this report have been independently reviewed and

validated by V ALIDAT A, LLC under contract to Honeywell. All chemical data collected

during the offshore investigation was evaluated and validated according to the Standard

Operating Procedures (SOP) established by the New Jersey Department of Environmental

Protection (NJDEP 2001), The data presented in this report supersede the preliminary

results reported periodically by Honeywell to The Louis Berger Group previously. The

procedures used during implementation of the field work are summarized in the Offshore

Investigation Post - Field Sampling Report October 2003 To January 2004 Activities,
Study Area 7, Jersey City, New Jersey (Parsons and ENVIRON 2004).

1.2 Site Description

A si te map is provided in Figure I. The Study Area 7 site ("Site") is a 34-acre


parcel located on Route 440 in Jersey City, New Jersey. The Site includes three separate,
contiguous sites:

PARSONS Page I ENVIRON

TIERRA-B-014919
• Roosevelt Dnve-In SIte (NJDEP SIte 115),

• Trader Horn Site (NJDEP Site 120),

• Clean Machine Car Wash Site (NJDEP Site 157).

The Site is primarily a vacant [at, although the Trader Horn facility is still in

operation. All portions of the site have some form of cover: the eastern portion of the site

is paved with asphalt; the western portion was capped with a PVC cover and overlain

with gravel as an Interim Remedial Measure (IRM); and the middle of the site still

contains a concrete slab that was fonnerly the foundation for the Valley Fair department

store. With the exception of Trader Horn, no buildings exist on the property.

The site is bordered on the north by the Jersey City Incineration Authority

(NJDEP Site 087), the Jersey City Incineration Authority Well (NJDEP Site 088); on the

east by Route 440; on the south by the Roosevelt Bowling Lanes (NJDEP Site 124),

Delphic Consolidated (NIDEP Site 125), ABF Trucking (NJDEP Site 140), Old
Dominion (NJDEP Site 134), and Degen Oil (NIDEP Site 073); and on the west by the

Hackensack River. The Site is currently vacant but was formerly used for commercial

purposes SA 7 is surrounded by a perimeter security fence on three sides and a wooden

bulkhead along the waterfront adjoining the Hackensack River. Surrounding land use is
industrial and commerci aL

1.3 Overview of Offshore Investigation Results

The offshore field work activities completed as part of the October 2003 to
January 2004 field investigation included the following;

• Bathymetric, Geophysical, and Hydrodynamic Field Surveys

• Sediment Grab Sampling for Chemical Characterization

• Water Column Sampling for Chemical Characterization

• SedIment Coring for Chemical and Geotechnical Characterization and


Radiodating

PARSONS Page 2 ENVIRON

TIERRA-B-014920
• Sediment Collection for Sedi ment Toxicity and Bioaccumulation Testing and
Benthic Infaunal Survey

• Drilllng of Rotary Borings for an Offshore Geotechnical Engineering Evaluation

• A Groundwater Upwelling Investigation and In Situ Testing

This report summarizes the results of the above investigations.

PARSONS Page 3 ENVIRON

TIERRA-B-014921
2.0 RESVL TS OF BATHYMETRIC, GEOPHYSICAL, AND HYDRODYNAMIC
FIELD SURVEYS

2.1 Bathymetric Surveys

A two-person field team of Ocean Surveys, Inc. (OSI), operating under the
direction of an American Congress on Surveying and Mapping (ACSM) certified
hydrographer, conducted the bathymetric surveys. The surveys were performed in
accordance with the United States Army Corps of Engineers' (ACOE) Engineering
Manual EM 1110-2-1003 for Hydrographic Surveys (EM 1110-2-1003) for navigation
and dredging support in soft bottom materials. Bathymetric survey data were co fleeted
from the vicinity of the Site and surrounding offshore areas between October 17 and 22,
2003. The results of the bathymetric survey are presented in the Honeywell SA 7 Sediment
Program Bathymetric Survey, Jersey City, New Jersey report prepared by OSI (2004a).

2.2 Geophysical Survey

The geophysical survey was conducted between October 22 and 28, 2003. The
geophysical field team used remote sensing technology to collect sub-bottom
stratigraphy, magnetic field intensity, and geomorphology information. Geophysical
survey data were collected from the vicinity of the Site and surrounding offshore areas.
The geophysical field survey consisted of an integrated suite of remote sensing
technologies including sub-bottom profiling, magnetic field intensity mapping, and side
scan sonar imaging. The results of the geophysical survey are presented in the Honeywell
SA 7 Sediment Program Geophysical Survey, Jersey City, New Jersey report prepared by
OSI (2004b).

2.3 Oceanographi<:/Hydrodynamic Characterization

Oceanographic and hydrodynamic survey data were collected from the vicinity of
the Site and surrounding offshore areas to collect water level, current velocity, and basic
water quality data for input to a sediment transport study and for evaluation and design of
sediment remediation options. The survey consisted of both an in situ program and a real-
time boat-mounted program using specialized field instrumentation. The in situ
instrument program consisted of measurement of current velocities, riverbed current

PARSONS Page 4 ENVIRON

TIERRA-B-014922
velocities, sediment bed elevation, in situ river conductivity and temperature

measurements versus depth (CTD), and tidal variation around the Site As an adj unct to
the longer-term In situ instrument program, the oceanographic field team conducted a

pair of real-time boat-mounted current velocity and CTD-Turbidity profiling surveys over

nominal l3-hour tidal cycles along four cross-river transects. The results of the

oceanographic/hydrodynamic characterization are presented in the Honeywell SA 7


Sediment Program OceanographiC Survey, Jersey City, New Jersey report prepared by

OSI (2004c).

2.4 Groundwater Upwelling Study and In Situ Testing

The groWldwater upwelling study was conducted to obtain supporting data for the

groundwater investigations being conducted onshore at the Site. Specifically, the purpose

was to obtain data on potential areas of groundwater to surface water seepage in the

immediate vicinity of SA 7. Because the installation of pennanent piezometers in the

riverbed was not possible, the investigation utilized a Trident Probe system to collect

specific conductance and temperature measurements as indirect measures of potential

areas of groundwater upwelling. In addition, hand penetrometers were inserted into the

sediments to evaluate the bearing capacity of the sediments and vane shear tests were

conducted to evaluate the undrained shear strength of the sediments in the vicinity of the

Site. The results of the groundwater upwelling study and in situ testing are presented in

the Honeywell SA 7 Sediment Program Vibratory Coring, Trident Probing, Hand


Penetrometer and Vane Shear Investigation, Hackensack River, Jersey City, New Jersey
report prepared by 051 (2004d).

PARSONS Page 5 ENVIRON

TIERRA-B-014923
3.0 SEDIMENT CHEMICAL CHARACTERIZATION RESULTS

Sediment grab and core sampling was conducted from the vicinity of the Site and
surrounding offshore areas (Figures 2A, 28, and 3). The field sampling procedures used
are documented in the Offshore Investigation Post - Field Sampling Report October 2003
To January 2004 Activities, Study Area 7, Jersey City, New Jersey (parsons and
ENVIRON 2004). A total of 1,429 surface and subsurface sediment samples were
collected and analyzed for 212 chemicals and 8 physical parameters, including:

Chemicals

• Total chromium and chromium VI

• Target Analyte List (TAL) metals

• Acid volatile sulfide and simultaneously extracted metals (AYS/SEM)

• Semi-volatile organic compounds (SYOCs)

• Polycyclic aromatic hydrocarbons (PAHs)

• Pesticides

• Polychlorinated biphenyls (PCBs)

• Polychlorinated dibenzodioxins and dibenzofurans (PCDDsIPCDFs)

• Polybrominated diphenyl ethers (PBDEs)

• Ammonia and pH

Physical Parameters

• Bulk density, water content, percent solids and total organic carbon

• Atterberg limits, grain size, standard oedometer and permeability (presented in


Section 5.1 of this report).

3.1 Data Validation

YALIDA TA, LLC evaluated and validated the analytical data according to the
Standard Operating Procedure (SOP) established by the New Jersey Department of

PARSONS Page 6 ENVIRON

TIERRA-B-014924
Environmental ProtectIOn. During the data validation process, the laboratory reports were
reviewed and quality assurance/quality control parameters were evaluated (where
applicable) as described in the data validation SOP (NJDEP 2001). The following
qualifiers were used where applicable:

• "R" indicates that the reporting limit or sample result has been determined to be

Wlusable due to a major deficiency in the data generation process. The data should
not be used for any qualitative or quantitative purposes.

• "f' indicates that the concentration should be considered approximate. This


qualifier indicates that the data validation process identifies a deficiency in the
data generation process.

• "ur' indicates that the sample-specific reporting limit for the analyte in this
sample should be considered approximate. This qualifier is used when the data
validation process identifies a deficiency in the data generation process.

• "B" indicates that detectable levels of the analyte were found in the associated
method blank.

3.2 Summary of Chemicals Detected

Summaries of the chemicals detected in sediment are presented in Tables 1, 2, and


3. The data tables include for each chemical the frequency of detection, the concentration

range, and the average detected concentration in sediment. In addition to the summary
statistics, the frequency of exceedance of chemical screening criteria established by New
Jersey Department of Environmental Protection and the National Oceanic and
Atmospheric Administration (NJDEPfNOAA) are also shown. Table I presents a
summary of chemicals detected in sediment samples collected at all depths of sampling in
the vicinity of SA7. Table 2 presents a summary of chemicals detected in sediment
samples from 0 to 0.5 feet below the sediment surface in the vicinity of SA7. Table 3
presents a summary of chemicals detected in sediment samples collected from the
reference areas.

PARSONS Page 7 ENVIRON

TIERRA-B-014925
3.3 Cross-Sections of Sediment Depths in the Hackensack River Adjacent to SA 7

Offshore sediment borings were drilled between November and December 2003
at a total of 41 locations in the vicinity of Study Area 7 for physical and chemical
characterization of river sediments. Sediment cores were collected using piston and
vibracoring methods at 33 of the 41 locations and deep geotechnical borings were drilled
using rotary drilling techniques at the remaining eight locations. Of the 33 sediment
coring locations, 26 were completed to a nominal depth of 10 feet below the sediment
surface (or "mudline") and seven were completed to depths greater than 10 feet (i.e., as
great as 17 feet) below the mudline. The deep gootechnical borings were typically drilled
approximately 20 feet into bedrock (i.e., a total depth of approximately 120 feet below
the mudline) The boring locations are shown on Figure 4.

Unconsolidated sediments consisting primarily of clays, silts and sands were


encountered in the upper 25 feet. Deposits found deeper than 25 feet are discussed in the
Subsurface Investigation, Study Area - 7 (Daylin-Grace Site), Jersey City, New Jersey
report prepared by Mueser Rutledge Consulting Engineers (l\1RCE) dated April 15,2004
(MRCE 2004). Draft sediment core boring logs were previously included in the Offshore
Investigation Post - Field Sampling Report October 2003 To January 2004 Activities,
Study Area 7, Jersey City, New Jersey (Parsons and ENVIRON 2004) and deep
geotechnical boring logs were included in the Subsurface Investigation report (MRCE
2004). Subsurface deposits encountered at shallow depths (i.e. upper 25 feet) include:

• Stratum D, Grey to Black Peat and Organic Clay: Typically dark grey organic
clay and clayey silt, scattered fine sand laminations, very loose to loose.

• Stratum SI, Grey Sand: Typically light to medium grey fine to medium-grained
sand, trace coarse sand and gravel, trace organic material, scattered laminations of
fine sand or silt, generally dense.

• Stratum RC, Reddish Brown Silty Clay/Clayey Silt: Typically reddish bro\Vll silty
clay and clayey silt, trace silty sand, dense to very dense.

Cross-sections showing the different shallow subsurface deposits in the sediment


and total chromium concentrations have been prepared for each cross-sections. Figure 4

PARSONS Page 8 ENVIRON

TIERRA-B-014926
shows the locations of the cross-sections offshore from the Site. Sediment cross-sections

extending parallel to the waterfront bulkhead at the Site are shovm in Figures 5A through

5E. Sediment cross-sections extending perpendicular to the waterfront bulkhead are

shovlITIin Figures 5F through 5K.

3.4 Metals

3.4. J Total Chromium and Chromium VI

Total chromium and chromium VI in sediment samp[es were analyzed by

Columbia Analytical Services, Inc. (Columbia), Total chromium was analyzed using

United States Environmental Protection Agency (EPA) Method 601OB. Chromium VI

analyses were conducted by two analytical methods, EPA Methods 7l96A and 7199,

folloVving extraction by two different methods (NIDEP and EPA). Table 4 presents the

analytical results of chromium and chromium VI in sediment. Summaries of chromium


and chromiwn VI concentrations in sediment are presented in Tables 1,2, and 3

Total chromium was detected in all sediment samples collected, with a

concentration range of 3.9 milligrams per kilogram (mg/kg) to 33,500 mglkg and an

average concentration of 534 mg/kg. Figures 6A through 6X show the concentration of

chromium in sediment in the vicinity of SA 7. Of the 421 total chromium samples

collected, 280 samples exceeded the NJDEPtNOAA Effects Range Low (ERL) screening

criterion of 81 mglkg, 137 samples exceeded the NJDEPINOAA Effective Range

Medium (ERM) screening criterion of 370 mg/kg, and 288 samples exceeded the NOAA

Apparent Effects Threshold (AET) of 62 mg/kg.

Figures 7A through 7E display the estimated median chromium concentration in

sediment in the vicinity of SA 7 using a three-dimensional interpolation method. These

figures show the offshore areas where total chromium concentrations are below the

screening criteria, or exceed the AET, ERL, and ERM benchmarks.

Chromium VI concentrations in sediment are shown in Figures 8A through 8X.

Chromium VI was detected in 218 samples, with a concentration range of 0.5 mglkg to
57 mg/kg.

PARSONS Page 9 ENVIRON

TIERRA-B-014927
342 Target Analyte List Metals

TAL metals analyses were conducted by Severn Trent Laboratories in Edison,

New Jersey (STL-Edison) using EPA Methods 60lOB and 7471. Table 5 presents the

analytical results of TAL metals in sedi ment. Summaries of TAL metals concentrations

in sediment and their screening criteria exceedances are also presented In Tables 1, 2 and

3. All TAL metals with the exception of thallium were detected in sediment samples. To

illustrate the presence of other metals in sediment, concentration profiles of arsenic, lead,

and mercury, are shown in Figures 9A through 9C, IDA through IOD, and 11A through

11 C, respectively.

3.4 3 Acid Volatile Sulfide and Simultaneously Extracted Metals

Acid volatile sulfide and simultaneously extracted metals (AVS/SEM) analyses

were conducted by Severn Trent Laboratories in Colchester, Vermont (STL-VT) using

EPA Draft Method A VS/SEM. Table 7 presents the analytical results of A VS/SEM in

sediment. Of the 39 samples in the vicinity of SA 7, 35 have an AVS/SEM ratio of less

than 1.

3.5 Semi-Volatile Organic Compounds and Polycyclic Aromatic Hydrocarbons

SVOC analyses were conducted by STL-Edison using EPA Method 8270C Table

8 presents the analytical results of SVOCs in sediment. Summaries of detected SVOC

concentrations in sediment and their NOAA AET screening criteria exceedances are

presented in Tables 1,2 and 3. PAH analyses were conducted by STL-Edison using EPA

Method SW8270. Table 9 presents the PAHs results and total PAHs concentrations in

sediment. In the calculation of total PARs, one-half of the detection limit was used for

non-detect samples. Total PAHs concentrations in sediment are also shown in Figures

12A through 12C. Summaries of detected PARs and total PAHs concentrations III

sediment and their screening criteria exceedances are presented in Tables 1,2 and 3.

3.6 Pesticides and O"ganotins

Pesticide analyses were conducted by STL-Edison using EPA Method 8081.

Table 10 presents the analytical results of pesticides in sediment Summaries of detected

pesticide concentrations in sediment and their screemng criteria exceedances are

PARSONS Page 10 ENVIRON

TIERRA-B-014928
presented in Tables I, 2 and 3. Organotin analyses were conducted by STL·VT using
Method OR560. Table 6 shows the analytical results of organotin concentrations in
sediment and surrunaries of organotins are shown in Tables I, 2, and 3. Dibutyltin.
tributyltin, and tetrabutytin were detected in sediment samples with a concentration range
of 1.9 micrograms per kilogram (ug/kg) to 16 uglkg.

3.7 Polychlorinated Biphenyls, Polychlorinated Dibenzodioxins and


Dibenzofurans, and Polybrominated Diphenyl Ethers

Polychlorinated biphenyls (PCBs), polychlorinated dibenzodioxins (PCDDs) and


dibenzofurans (PCDFs), and polybrominated diphenyl ethers (PDBE) analyses were
conducted by Alta Analytical Laboratory, Inc. (Alta) in EI Dorado Hills, California In
addition to measured concentrations, the Toxicity Equivalency Quotient (TEQ) of the
PCBs, PCDDs, and PCDFs was calculated to provide a single value normalized to the
toxicity of 2,3,7,8-TCDD for all dioxin-equivalent compounds contained in a given
sediment sample. The total TEQ was calculated by summing the product of the measured
concentration of each dioxin or PCB congener and its Toxicity Equivalent Factor (TEF)
using the dioxin-equivalent toxicity scheme for human exposure developed by the World
Health Organization (Van den Berg et al. 1998). The TEQ calculations include analytical
results of seven PCDD congeners, ten PCDP congeners and twelve coplanar PCB
congeners. In the calculation of PCB and PCDDIF TEQs, one-half of the detection limit
was used for non-detect samples.

3.71 PolychlOrinated Biphenyls

Total PCB analyses were conducted by Alta usmg EPA Method 8081 and
coplanar PCB analyses using EPA Method 1668. Table I I presents the analytical results
of PCBs in sediment. Summaries of PCB concentrations in sediment and their screening
criteria exceedances are presented in Tables I, 2 and 3. TEQ concentrations of PCBs
were calculated and are shown in Figures I3A through 13C.

3 72 Polychlorinated Dibenzodioxins and Dlbenzojurans

PCDD and PCDP analyses were conducted by Alta using EPA Method 8290.
Table 12 presents the analytical results of PCDDs and PCDFs in sediment Summaries of

PARSONS Page I I ENVIRON

TIERRA-B-014929
PCDDIF concentrations in sediment are presented in Tables l, 2 and 3, TEQ

concentrations of PCDDs and PCDFs were calculated and are shown In Figures 14A

through 14C

3.7.3 Polybrominated Diphenyl Ethers

PBDE analyses were conducted by Aha using EPA Method 8290. Table 13

presents the analytical results of PBDE in sediment. Summaries of PBDE concentrations

in sediment are presented in Tables 1,2 and 3.

3.8 Other Parameters

Nitrogen ammonia, total organic carbon (TOC), and pH analyses were conducted

by STL-Edison using EPA Method 350.1-350,2, modified ASTM Method D 2579, and

EPA Method 9040B, respectively. Bulk density and percent solids analyses were

conducted by STI...-Edison and STI...-Vf, respectively. Table 14 presents the analytical

results of nitrogen ammonia, total organic carbon (TOC), bulk density, solids, and pH in

sediment.

3.9 Pore Water Characterization Results

Pore water, the water occupying the space between sediment or soil particles, was

extracted from sediment of the nine stations sampled for toxicity and bioaccumulation

testing. The isolation of pore water from these sediments occurred at the Site between

November II and 13, 2003, Total suspended solids (TSS), chromium, and metals in pore

water were analyzed by MEC Analytical Systems (MEC) in Calsbad, California and

STL-Edison. TSS results are presented in the Offshore Investigation, Sediment Toxicity

Characterization Report for November 2003 Sampling Activities, Honeywell Study Area
7, Jersey City, New Jersey prepared by MEC (2004). Table IS presents the analytical

results of total chromium and chromium VI in pore water. Table 16 presents the

analytical results of metals in pore water,

PARSONS Page 12 ENVIRON

TIERRA-B-014930
4.0 WATER COLUMN CHARACTERIZATION RESULTS

4.1 Total Suspended Solids

Water column samples for TSS analysis were collected in November and
December 2003 during the oceanographiclhydrodynamic survey operations. The results
of TSS in the water column are included in the oceanographic-hydrodynamic
characterization report entitled Honeywell SA 7 Sediment Program Oceanographic
Survey, Jersey City, New Jersey report prepared by OSI (2004c).

4.2 Chromium

A water column sampling event was also implemented to evaluate the potential
presence of chromium in surface water adjacent to the Site and in the identified reference
areas. On October 16, 2003, shallow surface water samples were collected for chromium
analysis from three locations near SA7 and from two locations in each of the three
targeted reference areas. figures 2 and 3 show the locations of water column samples in
the vicinity of Study Area 7 and the reference areas. All chromium grab water column
samples were submitted to Columbia for analysis of total chromium and chromium VI.
Total chromium was analyzed using EPA Method 60 lOB and chromium VI was analyzed
using EPA Method 7199. Table 17 presents the analytical results of total chromium and
chromium VI in water column samples.

PARSONS Page 13 ENVIRON

TIERRA-B-014931
5.0 GEOTECHNICAL CHARACTERIZATION RESULTS

5.1 Geotechnical ParameteI"s

To collect information on the physical sediment characteristics necessary both for


evaluating potential sediment remedies and in possible designing of near-shore structures (e.g.,
docks or shoring) to be used as part of the SA7 remedy, a number of sediment boring samples
were collected for geotechnical evaluation. Figure 2b shows the locations of sediment borings for
geotechnical characterization. The offshore geotechnical boring program was implemented
between December 3 and 23,2003 under the oversight of:MRCE. Table 18 presents the results of
the sediment geotechnical parameters, which included natural water content, liquid limit,
plasticity index, gradation (grain size), organic content, and specific gravity of the sediment
samples.

Core sediment samples were also obtained for standard oedometer (consolidation) and
permeability testing. The sediment samples were collected widl piston cores during November
and December 2003. However, these samples appeared to have been disturbed either as a result
of the coring, storage, or transportation procedures, and were considered too disturbed to obtain
meaningful consolidation and permeability results. MRCE has undisturbed sediment core
samples collected with a fixed piston from the shallow portions of the deep borings, GEO-l
through GEO-S, which can be used to run these tests. The locations of these borings are shown in
Figure 2B. ENVIRON requested the results of standard oedometer and permeability testing of
sediment borings (GEO-2. GEO-4, GEO-S, GEO-7, and GEO-8) from IvlRCE. The results of the
standard oedometer and permeability testing are shown in Table 19.

5.2 Self-Weight Consolidation/Column Settling

In addition to the geotechnical samples, surface sediment was sampled from three
locations for self-weight consolidation and column settling tests on November 22, 2003. The
self-weight consolidation/column settling test samples were submitted to Trident Tech Services,
Inc. (Trident) of Chesterton, Indiana for analysis. The results of the self-weight consolidation-
colulTU1settling tests are presented in the Sediment Testing Report - SA 7, Jersey City, New
Jersey report dated February 20, 2004 prepared by Trident (2004).

PARSONS Page 14 ENVIRON

TIERRA-B-014932
5.3 Radiodating Analysis

To age-date different sediment depth intervals, sediment samples were collected from
certain sediment cores during the offshore sediment coring program for isotopic radiodating
testing and evaluating the depositional history of the offshore area near the Site and the stability
of the sediments. The radiodating samples were analyzed by Flett Research, Ltd. (Flett) of
Winnipeg, Manitoba. Canada for isotopic constituents using lead-210 (Ph-2l0) and cesium-137
(es-137) as indicator elements. Sediments to a depth of 10 em were also analyzed for bery IIium-
7 (Be-7), and a very limited subset of sample intervals was analyzed for radium-226 (Ra-226)
The radiochemistry results are presented in the Radiodating Analytical Report dated April 25.
2004 prepared by Flett (2004)

PARSONS Page 15 ENVIRON

TIERRA-B-014933
6.0 ECOLOGICAL TOXICITY STUDIES

6.1 Sediment Toxicity and Bioaccumulation Samples

Composite sediment samples for the analysis of toxicity were collected between

November 7 and II, 2003 A description of the sampling process was discussed in Section

3.7.2.1 of the Offshore Investigation Post - Field Sampling Report October 2003 To JanuQlY
2004 Activities, Study Area 7, Jersey City, New Jersey (Parsons and ENVIRON 2004). The

composite sediment toxicity samples were analyzed for total chromium, chromium VI, TAL

metals, AVS/SEM, sVOCs, PARs, pesticides, PCBs, PCDDlFs , PBDEs, and other parameters.

Results were compared to those from similar testing performed concurrently at three locations

elsewhere in the Hackensack River and upper Newark Bay. Bioassays were performed in

accordance with USEPA and us. Army Corps of Engineer test methods. The methods and

more detailed results of the sediment toxicity study are presented in the Offshore Investigation,

Sediment Toxicity and Benthic Injaunal Characterization Report jor November 2003 Sampling
Activities, Honeywell Study Area 7, Jersey City, New Jersey prepared by MEC (2004). Results

of the sediment toxicity samples were validated using the data validation method described in

Section 3.1 of this report and are shown in Tables 4 through 14.

6.2 Benthic Infaunal Smoyey

Sediment samples were collected offshore from SA 7 and in three reference locations to

determine the abundance and diversity of the benthic infaunal community in the sediment. The

benthic infaunal survey was performed in accordance with EPA methods. The methods and

results of the benthic infaunal survey are presented in the Offshore Investigation, Sediment

Toxicity Characterization Reponjor November 2003 Sampling Activities, HoneyweJl Study Area
7, Jersey City, New Jersey prepared by Iv.lliC (2004).

PARSONS Page 16 ENVIRON

TIERRA-B-014934
7.0 REFERENCES

Flett Research Ltd. (Flett). 2004. Results of Hackensack RiverlNewark Bay Radiochemistry
Measurements. Letter from R.J. Flett to C. Stubbs, Environ. April 25.

MEC Analytical Systems, Inc (MEC). 2004. Offshore Investigation Sediment Toxicity and
Benthic InfalUlal Characterization Report for November 2003 Sample Activities;
Honeywell Study Area 7; Jersey City, New Jersey.

Mueser Rutledge Consulting Engineers (MRCE). 2004. Subsurface Investigation, Study Area _.
7, (Daylin-Grace Site), Jersey City, New Jersey. April 15,

New Jersey Department of Environmental Protection (NJDEP). 200 1. Standard Operating


Procedure for the Completion of the Data Validation Report Forms and the Preparation of
the Final Data Validation Report, SOP No. 5.A.15, Trenton, New Jersey. October.

Ocean Surveys, Inc. (OSI). 2004a. Honeywell SA7 Sediment Program Bathymetric Survey;
Jersey City, New Jersey.

Ocean Surveys, Inc. (OSI). 2004b Honeywell SA7 Sediment Program Geophysical Survey;
Jersey City, New Jersey,

Ocean Surveys, Inc. (OSI). 2004c. HoneyweIl SA 7 Sediment Program Oceanographic Survey;
Jersey City, New Jersey.

Ocean Surveys, Inc. (OSI). 2004d. Honeywell SA7 Sediment Program Vibratory Coring, Trident
Probing, Hand Penetrometer and Vane Shear Investigation; Hackensack River, Jersey
City, New Jersey.

Parsons and ENVIRON International Corporation (parsons and ENVIRON). 2004. Offshore
Investigation Post-Field Sampling Report October 2003 to Janu;uy 2004 Activities; Study
Area 7; Jersey City. New Jersey. Febru;uy 27.

Trident Tech Services, Inc. (Trident). 2004. Sediment Testing Report - SA 7; Jersey City. New
Jersey. February 20.

Van den Berg, et al. (1998). Toxic Equivalency Factors (TEFs) for PCBs, PCDDs, PCDFs for
Humans and for Wildlife, Environmental Health Perspectives 106, 775,

PARSONS Page 17 ENVIRON

TIERRA-B-014935
Tobl. t
Summar)" ofChemir3h. in Sediment S:lilmple~ in ~he Vldnity ofSA7
DfI'hl('ted
S'ud,. Area 7; Jrruy Clt)'. New Jersey

Rang. ERL ERL ERM


Chrmi<'al!'l
Det~('"tion A ....er.tge Df'reC'ted ERM NOAA AET
of (NJDEP/ Excud":I.J1ce (NJDEI'/ NOAA
Frequrm:-)' CQor:-eneration Eu-e-edD,R-cf Erc-el"dnnct!
Detrl'flcm NOAA) Frequency AET
NOAA) Fl"'C'quenc)' Fnqlltn('y

M~(al:l m«l/kp):

A'l,Iminum 63/63 2380" ll800 8,630 ... _. ...


Antimony
Anenic
3/63 2.3·2.9 H ... _. '"

--
---
-_. 9.3
---
OiJ
Bal'"ium
BerylliulTl
60/53
53/53
L3 -ID
l5·638
19
137
8.2
... _.
39/50 70
...
3160
...
3l
48
71liO
48/53
62153 0.11 - I O.S --. ... ... --- ... ..-
Cfldmium 54/68
C.lcium
Chromium
63/63
0.14·10.1
34l- 37000
1.7
6,213
l.2
... _
28/5"
.
9.6
...
1154
---
3
...
7/14
---
411/421 39·33500 534 81 280/421 370 137/421 52 288/411
Hcxavalenl Chromium NJDEP 7196A 7/304 5.49·2J.1 10 ... ... ..- ... ---
H<xavolenl Chromium NJDEP 7199 2181304 '"
0.. 78·40.9 3.7 -'- ... --- ... ._ .
Hexa ....alent Chromium EPA 71%A
Hexavalent Chromium EPA 7199
1/304
144/304
l85·5,86 19 ...
_.
-. _. ... ._ .
---
.-.
0516·56.5 4.4 --. '" -- ... .-.
Cobalt 63/63 2.1·21 7.6 ... ... --- ...
Copper 64/68 4.5·715 10 18/63
129 34 48164 270 7/64
Iron 63/63 390 3/64
5310·38900 21,373 - ... -.. ... ... ._-
lead 641207 2.1 - l20 137
Magne.'lium 5J/63 1160·9390 5,051
47
-_.
_.
50/64
... _.
218 13/64
--
400
...
2164
... !
Ma."g~ncsc:
MC"rcury
63/63
601203
45.3 • 623 298 ... _. -. 260 40/63
0.041 ·64 6.8 0.15 53/60
Nickel 0.71 45/60 0.41 48160 !

POlA$$ium
64/68
63/53
1.5 - 120
298·2500
28
1,411
21
..- _.
37/64

_
_.
52 3/64 110
...
1/54
Selenium
Silver
3/63
51/63
2.7·3.7 3.2 ... .
-. _.
--.
I
._-
313
0.44·8.8
_.
I
2.4
Sodium 63/63 ~5I - L0900 4,290 _.
1 39/51 3.7
...
6/51
...
3.1 10/51
Thallium 0/63 .- .- _. _. _. ...
--
_.- _....
V.Rn.Adilim
Zinc
63/63
64/68
5.8·98.5
14.2 - 842
28 .-. ... _. ._- 57 3163
252 150 40/64 410 13164 410 13/64
IO ...... otlns (uP/kpi,
Dlbutyllio 21/63 1.9·14 5.1 ... -- -.. ... ...
M.onQ-butyllin
Tc-Ir~butyhin
7/63 12·2.3 1.7 ..- ... .-- ... ... ...
7/63 26-5.4 3.4 ... ..- ... ...
Triburyhin --- ---
19/63 1.9·19 H ._- -. ... -'. --- ...
,

Parson!
Page I of7
f: 1'<' , RON

TIERRA-B-014936
Tohle 1
SUJhmltl")' of Chem 1l'8b: Detf'(,'I'td III Sediment S:a.mpl"!I; in the: Vi(ini~' of SA ,
St .. dy Aru ;; ,JCr1It"y Ci1')', Nf''W Jenr~

1
!
Oetntlon
Rang.
Ave-rag-t D.tected
ERL ERL ERM ERM NOAAAET
Ch("mi('~l! of NOAA
Frtqurnc)' (NJDEP/ E.x(,f'f'danC"f' (NJDEP/ E:u'Il!l"donef' Exc-trdanc-l'
Conc~ntntlol1: AET
o.te~tion NOAA) Frrquf'oq NOAA) , Froeque-nc)' Foreqt.ch(",J

Sfomi-volucile Orvnnk Comnnund$ (1I.1I.i,

E,2,4~Trichloroben.tene 15164 13 ·140 49 _. -- -- ---


!.2·Djc~lomhc:nzen~ 11/64 17- 51 _. I
...
4.8 15115

! ,3-Dichlorobe:nzenr; 13/64 2Q·40


21
26 _.
--
--
--
---
IJ
...
II!!I
1.Il·Die}, IOfODc:f'l2:Cne 34/64 8.8· 160 71 -- _. --
---
-_. 110
---
41}4
2.4~S ..TriehJomphet'lol 0164 .- -- --- -- -- --. !
2, 4,6-Trich lorophenol 0164 ... _ ..
-- -.. -- , ...
} ---
- ..
~~4·Dic.hlomph'Cnol 0/64 ... ..- ... --- -- ._- !
6

2,4. Dimelhylph~nol 0164 --- ... --


_. _. --- ...
5 ---
2,4·Dillitrophc:nol 0164 ..- ..- _. ...
i 13
...
---
---
2.4·Din ilrololuene 0164 --._- .- -- 00-
_._. --
--- ... ---
2.6-Diflitrototucnc: 0164 .- --- --- -- ---
2·ChloropheMI 0/64 .- .- ...
!
_. ... _.
'"

.- 8

_.--
I
2-Mclhylphenol OIM -- .-- I ... -_. - ..
2-NilrOAtlilim: 0164 --- .- -. I _ .. ...
8
...
.-
--
2 - Nilrophenol 0/64 ... -_ .... --... --- ... --- ...
3,3'·Di(;1; IOfobenzldinc 0164
---- 00-

I --- --- _.- ---


3·Nilroa:niline OIM
-- ...
_. ._- I --. --- ..-
-- .-
00 •

4,6-Dil"l itro·2·m cf!'lyrph.enol


4 -Ch loro- 3 -n, elhy Ipheno I
0164
0164 .-- --
00-

... -- I
._-
...
--. --.
I
_.
-- - ..
_00

...
00-

4·Chloroaniline
4·Chloropher'lyl ph~hyl c,J,cr
21164
0164
12 - J80
...
III
...
--... 00.

'-' ---
4·Methylphctlo! _
""-
.. I .00
... ... ---
45164 8.8 - 230
.-
75 --- --. --. 100 10/45
4·Nitroanihne 0164
-- _.
00-

---... -. --. -- _ ..
4·Nitrop!tcnol
bi,(2 -Ch loro<thoxy)m clh.tle
0/64
0164
--- "-

.- ... _. -- ... _. ---


'- --. --.
b is(2·Ch loroeth yl )ether ._- _. _.
---
..-
--
b ;.(2 -Ch 1"",i.opropyl)etIJ er
1/64
0/64
120.
...
120 120
... --- _. ---
I
--
'"

--
---
...
h i5(2 -EIh y Ih" YI)pl1tl\.I .. e 4'164 80· 3JOOO 4,370 ... ... ..- ! ! -_. ...
...
00-

Botylbclllyl ph'h.I.,c 7/64 97 - 2600 861 00-


... --- 63 7n
Carbazoh::
Dibcnzofu,..Bn
51/64 82 - 390 85 --
... -- -- -- I ... ---
Di.lhyl phthal.'e
52164
5/64
11-2000 2'4
_. -- -. ... no 201~2
o;",elhyl phl11alo" 0/64
16 - 210

--- 140
98
.- ... _.
00-

,
..-
...
, --
00.
!
6
6
5!~
...
!
,
Di-n-butyl
Di-n·o<;"lohlh.I."
phthal.'e 11M
0164
140·
---
140
'-'
---
---
--
... --
---
-..
... I 58
61
1/1
I

---

Pag-e 2 of7

TIERRA-B-014937
T.blet
SummaI")' of Chemin I. D<I«led In Sediment S.mpl.,In the VklnlfJ ofSA7
Study A.... 7; Jeney Cll)', NowJon.y

Ran~e ERL ERL ERM ERM NOAA AET


o.l«lIon Avo(!ntge De-hcted
Cht'mkfll~ of (NJDEPI NOAA
Fre-quen(y Conl"entrntlon
ExC'tt"dance (NJDEPI E:r('ol"rdllnr-~ Excf'rdnnct
Dotff'("tion NOAA) AET
Fr"flJul'fW.")' NOAA) FNquen(')' Frcqurncy

llc-xachlorobcnz.enc 0/64 .- .- _. --- ... ._- ..-


He:'(Qch loroblltsdicnc:
He'!( eel1lorocyc lop'C"ntad icnc
0/64 .-
...
... --
_. ._. ---
_. ..-
6

_.
1.3 ..-
0/64
'- ... -- --
.-
Hc-XfIr;hlorodhane
hC)phoronc:
0/64
1/64 420 - 420
... ...
_. _.... ---
...
...
--- I
73
...
._.
.- .
Nilroben;rene 5/64 26 • 2~0
420
123 -- _. -- ...
I
I
N- Ni'lro"lo-ili ~l'l-propy lflmi n e 0/64 .- --- _ ..
-- ... ...
21
..-
5/~
---
N ·Nit rosodiphen yl am i n e 7/64 18·440 -. i
--- ...
Pel11achloropneflo( 0/64 ._.
171
-- _. '"

-- :
-- _ ..
28
17
617
.-.
Pflcnof 0/64 ..- -- ._. --. I
--. --- J 30 ...
:1 I
Pulv[v,l!, Arom.t1,""""ij;dro,arbom no/l, ;
1-Chloron.apl1thalenc
2·Moclhylnaph:hnlcllc
0/64
51164
...
12·4900
.-
316
_ ..
70
..-
3D/51
I
!
--.
670
._.
I

--- --- !
I
5/51 64 3}J51
Ac(:nephlhene 5~J64 8.9·11000 873 16
I !
~3J55 500 IS/55 130 26/55 I
Acenaphthylene ,
57/64 8.6 • 4700 480 44 53/57 I 640 12/57 71 52/57
Anthracene 57/64 28· 10000 1,~56 8~ 53/57 ! 1,100 17J~7 280 37/57
Ben~o{:J,)n.nlhrll.cene 59164 34· 16000 2,362 261 53/59 1,600 22159 960 34/59
Benz.o(a)pyrene 58/64 30·8800 1,574
Benzo(b)nooronlflcn< 58/64 19·5200 1,212
430
...
48/58
... _.
1,600 19/58
--
1,100
1,800
24/58
13/58
Benzo(8,fl,i)pc'Ylene
BcnzQ(k)nuClrflnlhent::
58/64
58/64
16·2600
27 - 6900
641
1,511
170'
240'
51158
53/58
-.
._-
---- 670
1.800
19/58
16/58
Cnrysene 59/64 <10• 20000 2,780 384 52/59 2,800 17/59 950 39/59
Dibenzo(n,h ),flnlhr8ct::nc 49/64 20·880 266 63 45/49 260 18/49
Fluorantl1ent:: 230 19/49
58/64 34 - 18000 3,837 600 471~8 5,100 14/58 l.3oo 32/58
fll,lorene 48/64 8 6 . 4600 5t4 19 47/48 540 10/48 12lJ 21148
'ndcno{ 1 ,2.3-cd)pyrem: 58/64 l3 • 2300 596 200' 48/58 ... ... 600 20158
Napfl'h.lene 54/64 18 - 10000 1,310 160 42/54 2,100 9/54 230
Phen.nthr~ne )5/5~
51164 2\ - 18000 2,219 240 ,
42/57 1,500 IS/57 660 24/57
Pyn:n~ 58164 65 • 28000 5,lt~ I
665 ~IJ58 2,600 27/58 2,400 29158
Df:&f!;cl-ili" 'jj,,/k·,"';.; I

4,4'-DDD
4,4'-DIJE
521136 11 ·76000 16,964 ... _. 20 48/52 16 49152
70/136 12· 820000 42,088 2.2 69no 27 63no 9
4,4'-DDT 69no
121136 13 - 110000 18,972 I 12112 7 12112 12 12112
Aldrin 0/94 .- ... 2' _ .. .-. ..-
alnh.·RHC I 9.5 ---
5/94 12·38 2J 6' 515 ! -.. ... I
I --- ...

Page 3 of7
EN"IRON

TIERRA-B-014938
Tabl. t
Sumnulry or Chenlka:1.s 1le-lecC'~cI in Sediment SAmples in the Vidnity o-fSA 7
Study AN'A 7; Jf'n~)' Cit" NrwJene)'

Range ERL ERL ElL....


Chemkfllls l)u~("H()n A""-rragt Drff'(fedl ERM NOAA ,\£T
Frequrn('y
or Conrf'nfnlltion
(N.1DEPI Exce~dal1-('e (NJDEI'I EXCIff'd;JJ1cl" ro:u{'('(Inn('t
Detf'C'f1on NOAA) Fnqu!'nc) AET
NOAA) Fr('qu~n{'y F....
equency
~
bet.·BHC 4194 18·23 21 ... ... -- ...
Chlo.-dan-e 0164 -- .-
5'
0.5
_ ..
_.
4/4
6 ... 28 ._-
dello·SHC
Dieldrin
0194
6/94
-- --- -. ._- ._ . ._- ..-
14 -78 27 0.02 6/6
E..,d05ulfR\1 J
8 6/6 1.9 6/6
11/114 3200·37000 12,]82 -.. --- ... ._- --- ._ .
Endo~ulron
Endosulfan sulfnlc
If 0194 --- --- --- _ .. ..- --- -_. ._-
Ehdrin
1194
6194
4900.4900 4,900 -- -- ... --. --- ---
Endril1 aldehyde
19 - 24000 12,00J JO 6/6 ._- --- -.- -..
Encl..-in kdon~
5194 19 - 140 48 -.- -_. --. --. _.- ---
gamma-DHC (Lindane)
14194 8.2 - 180 JS ._- ..- ..- ... ... ---
1194
Heploohlo' 3194
19·19
IJ . 62
19 JO
... _.
III --. --- 4.S 111
Hcpl acl1 lor .:r~:"idl:
44
..- ... OJ ][J
3i94 1j - 140 70 50 ]{] ... ... --- ..-
MelhoXl<hlor 11194 13·210000 22,837 ._- ---... -.- -- ..-
Toxaphlene 0/94 .- --- -- --- --- ... ..-
nj ........
ins 'Inri Fii .... ii" {"
T J '\.
Dwxi.n~ and F"ran;, TEQ ..... 64164 _ .. _ .. _ ..
2,),7,8-TCDO
0.3 - 171 16
--- H J1/6<1
1.2,].7,~-P.CDD
48168 247·2nO 175 --- ---
_ ..
--- -.. .. ,
--.
1,2,::,4,7,8-l-ixCDD
21168 0.9j3 - 16.2 10 --- I --- -- -.. ---
23/68 0.87 . 40 I ..- ... ._.
_.--
8.1
1,2,],7,8,9-H><COD
._. -- ---
1,2,\6.7,8-l-lxCDD
29/6S 0.451 -75.2 14 --- ... I ..- ...
34/68 0773 ·12E .. ... ...
1,2,3,4,6,7,HlpCDO
OeOD
59/68 304 • 1560
25
247 _.
---
...
,

--- _--. ...


...
---
63168 ..-
Tolol TCDD
6.31 - 14400 2,5JI --. --- -- ._- ._-
.9168 247-3060 209 -.. .-. _.
To.ol poeDD --- --- ._-
T 01.1 H><CDD
40168 '2.77· ]04 51 --- -- --. --
_. --- ---
To,,,1 HpCDD
54/68 509·1100 166 -.. --. ..- -..
6016E 2.4 - 4180 614 ... -- ._- ...
---
2,3,7,8·TCDF 48/58 -. -.
--- ._.
1,2,3,7,8·PeCDF
0906·491 31 --
_._. --. ... --.
...
_.-.
46/68 0.993·315
2,3,4,7,8·PeCOF
30 ! ... --- -_.
_.--
.7/68 U3·42I
1,2,3,4,7,8-HxCOF 55/68 289 - 4720
43
... ._- _ ..
1,2,3,7,8,9·ft,COF
274 -- ... --- -.. ...
28/68
1,2,],6,7.8-HxCDF 54/68
0319 - 142 15 --
...
-- -.. ... --- ---
2.3,4,6,7,8-H><CDF 46168
1.46·1020
0.862·352
74
_. ---
._.
-. ..- --- ...
29
--. ..- -_ . -_.
1.2 3 4 6 7 8-H"CDF 59/68 157 - '7820 716 --- ... -.. .-. ._- ...

Parson:!
Paso 4 of7

TIERRA-B-014939
T.bl.1
Sumrt1a~' afChemlC'ah: D.trl"totd in &:d;ment Samples tn the \1dnffJ urSA 7
Study A5'ea 7; J~rsIl!J City. N~w Jen.~

Rang. ERL KRL ERM KRM


Dclt<llaQ A'O"l'l"'O:g.- D~rt"C'ted NOAAAET
Chf"lnirsl"
FriE'quflnry
or (N,IDEP/ E~("('('da.n'Ct (NJOEPI EXl"eedanC'('
NOAA
Exrcrdan-rr-
CORcpntration
De4edion t'OAA) Frrqllf"nry AET
NOAA) Frequen{'y FrequcnrJ

1,2.3,4,7,S,a-HpCDF 37/68 0.727·165 26


_.
--- _. ... j
_. ... '.'

OCDF 5g;68 _.
15.5·25560 1,559
_. --- _...
. ... ---...
Tol.1 TCDF 53/68 41·11800 1,188 ... _.
Tol.1 PeCDF 55/68 1.6.1· 9180 756
_.
... _. _. ...
...
... ...
Tol.1 fi,CDF 56/68 2.54· R780 ... _. ... ... ...
Tol.1 HpCDF 61/68 1.57·22510
678
1,196 _. -- _. ... ... ...
Fol '-chlorinated 0' llen ....ls (.-..1 .......

CoplAnar PCB, TEQ" 64/64 19·2855 172 22,700


_.
0164 180,000 0164 130,000 Ul6~ i
_.... ...
PCB·77 4<l164 63.5·4.1200 3,902 -. ... ...
pCB·31 37/64 5.22' 5210 488 '"
_. '" ... ... 1
PCB·105 46/64 53.2·114000 9,103 ... ... --. .-- ._. ...
PCB·!06/118 50164 16.2 - 295000 22,861 ..• ... _..
'" ... ...
PCB·1l4 38164 6.61/·7570 685 ... ... -- . ... --- ...
PCB·ID 38164 7.28 - 5640 ... .-- -- .
PCB·126 2"'64 10.2· 1050
549
191 -- _.... ... ... I
...
---
--
...
.

PCB·156
PCB·Il7
43164 37 I ·23300 2,Til --- _. .-- ... I ... ...
37164 9.24·5190 599 ... ... -- ... I --. ...
PCB·167 41164 15.3·89l0 aS4 ... -. ... -_. ... -..
PCB·J69 7164 1/.1J6 -1/7.3 27 --_. ... --. ... -- . ...
PCB·l70
PCB·IRO
45164
49164
915 - 43100
7.85 . 103000
4,950
11,723 --. _.--. ..-
... '--
...
...
'--
--
.-.
.

PCR·1S9 341M 10.2 - 1600 257 ... ... --. ... ... ._-
Totol monoCB 47155 )2) ·11500 1,653 ... -.. _ .. ... ... .--
Totol diCS 48115 R.4 . 208000 20,351 .-- '" ... ... ... ...
T"l'!oPIIIMCB 47/55 5.-16· 1910000 117,257 ... ... -- . ... ... ...
Tol.RIldrRCB 491S5 )0.4·4010000 211,514 ... ... ... ...
Tota! pel'1lll;CB 43155 75.2·2320000 161,466 ... ...
'"

..- ... - ..
---
Tola! I1cxaCB 41155 2~.4 . 1010000 9.1,DI0 ... ... ... ... ... _ ..
TOI.I '"pl.CB 4015l l3.1 . 3891100 44,466 ... ... ._- ... -.. .-.
Total actaCB 36115 104. 101DOO 19,237 ... _. '" ... ... ...
To-tarnonaCB
Totnt decRCB
36155 nl·11400o 10,082 ... .-- -.. ... --. .-.
38155 59.2 . 42000 5.013 ... ... ..- _._- ... .. -
'"

P.ge 5 or?
f. N \ I I< () N

TIERRA-B-014940
Table'
SUtnmAry ofChemk"l, D("tr-c.~d In Sedim!'llt Samples Intlull Vldntl)' ofSA1
Study Ate'll 7~ Jeney City, N-ew J.crny

I
RJonge ERL ERL ERM
Chrm't"ol!l
Drte-efron A v~Ntgl" DIPtrlL"tfd ERM NOAAAET
of (NJDEPI E~('r'!dM(t (N.IDErl NOAA
Frt'qut",y Con.('l!'nrnU~nn E:s::ctedanc-e Exned;l,n('1!
Ol;!fl'ctlon NOAA) Frrqu-tnC'y I AET
NOAA) F~qth"f1(} Fre'luf'n('y

Arodor rm!tk..l
Arcx.11.lI'·IOI6 0172 --- --. _. ._- --- --. --- _ ..
Aroc lor-I 221 0172 --... --. --- --- -_. ... ... -_.
Arrx:.lor-1232 0172 --- -- ... ... -- _. ---
II.roclor-1242 0172 ... --- ... ... ... --. ._-
A.roclor-124R
Aroclor·1254
37m 46·960 260 ---
'"
-.. _. ... - .. .--
20n2 48-no 289 ... --- --. --. -..
""-oclor·1260 Isn2 46·420 191 -- ... ._- -_ . ---
--- ---
Pl:Ji"fDNlmillltlte-a Oinntn'l'l th .... 1",,191
BDE·I
BDE-2
221M 17.5·693 193 ---_. _. -. --- -.. ...
17164 _ ..
1l.2 - 439
--.
_....
148 ---
BDE-3 31164 ...
BOE·7 42164
9.n·1380 ]~5 --- ..- -.
_ ..
"- ---
1j5·1160 242 --- ... ---
BOE-IO 14164 103·14.8 4.9 ... ... --- ---
BDE·D --- --- ._. - ..
32164 ._. -_.
BDE·15 53164
0.646·283
0585.4QOO
54
351 .-- _.--- --
---
--.
--- ...
BDE·I? 40164 273·1['10 31Q ... _. _._. ---
.--
.--
8DE-25 7164 3.34 • 45_2 12 -.
_. _._. --
... ...
---
---
BDE·28
80E-35
44/64 3.2 - ]16 85 _. -.. --- ...
BDE·47
15/64 1.27 ·107 ]5 --
_. ..- ... --- ... ---
I
I

BOE-49
64/64 343 . 6460 630 ... _. ... _ ..
---...
,
4]/64 2.9·3070 634 .-. ..- '" --- ...
BDE·66
8DE-75
31/64 HI ·234 67 --. ... _.- -.. --- ---
28/64 l.Ol - 501 --.
BDE·n
134 --- -.. --- ! --- ---
80E·85
7164 O.63~ - 896 2.7 ... ... --- '" --- '--

_.--.
32/64 3.56·189
BDE-99
34 --- '" _.- -.. -..
64/64 31~·6550 597 ... --- ... ...
BDE·]00
8DE-116
62/64
7164
727·1480
682·29.6
j 12 _ .. ..- _. ...
---
-.. ---
13 --. ... .-- ... ... ...
BDE·126
BDE·138
7/64 2.13 ·9.97 4.1 --- ..- --. ... .-- ---
BDIO-IS3
10/64 5.49 ·120 37 .-- •.. -.- ... --- .--
BDE·IS4
36164
36/64
IU -1120 273
_.... ... ... ._. ... --.
7.52 - 936 --. _.
BDE-155 19/64
210
...
... --. ---
BDE·IS6
BDE-ISI
7164
338·107
3.74 - 42.9
42
10 _. _.
'" ...
--.
..-
...
---
_ ..
--.
---
7164 4.57· ~l 16 ... -- . --- --. --. --.

Page 6 of7
EN\!RON

TIERRA-B-014941
Tablel
Summary of Chfo..nl<'Rls Dthchd In Sediment S.mple-s In !he Vicinity of SA'7
Stud)' Ar~a 7;. Jeney Ch;y, New Jrr.sey

o.l«llon Ro"!:e ERL ERL ERM


Che-ml("sls Average O .. t .... Ced F-RM NOAAAET
Freqa'Cm-y
or (NJDEPI E.x.cred .....~ (NJDEPI
NOAA
C"rH',mt~"'ion E~['e(ld.lU1('e- Eutedann:
Dptectlofl NOAA) AET
FN-quruc)' NOAA) Fnqu-en('J FrrrJLI(lllC)'

80E-183
80E-197
38/64 10.4 ·4940 803 ..- _.-. -. _. .. _ ..

_....
.
33/64 7.l;S • <930 676 ...
BOE-~03 ... ... ...
32/64 1l.l·1910 609 _. ..- ... ...
RI'lE·207 ... _. ...
8DE·209
36/64
~2164
28 . 6980
178·291000
2,U17
59,384 ... _. _.
'" ... ... ...
Tolal Mono-8DE _. .-
_. ...
_.--.
'-'
32/64
TOlal Di·BDE ~3/54
12.1 • 1550
0.936.4190
~40
... -. ... ...
TOlal Tri·BOE 45154
832
... _. _.... --. ..- .--
Tot.1 r'ITa·SDE
3.25 . 3780 1,005 ... ..- ...
64/54 34.3·11500 1,890 ...
_. -- .
_. -. ... ... _.
Tolal PenlA·ODE
Total HexA.BDE
64/54
35/64
387. 8520 806
_.
... _. ... ...
19.6·2950 775 --. --. .--
T".I Hopl.·BDE 38/64 _. ...
... --.
r".] OeIA'SDE 34164
IOA·6580
931 - 8930
1,178
2,212
_ ..

-. _. _. ...
...
-- . ...
._-
TOlal NonA-BDE 36/54 zg • 13500 4034 --. _. _. ...
---
... ._-
~
New Jeney Dep.artmcM.1 of Ern:uonme-Illal ProLcction (NJDEP). 1998, GuidRl1ce [c)r Sedimcr11 Qunlity EVIl!uilIliQns. November.
Buchman, t\ltF" 1999. NOAA ~t:n:cniJl8 Quick ReferCDit~ Tablc~. NOAA HAL MAT Report 99-1 .. Seanle: WAf C08:5l..ldProteclion
IInd RestotAtion Di"i~ion. Nallon,l O<:eanic and Atmospheric AdminislriItion, I Z pllgt::.~

Note"
An .anlll)'~es Are ba,~d on V.fl:lid.aLll:d dota from rnc October 2003 Lhroug.h JOfllla.ry 2()04 field sampilnB evc::nb and from the 2002 Rc:mc:dial Invcslisstion .Report pl'"l:pnred by Tetl1l- Tc:t;h.
HeXIIYfldent r;;.f'lromium 8nalY'5-l:s were cDnducted by 1wo analytical mcthod.~(1196A and 1199) following ex.lfa.clioo by !\l,IO rntlhods (NJDEP and EPA).
ERL ~ Elfocll Ronge Low.
ERM • ElfeclS Range Medium
NIDEP New )c!'1ey Department of Em'ironmC'nral Protcction.
:>::

NOAA = Nation-al ~anic. .and AlmotphC"ne Admln~$lr.t'ltion.


AET " ApPArenl Efreel.5 Th,...hold.
EPA"" l'niled Stoic, Environmental p((lt~ction Agency.
mglkg ::: Miligr'll:J1ls per kilogram
uglkg = Microgram, per kilogram
pg!g :::p1cograms per gram .
= Vllh .Ie not Bi\,lillilablcfor
..-. this ch-emical
* ~ MarSllelE.3-tlJarinc: ~cdimcnl sl;n:cnlng crit!!ria not available, lh-c fre!:l,wlI:l.e:r 'c:dimcnt socrt:c:ning criteria was uscd.
*- TEQ;:=;Toxicity Equivalency Quolient~ TEQ calculation' do no( include: dMo from lhe 2002 RemcdiaJ In\'~sli8ation Repor1.

P."-on. ...
Page 70f7

TIERRA-B-014942
Tabl.2
Summ3ry orChemh:als Doete'Ct~din SrolnH~f\t frum 0 to O.!i rt Bfllo'W Mudline-
Stud)' Arl"l 1; Je-rsc)' City, N~'W Jerw)'

I
Rgnge
Det(lctlon A "tra~e Dl@:tt'cled
Ch~mlC:lI~ ERL (N.lDE?1 ERL E~c~edal1ce ERM(NJDEPI NOAAAET
Frequency
of ERM EUf'rdance NOAA
ConcenlralJon NOAA) Frequehcy F.:lc('ed3nr-1"
Delt:dlon NOAA) FrE!CJuency AET
Fr~qll'l'f1-('j
.... t.I~-~ m~k"'
AI\.Irruoum 40140 2380·\4700 7,~4S -- -- ... ...
Anlimony
Ar'\cnic
1140
40/40
2.3 - 2.3 2.3 ._- - -- _. ...
9.3
.- .

WI
Barium 40140
lA - 113
9.1 • 3~5
17 8.2
- _.
24140 70
... _.
2140 3S 4140
BCl"yTlium
Cadmium
39140 0.11 • 0.97
112
O.S _. -- - -.
4g
...
31140
---
38145 0.14-8.1 J.5
Calcium
1.2 15138 9.6 0138
40/40 34S·37OO0 .. 3 4138
Chromium 115149 7.4 - 14200
6,643
824
_
- - -. ... .-.
81 10011\5
Hc;uvdcJlI Chromium NIDEP 11%A
Chromhln'l NJDEP 7199
0145 - -.. -- -..
370
._-
SO/Ill
... _.
62 1041llS
...
Hcx~vllenl
H,,, .. I.n' Chromium EPA 71% A
30/45
0/4l
0593-
-
11.3 3.7
.- _'--. .-
.-
.- - ... -
Hexav.llenl Chromium EPA 7199 3414S n ... ... - '" ... --.
0.744·12.4
... ._ . ... ---
Cobal,
Copp.r
40140 2.4·21 7..1 .- -. .- - 10
41145 6140
Imn
L••d
40140
6.4-715
5310 - n900
119
20,051
34
... _.
32141 270
...
3/41
-
390
..-
2141
...
411130 7· 476 122 47
M.l,gne.~il.lm HI41 2U 6141 400 1/41
Manganne
40/40 1250- 9190 4,825 - -- ._- ._. ... ...
Mc:rcliry
40140 l16·520 269 ... ... ... -. 260
411\26 0.041·64 6.2 24140
0.15 35/41 0.71
Nick<:] 41/45 29141 041 3214\
16·120 26 21
PQI .... sium 22141 S~ 1/41
40140 ~9S. 2600 ... 110 1/41
S-clcnlum 3140 2.7 - 3.7
1,349
_ .. --
...
--- -. ... ...
Si~ver 35/40
3.~ ..- ... 1 31)
0.44·8.8 2.3 I
Sodium 25135 3.7 41H
40140 3.1 7/35
Thallium
HI·9360
-_.
4,243 --- -.. .-. -.. - ..
0/40 ... ...
'"

.-
Vanadium
Zinc
40140 5.8 - 98.5 26 _. .-
...
...
...
._-
...
S7
.-.
41145 19.2-842 231 2140
150 24/41 410 6141 41 D 6/41
~nntj"'~ u-/ko"

LL
Dibulyllin 17140 19· 14 ... -- -- - -. ..-
MQnoburyllin
Te'r~bl,Jtj'l1in
5140
5/40
1.2 -2
2.6 ·S.4
1.6
B
--
...
~
._.
-..
...
.- ... ...
Tribu'l'hin [6140 1.9· 19 ... .- --- ._-
I 6.3 --- ... .- -.. -..
'I

Page 1 cf7

TIERRA-B-014943
Tabl.2
Summary orCheml"ab Delectocd In Sf'dlrnent from 0 loO.S n Be-low Mudllne
Study Aru 1~ Jersey City, Norl'l'Jrr~)'

Chemll'Bls
Detection
Freq.u'C'nq
RAnge
.r
Detfctlon
A yerage D~tectl!d
Conuntratlon
ERL(NJDEPI
NOAA)
ERL E:toCwibnc-e
Frequency
ERM(NJDEP/
NOAA)
ERM. Enroedancc:
FreqQ~nC"y
l-=;l
I
NOAA
AET i
NOAA AET
EH'I:,:dancc
Fr-equenry

t.>mi.vol.tHf Orlank Comno'lJnd! (~·~k I i


1.'2,4-TrichJombcnlcm: IJ/41 13 - 140 II
_.--- - --- _. I
I
1,2·Dkl\lomb-c:nzc:n'C
1.3-DictllorobenHne
9/41
11/41
17 ·51 27
_.- -- _. I 48
IJ
IJlll
9/9
20 ·30 25 -- - --- ... .-.
1... -Di(:t\I<lrobc"l.~ne
2,4,5-TrichJOfO'phcllOl
29141 g.8 ·160
_.
68 -.
_. ._- .---- ..- 110
2,",6~Trichlmophc:nol
OJ4l
0141
-
.- -- -- --..- ---
... 3
l!l9
---
2,4·DithJorophcnol OJ41 -- ... --- ... - 6 ----_.
_. -
_..--
2,4·[)jmelhylphenol OJ41 ... -- 5
2.4-Dinilropheno] 0/41 ... _. --
-
.- - 1& ---
2,4·Dirtitrololuene:
- --. ... - -- - ---
2.6-Dinitrotolucfle
0/41
0/41 -. - _. .-
_ .. -
-
--
_.- I
._-
---
._-
_ ..
2·Ch/oroph"nol 0/41 - - - - -- ...
2-Melhylphenol
2-Nilraaniline
0/41
-
---
...
.- _.
.- -- ... --_.
8
8
-_.
..-
2-Nitrophcnol
0/41
- -- .- - _.
0/41
...
.- -
_. .- - .-. -
3-"3'-DicWorohen
]·Nitroan.iline
zidine 0/41
0/41 ._.
...
.- ... _.
'"
--- -- _. ---
._.
4.6-Di("liltO· 2·mc: thylphcllOl -_. ._. ... _. ..- --- ...
0/41
.- .-. ._-
-4 ·Chl orc~.3-me thyl ph-enol 0/41 ... ... .- ._-
---
-- ...
__..
'"
4-Chloman.iline 23141 12·380 110 ... ._. ._- _ ..
---
...
4-Chloroph'n)'1
4.Methyl phenol
ph'nyl ,'hor OJ41
33141
._- .- ...
.-.
- ... -_. ...
8.8·220
_.
68 .- --- .--
4-Nitroaniline ill4l - --- _. _._ . --...
100
•.. _.
6/33
4 - Ni trophenol OJ41 .- ... .- ...
b~$(2-Chi OrOcl h(lxy )mcl haRe 0/41 ._. '"

--- ... ._-


Dis( 2 ·Chloroelnyl}ell1er 1141 '- -.. ... ... ._-
bi s( 2-ctll-orni!JopropyI)c: Ihtr ()I 4 I
120·120
-
120
_. ---
_.
...
-
--. _.- -_.
...
---
---
...
---
bi.( 2·E'hylhe <) I)ph.h, I.'e
B~f)'lbc;nzyl phlh.alate
34/41
7141
80 - 20000 3,456
...
.- ._- ._. '" ..-
97. 2600 861 .- ...
C.lrbuolc
Dibcnzofur:lI1
35141 8.7 ·310 76 --- ... _. ---
.-
6J
._-
m
._-
_.-
37/41
Di<'hyl ph'h.I."
11 - 1800 lR9 - -. ... 110
Dimethyl phthalau:
11.1
_.
16·210 98
.- ... - ._-
.-.- - 6 ,
10137

Di'n-buryl pht""I"<
0141
1141 140· 140 140
_.
_. .-
--.
--
'-
6
,
511
...
[)j·n-o<",loh'hal.'e 0141 - -. -- ... .-
18
61 i
III
---

Page 2 of7
£N \"1 H 0 N

TIERRA-B-014944
Tobie 1
Sumrnuy orCh.emkal!§: Deote<:te-d Ih S~dimenl rr-ll'm 0 (0 Q..S n. Bflow MlJdUne
Study Area 1; Juse-y City, N("w J,crsty

DetecUon
Range
Chemical!! Av-enge Detec(ed ERl.{I'IJDEP/ NOAAAET
FrE:qul;"ncy
or ERL EJ:teedlnce ERM(NJDEPI Emf Enttdlncl' NOAA
DeilecUcm
COr'lcentrltloh NOAA) Frequency NOAA) Fr-equllnc)' ExclN'dancc
AET
}o"rrqueon(')"
I
I
Hexachlofobenzc::m:: - .-
0/41
._- -- - - --..- 6 ..-
I-Ic:-r.a(;hlorobulildi",C' 0/41 - "- - -- ._-
Hc.'( a..:hl orocyd open
J Ie;\; Jeld orocth~ nc
tadic:ne 0141 -
---
-- .-. -- -- -
13
... ---
0141
'-- --- -- .- --
I$QphofOnc
NilfDbe:nz.cne
0141 -- -- ---- - - ...
73
---
---
...
N· Nitroso-di -fl- "propyl .:limine
3141
0141
26·250
..-
142
- ... -_ . ---- ._-
.-.- 21
..-
]13

N~Ni tro:SQdi phc:nylamint.


... ...
PC1\la<:hlorophcnol
3141 73 - 440 208
...
- .- I 28 313
0/41 -' -- - - --- I'
Phenol 0141 .- .- -- - _.- --
17
130
---
_. il
,
:
0" L-Ydi'( Ar-nmaU-c H"tiro('Jrbot}$
2-Ch/ormaph'haJene
{ul1/k :
0/41 -- - _. - - - ...
2·Me'hyln.phlhalene 3714L 12 - 900 136 70 18137
---
.'\c.cna:ptuhc:nC' 670 1/37 64 ,1/37
38/41 8.9· Ill)OO 627 16 37/38 500
Ac;.l:'n~phI:h'}'Jc::ne 40141 8.6 - 1400 336 44 37/40
6/38 lJO 13m
ARI!v.;lleenc 640 ~140 71 36/40
3914l 28 - 6900 9~4 g; 36139 1,100 6/39
Bell1.o( ~)3nthrac-ene 40141 280 23139
34·7500 1,729 261 36140
B<;nzo(J)pyrcm:
1,600 11140 9GO 201110
40/41 30 - 5300
Bel'\lo{b)flu<lranlhcnc
Benzo( s"h, i )perrl cne
40141 19· 5200
1,208
978 _.
430
_.
33/40 1,600
--
9140
--
1,100
1,800
13140
5140
ECflw< Ii)fluoranlnene
40141
40141
16· 1800
27. 5500
517
1,223
170'
240'
36140
37/40
--
- _.- 670
1,800
9140 ;
!
Ch.ry~=nc- 40/41 40· 9000 7140
2,028 384 36140 2,800
Dibenlo( ~,h )"nlhr,;u:cnc 9140 950 25"0
35/41 20 - 870 21 L 63 32iJ; 260 !l35
Fll.,lounlh.e;nc 40/41 230 9135
34 ·18000 3,070 600 32140
F1uo~ne
5,100 7140 1,300
33141 33·2000 223 20"0
19 33/33 S40 3/33
Indcllo{ 1,2,J.ed)p,'r-enc 40141 120 10/3.1
N:lphlh.3le:n~ 39141
13·1800 477 lOO' 33140 .- ... &00 10140
18·6400 716 160 2SIJ9
Phen~nlh.rCI1C 2,100 3/39 230
39/41 2S - 49()() SI9 21139
240 27139 1,500 ~/39 (,(,0
P'yrcne 40/41 65· 18000 131.19
3,892 665 36140 2,600 16140 2,400 1B140
I
!P", c'
4,4'·DDD
4,4'·DDE
40191
~4I91
11-1MOO
12· 820000
17,346
47,000
-- --- 20 36140 16 37/40
2.2 53154 21
4,4',DDT 48154 9 53/54
10191 13 ·46000 11.763 I 101ll)
Aldrin _ .. .-.
7 10110 12 WILO
alllh,·BHC
0/71 2' --- ... '--
9.5 -..
5171 12·38 B 6' 515 ... I ..- ._- ..,

Plilr~ORS
Page 30f1

TIERRA-B-014945
Tabid
Summ.lry .,rChemlulll O-ettl::ted in Sediment from 0 to 0.5 n Btlow Mudline
St.udy Area?; Jer!licy City, N~w JeI'H~·

Range
Dt'teclhm A verBse D~ttcted ERL (NIDEPI NOAAAET
Chemical'!i
Fr~qurnt'y
or ERL E".edance ERM(NIDEPI ERM E.x:c:,.~d .. n-ce-
Concentration NOAA) Frequency NOAA) Exce-edBnu
DdtUion Frt:'quency AET
FrNlupnry
~
bela·BHC 1/71 20 - 20 20 S" III ... - - ._-
Chlordane 0141 - '- 1l.5 - _ ..
del.a-BHC 0/71 ... .- - -
6
- .'
-
---
2.8
_. ._.
Dicltlrin sm 14 -20 17 om SIS 8 SIS 1.9 SJS
~ndosul(an t 11171 3200·37000 12.382 - .- --- -- _ .. ._-
Endosulfa.n II 0/71 - ... - - ... _.-
Endosulfiilfl ~ulrnc 1/71 4900· 4900 4,900 _. - .-
--
- ...
_.-
...
E"drirt 6171 19·24000 12.003 3"
._-
616 .- .- ... ...
Efldrin aldehyde:
Endnn ketone
4111 19· 140 Sl
...
.- .- .- ... ...
11171 8.2·64
_. 29 ..- ... ... ...
samma·BHC
Hcpla<:Wor
eLinda"e) 0171
- 3"
...
.- - -
"

4.8
.

---
Hepl.ad\lorcpoxidc
2/71
2/71
13 ·62 38 ...
- - 0.3 212
Methoxychlor 7m
IS·140 78 S·
_.
212
- - _. .-.
TO~llIphcnc 0/11
13 - 210000
-
35,874
... -
- -
-'- ...
...
... --.
...
".
;
iO~'IU .nd l"tJran I [nrlJ~\
Di<:lxins and Fur.;)n~ TEQ"'''' 37137 1.3·82 16 .-. _. .•. ... 3.6 24137
:

i
2,3,7,8·TCDD 36139 2.47 - 13S0 127 -. - ... ... ...
I.2,3,7.8·P,COO
1,2,3,4,7,8·H.'CDD
17/39
IBI39
0,9S3 • %.2
0,965·40.5
93
8.•
-
...
_.
...
...
-
.-
...
...
...
... I
l,2,3,7,8,9·fhCDD 22139 0.451·75.2 14 _. _. '" -
.

...
_- ...
1,2,3,6,7,8-H.'CDD ...
00.

l, 2,3,4,6, 7 ,K.HpeDD
25139
37139
0.773 ·In
10.5 ·139ll
25
...
00-

... -
...
... ... I .. '
279 ... ._- ...
OCDD
1'0,.1 TCDD
38139 90.1·12370 2,738 - - ... ... .- I _ ..

To'al PeCDD
36/39 2.47·1520 IS3 -
...
- .- ... ... I
_.
..-
26139 9.61·304 54 - ... -.. ... !'
Toll' f{,COD 35/39 5,09· llGO 176 ... ... ". ... --- i -_.
T o,alllpCDD
2,3,7,8-TCDF
37/39 24.4·4IS0 706 - - --. ... ... I --.
J.2.3,7,8,PeCDF
31139 0.906, 491 36 - -
_. ... -- ... ,
'"
30139 0.993·31 S 35 - ... ... - .. :
2,3,4,7.8,PeCDF 30139 1.53·421 52 --. ... _. ..- ...
---
...
1,2,3.4.7,8·!1xCOF 36139 S.99· H2O 356 -. ... ... .-- .-.
...
00-

1,2.3.7.8,9'fhCDF 22/39 0.319'142 16 ... .- ... ... ..-


J ,2,J,6,7,8-H!<CDF 34139 2.87·1020 98 ... ... --. ... _.- ...
2.3,4,6,7,8·H.,CDF 30139 0.862·352 34 .-. ..- ... -- _ .. ...
1 2,3,',67 8·H ,CDf n'39 13.3 • 18Z1l 885 ... ... ._ . ... ... ...

Page 4 of?
EN \ l RON

TIERRA-B-014946
T.bl~ 2
Summary ofCh"mi-cah. Dl't-ec:ted In Sedi",~l1t from 0 loO.S n l)oe~o", MucJlioe
Stud)' Aru 7, Jct3i'f)" City, New Jer:!'eY

Range
Deh:t"tlon Avpr.g~ De-tKh·(j1 ERL(NJDEPI ERL E~cetdan(e NOAAAET
Chemicals of EAA1(NJDEPI ERM E:needllnc~ NOAA
Fr-rque-ncy Corll;~ntrallon 1'IOAA) Frequency EHf('d;lOn~
Dett'ctiun NOAA) Ff('q\.i~IlCY AET
Frpqll('n-C'~'

1,2,3,4,7,1.9-HpCDF 26139 0.n7 ·165 27 - _.- -- - ..- ---


OCDF 38/39 38.1·25560 1,974 '-
-
-- .- --. --- _ ..
To'" TCDF 37/39 4.1- 11700 1,167
- - '-- --- ...
To',1 P.CDF
To,.llbCDF
31/39
37/;9
2.46 ·9180
4.96·8780
818
W
'"
_ ..
...
---
-
--.
--... -..
---
-_.
To,,1 HpCDF 38/)9 18.3 - 22110 1,625 _ ..
-.. ---
_ ..
--- --- ---
rPnlvrn.IGrlnued Bihhf'tJvl, (nUrD)

Copl.n.r
PCB-77
PCB, TEQ"" 37/l7 6.9·1110 IS< 22,700 ... 180,000 ... 130,000 ---
35/39 635·28700 l,002 ... - ... --
_. .- ---
PCB-II 29139 5.22 - 2150 310 - _.- - --- _.
PCB-IDS 36139 14J·528oo 1,041 - - _.- - --
PCB-I06/lll
PCB. I 14
31139 62,9· B3000 18,910 - - --- _ .. _.---
30139 6.69 - 3640 110 '" -- - .- .-- ...
PCB·123
PCB·IIG
30139 7.18·3150 411 - -- _.- -- ... -
PCB-ISo
22139 10,2 - 512 156 - - _.
'- ---
34/39 37.1 ·23800 1,412 - -- ... ... .-- _.-
PCB·IS7 29/39 9.24 -1060 4iO .- ..- - ..- ... ---
PCB-167 33/39 1S.8 • 3590 781 --- -. - -- ... _ ..
PCB-169 7/39 9.06 - 97,3 27 - ... .-- --- ..- ...
_.-- _._.
Pell·PO
PCB·Uo
35/39
36/39
91.5 -18200
242·42700
4,106
--
--. -
...
--- ---
PCB-lX9 26/39 10,2 - 678
10,391
2IK _. ... ... ---
---
_ ..
---
..-
TOlal monoCB 2&/36 J2,J. iSIO 1,722 ... ... ... .- -- --.
Total diCB -_. -
Tolal triCB
21/36
28136
174-187000 20.165
... .-
- ... --... ---
TOial r.erraCB
212 - 1160000 98,S19
_. -- .- ...
To"l penlaCE
28/36 760 - 2030000 l81,026 - ... .-- ... ...
28)36 321·1050000 126,136 "0
--- -- ... ---.. --
Total h ... CB 28)36 126· 411000 74,727 _ .. _.
0--
--- _
...
To"l hoplaell 27/36 263- 163000 37,524 -. - - ---
TOT.!l oc!.lCB 27/36 104·46900 13.nO ... - -_.
.0.
_ .. ---
...
Total non.CB
Total del.:.CB
27136 97.1 - 53000 6,408 --
...
- --- --- -..
27/36 592·42000 4 l42
--. 0.-

Pagel of7
EN \' l R ON

TIERRA-B-014947
Table 2
Summary QrChemlc:::.ls Ddectnl in: ~dilnen{ from 0 lolLS rt Below !\1udline
Stud)' Aru 7; Jer!€!y City, N~w Je.r5oeY

[)e1.cUen
Range
Chemful5 A¥''t'r-agt! Drtrt'tl:'d ERL(NJDEPI ERL [:[ceedante ERM(NJDEPI ERM Excc-edan(f' NOAA AET
of NOAA
Fr~qufnC"y C'On.centration NOAA) . Frrqut!"ncy NOAA) EHl!pd,ul ....
e
Detectlun Frt'qu~'1C-Y AET
Frequ-fo-ry

.'oclor ""Ik.'

_-.
Arodor-l0 16 0150 - -- ... . .- ... --. ...
Aroclor·1221 0150 -- ... .- --. ... _.
Aroclor·1232
Aro<lor·1242
0150 -
_. •..
...
...
...
- - ... ...
---
...
0150
.- - _. ... ...
Aro<l or· 1248 25150 59·720 ... ... ... ...
Arocl~r·1254 12150 48·420
215
232 .- ... _. _.
---
..-
...
...
Arocl.r·1260 15/50 67 - 370 174 ._- ... .- ... ... -.
"~I·br~ .. I".I.d Dlnh •• ol "[he" 'n.I.'
BDE·l Im7 27.8 • 693 203 -
_. _. -
BOE-2 11137 17.S·255 S7 .- _.--- ... -_ ..
-- ...
BDE·) 23131 15.6· 812 2S0 - - -
_. _. .- _.
BOE-7 )4137 ),77·1160 233 - - .- .- ...
BOE-IO 12137 1.03 '14.8 5.4 - _.- - ... .-
BOE·I] 25m 0.646 -160 37
- - .- ...
'--
-.
BOE-IS
BOE·17
36/37
33/37
3.4)·2580
4.42·1190
306
297
_.- -
.-
-
~ -
...
...
...
...
BOE·2S 5/37 ... -
---
BOE·28 34137
3.34 - 45.2
3.39·301
IJ
19 _. .-
-
- _.- ...
...
...
BDE·JS 13137 1.21· 107 39 - i - ... _._ . ...
--
...
BOE·H
BOE·49
37137 90.1 ·6460 869 .- - ... --. ...
34137 5.S • 2540 568 - - ..• ... ..-
BOE·66
BOE·75
24137
23137
4.11· 234
1.01· 389
66
117
-
-
.-
.-
.-
...
...
_. ...
...
---
---
...
BOE·n 5137 0.635·8.96 2.S -. - .- .- ... _.-
BOE·~5
BOE·99
24/37 6.44· 189 )7
- -- .- .- ... ...
BDE·IOO
37137 94.8 ·6550 842 - - .- '- ..- ...
37137 2J.I -1480 203 - - .- '" ... ..-
BOE·116 5/37 7.1I ·296 13 - .- .- .- _ ..
.-.
BOE·126 5137 2.26 - 9.97
- - - _ ..
BDE-D8 7/37 S.49·78.9
4.2
34 -- .- -
-
.- ...
._.
...
llDE·ljJ 28/37 [7.3 - 1120 262 - _.- .- .- -- --.
BDE-1S4
BDE·lI5
28137 11.3·936 206 -- _. _.- .- ... ...
14137 3.81·107 44 - _. .- ... ---
BDE·l56 5137 3.74 ·42.9 13 - - .- ... .-.
BOE-li[ 5,37 7.36· 51 21 -- ... ... '"

Pas·60f1

TIERRA-B-014948
Tabid
Summary of Chemicals Detee-led tn Sediment from 0 (0 0.5 n Bi:low MudUne
Study Area 7; Jersey City, New JerleY

Range
DetE."dioll A veta@e Df'leded ERL(NJDEP/ NOAAAET
Chemical' or ERL EuredarlCof ERM(NJOEP/ ERM ElCt~anc-(' NOAA
FU'qufncy COl1ci;"ntrlHon NOAA) Frequeru;y E:t:e~!!danc:t"
D~tectlon NOAA) Frt'qlll1ncy AET
Fr-cqbtflCY

BOE-183
BOE-197
30/37
26137
18.3 - 4940
12.5 - 2780
640
574
-
--'- -
---
-
-_. -- ---
---
---
---
OOE-203
OOE-207
25/37 11.l-15~0 536
---- -
---- - --- ---
60£·209
29m
35/37
7004.5740
2070 - 291000
1,793
65,442
- --
-- ----- ---
TOI,d Mono~DDE 24/31
---- - -
-- --
To.al Di·BDE
19.2 - J650 437
_. - -- ---
36/37 3,43 - 2830 828
-- - -- ---
T 01.1 T ri·BOE 34/37 4.42·3360 914 -- - _..- - --- ---
TOlal Tetra-BDE
Toeal Pc:nt.l·BDE
31/31
37/37
100·11500 2,398 ---
_. - _.- -- ---
Tot.IIl".-60E
118 ·8520 1.120
_. - - -- -- --
TOlal Bcpta-BDE
28137 19,6 - 2S20 70S
- -- -
_. -- .-
30/37 18.3 - 6450 922 --- - ._-
--
_.--
To .. 1 (kla-BDE -"

To"'l Nona-ODE
27/37
29/37
14,5 -7080
70,4 - InDO
1.852
3SSJ
-
_. - --- -.- '-
- '- I .-
Sources:
New Jeney Dcpanmcnt ofEIll,-irQM1cnlal Prorecllon (NJDEP). 1998. GuiWincc fOT Sediment QWiljty Evaluations. No ...ember.
Buchman. M.F., 1999, NOAA Sc~ning Quick Refete:nc-c Tables, NOAA IIllZ.MAT Report 99~11 Scaule WA, COUlaJ Profeclion
;a.,d RUCor:iIJonDivi.sion, National ate,amic and Almospheric Administration, 12 page"

NOlot1:

AlI..Inalyscs are based on validilled dar, frorn Ihe Ottober 2003 lhro-ugh J.anua.ry 2004 field sampling e'toi~rs illDdfront the:: 2002 Rcmr::cli.aI Invc- .. tigation Rcp-or1 prepared by Te-ln. Tec::h.
Heuv:dcnl chromium analys¢., were f;Qnduf;tcd by two an,IYlit,l1 melhods (7196A and 7199) following extraction by two method" (N"IDEP and EPA).
ElU. • Elf"" Range low
ERM ... Effe(;tJ Range Medium.
NIDEP'" New JCf!lc)' Dep.arrmenl ofEnvironmcntaJ Proleclinn
NOAA = N.ation.:d OcurUc .Ind Almospheric Adrninhllration.
AfT - Apparenl Eff-t.;ts TIu-C'shold.
EPA -= UhJ.lcd StalC5 EnvironmenlaT Prolection Ag=-n-cy.
mglkg .. Miligram!l: per kilogram.
uglkg ~{i<:ro&ram~ pet kLiogr.ilm.
1:t

pgfg • pi<:ograR1' p« gram.


-- :: Value nOl available for d'lill chcrn.JcilI1.
.. ""M~ri"l;:fE:nuarinc scwmenT 't;.rt:cning a;nleria not .available, the frc:!lhwalC'f 1cdimcrn screening critcr\iJ was U$ed.
"'"TEQ = To:\.icity F'/,!lI;\·Jlency Quotienl; ITQ calculalions do nol in\:ludc d,til from rhe 2002 Rcmc::dI31Invesrig.:.Tiol1 Report,

PatwlI~
Page 7 on
f:NI'J fH)N

TIERRA-B-014949
Tablo 3
Summ • ...,. ofChemlt'ah Ddrded in Scdlmtnt from ch.e Rrrrrence Are&!.
Su'ldyAr~~ 7; Jenry City. Nnv Jenr)'

Ron::e AYerage ERL ERL ERM ERM


Chcmlcil:h Dorf~tlon NOAAAET
of Ootocled (NJDEPI NOAA
FrtqLumc," Ex«rd""('f tNJDEPI Exceedanoee E H''l'pd 8 n t"e
DneC"titm Con("enfrl'ltlon NOAA) Fh!quen,?, NOM)
AET
Frt-que-ncJ Fre-qut"nc'y

M~!ah (mp/Lp':
Aluminum
AntLmony
6/6
0/6 _.
8500·14600 10.642
.-
...
.-
.-
.-
.- '-
...
... ...
~enic 6/6
'"
9.3 ...
8·24.8 14 8.2 5/6 70 0/6
Barium 35 016
6/6 98.6·127 113 ..- .- .- .- 48 616
Beryllium
Cadmiu'ITI
6/6
5/6
062·0.93 0.7 .- .- _ .. .- ... ---
0.27· 4.5 2.0 1.2 3/5 9.6
I 015 3 115
Calcium
Chromium
6/6
616
2680·6930
122·227
4,732 -- .- .- --- ... _ ..
167 81 6/6 370 016 62
Hc:<ava!cnl Chromium NJDEP 71%A 0/6 ... .- .- .
_. ... ... ...
6/6
H«a ..alcnl Cnmmium NJDEP7199 4/6 1.09-11 4.6 -.. ... ... ... ...
.--
...
...
Hexa ... lenl Chromium EPA 7196A
Hex.valent Chromium EPA 7199
0/6
6/6 0.903·5.9
.--
2.5
...
... --
.-
.-
...
---
.--
...
...
.-.
...
Cob.lt 6/6 7.6· 11.3 9.2 .- ... ... ... 10 216
Copper 6/6 90.1 - 176 132 34 6/6 270
Iron
Lead
6/6
6/6
20600·31700
99.6·225
24,667
158
.-
47
.- .-
0/6
0/6
390
.-
016
..-
6/6 218 1/6 400 0/6
Magnesium 6/6 4700.8\00 6,050 .- ... _ .. .- ... ...
Manganese 6/6 263·516 356 -_. -- .- .- 260 6/6
Mercury 6/6 1.2·5.5 2.7 0.£5 6/6 0.71 6/6 0.41
Nickel 616
6/6 22.7·44.2 33 21 6/6 52 0/6
Potas;sium 6/6
_.
1540·2340 1,843 ... ... I
I ..- --
liU
. - 0/6
...
Selenium 0/6 .- ... '- .- .- 1
Silver .1/6 0.6.1·33 2.3 1 4/5 3.7 0/5 3.1
'--
S"dium
nallium
6/6
0/6
4040·10800
...
6.917
.- .-
.-
.-
...
._-
...
...
...
"-
2/5
...
... --.
... .-
V.:nadium 6/6 22.9· 38.7
Zine
29 -.- ... 57 0/6
6/6 200·4fi6 333 ISO 6/6 410 3/6 410 316
n_$I;'lcti .. " 'u"Jk"':

l1JlL
Dibulyllin
Monobutyltin
4/6
.- -- ... --. ...
Tetr.butyllin
0/6
0/6
.- .- .- _ .. ...
... ... -_.
I -.-
'"
Tribut)'hin 4/6 .- --- ... ._- ...

Pag-e I of?
EN\lRON

TIERRA-B-014950

Tabl.3
Summary oFChemicaIs Dete('ted In ~dirrlfnt from «hot Rder~n('e Are-a
Study Ar~1l7~Jenty C'ry, New Jeru'y

Rang. Avrn.Ef: ERL ERL


Che-mwals Detection ERM ERM NOAA AET
of Deucted (NJDEP/ Ex-ce-rdancf- NOM
Frequency (NJDEP/ Ex('eedliln('~ Ex{"('edar1("('
Dtu·(tjon Con("entr..1.iOll NOAA) Frcqutn(-y AET
NOAA) Jo-~.qucn("y Frequent-,.

1S;;;i: •• 1.'11.;:;: a-I, r·":·ound. 'uo/l,o .


1.2.4- T richlorobcnz-cnc
1,2·Dichlorobcnzellc
4/6 22- 30 38 .- .- -- -- 4.8 4/4
l)-Dichlnrobel\Zene
3/6 19 -46 31 .-
.- --..- -- -.- 13 }I)

1,4·Dichlorobenz~nc
2,4.5- Trichlorophcnol
3/6
316
19-35
33·100
_.
26
75 .- -_.
.-
---
---- ..-
110
---
0/5
-.
.-
_.-
.- ..- _.- ..- J
0/5
---
2~4~(j.Tricl1lorophenol 016 .- _. -_. I
---- ...
2,4-0iehlorophonol 01. -- ... ... .- --.-
6
...
2,4-Dimelhylphenol 015 ... ... -- 5
2r4~Di",itrophcI1Qt
----. -.. .- .- IS ---
0/6 .- .- .- ..- ...
2,4-Di.il(otoluene
2.6 ...Di:nilr-olol1.u::nc
015
0/. _. .-
-- ---- ._- ... ._. ---
... --.

2-Chlorophenol _. --
...
...
-- --- --- ...
2·Methylphenol
0/5
0/5 _. --
... -- --
_ ..
---
_ ..
8 .-
2.Nilro",nili.nc 0/. _. -- ---
.-
--- --. ...
8 --.
2·Nilrophenol ... .- ... .-- --.
0/.
.- .- ... - ..
3,3'· Diehl OT'Obcnzidinc
3-NLlro8nil~c
0/. -.
-.
.- .- .- _ .. !
.-
'"

--- --.
4,6- Di n;I,o-2-methyl pheno I
0/6
-.
-- -- ... -- ... ... --.
0/.
...
.- -- -- -- -- .-
4-Ch loro-3 .mclhylphcnol 0/6
- -- .- .- --- .-
._-
...
4--Chlorotlnilinl:
4-Chlorophcnyl pbonyl olber
4/6
016
_.
57 - 280 127
...
--
.- .-
--
._- .- .- --.
.-
.. -.. ... ...
4·Methylphcnol
4-Nitroanilinc
616 52- 1I0
...
74
.--
---
...
.- _
... 100 1/6
015
..-
.- .- ... ... ...
4·Nitrophenol
hi. (2 -Ch Iorocl h oxy )mel h 'no
0/6
_. ... -- -_. "- ... ._- ---
._---. ...
0/6
his (2 -Ck Ioroclh yl loth., ... '- .- ... --- ...
0/6
-- ... ... --- ._- - ..
bi. (2·Ch loroi,opropy I)elher 0/6 ... .- .- ...
bi, (2· Elh ylhexyl Jphth .181c 6/. --.... --- '" --- --.
Bulylbenzyl phlh811te 015
250·
_. 5800 2.130 .--
-..
...
.-
. - -.. - ..
Carbazole 616
'"
.-
,
.- ... -- 53
S8·390
--
'--

194
Dibcnzo[unn
... --- -..
.---
5/. 42·2100 709 --
.- -"-..
Diethyl phlhll.te 0/5 --- ... --
110 216
Dimethyl phlh81lte 016 _. --. ... I
... _ .. 6 --
Oi·n-'utyl
Di-n-octvl
phlb81a1e
ph/h.llle
0/. ... -- .-
I

-..
--
-- -- •
53
._-
---
0/. o..
--- --- .- --. 51 ._.

P8se 2 of?

TIERRA-B-014951
Tobl.3
Summary ofChfmie-ah D'te('1edIh S4!-d'ment f:rom (tit Rc:frnmoC'l' Ar-t1U
Study A... 7; J .... y CIl], N... J .... ;,.

IUlng. Average ERL

I
D-t'teetiDn ERL ERM ERM NOAA AET
Chp-mlC"ot!l- NOAA
Fl"'t'quc:ncy
of D....... d (NJDEPf E;I;Ce'l!:dllnco£ (NJDEPI Ex("udancf' Ex("c't'danc-('
DrtediQn ConC'enl:nttlon NOAA) Frequency AET
NOAA) Fr-tquen"y F"'Clut'f\(')"
!
HC;\.oCh~orobenz.c[\e 0/6 --
...
.- ... -- --. --._- 6 ..-
Hcxllch lorobul8dienc 0/6 -- ..- ..- -- ---
Hexach lorocyc lopcntad icnc: 0/6 --- -- ... -- '- _ ..
J.)
- .. ._-
Hexlllchloroethane
lsophorone
0/6
0/6 _.-
.. .-
.-
-.. --.
--
...
.-
.-
...
7~
._ .
---
Nitrobenzene 0/. _. .-
'"

... .- ---
... ..-
N·N itro,o~di-t1·propylam In c
N ..Nilmsodi phc:nyllmi no(!
0/6
0/6
--... --
_ ..
... -- -- .-
21
.-
"-

...
--- '- -- .-- _.-
Pent;l'lch!(jrophc:noJ 0/6 -- -- .- -- -.. - ..
28
n ...
1'1101101 Of6
-- - -- -- .- -- 130 '"
Pc!"t>"rlk .. io".:i'io: P·-dfv("Yrbons
"' 'u!"/k
2~Cnlorontphlh.!cnc 0/6 _. .- ..- .-
2-Melhylnophthol.n,
Acen8lphlhcne
616 '2·3100 819 10 '/6
--
610
--
216
.•. ...
6/6 81·12000 04 5/6
3,035 i6 6/6 500
Ae.nophthylene 6/6 216 DO 416
150·2400 9S0 44 6/.
Anthrl'~e-ne 640 216 71 ./6
616 260·7900 2.883 85
Benzo(R)ailthracenc 6/6 1,100 216 280
6/6 590·12000 4,4~8 SI6
261 6/6 1,600 3/6
Ben<o(')pyren. 6/6 660 - 11000 960 41(j
4,081 430 6/. 1,600 4/6
..-
Benzo(b)fluonmlhcn. 6/6 i,iOO 4/6
Benzo(8,h,i)p.rylen. 6/6
660 ·7900
400·5300
3,123 -- .- .- i,800 2/6
Bonzo(k)f)uomnlh.ne 6/6
2,002 170- 6/6 .- .- 610 416
Chl] •• n. 6/6
7.0·9300
870· 13000
3,593
5,028
240- 6/6 .- .- 1,800 2/6
384 6f6 2,800 216
Dibc=n:zo( R,h)anthrDCC lie 6/6 130 - 1900 950 S/6
713 63 4/6 260
Auonlntht:rn::: 6/6 2/6 230 2/6
1800·2'000 9,917 600 616
Fluorene 5,100 2f6 i,300 6/6
6/6 7~ • 2000 674 19
lJ\deno(I,2,3-edJpyr.ne 6/6 S40 2/6 120
6/6 4/6
Naphthah:ne 6/.
340·4900
95·14000
1,863
3,814
200-
160
6/6
416 ,
--
2,100
--
216
600 4/6
Phenanthn:ne 6/6 690.9\00 , 230 4/6
2,918 240 616 I,SOO
Pyren. 6/6 2/6 660 6/6
i4oo·200oo 8,000 665 6/6
I
2,.00 4/6 2,400 4/6

4,4'·DDD
4,4'·DDI:
0/6
i/6 20·20
- .- 2 .- 20 -_. 16 -_.
20 2.2 IIi 27 0/1
4,4'·DDT 0/6 -. --.- I -- 1 .-
9 ...
._-
Aldrin 0/6 ... 2- .- ... ...
12
olph.-BKe 5/6 17 -40 27 6- i ... ...
9.5
...
--.
~/~
...

P'AMOflS
Poge 3 of1
ENVIRON

TIERRA-B-014952
T.bl.3
Summary ofChel11iub Del~('ted In Swimel1t from Ihe Refert'nC't Al"'ru
Slud) Ar'rlil7; Jeruy Ch".. Ne-wJt'rsorJ

Range Avera.ee ERL ERL ERM ER,',f


Ch~mkal! Detec-tio" NOAA AET
of Dc:leded (NJDEPI Erceedlllnce NOAA
FNqurh('y (NJDErl EXC'tcdancr E'X'('ct'dliln('f'
Detection ConC'entnlllQI1 NOM) F... qumcy AET
NOAA) F... qu,ncy i FrequE'nt)'

bc.. ·BHC _. i
0/6 ... 5" --- .- ... ._ . ---
Chl",d.n.
dell.·BHC
0/6
0/6
_.
-. -.-
...
O.~
.-
. 6 ...
I
28 ...
Dieldrin 0/6 _. .- 0-02
.-
.-
.-
8
--
.-
,
... --.
...
Endo-sulra:n I _. .- 19
0/6
_. - .- -.. ... ...
Endos.lran II
Endo5ulfa" !u~f'tl::
End,;n
0/6
0/6 -.
_._.
...
.- -
.-
.-
'-
'-
.-
.-
...
...
...
._ .
_.-
...
0/6 .- 3' ... ... .-
&loon aldehyde
f..ndrin ketone:
0/6 .- ... .-
---
-_. .- ...
...
1/6 38·38 38 ... ... .- ...
'"
_ ..
gamm.-BHC (Lindane) 0/6 ..- .- 3' .- ...
---
'-
Heptachlor 016 -.
_. --
.-
... - ... ...
48
03
'"
._.
HeptJIohlor epoxide
MelllOxyohlor
016
1/6
S" .- ... ... ._ . ...
_.
26·26 26 -- ... .- --.- ... ...
To•• phene 0/6 .- .- - -- .- ...
DhH:I~·Pinel F'ul-.ii:i (poe;J~)
Dioxins snd FUl'"af1:!I TEQ'"
2,J,7,8·TCDD
6/6
5/6
66 - 3769
1.31 ·207
1,72S
%
--
...
...
.-
...
...
'" 3,6 6/6
. ... ._-
1,2,3.7.8-PeCDD
1,Z,3.4.7,S·lhCDD
S/5
6/6
0.561 - 7,04 3.6 .-
...
.-
...
_ ..
"
.- _.. ...
1,2,3.7.8,9-~L,C"DD
0.S·5,11 3_1
-- ... ... ..-
6/5 0.98· 24,1 9.1 ...
1,Z,3,6.7,8·HxCDD 6/6 ...
"-

...
--- .- --- ...
1,2,3,4,6,7,8· HpC"DD
1.01·51.9 17 ... ... ... _.-
6/6 20.3.702 299 ... ... ... _ .. ...
OCDD 616 793·6140 ... '"

T"",ITCDD
3,284 '" --- ... ... --.
To,.1 PeCDD
6/6
6/6
12.3·249
6.77'40.4
129
22
--
...
-.- ...
...
-.- ..- ...
J"lal H,CDD ... .- ... -..
JolalHpCDD
515
6/6
24,S·488 157
.-
-- ...
... '- ... ...
2,3,7,8·TCDF
53.9·1450 542 ...
... .- ._- ...
1.2,3.7,8-PeCDF
516
616
3.23·29,2
2.48·23
14 .-
.-
.- ... ... ...
2.3,4.7.8·PoCDF 616 2.44·47.9
II
.-
.-
...
...
...
.- .- ._-
1,2),4,7,8·HxCDF 6/6 535·219
21
... ... .- ,-- ...
98 ... ..- ... ...
1,2),7,8,9·HxCDF 6/6 0748·11,2 4.6 ... .- -- .- ... ...
1,2,3,6,7,8·HxCDF
2,3,4,6,7,8·H,CDF
6/6 3.39· 146 68 .-
...
.- ... .- ._- ...
J 2.3 4.6 78-HpCDr
6/6 1.57·24.6 12 ... ... ... ... - ..
6/6 235·1570 700 .- .- i
'" ... --- ...

Page. 4 of7
tN'IRON

TIERRA-B-014953
T.bld
Slimmal)' OrChf"ml-£"al5 Detuted if1 Sedimenc from thr Rl!'fnrnc~ Aroeu
Studr Are. 7: J'''''r Cll)', N.w J..... r

DetpC'tion
RAng' Avc:ntge ERL ERL ERM ERM
C"rn1-l('a.I~ NOAA Af.T
Frequen-cy
or Oe£f('t,d (NJDEP/ EXl"eedllniC"t! (NJDEP/ Exce'rd9lnc:-t
NOAA
Exr"rdBioce
Dele-crion ConCf'nfratJon NOAA) Frl:quent."y AET
NOAA) Frrquro<'}' Fl"cqutnc-y

.~~
[II
1.2,3.4.7.8,9·HpCDF 6/6 l.OS - 25.3 11 ._- .- -- -- .
OCDF
Total TCDF
6/6 32 - 1700 694 -- -- -.. -- --- ---
Tot.1 P,CDF
6/6 50.9-1790 809 -- -- ._- .-
Tot.1 H,CDF
6/6
6/6
39,3·1660
34,8 - 1660
7H
766
--
--
'" --- .--
Totsl HpCDF 6/6 347-1840 83;
--- --- ---
--- --- -- --
PciychiorjnSded Binhen'l'h: ([)2:/~~
Coplanar PCB!l TEQu
PCB·77
6/6 20·645 238 22,700 -- 180,000 .-- DO,OOO ---
PCB-81
6/6 78 ·6410 2.888 -- -- .- -- --- ---
616 9.71 ·366 203 -- -- -- ... --- _ ..
PCB·IOS 616 134·20300 7,024 --- -- -- ... --- -.-
PCB·l06/liB
PCB·114
6/6
616
398·51500
9.71 • 1330
18,171
447
.--
-- ---- .-
-_. ---
...
.-- --.
--- --
PCB-I23
PCB·126
616
5/6
9.71 - 792
9,71 ·248
272 ---
.-
---- .--
.-
-- --- ---
PCB-I 56
110 -- --- ---
PCB-IS?
6/6 38.1 - 6550 2,132 - -- _.- --- I ... ---
6/6 10.6·1080 412 -- .- -- .- --- .--
PCB-167 6/6 16_5·2700 904 .- - -..- --- --- ---
PCB-I69
PCB-I 70
416
6/6
8.79- 59,6
956·31900
29
8,207
--
--
--
.- --.
-- .-- -..
PCB-ISO 6/6 277·81900 ... --- ..-
-- -- ---
21.058
-- --- ---
PCB-189
Total monoCB
6/6
...
97.1- 1220
--
345
--
---
-- --
.-
--- '- --. --
Tot.1 diCB -- --. -- ---
--- -- --. ---
-- - .. -.. --.
Tol.llriCB ---
-_.
--
--
---- .-
'"

-- .- --- --- ---


TotallctnCH
--. --- -- -- --- _ .. -_.
Tot.1 po.laCB
.--
... -- --- -- --- ... ... _ ..
I

_.-- -- ...
Tol.1 hexaCB
TOllil heptaCB -- -.. ---
-- ... -- .- --- I

TolliloolaCB ... _. -- --
...
.- -- --. -- ---
--. --. -.. --- -- ...
Tol.1 """.CB
_.--- ...
--. - .. _ ... --- ---
To.. 1doc.CS --- -- -- --- --. --. _ ..

Pase 1 of1

TIERRA-B-014954
T.ble 3
SummAry of Chemical", Dr-Ire-trod in Sediment rrom Ihf' Rrfn~nc-e AruL5
Study Arts 7; Jer.s!'y City, New Jtrse,y

Rang~ Avtrage ERL ERL ERN!


Chf"mft'lIl!'1 Drt~c-tion ERM
F...quency
.r Dc.i~("fd (NJDU'{ Ex('etdanct (NJDEPI E:u:e-c-d.n{"t' ~"OMm
AET EX('I!('dnon
Dftection Cont't'nt .... tinll NOAA) F....quenl'y NOAA) Frc:qIH:"(')' Frequ~,,("y
'~dor (m.I1<.,
l\roolor-1016 -- --- -.- --. --..- .- ._- ._-
Amclor-1221 --- ..- ._- --- .- _ .. ..-
Aroclor·I232 -_. -- ... _ ..
Amclor·1242 -.. -_.
---
_ .. -- ...
... ... ...
l\roclor-1248 -.- _. ---
--
---
-'-
.- -.-
..-
_ ..
.-.
._- ~ _ ..
I\roclor-1254
-- _.-
_. .- ._- ._- ... ... --- ..
I\roclor-1260 - -- _.- '-- -- ..- --- ..-
, I

Puhb.ruminatrd Dil'thenvl t.fiun. (n9/o;p)


BDE·I _ ..
BDE-2
4/6 99.1-208 142 --
_.-
--. ---_ . .-- ._-
BDE·3
4/6
4/6
45.2 - 450
1%-420
181
329 ---
--.- .-
.- .-
-- -'- I
BDE·? 5/6 .- -- ..- I.
i
BDE-IO 1/6
35.5 - 552
3.1· J.I
JIB
.-
--
... ---._- '" --. ..- :
BOE.13 4/6
3,1
.-
-- ... --
I
BOE-IS
4:1.8. 159 90 -- .- -- -_. '--
BOE·I?
6/6 8.4 - 1050 405 .- -- .-
.-
._- ... ._-
SOE-25
SOE·28
6/6
0/6
5/6
20.4 - 1250
_.
2l.5 • S:13
4J8
._.
.-
--
.-
--
--.- .- --
--
_..
...
._-
-.. I
BOE·35
242 .- -- . _.- --- I
"

80E·4?
4/6
6/6
43.1-153
201-?09O
99
2,413
.-
--
--
.-
.- --
._-
..- --- "

BOE-49 -- -- ._-
6/6 42.3 - 3800 1,293 .- - .- -- ---
BOE-66 3/6 71.9 - 300 188 ._- -- .- ---. _ .. "- j

_ ..
SOB-n ._.
316
_.
3.71 - 383 13S .- .- - .. ...
BOE·??
BOE·85
0/6 .- .- .- -- -.. ... -.-
BOE-99
4/6
6/6
29.8 - 209
230·7240
106 ._-
--
--.- --.- ._- _ ..
'"

BOE-IOO
2,449
.- I -- . ... ...
BOE-116
6/6 59.7 - 1880 636
--
--.-- .- -- ... -.-
BDE·I26
1/6
0/6 _.
76.8 - 76.8 71
.- - ---- -- .- .-
80E-138 3/6 80.2 - 104 9) -.-
.-
.- I '-
j .-
...
.--.. ..-
BOE·153 -,-
BDE·154
4/6 378·1260 802 -- .- I
.- -- --- ._-
BOE·155
5/6
4/6
54.4·1120 545 --
--
-- .- '.- ._- .-.
BOE·Is6 0/6 _.
40.6 - 122 70
.- ---
--
--
.-.
...
-- -_.
._-
.-
_ ..
BDE.IBI 0/6 --- "-
-- -- .-
"-

-- ... '"

r~n:on~
Pas" 6 of?
ENVIRON

TIERRA-B-014955
T.bl.3
Summary of Chemic-. Is Ooelected In Srdlmrnl rrunl .he Rerertl1("f: AreM
Stud,. Are. 7; .hney Clt)', New Je1"!P]

De-lto ....tion
!Un:. Ave-rag€! ERL ERL ERM ERlVI
CI1~mk..l~ NOAA AET
of D-elnted {NJOErl EX"'f'~dRm·-t (NJnEr/ NOAA
Frt"quf'nc)' Exreotdlalnce EXCl"f'dllMce
Drlrl'tion Ccn~("ntnUhHi NOAA) FM""'Ilf~r1CY NOAA) Frequent)'
AET
Froequ{'~'I"J

80E·] g) 5/6 j9, I .4930 1,918 .- ... ..- ..- ... ---
BOE-I97 4/6 763· 4S80 2,503 ._- ... .- -_. _ .. ...
BOE·2m 4/6 755-4170 ...
2,166 --- '- ... ... ...
BOE·207
BOE·209
4/6
616
3760·23600
3jgO·470000
12,333 .-
.-
.- _.- -_. --- ...
TQ1RI MQno.BDE
226,225 ...
'- _ .. ._- ...
TOlAlDi·BDE
4/6
6/6
340· 1000
8.4 - 2460
651 -.-
..-
-- .- _.- ._. ..-
1,079 .- .- --- ... ...
ToI,1 Tri-BDE 616 33,9·3220 1,517 -- -_. .- -- . -.. ...
To'al Telra-8DE 6/6 24) • 13600 6,537 ..- ... ... ... ._- ...
Total Penla·BDE
TOl.l Hex.-BDE
6/6
5/6
290 - 9110 3,359 --.
-_.
-- ._- --. -_. ._-
l4.4·3550 2,081 --- -- _.- ..- ...
Total Hopta·BOE
T"'aIOeI.-BDE
516 59.1 .8230 3,176 ._.
.•. ----- .- .-
..
._- - ..
TOI&I NoM-BOE
416
4/6
2840· 1gSOO
7360·41800
9.275
22115 -_. .- --... _
..-
...
...
..-
---
Sources:

N~w Jl:n.ey DepArtment of Environment aT Protection (NJDEP). 1998. Guidance fOl" Sediment QUftlily EvalUlI.lioo:'l. NQvember
Buohman, M,P" 1999, NOAA So~e"i"S QUick Referenoe Tabl"", NOAA HAZMAT Report 99-1, ScBttie WA, Co.,t>] Proleolion
end Rc:~tornlion Division. NfltiOfl.\l1Occ:at1ic and Atmospheric Administration, 12 page!!.

NOle,'
All Bnalys.e$ ore: based On va!idaled data from the: Ol;;lobcr 2003 through J8nllftry 2004 field sampling evenU and frum the 2002 RemediAl II:lVc:sligalion RC'port prepared by Tetra Tech,
Hcx.elvalcllt chromium 8n81)'~es were conducted by two Bnslytieal rtIc:LhoW (7196A and 7199) following elC.lraction by two methods: (N'JDEP Rnd EPA).
ERL Effeots Ranse Low.
=
ERM = Effecta Range Mediulll
NJDEP", New Jcney Dr;portmenl ofEnvirol'1mcnlal Protection.
NOAA = NationAl O:eanic and Atmospheric AdmillistratlQn
AET ~ Apparent Elfeols Thre.hold.
EPA • United Stat=s EnvironmentA~ Protection Agency.
mglks = Miligram, pe' kilosram.
uglkg • Microgram' pcr kilogram,
pg/g = picOR11Im! per gram .
..... :IE" Value n-ot s....II;i1.eble for lhu chcmicat.
• = MarinelEstultine 'edfmettl
screening -criteria nol avoilablc, the: frc!hwatcf !.edimen~ ICI"e(ning criteria was llsed.
.* TEQ - Toxio;ity Equivalency Quotien[; TEQ c8Icula~lOf'l!J do nOl mclude dita from the 2002 Reme;.diallnv'C:srigation Report

PnnOH'1
PAse 7 of7
EN '.! AOI\

TIERRA-B-014956
T,ble 4
Analylic,1 RC5WtS ofTol,1 Chromium and He.,.,len, Chromium in Sediment
Study Area 7; Je~ey City, New Je~ey

Hexavalenl Hexav,lent Hex,v.lenr Hexavalent


Depth Chromium Chromium Chromium Chromium
Tot.1
D:Jte Below NJDEP NJDEP EPA EPA
Field Sample ID Chromium
Sampled Mudline Euract;on Extraction Extnclion Extraction
(mglkg)
(feet) 719M 7199 7196A 7199
(mglkg) (mglkg) (mglkg) (mglkg)
Reference &.m ...les:
SDOOI·RF1·()()0005-103 10116/2003 0-0.5 183 US UJ I.l8 J 825U1 5.9 J
SOOOI-RF2-oo0005-103 10/16/200) 0·0.5 143 13.3 UJ 1.67 UJ )3.3UJ 3.73 J
SJ)OO J .RF].000005-1 03 10116/2003 0·0.5 122 7.95 UJ 5.29J 7.95 UJ 0.90318
SOO02·RFI-000005·103 10116/2003 0-0.5 193 9.43 UJ II J 9.43 UJ 1.4518
SOO02·RF2-000005·103 1011612003 O· 0.5 133 11.8 UJ 1.48J IJ.8UJ L59JB
SD002-RFJ-OOOO05-103 10/16/2003 0- 0,5 227 8.15 UJ 109J 8.15 UJ 1.43 JB
!Studv Area 7 S.hlbits·
SDOOI·200·000005-203 1112512003 0-05 161 5.13 UJ 11.3 J 5,13 UJ I.1J
SOOO1-200-0050 I0.203 1112512003 0.5· I 263 5.45 UJ &.68 I 5.45 UJ 1.65 J
SOOO1-200.0 I 5020-203 11/2512003 1.5 - 2 1,700 9.3 UJ 1.l6UJ 9.3 UJ 393 J
SOOOI·200-025030-203 11/25/2003 2.5 ·3 526 6.& UJ 0.85 UJ 6& UJ 4,51 J
SOOO1-200-035040·203 11125/2003 3.5·4 352 7.22 UJ 0,903 UJ 7.nUl 1.44J
SOOO1·200-065070·203 11/25/2003 6.5·7 589 9,26UJ U6 UJ 9.26 UJ &5J
5DOOI-2oo-090095·203 1112512003 9· 9.5 55.5 5.11 UJ 515 J 5.11 UJ L29J
5D004-200.0oo005:203 1112212003 0·0.5 24.J J 4.84 UJ 1,91 J 4,84 UJ 0.897 J ,
SD004·2oo·0050 I0·203 ) 112212003 0.5· I 42.4 J 484 UJ 0.906 JB 4,84 UJ 0.621 J
SD004·200-0 15020-203 11/2212003 1.5 - 2 170 J 5,84 VJ 2.01 J 5.84 UJ 0.756 J
50004-200-025030·203 J 112212003 2,5·3 373 J 7.81 OJ 132J8 7.81 UJ 13.6 J I

SOO04-200-035040-203 11/2212003 3.5·4 355 J 8.53 OJ 1,29 J8 8.53 UJ 1.07 J


S[)(}Q4-200.065070-203 1112212003 6.5 -7 310 J 7.89 UJ 0.994 J8 7,89UJ 0.986 UJ
50004--200·085090·203 1112212003 8.5·9 357 J
~~-~_._- 8.23 UJ 3.77 J 8.23 UJ 4.84 J
5 DOOA-005-000005.203 121112003 0-0.5 304 5.63 UJ 2,03 J 5.63 UJ 0.563 U
SDOOA·005-OO50 10·203 I2IJ12003 0.5·1 358 598 UJ 0,598 VJ 5,98 UJ 0.598 U
S OOOA-005·0 15020·203 1211/2003 J.5 • 2 337 6.46 UJ 0.646 Ul 6,46 UJ 0,646 U
SOOOA-005-025030·203 1211/2003 2.5 - 3 2,170 7,53 UJ 0.753 UJ 7.53 UJ 0.753 U
SDOOA-005-035040·203 121112003 3.5 .4 2,570 8.6UJ 0.86 UJ 86 UJ 0.86U
SOOOA·005-065070·203 121112003 6.5·7 675 9.85 UJ I 0985 UJ 9.85 UJ 13.2 J
SOOOA·005-095I 00·203 1211/2003 9.5·10 16,9 ;
4.51 UJ 2.83 UJ 4.51 UJ 0,5958
SDOOA·025.000005.203 1112312003 0- 0.5 241 6.96 U 0,696 UJ 6.96 UJ 2.2618
SOOOA-025·0050 I0-203 1112312003 0.5· I 514 7.05U 0.769JB 7.05 UJ 0.8&2UJ
SOODA-025-OO5010-20) 11123/2003 0.5 • I· 477 7.26 UJ 0.748 JB 7,26 VJ 0.907 UJ
SDOOA-025·0) 5020-203 11/2312003 J.5 - 2 659 J 10,1 UJ l.01 UJ 1O.J UJ 6.49J
SDOOA·025·025030-203 11/2312003 2.5·3 I 1,050 J 8.23 UJ 5.62 J 8,23 UJ 5.5&J
SOOOA-025-035040·203 11/23/2003 3.5 - 4 497 J 6.84 UJ 40.9J 6.84 UJ 0.855 J
SOOOA·025-065070·203 11123/2003 6.5 - 7 540 8.2& UJ 3.21 JB &.28UJ 3,3118
SDOOA·025-0951 00-203 11123/2003 9.5 - 10 4.8 4.89 U 0.489 4.89 UJ 0.611 J
SDOOA.050-00oo05-203 11/2312003 O· 0,5 332 7.14 UJ 0.714 UJ 714 UJ 8.96 J
SDOOA.050-0050 10-203 11/2312003 0.5 . I 435 9,05 UJ 0,905 UJ 905 UJ 7,92 J
SDOOA·050-015020-203 IJ/2312003 1.5 - 2 1.690 10.2 UJ 1,72 JR 102 UJ 56,5 J
SDOOA-050-025030-203 11123/2003 2.5 - 3 727 8,4 U 0,884 J8 8,4 UJ 1.9818
S lJOOA-050-035040· 203 11/2312003 3.5 - 4 1.520 8,37 U 1.38 JB 8.37 UJ 3,5418
SOOOA·OSO-065070-203 11123/2003 6.5·7 669 8.73 UJ 9.04 J 8,73 UJ 3.23 JB
I
SDOOA·050-095099·203 1112312003 9.5·9.9 7,9 4.82 UJ 0.916 J8 4,82 UJ 0,602 J
SDOOA·]00-OOOO05·203 1112412003 0.05 1,230 J 8.68 UJ 3.43 J 8.68 UJ 6.62 J
SDOOA·lOO·00SOI0.203 1112412003 0.5 - J 483 J 8,02 UJ 954 J 8,02UJ 1.9 JB
SDOOA·100-015020·203 1]/2412003 J.5 . 2 464 J 805 UJ 0.861 J8 8,05 UJ 1.0] UJ
SDOOA·100-025030-203 11/24/2003 2.5 • 3 530 J 723 UJ J,l JB 723 UJ 4,68 J
SOOOA-I 00-03 5040-203 1112412003 3,5·4 713 7.7& UJ 1.3 7,78 UJ 4,51
SDOOA·100·065070-203 11/24/2003 6.5 - 7 273 5.08 UJ 4.3 r 5,0& UJ 0.779B
SDOOA-100-095Ioo·203 11124/2003 9,5 - JO 7 4,71 [;J 0.597 JB 4,71 UJ 0589 U

Parsons. Page I of7 ENVIRON

TIERRA-B-014957
Table .I
Allalytical Results of Tolal Chromium and Hel"'alenl Chromium in Sediment
Study Area 7; Jersey City, New Jersey

Hexavalen' He:X3v:aJenl He13V::llenl


Depth Chromium Chromium Chromium
H",~.",
Ouomium
]
Tot.1
Dole Below NJDEP NJDEP EPA EPA
Field Sample ID Chromiwn
Sampled Mudline E'trartion E~traction Eltraclioll Extraction
(mg/kg)
(feel) ?19M 7199 119M 7199
(mg/kg) (mg/kg) (mg/kg) (mg/kg)
,
SDOOA-200-000005-203 1211/2003 0-0.5 1,360 9.7& OJ 0.97& UJ 9.78 UJ 0.97& U
SDOOA-200..()050 10-203 121112003 0.5 . I 415 7.91 UJ 1.78 J 7.91 \.,'J 7.59 J
SDOOA-200..()J5020·203 121112003 J.5 • 2 21l 7.21 UJ 0.721 UJ 7.21 UJ 1.27B
SDOQA.200·025030-2OJ 1211/2003 2.5 - 3 275 7.71 UJ 13.4 J 77IUJ 4.53
SDOOA·200-035040·203 1211/2003 3.5 - 4 189 6.29 UJ 5.82 J 629UJ 2.6118
SooOA·200-065070·203 121112003 6.5·7 380 7.39UJ 21.31 7.39UJ 0.739 JB
SOOOA·200-095100-203 1~1/2003 '9.5·10 7.1 4.87 UJ I.4JB 4.87UJ 065B
SDOOB-005-000005-20j 121112003 0·0.5 130 461 UJ 3.03 J 4.61 UJ 0"42 B
SDOOB-005-000005-203 121112003 0-0.5" 32.8 4.66 UJ 1.0218 4.66 UJ 0.466 U
SDOOB-005-005010-203 121112003 0.5·1 175 5.16 UJ 0.516 UJ 516 UJ 0.516 U
SooOB-005..() 15020-203 1211/2003 1.5 • 2 390 9.85 J 16.2 J 4.88 UJ 3.79 JB
Soo08-005·025030-203 1211/2003 2.5 - 3 89.6 5.2 UJ 2.24J 5.2 UJ 3.26 JB
SOO08-005-035040-203 121112003 3.5.4 501 7.38 UJ 0.738 UJ 7.38 UJ 0.738 U
50008-005·065070·203 J2I1/2003 6.5 -7 72.2 5.11 UJ 0.633 J8 5.1 I UJ 0.571 B
SD008..()05·095 100-203 121112003 9.5. 10 5.4 4.98 UJ 0.66418 4.98 UJ 0.542 B
SOO013·02 5-00000 5·203 1211/2003 0·0.5 126 4.95 UJ 6.09 J 4.95 l!J I.2J
SOOOB-025-OO5010·203 1211/2003 0.5· I 573 5.26 UJ 5.57 J 5.86 J lJ.4 J
5OODB-025-005010·203 11125/2003 0.5· I' 602 5.17 UJ 12J 5.17 UJ 5.98 J
5DOOB-025-015020·203 J 211/2003 1.5·2 116 5.98 UJ 2.74J 5.98 UJ 0.598 UJ
50008-025-025030·203 1211/2003 2.5·3 785 8.13 UJ L02 UJ 8.13 UJ 0.813 UJ
5000B·025·035040-203 1211/2003 3.5 - 4 406 7.45 UJ 0.931 UJ 7.45 UJ 0.745 UJ
50008-025-065070·203 11125/2003 65·7 10.3 5.05 UJ 0.8%J 5.05 UJ
I 0.687 J
5000B-025-095099·203 11/25/2003 9.5 - 9.9 8.1 491 UJ 0.747 J 4.91 UJ 0.491UJ
SOO08·050·000005-203 11/2312003 0-0.5 372 5.23 UJ 0.654 J8 5.23 UJ 0.654 UJ
SOO08-050·0050 I0-203 llI23/2003 0.5· I 670 6.63 UJ 23.4 J 6.63 U1 1.91 JB
5OO0B-050-005010-203 11/23/2003 0.5· I" 522 7.1 U1 0.90818 7.1 UJ 4.71 J
5OO0B-050-015020-203 11/23/2003 1.5 - 2 421 8.2UJ 4.88 J 8.2 UJ 1.26JB
5OO0B-050-025030·203 11123/2003 2.5·3 47.1 4.85 UJ 1.24J8 4.85 UJ 4_32 JB
5DOOB-050..()35040-203 11123/2003 3.5 - 4 10.2 5.69 UJ 0.84418 5.69 UJ 0.787 B
SooOB-050·065070·203 11/2312003 6.5 - 7 6.4 4.23 UJ 0.537 J8 4.23 UJ 0.5358
50008-050-095098·203 11/23/2003 9.0; -9.8 5.2 4.87 tJ 0.526 JB 4.87 UJ 0.816 B
SOOOB·100-OOOO05·203 1112212003 0-05 156 4.94 UJ 536 4.94 UJ L&8JB
5OO0B-100-00501O·203 1112212003 0.5 - I 306 78 VI 15.1 7.8 UJ 22.6
Soo08-100-01502O-203 11/2212003 1.5 - 2 10.6 5.15 UJ J.33 5.15 UJ 0.99 B
SooOB·100·025030-203 1112212003 2.5 - 3 6J U7UJ 0.569c 4.87 UJ 0.655 B
SDOOB-lOO-035040-203 11/2212003 3.5 - 4 4.5 4.86 UJ 0.486 U 4.86 UJ 0.608 U
50008·100·065070-203 1112212003 6.5 ·7 4.6 471 UJ 0.471 U 4.71 UJ 0.589 U
SD008·100·080085·203 11/2212003 8·8.5 6.7 4.72 UJ 0.472 U 4.72 UJ 0.59 U
50008·200-000005·203 11/2212003 0-0.5 72.7 5.04 UJ 6.6 5.04 UJ 3.19 B
SOO08·200-005010-203 1112212003 0.5· I 208 6.43 UJ 6.72 6.43 UJ 1.88 B
SOO08-200-0 15020·203 1112212003 1.5 . 2 163 6.97 UJ 138 6.97 VI 1.04 B
5OO0B-200.025030-203 11/2212003 2.5·3 224 J 7.27 UJ 2.6 J 7.27 UJ 1.45 J
5OO0B-200.035040-203 11/2212003 3.5 -4 122 J 609 UJ 0.609 UJ 6.09UJ 3.58 JB
SOO08-200-065070-203 11/2212003 65·7 376 J 7.27 UJ 0.835 J8 7.27 UJ 0.909 UJ
50008 -200-090094- 203 1112212003 9.9.4 437 J 7.14 UJ 3.98 J 7.14 UJ 4.38 J
I SDOOC--0O5-000005~203 i ii:lO/2003 0- 05 170 103 UJ
I 1.03 UJ 10.3 UJ 1.03 OJ
5OOOC·005..()050 I0·203 11/20/2003 0.5 ·1 166 II UJ 1.1 UJ I) UJ l.IUJ
SDOOC-005-015020·203 11/2012003 1.5 - 2 194 9.85 UJ 09c85UJ 985 UJ 0.985 UJ
SooOC-005·025030-203 11/2012003 2.5·3 181 9.59 UJ 0959 UJ 9.59 UJ 09c59 UJ
5DOOC-005·035040-203 IJ12012003 3.5·4 206 8.93 UJ 1.33JB 8.93 UJ 0.893 UJ
SOOOC-005.065070-203 11/20/2003 6.5 - 7 198 8.75 UJ J2.7 J 8.75 UJ 0.875 UJ

Panons Page 2of7 ENVIRON

TIERRA-B-014958
Tobie 4
An.ly,ic.1 Results of Tot.1 Chromium and He .... I'nl Chromium in Sedimenl
Study Are. 7; Je"ey City, Ne .. Jersey

He ... olent Hex ••• lent RexDv.lenl Henv •• ent


De~th Chromium Chromium Chromium Chromium
Tol.1
Dote Belo .. NJDEP NJDEr EPA EPA
Field S.mple ID Chromium
SDm~led Mudline Extr:lclion EXIri1ction Extraetion Ellmelion
(mglkg)
(feet) 719M 7J99 7196A 7199
(mglkg) (mglkg) (mglkg) (mglkg)
SDOOC·00S-085090.203 11/20/2003 8.S - 9 198 6.8S U1 3.72J 6.8S UJ 0685 UJ
SDOOC-02S-000005·J 03 1011612003 0·0.5 149 109UJ 137 J 10.9 UJ 21 JB
SDOOC-025·000005·203 11/1912003- 0·0.5 180 9.76 UJ 0976 UJ 976 UJ 459
SDOOC·025-00S010·203 1111912003 0.5 - I 203 11,2 UJ 112UJ 11.2 uJ ).6
SDooC·025.015020·203 11119/2003 1.5 - 2 197 9,41 UJ 1.96 J 9.41 UJ 3.93
SDOOC-025 -0 25030· 20) JIll 9/2(0) 25·3 226 8.95 UJ 0.895 VJ 8.95 UJ 5.32
SDOOC-025-035040-203 11/19/2003 35·4 197 6.99 UJ 0699 UJ 6.99 UJ 0874 U
SDOOC-025-065070·203 lll19/2003 6.5 - 7 3IJ 8.42 UJ IJB 8.42 UJ 1.05 U
SDOOC-050-D65070-203 11/1912003 6.5.7° 768 8.&5 UJ 0.88S UJ 8.85 UJ I.lIU
SOOOC-025-095 100-203 11/1912003 9.5·10 593 7.74 UJ 0.942 JB 7,74 UJ 0967 U
SOOOC-050-000005-103 1111912003 0·0.5 274 9.43 UJ 0.943 UJ 9.43 UJ 328
SDOoC-OSO-0050 I0·203 I II I912003 0.5 - I 224 9.35 VJ I.72J 9.35 UJ 1.17 U
SDOOC-050·0 15020-203 11119/2003 1.5 - 2 234 8.79 VJ 1.38J &.79 VJ 8.73
SOOOC-050-025030·203 11/1912003 2.5 - 3 181 6.05 UJ 8,73 J 6.05 VJ 0.756 U
SDOOC-050-035040·203 11119/2003 35 -4 S76 8.83 UJ 0.905 JB 883 OJ J.lU
SOOOC·050·065070·203 11119/2003 6,S·7 696 8.64 UJ 0864 UJ 8.64 Ul 1.08 U
SOOOC-050·095 100-203 1111912(0) 9,5 - 10 309 6,86 UJ 2.71 J 6.86 VI 0.858 U
SDOOC-050-D95I 00-203 1111912003 9.S· 10° 294 666 VI 3.28 J 6.66UJ 0.832 U
SooOC·l 00~OOO05-1 03 1011612003 0-0,5 l27 7.58 VI 1,27 J 7.58 UJ l.05 J8
SooDe· I00-000005-103 10/16/2003 0.0.5° 136 7.52 UJ 5.45 J 7.52 VJ 7.61 J
SDOOC-100-OOOO05-203 1112112003 0-0.5 136 6,73 UJ 4.141 6.73 U 12.4 J
SDOOC-100·0050JO·203 1112112003 0.5 - 1 159 6.39 UI 4.761 6.39U 4.98 J
SooDe-100-0050IO-203 1112112003 0.5 - I" 126 S,91 UJ 4.49J 5.91 U 2.6 J
SooOC-1 00-0 15020.203 11/2112003 1.5 - 2 175 7,05 VI 0.705 UJ 7.05 V 0.705 U
SDOOC-100.025030.203 11121/2003 2.5 - 3 199 7.94 Ul 7.98 J 794UJ 4.15 J
SDOOC-100-035040·203 11/2112003 3.5 - 4 228 7.87 UJ 0.787 UJ 7.87 UJ 10.5 J
SDOOC-lOO-065070·203 11/2112003 65-7 293 8.32 UJ 10.1 I 8.32 UJ 0,832 UJ
SDOOC-J 00-090095-203 J 1121/2003 9· 9,5 110 6,08 UJ 0,766 J 6.08 UJ 6.63 I
SDOOC·200-000005-203 1112112003 0-0.5 534 5,76 UJ 556 J 5.76 UJ 1.82 J
SooOC-200-0050 10.203 1lI2112003 0.5 - 1 50.3 5.04 UJ 146J 5,04 VJ 1.07 J
SOOOC·200-015020·203 11/21/2003 1.5 - 2 321 8.46 UJ 2.98 J 8.46 UJ 3,78 J
SDOOC-200-025030-203 11/2112003 2.5 - 3 456 8.95 UJ 2.01 J 8.95 UJ 3.561
SDOOC·200-035040.203 11121/2003 , 35·4 388 8.02 UJ l.71 J 8.02 VJ 0.802 UJ
SDOOC-200-065070.203 1112112003 6.5 - 7 602 8.32 UJ 1.31 1 8.32 UJ 0,832 UJ
SDOOC-200.09OO95·203 1112112003 9- 9.5 334 828 UJ J.7J 828 UJ 0828 UJ
SJ)OOD-050-000005~ iUJ 1011612003 0.05

I I I
320 7.63 VI 0:95 UJ 7.63 UJ 1.59IB
SDOOD--ISO-00OO05-103 1011612003 O· 0,5 1,400 I J.7 UJ 1.46 UJ 11 ,7 VJ
Soo j WoOl 0-065070.2UJ
3.79 J 1/
IIIIS/2003 6.5·7 299 6.55 UJ 1.75 J 6.55 U 9,18 J
SDOIW·OIO-115120-203 1111512003 11.5 - 12 6.6 4.68 UJ 0.987 JB 4.68 U 0.468 V
SD02C-0IO-06S070-203 1111312003 6.5· 7 430 87 VJ 2.17 JB 8.7 VJ 0.87 UJ
S002C-01O·115120-203 )111312003 11.5 - 12 7.3 4,69 UJ 0.50J B 4.69 UJ 0.469 UJ
Sa02C-OJ 0·165170-203 1J113/2003 165 - 17 7.8 4.68 UJ 0.468 VJ 4,68 UJ 0.468 UJ
SD02E-O i0-065070-203 ii/l ~/2003 6.5 - 7 285 5.87 VJ 0.75IB
I 5.87 U 3,45 J
SD02E-01O-1I5120-20) 11115/2003 II,5 - 12 7.6 4.56 VJ 0.456 OJ 4,56 U 0.456 U
SD02E-010·165110-203 11115/2003 16.5.17 68 4.&5 UJ 0.60118 485 U 0.485 U
~D02E-025-000005·203 1112112003 0.0.5 216 937 UJ 0,937 UJ 9.37 UJ 5.41 J
SOO2E·025·0050 10·203 1112112003 0.5 . I 271 941 UJ 0.941 UJ 9.41 UJ 3.44J
S002E·025.0IS020·203 1112112003 1.5 - 2 208 825 UJ 0825 UJ 8.25 UJ 0.825 UJ
S002£·025·025030·203 11121/200) 2,5 - ) 207 6,45 VJ 0&4 J 6.45 UJ 3.15 J
SD02E·025-035040·203 1112112003 3.5 - 4 S60 7.09 UJ 2.18 J 7D9 UJ 0.709 UJ
SD02E-025·06~Q70-203 11/21/2003 6.5 - 7 406 8.26 UJ
- 1.9J 826 VI 6,71 J

Page 3 0l'7 ENVIRON

TIERRA-B-014959
Taule ~
AnalJlinl Results of Totol Chl'omium .nu He .. ,·.lenl Chromium in Sedimenl
Study Area 7; Jcrsey City. Nen Jersey

Hunalenl Hex3vaJent Hexavalenl Hexavalent


Oeprh Chromhun Chromiwn Chromium C1lromiwn
TO/DI
Date Be[ow NJDEP NJDEP EPA EPA
Field Sample ID Chromium
Sampled Mudline E.lraelion Ellraction Ellraclion E.lradion
(mglkg)
(feel) 7l96A 7199 719M 7199
(mglkg) (mglkg) (mglkg) (mglkg)
SD02E-025-090095·20J ll/211200J 9·9.5 53 4.85 UJ 0.738 J 4.85 UJ . 0485 UJ
SD02E'{)75-oo0005-103 101161200J 0·0.5 331 10 UJ 3.25 JB lOW 1.52 J8
5002£-075-000005-203 11120/200J 0- 0.5 157 9.8 UJ 2.45J 9.8 UJ 1.23 U
5DD2E-075-00oo05·203 11/20/2003 O· 0.5- 158 9.83 UJ 0.98] UJ 9.83 UJ 1.6
S002E.{)75-005010·20] 11/2012003 0.5 . I 185 10.2 UJ 11.91 10.2 UJ 1.02 UJ
S002£-075-0050 10-203 11I201200JI 0.5· I- 174 9.76 UJ 346J 9.76 UJ 0.976 UJ
SOO2E-075-O 15020·203 11/20/2003 IS - 2 189 9.46 UJ 0.946 UJ 9.46 UJ 0.946 UJ
SOO2£-075·025030·20] 11/20/2003 2.5 - 3 231 8.83 UJ 0.93618 8.83 UJ 351 J
5002£-075·035040·203 11/20n003 35 -4 218 8.42 UJ 3.22 J 8,42 UJ 104 J
SOO2E-075-065070·203 11/2012003 6.5·7 7.2 '4.63 UJ 1.12 JB 4.63 UJ 0.463 UJ
SD02E-075-085090·203 [ 1120/2003 8.5 - 9 7,4 4.87 UJ 0598 JB 4.87 []J 0.487 UJ
SD02W.ZOO-OOOO05-Z03 121212003 0·0.5 7.4 4.67 UJ 0.593 JB 4.67 UJ 0,467 UJ
SDOZW·ZOO-OO5010-203 121212003 0.5 - I 10.7 4.6 UJ 0.59718 4.6 LJ 0.46 UJ
S002W-200-O 15020-203 12121200] 1.5 . 2 7.9 4.88 UJ 1.2218 4.BB UJ 0.629 B
5OO2W-200-025030-203 121212003 2.5·3 22.9 4.98 UJ 0,498 UJ 4.98 UJ 0.49B Ul
S002W·200-035040-203 121212003 3.5 • 4 18.5 5.03 OJ 0.869 JB 5.03 UJ 0.50301
S002W·2OO-065070·20] 121212003 6.5·7 11.4 4.63 UJ 0463 UJ 4.63 UJ 0.463 U
SD02W-200-095 100-203 121212003 9.5·10 n'7 4.96 UJ 0,496 OJ 4.96 01 OA9h 111
5OO3E-010-000005-203 1l/lJ/2003 0·0.5 3.070 J 7.13 UJ 0.713 OJ 7.13 OJ 1.07 J
5003£-010-005010·203 1111112003 0.5· 1 126 J 5.78 01 0.591 JB 5.78 LJ 0.578 OJ
S003E.{) I0·0 15020·203 IIIl1/200] L5·2 466 J 8.83 OJ 3.36 J 88301 0.88301
S003£-01O·025030·203 1111112003 2.5 . 3 939J B.7[ 01 0871 UJ 8.71 UJ 0871 UJ
SD03E-O 10-035040.203 11/11/200] 3.5 - 4 315 J 7.74 UJ 849J 7.74 UJ 0.897 J
5003 E-O10·04 5050.203 11/1112003 4.5 . 5 127 J 6.2701 0.627 UJ 6.2701 1.08 J
5003 E-O I 0-05 5060·203 11111/2003 5.5 -6 4.] J 5.21 OJ 0.75 JB 5.21 OJ 0.521 UJ
SOO3E-<JI0·065070-203 1111112003 65.7 5.1 J 5.01 UJ 0.61318 5.01 OJ 0.501 UJ
5D03 £-0 I0·075080.203 1111112003 7.5. g 8.8 J 4.83 UJ l.lJ 4.83 UJ 0483 UJ
SOOlE·010·085090-203 1111112003 8.5 • 9 99.4 J 15.2 J 21.5 J 4.8 UJ 4.56 J
S\)(]3 E-<J1O-<J95100·203 IIIIIIZ003 9.5·10 225 J 4.63 Ui 1.6] 1 4.6301 6.19 J
S003£-<JIO·105 [10-203 III1112003 10.5· LI L67J 6.IZ J 2.57 J 4.6] OJ 0,463 UJ
5OO3E-OIO.115120-203 11/11/2003 11.5 • 12 , 132 J 5.94 J 10.2 J 4.78 UJ 2.6 J
500]£-010·125130-203 11/1 [12003 12.5· 13 15.81 4.71 OJ 0.634 JB 4.71 UJ 0471 UJ
S003£-O 10·135140-203 11I1l/2003 13.5· 14 23.5 J 4.71 UJ 0.5]81B 4.71 UJ 0.471 UJ
5003£-025-000005-203 11116/2003 0- 05 299J 5.8B Ui 8.91 J 5.88 UJ 0.744 JB
SOO3£-025·0050 10·203 1111612003 0.5· I 2291 7.26 UJ 6.731 7.26 UJ 4.2618
SOO3E-025·015020-203 1[/1612003 L5·2 450 J 7.97 UJ 20.71 7.9701 9.96J
S003£-025·025030-203 [ 111612003 2.5 - 3 283 J 704 UJ I.3J 7.0401 12,4 J
5003£-025·038043-203 11/1612003 3B . 4.3 9J 4.96 UJ 1.041B 4.96 UJ 0.496 UJ
5OO3E-025·065070·203 11/16/2003 6.5 - 7 8.5 J 4.88 UJ 1.9J 4.88 UJ 0.488 UJ
5003£-025·093098·203 11/1612003 9.3 . 9.8 71 4.87UJ 0661 JB
, 4.87 UJ 0,487 UJ
5D03 E-050·00oo05.103 1011612003 0·0.5 377 691 UJ (AS 1B 6.91 UJ 137 JB
S003E-050·065070·203 1111212003 6.5·7 6.7 4.77 OJ 1.011B 4.77 OJ 0.909
SOO3£-050-115120-203 lI/l2I2003 [1.5-12 6,4 483 UJ 0.596 18
i 4.83 UJ 0.598
5003£-075-000005.20] 11117/2003 0-05 536 J 8.58 UJ 0.858 U 8.58 U1 I.99J
SDOJ £-075-0050 10.203 1111712003 0.5· I 361 J 7.63 UJ 3.13 J 7.63 UI 0.763 UJ
5OO3E-015.015020·203 1111712003 1.5· 2 128 J 5.43 UJ 0.97818 5.43 VJ 2.45 J
S003 £-075-025030-203 III171200] 2.5·3 386 J 6.34 UJ 0.634 U 6.34 UJ 1.761
S003£-075-035040-203 1111712003 3.5·4 9J 4.91 UJ 2.2 J 4.91 UJ 0.49[ UJ
5D03£-075-055060-203 1111712003 55·6 6,4 J 4.73 OJ 0.473 UJ 47301 0,473 UJ
SDOJE.{)75·062067-203 1111712003 6.2 - 6.7 6.5 J
I SD03\1.1~150-000005_10J , 10/16/2003 I 0- Q.5 I 278 I
4.8U1
5.03 UJ I
O,4B OJ
4.7 I
4.8 UJ
5.03 UJ
0,48 UJ
1.0gJB I

PDl'S()nS
Page 4 of7 ENVIRON

TIERRA-B-014960
Table ~
Analytic,1 Results orTolal Chl'omilUll and Hexavalenl Chromium in Seulment
Study Area 7; Jersey City, :-if"' .Jerse~'

Field Sample ID
Date
Sampled
Depth
IkJow
Mudline
TOlal
Chrmniw10
(mglkg)
Hexavalent
Chrorniwn
r'JJDEP
Euraction
Hexavalent
Chromium
NJDEP
EXlraclion
lIeu"alent
Chromium
EPA
Extnlction
""'-".,
Chromium
ErA
Extl'llclion
]
(reel) 7196,\ 7199 7196.1. 7199
.. . _ . (rnglkgJ (~J (mglkg) (mgi~)
,
SD03W·200-Q0000l·203 I1124/200] 0-0.5 53,8 UUJ 3,16 4.& UJ 33 J8
SD03W·200-Q0501O-20] 1ll24i20OJ 0.5 - I 25 H8Ul 5.45 4.8& UJ 1]91B
SDmW·200-005010-20] 1112412003 0.5 - j- 13,7 5.0~ UJ 3.93 5.08 UJ 0635 U
SD03W·2oo-o15020-203 1112412003 1.5 - 2 5.8 4.72 UJ 0,478 13 4.72 UJ 0.59 U
S003W.2oo-Q25030-20] 1112412003 2,5·3 71 4,82 UJ 0.96618 4,82 Ul 0.602 U
SD03W-2oo-o35040-203 Il124/2003 ]5 - 4 7 4.9 Ul 0,49U 4.9 VI 0.613 li
SD03W·200-o65070·20] 111241200] 65 -7 66 4.8 UI 0,92918 4.8 UI 0.6 U
SD03 W·200-085090·203 111241200] 85-9 5.5 J 4.85 UJ 075! 1 4.85 UJ O.607lH
SD I3E-005·0oo005-203 11117/2003 0-0,5 2.850 I 7.26 VI 0.726 UJ 7.26 UJ 0.726 UJ
SO 13E-005-OO50 10-203 1111712003 0.5· I 2.190 J 9.64 UJ 0,964 UI 9.64 UJ 3.01 I
S013E·005-015020-203 1111712003 L5 - 2 5371 7.63 UJ 16.21 7.63 UJ 2,4 J
SD13E-005·0250]0·203 11117/2003 2,5·3 298 J 7.45 UJ 1.36 J 7,45 UJ ].28 J
SOI3£-OO5·035040-203 1lll7/2oo3 35 - 4 898 J 7,97 Ul 0.797 Ul 7.97 UJ 0.797 UJ
SD 13E-005-065070·203 1111712003 6.5 -7 289 J 8.03 UJ I.SII 8.03 UJ 0,803 UJ
so I3E-005-o95 100-203 11117/2003 9,5·10 4.1 4.81 UJ 0.481 UJ 4.81 U 0.481 V
SD13£-010·000005·203 1111212003 0·0.5 2.180J 7.31 UJ 0731 UJ 7.31 UJ 0,987 J
SD 13£·0 I0-0050 I0·203 1fI I 212003 0.5 - 1 734 J 9.11 Vi 0.98918 911 UJ 1.851
S013E-010·0 15020·203 1111212003 1.5 - 2 1,900 J 8.73 UJ 3.861 873 UJ 30J J
SOl 3£-0 10-025030-203 1Ii12l2003 2.5·3 1621 6.91 UJ 0.824 J8 691 Ul 0.691 UJ
80 I3E--O I 0·035040-203 111[212003 3.5·4 918J 8.85 UJ 1.43 J 8.85 UJ 0.885 UJ
8013£-010.0450S0-203 1111212003 4.5·5 519 7.26 Ul 1.57 J 7.26 UJ 2.12
SO 13£-0 1O-0S506O·203 1111212003 5.5·6 414 8.81 VJ 1.07 J8 8.81 UJ 6.56
8013£-010-065070-203 1lIl212003 65 - 7 4.1 5.44 UJ 0,81218 5.44 UJ 1.29
SOI3£-010-07S080-203 11/121200] 7.5·8 7.1 5,08 UJ 0,508 UJ 5.08 UJ 0.508 U
so 13£-0 I0--085090·203 11/121200] 8.5·9 3.9 4.9Vl 0.5971 4,9Ul 049U
SDI3£-O 10·085090·203 11/121200] 8.5 - 9- ].9 4.9Ul 0.49 UJ 4.9 VJ 0,49 V
SDI3£-O 10-095100-203 11/1212003 9.5 - 10 5.3 4.71 Ul 0.471 UJ 4.71 OJ 0411 U
SDI3£-010·1051 10-203 11/1212003 10.5 - II 9.7 4.54 UJ 0.508 JB 4.54 UJ 0.454 U
SO 13£-010-115120.203 1111212003 11S·12 8, I 4.8 UJ 0.48 UJ 4.8 UJ 0.48U
8013E-OIO·125130.203 11/1212003 12,5·13 1].7 4,79 UJ 0.78618 4.79 UJ O.479U
S013£-010·135140-203 1111212003 13,5·14 16.3 4,79 UJ 0.479UI 4.79 UJ 0.479 U
SDI3E-010.!4S150-20] 11/1212003 14.5· 15 15.6 4.74 UJ 0.57218 4.74UJ 0.474 U
SDI3E-OIO·IS5160-203 1111212003 15.5·16 11.6 4.63 UJ 0.6971B 4,63 Ul 0.463 U
SDI3E--050-000005·203 11I!7I2003 0-0.5 290 6.33 UJ 1.22 6.3] UJ 7.121
SO 13£-050·0050 10-203 11117/2003 0.5 - 1 168 699 UJ 0.699 V 6,99 UJ 0699 VJ
50I3E-050-015020·203 1111712003 1.5 - 2 521 8.75 Ui 1.73 8.75 UJ 0.875 UJ
S013£-050·025030·203 1111712003 2.5 - 3 730 191 UJ 1.67 7.91 OJ 9.84 J
SO 13£-050·035040.203 1111712003 3.5 - 4 470 7.91 UJ 1.59 7.91 UJ 19J
SOI3E-{l50-065070·203 11113/2003 6.5 - 7 5 4.78 UJ 0.738 B 4.78 UJ 0.478 UJ
SOI3E-050-065070·203 11113/2003 6.5 -7- 4.9 4.72 UJ 0.472 U1 4,72 VJ 0.472 VI
80 I3E-{l50· I15120-203 11/13/200] 11.5-12 8.3 452 Ul 0.647 B 4.52 UJ 0,452 UJ
8013£·100-000005·103 10/16/2003 0·0,5 !44 60] UJ 1.67 J8 6.03 UJ 10.5 1
SOI3£-100-000005-203 III 18/2003 0-0.5 264 7.35 UJ 0.94] 18 7.35 UJ 0.735 UJ
8D 13 £. I 00-005010-203 11118/2003 0.5 . I 502 881 UJ 29.3 8.81 VJ 0.831 UJ
SOl 3£·100-015020.203 1lI1S/2003 l.S - 2 367 1,5 UJ 2.14 7.5 UJ 0.75 Ul
SOI3£-100--025030.203 11/1S/2003 2.5 - 3 3]5 H3UJ 7.81 743 UJ 0741 V1
8013E·100.035040·20] 11118/2003 3.5 - 4 509 8.58 UJ 38 8.53 VJ 0.858 VI
S D I 3£·1 00-065070-20] 11/18/2003 6.5 - 7 5.3 4,76 UJ 0.898 JB 4,76 UJ 0,476 UJ
SDI3E-loo-095 100·20] 11/18/2003 9.5 - 10 7.8 481 UJ 064 JB 4,81 U1 0.481 UJ
SD I) \V -200-O00005-~203 12!2!200J 0-0.5 25,; 4.91 UJ 1.73 UJ
SO 13 W·2OO-0050 I0-203 1212'2003 05· I 7.5
l 48 UJ
L LIS JB
L
4.97UJ
4.8 Ul L 1.9J'i"]
0.727B .

Parsons Page 5 of7 ENVIRON

TIERRA-B-014961
T.ble 4
Analytical Results of Total Chromiwn and Hex.nltnl Chromium in Sediment
Study A rea 7; Jers')' City, New Jersey

HeX3\1alent Hel:avalent Hexa,'alent Hex8\'aJ.enl


De~lh Chromium Chromium Chromium enromium
TOlal
Dale Below NJDEP NJDEP EPA EPA
Field S.mple ID Chromium
Sampled Mudline E'traclion EXlraction E<traction Elltaction
(mglkg)
(feel) 719M 7199 7196A 7199
(mglkg) (mglkg) (mglkg) (mglkg)
SO 13W-200-DOOO05-203 [21212003 0·05" 17.1 4.87 UJ 2.99 UJ 4.87 UJ 1.I2J8
SO I3W·200-O! 5020·203 121212003 1.5 - 2 88 4.67 UJ 0.711 JB 4.67UJ 0.467 Vi
SO IJW-200-025030-203 121212003 2.S - 3 9.6 4.77 UJ 182 UJ 477UJ 0.477 VJ
SOI3W-200-03S040-203 121212003 3.S - 4 8.1 482 UJ III JB 4.82 UJ 0.618 B
SO 13W·200·06S070-2OJ 121212003 65-7 14 464 UJ 0.771 JB 464 VJ 0.464 UJ
SO 13 W-200.()95 100-203 121211003 9.5 - 10 5.9 4.83 UJ 0.483 VJ 4.83 Vi 0.483 VJ
SDGEI-010.()00005-203 1213/2003 0-0.5 1.450 7.08 UJ 116 JB 70& Vi 1.29JB
SOG£I-020-020040-203
SDG£I-Ol0-07S080-203
1/14/2004
121312003
2·4
7.5 - 8
346
7.5
--
5.12 UJ
.-
1.34JB
--
5.12UJ
-
0511 VJ
SOG£I·020·125130.203 121312003 12.5· 13 3&.2 5.49 J 907 J 4.65 UJ 0.7178
SOO£I-020-1&018S·203 1213/2003 1&·1&5 35.1 4.&5 VJ US JB 4.85 VJ 0.908 B
Soo£I·020·200205-203 121312003 20·20.5 35.8 4.88 VJ 0.%78 4.88 VJ 0.737 J
SooE2.()20.()00OO5-203 1/14/2004 0·0.5 464 _. - .- -
SOOE2-020-020040-203
SOOE2·020-040060-203
1/14/2004
12116/2003
2·4
4-6
473
S60
--
7.S8 UJ
--
1.27 J8
--
7.58 CJ
-
0.758 UJ
SOOE2-020-060080·203 12116/2003 6·8 13.4 48 UJ l.25 JB 4.8 UJ 0.567 JB
500E2-020-1OOI20-203 12116/2003 10 - 12 6.& 5 VJ 0.625 VJ 5UJ 0,5 UJ
5 OG E2-0 20-120 140- 203 12116/2003 12- 14 13.1 4.62 UJ 0.577 UJ 4.62 UJ 0.462 UJ
5DG£2-020-160 1&0-203 12116/2003 16 - 1& 13.& 4.&4 U1 0.605 UJ 4.84 UJ 0.484 UJ
500£2·020·200220·203 l2Il6/2003 10 - 22 9.2 485 VJ 0.606 UJ 4.85 UJ 0.485 UJ
500£2·020-240245-203 1211612003 24 - 24.5 7.4 473 VJ 0.915 B 4.73 UJ 0.473 UJ I
. 5DGEJ·038..Q00OO5-203 1219/2003 0-0.5 127 4.92 UJ 4.37 4.92 UJ 5.99
SDG£3·038.()35040-203 1219/2003 3.S - 4 Jl6 4.7& UJ 1.32 JB 4.7& UJ 0.591 B
5OOEJ-Q)&..Q6006S-203 1219/2003 6 - 6.5 1&.3 461 UJ 1.07 B 4.61 UJ 0.461 U
SOOE3-038·120125·203 1219/2003 12 - 125 21.9 5.11 UI 0.78& B 5.11 VJ , 0.511 U
SooE}'()38-160 165-203 121912003 16 - 16.5 20.7 5.2 UJ 0.906 B S.2 UJ I
0.52V
5OOE}-D38-16016S-203 121912003 16·16.S" 204 5.2& UJ l.08 B 51& UJ 0.52& U
SOOE3-03&-220225-203 1219/2003 22 - 22.5 24 5.13 UJ 0.642 U I
I 5.13 UJ 0513 V
500£4.040-000005·203 12I11/200} 0-0.5 333 6.33 UJ I 628 J 6.33 UJ 4.59 I
5OOE4-040..Q050 10-20} 12111/2oo} O.S - I 42} 6.79 UJ 1.1318 ~ 6.79 UJ 0.679 VJ
SOO E4-040-03}03 8-20} 12l11/20rn 3.3 - J.8 755 231 J 36.8 J 4.69UJ 3.2 J
!
SDOE4·040..Q85090·203 12111/2003 8.5 - 9 227 6.46 J 8.74 J 4.67 UJ 3.15 J
5DO£4-040-12012S-203 1211[/2003 12 - 12.5 944 4.94 UJ 318 4.94 UJ 0.494 UJ
SDOE4-040· 165 170-203 1211[/2003 16.S - 17 9.4 4.73 UJ 0.608 B 4.73 UJ 0473 VJ
SOO£4-040-220225-203 1211[/1003 22 - 225 93 I 4.94 UJ 0881 B 4.94 UJ 0494 UJ
SOO £5-060-000005.203 1/1412004 0-0.5 202 -- -- -- -
SOOE5-060.()20025-20] 12118/2003 2· 2.5 191 7.04 UJ 0.704 VJ 7.04 UJ 481 J
SOG£S-060-070075-203 1211&12003 7·7.5 85 4.7& UJ 0&46 J 478 UJ 0478 UJ
SOO E5-060. 070075-203 l21l812003 7·7.5" 78 4.77 UJ l.61J 477VJ 0.477 VJ
500£5-060·100105·203 1211812003 10 - 10.5 7.4 4.65 UJ 0.99J 4.65 UJ 0.465 VJ
5OOE5·060·150155-203 1211812003 15 - 15.5 9.8 4.93 UJ 0493 UJ 4.93 UJ 0493 UJ
5OOE5-D60-1 50 155-203 1211812003 15 - 155" IS.} 5 UJ O.S UJ 5UJ 0.5 UJ
500£5·060-190 195-203 1211812003 19- 19.5 IS.3 5.}1 UJ 0.531 UJ 5.31 UJ 0.531 UJ
500 ES·060-2.3023 5-203 1211&11003 23·23.5 22 S.35 UJ 0.535 UJ 535 UJ 0535 UJ
500£6-062-000005_203 12/8/2003 0-0.5 621 7.75 UJ 9.46 J 7.75 lJJ 0.775 UJ
SDO£6-062-02oo40·203
SDOE6-()62-070075-203
1/1412004
1218/2003
2-4
7 - 7.5
320
6.8
~.
4.87 UJ
-.-
141 JB 4.87
-- UJ
-
0.4&7 V
SDG£6-062·115120-203 121812003 11.5· 12 8.8 4.7} UJ 0.9678 4.73 UJ 0.473 U
500£6-062-155160-203 1218/2003 15.5· 16 20.5 4.69 UJ 0.7098 4.69 UJ 0.469U
5OOE6-062-235240·203 121812003 23.5·24 12.4 493 UJ 0617 U 4.93 UJ 0.493 U
500£7·01 &-000005-203 111412004 0-0.5 263 --

Parsons Page 6 of7 ENVIRON

TIERRA-B-014962
Table 4
Analytical Resuhs of Total Chl'omium and Hex.avalenr Chromium in Sellimelll
Study Area 7; Jersey City, New J,,"Sey

H·n:avalcnl Hel.:avillcnt Heu\'.!"nl Hel<l\'alenl


Depth Chromium Chrom.i.um Chromium Chr<>mi"Jil
Tol.r
Ihte Below NJDEP N-fDEP EPA EPA
Field S.mple lD Chromium
S.mpled MudUne E Ur:>Clion ht,..ction Extr:>clion EX.tr3clioll
(mg/kg)
(feet) 7196A 7199 7196A 7199
(mg/"t;) (mgIkg) (mg/kg) (mglkg)
SDGE7-0 IS.{)20040-203 1/14/2004 2-4 419 -- -- -- --
SDGE7-01 &.{)55060·203 12120/2003 55 ·6 115 5.57 UJ 14.2 J 5.S 7 UJ 3.84 J
SDO£7-01&-060065-203 12120/2003 6 - 6.5 50.5 5.08 UJ 1.7418 5.08 UJ 1.4 J8
SOOE7-018-1J0 135-203 12120/2003 13. I] 5 12.3 4.93 UJ 0.537 B 4.93 OJ 0.493 UJ
SOO£7-018-190195·203 12120/2003 19·19.5 7.1 4.76 UJ 0.476 OJ 4.76 UJ 0.476 UJ
8DOE7-018-230235-203 12120/2003 23 - 23.5 8.1 4.63 UJ 0,463 UJ 4.63 UJ 0,463 UJ
800£7-018-240245-203 1212012003 24 - 24.S 19.6 5.03 UJ 0.608 B 503 UJ 0.503 lJJ
8ooE8-0184)00005-203 1/14/2004 0-0.5 204 -- _.- -- -
SOOES-0184)20040·203 1/1412004 2- 4 735 -- -_. -- -
SDGE8·018..()50055·203 1212212003 5 - 5.5 764 7.22 UJ 1.36 J8 7.22 OJ 0.724 B
SooH-O 18-1)80085-203 1212212003 8·8.5 13 4.72 UJ 2.09 J8 472UJ 0.472 UJ
SOOE8-018-120125-203 12/2212003 12 - 12.5 4.9 4.71 OJ 0.471 UJ 4.71 UJ 0.471 UJ
Soo£8-01 8-1301 35-203 12122/2003 13 - 13.5 17.9 4.82 OJ 3.11 J 4.82 UJ 0.482 UJ
SOO£8-01&-185 190-203 12122/2003 18.5 - 19 8.2 4.83 OJ 0.592 B 4.83 UJ 0.516 B
SDGE8·0! 8·20521 0-203 1212212003 20.5·21 6.4 4.69 UJ 0.469 UJ 4.69 UJ 0.469 OJ
edimem Todcitv Comnns;le ImnleS:
X800 I-RF I-COODO 5-1 03 1111012003 0-0.5 202 &.62 UJ 0.89J 8.62 UJ 0.&62 UJ
XSODI-RFI-C00005·103 11/10/2003 0·0.5" 164 8.18 UJ 0.818 OJ 8.!8 UJ 0.818 J
XSOO1·RF2-COOO05-103 11/9/2003 0-0.5 137 ILl UJ 8.81 J 11.1 UJ III UJ
XSOOI-RF3-COOOOS-103 11/912003 0-0.5 228 &.62 UJ 4.12J 8.62 U1 1.4 J
XSOOC-100-COOOOS-103 11/9/2003 0-0.5 136 7.08 OJ 1.ItJ 7.08 UJ 0.742 J
XSOOD-I SO-COOOOS-l03 111812003 0-0.5 1.780 I 1.9 UI 48.8 J 11.9 UJ I.l9UJ
XSOI W-[ 7S-COOO05-103 11/812003 0-0.5 135 6.25 UJ 2.77 J 625 OJ 0625 UJ
XSOJE-050-COOO05-103 111912003 0-0.5 320 7.55 UJ 0.802 J 7.55 UJ 0.955 J-
XSIJE·IOQ-COOO05·103 1118/2003 0-0.5 234 6.86 UJ 2.57 J 6.86 UJ 0.686 OJ

NOles:
Chromium ....d hel<Avalent chromium analyses condueled by Columbi. Analytical Services, Inc. (Roell .. ter, New York).
Hex.avalent chromium analyses were conducted by TWo analytical methods (7196A and 7199)
following extrac~on by two methods (NJDEP and EPA).
• - The Mmple is a field duplicate.
J w The associaled .. Iue is an estimated quantity.
R - The result is unuseable.
U = The sample was analyzed for, but was not detected above the sample quantitation or detection limit.
UJ - The sample was analyzed for, but was not detected. The associ.led quantit.hon or detection limil is an eslimale.
B = The parameter was delected in the Blank sample(sl.
BJ = The parameter was detected in the BI.nk s.mple(s). The associated value is an estim.red quantity
-- = Not Bnalyzed.

P .... ons Page 70f7 ENVIRON

TIERRA-B-014963
T~-t's
H, 1. Metlll Rl'YJn~ In StlflmmC
:':IUtll'j.,~'; ~4o!'~C:!!i·,!"J..!o"'Ji'-io:]
0.1.. IXplh ......
'mlnum
'itf.llpl'l'(!' fr~) fmlo\qj:l

~orI6l'l'OO.' Oa·03 9110 ]'HIJ 19,8


,rvI6l100,~ 00. fU 1~6oo
1Il G6!l l' 0.27 J )01'OJ III
J!l'UJ 11600 4110
IJ.
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ENVIltON

TIERRA-B-014965
Table 6
Acid Volatile Sulfide and Simulf.neously EUraeted Metals Results in Sedimenl
Study Area 7; .Jersey City, New Jersey

Cadmium- Copper- Lead.


Add VolatHe Mercury- Nickel· Zinc -
Field Sample ID Dale Depth Volatile
Sulfide Volatile Volatile Volatile Volatile
Sampled (feet) Volatile Ratio of
Componenl Component Componenl
(mg/kg) Component Component Component
(mg/kg) SEr"I/AYS'
I {mg/'Kg} (mg/kgj (mg/kg)
~IR("f~"·f'~-.('eS.. mple:!>:· I (mgl1<g) (mg/kg)
SDOO I-R FI-OOOO05-IOJ 1011612003 I

SooOI-RF2-000005-IOJ
0.0 - 0.5 424 J o 14 J 34.9 70.1 0.0053 R 3.6 J
I
1011612003 00·05 88.7 0.17
145 J I J 60.7 108
SDOOI-RfJ-00000S_103 1011612003 003 R 6.4 J 196 1.02
00-0.5 101 J 0.6 J
SD002-RF1-OOOO05-103 44.1 65.5 0.077 R 46 J
1011012003 00-0.5 89.9 0.78
361 J 015 J 42.2 91.8
Soo02-RF2-00000HOJ 1011612003 0.015 R 4.5 J 114 0.26
00 - 05 1940 J IJ
Soo02-RFJ-00000S-103 54.6 113 0.022 R 6.7 J
1011612003 0.0 - 05 591 J 201 0.08
3.6 J
W,tudy 111 173 PI .of
V.ol.fO K
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13.4 j

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268

I
Area 7 Samples; 038
I SDoa 1-~uu-uVUU(J)-1(.l3
SDOO4-l0Q·000005_203
11/2512003
1112212003 00 - 05
328
57.6
1 033 J
0.18 J
1 23.3
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I 1.29
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00·0.5 225 0.78 67.6 J
S DOOA-02 5-00000 5- 203 132 J 0.037 50.9 J 332 J
11/2]12003 00 - 0.5 1230 1.09
096 J 54.2 J 140 J Oe}18 B
SDODA-025·000005·203 1112312003 25. I J 367 J 020
0.0-0.5' 435 l.lJ 71.7 J
SDOOA-050·00000S.203 122 J 0.054 B 11.8 J J09 J
11/2312003 00 - 0.5 1140 0.49
1.3 J 49.7 J 922 J 0064 I:l
SDOOA-100-000005-203 1112412003 57J 151 J 010
0.0·05 368 1.8 83.1
5 DOOA-200-00000 5-203 143 0.081 7.5 171
121112003 00 - 0.5 3400 0.41
4.3 148 J 297 J 0.066
SDOOB~OO5~OOOOO5.203 i21iiZ003 0.0 - 0,5 II J 283 J 0.08
131 0,16 9,2 J
SOOO13-025·000005-203 11.8 J 0.036 2.5 J 38.6 J
121112003 0.0·0.5 164 0.8 J 0.20
38.6 J 72J 0.056 7.5 J
SDODB-025-00000 5.203 11125/2003 0.0 - 0.5' 118 J 0.57
80.9 0.43 J 24.1 J 43.8 J
5DOOB-050-000005-203 1112312003 0.15 5.1 J 77.1 J 0.74
0.0 - 0.5 456 0.43 J
5DODll-050-000005·203 9J 268 J 0.0056 B 9.8 J
1112312003 00 - 0.5· 207 267 J 0.40
1.4 J 61.3 J 90.1 J
SO008· 100·000005.203 1112212003 0.04 B 12 J 265 J 0.88
00·0.5 359 0.54 J
5D008200-000005·203 35 J 34.8 J 0.18 10.9
1112212003 0.0·05 68.5 J 0.17
10.2 0.46 J 23.4 J
SooOC.005-000005-203 46.5 J 0.0059 1.6 60.~ J
' 111f\J~1\"''l'
lIJJ..V· .. VVJ 0.0 - 0.5 389 j 4.88
0.8 J 45.1 J 71.8 J
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0.0- 0.5 524 J 0.14 J 60.9
SDOOC·025-00000 5-203 761 0.24 R 11.6 J 107
1111912003 0.0 - 0.5 1750 J 0.19
1.2 J 62.5 J 85,9 J 0.097
5OO0C·050-000005-203 1111912003 9.4 J 129 J 0.06
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5OO0C-IOO·000005·103 1011612003 0.0 -0.5 105 J 0.09
352 J 0.12 J 43.1 54.2
5OODC.100-000005-103 0,3 R 7.7 J 79.1 0.21
1011612003 0.0·0.5" 365 J 0.12 J 43.3 54.2 0.33 R 7.6 J
SOOOC·100-000005-203 77.6
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0.20
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208 J 0.64 36.8 46.2 J
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0.024 J 3.1 J 77.6 J 0.32
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0.17
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0.0019 12.3 J
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l 0.(0)8 R 14.J J
l 219
375
0.11
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PI\P~ONS
Pa~e lof2
ENVIRON
"

TIERRA-B-014966
Table 6
Acid Volatile Sulfide and Simultaneously Estracleu Metals Results in Sediment
Study Area 7; Jersey City, Ne" Jersey

Cadmium- Copper- Lead. Mereury- Nickel.


Acid Volatile nnc -
Ficl<J Sample lD Date Depth Volatile Volatile
Sulfide Volatile Yolatile Volatile Vol.tile Ratio of
Sampled (feet) Component Component
(m g!k g) Component Component Component Component SEiWAYS'
(mglkg) (mglkg) (mglkg) (mglkg) (mglkg) (mglkg)
50021':·025·000005·203 1112112003 0.0·05 3610 J 2.2 203 178 J 0.12 J 20.3 J 431 J
SD02E·075·000005·103 0.10
10/16/2003 0.0·0.5 408 J 0.26 J 76.5 121 0.003 R 11.7 J 170 036
SD02 E·07 5-00000 5- 203 1112012003 0.0·0.5 J
1150 0.83 J 43.6 J 73.2 J 0.04 6.8 J 105 J
SD02 W ·200·000005.20.\ 008
121212003 0.0-0.5 149 J 0.028 J 2.9 17.1 0023 l.IJ 102 065
S OOJ £·025 -00000 5 -203 11116/2003 0.0-0.5 246 J D.13 28.8 55 J 0.021 B &.1 J 78.6 J
5DO.1£·050·000005-103 D.27
1011612003 0.0-0.5 189 J 0.3 J 59.4 74 0.0019 R 9.4 J 108 0.53
SDO.1W. [50-000005.103 10/1612003 0.0·0.5 21.8 J 0.04 J 9 13 0.0015 R 1.8 J
SDOJW -200·000005-203 22.2 0.85
1112412003 00·0.5 106 U 0.29 39.7 54 0.0&9 4 71.6 NA
SDI3£·005·000005-203 1111712003 0.0·0.5 2870 J 0.53 87.5 158 J 0041 B 86.2 J 253 J 0.08
SO 131':·050-000005.203 11/1712003 00-0.5 53.6 1.& 145 176 1.2 136 260 J 4.40
SD I.1E·100·000005-103 1011612003 0.0·0.5 63.4 J 0.19 J 36.7 48.7 0.001& R 4.6 J 70.8 100
SOI,£·100·000005·203 1111812003 00 - 05 175 1.3 83.2 139 0.0059 B 6.8 171 J 0.&1
SD IJ W ·200-000005.203 1212/2003 00·05 21.5 0.07 J 6.3 11.5 0021 2 J 21.1 0.76
Sediment Toxic;ty Co",nosil. Sa",nl .. ;
XSOOI·RFJ ·COOO05-103 1111012003 00·0.5 1190 0.87 76 101 0.084 12.6 165 0.12
XSOD I-RE I·COOO05·103 11110/200, 0.0 - 0 5' 606 0.92 79 105 0.097 13.1 171 0.24
XSOOI·RF2·COOO05·103 1119/2003 0.0·0.5 lllO 1.8 84.1 106 0.29 15.2 207 0.15
XSOOI· RF3·C00005· 103 1119/2003 0.0·0.5 676 18 77.2 92.8 039 14.2 163 0.21
XSOOC· 1OO-COOOO5-1 03 1119/2003 00·0.5 488 0.59 43.3 50 0.5 10.3 80.4 0.15
XSOOD· 150·COOO05.103 1118/2003 0.0·0.5 3470 5.4 499 368 5.9 20.7 608 0.1 &
XSO IW·175-COOO05.103 1118/2003 00-0.5 512 0.51 37.9 47.9 0.69 6.5 67.4 0.12
XS03E·050·COOOO5-103 111912003 0.0 - 0.5 660 0.99 86.6 97.8 0.27 11.6 155 0.21
XSUE·IOO·COOOO5·103 111812003 00- 0 5 632 0.85 68.& 82.8 0.33 98 129 0.1&

Notes:
• ~ The sample is a field duplicate.

I ; SEMIA VS is the <urn oflhe concenlrations of each meMI in urnole/g reported for a given 'ample, diVided by the acid volatile sulfide concentration in umolclg.
J ~ The associated value is an estimated quantity.
R ~ Th' result is "nus.,ble.
U ~ The Sam pic was analyzed for, but was not detected above the sample quantilalion or detection limi!.
U.I ~ The sample was analyzed for. but was nnt detected. The associated quantitatlon or detection limit is an estimate.
B ~ The paramoter WBs delceted in the Blank sample(s)
BJ ~ The parnmeler was detected in the Blank s.mplc(s). The associated value is all estimated quanlity.
NA= The r.atio could not be cBlculated because one or more of Ihe component concentrations was: not delected.

PAR;>ONS
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OOIJ.U O.OllU D.QI3 U CJ.-QII O_IJo IJ
0.01) U 0.019 '0019 GDllU 0,01] U
SDIJ,E-o~Q..otlOOO5·10) WI7/200~ o {). 0 ~ 00l1U OOIHl OOI:2'U QOUU 0014 U
OOIJ. U O.OlJ U OOJ)U 0.013 lJ C),on u o OJ) U i 00l) U 0013 U I OJ)IJ.U Don u
0023 OI3U
SDIJ.E·IOO.ooooo'·IO) 10'1612(0) 00· 0 ~ 0009:2 U o 0092U
OOllU 012 U 0012 U 0.011 U o,ouu QJH2 U
QOI} U om -DlJU
o,oo~n u 0,0091 U 0.0092 U 0.0092 U 0001 U
0012 tJ O.Cll:! U 0012 tJ 0012 L) , 00]1 LJ 0.011 U
SD I}E·I 00-00000' .:I'OJ llfl8!2'OOj 00· OJ· 'O'OIJU OOlltJ
00092 U ('J.~U 0,009'2 U O,Oonu 0.009"~U oronu
(lQI1U OlJ~2 1I 0,11 U
O,Ol) U 0.013 tJ I)O))U 00092 U 0.0092 U ooonl/
SDI 3[·100.01 ~()20·:l0) lIfUlf1001 U·!'O O,Ol;~ U
0013 U o I~U 0.01) U D,DI) U o.OUt; o Oil I! O.OHU
0009';1 U o.oonu OOO~2 U {J,onu
OOIlU 001) U 00'13 U 0011 U o Oil II ODI) U 0,01) t.r
DOIJ U O,OBU cUJU O.DO U O.ODU oouo
.
SDI 3E·IOO.Ql~O"'Q·20) 1If18f:lOO) ~ , . ·.0 O_(l-IJU O[)OlJ 000013U CIo.(JoI)l) OJJU
0_016 U OO~~U 0,016 U O"OI3U 001) IJ
0013 U
SOl )W·JOO-OOOOO~.lCJ. 12rlfJOOl 000, O.S 00079 U O0;l19u
OoQI6u 0,016 U 0.013 o 16-U O.OI!lU 00-16 U o-,OI6U o OI~U 00115 U 0016 U ; 0016U
I OGIJ U (01) U OOl)lI 001) U OO111' ouu
00.0079 U 0.0079 U 0.0079 U ()'016U
0-,0009 U O.019lJ a,ems U 0OO19U 0.00 U O.OO'9U 0,001'9 U 0.0019 U G.OO"'9U
O,016U 0016 U OOl6U OOlti U 016 U
XSOO'·P-.F! ·C(!IJ'J(J'~IC31 llll'Of2lAJ)
o-0CI19u 0OO1'j V o 0079"U 0007';-(1 o 00"19 II 001'Qu

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XSOO~ ·RF'I.("OOOJ.\·IO,1 11.'10I1«l~ 000 . 0 ~~ (;l)J4 U
o.or-4 " (),OUU OUU O.-QUU OOiHI o.olnJ .04)loIl,l
001-4 U OOI-4LJ OOI.U 0014 U o-ouu OOI<U OO"U OOIHJ 0.-01. U OOl4U
:\SOOI.Rn·CO(J:)OS·IO) If/9r.;lOO) o (J - 0 ~ O('Jl~U
Ol~ U Om .. u O.-ol~ U 0014 U -0.01" U ! 0015 J 0,014 U
001. U o Ol~ LJ oQI~ U 0101' II
OOl9U 'OOI9U OOl9U OOl9U 0019U Ol9U OQI9U
-0014 U OJJHU OOl.U a.014 U 001. LJ o O~ ,
X5001·R.FJ·CaooO,S,IO) IllW1(0) 00· O.S OOl" tJ -0021
OOl9U O(lI'9U -o,OI'U 'I O,OI9V . 0019 U o loll'
0.0.411 00'''" 00101 U Oouu O(ll9u no,'9U COl9U
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001 U 001 U Ol}ll' OIU
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B ""The p-tnmor1rr wu dtl'h'('(td in Ik.. 8h/J( r.'Tlp-.-(~)
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i:;N\';

TIERRA-B-014975
Table 10
Organa!in. Results in Sedimenl
Sludy A"ea 7; Jersey City, New Jersey

OMe Depth Oibutylt;n Monobulylli:n Tetrabutyltiol TI'ibulylli"


Field Sample ID
Sampled (feel) (l1gfkg) (f.lgfkg) (f.lg/kg) (f.lglkg)
~
IIReference Sam Dies:
SOOOI-RFI-000005-103 1011611003 00 - 0.5 24 U 19 U 3.2 V 28 U
SOOO l-RF2-000oo5-103 10/1612003 0.0 - 0.5 12 J 29U 5U 14 J
SDool-RF3-000005-103 1011612003 00- 0.5 II] 18 U 31 U 8.4 J
SOO02-RFI-000005-103 10/16/2003 00 - 0.5 28 U 2.1 U 3.6U 3.2 U
SDOO2-RF2·oo0005-103 10/16/2003 0.0- 0.5 221 2.8 U 4.8U 20 J
SDOO2-RF3-OO0005·103 10/16/2003 00 - 0.5 19 2.2 U 3.8 U II

IL
SlUdv Area 7 Samnles:
SDOOI-2oo-DOOO05-203 1 11/25/2003 1 0.0- 0.5 I 1.7U 1 IJU
-/ 2.2 U r 1.9 U
SDOO4-200-oooo05-203 1112212003 0.0- 0.5 1.5 U 1.2 U 2U I.8U
SDD04-200-D15020-203 11/2212003 1.5 - 2.0 8.8 1.3 UJ 2.2 UJ 2.8
SDD04-200-035040-203 11/22/2003 3.5 - 4.0 2.4 U 1.9U 3.2 U 28 U
SDOOA·005-0oo00S·203 121112003 0.0·0.5 2.9 J IJU 2.2 U 1.9U
SDOOA-025-000ooS-203 11/2312003 0.0 - 0.5 4.6 J J.5J 2.6 J 48J
SDOOA-025·0()()()OS-203 !lI2312003 0.0 - 0.5" 4.8J 1.5J 2.6 J 2.8 J
SDOOA·050-o00005·203 1112312003 0.0 - 0.5 7.lJ 2J 3.4 J 9.2 J
SOOOA-050-D 15020-203 11/23/2003 1.5 - 2.0 3J 2.3 J 3.9 J 3.4 J
SOOOA-050-o35040-203 11123/2003 3.5 - 4.0 2.3 J 1.8 J 3J 2.6 J
SOOOA·loo-OOOOO5-203 11/24/2003 0.0 - 0.5 27 U 2.1 UJ 3.5 U 3.1 U
SooOA-2oo-oo0005-203 121112003 0.0 - 0.5 3.4 U 26U 4.5 U 3.9 U
SDOOB-005-ooooo5-;W3 121112003 0.0 - 0.5 I.5U I.lV 1.9 U 1.7 V
5OO0B-025-ooooo5-203 11/2512003 0.0 - 0.5 2.3 1.3 V 22V 1.9 U
SooOB-025-oo0005·203 11/2512003 0.0·0.5" 1.6 U 12U 2.1 U 1.8 U
SoooB-025-015020-203 11/2512003 L5 - 2.0 1.9 V 1.5 U 2.5 U 22U
SooOB-025-035040-203 11/25/2003 3.5 - 4.0 2.2 U I.7U 2.9U 25 U
5OO0B-050-0oo005-203 11/23/2003 0.0 - 0.5 2.4 J I.2J 5.4 J 1.9 ]
SooD8-05O-OO0005-203 11/23/2003 0.0·0.5· 2J 1.6 J 26J 2.3 J
Soo08-100-ooooo5-203 11/2212003 0.0 - 0.5 1.9 J 1.3 UJ 2.3 UJ 2 UJ
50008-100-015020-203 1 [/2212003 1.5 - 2.0 1.6 V 1.2U 2U 1.8U
SOooB-200-000oo5-203 11/22/2003 0.0 - 0.5 I.7U UU 2.2 U 1.9 U
I
S OOOC-005-000005-203 11120/2003 0.0·0.5 4J 2.6 U 4.4 U 5J
I
SOOOC-005-D15020-203 11/20/2003 15 - 2.0 3.2 U 2.4 U 4.1 V 3.6U
SDOOC-005-035040-203 1112012003 3.5 - 4.0 4J 2.4 U 4.1 U
, 3.7 U
SDOOC-025-OO0005-103 101 l612003 0.0 - 0.5 5.8 J 2.5 V 4.2U 6.4 J
SDOOC·025-00ooo5·203 !111912003 0.0·0.5 49J 2.9U 4.9U 6.6
I
SOOOC-050-OO0005-203 11119/2003 00 -0.5 2.5 U 2U 3.3 U 2.9U
S DOOC-I 00-000005-103 10116/2003 0.0 - 0.5 3.9 J 1.8U 3.1 U 5.7 J
SDODC- too-000005-103 1011612003 0.0 - 0.5· 4.9 J 1.8 U 31 U 5J
500OC-IOO-000005-203 11/21/2003 0.0 - 0.5 2UJ I5UJ 2.6 UJ 2.3 UJ
SDODC· 100-000005·203 11/2112003 0.0 - 0.5· 2U ISU 2.6 U 2.3 U
5OOOC·200-000005-203 1112112003 00-0.5 1.9 U 15 U 2.5 V 2.2 U
80000-050-000005-103
50000-150-000005-103
1011612003
1011612003
00·
0.0-
05
05
I3J
39 U
16 U
3U
2.8 U
5.1 U ,- 41.~~ I
I
SD02E-025-000005-203 1112112003 0.0 - 0.5 3.1 UJ 2.4 UJ 4 VJ 3.8J
S002E-075-oo0oo5-103 10/16/2003 0.0 - 0.5 14 J 2.4 U 4U 12 J
'-
Parsons Page:: I of2 ENVIRON

TIERRA-B-014976
Table 10
Organotins Results ;n Sediment
Study Area 7; Jersey City. New Jersey

Date Depth Dib"tylt!n Monobutyltin Tetrabutyltin Tribulyltin


field Sample m
Sampled (feel) ("gtkg) (I'g/kg) (f!gfkg) ("glkg)

SD02E-075-000oo5-203 1112012003 0.0 - 0.5 31 U 24 U 4U 5.1 J


S0021::-075-0 15020-203 I 1/2012003 ]5-2.0 3.2 U 2.4 U 4.1 U 37U
S001E-075-035040-203 1112012003 3.5 - 40 2.7 U 2.1 U 3.5 U 3.1 U
S002W -200-000005-203 12/212003 0.0 -0.5 1.6U I.3U 22 U 1.9U
SD02W -200-015020-203 121212003 1.5 - 20 1.8 U 1.4 U 2.4 U 2.1 U
SD02W-200-035040-203 12/2/2003 3.5 - 4.0 16 U 13U 2.1 U l.9U
S003£-025-000oo5-203 1111612003 0.0·0.5 1.8 U 1.4 U 2.4 U 2.1 U
S003£-025-015020-203 1112012003 1.5 - 2.0 2U 1.6U 26U 23 U
S003E-025-035040-203 IlJ2012003 3.5 - 4.0 2.6 U 2U 3.5 U 3U
S003£·050-000OO5-103 1011612003 0.0·0.5 4.7 J 16 U 26U 521
5OO3E-075-000oo5-203 1111712003 0.0 - 0.5 23 U 1.8U 3U 2.7U
5003£-075-015020·203 111171.2003 1.5 - 2.0 1.6 U I.2U 2.1 U 1.8 U
S003£-075-035040-203 11/]712003 3.5 - 4.0 I.5U 1.2U 2U 17U
S003W ·150-000005·103 10/16/2003 0.0 - 0.5 1.6 U 1.2 U 2.1 U 1.8 U
S003W -200-000005-203 11/24/2003 0.0 - 0.5 17U I.3UJ 2.2 U 2U
SD03W -200-015020-203 11/24/2003 1.5 - 2.0 1.6 U I.2UJ 2.1 U 1.8 U
SD03W ·200-035040· 203 1112412003 3.5 - 4.0 J7U 1.3UJ 2.2 U 1.9 U
SD13E-005-OQ0005·203 1111712003 0.0- 0.5 5.6 J 1.9UJ 33 UJ 6.4 J
SOI3£-005·015020-203 IlIl7/2003 1.5 - 2.0 2.5 U 1.9 U 3.3U 2.9 U
SO 13£·005-035040-203 1l/1712oo3 3.5 - 4.0 2.6 U 2U 3.4 U 3U
SO 13E-050-000oo5-203 11/1712003 00-05 2.6 U 2U 3.5 U 3.1 U
5DI3E-100·000005-103 1011612003 00·0.5 1.9 U 1.4 U 2.5 U 2.2 U
SDl3E-100--OOO005-203 11118/2003 0.0- 0.5 2.5 U L9U 3.3 U 2.9 U
SDl3E-100-015020-203 1111812003 1.5 - 2.0 2.4 U 1.8 U 3.1 U 2.7U
SDI3E-IOO..(J35040-203 11118/2003 3.5 - 4.0 2.9 U 2.2 U 3.8 U 3.3 U
SD13W-200-000005-203 121212003 00-0.5 1.6 U I.2U 2U I8U
Sedim~nl TOlicilv Comn<lsite Samples:
X500I-RFI-COOOO5-103 11/10/2003 0.0 - 05 2.8 U 2.2U 3.7U 3.3 U
XSODl-RfI-COoo05-103 11/1012003 0.0 - 0.5· 2.8 U 2.1 U 3.6 U 32U
XSOOI·RF2-COOOO5-103 11/9/2003 0.0- 0.5 3.5 U 2.7U 4.6U 5.4
XSOO1-RF3-COOOO5-103 11/912003 0.0 - 0.5 4.5 2U 3.5 U 3.9
XSOOC-I 00·COOO05- 103 11/9/2003 0.0 - 0.5 2.3 U 18 U 3U 2.7U
XSOOD- 15O-COOO05-103 111812003 0.0 - 0.5 39 U 3U 52 U 4.5 U
XSO I W· 175-COOO05-103 11/812003 0.0- O.S 2U 1.5 U 2.6U 2.3 U
XS03E-050-COOOO5·103 1119/2003 0.0- 0.5 2.5 U 1.9 U 3JU 3.3
XSI3E-IOO·COOOO5-103 11/812003 0.0- 0.5 2.2 U I7U 2.9U 26 U

Notes:
• = The sample is a field duplicate.
J = The associated value is an estimated quantity.
R = The result is unuseable.
U = The sample was analyzed for, but was not detected above the sample quantilation or detection limit.
VJ ~ The sample was analyzed for, but was nol detected. The associated quantitation or detection limit is an estimate.
B = The parameter was detected in the Blank .ample(s).
BJ = The parameter was detected in the Blank sample(s). The associated value is an estimated quantity.

Parsons Page 20f2 ENVIRON

TIERRA-B-014977
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Table 1~
Other Parameters Result. in Sediment
Study Area 1; Jersey City, New Jersey

Bulk Percen.· TotalOrgank


Date Depth Ammoni:rI pH
Field Sample ID Densily Solids Carbon
Sam (lIed (feet) (mg/kg) (pH Units)
(glcm') (%J (mglkg)
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--- "'~
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rl1r --.

---
---
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--
IIStudy Area 1Samples;
SOOO 1-200-000005·203 11/2512003 0.0 - 0.5 24.5 1.68
SooO 1·200-D05010·203 [ 1/2512003 05 - 1.0 --- 1.17 _.7& 8.26 J
8.39 J
15,400
15,300
SOOO 1-200-il 15020·203 11125/2003 15 - 2.0 .- 1.23 -. 7.931 59,400
SDOO 1-200-025030-203 11I25/2003 2.5 - 3.0 -_. 083 ._- 7.42J 53.100
SOOO 1-200-035040-203 . - 1112512003 3.5 - 4.0 -- --- ... 756J 23,600
Soo04-200·0ooo05·203 11/22/2003 0.0 - 0.5 8U 1.79 85.3 7.93 2,410
S0004-200·0050 10-203 1112212003 0.5· 1.0 ._- 1.73 _. 8.55 4.060
SOOO4-200-0 15020-203 1112212003 1.5 • 2.0 -_. 1.48 76 8.51 11,900
SD004·200·025030·203 1112212003 2.5 - 3.0 - 0.8 .-. 751 5J,200
SOO04-200-035040-203 1112212003 3.5 -4.0 --- 068 53.1 7.8 49.600
SDOOA-005·00oo05-203 W1I2003 0.0-0.5 52.4 138 78.2 8.56 J 17.500 ,
SOOOA-il05-il0501O-203 121112003 0.5 - 1.0 --- 0.96 --- 887 J 38.600
SOOOA-005-0 15020·203 121112003 1.5 - 2.0 --- 1.38 .- , 8.96 J 107.000
SDOOA-005·025030·203 121112003 2.5 - 3.0 - 0.67 ... 8.89 J 64,&00
S DOOA-005 ..{}J 5040·203 1211/2003 3.5 - 4.0 ... --- .... 914 J 65.800
S DOOA-025-DOOOO5-203 1112312003 0.0 .. 0.5 45 1.15 64.9 8.02 J 17,700
SooDA -025-ilOOO05·203 1112312003 0.0·0.5' 31.4 --- 65 &27J 21.&00
SDOOA·025-D050 10·203 . 1112312003 0,5 - 1.0 --. 0.96 -- 8.52 J 46,200
SDOOA-il25-il 15020·203 111231200J 1.5 - 2.0 --
i
0.5 ..- 8.15 J 160.000
SDOOA·025-<J25030·203 11123.'200J 2.5·3.0 - 0.73 -. 7.51 J 43.100
8DOOA-025-035040·203 IJJ23f2oo3 35 -4.0 ... 0_75 --- 7.65 J 38,700
SDOOA-il50-OOOOO5-203 11123/2003 0.0·05 39.5 0.9 502 &.13 J 24.400
SDOOA-{)50-D050 10-203 11/2312003 0.5 - 1.0 ---
_ ..
061 -- 1122 J 33.900
SDOOA-il50-0 15020·203 1112312003 1.5 - 2.0 0.6 43.6 7.97 J 62,700
SooOA·050-025030·203 1112312003 25·3.0 --- 084 --- 7.53 J 46,500
SooOA-05Q..035040-203 1I1231200J 35 -4.0 .-- 0.86 57 7.78 J 33,100
SOOOA-100..()()0005-203 [ !/2412003 00 - 0.5 69 0.78 47.7 7.97 J 75.\00
SDOOA-IOO-005010-203 11124/2003 0.5 - 10 --- 0.74 --- 8.05 J 77,400
SDOOA-IOO-O I5020-203 11124(2003 1.5 • 2.0 --- 0.76 -- 7.3 J 42.700
SDOOA-100-{)25030-203 1112412003 2.5·3.0 ... 081 --- 7.72 J 25.700
SooOA-IOO-03S040-203 11124/2003 35.4.0 -- 0.73 --- 7.36 J 49.300
SooOA-200-00000S·203 121112003 0.0·0.5 80.4 0.63 37.7 7.14J 74,900
SDOOA·200·005010·203 12/112003 0.5 - 1.0 --- 0.87 --- 8.16J 54,500
SDOOA·200·0 15020·203 121112003 1.5-2.0 ..- 0,73 _ .. 7.7 J 30,300
SOOOA-2oo-025030-203 121112003 2.5 - 3.0 -- 0.&9 ._- 8.04 J 26.200
SooOA-200-il35040·203 1211/2003 3.5 - 4.0 -- 093 -.. 7.85 J 33,000
S LiOO I:J-005-DOoOO5- 203 121112003 0.0·0.5 83.1 188 88.7 &.53 J 8,270
SDOOB-005..()()50 10-203 121112003 0.5·1.0 ... 172 -_. 8.85 J 9.670
80008·005-015020·203 12/112003 1.5 ·2.0 --- 1.55 ._. 8.9 J 11,900

Parsons Page I of 4 ENVIRON

TIERRA·B·014986
Table I~
Other Param"ers Results in Sediment
Study Area 7; Jersey City, New Jersey

Bulk Percent Total arg.nk


D.le Depth Ammonia pH
Field S.rnple ID Densiry' Solids Carbon
Sampled (reel) (mglkg) J (pH Units)
(%) (mg/kg)
~
SOO08-005-025030-203 12/112003 2.5 - 3.0 --- 1)6 .-. 8,03 J 28,600
50008-005-035040-203 12/1/2003 3.5 - 40 -.- 083 --- 7.99 J 33,900
30008-025-000005-203 12/112003 0.0·0,5 11.1 l65 77.7 B.5 J 13,100
SOO08-025-000005-203 1112512003 0,0 - 0.5' 20.7 ... 81.1 8.62 J 10,300
5D008-o25-0050 10-203 121112003 0,5 - 1.0 --- 1.4 -- 8.3 J 19,000
30008-025-015020-203 1211/2003 1,5-2.0 -- 09 68.4 7.72 J 29,200
5000B-025-o25030-203 12/1/2003 2.5 - 3.0 --- 1,53 --- 7.38 J 61.800
5OO0B-025-035040-203 121112003 3.5 - 4,0 --- 1.52 58.8 7.433 30.600
S0008-o50-OO0005·203 11/2312003 0.0·0.5 455 149 80.3 8.34 J 22,400
Soo08-050-000005-203 11/23/2003 0.0 - 0.5' 25,3 ... 64.3 8.121 27,000
S0008-o50-o050 10-203 11/2312003 0,5 - 1.0 --- 0.98 --- 861 J 25.700
SooOB-050-0 15020-203 1112312003 1.5·2.0 .-- 0.83 -_. 7,67 J 36,000
SooOB-050-o25030-203 1112312003 2.5 - 3.0 -.. 1.69 -_. 8.43J 7,320
SOO08·050-035040-203 11123/2003 3.5 - 4.0 --- 1.71 _.- 8.17 J 7,630
SoooB-1OO-OOOOO5-203 1l/2212003 0,0 - 0.5 10.7 1.28 74.9 7.92 10,400
SooOB-loo-OOOO05-203 1112212003 0.0·0.5" 12.9 --- ..- 7,56 8.530
snoOB-1 00-0050 10-203 1112212003 0.5 - 1.0 -.- 1.31 --- 7.93 34,200
SooOB-100-015020-203 1112212003 1.5 - 2.0 -.' 1.71 83 8.05 3,260
SoooB·lOO-o2503O-203 1112212003 25 - 3.0 --- 1.76 --- 8.41 637
S0008-IOO-o35040-203 1112212003 35 - 4.0 -- 1.66 --- 8.63 593
S0008-200-OOOO05-203 1112212003 0.0 - 05 72 1.35 78 ..5 ._, 3,770
SDOOB·200-o05010-203 1112212003 0.5·1.0 --- o.n _. --- 30.800
S0008-200-0 15020-203 1112212003 1.5 - 2,0 --- 1.29 --- --- 30.900
SOOOB- 200-025030- 203 1112212003 2.5 - 3.0 -. 1.13 --- -.. 41.000
SooOB-2oo-035040-203 1112212003 3.5 - 4.0 --- I.ll --- --. 26.000
SOOOC-005-000005-203 1112012003 0.0 - 05 ! 134 0.52 39.1 7,99 J 34,500
_ ..
SOOOC-OOS-0050 10·203
SDOOC-005-o 15020-203
1112012003 0.5 - 1.0 0.48 --- 8.3 J 38.000
11/2012003 1..5·2.0 --- 052 40,7 8.12 J 37,900
SDOOC-005-o25030-203 1112012003
;
2.5 - 3.0 ._- 0.5 --- 7.92 J 45,300
SOOOC-005-035040·203 1lI2012003 3.5 - 4.0 --- 059 41.4 7.98J 37,700
SOOOC-<l25-000005-103 10/1612003 0.0 - 0.5 ---
31.3 39.5 798j ---
SDOOC-025-o00005-203 11/[912003 0.0 -0,5 113 0.5 35.6 7.65 39,400
SDOOC·025·005010·203 11/[9/2003 0.5 - 1.0 _.- 0.53 --- 8.34 J 39,500
SDOOC-025-o 15020-203 I ilI912003 15 - 2.0 --- 0.54 --- 7.9J 38,800
SDOOC-025-o25030·203 llfl9J2oo3 2.5 - 3.0 -- 0.59 --- 7.92J 35,300
SDOOC-025-o35040-203 11/1912003 35 - 4.0 --- 0.79 --- 7.67 J 38.800
SooOC-O 50-000005-203 1111912003 0.0 - 0.5 63.8 0.55 50.6 8 15 J 40,300
SOOOC-050-00501O-203 11119/2003 0,5 - 1.0 --- 0.55 --- 8.12 J 33,200
SOOOC-O.50-O 15020-203 11/19/2003 15-2.0 --- 0.63 --- 8.44 J 29.300
SDOOC-050-o25030-203 1111912003 2.5 - 3.0 --- 0,81 --- 8.423 24,200
SDOOC-050-035040-203 1111912003 3,5 - 4.0 --- 0.95 --- 8,17 J 63.100
SDOOC-l00-000005·103 1011612003 0.0 - 05 16.4 --- 54.9 7,99 J --
SooDe-1 00-000005-1 03 1011612003 0,0 - 0.5" 16.9 ..- 53.7 7.77 j ---
SooOC-loo-oOOOO5-203 11/2112003 0.0 - 0.5 40.7 103 656 8.33 J 25,300
SooDC-lOO-oOOOO5·203 11/2112003 0.0 - 0.5" 53.3 --- 65.3 8.21 J 26,600
SooOC-lOo-0050 10-203 11/2112003 0.5 - 1.0 --- 1.16 --- 801 J 41,400
soooe-I 00-0 15020-203 11/2112003 1.5 - 2.0 --- 106 --- 831 J 31,700

Parsons Page 2 of 4 ENVIRON

TIERRA-B-014987
Table 1-1
Other Parameters Results in S"diment
Study Area i; Jersey City, New Jersey

Bulk Percent Tot.1 Org.nic


Date D"plh Ammonia pH
Field Sampl" ID Oensity SolidS Carbon
Sampled (reel) (mg/kg) (pH Units)
(g/cm') (%) (mgll<g)
-
SooOC-IOO-025030-203 11/2112003 2.5 - 3.0 ._. 0.74 ..- 7.97 J 32.100
SDOOC·100·035040-203 Ill2l/2003 3.5 - 4.0 ... 0.72 --- 7.n J 68.800
SDOOC-200-000005·203 11/2112003 0.0- 0.5 22.7 124 67.8 8.62 J 6.100
SooOC-200-OO50 10-203 11/2112003 0.5 - 1.0 ... 1.68 ... 8.71 J 13.600
SDOOC-200-o 15020·203 1112112003 1.5·2.0 --- 0.61 --- 8.2 J 10,500
SDOOC-200-o25030-203 11/2112003 2.5 - 3.0 --- 061 --- 7.75 J 71.900
SooOC-200-o35040-203. 1lI21/2003 35 - 4.0 - 0.65 --- 791 J ;;4.700
SOOOO-050-OOOO05-103 10/16/2003 0.0 - 0.5 10.1 --- 61.3 1.83 J ---
SoooO-150-OOOOO5·103 10/1612003 0.0·0.5 40.1 --- 33 132 J ...
SD02E-025-000005-203 11/2 W003 0.0 - 0.5 64.7 0.54 42.4 8.5 J 35.100
5OO2E-025-00501O-203 11/2[12003 0.5· 10 --- 0.61 --. 8.58 J 33.300
5OO2E-025·0 15020-203 11/2112003 L5·2.0 --. 0.9 --- 851 J 25.400
S002E-025-025030-203 11/2112003 2.5 - 3.0 --- 086 ... 1.93 J 28,100
S002E-025-o35040-203 1112112003 3.5 ·4.0 ._- 0.76 _.- 1.88 J 26,900
5OO2E-075-oo0005-103 1011612003 0.0 -0.5 29 '-- 41.6 7.78 J ...
SD02E-075-oooo05-203 1112012003 0.0·0.5 173 0.56 41.8 8.07 J 32,900
S002E-075-0050 10·203 11120/2003 0.5 - 1.0 --- 0.53 --- 8.311 34.300
S002E-075-o 15020·203 11/20/2003 1.5 • 2.0 --- 0.52 41.4 824 J 34,900
S002£-07 5-025030·203 11120/2003 2.5 - 3.0 -- 0.53 --- 81 35,200
SD02E-075-D35040~203 11/2012003 3.5 -4.0 ._- 0.6& 47.9 8.31 J 39,800
SD02W·200-000oo5~203 12/212003 0.0·0.5 8U 1.15 78.6 7.96 J 766
S002W·200-005010-203 12/212003 0.5·1.0 --- 1.53 --- 7.73 J 335
SD02W·200·0 15020-203 12/212003 1.5 ·2.0 ~.- 1.92 11 7.933 641
SD02W-200-o25030-203 1212/2003 2.5 - 3.0 --- -_. .- 8.31 J 4.000
S002W ·200·035040-203 1212/2003 3.5 -4,0 -- --- 79.4 8A5J 4.410
S003E-025-000oo5-203 1111612003 0.0 -0.5 35.3 1.23 70.9 883 J 19,300
S003E-Q25·0050 10-203 t 1I16/2003 0.5 - 1.0 --- 0.94 --- 8.68J 21,300
SD03E-Q25-0 [5020·203 J 111612003 1.5 • 2.0 --. 0,66 64.2 7.93 J
SOO3E-025-D25030·203 11/1612003 2.5 - 3.0 -- 069 _~ 8.19 J
31,400
31.100
S003 E-Q25-Q3 5040~203 11/18/2003 3.5·4.0 -- 0.87 49.3 ~- ._-
S003E-025-Q38043-203 11I1612003 3.8·43 --- -. ... 8.56J 2,950
S003E-050-OO0oo5-103 10/16/2003 0.0 - 0.5 8U -.. 64.5 7.76 J ._-
SD03E-075-oo0005-203 11/1712003 0.0 - 0.5 --- 0.77 55.8 8.07 J 30.800
_ ..
S003 E-075-0050 \0·203 11/17/2003 0.5·1.0 0.73 --- 8.12 J 29,800
SD03E-075-0 15020·203 1111712003 1.5 ·2.0 --- 0.81 81.9 8.55 J 4,010
SD03E-075·025030-203 1111712003 2.5 - 30 --- U ... 864 J 20.600
8oo3E-075-o35040-203 11/1712003 3.5·4.0 --- 1.2 86 857 J 1.290
SDuJW - i50-000005-1 03 10/16/2003 0.0 - 0.5 8U ..- 82 7.84 J ._-
S003W·200-000005-203 [ 112412003 00 ~ 0.5 8.5 1.8 75.5 8.09 J 9,670
S003W·2OO-005010-203 11/2412003 05 - 1.0 --- 1.99 --- 8.47 J 10,600
SD03W-200·0 15020·203 11/2412003 1.5 - 2.0 --- 1.8 82.1 &.52 J 711
SD03W -200-020025·203 11124/2003 2.0 ~ 2.5 .. - 1.74 -.- ._. _ ..
SD03W -200-025030-203
SD03W-2oo-D35040·203
11124/2003
1112412003
2.5·3.0
3.5 - 4.0
--
_.-
--- ._. 7.96 J 1.140
1.74 778 8.02 J 222
SD i3c·005-000u05-20J 1Ul7/2oo3 0,0·0.5 53.2 0.87 52.5 8.52J 69,900
SO 13E·005-OO50 10·203 1111712003 0.5 - 1.0 . --- 0.59 --. 8.77 J 74,900
80I3E·005-0 I 5020·203 1111712003 15 - 2.0 --- 0.71
--
51.6 831 J 82,600

Parsons Page 3 of 4 ENVIRON

TIERRA-B-014988
T.ble 14
Other Por.meters Results in Sedimenl
Srudy Area 7; Jersey City, New Jersey

Bulk Percent Total Organic


Oa,. Depth Ammonia pH
Field Sample 10 Density Solids Carhon
Sample<! (feel) (mg/1(g) (pH Units)
(glcm') (%) (mg/kg)

SD 13£-005-025030-203 Illl712003 2.5 - 3,0 --- 0.61 ..- 7881 29.200


SO I3E-005-035040-203 1111712003 3.5 - 4.0 --- 0.79 504 7.93 J 45.000
SO 13E-050-0oo005·203 11/1712003 0.0 - 0,5 108 0.72 48.7 8.22 J 27.600
SO 13£-050-005010-203 11/1712003 0.5 - 1,0 _ .. 0,93 ..- 8.571 21,300
SO 13E-050-0 15020-203 11117/2003 15-2.0 ._- 066 .- 7.491 44,800
SD 13£-050-025030-203 1111712003 2.5 - 3.0 -- 0.79 --- 7,85 J 23,300
SO 13E-050-035040-203 11117/2003 3.5 - 4.0 --- 0.75 --- 7.76 J 35.600
50I3E-loo-OOO005-103 1011612003 0.0 -0,5 7.3 --- 69 7.79 J _.-
SO 13E-100-oooo05·203 1111812003 0.0 -05 151 0.71 51.5 8A91 38.800
SD 13E-loo·005010-203 ll/1812003 0.5 - 1.0 -- 0.66 -- 7.98 1 28.800
SD 13E-loo-015020-203 11/1811003 1.5 - 2.0 --- 0.94 55.3 8,82 J 36,900
SD 13E-I 00-025030-203 I III 8/2003 2.5 - 3.0 --- 1.51 ... 7,72 J 35,200
SD 13E-100-035040-203 1111812003 3,5 - 4.0 _ .. 0.62 44.8 7.931 42.600
SD 13W -200·000005-203 121212003 0.0 - 0.5 8U 1.8 82,6 8.041 1,770
SO 13W -200-005010-103 1212/2003 0.5 - 1.0 --- 1.9 --- 8.191 3.180
SDIJW-200-o 15020-203 121212003 1.5 - 2.0 -- 1.87 -.- 7.591 415
SO IJW·200·025030-203 121212003 2.5·3.0 --- 1.87 - 7,681 411
SDI3W·2oo-035040-203 12/2/2003 3.5 - 4.0 --- --- ._- 7.311 396
Sediment Toxicitv Com""si'. Samnl •• :
XSOO I- RF (-COOO05-1 03 11/1012003 0.0·0.5 -- - .. 461 --- - ..
XSOD I-RF I-COOO05-103 11/J011003 0.0" 0.5* 42,9 -- 466 7.99 J -_.
XSOO I-RF2-COOOO5-103 Itjg/20G3 0.0 - 0.5 142 -- 36.6 7.24 J ---
XSOOI·RF3-Coo005-I03 11/912003 0.0 - 0 5 5&.3 --- 49 7.99 J ---
XSOOC· IOO·COOOO5-103 11/912003 0.0 - 0,5 25.9 -_. 56.5 8.12 J ---
XSOOO-150-COOOO5-103 11/&/2003 00-05 119 --- 32.8 6,671 ...
XSOIW-175.cOOO05-103 1118/2003 0.0 - 0.5 14.8 .- 66 6991 ...
XS03E-O 50-COO005-1 03 111911003 0.0 - 0.5 244 -- 52.5 8.L11 """

XS 13E-IOO.cOOOO5-103 11/8/2003 0.0 - 0.5 25.9 .- 575 8.13 J --.


Note.:
• = Tne sample is a field duplicate.
J r The associated value is an estimated quantity.
U = The sample was analyzed for. but was not detecled above the sample quantilation or detection limit.
--- = Not 8Jlalyzed,

Parsons Page 401'4 ENVIRON

TIERRA-B-014989
Table 15
Total Chromium Results in Pore Water
Study Aru 7; Jersey City, New Jersey

Depth Chromium Chromium


Field Sample ID Date Sompled (Filtered)
(feet) (Unfiltered)
(uglL) (uglL}
Reference SarnDles:
PWOO I· RF I·C00005-1 03 1111012003 0.0 -0.5 10.7 J 1300J
PWOO I-RF2·C00005· 103 J 11912003 0.0 - 0.5 I J.J J 69.8 J
PWODI-RF2-COOO05·103 1111012003 0.0-0.5* IO.3J 100 J
PWOOI-RF3-COOO05·103 11/9/2003 0.0 - 0.5 IOU 133 J
Studv A rea 7 Sam nres:
PWOOC'100-Coo005-103 11/9/2003 0.0 - 0.5 IOU III J
PWOOD-150·COOO05-103 11/8/2003 0.0-0.5 17.1 J 1710 J
PWOIW-175-COoo05-103 11/8/2003 0.0·0.5 IOU 10201
PW02E-075-COOO05-103 11/11/2003 00 - 0.5 IOU 9281
PW03E-050·COOO05-103 11/9/2003 0.0- 0.5 IOU 4491
PWI3E· loo-COOO05-103 11/8/2003 0.0- 0.5 11.2 J 438 J

Noles:

Total chromium in pore waler a".IFed by Columbia Analytical Services, Inc. (Rochester, New York)
using EPA Method 60108.
• = The s.~mple is a [leld duplicate.
J - The associated value is an estimated quantiI)'.
U - The sample was onalyzed for, but was not deteoted above the sample quantitation or deteClionlimit.

Parsons
Page 1 of 1
ENVIRON

TIERRA-B-014990
hbleU-
T "I.. ~~.h Rnulb in f'ut W:iler
51""")' Ar~ 'l"; J~ Clt,.. N_ Jcn~y

~·.n.dhl"'l

,.
{bell ..)
P'WOOI,RFI-COOOO5_10) lJflQ{2\JOJ 1)'0-"0,5 ISH.l 3.9U 6.!-lJ 2>,3 .2U 21ttXlr,;, S.(i U
PWOOI.RF2,COOOU'~IO)

FWOOI-'RF2·COOOO5.lOl
1I191'200J
11/10/200)
(I,g.oDS
00- 0'" '"
noli U
3.!iU
3,9U
B
, .:iiJ,1
"'.7
O.L U
0.1 U
U4,OOO'
1'7,000'
1 'U 1).'
PWQOt·Rfl·COOOOJ-IOl IlflJl'200) 00-0:5 ID ).'9u 12.3 I'. "U ~',OOO "
It
J6
'"
PWO(IC·JOO.cOOOOi.IOJ 1II'JI'lOOl 0.0 - (lJ. "
H
!ll
JI!i

PWOl'JD-I~O-eoooo~~10]' 1111!lO(I] OO-O~


UU 9.~ ".2

','
'2U O-BU IB6 •.-Ql)(l
.,
H·lJ 't,04U 'uU :m.ooo .2. O.lll

. .
IUU 4.3-1 U·U O.lJU 189,000
PWDIW·l15·COOOO3-_IOl 111811003 1),0.05
11.6U JI.2 D.6 O.oSU
71'U •. 611 ~.ooo 64' 0.1 U '"
.,,,
".,
-O,IU Il6,OOO JJ:V 1UIJ <iI,5U
PW"'2E...oU.cooo'Os·JO]
P'IJJOJ.E-Ojo..co'OO05.IOJ
11/1lf200J
11"1'200)
00· O~
0'0.0'5
IUU
J.9U
U
Jo.2
20'
)1,9
O,c5U
0.1 U
'lHIU

'Ul,J
1",000
114,iJOO
'HU .,u 463,000

'1·4.000 .,
1<1 O.J u
O.J U
"
H,G
,n
P\lII)E·t«l.<'oOOOOS_IOi 1'lInOO) 0,0 -OJ II (>1) 525 :s.s.'t D,1l U
'.7 ~u 2,%l} jIjJJl-OO
50' <:Il U
<J.tU ]70.000
'" 104:'/0 2o, 0472.001) <12 I'U~ '< ~J i
PWOOI·RfI-COOOO~JOJ
PWOOI·Rfi-COOiJ(l}.IOJ
1111012003
1119!'2003
00.0 J
0.0,05
n,loOO
4,"0
107.

".
U
O,IU
9.IJ
.,"
20),000
187,000
..
" '"
'" HU )5U
..,
l)]Q

'us
117,O'OO 10190 <.,. 21_9
"
'"
"
1.~.'>O
PWOOI·R,f2--C'(1000-'.IOJ
P' ....OOI,RF}·COOOO-S_I03
Ij/ll)l2(l0)
11l'}I'2OOJ
00(1·
0,0· OJ
D S" l!I.SDO
1.000 ". O.:I2:J O~ U ~noo-o
t.,
IU
~,060
1).300
~l),"

12,J
'240 0.61
0 .•
'"
.,
~~.1 2280
e.l U O,I-6J J5),000 lHJ OOJ 8,IlJO IH
L'
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;."
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......
,?wnoC·IOC-C ~jijj iii'J"/lt)o) Q.I1-0J. :5.77G
PWOOD·l!io-.COOOl)~·lg) 11t11200} 0.0 _ Q, 115001
O.2U Q-.8U 116,000 I6J 1U >0 7,6)0 -4-6,'9 SoCO.OOO
PWOIW.I"-COOOO}.lOJ !ttl!201H GO-Oj 30.500 r
213
",
0.116
U
1.1 ]98,000 1160 D :16,100 "n 513,000 '"
"0
J.:l
lD:-5
t.9
:21_2
J"',O'J9 7.lU l4U USO.~ :8aU 11.• 7l.
•••
!i;:
1 157,~O In 1.9 ),600,000 '-'llJ
PWO,"E~?j-COOOOS_I'Ql HII1f100) 00 _ 0-.5 104, ~OQ J
".
,., G.!1 ,utJ '"
,..
m ••
~S.:lDO 4.4!1' ~'SI.OOO I... 3-0.6 51 ,.1 '" ,,,
,.,. ,,,
PWO)E~"'<OQOO~.I(I:) 1119f,l:OOJ 00 - oJ 161.000 m '4.'900 13] ),-4)0.000 9. U iLl'
1~,600 O_']J t.iJ
"".000 m. ,n 116
PWOE·lOO.cOOOOj..IOJ 11l'l:nOOJ 00 -O,S I)100 i
'64 0.1': I.,
15S,,»O
IU,Ol;lQ

'"
28' I!Uoo HZ 461,000
oIn,ooo
m 124.000
I" ::~

HU
loll
:U
'-4'0000
UJO,OOO
9.04:1,1
'*.41,J ,.,
'" ..,
HOld' '" 20.000 'U7 I m : ..; ! ::,: ''''7.000: ~ ~ IJ 1..1 U ~,'I!-O,OOO 9' ~ u
="'1 m
~ot aampk it Il\cld' 4u~ic.c.
J ... Th •• Clti.tcI- 'nI'IJI! II ... r-_lrn.d qullftily
U ~ The !I'UI1plr ..... ~)'1:td rCl-r, bul wu Ml: -dt1i"C1C:oJ-bovc Ihc IlImpit '1'UartiUIJlH'I ~ -dI!C«UCIn lUTLit

r"nDI('II
~IQrl

TIERRA-B-014991
Table 17
Total Chromium and Hexavalent Chromium Results in Surface Water
Study Area 7; Jersey Cil)', New Jersey

Hexavalent
Depth Chromium
Field Sample lD Date Sampled Chromi~m
(feet) (uglL)
(ugfL)
Referenee SamBles (Filtered):
SWOOI-RFI-DOOSUR-103 10/16/2003 00 -0.5 IOU 10 UJ
SWOOI-RF2-DOOSUR-103 IOf16/2003 00·0.5 IOU IOUJ
SWOOI-RF3-000SlJR-103 IOfl612003 0.0 - 0.5 IOU IOUJ
SW002-RFI-oOOSUR-I03 1011612003 0.0·0.5 IOU IOUJ
SW002-RF2-DOOSlJR-103 1011612003 00 -0.5 IOU IOUJ
SWOO2 -RF3 -DOOSUR -103 10/1612003 0.0 - 0.5 IOU 10 UJ
Study Area 7 Samnles (Filteredl:
SW02W-D50-DOOSUR-103 I 01 1 6f2003 0.0 - 0.5 IOU 1001
SW03 W-D25-DOOSUR-103 IOfl6/2003 0.0·0.5 IOU 1001
SWD3W-D25-DOOSUR-I03 10/16/2003 0.0 - 0.5' IOU 10 UJ
SWI3W-100-oOOSUR-J03 10/16/2003 00 - 0.5 IOU IOUl
Reference Samoles Ilfnfiltered):
SWOOI-RF1-G00SUR-I03 10/16/2003 0.0 - 0.5 lOU !O 01
SWOOI-RF2-G00SUR-103 10/1612003 0.0 -05 IOU 1001
SWOO l-RF3-D00SUR-l 03 IOfl 6/2003 0.0 - 0.5 10 U 1001
SW002-RFl-DOOSlIR-l03 1O!l6f2003 0.0 - 0.5 IOU 10 UJ
SW002-RF2-DOOSUR-! 03 10/1612003 0.0 - 0.5 IOU IOUl
SWOO2-RF3-000SUR-I03 10116/2003 0.0 -0.5 IOU IOUJ
Study Area 7 Samnles fTJnfiltered1:
SW02W-D50-D00SUR-103 1011612003 0.0 - 0.5 IOU 10 UJ
SWOJ W-025-DOOSUR.103 10/16/2003 0.0 - 0.5 IOU 1001
SWD3 W -D25 -DOOSUR -103 1011612003 00 - 0.5' IOU IOUJ
SWI JW-100-OO0SUR-IDJ IOf16/2003 0.0 - 0.5 IOU 10 UJ

Notes:
Total chromium in SUlfaee water analyzed by Columbia Analytical Services, Inc. (Rochester, New York)
using EP A Method 60 JOB.
Hexavalent chromium in surface water analyzed by Columbia Analytical Services, Inc. (Rochester, New York)
using EP A Method 7199.
, = The sample is a field duplicate.
J = The associated value is an estimated quantity.
UJ = The sample was analyzed for, but was nOI detected.
The associated quantitation or detection limit is an estimate.

Paa-s()ns Page 101' I ENVIRON

TIERRA-B-014992
Table 18
Summary of Sediment ~(}Ie<:hnic.1 D.ta
Study Area 7; Jersey City, Ncw Jef5ey

i
ATTERBERG LiMitS
eRADAHON
Depth Average NalUral
N.tura:l Natural Water
&ring USCS Natural Uquid Plasticity
Below Wafer Water
Group Water 8./0 Coarse % Content of Organic
Number Mudline Limit Index Content of 0/0 Fine Specific
Content % Gravel Medium % Fines
Symbol Content ("!o) (%) Sand S.nd Gradation Content Gravity
(feet) ("!o) UmitSlll1lpll,
S8Jld Sample ("!o)
(%) of Solids

mr
("!o)
CV~j

I1
8000'-200 00·0.5 8C 32 29 37 19 31
5Dool-2oo 0.5-LO SC 17.9 43.4 26.7 33
41 41 39 18 41 2.71
80001-200 1.5-2.0 0.1 1.6 14.3 53.8
8C 47 5! 44 30.2 41 2.5 272
23 47 00 0.6
SOool-200 2.5-3.0 8C 48 14.6 45.1 39.7 44
49 37 13 45 3.4 272
SOool-2oo 3.5-4.0 0.0 0.9 16.0 55.0
CH 78 81 68 40 78
281 49 2.8 264

·•·
f\f\

··
nl'\
SDOO4·200 v.y U.V 0.5
0.0-0.5 SP-8M 20 20 • 1.7 97.8 76 4.1 274
8 D004-2oo
S0004-200
S0004-200
05-10
1.5-2.0
2.5-3.0
SP-SM
8M
CH
20
33
91
21
34
92 77
·· •
0.1
0.0
0.3
0.5
0.8
1.1
i
29.6
245
9.3
62.7
64.7
65.6
7.1
JO.t
23.8
19
20
33
0.7
08
1.3
275
246
270
48 91 3.6 1.1
8D004-200 3.5-4.0 CH 114 12.1 14.3 68.9 91
tIS 90 63

·· ··
56 114 2.69

··
SDOOA-005 0.0-0.5 0.0 0.2 [.2 9.6 on"
Sivl 29 30 I O:1',V i 14 7.2 265
8DooA-005 05-1.0 9.6 8.5 I 23.5 42.8
8M 46 46 15.7 29 3.3 2.78

•·
8DooA-005 7.8 6.6 18.!
l.5-2.0 8M 63 64 • *
38.4 29.0 46 4.0 2.66

··
5DooA·005 4.6 9.8 21.9
2.5-3.0 8M 52 54 • 39.[ 24.6 62 8.0 2.56
SDooA-005
SDOOA-025
SDOOA·025
35-4.0
0.5-1.0
1.5-2.0
8M
SM
SC
84
65
t52
86
69 47
· •
17 66
9.6
7.5
0.7
14.7
12.9
4.9
24.3
19.1
6.0
32.0
29.9
41.1
19.4
30.7
47.4
50
83
7.9
10.2
2.72
2.65
154 84 34 147 63 6.2 2.64
SDooA-025 2.5-3.0 1.3 6.4 13.1 386
CH 84 S2 55 27 89
40.5 154 21.3 2.43
SOooA-025 B-4.0 0.0 0.1 0.4 22.1
CH 90 93 67 37
774 82 5.4 2.71
80ooA-050 82 1.7 J.7 1.3
00-0.5 CL 76 79 49 27
12.0 83.4 93 68
SOOOA·050 0.5-1.0 CH
77 0.0 0.5 1.0 27.7 70.8
""-
82 92 55 30 75 2.9 2.74
SOOOA-050 84 0.0 03 12
15·2.0 CH 152 [52 24.0 74.5 77
92 57 151 0.0 5.1 2.74
SOOOA·050 25-3.0 CH 0.1 0.3 8.9
III 117 75 44 90.7 152 8.1 263
112 0.0 0.0 0.2
SOOOA·050 3.5-4.0 CH 77 5.0 948 108
30 67 39 96 7.3 264
SDOOA-100 0.0 0.0 0.1
0.0-0.5 CH t02 104 59 33
16 98.2 91 4.8 2.75
$ DooA· 100 102 0.0 0.3
05-10 CH 94 1.5 25.6 72.6 102
95 60 31 94 00 O.l
55 2.64
Sl)ooA-IOO 1.5-2.0 CH 105 0.6 17.4 81.9
106 7J 44 105 95 5.8 2.68
5 DooA· 100 2.5-3.0 CH 95
0.0 0.0 0.0 3.1 96.9
96 65 37 95 0.0
105 48 2.79
SDooA·IOO 0.0 0.2
3.5-4.0 CH 104 105 98
I.l 98.S 95 4.4
SOOOA-200
59 104 00 0.0 0.1
280
00-0.5 CH 164 170 1.4 985 104
104 65 J62 0.0 7.2 276
50ooA-200 0.5-10 0.0 0.1 61
CH 118 130 79 48 114
93.8 152 101 2 (,.j
0.0 0.0 0.4 89 90.7 114 7.1 267
=
P91"SOnS
Page [ of 5
Er-IVIRO"

TIERRA-B-014993
Table 18
Summary of Sediment c;.,ote<:hnical Data
Study Are. 7; .Jersey C;I)', New .1ersey

A.TTERBERG LjMizS GRADATION

Natural Water
Boring
Contenlof Orgflnic Sped lie
Number
Gradation Contenl Gravity
Sample (%) of Solids
£0,1. \
\ 'v,
SOOOA.200
SDOOA·200 90.8 74 ~~
/ SOOOA-200
SOOOB-005
98.4
97.3
92
85
~.~ I 2~~ i
4.2 2.77
SDOOB-005 4.1 19 0.6 271
5000B-005 6.9 24 1.4 279
5000B-005 33.3 23 12 2.70
5D008·005 79.4 34 2.5 270
5D008-025 93.8 83 49 2.67
50008·025 8.7 19 0.9
50008-025 44.9 19 1.6 2.75
S0008-025 83.8 29 1.7 272
50008-025 97.4 104 53 2.71
S0008·050 98.0 84 4.5 270
SD008-050 10.6 66 3.4 270
SD008·050 89.2 68 4.0 2.80
SD008·050 91.7 31 21 278
5D008-050 76.7 32 IJ 2.77
SD008·JOO 24.5 28 1.8 26B
50008-100 30.3 40 19 270
50008-100 HO 44 24 273
50000·100 209
5DOOB-100 38 266
5D008-200 1.8 +
5 D008-200 26.7 26 271
50008-200 40.1 272
50008-200 19.3 34 2.71
S0008-200 43.9 50 2.70
5DOOC-Q05 46.6 47 272
5DooC-005
SOooC-005
J 98.2
99.6
+ 2.28
265
98.2 261

Pal'sons
Page 2 of 5
ENViRON

TIERRA-B-014994
Table 18
Summary of Sediment GeoledmJe.1 Dala
Stud)· Area 7; Jersey Cli)', New Jersey

Averal;e
A""""OUMn. ~ GRA.DATION
Del'lh Natural Natural
uses Natunl Natural Water

%"",r=
Boring Be!o", Water U~Ujd P1a"licit)· Water % Co.rs~
Groul~ Wat ... % Conlenlof
Number Mud'in" Limit Index Content of % Grave~ S d Organic Specific
Symbol Conlent Medium
(feet) Conlen,t (%) (%) Lirnil Sam 1'1" an Sand V. Finrs Gradation Content Gravir:\"
("!o) Sand
(%j San,ple (%) of Solid.
(%)
SDOOC-005 ("!oj
2.5-3.0 OH 132 121 117 66 144 0.0
SDOOC-005 3.5-40 OH 116 121 97 52
0.0 0.0 1.0 99.0 .,. 7.2 2.61
SDOOC-025 III 0.0 0.0 0.0
0.0-05 CH 126 78 57 34 78
0.5 99.5 ... 2.1 2.6&
SDOOC-025 0.5- [.0 00 0.0 0.2 2.9
OH 157 160 121 968 173 2.7
61 I53 0.0 2.64
SDOOC-025 l.5-2.0 OH 0.0 0.0 3.1 96.9 ...
141 138 1/3 61 6.6 2.61
I43 0.0
SDOOC-025 2.5-3.0 OH 142 142 112 62 142
0.0 0.0 , J.l n.9 ... 66 2.62
SDOOC-025 3.5-4.0 0.0 0,0 0.0 14
OH I31 125 98.6 7.5
SDOOC-050 00·0.5 OH 137
109 57 136 0.0 0.0 0.0 1.0 99.0
'"
+
2.65
137 87 46 137 5.2 2.72
SDOOC-050 05·1.0 0.0 0.0 0.7
OH 124 127 94 12.6 86.7 138 2.2
50 121 0.6 1.8 2.60
SDOOC-050 15-2.0 OB 137 6.9 9.7 80.9 +
131 102 56 142 65 270
SDOOC-050 0.0 0.0 0.0 3.2 I .,.
25·3.0 OH 105 100 96.8
84 39 110 0.7 04 i 6.3 261
SDOOC-050 3.5-4.0 OH 74 75 63 27 74
1.8 13.7 83.3 ... 5.0 2.76
SDOOC-IOO 0.0-2.0 0.0 0.5 0.6 12.1 .,.
CH 84 84 74 41 86.8 4.4 2.66
SDOOC·IOO
84 0.0 0.0 0.8
0.0-0.5 CL 27.2 72.1 ...
SDOOC·IOO 0.5-1.0 SC
64 64 42 17 64 0.1 0.2
I
1.3 47.8 505
'-- 265
47 46 33 10 4&
64 1.4 2.72
SOooC-IOO 0.0 0.2 5.4 .,.
1.5-2.0 CH 59 66 56 29 52
63.0 3\.4 2.5 2.60
SDOOC-lOO 0.0 0.1 1.1 42.6
25-30 CH 81 80 68 35 82
56.2 + ..- 2.65

.
SDOOC-JOO 0.0 0.0 0.0
3.5-4.0 OH 83 &4 2.3 97.7 + 4.9
68 34 82 2.66
SDOOC-200 0.0·05 SC 35 35 * *
0.5
0.5
0.8 4.1 17.7 no + ._- 2.64
SDOOC·200 0.5-1.0 SM 25 -- -_. 0.6 22.4 52.5 24.1 .,.
SDOOC·200 1.5-2.0 SC 63
25
68 59
-- 0.0 i 0.1 19.9 61.2 18.8 +
1.6 267
32 57 0.0 I.I 2.68
SOooC-200 2.5-30 OH 0.8 12.2 38.1 48.9 ...
129 129 III 57 129 14 2.67
SDOOC-200 3.5-40 0.0 0.0 0.0
OH 112 112 110 59 112
6.9 93.1 ... 4.2 2.55
SD02E·025 0.0 0.0
0.0-0.5 OH 139 139 !Q2 53 ,or, 0.3 57 94.1 ... 3.5 2.5S
$002E·025 0.5-1.0
U7 0.0 0.0 00 0.9
OH 123 123 94 43 99.1 + 64
123 3.3 263
S002E-025
S002E-025
l.5-2.0
25-3.0
OH
OH
83
76
80 78 39
I
86 I 0.0
1.7
0.4
4.9
1.1
[07
4.0
79.4
94.5
'" 81 2.63
78 74 39 73 + 54 270
SD02E-025 0.0 0.0
15-40 CH 56 57 61 36 56
0.0 7.7 923 ... 6.4 2.63

.
0.0 0.0
SD02£-075 00-2.0 OH 120 120 91 38 120
0.0 0.2 99.8 ... 4.1 270
SD02E·075 0.0-0.5 0.0 0.0 0.2 10.2
CH 141 141 95 59 89.7 --.
I: 141 0.3 01 2.65
S002E-075 0.5-10 OH 129 0.4 4.7 94.5 141
127 111 63 130 1.8 2.65
0.0 0.0 0.3 4.4 95.3 + J.3 2.60

Pa"sons
Page 3 of 5
fN\IHON

TIERRA-B-014995
Table 18
S"mmary of Sediment Geotechnical Dala
Study Area 7; ,Jersey City, New Jersey

AITERBERG LIMITS GRADATION


Averag'~
Deplh Natural
Boring Below
uses Natural
Water
GrouJl Water
Number Mudl;ne Content
Symbol Contenl
(reel) (%)
(%)
5D02£.075 1.5·2.0 CH 126 121
8002£-075 2.5-3.0 OH 115 113
1 5D02£·075 35-40 OH 118 117
5D02W-200 0.0·0.5 SW-SM 18
j SD02W·200 0.5-1,0 SP II 1I
SD03E-025 0.0·0.5 CH 44
~D03E-025 05-1.0 OH .- ••- - 0.1 0.7 2.2 9.1 87,9 44 0.9 2.73
77 79
5D03E·025 67 24 74 0.0 0.0 0,0 0.4 99,6 + 4,5 269
1.5-2.0 OH 97 97
5003E-025 2.5·3.0 CH 67 79 35 97 0.0 0.0 00 1.0 99.0 + 5.1 2,70
67
5003E-025 38-4.3 8M 64 33 67 0.9 0.5 09 19.9 778 + 4.1 2,72
26 26
5003E-050 4,0-4.5 CH 107
• • • 0.0 (I.[ 10.8 74.5 14.6 + La 264
5003E-075 0,0-0.5 77 44 -- 0.0 0.2 1.3, 29.3 69.3 107 __• ._.
OH
5003£-075 05-1.0 OH "- ••• -.- 0.0 0.0 1.0 10.5 88.5 + 4,7 2,67
86 86
SD03E-075 15-2.0 OH -- -- -- 0.0 0.0 0.5 1.8 97.7 + 4.6 273
81 81
8D03£-075 2.5-3,0 .- ••• -.- 0,0 0.0 0.6 2.0 97.4 + 5,3 2,67
SP·SM 20 20
8003E-075 3.5-4,0 SP 20 20
• • • 0,0 0.1 9.8 80.9 9.2 + 0.5 2,68
SD03W-200 0.0-0.5 SM 34 • • • 2.2 1.0' 9.8 85,6 l3 + 0.3 •__
34
SD03W·2oo 0.5,1,0 SP-SM • • • 11.0 0.9 20.1 52,3 15.6 + 2.66
38 38
SD03W·200 !.S-2.0 SP-SM 16 • • • 2.2 1.6 28.8 546 12.8 • __• 2.69
16
5003W·200 2,5-3.0 SP-SM • • • 3.8 6.5, 51.0 33.4 5.4 + 2.64
15 15
8003W-200 35-4.0 SP • • • 2.7 4.2 29.6 54,7 8.9 + .__ 266
16 16
SO 13£-005 0.0-0.5 SM • • • 8.3 1.4 46.7 42,6 0.9 + .__ •• _
69
SD 13E-005 05-1.0 CH 13 t 134 • • • <~.j 16.2 9.6 8.1 42.S 69 3.2 2.51
SD I3E·005 15-2,0 OH 99 89 51 134 9.8 2.2 2,4 15.l 70.6 127 20 2.48
99
5D13E-005 2.5-30 CH 85
66 33 99 1,5 1.8 6.1 19.6 71.0 99 U 2.62
81
SD13E·005 3.5-4,0 CH 72 39 89 0,0 0,0 0.3 0,3 99.4 + .. _ 2,70
100 102
5013£·010 10.5-11.0 SP·SM 88 52 98 0,0, 0.0 1.0 1,7 97.4 T ._. 2.72
14
5013E-010 • • • 12.4 8.4 35.0 36.9 73 14 ___
140-15.0 OL 19 +
SDl3E-OIO 8.0-9.0 • • • 0,0 0.1 0.4 14.0 85.4 19 _.. _._
SP 21 +
SDI3E-050 00-2.0 CH • • • 0.4 0.6 9.9 89, I 0,0 21 .. _ .• _
67 75
5DI3£-050 00-0.5 55 30 59 0.0 0.0 0.0 1.0 99 a ~ ••• 2,74
SC 53 53
32 10 53 OJ 0.6 5,7 52,8 JO,6 52 1.6 264

P<lr~ons
Page4of5
FNVlr~ON

TIERRA-B-014996
Table 18
Summary of Sediment c;.,ole<:hnie.1 Data
Shirl)' Area 7; Jersey City, New Jersey

A TTERHERG LIMITS
GRADATION
Average N.hlr81
Depth Nahlrol Natural Water
Boring USCS Nahlrol Liquid Pla.tidly Water
Below Water % Content of
Group War.r °/. C09r5e G/o Fine Organic Spedfi<
Nwnber Mudl;n. Limit Index Content of 11/0 Gravel
Cootent Medium 0/. Fines Gradation Content
Symbol Conlenl (%) (%) SAnd Sand GrAvi!)'
(feel) (%) Limit Sam pie Sand
(%) Sample ("!o) of Solids
(%)
(%)
SDI3£·050 0.5-1.0 CH 59 59 57 29 59 0,0 1.5 0,0
5D I 3£·050 1.5·2.0 1.8 96.7 + 3.1 2,77
OH 85 83 81 42 88 0,0 0.0 0.0 13 98.7 +
5013E-050 2.5-3.0 OH 92 91 85 55 2,74
46 92 0,0 00 0.0
5013£-050 35-4.0 2,5 97.5 + 5.5 2,63
OH 78 82 76 40 74 0,0 0.0 0.0 0,8 99.2
SO I3E-I00 0,0-0.5 CH 102 79 107
i
4.5 2.75
68 174 00 0.6
SO I3E-IOO 0,5-1.0 8.8 37.9 52.7 79 2.1
CH 82 74 2.61

.
58 31 89 1.3 0.3
50I3E·IOO 15-2.0 3.2 17.6 77.S + 4.1
CH 93 92 81 47 94 2.63
0,0 0.0 0.0 2.1 97.9
5013E-IOO 25·30 OH 96 100 4.6 2.93
95 53 91 0.0 0.0
S013E-IOO 3,5·4,0 0.0 l.l 98.9 + 4.9
CH ll8 106 107 2.6&

·• ·•
70 130 0,0 0.1
5DI3W·200
5013W-200
0.0-0.5
0.5-1.0
SM
8M
21
17
21
17 ·· 0.3 0.9
l.l
23.9
9.0
59,6
89.8
15.3
+
+
6.5
---
2.58
2.68

··· ··· ·
1.5 2.8 251
SDI3W-200 1.5-2.0 se 14 14 10,1 0.7
52.9 17,7 + --- 2.70
sp-se 18.3 54.5 16.4
SD13W-200 2.5-3.0 13 13 • + --- 2.68

·
0.0 0.3 19.0 71.7
SD13W·200 3.5·4.0 sp-se 15 15 4.1
9.0 + OJ 2.65
1.3 26.7 5&.9 9.0 + --. 272
Notes:
All lests summarized were performed in a Mueser Rutledge Consulting Engineers laboralory,
• Average natllral waler content" is a weighted average of all material tesled .
• • Soil non plastic,
+ ~Natllral water Conlen! not laken,
-- ~ Nol enollgh soil in jar to 11m tes\'

Panon:s
Page 5 of 5
ENVIRON

TIERRA-B-014997
....

Tab-lit 19
Sr. "Hhlll-d OI'dQ-me~~r .nod Perltl-.blltty T a-Un-g Resulbi
Stud,. Aru 1: j~l~l Ctt)r. Nom'Jt'Tlq"

uses N.t\1nl lnltli.I Pinal


S.mph~ LI" ..ld PlasdC:lly P-'*sU(1) Uquldlty IniUa. Ji'lnal
Bori"« Eln_lIo1,
W.1A'1'" Inltlat E.dnlued [xbtlnl
C.rvup Umll LlmU S .....clf1c W.,er Witt" DegrnQr FllUlt
NUl'nhe'r Nl.lm~r {fut) Endn rnd ... Dl'(nf-01 Pn~:t1.'OlkI.Uon
C.nlrrtt Yohl" Vo-Id OvubUrdC'p CompruJion S1tt"lUll'g
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rars:ftnJ
~~lorl

TIERRA-B-014998
JERSEY CITY
Honey\\'ell NEW JERSEY

STUDY AREA 7
SITE MAP

PARSONS
OCEAN SURVEYS, INC. MECbm:;.;""'._ ...... UmncrTech, Inc.
PRIVEL£GED AND CONFIDENTIAl. PREPARED AT n-H~ REQUEST OF COUNSEL

TIERRA-B-014999
! It) o
~
125

EXPLANATION

Sediment Sample

'0 Water Sample

iii No Sample'

'NOTE.:
ATTHA:EE U:X:ATlONS.$,t.MPUNG
WAS ATTEJJ:f7TED; HOWEVER
SAMPLES COULD NOT BE COUECT"ED
BECA1.JSE COARSE SEO!MENTS WERE
FOJNO. ROC-K FfUG~Et>rTS WERE
ENCOUNTCFrWAllOCATrON$
00&-02.'5 AND OOS-D50. CO~
SAND AND SHELL ffMGMfN"f$
INERE ENCOUNTERED AT LOCATJiJN
t3:Y/~200.

FIGURE 2A
JEASEYCITY
Honeywell NEW JERSEY

STUDY AREA 7
LOCATIONS OF SEDIMENT
GRAB SAMPLES AND WATER
COLUMN SAMPLES NEAR SA?

PARSONS DCEAN SURVEYS, INC. MEC."", .. ~~- Limno-Tech,Inc.

PRIVELEGED AND CONFIDENTIAL. PREPARED AT THE REQUEST OF COUNSEL. 'i1Hon09~.eII-He.ck9n.sa::k Rlwt\G1S'Map-s\MapsForSeoRaktAl)pM!G\I'lSlXf\

TIERRA-B-015000
II~ EXPLANATION
o
~
125

A 10' Core

A 20' Core
0,_<, , __... ".

Radiodating Core
'"

FIGURE 28
JERSEY CITY
Honeywell NEW JERSEY

STUDY AREA 7
LOCATIONS OF SEDIMENT
BORINGS FOR CHEMICAL
AND GEOTECHNICAL
CHARACTERIZATION

PRIVELEGED AAO CONFtDfN'TIAL PREPARED AT THE REQUEST OF COUNSEL


MEC ","',,,.,,,.,,. Umno-Tech, Inc.

TIERRA-B-015001
FIGURE 3

JERSEY CITY
NEW JERSEY

STUDY AREA 7
LOCATIONS OF SEDIMENT
GRAB SAMPLES AND WATER
COLUMN SAMPLES IN
REFERENCE AREAS

M:EC .."",,,,,,, . Limno-Tech, Inc.


PRlVELEGED AND CONFIDENTIAL PREPARED AT TliE REOOEST OF COUNSEL

TIERRA-B-015002
r 16 :-
EXPLANATION
125
. :::".' ~
,.., .. '.-.

I
.A 10' Core

.b:. 20' Core

Radjodaling Core

FIGURE 4
JERSEY CITY
I-loneyv,'ell NEW JERSEY

STUDY AREA 7
CROSS-SECTION
LOCA TION MAP

PARSONS i~""-:;'I~~'~:;no.",'2'~2..N~$ OCEAN SURVEYS. INC. MIC"."" .." Limno-Tech, Inc.

PRIVElEGEDANDOJNAOENTlAl. PAEPAREOAT'rHE RECXJESTOfOOUNSEL "'~~F~""""""lo.;.Oo<:I"'~l"'UG

TIERRA-B-015003
SUPPLEMENTAL REMEDIAL INVESTIGATION REPORT
REMEDIAL ACTION SELECTION REPORT
REMEDIAL ACTION WORK PLAN

5
NEW JERSEY CITY UNIVERSITY PROPERTIES

JERSEY CITY, NEW JERSEY

Site 090
'~o/~;.,

Volume 1: Text, Tables, Figures

~' ..
' -"-,,-,,-,,,".,.~._ .... _ ~
I •• ·--<.C:_~.'

JUNE 2007 Honeywell 6MACTEC PN3480060208

BBA000004
TIERRA-B-015004
SUPPLEMENTAL REMEDIAL INVESTIGATION REpORT/
REMEDIAL ACTION SELECTION REpORT/
REMEDIAL ACTION WORK PLAN

STUDY AREAS
NEW JERSEY CITY UNIVERSITY PROPERTIES

JERSEY CITY, NJ

Prepared for:

Honeywell
Honeywell
101 Columbia Road
Morristown, NJ 07962

Prepared by:

,MACTEC
MACTEC Engineering and Consulting. Inc.
200 American Metro Boulevard, Suite 113
Hamilton, New Jersey 08619

JUNE 2007

TIERRA-B-015005
Table of Contents

Executive Summary

1.0 Introduction 1
1.1 Purpose and Scope I
1.2 Report Organization , 4

2.0 Site Description 5


2.1 Site Location 5
2.2 Site History 7
2.3 Environmental Setting 8
2.3.1 Regional and Site Geology 8
2.3.2 Regional and Site Hydrogeology ··· 10
2.3.3 Site Topography and Surface Water 11
2.4 Current and Future Land Use · 12
2.5 Previous InvestigationslRemedial Actions 12

3.0 Surrunary of Remedial Investigation Results 14


3.1 General Overview 14
3.2 RIWP Addendum for Shallow Groundwater (2005) 14
3.2.1 Soil Borings/Soil Sampling 14
3.2.2 Groundwater Investigation _ 15
3.3 Soil Investigation Results 17
3.3.1 Remedial Investigation Report (1999) 17
3,3.2 Remedial Investigation Report Addendum (October 2004) 18
3.3.3 RIWP Addendum for Shallow Groundwater (AprillMay 2005) 19
3.3.4 Additional Soil Delineation (November 2006) 19
3.4 Groundwater Investigation Results 20
3.4.1 Remedial Investigation Results (November 1999) 20
3.4.2 Report on Groundwater for Study Area 5 (October 2004) 21
3.4.3 Deep Overburden GrOlUldwater Report for Study Area 7 (February 2007) 21
3.4.4 RIWP Addendum for Shallow Groundwater (AprillMay 2005) 23
3.4.5 Additional Shallow Groundwater Sampling (Mayl AugustlDecember 2006) 23
3.5 Study Area 7 Source Area Treatability Studies 24
3.6 Conclusions and Recommendations 25

4.0 Remedial Action Selection Report 28


4.1 Remedial Action Objectives 28
4.2 Soil Remedial Actions · 30
4.2.1 Evaluation of Potential Remedial Actions 30
4.2.2 Recommended Remedial Action · ·· · · 31
4.2.3 Coordination with Site Redevelopment and Other Remedial Actions 32
4.3 Groundwater Remedial Actions · ·..··..· 33
4.3.1 Evaluation of Potential Remedial Actions 33
4.3.2 Recommended Remedial Action · 36
4.4 Remediation Standards 36
4.5 Satisfaction of Criteria Pursuant to NJ.A.C. 7:26E-5.1 38
4.5.1 Effectiveness of the Remedial Action 38
4.5.2 Implementability of the Remedial Action · · ·..· 39

TIERRA-B-015006
Table of Contents

4.5.3 Compliance with Applicable Federal, State, and Local Regulations , .40
4.5.4 Potential Impacts on the Local Community 40
4.5.5 Potential for Remedial Action to Cause Natural Resource Injury 41
4.5.6 Criteria for Restricted Use Remedial Action 41

5.0 Remedial Action Work Plan · 43


5.1 Remedial Action Description 43
5.2 Pre-Remediation Activities 46
5.2.1 Remedial Action Design 46
5.2.2 Property Access Agreements 53
5.2.3 Regulatory ApprovalslPermits 53
5.3 Remedial Action lInplementation 53
5.3.1 Site Preparation , , 53
5.3.2 Health and Safety 54
5.3.3 Contractor Mobilization 54
5.3.4 Soil Excavation and Site Grading 55
5.3.5 In-Situ Treatment (Source Control Component) 57
5.3.6 Installation of Engineered Barrier (Soil Capping) _ 58
5.3.7 Groundwater Treatment (Penneable Reactive Barrier) 59
5.3.8 Site Restoration 60
5.4 Post-Remediation Activities 61
5.4.1 Engineering and Institutional Controls 61
5.4.2 Post-Remediation Operation, Monitoring, and Maintenance 62
5.5 Quality Assurance Project Plan 63
5.6 Construction Activities 63
5.7 Remedial Action Cost Estimate 64
5.8 Remedial Action Schedule 64

6.0 Remedial Action Report 65

7.0 References 66

8.0 List of Acron)'l11S and Abbreviations 67

TABLES

lA Soil Sampling Results - AprillMay 2005


1B Grain Size Analysis Results - AprillMay 2005
2 Soil Delineation Results - November 2006
3 Groundwater Sampling Results - AprilIMay 2005
4 Groundwater Sampling Results - Mayl AugustJDecember 2006
5 Groundwater Elevation Data
6 Remedial Action Cost Estimate

ii

TIERRA-B-015007
Table of Contents

FIGURES

1 Site Location Map


2 Existing Site Conditions and Proposed Site Development Plan
3 Soil Sample Results for Hexavalent Chromium
4 Shallow Groundwater Elevation Contour Maps
4A Shallow Groundwater Elevations Map - April 2005
4B Shallow Groundwater Elevations Map - May 2005
4C Shallow Grolmdwater Elevations Map - May 2006
4D Shallow Groundwater Elevations Map - August 2006
4E Shallow Groundwater Elevations Map - December 2006
5 Groundwater Sampling Results
6 Remedial Action Site Plans
6A Remedial Action Site Plan
6B Remedial Action Concept Detail - Permeable Reactive Barrier
6C Remedial Action Concept Detail - Source Area Treatment Plan (HydroQual Inc.)
6D Remedial Action Concept Detail- Source Area Treatment Detail Sheet I (HydroQual Inc.)
6E Remedial Action Concept Detail- Source Area Treatment Detail Sheet 2 (HydroQual Inc.)
7 Conceptual Site Cap Design Cross Section and Details
8 Conceptual Plan for Former Morris Canal Area
9 Remedial Action Schedule

APPENDICES (Volume 2)

A Reference Documentation: Correspondence and Reports - Data Tables/Figures /Boring Logs


AI: RIR for Study Area 5 (TetraTech, Inc., November 1999)
A1: R1R Addendum for Study Area 5 Sites 090,153, and 184 (TetraTech, Inc., October 2004)
A3: Final Groundwater Investigation Report Study Area 7 (HydroQual, Inc., February 2007)
A4: Additional Soil Data (New Jersey City University, 2005)
AS: RffiIRA WP for NJCU West Campus Expansion (TetraTech, Inc. February 2006)
B NJDEP Well Permits
C Soil Boring Logs
D Monitoring Well Records/Completion Forms
E Groundwater Sampling Field LogslForms
E-l: Groundwater Sampling Field Data Sheets
E-2: Groundwater Contour Reporting Forms
F Soil Sample Laboratory Results and Data Validation Reports
G Groundwater Sample Laboratory Results and Data Validation Reports
H Health and Safety Plan
I Perimeter Air Monitoring Plan
J Quality Assurance Project Plan
K Draft Deed Notice
L Draft Classification Exception Area Application
M Electronic Data Deliverables
N In-Situ Treatment Information for Site 117 Source Area (HydroQual, Inc.)
N-I: Treatability Study (Calcium Polysulfide - Source Area)
N-2: Case Studies (Calcium Polysulfide Treatment)

111

TIERRA-B-015008
EXECUTIVE SUMMARY

Honeywell International Inc. (Honeywell) has completed an evaluation of remedial action alternatives to
address chromium contamination for the portion of Study Area 5 proposed for redevelopment by New
Jersey City University (NJCU or University). This portion of Study Area 5 is comprised of the following
sites:

Site Name NJDEP Site No.


Former Baldwin Steel 90
Former MJ. Holdings 184
Portion of the Former Morris Canal Site 153

These sites are collectively referred to herein as the "Site", and encompass a total of approximately 14
acres located in Jersey City, Hudson County, New Jersey (see Illustration I).

This combined Supplemental Remedial Investigation Report (SRIR), Remedial Action Selection Report
(RASR), and Remedial Action Work Plan (RA WP) reflects Honeywell's concerted efforts to produce an
integrated remedial approach to the New Jersey City University site (a portion of Study Area 5),
developed in close cooperation with and supported by the University. The approach selects a remedial
technology based on the specific uses anticipated for the chromium impacted portions of the Site,
consistent with the guidance in the Department's recently issued Chromium Directive (Policy). These
uses fall into both the Residential and Commercial categories that are discussed in the Policy. Honeywell
and NJCU have met numerous times to coordinate the remediation with the redevelopment, and have
recently formed ajoint team to continue this coordination through the life of the project.

This cooperative effort has resulted in a comprehensive approach to chromium remediation. This RA WP
applies a combination of remedial technologies that will fully protect human health and the environment
and effectively integrate the remediation with the redevelopment. This proactive approach 1) is
encouraged by New Jersey's Brownfields Legislation, 2) fully meets both the spirit and intent of the
Policy, and 3) complies with the Technical Requirements for Site Remediation. We strongly believe that
this approach is a model that demonstrates what can be achieved under the new Policy.

·---------·--~---_··---------------7
e~o-tllVol:l

N
t

LEGEND
( 81te Boundary
RESlOEHTlAl. AOC SITE 114 : Rni<J.,.,li.IAOC
I . Commerei'" AOC
:
.,_...._-. "-"1 ~
~
c::J
Proposl'd e.c...v
Proposed ClIP A'....
P,oposed 8ulldltl9l'
lon .Ar~_

S~IO ,
I

- Impermeilble Barner

J!
________ -
BioBa"ie, (PRS)
Chromium Imp.acted Soil.
o..\in •• ';on line 120mo/lllli

Impermeable 8 ... ,ler

IIlustrati0ll1. NJCU Property Layout

ES-I

TIERRA-B-015009
Working with the property owner, Honeywell has developed a viable and protective remedy for
contamination associated with both chromite ore processing residue (COPR) and sodium chromate. The
CaPR was likely used as fin on the Site and the sodium chromate likely resulted from housekeeping
practices associated with the adjacent, former Mutual Chemical site. The remedy supports the aggressive
Site redevelopment plan and schedule envisioned by NJCU.

The remedial approach presented herein was developed to align remediation solutions with NJCU's plans
for the property and is fuJly protective of human health and the environment. NJCU's redevelopment of the
Site will result in both residential and commercial uses. Honeywell, following the guidance of the Policy
and Technical Requirements for Site Remediation, has selected remedies that support the site uses. For
residential uses, defined by the Residential Area of Concern (RAOq, excavation will be applied. For
commercial uses, similarly defined by the Commercial Area of Concern (CAOq, both state of the art
engineering controls and an innovative reactive wall (or permeable reactive barrier) will be applied (see
lllustration 1). The combination of remedial approaches described in this document will ensure that:

• Chromium-impacted soil will be excavated in the RAOC;


Chromium-impacted soil will be effectively isolated to prevent direct contact in the CAGC;
Impacted groundwater will be addressed by focused source soil removal/treatment and in-situ
permeable reactive barrier (PRB) treatment remedy;
• Prevention of re-contamination of excavation areas; and,
• The Site will be restored quickly to productive use as part of a major redevelopment project benefiting
the surrounding community.

Honeywell supports the planned Site redevelopment because:

• It protects human health and the environment;


• Quickly returns the Site to productive use;
• Is consistent with the NJDEP's Policy; and,
• Meets the objecti yes of the New Jersey Brownfields Legislation that encourages cleanup and reuse of
sites impacted by historical contamination.

NJCU fully supports Honeywell's approach and is ready to proceed with the Site development pending
review fPld approval of this RA WP by the NJDEP. NJCU intends to request funding for their
redevelopment through the Environmental Infrastructure Trust Fund. Their goal is to submit an application
to the Trust Fund in August, 2007 and that funding application requires an approved RA WP.

The components of the proposed remedial actions include:

• Excavation of soils containing hexavalent chromium above 20 mglkg to a depth of 20 feet (20/20) in
the Residential AOe. The Residential AOC extends to the nearest physical feature of the adjoining
Commercial AOC.

• Additional focused soil excavation in the Commercial AOC to provide clean utility corridors and to
coordinate the proposed capping system with proposed Site development features along Route 440.

• Engineering controls (cap) for the Commercial AOC where soils exceed 20 mglkg hexavalent
chromium.

ES-2

TIERRA-B-015010
• Installation of an in-situ permeable reactive barrier (PRB) using a biological medium for the treatment
of residual impacted groundwater across the western portion of the Site.

• In-situ groundwater treatment system to reduce source concentrations on the adjacent Home Depot site,
which is contributing to the deep aquifer contamination.

• Impermeable barrier and backfill liner systems to prevent recontamination of excavated areas from
potential upgradient sources.

• Institutional Controls (Deed Notice) for soils remaining with hexavalent chromium above 20 mg/kg.

• Institutional Controls for groundwater (Classification Exception Area [CEA]), if necessary.

The remedial approach described herein goes beyond what is required in the Policy for the RAGC by
providing for full excavation to 20/20. Treatment of the chromium impacted soils is allowed under the
Policy, but Honeywell has chosen to excavate all of the RAGC to 20/20, primarily to meet NJCU's schedule
requirements. The remedial approach also provides an added measure of protection for the CAGC by
including a redundant groundwater protection system as a "belt and suspenders" approach. In addition to
the PRB, Honeywell will be installing piping that will enable a pump and treat system to be activated, if
necessary.

The NJCU West Side Campus Expansion will serve to broaden the physical resources of the University
and enable them to provide expanded learning opportunities for New Jersey residents, primarily from
Hudson County. It will also provide attractive retail outlets and market rate housing that will help to
continue the revitalization of Jersey City's west side. Honeywell's remediation plan will enable this
redevelopment to move forward quickly and with a fully protective remedy.

ES-3

TIERRA-B-015011
1.0 INTRODUCTION

1.1 PURPOSE AND SCOPE

This combined Supplemental Remedial Investigation Report (SRIR), Remedial Action Selection Report
(RASR) and Remedial Action Work Plan (RA WP) was prepared by MACTEC Engineering and
Consulting, Inc. (MACTEC) on behalf of Honeywell International Inc. (Honeywell) to address chromium
contamination on the portion of Study Area 5 (SA-5) proposed for redevelopment by New Jersey City
University (NJCU). This portion of SA-5 is comprised of sites designated as Baldwin Steel (NJDEP Site
090), M.1. Holdings (NJDEP Site 184), and a portion of the Former Morris Canal Site (NJDEP Site 153)
abutting Sites 090 and 184 (collectively referred to herein as the "Site"). This document addresses
remedial investigation (Rl) requirements and proposes remedial actions for the Site in accordance with
the requirements of the Administrative Consent Order (ACO) and the New Jersey Technical
Requirements for Site Remediation (Technical Requirements) (NJDEP, 2003).

Honeywell (formerly Allied Signal, Inc.) entered into an ACO with the New Jersey Department of
Environmental Protection (NJDEP) on June 17, 1993, to investigate and, if necessary, remediate
chromium contamination at twenty-one (21) Sites referred to by the NJDEP as the Hudson County
Chromium Sites. The Sites are located in Jersey City, New Jersey, and are grouped into seven (7) Study
Areas. SA- 5 is comprised of five (5) contiguous Sites identified as follows:

• Ryerson Steel (Site 117)


• Baldwin Steel (Site 090)
• MI Holdings (Site 184)
• Route 440 Vehicle Corporation (Site 079)
• Fonner Morris Canal Site (Site 153)

A Remedial Action (RA) for soils has already been completed at the former Ryerson Steel site (Site 117
but now conunonly referred to as the Home Depot site). This action was part of the redevelopment of the
property as a retail shopping center. Previous investigations and remedial actions have also been
conducted on portions of Site 184 (MI Holdings). Previous investigation and remedial action activities
on the eastern portion of Site 184 were reported to NJDEP on December 1, 1992, and additional Site
characterization and remediation was completed in the western portion of Site 184, including excavation
and off-site disposal of contaminated soils. These activities were documented in a report prepared by
Woodward-Clyde Consultants dated August 30,1993.

RI activities have been substantially completed on the remaining Sites comprising SA-5. A report
entitled Draft Remedial Investigation Report (RIR) - Study Area 5, dated November 1999, prepared by
TetraTech, Inc., documented the results of previous RI field activities on the five (5) sites comprising
SA-5 (TetraTech, 1999). The NJDEP provided comments on the RIR in a letter dated October 9, 2001,
and Honeywell provided responses to the NJDEP review comments in a letter dated December 19,2001.
An RIR Addendum with results of additional soil sampling performed on Site 090 (Baldwin Stee!) and
Site 184 (MI Holdings) was submitted to the NJDEP in October 2004 (TetraTech, 2004).

A Remedial Investigation Work Plan (RIWP) Addendum for Shallow Groundwater was prepared by
MACTEC and submitted to the NJDEP in March 2005. The results of the additional RI field activities
are presented in this report. The additional RI activities were conducted to address NJDEP requirements
for shallow groundwater in response to the NJDEP comment letter dated December 21,2004 on the RIR

TIERRA-B-015012
Addendum, and subsequent discussions including a meeting held on February 3, 2005 between
representatives of Honeywell and the NJDEP. Honeywell provided responses to the NJDEP comments
on the RIR Addendum in a letter dated February 15,2005. Prior to field mobilization for the additional
Rl activities in April 2005, a conference call was held between representatives of Honeywell and the
NJDEP to discuss the proposed supplemental field activities. NJDEP provided preliminary verbal
comments on the RIWP during the conference call on April 8, 2005, and subsequently provided written
comments in a letter dated June 3, 2005. Honeywell transmitted a letter dated July 1,2005, with
responses to the NJDEP review comments.

The RI has included a total of over 80 soil borings and analysis of over 700 samples for total and
hexavalent chromium on the Site. Based on the RI soil data, the horizontal and vertical extent of
hexavalent chromium above the most stringent NJDEP Soil Cleanup Criteria of20 mglkg has been
characterized and delineated.

This RASR/RA WP presents an evaluation of remedial alternatives and selected remedial actions to
address chromium contamination, to be implemented as part of the Site redevelopment activities.
Working with NJCU, Honeywell has developed a viable and protective remedy to address contamination
associated with the historical placement of chromium-containing fill at the Site. Currently, an interim
remedial measure (IRM) consisting of pavement and existing floor slabs serve as a cap to prevent direct
contact with contaminated soils. NJCU plans to redevelop the land into a mixed-use facility, referred to as
the NJCU West Campus Development, consisting of student housing, retail, and other educational facilities.
Under the current redevelopment plan, it is anticipated the existing pavement and building foundations will
be removed, and a remedy to address chromium contamination will be implemented.

The remedial approach takes into consideration the recently issued Chromium Policy (NJDEP
Memorandum dated 2/8/07) and NJCU's redevelopment plan, which includes residential and commercial
uses. Honeywell, following the guidance ofthe Chromium Policy, has selected remedies that address the
site uses. The components of the proposed remedial actions for chromium include:

• Pre~remediation activities including obtaining property access agreements; remedial design; and
regulatory approvals including soil reuse plan approval (if necessary), soil erosion sediment control plan
(SESCP) certification, and local construction permit approvals.

• Excavation of chromium-impacted soils in the Residential AGC (RAOC). Soils containing hexavalent
chromium above 20 mg/kg in the RAOC will be excavated to a maximum depth of20 feet. As a
conservative measure, Honeywell has extended the RAGC out from the footprint of residential use
buildings to the nearest physical feature of the adjoining commercial area (CAGC).

• Engineering controls for soils exceeding 20 mgikg in the CAGe. The engineering controls include a
capping barrier with impervious geo-membrane liner, geo-composite drainage layer, and minimum
two fect clean soil cover, or minimum I-foot clean soil and pavement cover.

• Additional focused soil excavation may be performed to provide clean utility corridors in connection
with the proposed Site development and to coordinate the proposed capping system with proposed
Site development features along Route 440. Soils excavated for utility corridors and grading for cap
installation will be re-used by consolidation and capping on-site.

TIERRA-B-015013
• Installation of an in-situ permeable reactive barrier (PRE) that will use biologically mediated reduction
for treatment of hexavalent chromium. The PRE will run primarily along the western border of the Site.

• Implementation of an in-situ groundwater treatment system to address residual source material on the
Home Depot property (Site 117), which is contributing to the deep groundwater chromium plume. An
impermeable hydraulic barrier will be installed along the southern property line of the Site to
hydraulically isolate remediated areas on the Site from "source area" groundwater on Home Depot.

• Installation of impermeable barrier and backfill liner systems to prevent recontamination of


excavated areas from potential upgradient sources.

• Institutional Controls (Deed Notice) for soils above 20 mg/kg hexavalent chromium, including
maintenance of existing engineering controls (e.g., concrete, pavement) and newly installed controls
during the remedial action and Site redevelopment (e.g., engineered barrier, clean fill, paving).

• Post-remediation groundwater monitoring to evaluate chromium concentrations with respect to the


NJDEP Groundwater Quality Standard (GWQS) of70 micrograms per liter (ugIL), and Institutional
Controls for groundwater (Classification Exception Area [CEAD, if necessary.

This RASRJRA WP addresses soils and shallow groundwater impacted by chromium contamination
above applicable remediation criteria, and satisfies the Technical Requirements for Site Remediation
while incorporating the objectives of New Jersey's Brownfields Program. While the NJCU final design
and development work progresses, Honeywell will proceed with final engineering design activities. The
remedy for soils takes into consideration the current NJDEP chromium policy and current redevelopment
plans by NJCU. NJCU is in agreement with deed notice restrictions for the remedial approach in this
RAWP.

The proposed remedial actions for the portion of Site 153 (Former Morris Canal) abutting Sites 090/184
(NJCU Property) include limited soil excavation as may be required for cap installation and for providing
clean utility corridors to support the proposed Site development by NJCU. Honeywell has proposed to
buy this portion of the former Morris Canal from the Bayonne Municipal Utilities Authority (BMUA),
and anticipates successful completion of this purchase in the next several months. At that point, as the
property owner, Honeywell would agree to deed notice and institutional controls for this property.

The R1 data for the Site and data from the regional groundwater investigation being conducted under the
oversight of a court-appointed Special Master for Study Area 7, demonstrate that shallow groundwater
conditions at the Site are not a source of the groundwater impacts in the deep groundwater zone. Further
investigations and remedial actions for the deep groundwater zone are being addressed under separate work
plan(s) subject to review/approval by the Special Master for Study Area 7. The Final Groundwater
Investigation Report (GIR), for the regional investigation, was submitted to the Special Master and NJDEP
on February 2, 2007 (HydroQual, Inc., 2007).

Based on the Final GlR and additional data collected at Site 117 (adjacent to Site 090), an in-situ
groundwater treatment system is proposed by Honeywell to address the residual source on Site 117
contributing to the regional groundwater contamination. The proposed groundwater treatment system is
included with this RA WP for NJDEP review and approvaL

TIERRA-B-015014
1.2 REPORT ORGANIZATION
This RASR/RA WP has been prepared to meet the provisions specified in the New Jersey Technical
Requirements for Site Remediation, NJ.A.C. 7:26E-5.2 and 6.2, and contains the following sections:

1. Introduction. This section contains background infonnation and describes the report
organization.

2. Site Description. This section contains information on Site location, history, soils, geology,
hydrogeology, topography and surface water bodies, previous remedial investigations, and
remedial actions.

3. Summary of Remedial Investigation Activities. This section contains a summary of RI soil and
groundwater investigation results, including a summary of previous investigations and the
supplemental Rl activities completed during 2005.

4. Remedial Action Selection Report. This section identifies remediation objectives and includes
information pertaining to remedial action selection pursuant to N.J.A.C 7:25E-5.2.

5. Remedial Action Work Plan. This section describes the work elements of the proposed remedial
action pursuant to N.J.A.C 7:26E-6.2.

6. Remedial Action Report. This section describes the items to be included in a report documenting
the completion of the remedial action activities.

7. References. This section presents a list of selected references used in preparing this document.

8. List of Acronyms/Abbreviations. This section includes a list of acronyms used in this document.

TIERRA-B-015015
2.0 SITE DESCRIPTION

This section presents a Site description and background information for the portion of SA-5 that is the
subject of this document: Baldwin Steel (Site 090), M.L Holdings (Site 184), and the northern portion of
the Former Morris Canal (Site 153) next to the Baldwin Steel and M.L Holdings Sites. The property
comprising Sites 090 and 184 is owned by NJCU. The portion of Site 153 abutting Sites 090 and 184 is
owned by the City of Bayonne Municipal Utilities Authority (BMUA) and is in the process of being
acquired by Honeywell.

2.1 SITE LOCATION


The Baldwin Steel (Site 090) and M.L Holdings (Site 184) properties are located next to each other in
the area between Route 440 and West Side Avenue (Figures 1 and 2). Surrounding land use is
primarily industrial and commercial and includes the former Ryerson Steel Site (Site 117 or Home
Depot site; currently occupied by a retail shopping center) located immediately south of Site 090
(Baldwin Steel); Route 440 Vehicle Corporation (Site 079; currently occupied by a car dealership)
located north of Site 184 (M.l. Holdings) on the opposite side of Carbon Place; the Former Morris Canal
(Site 153) located along the western boundary of Sites 090 and 184 along Route 440; and commercial
areas on the opposite side of West Side Avenue to the east. Further details regarding the subject
properties follow.

Baldwin Steel (Site 090)


The Baldwin Steel property is located at 500 Route 440, designated as Block 1286, Lots 5 and 60 on the
Jersey City tax maps. The property encompasses approximately 6.8 acres, currently owned by NJCU,
and contains the concrete floor slab of one large building previously used for steel fabrication and
distribution.

The property consists of a rectangular parcel (approximately 1,000 feet long and about 300 feet wide)
bordered on the north by M.L Holdings (Site 184), on the east by an inactive rail spur line and property
occupied by NJCU, on the south by a retail shopping center (Site 117; Former Ryerson Steel or Home
Depot site), and on the west by the Former Morris Canal (Site 153) and Route 440. With the exception
of paved parking areas bordering Route 440 and a paved corridor along the south side of the property
(between the former Baldwin Steel building and aforementioned retail shopping center), the property is
covered by the former building slab (estimated 650 feet long by 250 feet wide or 162,000 square feet).

The Baldwin Steel Site was previously used for storage, cutting and rolling of various types of steel (e.g.,
aluminized, galvanized, cold-rolled, etc.), typically used for fabrication into ductwork. Tractor trailers
delivered raw materials via access from West Side Avenue and exited the facility at the western end onto
Route 440. A rectangular office space was located at the rear of the plant and connected the ,plant to an
irregularly-shaped storage building. The building was a large structure constructed of a concrete
foundation, steel colunms, steel and wooden trusses, and corrugated steel siding. The office and storage
buildings were constructed of con'crete foundations and brick. The office building was a one-story
structure, while the storage building was two stories. No sub-grade floors or basements existed in the
building structures, with the exception of press pits located beneath some ofthe heavy equipment used
for cutting and rolling. It is believed that the buildings were constructed prior to 1930.

Site utilities include electrical service, water, sanitary sewer, storm sewer, and fuel oil lines. All utilities
are located underground with the exception of the electrical lines, which include both overhead and
underground lines. An underground water line which provides water to three hydrants on-Site is also

TIERRA-B-015016
located along the roadway on the south side of the former Baldwin Steel building. Potable and non-
potable water entered the former office/storage building and the plant via lines from West Side Avenue
in the northeast comer of the property. The sanitary sewer line ran along the interior of the plant
building and tied into a sanitary sewer line along Route 440.

The Baldwin Steel Site is surrounded by a chain-link fence ranging from four to eight feet in height.
Access to the property is from three gates, one located at the rear of the facility which allows access from
West Side Avenue and two located at the front of the property for access from Route 440. The entire
property is either occupied by building floor slabs or is covered with paving. All areas on the site were
paved as a result of remedial action upgrades during an Interim Remedial Measure (IRM) completed in
1990 by a contractor for Honeywell (formerly Allied Signal). The pavement on the east and south side
(along the Former Ryerson Steel property boundary) of the building is uneven, possibly due to placement
of underlying fill material in this area.

M.L Holdings (Site 184)


The M.I. Holdings property is located southeast of the intersection of Carbon Place and Route 440,
designated as Block 1286.5, Lots 1 & 2 on the Jersey City tax maps. The property encompasses
approximately seven (7) acres and was formerly an active chemical manufacturing facility. The property
is currently owned by NJCU and occupied by several buildings, paved parking lots and landscaped areas.

The M.l. Holdings Site is bordered by Carbon Place to the north, Route 440 to the west, Baldwin Steel
(Site 090) to the south, and property occupied by NJCU to the east. The majority of the property is
paved, with several small lawn areas and a chain-link fence around the perimeter of the property. The
Site contains three (3) buildings and paved parlGng lot areas. In 1993, Woodward-Clyde Associates
completed a remedial action at the Site, which included excavation of mercury/chromium-impacted soils,
building demolition, and asphalt capping. The paved areas are in good condition, with no evidence of
cracks or potholes leading to exposure to underlying fill soils. The property is surrounded by a chain link
fence approximately IO-feet in height, with access to the property from several entrance gates along
Carbon Place and from the eastern side of the property along West Side Avenue. Site physical features
also include overhead utilities (electrical lines) and underground utilities (gas, water, and sewer lines).

Former Morris Canal Site (Site I53)


The Former Morris Canal site consists of a narrow strip of land located along the northbound lane of
Route 440 between Carbon Place and Danforth Avenue, adjacent to former Ryerson Steel (Site 117),
Baldwin Steel (Site 090), and M.L Holdings (Site 184). The property comprising the Former Morris
Canal is designated as Block 1289.5, LotE, currently owned by the BMUA, is approximately 1,500 feet
long by 20 feet wide, including about 700 feet adjacent to Sites 090 and 184. Utilities along the Former
Morris Canal site include storm and sanitary sewer lines, electric, gas and water lines that provide service
to the adjacent commercial and industrial sites. The portion of the Former Morris Canal abutting Sites
090 and 184 is paved and contains a 36-inch diameter sewer pipeline (force main) owned and operated by
the BMUA; the pipeline is constructed of steel with concrete casing support, with the top of the pipeline
situated just below the surface pavement. Honeywell has reached agreement with the BMU A regarding
the purchase of the property comprising Site 153, and anticipates completion of the property transaction
in the next several months.

TIERRA-B-015017
2.2 SITE HISTORY
The operating history for the properties comprising the Site was documented in the Remedial Investigation
Report (RJR) dated November 1999 (TetraTech, 1999). Site history for the Baldwin Steel and M.L
Holdings Sites are summarized below.

Baldwin Steel (Site 90)


The properties comprising the Baldwin Steel Site have been used for industrial purposes for
approximately 100 years. The parcel designated as Block 1286, Lot 6D was deeded to the Mutual
Chemical Company in April of 1895. This property was transferred to AlliedSignal (formerly Allied
Chemical and Dye Company) in August 1955, to Ryerson Steel in 1966, and then to Baldwin Steel in
1970. During its industrial history, this parcel was used to support the production of sodium dichromate
(Mutual Chemical), steel production (Ryerson Steel), or steel cutting and rolling (Ryerson and Baldwin
Steel). During the period of AlliedSignal's ownership from 1955 to 1966, this parcel was a vacant lot.
The adjacent lot, Block 1286, Lot 5, was transferred from John and Mary Winner to Ryerson Steel in
August 1914, and then to Baldwin Steel in 1970. This parcel was used for either steel production,
fabrication, or rolling and cutting of steel throughout its industrial history.

No detailed historical information regarding the placement of Chromium Ore Processing Residue
(COPR) on this property is available. It is believed that chromite ore was stored on a portion of Lot 6D
by the Mutual Chemical Company during approximately 60 years of operation.

M.l. Holdings (Site 184)


The M.I. Holdings Site was used by industrial or commercial enterprises for over 90 years. A portion of
the property was deeded to the Chicago Railroad Equipment Company in 1899, and another portion was
leased to Kewanee Manufacturing through 1909. A portion of the property was subsequently deeded to
Rudolph Chillington (1912), Chillington Manufacturing Company (1914), and Mallinclcrodt Chemical
Works (1939). Another portion of the property was deeded to the Mallinckrodt Chemical Works in 1918.

Prior to 1940, Mallinclcrodt produced inorganic chemicals such as salts or oxides of iron and mercmy.
During the 1940s, Mallinckrodt participated in the Manhattan Project under contract with the U.S.
Government for the testing of uranium trioxide. Mter World War II, the plant continued to produce
mercury compounds and other inorganic chemicals such as zinc acetate, potassium sulfate, potassium
chloride, ferrous sulfate, ferric chloride, and sodium nitrate. Production of mercury compounds ended
around 1974, when general facility improvements were made including demolition of the mercury
production equipment and various buildings. The majority of the open areas on the property were paved
at that time.

From thc 1940s to approximately 1980, Mallinckrodt also conducted packaging operations (both wet and
dry operations) at the facility for a variety of both organic and inorganic chemicals. Some of the liquid
packaging operations included preparation of bottles of alcohols, acetone, xylenes, benzene and toluene.
Organic liquids were received by railroad or truck in drums and carboys before packaging in bottles. The
bottled liquids were stored in various warehouses at the facility. Mineral acids and ethers were also
received by railroad for packaging operations. In the late 1970s, most ofMallinckrodt's operations
decreased to the production or packaging of the chemicals noted above as a result of the transfer of
material handling and sub-division (packaging) operations to a new plant in Kentucky. In the early
1980s, Mallinckrodt's production of chemicals was primarily limited to calcium and zinc stearate
dispersions. All other production operations (packaging of organic and inorganic chemicals) ceased by
1982. Zinc stearate dispersion production ceased in the late 1980s. More recent operations by M.I.
Holdings were limited to the production of calcium stearate dispersions. As previously noted, a remedial

TIERRA-B-015018
action was conducted on behalf ofM.I. Holdings by Woodward-Clyde Associates during 1993. The
remedial action consisted of excavation of mercury/chromium-impacted soil, building demolition and
asphalt paving as a cap. A deed notice and classification exception area (CEA) was also established for
the western portion of the site.

Former Morris Canal (Site 153)


Historical information and maps indicate that the fonner Morris Canal was located along the area now
occupied by Route 440 (formerly Route 9W) during the 1800s and early 1900s, and that the canal was
closed during the 1920s and subsequently filled in. Historical maps indicate that a railroad line (Lehigh
Valley Railroad) was also located along the area of the former canal during the early to mid-1900s.
Chromite ore production residue (COPR) was allegedly used as fill for a portion of the former canal.
During 1990, the City of Bayonne excavated a section of the former Morris Canal, installed a sewage
pipeline, and backfilled the excavation with clean fill. Pursuant to a "Release and Agreement" reached
between the City of Bayonne and Allied-Signal, Inc., the City of Bayonne was responsible for the
excavation and disposal of soils containing hazardous substances and/or wastes as part of the sewer line
installation project. The property was paved with asphalt following installation of the sewer line.

2.3 ENVIRONMENTAL SETTING

2.3.1 Regional and Site Geology


Information on regional and Site geology is presented below based on information from the RIR
(TetraTech, 1999) and the ongoing regional groundwater investigation associated with Study Area 7
(HydroQual, 2005; 2007). Relevant reference information and figures are included in Appendix A.

Regional Geology
Jersey City is located within the upper portion of the drainage basin for Newark Bay, and lies within the
glaciated section of the Piedmont Province. The bedrock in most of the region is comprised of Lower
Jurassic to Upper Triassic age sedimentary rock units known as the Newark Supergroup, and was formed
from sediments deposited within a northeast-southwest trending structural basin known as the Newark
Basin. The sedimentary rocks of the Newark Supergroup in New Jersey are composed of reddish-brown
arkosic sandstone, mudstone, siltstone, conglomerate, and dark gray argillite. These sedimentary rock
units have been intruded by igneous rock units (primarily diabase) in the form of sills and dikes, which
now generally form ridges such as the Palisades and the Heights in Jersey City.

The Newark Supergroup has been divided into three formations on the basis of distinctive lithology: (1) a
lower unit identified as the Stockton Formation; (2) a middle unit identified as the Lockatong Fonnation;
and (3) an upper unit identified as the Brunswick Group. Based on geologic mapping performed across
northern New Jersey, including Study Area 5 (Drake, Jr., et aI., 1996), it is anticipated that SA-5 overlies
a contact between the predominantly mudstone units of the Lockatong Formation and the north-northeast
trending diabase dike to the east. Regional mapping also indicates a north-northeast trending, southeast
dipping normal fault lies approximately one-half mile east of the Site. Additional geologic information is
currently being collected as part of the SA-7 investigation.

The beds of the Newark Supergroup generally strike to the northeast in the Hackensack River basin and
dip at approximately 16 degrees to the west-northwest. A prominent set of vertical joints strike N 45° E,
approximately parallel to the strike of the beds. A less prominent set of nearly vertical joints strike north
75 degrees west, sub-parallel to the dip of the bedding (Anderson, 1968). Faults, where present, typically
strike northeastward and are parallel to or intersect the strike of the beds at low angles. The bedrock
surface is irregular, shaped by pre-glacial and interglacial streams and further modified by glacial scour.

TIERRA-B-015019
The bedrock surface is overlain by glacial till/stratified lacustrine deposits, and alluvialliacustrine
deposits laid down by several glacial advances across the area, principally during the Wisconsin glacial
period. The glacial till is generally described as an unsorted mix of sand, gravel, silt and clay in a
continuous layer overlying bedrock, as well as in discontinuous lenses within the stratified lacustrine
deposits. The lacustrine deposits generally consist of very fine sand, silt and clay with noticeable
layering and varves characteristic of alluvial deposition. The alluviaVlacustrine deposits are typically
characterized as a fine to medium sand with some silt that appear to coarsen to the east.

The various glacial deposits are typically overlain by Holocene age alluvium deposited within the
floodplains of present day streams. Meadow mat, consisting of decaying marsh deposits, is also found in
many low lyin g areas and much of the region has been artificially filled with material of varying
composition in an effort to raise the ground surface above the surrounding surface water features.

Site Geology

Fill Material
The majority of the ground surface at the Site is covered with asphalt pavement (parking lots, roads) or
buildings, which overlie a continuous layer of man-emplaced fill material. The fill ranges in thickness
from approximately 5 to 17 feet, with an average thickness of 10 to 12 feet, and generally consists of silty
sand with miscellaneous construction debris such as gravel, brick, glass, wood, and concrete. Slug test
results for the fill zone indicate generally low permeability on the order of approximately 0.5 feet/day.

Meadow Mat
Meadow mat consists of a highly organic deposit of peat and fine-grained sediments that occurs in a thin
layer in the western portion of the Site. Meadow mat is generally not present beneath the majority of the
Site further east from the fonner Moms Canal.

Lacustrine Sand
The Lacustrine Sand has generally been described as a fine to medium sand with some silt that directly
underlies the fill material and meadow mat (where present). Occasional discontinuous layers of brown-
gray sand are present near the top of the unit as are fine-grained silt lenses throughout. This unit
correlates to the S-2 Sand identified beneath SA-7. The thickness of this unit general1y increases from
east to west and from north to south and is bifurcated beneath SA-7 by a red clay unit. Three (3) slug
tests conducted in the Lacustrine Sand during the Rl suggest hydraulic conductivity values on the order
of 0.5 feet/day, whereas eleven slug tests constructed in wells screened within this stratum beneath SA-7
suggest hydraulic conductivity values on the order of 5.0 feet/day.

Glacial Till Lacustrine Deposits


This unit consists of ice contact stratified drift including fine sands with inter-layered seams of silt and
clay. Occasional lenses of coarse sand and gravel have also been observed in this unit. The limited data
available on these deposits suggest hydraulic conductivities on the order of 0.1 ft/day.

Bedrock
The bedrock consists of the Triassic age Lockatong formation of the Newark Supergroup and may be
underlain in the eastern most area by Diabase. The bedding planes dip generally to the northwest at
approximately 15 degrees while the bedrock surface generally slopes to the southwest. The bedrock is
approximately 110 ft below ground surface in the vicinity of the SA-5 (HydroQual, February, 2007).

TIERRA-B-015020
2.3.2 Regional and Site Hydrogeology

Regional Hydrogeology
The Site is located in a broad area of low relief near Newark Bay, with expected low groundwater
gradients. Close to the bay, shallow groundwater is influenced by tidal fluctuations, with low-lying and
marshy areas being only slightly above high tide. Regionally, groundwater flow is generally toward the
major water bodies in the area, including the Hackensack River, Passaic River, and Newark Bay. These
major water bodies serve as regional groundwater discharge points and hydrogeologic boundaries. The
size and influence of these water bodies is such that groundwater will not migrate across them, but will
discharge to the rivers and the bay.

The groundwater underlying the Hudson County Chromium Sites can be characterized as a multi-aquifer
system. In general, there are two water-bearing zones/systems underlying the study area: (I) a surficial
water-bearing zone within unconsolidated materials consisting of man-deposited fill, glacial drift
(composed of clay, silt, sand, gravel, and boulders), fluvial fine- to medium-grained sand, and (2) the
underlying water-bearing zone within fractured bedrock.

Groundwater in the shallow, unconfined to semi-confined water-bearing zone is recharged through direct
infiltration of precipitation. Groundwater movement within this zone is through pore spaces between
sediment grains. Depths to groundwater vary from less than one foot to 10 feet bgs or more. The
direction of shallow groundwater flow is toward local surface waters that serve as groundwater discharge
points, including small, unnamed drainages, the nearby rivers, and Newark Bay. Close to the rivers and
the bay, shallow groundwater is tidally influenced.

Site Hydrogeology
Groundwater beneath the Site occurs within the fill material and underlying lacustrine sand deposits
under unconfined conditions, and within the underlying bedrock under confined or semi-confined
conditions. A layer of meadow mat in the western portion of the Site, separates the fill material from the
underlying natural formations. Where the meadow mat is absent, the two units may be in contact.

Existing data shows that the upper (fill) and deeper (natural) groundwater bearing zones are distinct,
where separated by the meadow mat. Groundwater flow pattern and direction are different in the two
units. Contaminant distribution profiles in the two units are also distinct. Chromium is the only
contaminant detected in the deeper zone, while a suite of contaminants has been detected in the shallow
zone. The SA-7 investigation has shown that, where the meadow mat is present, chromium has not
migrated vertically from the shallow to the deeper zones. Based on these data, it has been concluded that
contamination in the shallow zone above the meadow mat is associated with chromium-impacted fill,
while contamination in the deeper units is related to historical discharges at the former Mutual Chemical
facility located south of the Site.

Groundwater flow in the area of the Site has been mapped as part of the comprehensive SA-7
investigation, which has identified four hydrostratigraphic zones as follows:

Shallow Zone - above the meadow mat and generally in fill material
Intermediate Zone - just below the meadow mat (generally not present beneath SA-5)
Deep Zone - within the lacustrine deposits just above the glacial till/ice contact deposits
Upper Bedrock Zone - Just below the top of bedrock

10

TIERRA-B-015021
Regional groundwater contour maps for the Shallow and Deep Zones are presented on figures in
Appendix A. The groundwater contour maps indicate that groundwater flow in the fill material (Shallow
Zone) is generally to the west or northwest and is strongly influenced by near surface features such as the
stonn sewer along Route 440. Groundwater flow in the lacustrine deposits (Deep Zone) is similarly to
the west-northwest, with little or no influence from near surface features, thus groundwater flow
continues west and northwest to the Hackensack River. Groundwater flow within the Upper Bedrock
Zone beneath SA-7 is to the northwest, and similar conditions are expected beneath the Site.

As previously indicated, slug test data for the Shallow Zone (Fill) indicate a relatively low permeability
for the fill material of approximately 0.5 feet/day, with an estimated flow velocity of 3 feet/year based on
average gradient of 0.005 and porosity of 30% (TetraTech, 1999). Slug test data for the Deep Zone
(Lacustrine Sand) indicate hydraulic conductivity values on the order of 5.0 feet/day, with an estimated
flow velocity on the order of 18 feet/year based on an average hydraulic gradient of 0.003 and porosity of
30%. Limited data available for the glacial till/ice contact deposits suggest hydraulic conductivities on
the order of 0.1 feet/day.

Based on information from the RIR, there are no public water supply wells located in Hudson County. A
previous file search was conducted during 1999 at the NJDEP Department of Water Allocation Division
office in Trenton, NJ. Coordinates of the study area were supplied, and microfilm records of wells
within one mile of the study area were obtained. A review of the information indicates that there are no
industrial or public water supply wells down-gradient from the Site.

2.3.3 Site Topography and Surface Water


The ground surface at the Site is relatively flat, bordered by Route 440 to the west and West Side Avenue
to the east. Ground surface elevations range from approximately 8 to 20 feet above mean sea level
(MSL), with the highest elevations on the eastern portion of Site 090 (Baldwin Steel). Historically,
ground surface elevations were approximately 5 to 10 feet lower prior to placement of fill across the area.
The ground surface at Site 090 (Baldwin Steel) is approximately 5 to 10 feet higher than the ground
surface at the Site 184 (M.I. Holdings), indicating a greater amount of fill on Site 090 (Baldwin Steel).
Surface water runoff in the area of the Site is controlled by surface pavement and storm water catch
basins located within the Site property and along surrounding streets.

The Fonner Morris Canal runs north-south along the western boundary of the Site along Route 440. The
portion ofthe canal through Jersey City opened in 1836 and was filled with salt water, and this section of
the canal was equipped with tide locks at both ends that prevented the water from flowing out at low tide
(http://www.jerseycityonline.comlmorris_cana1.htm). The canal was closed and drained in 1924. The
canal was subsequently filled in and no visual evidence of the former canal exists. The majority of the
former canal area is now covered with pavement, and the portion of the former canal next to the Site
contains a sewer line.

No surface waters are present at or adjacent to the Site. The principal water bodies in the vicinity of the
subject Site include the Hackensack River, Passaic River, and Newark Bay. The nearest surface water
body is the Newark Bay, located approximately 4,000 feet to the west. The Site is located within the
Hackensack River basin, which extends northward from Newark Bay into southeastern New York State.
The Hackensack River is used for water supply in the upper reaches of the basin; however, in the vicinity
of the Site, the river is classified as SE-3 (saline estuarine waters) with the following designated uses:

1. Secondary contact recreation;


2. Maintenance and migration of fish populations;

II

TIERRA-B-015022
3. Migration of diadromous fish;
4. Maintenance of wildlife; and
S. Any other reasonable uses

Several municipalities draw water from the river during the summer months, resulting in very little net
flow in the lower reaches of the river during the time periods of water diversion from the river. This
results in poor flushing of the lower reaches (tidal portion) of the river during these time periods.

The Hackensack River is tidally influenced along the reach adjacent to Jersey City. According to
National Oceanic and Atmospheric Administration (NOAA) records, the mean tide level of the
Hackensack River in the area of Jersey City is approximately 2.84 feet above MSL and the mean tide
range is approximately 5 feet. Water quality in the Hackensack River is affected by industrial discharges
(over 100 permitted discharges into the river) and by the tides. Low dissolved oxygen levels are common
in the river during the summer, and total dissolved solids levels are slightly to moderately saline.

2.4 CURRENT AND FUTURE LAND USE


Currently, Site 090 (Baldwin Steel) is inactive and consists of a vacant fenced lot with the majority of the
ground surface covered with building structures and pavement. Site 184 (M.I. Holdings) consists of a
fenced paved [at with several buildings and small landscaped areas. As previously indicated, these
properties are proposed to be redeveloped by NJCU into a mixed use facility consisting of student housing,
retail, and other residential and educational functions. Preliminary Site plans for the NJCU development
project are included as Figure 2. Demolition activities (including the former Baldwin Steel building) were
performed during 2006. The current estimated Site redevelopment schedule includes construction
beginning during the latter part of2008.

2.5 PREVIOUS INVESTIGATIONS/REMEDIALACTIONS

Previous investigations and remedial actions conducted at Site 090 (Baldwin Steel) and Site 184 (M.l.
Holdings) prior to the Rl are summarized in this section, along with information on Site 153 (Fonner
Morris Canal) located along the western boundary of Sites 090 and 184. R1 results based on the findings
from the RlR and RIR Addendum are presented in Section 3.0.

Baldwin Steel (Site 90)


Samp] ing of surface and subsurface fill material was conducted in March 1989 by Langan Environmental
Services, Inc. (Langan, 1989). In addition to total chromium analysis, qualitative colorimetric analysis
for hexavalent chromium was conducted. A total of nineteen (19) samples were collected over a grid
system around the perimeter of the Baldwin Steel building. Total chromium concentrations ranged from
125 mglkg to 15,810 mg/kg. Colorimetric responses indicating the potential presence of hexavalent
chromium were noted in all but two of the samples collected. NJDEP conducted a building inspection on
January 12, 1994. As a result of this inspection, the NJDEP concluded that there was no visual evidence
of chromate contamination at the facility.

A contractor for Allied Signal, Inc. completed an Interim Remedial Measure (asphalt cap) at the Baldwin
Steel Site in 1990. Capping of areas of exposed soil was completed during the Interim Remedial
Measure. This remedial measure was completed to prevent direct contact exposures, control potential
fugitive dust emissions, reduce percolation of precipitation, and prevent overland runoff of chromium
containing materials. A contractor for Allied Signal, Inc. also upgraded the asphalt cap by placement and
rolling of additional asphalt along the southern fence line in October 1994.

12

TIERRA-B-015023
M.1. Holdings (Site 184)
SamplIng and analysis of soil and groundwater were conducted by A WD Technologies and Woodward-
Clyde Consultants. A WD Technologies installed six (6) monitoring wells at the Site in 1987 (three
shallow and deep clusters) and sampled these wells on three occasions in 1987 and once in 1988. In
addition, three (3) soil samples were collected during the installation of these wells. In 1993, Woodward-
Clyde collected surface and subsurface soil samples at 17 locations in the southwestern comer of the
property and subsequently collected eight (8) post-excavation sidewall samples. Woodward-Clyde also
completed one round of monitoring well sampling and analysis in 1993. Total chromium concentrations
were detected in soil samples up to 36,000 mglkg. Total chromium concentrations were detected in
unfiltered and filtered groundwater samples up to 2.24 mg/I and 2.0 mg/I, respectively.

A remedial action was conducted at the M.l. Holdings Site by Woodward-Clyde in 1993. The remedial
action was conducted to remediate (remove) soil containing mercury. Based on a summary report
prepared by Woodward-Clyde, approximately 900 cubic yards of sail/fill were excavated from three
areas located in the southwestern comer of the property. Excavation depths ranged from two to
three feet. A narrow strip of land along the western boundary of the Site was not remediated. This
portion of the Site was investigated during the RI for soils.

TetraTech, Inc. on behalf of New Jersey City University (NJCU) performed additional RI activities on
the Site during 2004-2006 to address non-chromium contaminants under a Memorandum of Agreement
with the NJDEP. The additional RI activities included geophysical survey, test pit investigation, soil and
groundwater sampling, and baseline ecological evaluation (BEE). The results of these activities were
documented in a Remedial Investigation ReportlRemedial Action Work Plan (RIRIRA WP) (TetraTech,
February 2006), which is currently under review by the NJDEP. The recommendations proposed in the
RIRJRA WP include pre-design investigations, investigation of catch basins and sewer lines, investigation
of sub-slab areas following removal of building slabs, and further delineation of chlorinated VOCs (e.g.,
carbon tetrachloride) in groundwater. The recommended remedy includes extension of the existing cap
and deed notice area to cover the entire Site, and maintaining the existing CEA for residual groundwater
contamination. A figure illustrating the proposed remedial actions is included in Appendix A-5.

Former Morris Canal (Site 153)


The property comprising the Former Morris Canal Site consists ofa narrow strip ofland along the
shoulder of Route 440 North. The portion of the Former Morris Canal Site located adjacent to Sites 090
(Baldwin Steel) and 184 (MI Holdings) is approximately 700 feet long and 40 feet wide. In 1990, the
City of Bayonne excavated a section of the former Morris Canal, installed a sewage pipeline, and
backfilled the excavation with clean fill. Pursuant to a "Release and Agreement" reached between the
City of Bayonne and Allied-Signal, Inc., the City of Bayonne was responsible for excavation and disposal
of soils containing hazardous substances and/or wastes as part of the sewer line installation project. The
property was paved with asphalt following installation of the sewer line. Previous investigations on the
portion of the Former Morris Canal Site adjacent to Sites 0901184 were conducted during 1997-1999 and
documented in the RIR dated November 1999. The Rl results are discussed in Section 3.

13

TIERRA-B-015024
3.0 SUMMARY OF REMEDIAL INVESTIGATION RESULTS

3.1 GENERAL OVERVIEW

This section presents a summary of the RI results for Baldwin Steel, M.L Holdings, and the northern
portion of the Fonner Morris Canal based on information presented in the RIR and RIR Addendum
(TetraTech. 1999; 2004). A more detailed discussion of the RI data including results for other sites
comprising SA-5 is presented in the RIR dated November 1999. Additional soil delineation data for
Baldwin Steel and M.l. Holdings is presented in the RIR Addendum dated September 2004. Relevant
data summary tables and figures from the RlR Addendum are included for reference in Appendix A.
Comprehensive soil analytical data for hexavalent chromium (including the extent of soils containing
hexavalent chromium above 20 mglkg) is presented on Figure 3.

This section also presents results of additional Rl activities completed during 2005, as specified in the
March 2005 RIWP Addendum for Shallow Groundwater submitted to the NJDEP. The additional Rl
activities were conducted to collect additional data for evaluation of remedial actions for chromium
contaminated fill that may be acting as a potential source of shallow groundwater impacts at the Site, and
included additional soil borings and monitoring wells. Copies of well permits are provided in Appendix B.

3.2 RIWP ADDENDUM FOR SHALLOWGROUNDWATER (2005)

3.2.1 Soil Borings/Soil Sampling

A total of nine (9) soil borings were advanced using hollow-stem auger (HSA) drilling methods and/or
direct-push sampling equipment. The borings included seven (7) locations in the western portion of Site
90 (Baldwin Steel) and two (2) locations on Site 184 (M.!. Holdings), designated as follows:

090-$B-001: within area of chromium-impacted soils beneath existing building


090-SB-002: within area of chromium-impacted soils in western portion of property
090-SB-003: refine horizontal delineation in south-central portion of property
090-SB-004: refine horizontal delineation in south-central portion of property
090-SB-005: refine horizontal delineation in south-central portion of property
090-MW -010: within area of chromium-impacted soils in southwest portion of property
090-MW -011: upgradient of existing monitoring well MW -090-EO 1
l84-MW -00 l: upgradient of chromium-impacted fill soils
184-MW -002: within area of chromium-impacted soils in northwestern portion of property

Soil borings were advanced to a maximum depth of approximately 20 feet bgs, and soil samples were
collected using split-spoon samplers. Soil samples were visually inspected for the presence of COPR
(e.g., yellow-green or colored staining or nodules), and field screened for the presence of organic vapors
using a photo-ionization detector (PID). Soil boring logs are included in Appendix C.

Soil samples were collected from three (3) locations (090-S8-003, 004,005) and submitted for laboratory
analysis for total chromium and hexavalent chromium to provide additional data for delineation beneath
the existing building. Selected soil samples were also submitted for laboratory analysis for Synthetic
Precipitation Leaching Procedure (SPLP), total and hexavalent chromium. Selected samples were also
collected and submitted for grain size analysis. Sample depth intervals for SPLP analysis corresponded

14

TIERRA-B-015025
to depths with elevated hexavalent chromium based on previous soil data. A surrunary of the soil and
SPLP sample results is presented in Table lA and grain size analysis results are included in Table IB.

Laboratory analytical parameters and methods for the soil sampling program included:

SPLP by USEP A Method 1312 with totaVhexavalent chromium analysis on the leachate
Total Chromium by USEPA Method 3050B/601GB
Hexavalent Chromium by USEPA Method 3060AJ7l96A
Grain Size by ASTM Method D422

Data validation was performed by Validata, LLC of Seattle, W A. Data validation procedures included
validation of all samples analyzed for chromium and hexavalent chromium. Based on the data validation
results, the laboratory analytical data were determined to be acceptable, with minor qualifications. Soil
sample laboratory reports and data validation summary reports are included in Appendix F. Electronic
data deliverables are provided in Appendix M.

AIL soil sampling locations were surveyed for horizontal coordinates and surface elevations by Keller &
Kirkpatrick of Parsippany, NJ. The horizontal datum was established to within 0.10 foot using the New
Jersey System of Plane Coordinates (NAD 83). Vertical elevations were established to within 0.01 foot
using the North American Vertical Datum (NA VD 88).

3.2.2 Groundwater Investigation

Four (4) shallow monitoring wells were installed during April 2005 to depths ranging from 12 to 16 feet
bgs. The monitoring wells are identified as follows:
090-MW-OlO: within area of chromium-impacted soils in southwest portion of property
090-MW-011: perimeter of chromium-impacted area, upgradient of existing well MW-090-EOI
184-MW-001 : upgradient of chromium-impacted soils
184-MW-002: within the area of chromium-impacted soils in the northwest portion of the property

Monitoring wells were installed using HSA drilling methods and constructed of 2-inch diameter schedule
40 PVC well materials, with flush mount protective casing.· Following installation, each monitoring well
was developed in accordance with NJDEP requirements to remove drill cuttings and/or formation fines
from the well screen. Monitoring wells were screened across the water table to provide groundwater
quality data for the shallow water-bearing zone (fill). Monitoring well records and construction diagrams
are provided in Appendix D. A surrunary of the construction details is provided below.

Monitoring Well Sampling Summary/Construction Details


Monitoring Well ID Well
Depth
I Interval
Screen Well Diameter 1 Site Location
'"090-MW.01O ] 16.0' Ll9~!~Q'_ I
..~__. 2-inch 1 Baldwin Steel (Site 090)
090-MW-Oll 16.0' 6.0-16.0' 2-inch Baldwin Steel (Site 090)
090-MW-EOI 14' 10-14' 2-inch Baldwin Steel (Site 090)
184-MW-OOI 12' 2-12' 2-inch MI holdings (Site 184)
!184-MW-002 j 12' I2-12' I 2-inch I MI holdings (Site 184)
L2Q-MW-8A* I 18' I3-18' I 2-inch I Baldwin Steel (Site 090)
• 90-MW-8A was Installed dUring recent RI actIVItIes by NJCU; sampled dUring second round only (May 31, 2005)

15

TIERRA-B-015026
Two (2) rounds of groundwater sampling were completed during 2005 including one round on April 28,
2005 and a second round on May 31, 2005. Three (3) rounds of groundwater sampling were completed
during 2006 as follows: May 10,2006, August to, 2006, and December 13, 2006. Groundwater
monitoring well sampling procedures included low flow purge/sample methods. Field sampling included
water level measurements and the collection of field parameters including pH, temperature, conductivity,
dissolved oxygen (DO), and reduction-oxidation potential (Redox). Groundwater sampling field data
sheets and groundwater contour map reporting forms are included in Appendix E.
HydroPunch groundwater samples were also collected during soil boring activities from two soil borings
(SB-003 and SB-005) and analyzed for total and hexavalent chromium (unfiltered and filtered) to provide
additional data on shallow groundwater for the southern portion of the Site beneath the existing building.
Groundwater grab sample 090-PZ-OOl was collected from 090-SB-003 borehole, and sample 090-PZ-002
was collected from 090-SB-005 borehole. The screened interval at both locations was from 3 to 13 ft bgs.

Groundwater samples were submitted for laboratory analysis for total and hexavalent chromium
(unfiltered and filtered). The first round of sampling also included the following additional watcr quality
parameters to provide additional data for evaluation of natural attenuation and groundwater treatment
options: pH, alkalinity, calcium, iron, magnesium, ferrous iron, sulfate, and total organic carbon (TOC).
Groundwater sampling results for samples collected during 2005 and 2006 are summarized on Tables 3
and 4, respectively.

Laboratory analytical parameters and methods fOT groundwater samples included:


Total Chromium using USEPA Method 6010B
Hexavalent Chromium USEPA Method 7196A
Other Water Quality Parameters: pH (Method 150.1); Alkalinity (Method 310.1); Calcium, Iron and
Magnesium (Method 60 lOB); Ferrous Iron (Method 3500-Fe), Sulfate (Method 375.4), Sulfide (Method
376.1), Total Organic Carbon (Method 415.1)

The groundwater sampling completed during May 2006 included analysis of additional parameters
including Target Analyte List (TAL) metals, chlorides, hardness, nitrates, salinity, specific conductance,
sulfides and total dissolved solids (TDS). Data validation was performed by Validata, LLC of Seattle,
W A Data validation procedures included validation of all samples analyzed for chromium and
hexavalent chromium, and approximately ten (10) percent of samples analyzed for other parameters
following NJDEP standard operating procedures for validatlon of analytical data. Based on the data
validation results, the laboratory analytical data were determined to be acceptable, with some
qualifications. Two (2) groundwater grab samples (filtered samples) (90-PZ-00IF and 90-PZ-002F)
submitted for hexavalent chromium analysis were rejected because the samples exceeded the required
holding time; however total chromium results were acceptable for these locations. Groundwater sample
laboratory reports and data validation summary reports are included in Appendix G. Electronic data
deliverables are provided in Appendix M. Groundwater elevation data are presented in Table 5.
Groundwater contour mapss are included as Figures 4A through 4E. Groundwater contour reporting
forms are contained in Appendix E-2.

16

TIERRA-B-015027
3.3 SOIL INVESTIGATION RESULTS

The Rl soil investigation activities were conducted in several phases, with results summarized below.

3.3.1 Remedial Investigation Report (1999)

The RI soil investigation was conducted in several phases during 1997 to 1999 and reported in the Draft
RIR (Tetra Tech NUS, Nov, 1999). A total of 47 soil borings (up to 8 feet bgs) were completed on the
subject Sites, including 15 borings at Baldwin Steel, 12 borings at M.I. Holdings, and 20 borings within the
Former Moms Canal. Samples were collected from selected depth intervals for submittal for laboratory
analysis for total and hexavalent chromium. Approximately ten percent of the soil samples were also
analyzed for Target Compound List (TCL) volatile organic compounds (VOCs), semi volatile organic
compounds (SVOCs), and pesticide/polychlorinated biphenyls (PCBs); TAL metals; and total petroleum
hydrocarbons (TPH).

Baldwin Steel (Site 090)


Surface Soil: Chromium (total) was detected in all of the 15 surface soil samples at concentrations
ranging from 26.6 mglkg to 10, 100 mg/kg, with the maximum concentration detected in sample 090-SB-
B02 (0-2 ft) collected in the southeast portion of the Site. Hexavalent chromium was detected in 14 of 15
surface soil samples at concentrations ranging from 7.6 mg/kg to 739 mg/kg, with the maximum
detection in the sample 0-2 ft sample from 090-8B-B08, collected near the southern boundary ofthe
property. Other constituents detected in surface soil samples included several VOCs (methylene
chloride, toluene, xylenes) at trace concentrations (less than 1 mgfkg), below the NJDEP Soil Cleanup
Criteria (SCC). PARs and metals were also detected at concentrations below the SCC.

Subsurface Soil: Chromium (total) was detected in all of the 82 subsurface soil samples, with the
maximum concentration (36,800 mg/kg) detected at sample location 090-5B-808 collected from a depth
interval of 12 to 14 feet bgs near the southern boundary. Hexavalent chromium was detected in 61 of 82
subsurface soil samples at concentrations ranging from 2.6 mg/kg to 8,210 mg/kg, with maximum
concentration (8,210 mg/kg) in sample 090-SB-EOl, collected from a depth interval of 8 to 10 feet bgs in
the western portion of the Site. No other anatytes were detected above the NJDEP sec, with the
exception of arsenic in two samples (samples 090-8B-B02, 2-4 ft bgs: 42 mg/kg and 090-SB-C03 10-12
ft bgs: 39 mglkg) above the sce of20 mg/kg.

M.1. Holdings (Site 184)


Surface Soil: Chromium (total) was detected in all of the 12 surface soil samples at concentrations
ranging from 13.6 mg/kg to 19,800 mgikg. Hexavalent chromium was detected in 10 of 12 surface soil
samples at concentrations ranging from 2.7 mg/kg to 368 mglkg. The maximum detection of total and
hexavalent chromium was in the 0-2 ft sample from 184-SB-A09, located in western part of SA-So

Subsurface Soil: Chromium (total) was detected in all of the 56 subsurface soil samples at concentrations
ranging from 3,5 mg/kg to 35,000 mg/kg. Hexavalent chromium was detected in 26 of 56 subsurface soil
samples at concentrations ranging from 2.6 mglkg to 8,080 mg/kg. The maximum concentration of total
and hexavalent chromium was detected at I 84-SB-A03, collected from a depth interval of 4 to 6 feet bgs
along the northwest comer of the Site.

Other constituents detected in subsurface soil samples included several VOCs (benzene, chloroform,
methylene chloride, dichlorobenzene, ethylbenzene) at low concentrations (less than 1-2 mg/kg) below

17

TIERRA-B-015028
the sec. PAHs and metals were also detected at concentrations below the sec, with the exception of
copper (Sample 184-SB-A02-0406: 659 mg/kg) detected slightly above the SCC of 600 mglkg.

Former Morris Canal (Site 153)


A total of 26 borings were installed to characterize the former Morris Canal (Site 153), including five (5)
borings (15 3-SB-AO 1 through ADS) within the portion of Site 153 next to Baldwin Steel (Site 090) and
M.l. Holdings (Site 184).

Surface Soils: Chromium (total) was detected in all five surface soil samples at concentrations ranging
from 59.3 mglkg to 11,200 mglkg (153-SB-05). Hexavalent chromium was detected in all five surface
soil samples at concentrations ranging from 5.4 mglkg to 624 mglkg. The maximum detection of total
and hexavalent chromium (total) was at sample location 153-SB-A05 (0-2 fi bgs), collected near the
southwest corner of Site 090. Surface soil samples were not analyzed for any other parameters.

Subsurface Soil: Chromium (total) was detected in all of the subsurface soil samples at concentrations
ranging from 9.8 mglkg to 39,800 mg/kg. Hexavalent chromium was also detected in all of the
subsurface soil samples at concentrations ranging from 2.5 mg/kg to 9,150 mg/kg. The maximum
concentrations of both total and hexavalent chromium were detected in sample 153-SB-A05, collected
from a depth interval of 6-8 ft bgs near the southwest corner of Site 090.

Benzene was detected in sample 153-SB-A03 (1.3 mg/kg; 8-10 ft bgs) slightly above the NJDEP Impact
to Groundwater Soil Cleanup Criteria of 1 mglkg near the western boundary of Sites 090 and 184.

3.3.2 Remedial Investigation Report Addendum (October 2004)

The RIR Addendum (Tetra Tech NUS, Oct. 2004) presents results of additional soil borings and
sampling conducted during 2003 on the properties subject to redevelopment by NJCU, including 34
borings at Site 090 (Baldwin Steel) and 12 borings at Site 184 (M.L Holdings). Approximately 440
samples were analyzed for total and hexavalent chromium. The report also includes sampling results for
the portion of the Former Morris Canal adjacent to the Baldwin Steel and M.I. Holdings Sites.

Total chromium concentration ranged from 1.9 to 69,600 mg/kg, with the highest concentration detected
at090-SB-20 (8-10 ft bgs) in the southwestern portion of Site 090 (Baldwin Steel). Hexavalent
chromium concentration ranged from less than 2 mglkg to 28,400 mg/kg in sample 090-88-114, which
was collected at a depth of 6 to 8 feet bgs in the southwestern portion of Site 090 (Baldwin Steel).

Three (3) additional borings (184-SB-13, 184-SB-14, and 090-SB-37) were completed by Tetratech in
February 2005 to provide additional data in the eastern portion of the Site. A total of30 soil samples
were collected and analyzed for total and hexavalent chromium from various depth intevals, and results
indicated that hexavalent chromium was detected above 20 mg/kg in one sample (090-SB-13; 88.4 mg/kg
at 0-2 ft bgs). All other samples contained less than 20 mg/kg of hexavalent chromium.

The RI soil data indicate that the horizontal and vertical extent of hexavalent chromium above the
NJDEP soil cleanup criteria of 20 mg/kg was delineated (Figure 3). The portion of the proposed
redevelopment area impacted by hexavalent chromium concentrations is along the western and
southwestern boundaries (estimated at approximately 4.5 acres). The impacted area is bounded by the
Baldwin Steel (Site 090) boundary to the south (adjacent Site 1 17 has already been capped by
Honeywell), the Morris Canal Site to the west (where RI efforts are ongoing), and clean borings (no
exceedances of 20 mglkg) to the north and east within the Baldwin Steel and M.L Holdings property

18

TIERRA-B-015029
boundaries. Hexavalent chromium concentrations slightly above 20 mglkg were detected in shallow soils
beneath existing pavement at a few isolated locations outside the main chromium-impacted fill area.

Hexavalent chromium results exceeding the NJDEP soil cleanup criteria are indicated on Figure 3. The
RIR and RIR Addendum text and tables with soil sample results for total and hexavalent chromium are
included in Appendix A for reference.

3.3.3 RIWP Addendum for Shallow Groundwater (April/May 2005)

Soil samples were collected from three (3) locations (090-SB-003, 090-SB-004, 090-SB-005) to provide
additional data for horizontal delineation in the southern portion of Site 090 beneath the existing building
(as indicated on Table 1 and Figure 3). Total chromium concentrations ranged from 4.1 mg/kg to 555
mglkg, with the maximum concentration of total chromium detected in sample 090-SB-003 (12-14 feet
bgs). Total chromium did not exceed the NIDEP sce of 120,000 mglkg for trivalent chromium.
Hexavalent chromium concentrations were less than 20 mglkg, with the exception of one sample: 090-
SB-003 (91.3 mglkg at 12-14 ft bgs). Grain size analysis was performed on samples obtained from
locations 090-SB-00l, 090-SB-002, 090-8B-003, 090-MW-OI0, 090-MW-Ol1 and 184-MW-002. A
majority ofthe samples were described as a fine to medium sand (Table IB).

3.3.4 Additional Soil Delineation (November 2006)

Additional soil sampling was performed during November 2006 to provide further soil delineation under
proposed building footprints (Buildings 5 and 7) in the southwest portion of the Site, and to evaluate soil
pH data with respect to sources of chromium impacts (i.e. COPR fill versus dichromate sources). Soil
samples were collected at 2-foot intervals from 14 sampling locations (090-SB-006 through 090-SB-O 19)
to the top of the peat stratum (maximum 16 feet bgs). Results are summarized on Table 2 and Figure 3.
Analytical data packages and electronic data deliverables are contained in Appendices F and M,
respectively. Boring logs are contained in Appendix C.

Analytical results were used to confirm chromium-impacted soils beneath proposed Buildings 5 and 7.
Field observations of eOPR-impacted fill and elevated hexavalent chromium results (> 1,000 mglkg)
were noted at seven locations (090-8B-007, 090-SB-008, 090-SB-OI5 through 090-SB-019). Hexavalent
chromium concentrations were slightly above 20 mg/kg at four locations (090-8B-009, 090-SB-OI0, 090-
88-012, 090-SB-0 14). The remaining samples did not contain hexavalent concentrations in excess of 20
mg/kg (090-SB-006, 090-SB-Oll, 090-88-013).

Soil samples were also analyzed for pH to evaluate the source of hexavalent chromium. High pH values
(>11) were detected in samples with hexavalent chromium levels above 1,000 mglkg and field
observations ofCOPR-impacted fill. Samples containing low levels of hexavalent chromium above 20
mglkg showed relatively neutral pH results.

19

TIERRA-B-015030
3.4 GROUNDWATER INVESTIGATION RESULTS

Groundwater investigations at the Site were conducted in several phases during the previous RI for SA-S,
the supplemental RI activities conducted during 2005-2006, and as part of the regional groundwater
investigation under the oversight of a court-appointed Special Master for Study Area 7.

3.4.1 Remedial Investigation Results (November 1999)

Previous groundwater investigations included sampling of monitoring wells installed within SA-S as part
of the RI, the SA-7 investigation, and other investigations completed on behalf of the property owner
(NJCU). The RI activities for SA-5 included installation of 16 monitoring wells, including two (2) wells
at Baldwin Steel (Site 090) and three (3) wells at M.l. Holdings (Site 184). Groundwater investigation
results are sununarized in this section, with reference infonnation provided in Appendix A. A summary
overview of previous groundwater investigation results by cae is provided below:

VOCs/SVOCs
Five (5) monitoring wells were sampled for VOCs and SVOCs as part of an investigation on Site 184
(MI Holdings) during September 1992 and March 1993. The following VOCs were detected above the
GWQS in MW-3B: benzene (88-230 ug/L), xylene (200-220 ugIL), trichloroethylene (640-5,200 ug/L),
1,2-dichloroethenes (total) (330-560 ug/L), and vinyl chloride (13-24 ug/L). The lower concentrations
were detected during the March 1993 sampling round, indicating declining concentrations. No SVOCs
were detected above the GWQS. MW-3B, formerly located near the western boundary ofM.!. Holdings
(Site 184), was screened from approximately 35 ft to 45 ft bgs, at the base of the Lacustrine Sand.

Inorganics
The majority of groundwater sampling completed within SA-S has been for inorganics. Sampling
completed as part ofthe SA-5 and SA-7 regional groundwater investigations primarily focused on
chromium and major cation/anions with some additional analyses for several anions/cations and
miscellaneous parameters. Work completed on the Site 184 (M.I. Holdings) focused on mercury but also
included chromium and other Priority Pollutant List metals.

Chromium (total and hexavalent) was the most frequently detected metal with reported concentrations
above the GWQS in both filtered and unfiltered samples. Other metals reported above the GWQS in
filtered samples collected from Site 184 (M! Holdings) included cadmium (well MW-2B), mercury (well
MW-2A) and thallium (well MW-3B). Arsenic, lead, mercury, and thallium were also reported above the
GWQS in groundwater samples collected from HydroPunch borings on Site 90 (Baldwin Steel).
Additionally, the following inorganics were occasionally detected in groundwater above the GWQS
during the RI: aluminum, iron, sodium, ammonia, sulfate, chloride and total dissolved solids (IDS).
Groundwater samples collected using low-flow sampling techniques typically have lower metals
concentrations than either HydroPunch samples or samples collected using conventional sampling
techniques, which were likely used during the 1992 and 1993 sampling rounds.

Groundwater data collected during previous investigations associated with SA-5 indicate that
groundwater impacts at Site 090 (Baldwin Steel) and Site 184 (M.l. Holdings) include total and
hexavalent chromium above the GWQS. Chromium concentrations above the GWQS are present within
the Shallow Zone (contained within the fill material) beneath most of Site 117 (Ryerson SteelfHome
Depot) and Site 153 (Morris Canal) adjacent to Route 440. As previously indicated, a thin layer of
meadow mat is present in the western portion of SA-5, and a downward hydraulic gradient was identified

20

TIERRA-B-015031
between the fill material and the underlying lacustrine deposits. Where the meadow mat is not present,
the shallow and deep zones are in hydraulic communication.

3.4.2 Report on Groundwater for Study Area 5 (October 2004)

HydroQual, Inc. prepared a draft report during October 2004 focusing on groundwater conditions at SA-5
to support the development of a RASRJRA WP for Baldwin Steel (Site 090) and M.l. Holdings (Site 184).
The report indicated that groundwater flow direction in the Shallow Zone at SA-S is generally toward the
west and north, and is influenced by near surface features including storm sewers along Route 440.

Hexavalent chromium concentrations detected in the shallow groundwater zone were generally below the
GWQS (70 ug/L) in the majority of monitoring wells at Sites 90 and 184 within SA-5. Groundwater
sample results for monitoring well 090-MW-EO 1 (located in the western portion of the Site near Route
440) indicated total and filtered hexavalent chromium concentrations of770 ugIL and 583 ug/L,
respectively. The report also contains results of groundwater grab (HydroPunch) samples collected by
others, indicating elevated chromium concentrations in the southwest portion of the property.

Vertical aquifer screening sample results obtained during installation of deep monitoring wells (090-
MW-090, 90-MW-7BR) located in the southwestern portion of the Site indicate that hexavalent
chromium was detected in 090-MW-090 above the GWQS (70 ug/L) near the bottom of the fill unit (12-
14 feet bgs) and at various depths greater than 25 feet bgs, with the highest concentrations detected at
depths below 60 feet bgs. There were no detections in the interval between the bottom of the fill and the
deeper natural deposits. Vertical screening results for 090-MW -7BR indicate that hexavalent chromium
concentrations above the GWQS were limited to samples collected from depths below 25 feet bgs. The
vertical aquifer screening results indicate that the chromium levels detected in the deep groundwater zone
are several orders of magnitude greater than the Shallow Zone. The groundwater data indicate that the
highest hexavalent chromium concentrations in the shallow groundwater zone have been detected at SA-
7 (Sites 87 and 115) on the opposite (west) side of Route 440, and other nearby Sites associated with SA-
5 (Sites 117 and 153) south of the subject Site.

3.4.3 Deep Overburden Groundwater Report for Study Area 7 (February 2007)

As part of the Regional Groundwater study for SA-7, HydroQual, Inc. on behalf of Honeywell prepared a
Final Groundwater Investigation Report dated February 2, 2007 to describe the hydrogeology of the deep
overburden deposits in the vicinity of Study Areas 5,6, and 7, and to characterize the deep overburden
groundwater chromium plume (HydroQual, 2007). This study included both the landward portion of the
plume and the portion that extends beneath the Hackensack River. The term "deep overburden" refers to
the deposits between the meadow mat and the bedrock surface. Groundwater occurs within the fill
material above the meadow mat under unconfined conditions, and within the lacustrine sand and bedrock
under semi-confined and confined conditions, respectively. The report indicates that groundwater flow
in the intermediate zone below the meadow mat is toward the Hackensack River. Groundwater flow in
the deep zone is to the west-northwest beneath SA-5. but then turns to the north-northwest beneath SA-7
and SA-6 North. A coarse-grained sand deposit (beneath the eastern portion of SA-7) and the low
permeability red clay (beneath the western portion of SA- 7) control groundwater flow in the deep zone.

Two independent chromium plumes have been identified; one in the fill and shallow overburden above
the meadow mat, and one in the deep overburden. Chromium in the shallow overburden plume is a result
of groundwater in direct contact with COPR, and COPR-impacted soil, and is unrelated to the deep
plume, which has its origin at the former Mutual Chemical Company production facility east of Route

21

TIERRA-B-015032
440 (Site 117; current location of the Home Depot facility). The report indicates that the source of the
deep plume is from the historic vertical migration of chromium through the lacustrine sands into the deep
overburden. The deep plume then travels through the deep, highly penneahle, coarse-grained sand layer
where it travels horizontally to the north-northwest where it moves back up through the lacustrine sands
ultimately discharging to the Hackensack River.

In contrast to the COPR-related sources of the shallow plume, the deep overburden plume was likely
caused by historic releases of chromate solutions from the various processes at the fanner Mutual
Chemical Company production plant. Based on the historical information provided in the Final
Groundwater Investigation Report, the most likely location of process-related discharges is in the vicinity
of Building F, in the northwest comer of the fonner plant, where the "wet" operations took place. The
vertical profile of hexavalent chromium concentrations in pore water adjacent to the wet operations area
supports the conceptual model of process-related discharges. Pore water quality data collected from
borings 090-MW-07, I 17-MW-I4, and 090-MW-07BR located within close proximity to the wet
operations indicate that hexavalent chromium is present throughout the entire vertical column from the
Shallow Zone to the top of bedrock. Concentrations range from a low of 1.5 mgIL to a high of 6,920
mg/L. This was the only location within the project area in which such a vertical continuum was
identified. The highest concentrations noted in these borings are at a depth of approximately 65 feet and
in contact with the 5-3 Sand. The fact that the Shallow and Intermediate Zones in this source area
continue to exhibit hexavalent chromium in concentrations in excess of 10 ppm, indicates that residue
from past housekeeping practices may still be present in the subsurface. Although a relatively thin layer
ofCOPR-Iike material was identified in boring 117-MW-I4, it is unlikely that this small volume could be
solely responsible for the persistence of these elevated concentrations decades after plant operations have
ceased. It is more likely that some form of solid-phase residual of the historical sodium chromate
discharges is present within the fill and/or underlying lacustrine deposits.

Hexavalent chromium was detected in the deep overburden at concentrations greater than 1,000 mglL in
three wells: 090-MW-09 had 2,460 mg/L in the unfiltered sample collected in April 2004; 117-MW-14
had 6,920 mg/L in the unfiltered sample collected in December 2006; and 115-MW-19 had 2,250 mgIL
in filtered sample collected in September 2004. These wells are located within the Site property,
adjacent to the Site property, and approximately 400 feet west of the Site, respectively. Vertical aquifer
sampling results indicate that the chromium levels detected in the deep groundwater zone are several
orders of magnitude greater than the Shallow Zone. Vertical aquifer sampling results and relevant
figures from the reglOnal investigation illustrating the regional extent of chromium impacts and vertical
gradients are included in Appendix A.

Hexavalent chromium was a(so detected beneath the riverbed sediments at concentrations ranging from
0.732 mg/L to 218 mg/L. The report indicates that the plume is believed to have attained a largely
steady-state position beneath the river with ongoing discharge upward through the relatively thin
sediments in a topographic depression area beneath the river, with little or no further lateral migration of
the plume. Hexavalent chromium was not detected above the detection limit of 5 ugll in any of the 26
pore water sample locations beneath the river. (HydroQual, Inc., 2007).

HydroQual conducted an evaluation of deep overburden groundwater remedial alternatives to address


chromium contamination, as presented in the Deep Overburden Groundwater Remedial Alternatives
(DORAA) Report (HydroQual, Inc., 2006). The evaluation included a recommendation that Alternative
No.3, consisting of a groundwater pump/treat system that captures the entire deep overburden
groundwater plume, be implemented. Alternative No.3 includes pumping of an extraction well, located

22

TIERRA-B-015033
adjacent to the Hackensack River, with piping to and treatment at the existing SA-7 wastewater treatment
plant. A Court Order dated 10/6106 approved the DORAA Report and the selection of Alternative No.3,

3.4.4 RIWP Addendum for Shallow Groundwater (April/May 2005)

Groundwater sample results for two rounds of sampling performed during 2005 (April and May) are
indicated on Table 3 and Figure 5. Monitoring wells sampled include 090-MW-EOl, MW-090-010,
090-MW-Oll, l84-MW-OOl, I84-MW-002 and 090-MW-8A. Groundwater field parameter
measurements are indicated on the groundwater sampling field data sheets in Appendix E. Groundwater
elevation data are presented in Table 5. Groundwater contours are included as Figures 4A and 4B.
Total cltromium was detected in the following monitoring wens above the GWQS (70 ugIL) with maximum
concentrations shown in parenthesis: 090-MW-EOI (117 ugIL); 090-MW-OlO (5,280 ug/L); 184-MW-D02
(245 ug/L) and 090-MW-8A (514 ugIL). Elevated total cltromium concentrations were also detected in
groundwater grab samples 090-PZ-00I (7,220 ugIL) and 090-PZ-002 (2,640 ugIL). Groundwater grab
sample 090-PZ~001 was collected from 090-SB-003 borehole, and sample 090-PZ-002 was collected from
090-SB-005 borehole. The screened interval at both locations was from 3 to 13 ft bgs. These results are
likely biased high due to the groundwater grab sampling method. Hexavalent chromium was detected
above the GWQS in two wells as follows: 090-MW-OIO (5,220 ug/L) and 90-MW-8A (497 ugIL). Both of
these wells are located within the area of chromium-impacted soils in the southwest portion of the Site.
Field measurements indicate that elevated pH levels were detected at 090-MW-01O (pH > 12), whereas
neutral pH conditions were detected at other wells including 090-MW -8A (pH of 6.44). Groundwater field
data indicate relatively neutral pH values (ranging between pH 6 to 9), with the exception of 090-MW-O 10
in the southwest portion of the Site.

Groundwater sampling included other water quality parameters (selected metals, alkalinity, ferrous iron,
sulfate, TOC) and field measurements (DO, oxidation-reduction potential [ORP]) to provide additional
data for evaluation of natural attenuation and potential groundwater treatment options. Alkalinity values
ranged from 46 mg/I to 789 mgll, with the highest alkalinity values detected in 184-MW -002 and 090-
MW-OIO. Ferrous iron, sulfate, and TOe values ranged from 0.15 to 0.24 mg/I; 9.8 to 45.5 mg/I; and 2.5
to 20 mg/I, respectively. DO results ranging between I to 10 mgll were detected in the majority of
monitoring wells, with the exception of090-MW-0IO and 090-MW-Ol I which had DO values below I
mglkg or non-detect. ORP results indicated negative values in the majority of wells, with the lowest
values detected in 090-MW-OIO. Data for 090-MW-OIO include a lack of DO along with negative ORP
values, indicating anaerobic reducing conditions where the highest chromium concentrations were
detected in the southwest portion of the Site. The results indicate subsurface conditions favorable
for chromium reduction (Cr -6 to Cr~3) in groundwater beneath the Site.

3.4.5 Additional Shallow Groundwater Sampling (May/August/December 2006)

Groundwater sample results for sampling performed during May, August and December 2006 are
indicated on Table 4 and Figure 5, Monitoring wells sampled include 090-MW-OlO, 090-MW-ll, 090-
MW-8A, 090-MW-E01, l84-MW-OOI, 184-MW-002. Monitoring well 090-MW-8A was not sampled in
August 2006 as it could not be located following building demolition activities. Groundwater field
parameter measurements are indicated on the groundwater sampling field data sheets in Appendix E.
Groundwater contour maps are included as Figures 4C through 4E.
Total chromium was detected in the foiIowing monitoring wells above the GWQS (70 ug/L) with
maximum concentrations shown in parenthesis: 090-MW-OIO (3,500 ugIL), 090-MW-8A (380 ug/L), and
184-MW -002 (222 ug/L). Hexavalent chromium was detected above the chromium GWQS (70 ugll) in

23

TIERRA-B-015034
90-MW-8A (345 ugIL), and below the GWQS in 090-MW-010 (64 ug/L). These wells are located within
the area of chromiurp-impacted soils in the southwest portion of the Site. The most recent round of
sampling (December 2006) indicates hexavalent chromium detected in only one well: 90-MW-8A (332
uglL). Laboratory analysis shows elevated pH levels at 090-MW -010 (pH 12.08), whereas near neutral
pH conditions were detected at the remaining wells. Groundwater field data also indicate relatively
neutral pH values (ranging between pH 6 to 9), with the exception of090-MW-OIO in the southwest
portion of the Site.
Groundwater sampling included other water quality parameters (TAL metals, natural attenuation
parameters) to provide additional data tor evaluation of natural attenuation and potential groundwater
treatment options. Alkalinity values ranged from 23 mg/l to 784 mgll, with the highest alkalinity values
detected in 184-MW-002. Ferrous iron, sulfate, and TOC values ranged from <0.1 to 4.9 mg/I; <5 to 328
mgll; and 1.6 to 47.2 mg/I, respectively. Sulfide results ranged from <1 to 32.4 mgIL. DO results ranged
between 0 and 6 mg/l, with DO not detected in 090-MW-OIO, 090-MW-Oll, 184-MW-OOl, and 184-
MW-002. ORP results indicated negative values in the majority of wells, with the lowest values
detected in 090-MW-OIO. Monitoring wells 090-MW-8A and 090-MW-011 (located outside the zone of
highest hexavalent soil impact) show positive ORP values. Data for 090-MW-OIO include a lack of DO
along with negative ORP values, indicating anaerobic reducing conditions where the highest chromium
concentrations were detected in the southwest portion of the Site. The results indicate subsurface
conditions favorable for chromium reduction (Cr+6 to Cr+3) in groundwater beneath the Site.

Other metals detected above the GWQS included aluminum, arsenic, iron, lead, manganese, mercury, and
sodium. The greatest number of metals above the GWQS were detected in 090-MW-OIO, including
aluminum (2,920 ug/L), arsenic (58.7 ug/L), iron (12,000 ug/L), lead (80.7 uglL), mercury (28.8 ug!L),
and sodium (292,000 ug/L). Elevated mercury (22.6 ugIL) was also detected above the GWQS in 184-
MW-OOI. TDS and chloride concentrations ranged from 220 to 1,140 mg/l and 18 to 109 mg/l,
respectively.

3.5 STUDY AREA 7 - SOURCE AREA TREATABILITY STUDIES

Honeywell has conducted a treatability assessment of source area material on the Home Depot site (see
Appendix N). Laboratory tests were conducted on soil obtained within the footprint of the former
Mutual Chemical Company facility (source of Study Area 7 deep overburden groundwater
contamination) to provide a direct measure of the leachability of soil-associated hexavalent chromium
(Cr(VI)) and to assess the performance of an abiotic reductant for Cr (VI). The major objectives of this
study were to (i) use kinetic leaching tests to determine the leaching characteristics ofCr(VI) from
representative soil samples from within the source area defined by the prior wet operations on SA-5, (ii)
evaluate possible Cr(VI)·mineral and/or chemical mechanisms that may be responsible for Cr(VI)
retention in the soil, and (lii) evaluate the reductant dosing requirements for reduction of Cr(VI).

A full description of the studies, including the field collection, laboratory methodology and analyses, and
results is presented in Appendix N (Treatability Study - Source Area Study Area 7, HydroQual Inc.) The
results of the studies are briefly summarized as follows:

At hydraulic gradients ranging from approximately 14 to over 70, multiple pore volume exchanges
(up to 40 or more) were required to sufficiently leach Cr(VI) so that effluent concentrations were
below the New Jersey groundwater quality criterion of70 ppb.
The large number of pore volume exchanges, both within fine sand samples as well as silty clay
samples, indicates that Cr(VI) is not leached within the typical 3-5 pore volume exchanges expected
if only dissolved phase chromium were present and readily leachable from the pore spaces.

24

TIERRA-B-015035
• The leaching curve response (Le., a slow, relatively steady decline) could be indicative of diffusion
of Cr(VI) from within the sample, which could be accounted for by the presence of Cr(VI) in
micropores, or a combination of diffusion, sorbed material, and solid phase material.
• The fill sample that appeared to exhibit visual evidence of solid phase chromium at the time it was
collected, did not contain COPR, but did contain a chromite phase (trivalent chromium) indicating
that the formation of solid phase material did indeed occur. Apart from this conclusion, chromium
was detected in three of the five samples tested.
• The addition of calcium polysulfide at two times the stoichiometric ratio based on total extractable
Cr(VI) by alkaline digestion resulted in concentrations of Cr(VI) in effluent samples below the
GWQS without indication of a return to higher levels for the sample tested with more than one dose
(i.e., fine sand sample). Calcium polysulfide dose ratios for treatment should range from two to three
times the stoichiometric ratio, based on the overall results of the testing.

3.6 CONCLUSIONS AND RECOMMENDATIONS

Soil Investigation

• The RI included over 80 borings and analysis of over 700 samples for total and hexavalent chromium
on Site 090 (Baldwin Steel), Site 184 (M.!. Holdings), and the northern portion of Site 153 (Former
Morris Canal) next to Sites 090 and 184 during the RI. The horizontal and vertical extent of
hexavalent chromium above the NJDEP Soil Cleanup Criteria has been characterized and delineated.

• The portion of the Site and proposed redevelopment area impacted by hexavalent chromium
concentrations greater than the NJDEP soil criteria (20 mg/kg per the NJDEP chromium policy) is
along the western and southern boundaries of the Site (estimated at approximately 4.5 acres). The
impacted area is bounded by the Site 090 (Baldwin Steel) boundary to the south (adjacent Site 117 to
the south has already been capped by Honeywell), Site 153 (Former Morris Canal) boundary to the
west (where additional RI efforts are ongoing), and clean borings (no exceedances of20 mg/kg) to
the north and east within Site 090 (Baldwin Steel) and Site 184 (M.I. Holdings). Hexavalent
chromium concentrations slightly above 20 mg/kg were detected in shallow soils beneath existing
pavement at a few isolated locations outside the main chromium-impacted fill area.

• A one to two foot thick layer of meadow mat (peat) is present in the western portion of the Site. The
highest hexavalent chromium concentrations occur in saturated fill material above the meadow mat,
at depths between approximately 6 to 14 feet bgs. RI results indicate good correlation between field
observations of possible COPR impacted soils and laboratory data indicating elevated hexavalent
chromium concentrations. Field observations of possible COPR and/or COPR contaminated fill were
noted in some of the borings as relatively thin layers (e.g., yellow-green colored streaks or nodules)
mainly at the bottom of the fill. Typically, the hexavalent chromium concentrations are one to two
orders of magnitude less in the underlying samples collected from (and below) the meadow mat,
which appears to be acting as a confining layer that prevents downward migration of hexavalent
chromium into the deeper groundwater zone.

• SPLP data for soil samples collected at SA-5 is limited and indicates high variability and uncertainty
with respect to correlation of hexavalent chromium concentrations in soils with SPLP leachate
results. The high variability of the SPLP results indicates that the SPLP test cannot be used to
predict groundwater impacts at this Site. Groundwater data provides more conclusive evidence
regarding actual source impact to groundwater.

25

TIERRA-B-015036
Groundwater Investigation

• Two independent chromium contamination plumes have been identified in groundwater; one in the
shallow fill and overburden zone above the meadow mat (where present) and one in the deep
overburden zone. Vertical aquifer sampling data indicate that the chromium levels in the deep
overburden groundwater zone (below the meadow mat) are several orders of magnitude greater than
the Shallow Zone, indicating that shallow groundwater conditions at the Site are not a source of the
groundwater contamination present in the deep overburden zone.

Total and hexavalent chromium concentrations in groundwater within the Shallow Zone beneath the
majority of the Site are below the GWQS or not detected. Elevated chromium concentrations above
the GWQS ono ugIL were detected in the southwest portion of the Site (090-MW-01O, 090-MW-
8A) and the northwest corner of the Site (I84-MW -002). The presence of elevated hexavalent
chromium in the Shallow Zone groundwater is associated with chromium-impacted fill soils,
particularly in areas with high pH levels (e.g., 090-MW-OIO; pH >10).

• Total and hexavalent chromium concentrations detected in the Shallow Zone were lower during 2006
as compared to data collected during 2005. Groundwater sample results for 090-MW-OI0 indicate
that total chromium levels decreased from 5,200 ugiL (May 2005) to 3,500 uglL (December 2006),
and hexavalent chromium levels decreased from 5,170 ugIL (May 2005) to 64 ugIL (May 2006) to
non-detect (December 2006). In 090-MW-8A, total and hexavalent chromium concentrations
decreased from 514 ugll and 496 ugll (May 2005), respectively, to 356 ugll and 332 ugll (December
2006), respectively. In 184-MW-002, total chromium levels decreased from 180 ug/l (May 2005) to
83 ugIL (December 2006). Hexavalent chromium results during 2006 were non-detect or below the
GWQS in all monitoring wells, with the exception of 090-MW -8A. The presence of elevated
hexavalent chromium in 90-MW-8A with neutral pH conditions indicates that hexavalent chromium
at this location may be associated with dichromate rather than COPR-impacted fill.

• Groundwater results indicating initial elevated total and hexavalent chromium concentrations may be
associated, at least in part, with suspension/dissolution of contaminants from physical disturbance of
chromium-impacted fill during well installation. This pattern of initial elevated concentrations near
the time of well installation followed by substantially lower concentrations has been observed at
other chromium-impacted fill sites.

• The regional groundwater investigation for SA-7 indicates that elevated chromium is present in the
Deep Overburden Zone near the boundaries of Site 117 (Ryerson Steel), Site 153(Former Morris
Canal) and Site 90 (Baldwin Steel), and extends west of Route 440 in the area of SA-6 and SA-7.
The source of the deep groundwater plume is believed to be from past operations at the fanner
production plant (Site 117; Ryerson Steel; currently occupied by Home Depot), likely associated
with historical discharges or spills of materials used at the plant (e.g., sodium dichromate) and
vertical migration of chromium through the lacustrine sands into the deep overburden where it mixes
with groundwater moving through the deep, more permeable, coarse-grained sand layer.

• Other constituents detected in groundwater above the GWQS during the most recent sampling
completed during 2006 included aluminum, arsenic, iron, lead, manganese, mercury, and sodium.

• Other constituents detected in groundwater above the GWQS in connection with investigations by
others include VOCs (benzene, xylene, TCE, DCE, vinyl chloride) and metals (cadmium, mercury,
thallium) at Site 184 (MI Holdings).

26

TIERRA-B-015037
• Groundwater measurements indicate strong reducing conditions, as evidenced by lack of dissolved
6 H
oxygen and negative ORP values. These conditions favor the natural reduction of Cr+ to Cr

• R1 data for the Site and nearby sites within Study Areas 5, 6 and 7 include groundwater results for
chloride and TDS. Over 300 chloride and TDS sample analyses have been completed over a nine-
year period, with results indicating that groundwater exceeds the GWQS for these compounds on a
regional basis. In some cases, the concentrations exceed the criteria for Class IIIB groundwater
designation, suggesting impacts from saline surface water (Newark Bay). The exceedances of the
GWQS (or Class UIB threshold values) are not bounded by property lines or location of historical
operations, thus they are ubiquitous and regional. The level and extent of the impact varies by
stratigraphic unit and is likely a function of the history and properties of each unit. In the Shallow
Zone (above the meadow mat), impacts are likely related to the filling of the estuarine marshes and
subsequent interconnection of the bay with the fill zone. The intermediate and deep glacial zones
and the bedrock are likely impacted from historic pumping operations. The level and extent are
governed by geologic properties of these units (e.g. permeable zones in the glacial sediments and
fracture zones in the bedrock).

Recommendations
Soil and groundwater impacts have been adequately characterized and delineated, and sufficient data
exist to proceed with remedial action selection to address chromium contamination detected in soils and
groundwater at the Site. A Remedial Action Selection Report and Remedial Action Work Plan are
presented in Sections 4 and 5, respectively.

27

TIERRA-B-015038
-,'

Permit No.: NJ0027022


------------- ,
,
".
Name of Permit4ee:
Jersey City Sewerage Authority

Effective Date: February 28, 1975

Expiration Date: June 30,1977

NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM

PERMIT TO DISCHARGE

In reference to the applicatio~ received from the above-mentioned


permittee for a permit authorizing the discharge of pollutants in com-
pliance with l:he provisionsoi the Federal I-,'aterPollution Control Act,
as amended by the Federal '(.Jater'Pollution Control Act Anendments of
1972, P. L. 92-500, October 18, 1972 (33 V.S.C. ~§1251-1376) (herein-
after referred to as "the Act"),
Jersey City Sewerage Authority
575 S ta te Highway Xo. 440
Jersey City, NEW Jersey 07306

(hereinafter referred to as "the Permittee")

is authorized by the Regional Administrator, Region II, U.S. Environmental


Protection Agency, to discharge from:
lty ~est Side Sewag Treatment Plant

and thirteen overflow discharges

to receiving waters named Newark Bay and Hackensack River


----------------------
in accordance with the following conditio~s.

BCJ000008

TIERRA-B-015039
PBr:~ 'of 28 pages
,NJ0027022

A. G~liHAL CONDl'l'ION~:

1. All d.i scharges authorized herein s~lall be con si stent. ..... i th the te rms
and conditions of this pernit. The di~charee of any pol1ut~~t more
freq'Uently tr l!,,'1, or at a level, in excess of, that identified. and
authorized by this permit shall consti tute a violation of the terms
a~i conditicns of this ?ermit. Such 0 violation may result i~ the
i~position of civil ani/or criminal penalties as provided for in
Section 309 of the Act. Facility modifications, additions, and/or
expansions that increase the plant capacity must be reportei to the
per~itting authcrity ani this ?ermit then nodified or re-iss~el to
reflect such changes. Any o.nticipa::'e.i
change in the facili ty ,iischarge,
incluiinf, a~y new significant in1ustrial discharge Or significant
changes in t~~ quantity or quality of existing indus~riGl iisc~~rges
to t!~e treet~ent Sj'stE:::: that will result in :-Jewor increasei :..iscr.arges
of pollu-::'ants::ru.st· be re:;?or:'ed.
to the ;{egicnal Ad.:ninis':ratcr. ::odificn.tic:s
to the per~~t ~ay ~hen be Dade to reflect any necessary chanses in
perrr~t condi::'ions, inclUding any necessary effluent linitatic~s for
any 90l1uta~ts net 'identified. ani li::1i. ted. herein. In no case ere any
ney: connections, increased. flows, or significant chal'';2s in in:'':'uen t
quality ?er::~tte1 that will cause Violation of the effluent li~tatio~s
specified. herein.

2. !,:ter Iiotic!'::
E::.rJl o;.'rJortunit:,r
fer ::l h€:,ri~lg, this [)tr::,J.::' ma:r 'be ~od.ifie'i,
suspen::e·i, or revo~ed in whole or in port dmine its term for cause
incl~jinr, but not li~~ted to, the ~01lo~~ng:

a. violation of any terms or coniitions of this permit;

b. obtaining this per~~ by rr~sTe?resen~8tio:-J or failure to


disclose fully all relevant fac~s; Dr,

c. a chp_~ge in any condition that requires either a te~porary or


permanent reiuction or eli~nation of the permitted dischar&e.

3. !;ot,,:ithstan'iing2 above, if a toxic effluent standard or prohibition


(inclu1ine a~y schedule of cOwpliance specified in such efflu~~t
standard or prohibition) is est3bli~hcj unJer Section 307(8) of tte
hct for a toxic pollutant ~hich is pre~ent i~ the disc~arge authdriz~~
~'-':rcinand such stander:!.or prohibition is ·::lorestrinc;\Ont than an;)'"
lioitation upon such pollutant in t~i~ per~t, this permit shall ce
revised or ~odifiei in accor1ance ~ith the toxic effluent st~~iari
or prohibition and the perrr~ttee shall be so notified.

4. The per~ttee shall allow the hea:!.of the state water ~ollutic~
control agency, the Recional A'1~~~nistTatcr, and/or their authorized
representatives, upon the ~rc~entatic~ of crede~tials:

TIERRA-B-015040
Page 3 ~ 28 pages
NJ0027022

a. to enter upon the permitteeLs premises where an effluent source


is located or in which any records are required to be kept under
the terms and conditions of this permit; .
b. to have access to and copy at reasonable times any records
required to be kept under the terms and conditions of this
permit;
c. to inspect at reasonable times any monitoring equipment or
monitoring method required in this permit; or,
d. to sample at reasonable times any discharge of pollutants,
e. to inspect the operation of the treatment facilities.
5. The issuance of this permit does not convey any property rights in
either real or personal property, or any exclusive privileges, nor
does it authorize any injury to private property or any invasion
of personal rights, nor any infringement of Federal, state, or local
laws or regulations; nor does it obviate the necessity of obtaining
State or local assent required by law for the discharge authorized.
6. This permit does not authorize or approve the construction of any
onshore or offshore physical structures of facilities or the under-
taking of any work in any navigable waters.
7. Except for data determined to be confidential under Section 308 of
the P,ct, all monitori ng reports requi red by thi s permitsha 11 be
available for public inspection at the offices of the head of the
State water pollution control agency and the Regional Administrator.
Knowingly making any false state~ent on any such report may result
in the imposition of criminal penalties as provided for in Section
309 of the Act.

8. The diversion or bypass of any discharge from the treatment ~/ol·ks


by the permittee is prohibited, except: (1) where unavoidable to
prevent loss of life or severe property damage; or (2) where
excessive storm drainage or runoff would damage any facilities
necessary for compliance \'Iiththe terms and conditions of this
permit. The permittee shall notify the Regional Administrator in
writing "Iithin 72 hours of each diversion or bypass in accordance with
the procedure specified above for reporting non-compliance.
Within 30 days after such incident the permittee shall submit to
EPA for approval a plan to prevent recurrence of such incidents.
Normal operation of overflows and bypasses (listed in Section C-l)
should not be reported under the requirements of this condition.
The notification and plan herein required apply only to discharges
resulting from unusual situations such as breakdowns. power fail~
ures. and bypasses occurring during dry weather periods. A sum-
mary description of discharges from bypass points should be sub-
mitted with the permittee's quarterly self-monitoring reports.

TIERRA-B-015041
Page 4 of ,-ages
,.oN.l0027022

9. If for any reason the permittee does not comply with or will be
unable to comply with any effluent limitation specified in this permit,
or should any unusual or extrordinary discharge of wastes occur from
the facilities herein permitted, the permittee shall immediately
notify the Regional Administrator and appropriate State agency by
telephone and provide the same authorities with the following infor-
mation in writing within five days of such notification:
a. A description of the non-complying discharge including its
impact upon the receiving waters.
b. Cause of non-compliance.
c. Anticipated time the condition of non-compl iance is expected
to continue, or if such condition has been corrected, the
duration of the period of non-compliance.
d. Steps taken by the permittee reduce and eliminate the non-
complying discharge.
e. Steps to be taken by the permittee to prevent recurrence of
the condition of non-compliance.
10. Permittee shall take all reasonable steps to minimize any adverse
impact to navigable waters resulting from non-compliance with any
effluent limitation specified in this permit. The permittee will
also provide accelerted or additional monitoring as necessary to
determine the nature and impact of the non-complying discharge.
11. Except as provided in permit condition 8 on bypassing, nothing in
this per~it shall be construed to relieve the permittee from civil
or criminal penalties for non-complying discharge.
12. Nothing in this permit shall be construed to preclude the institution
of any legal action nor relieve the permittee from any responsibilities,
liabilities, or penalties established pursuant to any applicable
State law or regulation under authority preserved by Section 510
of the Act.

13. In the event of any change in control or ownership of facilities


from ''''hich
the author'ized discharges emanate, the pel-mittee shall
notify the succeeding owner or controller of the existence of this
permit by letter, a copy of which shall be forwarded to the Regional
Administrator and the State water pollution control agency.
14. The provisions of this permit are severable, and if any provision
of this permit, or the application of any provision of this permit
to any circumstance, is held invalid, the application of such provision
to other circumstances, and the remainder of this permit, shall not
be effected thereby.

", '

TIERRA-B-015042
Pnr.c 5 ..,f "-28- pages
NJ0027022

15. The per~ttee shall provide notice to the Regional Aiministrator


of the following:

a. Any :lew introduction of ~ollut<:nt::;into suell treatment ;.;orks


from n source which would be a new source as dc~inei in seetien
306 of the Act if such source ;.;eredischarginG pollutants;

b. Any new introduction of pollutants wn~cn exccel~ lO~OOO


gallons on Do'1:.' 1 iay into such treatr.l.en::. works .from a source
,,~hieh",ouJ.d ce subject to section 301 of the Act if such
source were discharging ?ollutants; and,

c. substant.ial change in vclu=,e or character of' ;ollutants


r'\n~T
bein[ introduced into such treatmen~ works by a source intro-
ducing pollutants into such wcrks at, the time o~ issunnce of
the permit.

fuch notice tiC:1 en the qunli t~1 Do'1d.qurmti t:r


shall i'1clude infer::'!;;.
of effluent to be introduced into such treat~en~ works; and un
anticipated impact 0:..' such cIlange in the quantity or quali ty o:.~
efflu€:lt to be discharged frc:n suc:-tpublicI:r owned treatnent. "'cr"'s.

16. ~he pel~ttee shall require 2ny iniustrial user o~ such trea~me~~
~orks tc comply ~~th the require~ents of section 204(b), 307, ar.i
303 of the Act. 1.:1.-:" industrial Ilser subject to the rcq,uirt:!mem.s of
section 207 of tho:: ;·.ctshall be required. by the per::.i
ttee to rr~?nre
an1 trQn~,,~t to the Regionol A·ir~~istrator ?eriodic notice (ever
in~ervals not. to exceed. 9 r:lonths) of prct;ress tower:! full conplianc,,",
¥ith secti~n 307 reQuireaents.

17. ?~~ ?er"ttee shall req~re &ny injustrial user of stor~ s~~ers ~o
cO:1ply "i. th :'he rec;,uirer:.entcf section :;03 of the Ar;:.t.

TIERRA-B-015043
Page 6 of 28 page s
NJ0027022

B. REQUIRED EFFLUENT LIMITATIONS AND MONITORING


AND OPERATIONAL REQUIR&~NTS

1. Required Effluent Limitations

During the period beginning on the effective date of this permit


and lasting until the eA~iration date of this permit,<discharges
shall be limited and monitored by the permittee as specified
below;

a. A substantially complete removal of settleable solids shall


be achieved.

b. The chlorination facilities shall be operated continuously,


year round. A chlorine residual of not less tha~ 0.5 mg/l
shall be maintained in the effluent at all times.

c. S~e Table I _

d. Except as specifically authorized in this permit, the


permittee shall not discharge floating solids or visible
foam.

e. The efflue~t values for pH shall re~in within the li~~ts


of 6.0 to 9.0.

f. The 3D-day average quantity of effluent discharged from the


l!astewater treatment facility shall not exceed .J..6..-.O.- million
gallons per day (mgd).

TIERRA-B-015044
,Enge '7 of28 Pages
NJ0027022
2. Fac11ity QPeration and Quality Control

All waste collection, control, treatment and disposal facilities


shall be operated in a manner consistent with the following:

a. At all times, all faci11ties shall be opera~ed as effici~1tly


as possible and in a t:anner which will minitnize upsets and
discharges of excessive pollutants.

b. The permittee shall provide an adequate operating staff


which is duly qualified to carry out the operation, oainte~ance
and testing functions required to insure compliance with
the conditions of this permit.

c. Maintenance of treatnent facilities that results i~


degradation of eff1uent quall ty shall be scheduled during
non-critical water quality periods and shull be carried out
in a manner approved by the permitting authority.

d. Under no circumstances shall the permittee allcw introduction


of the follmdng wastes into tbe waste treatment syste:n~

ea. Wastes which create a fire or explosion hazard in


the treatment works.

bb. Wastes vhich ~ll caucc corrosive struc~ural ~~age


to treatment ~orks.

cc. Solid or viscous subst~~ces in amounts which cause


obstructions to the flow in sewers or interfer~nce with
the proper operation of the treatment works.

dd.. Waste.raters at a flO">" rate e:1d/or pcllut.f>.::t


-i,~,sc:-larGe
rate "'hich is excessive over relatively short time
periods so as to cause a loss of treatment efficiency.

3. Self-Monitoring and Reportin§ Requirements

e. The percdttee shall effectively monitor the operation and


efficiency of all treatment and control facilities ~~d the
quantity and quality of the treated discharge. Monitoring
data required by this permit shall be s'I.llll:narized
0:•. an
average calendar month basis. Individual reports arc to
be submitted on a oua-~erl~ basis. Duplicate original
copies of the discharge monitoring report fOim (EPA ferm
3320-1). properly completed and signed by the permittee

TIERRA-B-015045
t'n[~c 8 ....Pl" - -28 ,;a~es
NJ002?022.

must be submitted wi thin 28 days after the end of each report


p~riod to th~ Regional Administrator nnd the state Agency at
the follo.:inr, audresses:

u.s. Environmental Protection Agency


Region 1I
Status of Compliance Branch
26 Federal Plaza
New York, New York 10007

Director
Division of I-laterResources
New Jersey Department of
Environmental Protection
Labor & Industry Building
P. O. Box 1390
Trenton, New Jersey 08625

Quarterly report::; W"ill be required. for )Jeriods bc£=,inni:w, 011


}~rch 1, 1975. The data collected and submitted shall include
the following parameters and cesting frequencies:

::ee T<3ble I

fanples and l:l'O'csnre::1ents of ti1e effluen~ t:l.kento achieve complis!1ce


\o1i"..!1
the I:\cdtorinE require::::.ents specified 3bove shall be ta.,ken at
t::c point C'f' co::-.bind.flo\o1 into tlle outfall se;.'er.

fe...'1?les E.Jld l:lCaSUIer:lent of the influent ....


astewater taken J;.o :r.e'.!t. ~he
nonitorir:B requiremmts specifie;l &.boveshall be token at the point c::
plant bflm,'.

ether ~ea$ur~~ents of oxygen de~nnd cun be substituted fo~ Bio-


-:::-Jer.'.icalCx)'cen DelT'..and(BOD) where the p~rmittee can demon:;trate
lOnJ>t('r.:l ccrrelation of the method with BODvalues. Suhsti tutic:1
of ~uch meacu=cments must receive prior approval of the per~~ting
a'J.thority.

The analytical and $ompling ~ethods us~d shall confor~ to the latest
edition of the refere.l\ce r.lethod:; listed. belo.... (These are
interim
references to be rC!placed by See. 304( [J £Uidel.incswhen a.vaila.ble).
Huwever, different but equivaJ.ent r.Jethods are n.1.lowable if they
receive the prior written a.pproval of the perrnittinC authority.

TIERRA-B-015046
~age :> of ."28 _.pages
NJ0027022

L Standard Methods for the Examination of Water and Wastewaters,


13th edition, 1971, American .Public Health Association,
New York, New York 10019.

2. A.S.T.M. Standards, Part 23. Water; Atmospheric Analvsis,


1972, American Society for Testing and Materials, Philadelphia,
Fa. 19103.

3. Methods for Chemical Analysis of Water and Wastes, April 1971,


Snvironmental Protection Agency, Water Quality Office,
Analytical Quality Control Laboratory, 1014 Broadway, Cincinnati,
Ohio 45202.

The perDlittee shall periodically calibrate and perform maintenance


procedures on all monitoring and analytical instrumentation at
intervals to insure accuracy of measurements.

4. Recordin&

The permittee shall record for all samples the date and time of
sampling, the sampling method used, the date analyses were performed,
the identity of the analysts, and the results of all required analyses
and measurements.

All sampling and analytical records mentioned in the preceding para-


graph shall be retained for a minir.n.li"D
of three years. The permittee
shall also retain all original recordings from any continu~us monitoring
instrumentation, and any calibration and ~aintenance records, for a
minimum of three years. These periods will be extended during the
course of any unresolved litigatio~. or When so requested by the
Regional Administrator.

5. Solids Disposal

Collected screenings, slurries, sludges, and other solids shall be


disposed of in such a nanner as to prevent entry of those wastes
(or runoff from the wastes) into navigable waters or their tributaries.

6. Discharg~ Location Description

Treated effluent is discharged through a singJ.e outfall (Discharge


No. 002) into Newark Bay. 240 feet from shore and 11 feet below the
water surface. The point of discharge is located at latitude
40D43'00" and longitude 74D06'15".

In addition, there are thirteen overflow points in the collection


system that discharge untreated wastewater during periods of wet
weather. A descriptive listing of these points can be found in
Section C-II of this permit.

TIERRA-B-015047
\
Page 10 or 28 pages
-·~:l\'tJ002
7022
Ta.ble II - Gclf-t·~oni taring Requirements y
Hinimum Honitoring Requirements
?arwneter )·1eo.sUTc:T:lent .F'recucnc Sa:n 1 e

Total Flow, mgd continuous N/A


BOD:2)mg/l daily 24-hour composite
BOD), lbs/o.ay
'Settleable Solids) ml/l 6 per day grab
Suspended Soli as, mg/l daily 24-hour composite
Suspended Solids, Ibs!day
Residual Chlorine, r:g/ly 6 per day grab
Fecal Coliform, N per 100 ml daily grab
y
pH 6 per day grab
Temperature. DC 1/ 6 per day grab

, I
::J -~.,- .......- .... -_.- _.. :ec, i:,:flue~t and effluent
measurement and testin~ are reQuired.

y Only efflue.'1:' testing required.

* To be calculated based on actual flow and


actual testing results for parameters noted~

TIERRA-B-015048
Pag .... ,110'£.28 Pages
NJ0027022

Section C -

II Special. Conditions"

TIERRA-B-015049
I'uge I~ or l~ pG~.F~s
NJ00270'>4\
~ ~ct~on
. C- I

Schedule of Compliance 11

The permittee has indicated that the level of treatment currently


being afforded the discharge is not rn2eting the level of treat-
ment as provided for in Section 301. (iJ)(1) (8) and (C) of the
I\ct. Therefore. the pel~mitt2e shall comply VJlth the.follo;·/ing
schedule and shall report to the Regional Ad@inistrator'and the
He\'1 Je~'sey D2pa~'tm211t of Environmental' Protection \"ithi n 14 'd(lYs
follO'.·Jin9 euch date on the schedu1e detailing its compliance or
non-compl iance. 2/
The Hudson County Sel·,erage Authori ty is cUl"lently prcpi:lri n9 .
an Engineering and Facility Plan for the Hudson County (ll'ea. nJSDEP
'has indicated that this study must b~ ccmpleted by Decen",ber 1,11975.
Th2refore. the pennittee \'Ii 11 co;r.ply \·lith the fol1m'Jing ,equircments:

a. Interim Plan. No later than August 31, 1975


, the permittee shall submit to both
the Regional Ad;1'linistrator and the l-1e;·J" Jei'sey DepClltment of
Environmental Protection, an Engineering R~port ~~ich discusses
the p~rfilitteels proposal to r;-:aximize the 12'!21 of treatm2i1t
to be pl~ovided at its existing facilities at a minimal
capital expenditure. Upon approval of the Regional Administrator
and the New Jersey Department of EnviroAm2nta1 Protectio~, the
permittee will implement the progra~ ai~Ed at maximizing the
treatment level as provided fDr in this Engineering Report.

b. FinuLP12il. !-lithin 60 C;\ys of j!2~': Jer.sey D::P21"tr:~=nt cf


£nvirun~ner:tu.l Prot2cticil ap;wo'/Cll af the Engineering i),j:d
Facility PlZln pr-epared by the H~!dson Caui1ty S2· ..fera~]e ,rlutha:-ity,
the periTlitte2 shall suiJ:7\i";:; to the i!e~·! Jer-:52Y Department of
Envil'onm::ntal Prot0ctio:1 and the Regio!~21 f\d~iinistri}tor a pl':::1 .lI

of <1ctiO;j1l tJhicn outlii12s the f:,ajcn' steos the D2r[~littee E1~!S~


initiClte to be in cOi-;:pli2il~e \'Iith the recosi~er:dations of .
the Hudson County S2~'lfrage f\Lltho~'i ty report.

If the COLinty plan. as approved by j':e~'JJersey Department of


Envil"Oils2r.ta1 Protecticn prc)'/iG25 TOI' the ab"ncon:i,ent of the
pen;litteels dischai'ge facility ?nd the disci1Jrge of al1 i'iaste-
\·:atc\~ to a ~"egio:1al faci1ity, the pemittee's "plan of actio:"!"
shall include at least the follo;'iing:

i. a statement as to the nature of nodif~catio~s to the


per~llitte::ls f2.ciliti~s that \'iill be l'ecjuired to connect
to th~ rC9ional faciliti~:;.
ii. (]11 c::.tiiJ;:ltcci date tiJ2 per;nittee's fc:.cilities \'Ii 11 be
ab:Jndnn~d.

Iof tile COU:lty :'13:il" uS iJ~'i,ro'''2J OJ t;~·~:::::.; J2l'S2:1 D:::p21'ti,,:n t of


F.nv il"v :i:::::!~Ull i' \"0 ~ec t i 0;1 , ;Jl"O\' i(:2;:; fo!" th l:' i:;':p2 ns i.:)1) and / ('il' :"J ~;g(iHi i :i J
of tll:.? p('!'l,iitte::'s existin~: ~;~ste;·:i:t!.?r trebt;;':.>ni.: fc:ciliti-2s, th~
P(~i'I:il. .!.. I.. cc s
I ,. l'
E~~) or~;-,(.\.t.
,.., ,',.. " . l' 11K
,,:1 s.~= I
. l',:G2 ilL. 1 2l'.S~·i:
•. 1l~ '10 ~ 11 0\'11119=
.

TIERRA-B-015050
" ... Page 13 of 2"8 pages
NJO_027022
i) a statemen"'~lS to the pel'dttee's ir:tent . 'file for
a federal .....IIS tr:.Jction Grc:nt or to COflStru .. C the ncc~ssary
facilities \-/;thout Federal aid.

ii1 if'the pc:r>:littee elects to apply for Fed2rc]] fund:» the


permi ttce \-;1 11 ;'ncl Ud2 the' es t irr;ated c.J te by \·:h i a en
Fed2ral CO;'1structioil Grtnt cplicc1tioil H111 b2 filed \'lith
the State Ag2ncy.
• • .)
l'n
• r::
11
t'ne periTIll.l.ee
. 1 t ...
.I. ...
e ec S.LO iin.:.llce
........
Ln2 canst-rue
t. "~ ....
10n 0;- LDe
necessary facilities \-iithoi.Jt Federal Aid, the p2rmittce's
submission will include a cc~olete schedule for the
financip9" construction 2nd co.:-r:pleticn of the upgraded
. facil ity.

1/ If the_ ti~e period ~llott<:~d for' the completion of an interii.1


reqU)reffient specified above is 9r2~ter ~h~n 9 months, then
the p2rmitte~ shall subsit a report detailing its progress
tO~':~rJ completic:1 of the inted:n requirer,";-2i1t at the end of
the first 9-mcnth p=:dod 2f;d at th~ end of each succe2di:lg
9-month period (including, of cou;-se~ the iepart, specified
above, required ~"'jthin i4 days foilo:'Jing the specified
cO;l1p1.etion date). . .
2/ E(Jen notice of nC:1-coiilpliar.c~ sh.;,ll incluG2 the -rollO'.';;ng
infom~ tion:

A. A short descripti0n of the ncn-CG~pll~~C~;

c. A description of any factors ~hich tend to explain


or mitigate the ncn-cc~pli2nc2; a~d
D• An c:s":','"
-= ... r,)J ~-
I..C
CC..l.
l
1

I..n2
'.L.l.f
U Le I..ne p~rii1'\,.
r.ee
""",. """'1
i~11I
1
COil:PY
\'Jith the elapsed schedule i2q'Ji1'eif.2.'1't ;:nd en _
ass2ssr.:ent of th2 prababiiitv that D2ij'.~itt22 ~Iil]
meet the next schedule requi~e~ent ~n time.

TIERRA-B-015051
,-,
Section C-II "I
r P \ 14 of 28 pages
N.)vu27022

SPECIAL PERMIT CONDITIONS FOR PUBLICLY-OWNED TREATMENT


WORKS COMBINED SEWER OVERFLOWS AND/OR BYPASSES

I. Operation of Systems with Combined Sewers

A. General Requirements

1. The permittee shall operate the treatment works~ including


the treatment plant and total sewer system. to minimize
discharge of the pollutants listed in the permit from com-
bined sewer overflows or bypasses.

2. No new sources of stormwater inflow shall be connected


. to any separate sanitary sewers in the sewer system •.

B. Preliminary Requirements

1. Report on Maximum Treatable Flow Rates

The permittee must report to the Regional Administrator


and the State agency by August 31. 1975
the maximum treatable flow rates for the treatment plant
or 8.r:.y complete unit process. The !r'.3.:dmum treatable
flow rates must. at least, be equal to one of the following:

a. The maximum hydraulic now rate for which the


treatment plant was designed, or the maximum
hydraulic flow rate for which the treatment plant
can provide partial treatment.

b. The maximum now rate that, based on historic


records or theoretical determinations, would
cause a treatment plant upset such that other
permit conditions could not be achieved.

c. The ma.ximum flow rate that can be delivered to


the plant without causing seriously adverse con-
ditions in the interceptor and lateral sewer
system such as substantial.property damage.

The permittee shall operate the system so as to achieve


the maximum treatable flow rate prior to a discharge from
a combined sewer overDow or bypass.

TIERRA-B-015052
~ .
.Pas 5 of 28 pages
NJ0027022

2. The permittee may submit, in lieu of the above, a


detailed operational plan designed to minimize
pollutant discharges from the treatment and sewer
system. The permittee must demonstrate that, if
implemented, the plan would provide for a lower
discharge of pollutants from the system during wet
weather than that occurring if the hydraulic flow
was treated during wet weather at the limiting flow
rate in B. 1. above. The treatment plant and
sewer system shall be operated in accordance with
this plan.

3. The permittee shall also report by August 31 1975


to the permit issuance authority a proposed method
for estimating the number and location of new sewer
connections which will be served by combined
sewers for the duration of the permit. and a pro-
posed method for estimating the impact of the
additional flows generated by these new sewer con-
nections on the volume of discharges from the com-
bined sewer system. This method shall be used in
the development of the operational plan required in
Section C. below.

c. Operational Plan

An interim operatio,nal plan designed to minimize the discharge


of pollutants from combined sewer overflo'.Vs and bypasses
must be submitted by the permittee to the Regional Admin-
istrator and the State agency by re'lJruary 28. 1977
The plan will prOVide for optimal coordinated operation of
the sewage treatment plant and contributing sewer systems.
The plan will specifically:

1. Refine the estimate of maximum treatable flow.

2. Report, if applicable.. the number, location. types. and


kinds of regulators and their respective operating history,
maintenance program. and performance efficiency.

3. Report the calculated or estimated storage capacities


of the sewer system upstream from all control devices
such as pump stations and regulators, or combined
sewer discharges.

4. Provide operational procedures for utilizing at least 80%


of the a\'ailable capacity of interceptors and trunk lines
upstream of any control devices such as pump stations,

TIERRA-B-015053
Page 16 of 28 pages
NJ0027022

or regulators prior to any discharge from a combined


sewer overilOl'/ or bypass; or provide, if such storage
capacity utilization cannot be achieved with existing con-
trol devices, the operational procedures for maximizing
the use of storage prior to any combined sewer discharge.

5. Provide a method to determine if the upstream storage


capacity was utilized prior to any discharge from~he
combined sewer system.

6. Analyze the effect on the total volume of combined sewer


discharges of new sewer connections anticipated for the
duration of the permit. If these additional connections
are expected to increase the total volume of discharges
for like meteorological conditions, the plan must provide
a method for prevention of this increase by regulation or
control of new connectiOrlS andlor an offsetting of any
added flows by such means as sewage and inflow reduc-
tion, in-"system flow routing, and treatment and enlargement
of sewer and treatment capacity.

II. IVlonitoring of Systems with Combined Sewers

A. General Requirements

Point sources 003 through . 015 are


overilows resulting when t~e hydraulic flow capacity of the
system has been exceeded (see page 20 & 2l for a listing of these
point sources). These discharge points may be utilized for
wet weather overflows or bypasses to the extent specified by
the approved preliminary report and interim operational plan.
For all overflows the permittee is required to take the follow-
ing actions:

1. Submit to the Regional Administrator and the State agency


an approvable plan for implementin~ a monitoring program,
as specified herein, by August 3.1., 1975.

2. Within six months of approval of the plan required in


paragraph II. A. 1.. the permittee will implement the moni-
toring progra..rn to determine the location, cause, frequency,
duration, quality, the quantity of wastes discharged (average
and maximum pounds per day) and the method of discharge
from these point sources. Eifluent quantities determined
should include at least the five day BOD, suspended solids.
and fecal coliform.

TIERRA-B-015054
Page 17 of 28 pages
NJ0027022

B. Sampling

1. Sampling requirements fot' combined ~e\Ver disch~rg~


events are based on the frequency, duration or anlount
of discharge. The permittee shall monitor the location.
cause~ duration. and frequency of combined sewer dis-
charge events to the extent necessary to determine which
sampling requirements, if any, are applicable to each
discharge location. This monitoring shall be conducted
during a 12-consecutive-month period.

2. Adequate rainfall records in the major combined sewer


catchment areas must be kept during all sampling and
monitoring re!=l.uiredin paragraphs 3 and 4 of this
section.

3. Type 1 Discharges:

a. Description

Combined sewer discharge events occurring at least


20 times a year, or for a yearly total of at least
90 hours, or with an estimated total volume of any
discharge. event in excess of 2.0% of the annual
average of daily flow during the most recent year
of. record.

b. Sampling and l'\'Ionitoring Requirements

i. A record shall be maintained of the frequency


of discharge events from all Type 1 discharge
locations. The permittee must also establish
a profile of at least four separate discharge
events during the sampling year for a minimum
of 250/0 of the Type 1 discharge locations. These
locations shall be chosen so that they are, to
the extent possible, representative of all the
Type 1 discharge locations.

ii. The profile shall be established as follows:

Discrete samples shall be collected and corres-


ponding rates of £10\'1 shall be recorded within
the first five minutes after the start of the dis-
charge event. and during each 15 minute interval
up to 90 minutes or the end of the discharge,
whichever comes first. The sampling sequence
shall be 0-5, 15, 30, 45.. 60, 75, 90 minutes.
The rate of flow shall be recorded each hour
thereafter for the remainder of the discharge
event.

TIERRA-B-015055
P~ge 18.0£ 28 pages
NJ0027022'

iii. The ab'ove samples must be analyzed for each


pollutant limited in the permit. (See paragraph
II(A.2). above.)

4. Type 2 Discharges:

a. Description

Combined se\ver discharge events occurring at least


10 times a year, or for a yearly total of at least
25 hours. or with an estimated total volume during
any given discharge event in exce3S of O. 50/0of the
annual average of daily flow during the most recent
year of record.

b. Sampling and IVlonitoring Requirements

i. The permittee shall maintain a record of the


frequency of discharge events from at least 15%
of the Type 2 discharge locations. These dis-
charge locations shall be chosen so that they
are, to the extent possible. representative of
all Type 2 discharge locations.

ii. The permittee shall also establish a profile by


sampling and analysis of one discharge event
during the sampling year for each of the T)'})e
2 discharge loc:'iticns chosen :or mO:l.itocing.
This profile shall be obtained in accordance
with 'the procedures in paragraphs 3. b. E. and
iiL of this Section.

III. Reporting Results

A. Interim Reports

An interim status report on the monitoring program and the


abatement study (required by Section B. below), must be
submitted to the Regional Administrator and the State agency
at cOachsix, month interval starting on August 31, 1975.

B. Final Report

Within tw'enty-four months of approval of the plan required


in Section II, paragraph A.I., the permittee must submit a
final plan describing an abatement program to eliminate or
significantly reduce pollution from these sources so as to
maximize the achieYement of water quality standards. The
plan shall include:

- TIERRA-B-015056
Page 19 of 28 pages
NJ0027022

1. The r.esults of the monitoring and sampling required in


Section II shall be summarized as follows:

a. A table shall be prepared showing the frequency of


discharge from each Type 1 and Type 2 discharge
monitored during the 12-month period.

b. A table shall be prepared to display the data obtained


on each discharge event subject to sampling and analy-
sis. The table shall include:

i. Time of day and duration of discharge event.

ii. Total volume discharged during event.

iii. Associated rainfall data for the catchment area.

iv. Flow weighted average concentration of sampled


pollutants during the sampling period.

2. An infiltration/inflow analysis in accordance ,\lith the pro-


cedures for "Grants for Construction of Treatment Works"
(40 CFR 35).

3. A plan to remove major sources of inflow from the sani-


tary portions of the sewer system.

a. dual use tre~tment facilities;

b~ storing and/ or treating initial or final sewer


system flushes;

c. storage and subsequent treatment of discharges;

d. improvements in the sewer system.

5. Estimates of the cost. quantities of discharges and pollutants


'controlled, and the benefits of the various plans or strate-
gies for a wide range of design storms. .

TIERRA-B-015057
Q~sr.r:;pt;ve Li:Jj!b-2..Uj_~churJJ~ Points
HHh in the :~9m~);11 e<i $(;'..1<:)" Sys torn

Discharge Discharge
r~~Htbci" ;!:~!:~-;

:".:~ lJ I <.I1.v"

004 Danforth Ave. 40(>42~3!l 74°061011l Newark Bay


South-Rcgul ator
005
C05 Danforth Ave. 40°42 '~3'1 74°0610111 Ne~'larkBay ~)
North-Rc QU 1i.l to r
006 Duncan Ave. 40°43 -;911 74°05'08"
Regulator
Hackensack·River

007 Sip Avenue 4004t, 0311 74°04'52 11


Hackensack Ri ver
Regulator
008 r~anhilttan Ave. 40°44 -::;I'l 74°03'4811 Hackensack River
Regulator
009 Secaugus Road 40°45 37" 74°0215011 Pennhorn Creek
Regulator
'.',

010 St. Paul sAve. 40°44" ,~21l z....,


74°04'2111 Hackensack Ri ver~
Regulator 0 __ . )
N
'-J

all Van ~'iinkle Ave. 40°44'20" '74°04 31" 1


Hackensack
0"-'
River~ 0
Regul ator
0
-I,
012 Broad1day Regul a tor 40044"j 6" 74°04 43 1 11
"Hackensack Ri vel' N
co
013 Clendcnny Ave. 40°'13'22" 74°0513011
Regulator
Huckensack Ri ve I· -n
"
L.o;...
fil
III

TIERRA-B-015058
Discharge Discharg~ Di~churge Point
Nurr:bcT' Nume Latitude Longitude Receiving Water~al

014 Claremont
Regulutor
Ave. 40°43'05" 74°05'41" Hackensack River .
015 Fisk Street 40°42'55" 74°05'4]1' Hackersack River
Regu1 i1tor

Discharge No. 001 is obt?ined in the Jersey City S.A. Eastside Treatment Plant NPDES permit
'(No. NJ0027014).

Discharge No. 002 13 the Westside Treatment Plant's outfall line.

N
<Xl

TIERRA-B-015059
,.,'
.__ ...~.
--- ",

\
Page ,of 28Page
NJ0027022
SCHEDULE OF COMPLIANCE FOR INDUSTRIAL
DIsCHARGE n~roRMATlon

It 1s apparent that other pollutants attributable to inputs from


major contributing industries using the m~~c!pal system are also
present in the facility's discharge. At such time as sufficient
information becomes available to establish limitations for such
polluta.'1ts,this permit f1\.ay
be revised to specii'y effluent limi ta-
tions for any or all of such other pollutants in accordance with
industrial best practicable tecr~ology requirements or vater quality
-standards.

Not later then 180 days following issuance of this permit, the
permittee Ehall have prooulgated an enforceable industrial waste
ordinance. This ordina.'1ceshould aJJ.O'lf' the pert:litteeto enforce
all pre-treatment requirements necessary to ensure compliance with
the terms ond ccndi tions of this :perm!t, as "ell as to ensure com-
pliance by all major contributir.g industries* with the pre-treatment
standards and any other applicable require~ents promulgated pursuant
to Section 307.of the Act. A copy of this c~dinance is to be submitted
for approval by the permit issuing authority, such approval being
an enforceable provision of this :~D~Spercit. ThiG ordinance shall
require each major contributing industry to sub~t to the permittee
periodic notice (at intervals net to exceed 9 months) regarding
sp-ecific actions taken to achieve i'ull compliance ".riththe requireme:lts
of Section 307. On the last day of the !!lor:ths cf Septenber
and I-larch , the p'er::-~i
tte~ shall submit to "t.nepermit
issuing authority 8. report sU:'Tt"43.rizine;
th·~progress of all 1<.,'10',,'11
major contributing ir;ciust.ries ,,0
s"J.'Dject the requirer.ientsof Section
307 tm:ards full compliance 10. th sucn requirements. Such reports
shall include at least the follOWing information:

(1) A narrative s~ry of actions taken by the permittee to develop,


promul£ate a.~d enforce the local industrial waste ordinance and
thereby ensure that all mnjor contributing industries cocply
with the reqlurem~~ts of Section 307.

(2) The number of rrajorcontributing industries using the treatment


works, divided into SIC ~TOUP categories.

(3) The number of major contributing industries in full co~pliance


with the requirements of Section 307, or not subject to these
requirements (e.g., discharge only co~patible pollutants).

(4) A list identi~~ng by name these reajor contributing industries


presently in violation of the requirements o~ Section 307.

TIERRA-B-015060
-:-'\
Pl 23 oE28 pages
NJ0027022

These semi-annual reports must be filed with the permitting authority by


September 30 and HaTch 31 of each year until compliance is
achieved. Submission w"'Quldbe required again only if a major contributing
industry reverts to violating the requirements of Section 307.

Immediately upon issuance of this permit, the permittee shall establish


and implement a procedure to obtain from all major contributing industries
specific information on the quality and quantity. of effluents introduced
by such industrial users. The follOWing information shall be reported
to the permitting agency on a quarterly basis beginning Sente8he,. 30,;1975;
quarterly reports reflecting no change from the previous qu~rter may
simply relate this fact, without submitting repetitive data. These
reports should follow the fOl~at outlined in Appendix 1 to this permit.

Based on the information rega.ding industrial inputs reported by the


permittee pursuant to the preceding paragraph, this permit may be amended
to reflect the municipal facility's effluent requirements for incompatible
pollutants.

Pursuant to Section 307 (0) (1) of the Federal Hater Pollution Control
Act Amendments of 1972, the Administrator published "Pretreatment
Standards" for pollutants introduced into a publicly o~~ed treatnent
works in the Federal Register, Volume 38, 215 on Thursday, :Xovember 8,
1973. Nothing in this permit shall be construed to relieve any major
industrial contributor from their ob1ieations to co:!\ply"lith these
standards.

* A major contributing industry is onc that: (a) has a flow of


50,000 gallons or more per average ~orkday; (0) has a flow
greater than five percent of the flow carried by the municipal
system receiving the ,,'aste; (c) has in its ..
·aste a toxic pol-
lutent in toxic amounts as defined in standsrds issued under
Section 307 (a) of the Act; or (d) has significant i~pact, either
singly or in combination ~ith other contributing industries, on
the treatment ~orks or the q~ality of its effluent.

TIERRA-B-015061
'\

Page 240£ 28pages


NJ0027022

APPEh''DTX I

To comply with the reporting requirements of Cont:lition C-III ;


the following procedure should be utilized for each major contributing
industry:

Using the following format, a description of each


major contributing industry discharging to the
municipal system should be prepared. A separate
set of six guest ions should be completed for each
major industrial user.

"See Section IV of Standard Form "A" attached."

It is the responsibility of the per:nittee to obtain the required


information for all major industrial contributors to his facility,
including those contributing via another system. Actual data
should be provided if available; otherwise, the best estimate
should be provided and the response r.arked. "interim". If certain
of the requested information does not apply, it should be marked
"N.A."

Specific instructions follow:

~estion 1: Najar contributing facility - Give the name and


address that designates the loc2t!c~ 0f t!le industrial facility.

Q.uestion 2: Prinary standard industrial classification code-


Vsing four-digit standard industrial classification (SIC) codes,
indicate the type of industrial facility that is discharging into
the municipal system. Standard industrial classification (SIC)
code numbers and descriptions May be found in the 1972 edition
of the "Standard Industrial Classification I'lanual"prepared by
the Executive Office of the President. Office of Management and
Budget, which is available from the Government Printing Office.
Washington, D.C. Do not use previous editions of the manual.
Copies are also available for examination at state water pollution
control offices, Regional Offices of the Environmental Protection
Agency, snd at most public libraries.

Question 3: Principal product or raw material - Specify either


the principal product or the principal raw material and the maximum
quantity per day produced or consu~ed. Quantities are to be reported
in the units of measurement given in Tahle B for particular SIC
categories. Enter the letter-nu1T!bcr code from the "Code" colunm
in Table B for the units selected under "Units. " For SIC categories
not listed. use the units of measurements normally used by that industry.

TIERRA-B-015062
---.....

Question~: Indicat~ the characteristics of the wastewater


from the contributing industry in ter1:'1sof parameters the t
will adequately identif'y the waste, such as BOD, COD, Cr, Zn,
pH units, degrees Fahrenheit, etc. 1~e characteristics should
be indicative of the h~ste stream after any prewtreatment is
provided by the industrial facility but prior to entering the
municipal system.

In addition to parameter names, report values in units specified


in Table A. The first column, "Parameter & Units, indicates
the preferred lli,itsfor reporting data for a given parameter.
The second column, "Method lists the preferred -a."1alytical
ll
,

method (if any) for determining the required par~eter val~~s.


The next three colu:n.'1s, References, " give the page nUIncers in
II

standard reference works where a detailed description of the


recommended analytical technique given under "Hethod" can be
found. These standard references are:

(1) standard !I;ethoas for the Examination 01 Water and Wastewaters


13th Edition, 1971, America..'1
Public Health Associa.tion, Jlew York,
New York 10019.

(2) A.S.T.M. Standards, Part 23, ~ater; Atmospheric Analysis,


1972 American Society for Testing and :.~aterials,Philadelphia,
Fa. 19103

(3) £FA :·:ethods for Chedcal Analysis of ":ater ani i-ie.stes,


April 1971, Environmental ?rotection Agency, I\ater Quality
Office, PJ1als~ical ~uality Control Laboratory, KERC, Cincinnati,
Ohio 45208.
Copies of these pUblications are Evailable fTom the above ~o'~ces,
or for review in the Regione.1 Offices of the EnviroI'l!::lentul
Protection Agoncy or the stnte Water Control Beard.

The last colUTI'n, "Data Reporting Level," indicates thRt nearest


significant figure (digit) to which the data must be reported.
For example, the figure X for cr~oride indicates that chloride
data must be reported to the nearest whole milligram per liter.
This level should not be confused with "detectable.limits";
applicable detection limit information can be obtained from the
appropriate reference source.

TIERRA-B-015063
FOR.., APFRO~·£t
OMS No, 158-ROlt
Page 2~-~f 28 pages
NJ002~ , FOR AGENCY USE

STANDARD FORM A-MUNiCiPAL

SECTION N. INDUSTRIAL WASTE CONTRIBUTION TO MUNICIPAL SYSTEM

Submit a description 01 each major Industrial faci lity diSChargingto the mu nlcipa, system, using a separate Section IV for each facility deocrlp--
tlon. Indicate the 4 digit Standard Industrial crassificaUon (SIC) Code for the industry, the maJor product or raw material. the flow (In tho",-
sand gallons per day). and the cnaracteristlcs 01 the wastewater diocharged from the industrial lacHity into the municipal system. Consult Table
"\ for standard measures of prOducts or raw materialS. (see Instructions)

t. Major Contributing Facility


(seeInstructions)
Name

Number& Street 40fb

City 40tc

County 401d

State 401e

Zip Code 4011

2. Primary Sta"darCllnClu.trial 402


Clas,/Iicati on Cod. (see
innructio ns)
Units (S""
QuantIty ~~
3. PrtMc'fpZiI Product Of'" Raw
Materi.al (!oe instructions)
.... , .
Product 403a A03c !l-------

I~03d ~ I,<\03i. ---

4. FlOW Indiczle n,e-


volume of v:a~er
di~ch~(ged into t ne munic:pal ~ys' 4040 ______ tnousand gal:ons per day
tern in thousand g.allons per day
.and wr.c-th(:( this. ~ischzr~e
mitter.t or continuous.
is int-cr~ 404b o I"armi:te;;t (int) 0 ContlnuouS(cen)

5. Prct,e>tment Pro.ided l"dic~le if 40S DYes DNO


proetrtatrn£rH is pro ....
j~ed orior to
en'erl nf; the rnu nicip.al system

Ei.. Ct1;UoiIt\e:r''5tit.s of W.ol.5tew,iHer


(.ee ins! rucl iens)

Parar;;et(>(
,jame
Pa(~~eter
4060
Number

406b Value .

EPA Form 7550-22 (7-73)


IV-l This section contains 1 pill/e.
GP 0 865.706

TIERRA-B-015064
Page 27 of 28 pag€s
NJ0027022

Sampling Schedule I

The permittee shall take daily 24-hour composite samples** of in-


take water (surface water body only) and of each discharge over a ty-
pical production period of at least 7 consecutive operating days. One
or two grab samples per day shall also be taken during maximum antici-
pated waste loadings (i.e. naximu~ production period, batch dumping,
washing operations). This sampling program shall be carried out to
insure complete, reliable results which will typify the plantts
discharge.

In lieu of this sampling program the permittee may submit documenta-


tion indicating the results of previous sampling programs for all or
part of the required parameters. The data utilized in obtaining the ave-
rage and maximum values which appear in the permit application can be
substituted for this report if the reported values can be shown to he
representative of the permittee's current dischargers).

**Grab samples only shall be taken for analysis of dissolved oxygen,


eil 2nd grease, pll and any bacteri0lo~ical analysis. Care shall be exer-
cised when collecting a composite sa~~ple such that the proper preserv-
ative is present in the sample contai~er duri~g sample collection. De-
pending on the analysis to be conducted, several different containers
and ?rescrvation techniques ~~y be required. Samples shall be analyz2d
as quiCKly as possible after collection and in no case shall the 'i:laxitnum
holding time exceed that contained in the references cited .in Table A
of standard forms application.

TIERRA-B-015065
Page 28.of 28 pages
NJ0027022

This permit shall become effective on February 28. 1975.

This permit and the Authorization to discharge shs1l be binding


upon the permittee and any successo~s in interest of the permittee and
shall expire at midnight on June 30. 19;7. The permittee shall not
discharge after the above date of expiration. In order to receive
authorization to discharge beyond the above date of expiration. the
permittee shall ~ubmit such info~tion. forms •.end fees as are
required by the agency Iluthorized to issue HPDES permits no later
than January 2. 1977 '

By authority of

(Date)

Meyer Scolnick. Director


Enforcement and Regior.al
Counsel Division

TIERRA-B-015066
~SEWAGE
CONTINUED fROM PAGE 1

1~--~-- ~------~

"'These results show that the Alan MytBlkaj- diredvf of the In since the study ~gan, said Man"
city has a $l!:'riQus problem with te-r3tate Sanitation Commission, roo adding that the study will be
maintenance I,)f its sewerage tn- s,n autonomous agli!Ocycharged romplete when .each pi~ ha.s
fra!:ltrutttlr~T" Manz.o said, with monit.oi"ingwater quality been sampled three times,
'They (city offici.l.) are going to in the trist.ate area. At each of the outfall pipes,
be very embarraased by what we . Mytdka said he would do Ma.mo said, inves-tigatora- have
turn out". ' "whatever it t.akes" to stop .cop· found fee.a] (oliform levels far
,., Manzo, an outspoken health firil"i-ed vioiatkms, including lak- :exc"*,,ding aHowed' .etandarde.
code enfora::er, h9.s- publicly ing the city to CQurt. Fee"l ooliform, a bacteria f"und
dashed 'with city officials "nd' A spok""man for tbe state De, in human feces, was fQund at
ma.jor developers:· Manm's de- partmenl t)f Environmentai Pnr 2,400 paW. per 100 millilitero at
partment undertook the study in iection said that if the city ea-ch {)f the outfaH 81ie3. Water
July, anti p]STI5 to release it in Health Department had found dist;harged from sewage t~at·
lat.e October_ any vi-olaUons, the state depart.- ment plant must have feea.l col.
City officials reacted mm-fl ment would like to know al:xmi iform 1••• 1. below 200 parts per
with ~nger than embarrassment
tv M(U~zo>scha-rg-es. Mayor An-
thony R. -Cucd, acknowledging
them, Lns-t m{loth,
Hsckenser;;k had been fme-d:
rnQl'e than $400.00-0 for dis-
h:e ·eaidt lOG mmUlte"", a .tate d.!,art~
ment spokesman
Manw said
said.
that because it
'l
defitienc-e8 in the rntmicipat
s-ew'?r .system, :Raid the dty was
~hea:n~:~. raW sewage during d~ rained gO litU-e in July and Au,
gust. the "ve.t mejodty" of the
8pend~f.lg $102 milhon over five Like many o.th..e-r Hudson Il8ml'l•• were taken during dry
yenrn lo bring the 10Q·year.otd County municipa.lities, this! weather,
pipe c(lmplex into good condi· city's system -c-ombihe$ its storm, The findings .how the regu· o

HO-I'L . water a.nd sanitary aewage "')la-· laLor-a arfl maJfunctlQn-ing. Msn~
louis M. -Malllzo#chlef i-~S~ge-tO., '0' tb6~~~;ey
~itl H.ahh D-eparim_8ot, &;li.smlns"S theelen-denn)' • "We a~e not lurning Q-urbatks tern. On rainy d.eys. storm water w said. R..egulatoTS aTe- devices
"\verm-e:S8WIM oU1'hdi pipe yu-stard3y, A !liudy befng Utldeiiakl'1ln b~htS d8va'tm-en~ a::;.rGc manunoC~ii;)t':H1g tin the problem/I he said. "'But overl()eds the city'a tWI'J sewage ntled into the main sewersge
ouUaUs ar-e releasing niW 'Sewago into the HtiH:;'kef1.$~IM:::~
lu\~ud'8-gn dvsn. - I, ~t'5- not something YVl.r'Van put a treatm-e:nt plants and the excess pipes that are d-esigne.d to aHow
f '. • i' I: ' .. \ :
>'
J""'''''
,t
USA
'-
-S"'>1&0 il'fE ;'lj~!I¢N t;l1SltATCl-l
$ancla~~ un and 1!l:ake it go, a rnixtur~ of B€Wage s,·nd freah
j

,ra.in-dHut.ed was~ to flow out

aste,f·oul's~.r·ivers
~ , ~: J. ~ ";_ -- . .;"'-,_ _:'.' ,":, . ". J'. ,! '
a:w!':\y. water, is p=er-roitted tn be. re~ into the rivers only when the
h~l~se{l through the outf.aUs. sewerage system backs up.
REPRESENTATIVES OF The city department launched Mithael Barnes, the dt:-/!!'
atate and regionai poHutiulJ (:{m· lL,,>invest.igation of the city's out" chief engiuE!ier, rf!:ojJKlns.ibl~ for
trol agerH::!.t;oS sa.d while they faHa tm <July 19, aet:(l-rding W m.n-intai.n~ng-the sewage Gutflo-w
Study:outf~ns releasingunireated sewage
~ • 1 ',.' , - '
were unaw.Qr'E! of M8nw\s find-
. 'inge, if they .founa them to be
Ma-n::w,and haa since found that
wst-er leaving and surrQumEng
most of the 20 outfall pipe.
syst~rn, :a-ccuse-dMsn2'£ of sding
irreBponaibly by. not infotming
th-e city of biB pr€Hminary find·
substantiated, the city could be
By JONATHAN BfUNC:KMAN jng th-e lnvp.$tlgatiLln. Bald the uncompleted study heavily fined.' ' being: studie<:!is highly I"'Huted in~.,
The Hurls-on DIspatch . lEi fin(Hng that most of lh~ city's Jl{JUtfaH plp-es·' "If you have 24 houTS of dry with sewage, even during dry j If heis fQund s malfunction-
JERSEY CITY -Large amounts of' untr-eated :rel-e-asing raw sewage ~nto th-e rivers
aTe -dudng w-eather und there's still Taw weather. ing l"€gulator. he should have
sewag-e ate f10wtng dkectJy into the Hudson ' dry weal-heL The dty's- 26 outfall pipes are de· sewag-e coming (Jut 'Of the out· MOST OF the pip.shave tcld us immediately," .aid
Ha-ckensack rivers bec~use of malftindiQns in sign{ld, to discharge diluted Wl:ls.te into the -dvers faUs.. that's a v.aolaU(ln,'" said bee~ sampled on tWiJ (JC(;aS10I18
Barne:5.
city sewage system, according L(l stu.dy be:in_g om. only whe.n h~avy rutn overloads the :,:;ewerage ~Y5'
dueled by the Health DBpartmeqt here, tern.
Chief Health l!1speetor Louis M. Manw, head· Plea~- ~ee SEWAGE Page-a

SCIOllflO18

TIERRA-B-015067

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