Professional Documents
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Journal of Environmental Chemical Engineering
Journal of Environmental Chemical Engineering
A R T I C L E I N F O
A B S T R A C T
Editor: P. Fern´andez-
Iban˜ez Water-energy nexus is a highlighted topic nowadays, particularly, the energy consumption in wastewater
treatment plants (WWTPs) is becoming an important issue. WWTPs typically consume more energy than the one
Keywords: that can be obtained from the biogas produced from sludge anaerobic digestion. In this work, a process-level
Wastewater treatment plant analysis is presented to study the feasibility of integrating wastewater and municipal solid waste (MSW) treat-
Sewage sludge ment to achieve the energetically self-sustainable operation of a WWTP. The influence of the climate of different
Municipal solid waste
regions across the Iberian Peninsula on the energy requirements has also been evaluated. Mesophilic and ther-
Energy
mophilic digestion are compared in Salamanca as a case base, and the optimal digestion temperature is also
evaluated, finding a value of 30∘C. Moreover, in all cities considered, it is necessary for MSW to provide between
37% and 40% of the facility energy consumption corresponding to around 0.19 kg of MSW per kg of sludge, with
a small difference between cities. From an economic point of view, an investment between 0.09 and 0.16 €/kg of
sewage sludge is required for the integrated process. Therefore, this techno-economic assessment demonstrates
the feasibility of integrating these two treatments for a fully self-sufficient and sustainable process.
* Corresponding author.
E-mail address: mariano.m3@usal.es (M. Martín).
https://doi.org/10.1016/j.jece.2023.110673
Received 23 January 2023; Received in revised form 12 June 2023; Accepted 28 July 2023
Available online 1 August 2023
2213-3437/© 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-
nc-nd/4.0/).
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Variables/ parameters Equipments and others Bioreactor Digester. Compresi Gas compressor i. Furnacei Fu
Ebiogas EdigesThermal energy provided by biogas (kW). HXiHeat exchanger i.
Thermal energy requirements in digestion process (kW). MixiMixer i.
EMSW Thermal energy provided by MSW (kW). MSiMolecular sieve i.
SepiSeparator i.
F(unit i, t, i1) t1) n i t1)unit n i t1) Mass flow rate of stream from unit to unit1 (kg s—1).
SnkiSink of stream i.
fc(k, unit i, t, i1) t1) n i t1)unit n i t1) Mass flow rate of component k from unit to unit1 (kg s—1).
SrciInlet source i. TurbiGas expander i.
fcMSWelectrical Mass flow of MSW to provide electrical energy (kg s—1).
fcMSWthermal Mass flow of MSW to provide thermal energy (kg s—1).
2
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
achieve the self-sufficient operation is the use of an external source
of
3
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
4
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Fig. 1. Schematic diagram of the integrated process of sludge and MSW treatment.
and, that can be regenerated using oXygen, following this reaction [33]:
2Fe2S3 + 3 O2→2Fe2O2 + 6S (3)
Considering that the H2S is completely removed and the factor that
the solid remains in the bed and water is generated, the mass balance
model is computed based on the stoichiometry of the first reaction.
5
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
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E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
The amount of condensing steam that has to be produced in the
furnace in which the MSW is incinerated to provide these energy re-
quirements can be obtained by doing the energy balance (See Supple-
mentary Material).
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E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Table 1 turbines has the same value as the electrical consumption, so, modeling
MSW composition. the Rankine cycle, the amount of steam and the energy requirements can
Component Ultimate Analysis be obtained. Once obtained these energy requirements the amount of
C 57.62
MSW needed for power purposes (fcMSWelectrical ) can be determined by an
H 8.45 energy balance. Further details are shown in the Supplementary
O 31.50 Material.
N 0.24 Finally, by doing a mass balance, the total amount of MSW that is
S 0.47
needed to provide the additional thermal energy requirements in the
Cl 1.72
Total moisture (%) 50
digestion process and the electrical requirements in the WWTP is
determined (Eq. (11)).
fc(MSW,Src6,Furnace2) = fcMSWthermal + fcMSWelectrical (11)
Snk10
Flue gases
Part of this energy is devoted to the production of steam that pro- requirements. For the optimized process, different regions of the
vides additional energy in the digestion process. This steam is consid- Iberian Peninsula have been studied considering the different cli-
ered to bebysaturated
obtained at 10.2 atm The
biogas combustion. as well as theofproduced
amount MSW thatwith flue gases
is needed for mates that influence the air and water temperature each month
which are shown in the Supplementary Material. In addition, the
thermal requirements (fc process of the incineration of MSW is modeled and integrated with
) is computed taking into account the
(MSWthermal ) the sludge anaerobic digestion to obtain the amount needed to pro-
amount of condensing steam needed considering the value of the addi- computed by the correlations proposed by Leo´n and Martín [28] as
tional thermal energy in the bioreactor and the heat exchanger (see a function of pressure and temperature. In each of the turbines, the iso-
Supplementary Material). entropic efficiency is fiXed at 0.9. The sum of the power produced in the
So, in the end, the global energy balance on Eq. (10) must be
satisfied.
)
QextraHX3 + QextraBioreactor = fc(H2 O,Furnace1,Mix1) + fc(H2 O,Furnace2,Mix1) ⋅Hsteam
(10)
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E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
vide the additional thermal energy and the power to operate the
WWTP in these cities. Particularly, the climates that are chosen
are:
– Oceanic climate in A Corun˜a, with temperatures between 10
∘ ∘ ∘ ∘
and 13 C and 10–11 C in winter, and 16–19 C and 14–16 C in
summer for air and water, respectively.
– Coastal Mediterranean climate in Barcelona, with temperatures
∘ ∘ ∘
between 9 and 13 C and 9–10 C in winter, and 20–23 C and 17–
∘
19 C in summer, for air and water, respectively.
– Continental Mediterranean climate in Salamanca and Madrid. In
∘ ∘
Salamanca, with temperatures between 4 and 6 C and 6–7 C in
∘ ∘
winter, and 18–21 C and 15–17 C in summer, for air and water,
∘ ∘
respectively; and, in Madrid, with 6–8 C and 8 C in winter, and 21–
∘ ∘
25 C and 17–20 C in summer.
– Oceanic Mediterranean climate in Sevilla, with temperatures be-
∘ ∘ ∘ ∘
tween 11 and 12 C and 11 C in winter, and 23–27 C and 19–21 C
in summer, for air and water, respectively.
These cities have been chosen to study most of the climates within
the Iberian Peninsula, but also to cover a wide range of WWTPs sizes in
order to evaluate their influence on the results.
The population of the different cities that are considered and the size
of their WWTP is shown in Table 2. The size of each WWTP is related to
the amount of organic matter that is treated, also shown in Table 2,
considering that a person in Spain produces 26.9 kg of dry matter
per
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E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
City Salamanca La Sevilla Madrid Barcelona combustion. The amount of biogas generated depends on the digestion
Corun˜a 3
temperature, obtaining 0.47 m /kg in the mesophilic condition and
3
Population 144000
a
244850
b
689000
c
3266000
d
1637000
e
0.58 m /kg in the thermophilic condition. The thermal energy that is
(hab.) needed in the digester has the same value in both cases, 914.5 kW,
WWTP size (hab. 260040 600000 950000 1335000 1706250
eq.)
because it is considered an isothermal process, it only depends on the
Processed sludge 1.34 3.10 4.91 6.90 8.82
enthalpy of the reaction. Nevertheless, the digestate dewatering con-
(kg/s) sumes more energy in the mesophilic case, 467 kW vs. 358 kW, because
Electricity 1.46 3.36 5.32 7.48 9.56 the outlet temperature of the heat exchanger has always the maximum
consumption ∘
value (150 C), so the gradient temperature of the thermophilic case is
(kW)
lower, and the average temperatures have the same value in both cases.
a: Huerta Otea WWTP [39], b: Bens WWTP [40], c: Copero WWTP [41], d: La These two thermal energy requirements do not change over the months.
China WWTP [42], e: BaiX Llobregat WWTP [43]. However, there are two more energy requirements in the process, which
are the sludge heating before digestion and the air heating before
year [37]. Also, it conditions its electricity consumption, shown in combustion, and these values do change with the different water and air
Table 2 too, considering that the average consumption of a WWTP in temperatures over the months. These values are shown in Fig. 6. For the
Spain is 5.6 kW/hab.eq. [38]. In the case of Madrid, it is shown that mesophilic case, the sludge and air heating consume from 163 kW and
the size of the WWTP is lower than the population, and, also, that the 13 kW, respectively, in January, the coldest month, to 101 kW and 2 kW
size is lower than the size of the WWTP of Barcelona, despite the fact in July, the warmest month. For the thermophilic case, the energy
that the population of the latter is smaller. There is not one WWTP consumption changes from 275 kW to 213 kW in sludge heating, and,
that covers the total population of Madrid, because of its high the energy consumption for air heating is the same as in the mesophilic
population, so there are several WWTPs distributed throughout the city case (from 13 kW to 2 kW), because the amount of air and the temper-
and one of the largest is chosen in this work. ature gradients are the same in both cases. Fig. 6 shows the additional
thermal energy that is necessary for both digestion processes. The
4. Results analysis shows that the energy provided by biogas combustion is not
enough to comply with the total energy requirements. Although the
In this section, the process analysis and economic results are pre- digestion temperature is lower in the mesophilic case, it can be seen that
sented for the case base of the WWTP in Salamanca and the integrated the amount of additional energy is higher than in the thermophilic case,
processes in the different WWTPs considered. from 40% to 38% in mesophilic and from 38% to 36% in thermophilic,
and, in both cases, is lower as the month gets warmer. As expected, this
fact is due to the significant contribution of digestate dewatering to the
4.1. Case base analysis
total thermal energy requirements of the process, which is higher in
mesophilic digestion (approXimately 30% vs. 23%). In fact, the addi-
4.1.1. Process analysis
tional thermal energy without considering digestate conditioning is
As a case base, the operating conditions of the two operating modes
Fig. 6. Energy contribution of sludge and air heating to mesophilic and thermophilic digestion in Salamanca and percentage of additional energy needed.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
higher in the thermophilic case (16–20% vs. 9–14%) (Fig. 6). Although it
is shown that digestate dewatering consumes a large amount of energy month, and the maximum value has been considered to obtain the
this section of the process is included due to its advantages. The diges- capital cost, i.e., the equipment is the same each month and only
tate can be used as fertilizer because it is rich in nutrients such as ni- changes the utilization factor of some of them. The utilization factor is
trogen, phosphates, and minerals, so it can reduce the need for artificial defined as the ratio between the capacity in each month of the equip-
or synthetic fertilizers which are known to be harmful to the environ- ment and its maximum capacity. In both digestion processes, only the
ment, and, also, more expensive. The removal of water reduces utilization factor of the furnace changes. Taking into account the heat
handling, transport, and storage costs and results in a drier compost that duty over the months shown in Fig. 6 and the maximum capacity cor-
is easier to spread on the soil, and nutrients are not compromised during responding to January in both cases, the utilization factor of the furnace
the dewatering process [44]. is reduced to 83.6% in the case of mesophilic and to 85.4% in the case of
Then, once the process operation has been presented, the optimal thermophilic. Regarding annualized investment, considering an annual
∘
digestion temperature is to be determined within the 30–55 C range. It capital charge ratio of 0.3 [45], similar costs are obtained: 0.079 €/kg of
∘
turned out to be 30 C for all months, regardless of the water tempera- sludge for mesophilic digestion and 0.080 €/kg of sludge for thermo-
ture. The optimization selects the lowest digestion temperature of the philic. These values are close because the main contributor to the in-
range in order to reduce the thermal energy involved in the process. vestment is the equipment cost, particularly, the cost of the digester
Considering the previous part, the total energy requirements are slightly which is the same for both digestion processes. The cost of the
lower in the mesophilic case, because there is a net energy difference in digester contributes 84.6% to the total equipment cost in the case of
its favor considering sludge heating up and digestate conditioning. mesophilic and 83.6% in the case of thermophilic. This gap is caused
However, while the additional thermal energy requirements are reduced by the dif- ference in the heat exchangers and furnace cost because
with increasing digestion temperature, the increase in biogas production the cost of the rest of the equipment has the same value in both cases.
does not compensate. Therefore, the value of the total energy is crucial In Fig. 7, the value and the breakdown of the equipment cost for both
to obtain the optimal temperature. This optimal temperature is the value mesophilic and thermophilic processes in Salamanca are presented.
used to study the influence of the climate because it determines the The cost of the furnace in mesophilic digestion is lower because the
value of the energy that heats up the sludge before digestion and the air thermal energy requirements are also lower, so the size of the
before combustion. In this case, approXimately, an additional energy equipment is reduced. The price of the furnace contributes to the
between 38% and 40% is needed, a higher value than in the case of equipment cost with a percentage of 7.97% in the case of mesophilic
∘
mesophilic digestion at 35 C because the digestion temperature is lower. and 8.24% for thermophilic. For the heat exchangers, the cost is
The change over the months and the different contributions to the total higher in the case of thermophilic, although the cost of the heat
energy are shown in Section 4.2, where they are compared to other exchanger that dehydrates the digestate is lower, because the gradient
climates. temperature is lower, however, the cost of the heat exchanger after the
digester is higher, for the same reason, and makes the total heat
4.1.2. Economic analysis exchangers cost increases. Its contribution to the total equipment cost
An economic analysis of the digestion process for both operating is 2.82% for mesophilic and 3.57% for thermophilic. The contribution
conditions, mesophilic and thermophilic, in Salamanca, is presented in for the rest of the equipment in both cases is 3.70% for compressors
this section. Investment and operating costs are estimated. The invest- and 0.87% for the PSA system. In the case of operating cost, it is also
ment does not present a variation over the months, so the total operating similar in both digestion processes, because of the similarity in the
cost neither changes, because the amount of sludge that is treated is investment cost, only deferring the items that directly depend on it.
considered the same over the year and the design of the WWTP does not The operating cost has a value of 0.072 €/kg for mesophilic 0.073
change over the months. The equipment cost was obtained for each €/kg for thermophilic. The operating cost and its breakdown are also
shown in Fig. 7 for mesophilic and thermophilic conditions in
Salamanca.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Fig. 7. Value and breakdown of the capital cost (CC) and operating cost (OC) for mesophilic and thermophilic anaerobic digestion in Salamanca.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
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E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Fig. 8. Total energy requirements per month in Salamanca, La Corun˜ a, Sevilla, Madrid and
Barcelona.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Fig. 9. Energy contribution of sludge and air heating to digestion and percentage of additional energy needed in the different WWTPs per month: a) Salamanca, b) La
Corun˜ a, c) Sevilla, d) Madrid and e) Barcelona.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
because, as it was said, most of the fed MSW is devoted to electricity
production and this amount does not change over the year. It can be
seen that the percentage of the total MSW is not directly related to the
size of the WWTP. This percentage is higher as the relationship between
the population and the equivalent population (hab.eq.) of each city in-
creases. Furthermore, in all cases, there is enough MSW to supply the
plant, a fact that could be relatively predicted previously according to
the work of Gonza´lez-Nú n˜ez et al. [24], where the energy that
can be produced from MSW of different cities studied in this work is
shown.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
Fig. 10. Amount of MSW to provide extra thermal energy requirements per month in Salamanca, La Corun˜ a, Sevilla, Madrid, and Barcelona.
Table 4 decreases. Therefore, although, both capital costs are higher in the
Total investment cost of the integrated process per kg of sludge and per kg of larger WWTP, they benefit from economies of scale.
MSW for the different cities.
Fig. 11 shows the breakdown of the equipment and the operating
cost for the different cities. The digester is the main item in the distri-
City Salamanca La Sevilla Madrid Barcelona bution of the capital cost in all cities, with around 51% of the total
Corun˜a
inversion, followed by the steam turbines, with a 25%. The digester
Investment (€/kg 0.163 0.116 0.099 0.093 0.086 percentage changes with the size of the WWTP, i.e., the amount of
sludge)
sewage sludge processed, it goes from 43% in Salamanca, which is the
Investment (€/kg 0.859 0.610 0.525 0.491 0.456 smallest WWTP, to 57% in Barcelona, which is the largest WWTP. The
MSW)
percentage corresponding to the steam turbines follows the opposite
trend, it is lower as the size of the WWTP increases, ranging from 33% in
and per kg of MSW, from 0.46 €/kg to 0.86 €/kg, in Barcelona and Salamanca, to 20% in Barcelona, although their cost is higher in the last
Salamanca, respectively. It can be seen that, as the size of the WWTP one because of the electricity consumption. The capital cost of the rest of
increases, the investment cost per kg of sludge and per kg of MSW the equipment slightly changes between cities. An average of 5.3% for
Fig. 11. Value and breakdown of the capital cost (CC) and operating cost (OC) of the different WWTPs.
1
E.C. Blanco et Journal of Environmental Chemical Engineering 11 (2023)
the heat exchangers, 3.3% for the biogas furnace, and 13.1% for the
MSW furnace, and the rest goes for the compressors and the PSA system. Additionally, prices ranging 0.08–0.23 €/kWh are obtained for the
Regarding operating cost, all items that constitute this cost, increase electricity produced by the incineration of MSW. Comparing these prices
with size, however, their contribution to the total value is different. The to other renewable or traditional sources, there is a pro Ximity in prices
main contributor to the total value is the capital charges item with an that makes feasible the use of MSW as an energy source in order to
average percentage of 60% of the total operating cost, but with a small reduce the use of fossil fuels. This analysis allows for a successful inte-
increase with the size of the WWTP. It ranges from 58.2% to 61.1% in gration of these treatment processes with the objective of a fully self-
Salamanca and Barcelona, respectively. The percentage of the three sufficient and sustainable system.
other items which are represented that barely increase with the size and
are almost constant are maintenance, insurance, and local taxes, with an CRediT authorship contribution statement
average value of 20%, 4%, and 8%, respectively. As there are items
whose percentage increases, the labor and the item which is called Elena C. Blanco: Conceptualization, Dara curation, Formal Analysis,
others decrease with the size. The relationship between the labor cost Investigation, Methodology, Software, Visualization, Writing U˝
and the size of the WWTP is nonlinear, so, although the value increases Original
with the size, its contribution to the total operating cost decreases; so, Draft. Mariano Martín: Formal Analysis, Founding,
they benefit from economies of scale in this case. In the case of the item Conceptualization, Resources, Supervision, Writing U˝ Review &
others, it is constituted by four contributors: miscellaneous materials, Editing. Pastora Vega: Conceptualization, Founding, Project
utilities, laboratory, and supervision. The miscellaneous materials and Administration, Supervision,
Writing U˝ Review & Editing.
utilities cost are almost constant with the size; however, the laboratory
and supervision costs are obtained as a percentage of the labor cost, so
they decrease with the size and make the item other also decrease. Declaration of Competing Interest
Furthermore, it must be noted that the cost of the raw materials, sludge,
and MSW, has not been considered, because as they are residues, they The authors declare that they have no known competing financial
have been considered free. Considering only the section concerning the interests or personal relationships that could have appeared to influence
incineration of MSW, a price can be obtained for the electricity and put the work reported in this paper.
into perspective with other generation sources. This price is lower as the
higher electricity consumption, so the biggest WWTPs take advantage of Data availability
economies of scale. The highest price is obtained in Salamanca, 0.23
€/kWh, followed by La Corun˜a and Sevilla, with a price of 0.14 Data comes from open sources and is available in the cited
€/kWh references.
and 0.12 €/kWh, respectively, and, finally, the lowest electricity prices
are obtained in Madrid and Barcelona, 0.10 €/kWh and 0.08 €/kWh, Acknowledgments
respectively. These prices are nearly constant throughout the months, as
they minimally change because the operating cost also changes. This The authors acknowledge MICINN Spain grant PID2019-105434RB-
cost changes because the furnace is also used to produce the steam that C31 and Programa Investigo JCYL to Elena C. Blanco.
provides the thermal energy requirements to the WWTP, which are
different over the year, so the amount of MSW also changes changing the Appendix A. Supporting information
items of the cost depending on it. However, this price will increase if the
gas treatment section, which is not considered, is included in the pro- Supplementary data associated with this article can be found in the
cess. These prices are not far from the prices that present the two main online version at doi:10.1016/j.jece.2023.110673.
renewable sources, 0.05–0.1 €/kWh for solar PV panels and 0.1–0.15
€/kWh for wind turbines, especially in the largest WWTP. If compared to References
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