DHRUVA PUBLIC SR.SEC.

SCHOOL

Test / Exam Name: Test Standard: 12th Science Subject: Chemistry

Student Name: Section: Roll No.:
Questions: 37 Time: 180 Mins Marks: 70

Q1. Give the IUPAC names of the following compound: 1 Mark

CHF2CBrClF

Q2. Give IUPAC name of the following ether: 1 Mark

Q3. Arrange the compounds of each set in order of reactivity towards SN2 displacement: 1 Mark
1-Bromobutane, 1-Bromo-2,2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-3-methylbutane.

Q4. Give IUPAC name of the following ether: 1 Mark

C2 H5 OCH2 − CH − CH3

CH3

Q5. Give equation of the following reaction: 1 Mark

Dilute HNO3 with phenol.

Q6. Write structures of the following compounds: 1 Mark

4-tert. Butyl-3-iodoheptane.

Q7. Draw the structures of major monohalo products in each of the following reaction: 1 Mark

Q8. Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl 1 Mark
(primary, secondary, tertiary), vinyl or aryl halides:
CH3CH=CHC(Br)(CH3)2.

Q9. Given the standard electrode potentials, 1 Mark

K+/K = –2.93V, Ag+/Ag = 0.80V,
Hg2+/Hg = 0.79V
Mg2+/Mg = –2.37 V, Cr3+/Cr = –0.74V
Arrange these metals in their increasing order of reducing power.

Q10. Write structures of the products of the following reactions: 1 Mark

Q11. Which one of the following has the highest dipole moment? 1 Mark
1. CH2Cl2.
2. CHCl3.
3. CCl4.
Q12. How the following conversion can be carried out? 1 Mark
2-Chloropropane to 1-propanol.

Q13. Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular 1 Mark
masses. Explain this fact.

Q14. Suppose a solid solution is formed between two substances, one whose particles are very large and 1 Mark
the other whose particles are very small. What kind of solid solution is this likely to be?

Q15. Explain the following with an example. 1 Mark

Reimer-Tiemann reaction.

Q16. What is meant by positive and negative deviations from Raoult's law and how is the sign of ΔmixH 2 Marks
related to positive and negative deviations from Raoult's law?

Q17. The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had 2 Marks
only 80% of the 14C found in a living tree. Estimate the age of the sample.

Q18. If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would 2 Marks
flow through the wire?

Q19. A first order reaction takes 40 min for 30% decomposition. Calculate t1/2. 2 Marks

Q20. The resistance of a conductivity cell containing 0.001M KCl solution at 298 K is 1500 Ω. What is the cell 2 Marks
constant if conductivity of 0.001M KCl solution at 298 K is 0.146 × 10–3 S cm–1.

Q21. Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. Calculate 2 Marks
the solubility of methane in benzene at 298 K under 760 mm Hg.

Q22. How would you determine the standard electrode potential of the system Mg2+|Mg? 2 Marks

Q23. Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10. 2 Marks

Q24. The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. Calculate its molar conductivity. 2 Marks

Q25. State Henry’s law and mention some important applications? 2 Marks

Q26. Write the mechanism of hydration of ethene to yield ethanol. 2 Marks

Q27. Write the mechanism of the reaction of HI with methoxymethane. 2 Marks

Q28. Give the equations of reactions for the preparation of phenol from cumene. 2 Marks

Q29. Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the 3 Marks
corresponding phenoxide ions.

Q30. Give two reactions that show the acidic nature of phenol. Compare acidity of phenol with that of 3 Marks
ethanol.

Q31. Write the Nernst equation and emf of the following cells at 298 K: 3 Marks
Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)

Q32. An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. 3 Marks
Calculate the molality of the solution. If the density of the solution is 1.072 g mL–1, then what shall be
the molarity of the solution?
Q33. Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of
pure benzene and naphthalene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate 3 Marks
the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene.

Q34. Calculate the molarity of each of the following solutions: 3 Marks

1. 30 g of Co(NO3)2. 6H2O in 4.3 L of solution.
2. 30 mL of 0.5 M H2SO4 diluted to 500 mL.

Q35. Define the following term: 1 Mark

Mole fraction.

Q36. Primary alkyl halide C4H9Br (a) reacted with alcoholic KOH to give compound (b). Compound (b) is 5 Marks
reacted with HBr to give (c) which is an isomer of (a). When (a) is reacted with sodium metal it gives
compound (d), C8H18 which is different from the compound formed when n-butyl bromide is reacted
with sodium. Give the structural formula of (a) and write the equations for all the reactions.

Q37. Identify A, B, C, D, E, R and R1 in the following: 5 Marks