DPP No.

14
TARGET : JEE-2024 Max. Time : 45 Min.

DPP No. : 14 (JEE-ADVANCED)

1. In which options both compounds can show geometrical isomerism

Cl
(A) , N (B) , C2FClBrI
Cl Cl OH Br

(C) , Ph2N2 (D) CH3–CH=N–OH, H2C=CH–CH=CH–CN

Ans. (BD)

Me Cl
C=N C2FClBrI.
Sol. (A) Cl Cl Me OH (B) Br
yes no yes yes
:
:

Ph–N=N–Ph CH3
(C) (D) C=N CH2=CH–CH=CH–CN
no yes H OH
yes yes

2. Which of the following can not show geometrical isomerism?

Cl
Cl
OH OH
(A) (B) (C) (D)

OH
Br
Ans. (C)

3. For which of the following pairs of compounds are the CORRECT notations given.
Ph
Ph Ph N=N
(A) N=N Ph
anti azobenzene syn azobenzene

CH3 CH3 OH
C=N C=N
(B) H OH H
syn acetaldoxine anti acetaldoxine

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 H H
COOH H
C=C C=C
H COOH
(C) NH 2 NH2
Trans-o-aminocinnamic acid Cis-o-aminocinnamic acid

CH3 CH2–CH2–CH3 Cl–CH2 CH3

C=C C=C
(D) H CH3 Br–CH2 CH2CH3
Z-isomer E-isomer
Ans. (BC)

4. Which of the following compound has Z configuration?

O
NH2–C
CH=O
C=C C=C
(A) (B) Cl–C
COOH
O

H2N OCH3

CH3 C(CH 3)3

C=C OCH3
(C) (D)
H CH(CH3)2
NH2
Ans. (BCD)

5. The incorrect order with respect to the properties mentioned for the following pair of compounds is :

<
(A) (Stability)
Trans Cis
CH3 CH3 CH3 H
(B) C=C < C=C (Stability)
H H H CH3
CH3 Cl CH3 H
(C) C=C > C=C (Boiling point)
H H H Cl
CH3 Cl CH3 H
(D) C=C > C=C
H H H Cl
Ans. (CD)

Comprehension #
Observe the following compound :
CH3

CH3–CH=CH

OH

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6. The total number of its geometrical isomers is :
(A) 2 (B) 4 (C) 8 (D) 16
Ans. (B)
CH3

Sol. CH3–CH=CH

22 = 4 OH

7. Total number of multiple bonds which shows geometrical isomerism including multiple bond of phenyl
group.
(A) 3 (B) 2 (C) 1 (D) 4
Ans. (C)

8. Match the column-I with column-II :

Column I Column II

(A) Geometrical isomerism (p)

Cl

(B) Z-isomer (q)

Cl

(C) Cis-isomer (r)

CH3 CH3
(D) E-isomer (s)
H Br

Ans. (A)  (q, r, s); (B)  (q, r); (C)  (q, r, s); (D)  (s)

9. Geometrical isomerism is possible in how many of the following molecules/compounds.

NH Cl
Br
(1) (2) (3) (4)
NH

NH Me

(5) (6) (7) (8) MeS

NH

(9) (10)
Ans. 6 (2, 3, 4, 5, 6, 8)

10. Total number of position isomers of tetrachlorocyclobutane which can shows geometrical isomerism are:
Ans. 3
Cl Cl Cl
Cl Cl Cl Cl
Sol.
Cl Cl Cl Cl Cl

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