Njeets Full Test - 07

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FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2024)
CLASS – XII & XII PASS
FULL TEST - 7
QP CODE: 0000.0
CONDUCTION DATE: 04-01-2024
Time Allotted: 3 Hours Maximum Marks: 300
▪ Do not open this Test Booklet until you are asked to do so.
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide
rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks will be awarded for every correct answer and -1 mark will be
deducted for every incorrect answer.
(i) Part-C (01-05) contains Five (05) Numerical based questions with single digit integer as answer, ranging from 0 to 9
(both inclusive). Each question carries +4 marks will be awarded for every correct answer and NO MARKS will be
deducted for every incorrect answer.
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Useful Data Chemistry:

Gas Constant = 8.314 J K−1 mol−1
R
= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
2
Acceleration due to gravity g = 10 m / s

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Section – I (Physics)
PART – A
Single Correct Choice Type
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of
which ONLY ONE option is correct.
A 2B 3
Q1. If Z = , then the relative error in Z will be :
C4
A B C 2A 3B 4C
(A) + + (B) + −
A B C A B C
2A 3B 4C A B C
(C) + + (D) + −
A B C A B C
Q2. A is a vector quantity such that A = non-zero constant. Which of the following expression is true for A ?
(A) A . A = 0 (B) A  A  0
(C) A  A = 0 (D) A  A  0
Q3. Which one of the following relations is true for two unit vector Â and B̂ making an angle  to each other?
ˆ + Bˆ = Aˆ − Bˆ tan 
(A) A (B) Aˆ − Bˆ = Aˆ + Bˆ tan 
2 2
ˆ ˆ ˆ ˆ
(C) A + B = A − B cos  ˆ ˆ ˆ ˆ
(D) A − B = A + B cos 
2 2
Q4. If force F = 3iˆ + 4jˆ − 2kˆ acts on a particle having position vector 2iˆ + ˆj + 2kˆ then, the torque about the origin will
be :
(A) 3iˆ + 4jˆ − 2kˆ (B) −10iˆ + 10jˆ + 5kˆ
(C) 10iˆ + 5jˆ − 10kˆ (D) 10iˆ + ˆj − 5kˆ
Q5. The height of any point P above the surface of earth is equal to diameter of earth. The value of acceleration
due to gravity at point P will be : (Given g = acceleration due to gravity at the surface of earth).
(A) g/2 (B) g/4
(C) g/3 (D) g/9
Q6. The terminal velocity ( t ) of the spherical rain drop depends on the radius (r) of the spherical rain drop as :
(A) r1/2 (B) r
(C) r 2 (D) r 3
Q7. The relation between root mean square speed ( rms ) and most probable speed ( p ) for the molar mass M of
oxygen gas molecule at the temperature of 300 K will be :
2 3
(A) rms = p (B) rms = p
3 2
1
(C) rms = p (D) rms = p
3

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Q8. In the figure, a very large plane sheet of positive charge is shown. P1 and P2 are two points at distance and
2 from the charge distribution. If  is the surface charge density, then the magnitude of electric fields E 1 and
E 2 at P1 and P2 respectively are :
+
+
+ 2
+ E2
+ P2
+ +
+
+ +
+ +
+ +
+ E1
+
+ P1
+

+
(A) E1 =  / 0 , E2 =  / 20 (B) E1 = 2 / 0 , E2 =  / 0

(C) E1 = E2 =  / 20 (D) E1 = E2 =  / 0
Q9. Match List – I with List – II.

List – I List – II
(A) AC generator (I) Detects the presence of current in the circuit
(B) Galvanometer (II) Converts mechanical energy into electrical energy
(C) Transformer (III) Works on the principle of resonance in AC circuit
(D) Metal detector (IV) Changes an alternating voltage for smaller or greater value
Choose the correct answer from the options given below :
(A) (A) – (II), (B) – (I), (C) – (IV), (D) – (III) (B) (A) – (II), (B) – (I), (C) – (III), (D) – (IV)
(C) (A) – (III), (B) – (IV), (C) – (II), (D) – (I) (D) (A) – (III), (B) – (I), (C) – (II), (D) – (IV)
Q10. A long straight wire with a circular cross-section having radius R, is carrying a steady current I. The current I is
uniformly distributed across this cross-section. Then the variation of magnetic field due to current I with
distance r(r < R) from its centre will be :
(A) B  r 2 (B) B  r
1 1
(C) B  2 (D) B 
r r
Q11. If wattles current flows in the AC circuit, then the circuit is :

(A) Purely Resistive circuit (B) Purely Inductive circuit
(C) LCR series circuit (D) RC series circuit only
Q12. The electric field in an electromagnetic wave is given by E = 56.5 sin ( t − x / c ) NC−1 . Find the intensity of the
wave if it is propagating along x-axis in the free space.
(Given 0 = 8.85  10−12 C2N−1m−2 )
(A) 5.65 Wm −2 (B) 4.24 Wm −2
(C) 1.9  10 −7 Wm−2 (D) 56.5 Wm −2
Q13. The two light beams having intensities I and 9I interfere to produce a fringe pattern on a screen. The phase
difference between the beams is  / 2 at point P and  at point Q. Then the difference between the resultant
intensities at P and Q will be :
(A) 2 I (B) 6 I
(C) 5 I (D) 7 I

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Q14. A light wave travelling linearly in a medium of dielectric constant 4, incidents on the horizontal interface
separating medium with air. The angle of incidence for which the total intensity of incident wave will be
reflected back into the same medium will be :
(Given : relative permeability of medium r = 1)
(A) 100 (B) 200
(C) 300 (D) 600
Q15. A thin uniform rod of mass ‘m’ and length ‘’ is standing on a smooth horizontal surface.
A slight disturbance causes the lower end to slip on the smooth surface. The velocity of centre of mass of the
rod at the instant when it makes an angle 60° with vertical will be
9g g
(A) downward (B) , 30° with downward vertical
26 13
3g 3g
(C) horizontal (D) , 60° with downward vertical
26 13
Q16. The ratio for the speed of the electron in the 3rd orbit of He+ to the speed of the electron in the 3rd obit of
hydrogen atom will be :
(A) 1 : 1 (B) 1 : 2
(C) 4 : 1 (D) 2 : 1
Q17. The photodiode is used to detect the optical signals. These diodes are preferably operated in reverse biased
mode because :
(A) fractional change in majority carriers produce higher forward bias current
(B) fractional change in majority carriers produce higher reverse bias current
(C) fractional change in minority carriers produce higher forward bias current
(D) fractional change in minority carriers produce higher reverse bias current
Q18. An open pipe is suddenly closed at one end with the result that, the frequency of third harmonic of closed
pipe is found to be higher by 100 Hz than the fundament frequency of open pipe. The fundamental frequency
of open pipe is
(A) 200 Hz (B) 300 Hz
(C) 240 Hz (D) 480 Hz
Q19. The difference of speed of light in the two media A and B ( A − B ) is 2.6  107 m/s. If the refractive index of
medium B is 1.47, then the ratio of refractive index of medium B to medium A is : (Given : speed of light in
vacuum c = 3 x 108 ms-1)
(A) 1.303 (B) 1.318
(C) 1.13 (D) 0.12
Q20. A teacher in his physics laboratory allotted an experiment to determine the resistance (G) of a galvanometer.
1
Students took the observations for deflection in the galvanometer.
3
Which of the below is true for measuring value of G?
1
(A) deflection method cannot be used for determining the resistance of the
3
galvanometer.
1
(B) deflection method can be used and in this case the G equals to twice the value of
3
shunt resistance(s).
1
(C) deflection method can be used and in this case, the G equals to three times the
3
value of shunt resistance(s).
1
(D) deflection method can be used and in this case, the G value equals to the shunt
3
resistance(s).
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PART – C
Integer Type
Q1. A uniform chain of 6 m length is placed on a table such that a part of its length is hanging over the edge of the
table. The system is at rest. The co-efficient of static friction between the chain and the surface of the table is
0.5, the maximum length of the chain hanging from the table is……….. m.
Q2. The equivalent capacitance between points A and B in below shown figure will be……… F .
8 F 8 F
A B
8 F 8 F 8 F 8 F
Q3. The total current supplied to the circuit is shown in

figure by the 5 V battery is……….A.
5
5
5V 5
2.5 
Q4. The current in a coil of self inductance 2.0 H is increasing according to I = 2 sin t 2 A . The amount of energy ( )
spent during the period when current changes from 0 to 2 A is……….J.
Q5. ( )
A force on an object of mass 100 g is 10iˆ + 5ˆj N . The position of that object at t = 2 s is aiˆ + bjˆ m after ( )
a
starting from rest. The value of will be…….
b
space for rough work

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Section – II (Chemistry)
PART – A
1. The energies of activation for forward and reverse reactions for A 2 + B2 2AB are 180 kJ mol−1 and 200
kJ mol−1 respectively. The presence of catalyst lowers the activation energy of both (forward and reverse)
reactions by 100 kJ mol−1. The enthalpy change of the reaction ( A 2 + B2 ⎯⎯ → 2AB ) in the presence of
catalyst will be (in kJ mol−1)
(A) 300 (B) 120 (C) 280 (D) 20
2. The half life period of a first order chemical reaction is 6.93 minutes. The time required for the completion of
99% of the chemical reaction will be (log 2=0.301) :
(A) 230.3 minutes (B) 23.03 minutes (C) 46.06 minutes (D) 460.6 minutes
3. The exothermic formation of CIF3 is represented by the equation:

Cl2( g ) + 3F2( g ) 2ClF3( g ) : rH = −329 kJ
which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2 , F2 and ClF3 ?
(A) Increasing the temperature (B) Removing Cl2
(C) Increasing the volume of the container (D) Adding F2
4. The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the
acid is ionized is
(A) 4.5 (B) 2.5 (C) 9.5 (D) 7.0
5. In which of the following arrangements the order is NOT according to the property indicated against it?
(A) Al 3+  Mg 2+  Na +  F − increasing ionic size
(B) B  C  N  O increasing ionization energy
(C) I  Br  F  Cl increasing electron gain enthalpy
(D) Li  Na  K  Rb increasing size
6. The set representing the correct order of ionic radius is :

(A) Li+  Be2 +  Na+  Mg2 + (B) Na+  Li+  Mg2 +  Be2 +
(C) Li+  Na+  Mg2 +  Be2 + (D) Mg2 +  Be2+  Li+  Na+
7. The molecular shapes of SF4 , CF4 and XeF4 are

(A) the same with 2,0 and 1 lone pairs of electrons on the central atom, respectively
(B) the same with 1, 1 and 1 lone pair of electrons on the central atoms, respectively
(C) different with 0, 1 and 2 lone pair of electrons on the central atoms, respectively
(D) different with 1, 0 and 2 lone pairs of electron on the central atoms respectively
8. The frequency of light emitted for the transition n = 4 to n = 2 of He + is equal to the transition in H atom
corresponding to which of the following?
(A) n = 4 to n = 3 (B) n = 3 to n = 1 (C) n = 2 to n = 1 (D) n = 3 to n = 2

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9. Which of the following molecules is expected to rotate the plane of plane polarized light?
CHO
(A) HO H (B)
SH
CH2OH
COOH
H2N NH2
(C) H H (D) H2N H
Ph Ph
H
10. For which of the following molecule significant   0?

Cl CN OH SH
(a) (b) (c) (d)
Cl CN OH SH
(A) Only (c) (B) (c) and (d) (C) Only (a) (D) (a) and (b)
11. Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so
obtained is diazotised and then heated with cuprous bromide. The reaction mixture so formed contains
(A) mixture of o− and p−bromotoluene (B) mixture of o− and p−dibromobenzene
(C) mixture of o− and p−bromoaniline (D) mixture of o− and m−bromotoluene
12. The hydrocarbon which can react with sodium in liquid ammonia is
(A) CH3CH2CH2CCCH2CH2CH3 (B) CH3CH2CCH
(C) CH3CH=CHCH3 (D) CH3CH2CCCH2CH3
13. Compound (A), C8H9Br, gives a pale yellow precipitate when warmed with alcoholic AgNO 3. Oxidation of (A)
gives a acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A).
CH2 Br
CH2 Br
C2H5 CH2 Br
(A) (B) (C) (D)

Br CH3
CH3
CH3
14. In the following sequence of reactions,

P +I2
CH3CH2OH ⎯⎯⎯ → A ⎯⎯⎯
Mg
ether
→B ⎯⎯⎯
HCHO
→C ⎯⎯⎯
H2O
→D
the compound ‘D’ is
(A) butanal (B) n-butyl alcohol (C) n-propyl alcohol (D) propanal

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15. Sodium phenoxide when heated with CO2 under pressure at 125C yields a product which on acetylation
produces C.
ONa
+
+CO2 ⎯⎯⎯ → B ⎯⎯⎯ →C
c
125 H
5 Atm Ac2 O
The major product C would be:

OH
OH OCOCH3 OCOCH3 COCH3
COOCH3 COOH
(A) (B) (C) (D)
COOH
COCH3
16. An amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain temperature and
0.50 atm. Pressure. Ammonium hydrogen sulphide decomposes to yield NH 3 and H2S gases in the flask.
When the decomposition reaction reaches equilibrium, the total pressure in the flask rises to 0.84 atm. The
equilibrium constant for NH4HS decomposition at this temperature is
(A) 0.30 (B) 0.18 (C) 0.17 (D) 0.11
17. The lanthanide contraction is responsible for the fact that

(A) Zr and Y have about the same radius (B) Zr and Nb have similar oxidation state
(C) Zr and Hf have about the same radius (D) Zr and Zn have the same oxidation
18. The actinoids exhibits more number of oxidation states in general than the lanthanoids. This is because
(A) the 5f orbitals are more buried than the 4f orbitals
(B) there is a similarity between 4f and 5f orbitals in their angular part of the wave function
(C) the actinoids are more reactive than the lanthanoids
(D) the 5f orbitals extend further from the nucleus than the 4f orbitals
19. The molecules having smallest bond angle is

(A) NCl3 (B) AsCl3 (C) SbCl3 (D) PCl3
20. In Fe ( CO )5 , the Fe – C bond possesses

(A)  − character only (B) both  and  characters
(C) ionic character (D)  -character only
PART – C
Numerical Based Type
1. The following mechanism has been proposed for the reaction of NO with Br 2 to form NOBr:
NO ( g ) + Br2 ( g ) NOBr2 ( g ) ; NOBr2 ( g ) + NO ( g ) → 2 NOBr ( g )
If the second step is the rate determining step, the order of the reaction with respect to NO ( g ) is
2. The “spin-only” magnetic moment [in units of Bohr magnetion, ( B ) ] of Ni 2 + in aqueous solution would be
approximately (nearest integer) (Atomic number of Ni = 28)
3. The number of hydrogen atom(s) attached to phosphorus atom in hypophosphorous acid is
+
4. The oxidation state of Cr in Cr ( NH 3 )4 Cl2  is

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5. The Gibbs energy for the decomposition of Al2O3 at 500C is as follows:

2 4
Al2O3 → Al + O2, rG = + 966 kJ mol–1
3 3
The potential difference needed for electrolytic reduction of Al2O3 at 500C is x. The value of 2x is
pace for rough work

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Section – III (Mathematics)

PART – A
12 22 32 42
Q1. Sum of the series + + + + ........... (infinite terms) is
1! 2! 3! 4!
(A) e (B) 2e
(C) e2 (D) 
Q2. ( )(
The sum of all the real roots of the equation e2x − 4 6e2x − 5e x + 1 = 0 is )
(A) loge 3 (B) − loge 3
(C) loge 6 (D) − loge 6
ex e− x
Q3. Let I =  dx , J =  e−4 x + e−2 x + 1 dx then the value of J − I equals
e4 x + e2 x + 1
1  e4 x − e2 x + 1  1  e2 x + e x + 1 
(A) log  4 x  + c (B) log  2x +c
 e + e +1  e − e +1
2x x
2 2
1  e2 x − e x + 1  1  e4 x + e2 x + 1 
(C) log  2 x +c (D) log  4 x +c
 e + e +1  e − e +1
x 2x
2 2
Q4. Let x,y  0 . If x 3 y 2 = 215 , then the least value of 3x + 2y is

(A) 30 (B) 32
(C) 36 (D) 40
(
 sin x −  x 

)
, x  ( −2, − 1)
 x −  x 

Q5. 
Let f ( x ) = max 2x, 3  x  , 
x 1

 1 , otherwise


where [t] denotes greatest integer  t . If m is the number of points where f is not continuous and n is the
number of points where f is not differentiable, then the ordered pair (m, n) is:
(A) (3, 3) (B) (2, 4)
(C) (2, 3) (D) (3, 4)
Q6. The value of the integral

/ 2
dx
 (1 + e )( sin
− / 2
x 6
x + cos6 x )
is equal to
(A) 2 (B) 0

(C)  (D)
2

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 n2 n2 n2 n2 
Q7. lim  2 + 2 + 2 + .... + 2  is equal to
(
x → 
 ) ( )
n + 1 (n + 1) n + 4 (n + 2 ) n + 9 (n + 3 ) ( )
n + n2 (n + n ) 
 ( )
 1  1
(A) + loge 2 (B) + loge 2
8 4 4 8
 1 
(C) − loge 2 (D) + loge 2
4 8 8
Q8. A particle is moving in the xy-plane along a curve C passing through the point (3, 3). The tangent to the
curve C at the point P meets the x-axis at Q. If the y-axis bisects the segment PQ, then C is a parabola with
(A) length of latus rectum 3 (B) length of latus rectum 6
 4   3
(C) focus  ,0  (D) focus  0, 
3   4
x2 y2
Q9. Let the maximum area of the triangle that can be inscribed in the ellipse + = 1, a  2 , having one of its
a2 4
vertices at one end of the major axis of the ellipse and one of its sides parallel to the y-axis, be 6 3 . Then
the eccentricity of the ellipse is :
3 1
(A) (B)
2 2
1 3
(C) (D)
2 4
Q10. Let the area of the triangle with vertices A (1,  ) , B ( ,0) , C ( 0,  ) be 4 sq. units. If the points ( , −) ,
( −, ) and (  , ) are collinear, then
2
 is equal to
(A) 64 (B) -8
(C) -64 (D) 512
Q11. The number of distinct real roots of the equation x7 − 7x − 2 = 0 is

(A) 5 (B) 7
(C) 1 (D) 3
Q12. Number of points of discontinuity of f(x) = [2x2 – 5] in [1, 2), is equal to

(where [x] denotes the greatest integer less than or equal to x)
(A) 14 (B) 13 (C) 10 (D) 8
Q13. The number of solutions of the equation

    1
cos  x +  cos  − x  = cos2 2x, x  −3, 3 is :
 3   3  4
(A) 8 (B) 5
(C) 6 (D) 7
x −1 y − 2 z − 3 x−2 y−4 z−5 1

Q14. If the shortest distance between the lines = = and = = is , then the
2 3  1 4 5 3
sum of all possible values of  is :
(A) 16 (B) 6
(C) 12 (D) 15

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Q15. Let the points on the plane P be equidistance from the points ( −4, 2, 1) and ( 2, −2,3) . Then the acute angle
between the plane P and the plane 2x + y + 3z = 1 is
 
(A) (B)
6 4
 5
(C) (D)
3 12
Q16. Let â and b̂ be two unit vectors such that (aˆ + bˆ ) + 2 (aˆ  bˆ ) = 2 . If   (0, ) is the angle between â and b̂ ,
then among the statements :
(S1) : 2 aˆ  bˆ = aˆ − bˆ
(
(S2) : The projection of â on â + bˆ is
1
2
)
(A) Only (S1) is true. (B) Only (S2) is true.
(C) Both (S1) and (S2) are true. (D) Both (S1) and (S2) are false.
 3
Q17. (
If y = tan−1 sec x 3 − tan x 3 , ) 2
 x3 
2
, then
3
(A) xy "+ 2y ' = 0 (B) x2 y "− 6y + =0
2
(C) x 2 y "− 6y + 3 = 0 (D) xy "− 4y ' = 0
Q18. Consider the following statements :

A : Rishi is a judge.
B : Rishi is honest.
C : Rishi is not arrogant.
The negation of the statement “if Rishi is a judge and he is not arrogant, then he is honest” is
(A) B → ( A  C) (B) ( ~ B)  ( A  C)
(
(C) B → ( ~ A )  ( ~ C ) ) (D) B → ( A  C)
x2
Q19. The slope of normal at any point ( x,y ),x  0, y  0 on the curve y = y ( x ) is given by . If the
xy − x2 y2 − 1
curve passes through the point (1, 1), then e.y ( e ) is equal to
1 − tan (1)
(A) (B) tan (1)
1 + tan (1)
1 + tan (1)
(C) 1 (D)
1 − tan (1)
Q20. Let   be the largest value of  for which the function f ( x ) = 4x3 − 36x2 + 36x + 48 is increasing for all
x  R . Then f (1) + f ( −1) is equal to :
(A) 36 (B) 48
(C) 64 (D) 72

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -14
PART – C
Integer Type
Q1. Let S = z  C : z − 3  1and z ( 4 + 3i ) + z ( 4 − 3i )  24 . If  + i is the point in S which is closest to 4i, then
5
(  + ) is equal to………
4
Q2. The remainder on dividing 1 + 3 + 32 + 33 + .... + 32021 by 50 is………..
Q3. The area (in sq. units) of the region enclosed between the parabola y 2 = 2x and the line x + y = 4 is 6A ,
then A is
Q4. If the circle x2 + y2 + 4x +22y + l = 0 bisects the circumference of the circle x 2 + y2 – 2x + 8y – m = 0, then l +
m is  number, then  +  is
x2
Q5. Let the hyperbola H : − y 2 = 1 and the ellipse E : 3x 2 + 4y 2 = 12 be such that the length of latus rectum of
a2
H is equal to the length of latus rectum of E. If eH and eE are the eccentricities of H and E respectively, then
( )
the value of 2 eH2 + eE2 is equal to………
space for rough work

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -15
FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2024)
CLASS - XII
FULL TEST - 7
Q.P.CODE: 0000.0
CONDUCTION DATE: 04-01-2024
ANSWERS
PART – A
1. C 2. C 3. B 4. B
5. D 6. C 7. B 8. C
9. A 10. B 11. B 12. B
13. B 14. D 15. A 16. D
17. D 18. A 19. C 20. B
PART – C
1. 2 2. 6 3. 2 4. 4
5. 2
PART – A
1. D 2. C 3. D 4. C
5. B 6. B 7. D 8. C
9. A 10. B 11. A 12. B
13. C 14. C 15. C 16. D
17. C 18. D 19. C 20. B
PART – C
1. 2 2. 3 3. 2 4. 3
5. 5
PART - A
1. B 2. B 3. C 4. D
5. C 6. C 7. A 8. A
9. A 10. C 11. D 12. B
13. D 14. A 15. C 16. C
17. B 18. B 19. D 20. D
PART – C
1. 4 2. 4 3. 3 4. 5
5. 7

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -16

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NJEETS-2024 - FT - 7 -PCM -17
HINTS & SOLUTIONS

PART - A
A 2 B3
Sol1. z=
C4
The relative error in z is given by
z 2A 3B 4C
= + +
z A B C
Sol2. A  A = A Asin  nˆ
= A A sin0 nˆ
=0 [Since Angle between the vectors are zero degree]
AA = 0
Sol3. ˆ +B
A ˆ = A2 + B2 + 2ABcos 
= 1 + 1 + 2cos  B̂
 Â
= 2 (1 + cos  ) Â −
− B̂
= 2  2cos2 
2
Aˆ + Bˆ = 2cos  − (1)
2
ˆ −B
A ˆ = A2 + B2 − 2ABcos 
= 1 + 1 − 2cos 
= 2 (1 − cos  )
= 2  2sin2 
2
= 2 sin  − ( 2)
2
( 2)  (1)
Aˆ − Bˆ 2sin 
= 2
Aˆ + Bˆ 2cos 
2
 Aˆ − Bˆ = Aˆ + Bˆ tan 
2
Sol4. r = 2 î + ˆj + 2kˆ
F = 3 î + 4jˆ − 2kˆ
 = r F
( ) (
= 2iˆ + ˆj + 2kˆ  3iˆ + 4ˆj − 2kˆ )
î − ˆj kˆ
2 1 2
3 4 −2
= î ( −2 − 8 ) − ˆj ( −4 − 6 ) + kˆ (8 − 3 )
 = −10 î + 10 ˆj + 5kˆ

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -18
GM
Sol5. g1 =
(R + h )
2
GM / R2
g1 = 2
 h
1 + R 
 
g
g1 = 2
 h
1 + R 
 
Given h = D = 2R
g
g1 = 2
 2R 
 +
R 
1

g
g1 =
9
Sol6. Let, Rain drop moving with terminal Fb

velocity v t in the air Fb (Bnoyancy force) Fv
4 3
= r air g
3
4
mg =  r 3 air g
3
Fv = ( viscons force) = 6 r vT air
Fb + Fv = mg
mg
4 4
 r 3 air g + 6 r v T = r 3  g
3 3
4 3
r (  − air )
vT = 3
6r
2 r2
vT = (  − air )
9 
vT  r 2
3RT
Sol7. Vrms =
M
2RT
& vP =
M
v rms 3
=
vP 2
v rms = 3 vP
2
Sol8. (Independent of distance) 2

 P2 E2
E1 = E 2 = P1
20
 Independent
E1 = of distance
2 0

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -19
Sol9. Based on theory
Sol10. for  R2 Area → ‘ I ’ current Direction of current

I
1 unit Area →
 R2
I
r 2 →  r2
 R2
I r2
i=
R2
Now, consider Amperian loop of radius small B
‘r’ In Amperian loop magnetic field will be
r
tangential to the amperian loop.
 B  d i = 0 Ienclosed (Ampere circuital law) R
B
I r2
B  2r = 0 2
R
0 I
B= r
2 R2
Br
Sol11. Purely inductive circuit


=
2

cos = 0
2
Average power = 0
( (
Sol12. E = 56  5 sin w t − x
c ))N / c
E0 = 56  5
0 = 8  85  10 −12
C = 3  108
1
I = 0 E02 C
2
1
=  8  85  10−12  ( 56.5 )  3  108
2
2
= 42377.11 10−4
I = 4.24 wm −2
Sol13. Given, I1 = I
I2 = 9I

case1  =
2
IP = I1 + I2 + 2 I1 I2 cos 

= I + 9 I + 2 I 9I cos
2
= 10 I
case 2  = 
IQ = I1 + I2 + 2 I1 I2 cos 
Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -20
= I + 9I + 2 I 9Icos 
= 10 I − 6I
IQ = 4I
IP 10 I
=
IQ2 4I
IP − IQ = 10 I − 4I = 6I
Sol14. Velocity of light in medium 2

1
=
m m Medium 1
1 1
v2 = 2
0 r 0 r Medium 2 r = 1
c
1 r = 4
=
1 0 0 4
1
v2 =
2 0 0
C
v2 =
2
C C
2 = = 2 = 2
v2 C
By snell’s law for total internal Reflection
 2 sin C  1 sin90
2sin C  1
1
sin C 
2
C  30
1  m 2 m3 2  2
Sol15.  +   = mg (1 − cos 60 )
o
2  12 16  2 60°
sin 60o
24 g 2
 = ICR
13
3 9g
V=  =
2
2 2 26
z
Sol16. v 
n
z
v =k [ K → constant
n
for 3rd orbit of He+
k  2 2k
vHe+ = = − (1)
3 3
k 1 k
vH = = − ( 2)
3 3
vHe+
= 2 :1
vH

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -21
Sol17. Very small change in minority charge carriers produces high value of reverse bias current.
Sol18. Initial
1
V0 = XV
21
For closed pipe
3
VC = V
4l
VC = V0 + 100
3V
 = V0 + 100
41
3 V 
   = V0 + 100
2  2l 
3
 V0 = V0 + 100
2
V0 − 200
C
Sol19. B =
vB
3  108
vB = = 20.408  107
1 47
v A − v B = 2  6  107
3  108
vA − = 2  6  107
1 47
3
v A = 2  6  107 =  108
1 47
v A = 2  6  107 + 20  408  107 = 23  107
C C
B = & A =
vB vA
B v A 23  107
= =
A vB 20  408  107
= 1 127
 1 13
Sol20. In galvanometer G
I Ig
(
 I − Ig S = IgG)
Ig S
=
I S+G
1 S
 =  S + G = 3S  G = 2S
3 S+G
S
PART – C

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -22
Sol1. L- x
F.B.D of hanging length
F.B.D of chain lying on the table.

f = T = N
x
  xg =  (L − x ) g
 x =  (L − x )
x = 0.5 ( 6 − x )
 x = 3 − 0.5x
1.5x = 3 T
30
x=
15 T = xg
x = 2m
xg
T
f
 (L − x ) g
24  8
Sol2. ceq = = 6F 1 1 2
32 A B
2 8F 8F 8F 8F 8F
8F
8F
8F
8F
8F
A 1 8F 2 8F B

8F
8F
A 8F 8F 1B

A 8F B
24F

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -23
Sol3.  Re q = 2.5  2 2
v 5
I= = = 2A 5 5
Re q 2.5
5v 5
2.5 
2
=
5
2 1
5
2.5 
5
3
5v
Sol4. Given, L = 2H
I = 2sin ( t 2 )
2
L 2 2 L
u =  Lidi = i  =  4 − 0
0 2  0 2
2
u=  4 = 4J
2
Sol5. F = 10 î + 5 ˆj
10 ˆ 5 ˆ
a= i+ j
m m
10 ˆ 5 ˆ
= i+ j
0.1kg 0.1
a = 100 î + 50 ˆj
a x = 100, a y = 50
1
Sx = ut + at 2
2
1
= 0  2 +  100  2  2
2
Sx = 200m
1
S y = uy t + a y t 2
2
1
= 0  2 +  50  2  2
2
= 100m
S = S î + S ˆj
x y
= 200 î + 100 ˆj
= aiˆ + bjˆ
a 200
= =2
b 100

NJEETS-2024 - FT - 7 -PCM -24
Rankers Academy JEE
PART – A
1. D
Sol. In absence of catalyst
180
Potential energy
80 100
In presence 200
of catalyst
Reaction coordinate
So, HReaction = Ef − Eb
= 80 – 100 = -20
Hence, (D) is correct.
2. C
0.6932 0.6932
Sol. = = min−1
t1/ 2 6.93
Also t =
2.303 Ao 
log
 A
 Ao  = initial concentration (amount)
 A  = final concentration (amount)
2.303  6.93 100
t= log
0.6932 1
= 46.06 minutes
3. D
Sol. Favourable condition for forward reaction according to Le Chateliers principle is increase in concentration of
reactant i.e. F2
4. C
Sol. For buffer solution
Salt 
pH = pKa + log 
 Acid
Salt 
= 4.5 + log 
 Acid
as HA is 50% ionized so [Salt] = [Acid]
pH = 4.5
pH + pOH = 14
 pOH = 14 – 4.5 = 9.5
Hence (C) is correct.
5. B
Sol. IE1 of N is greater than IE1 of O due to half-filled stable configuration in N.
6. B
Sol. Follow the periodic trends
7. D
Sol. SF4 has sp3d hybridization with lone pair, CF4 has sp3 hybridization with no lone pair and XeF4 has sp3d2
hybridization with two lone pairs.
8. C
Sol. For He+

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -25
  1 1 
= R H  ( 4)  2 − 2 
c 2 4 
For H
  1 1 
= R H  (1)  2 − 2 
c  n1 n 2 
On substituting, n1 = 1; n2 = 2 the equation is satisfied.
Hence, (C) is the correct answer.
9. A
Sol. The plane of polarized light is rotated by optically active compound, i.e. it should be chiral.
So, (A) has, chiral C-atom. So, it is optically active.
In (B), (C) and (D) plane of symmetry is present.
Hence, (A) is correct.
10. B
Sol.
H H
O S
O S
H H
Due to infinite possible conformations in the above cases (of which only one has zero ); a weighted  will
finally exist.
11. A

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -26
CH3 CH3 CH3

NO2
⎯⎯⎯⎯
Nitration
→ +
NO2
Sn/HCl
Sn/HCl
CH3
CH3
NH2
NH2
NaNO2/HCl
NaNO2/HCl
CH3
CH3
N2 Cl
CuBr N2 Cl
CuBr
CH3
Br
CH3
Br
12. B

Sol. CH3 CH2 − C  CH ⎯⎯⎯⎯⎯Na / Liq.NH3

→ CH3 CH2C  CNa 
It is a terminal alkyne, having acidic hydrogen.
Note: Solve it as a case of terminal alkynes, otherwise all alkynes react with Na in liq. NH 3.
13. C
Sol. +
CH2Br CH2
3( )
AgNO alc.
+ AgBr 
⎯⎯⎯⎯⎯ →
CH3 ( pale yellow )
(A) CH3
O
[O] COOH

⎯⎯⎯
−H O
→ O
2
COOH
(B) O
pthalic anhydride
14. C
P +I2
CH3 CH2OH ⎯⎯⎯ → CH3 CH2I ⎯⎯⎯⎯Mg
dry ether
→ CH3CH2MgI
Sol.
(A) (B )
H− C = O
→ CH3 CH2 CH2 OH + Mg ( OH) I

|
⎯⎯⎯⎯
H
→ CH3 − CH2 − CH2 OMgI ⎯⎯⎯
HO 2
(C) (D )
Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -27
 the compound D is n-propyl alcohol.

Hence, (C) is correct option.
15. C
Sol.
ONa OH OH OCOCH3
H3O+ ⎯⎯⎯→
Ac2O
⎯⎯⎯⎯⎯CO2
→ ⎯⎯⎯→
1250 C, 5atm
COO− Na + COOH COOH

(Aspirin)
16. D
NH 4 HS ( s ) NH 3 ( g ) + H 2 S ( g )
Sol. Initially 0.5atm 0 atm
At eq. 0.5+x atm x atm
 0.5 + x + x = 2x + 0.5 = 0.84

 x = 0.17atm
PNH3 = 0.5 + 0.17 = 0.67 atm
PH2 S = 0.17 atm
K = PNH3 PH2 S = 0.67  0.17 = 0.11 atm2
17. C
Sol. Due to Lanthanide contraction.
18. D
Sol. The actinoids exhibit more number of oxidation states in general than the lanthanoids. This is because the 5f
orbitals extend further from the nucleus than the 4f orbitals.
Hence, (D) is correct.
19. C
Sol. As the size of central atom increases lone pair repulsions increases so, bond angle decreases
20. B
Sol. Conceptual
PART – C
1. 2
Sol. Rate law equation = K  NOBr2  NO
KC =
 NOBr2 
 NO  Br2 
 NOBr2  = kc  NO Br2 
Rate law equation = K .KC  NO   Br2 
2
Hence order is 2 w.r.t. NO.

2. 3
Sol. Ni2+ = [18] 3d8
 Number of unpaired electrons is 2

 = n ( n + 2 ) = 2 ( 2 + 2 ) = 8 = 2.81M
3. 2
Sol.
O
HO P H
H
4. 3
Sol. x + 4  0 + 2 ( −1) = 1
5. 5
Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -28
−G
Sol. G = – nFE  E =
nF
966  103
E = −
4  96500
= –2.5 V
 The potential difference needed for the reduction x = 2.5 V
 2x = 22.5 = 5 volt

PART - A

n 2 
n 
( n − 1) + 1 = e + e = 2e
Sol1.  n! =  ( n − 1)! =  ( n − 1)!
n =1 n =1 n =1
Sol2. e2x − 4 = 0 or 6e2x − 5ex + 1 = 0

 1  1
 x = n2 x = n  , n  
3 2
= − n3, − n2
e3 x ex  e2 x − 1  x
Sol3. J −I = − dx =   e4 x + e2 x + 1  e dx
1 + e2 x + e4 x e4 x + e2 x + 1
Let e x = t
 1
t2 −1 1 − 2  dt
dt =  
t 
J −I = 4 2
t + t +1  1
2
 t +  −1
 t
Sol4. x1y  0 and x 3 y 2 = 215

AM  GM
3x + 2y 1
5
 x3 y2 ( ) 5
 3x + 2y  40
 sin ( x + 2 )
 , x  ( −2, − 1)
 x + 2 , x  ( −1, 0 
Sol5. f (x) =  0 
 2x
, x  ( 0, 1)
 , otherwise
 1
f (0 − h) − f (0 )
LHD = Lt =0
h →0 −h
f ( 0 + h) − f ( 0 )
RHD = Lt =2
h →0 h
Hence f ( x ) is not differentiable at x = −1, 0, 1
 m = 2, n = 3

NJEETS-2024 - FT - 7 -PCM -29
Rankers Academy JEE

2
dx
Sol6. I=  (1 + e )( sin

x 6
x + cos6 x )
………….(i)
−
2

2
ex dx
I=  (1 + e )( cos

x 6
x + sin6 x )
……….(i)
−
2
 
2
(1 + e ) dx x 2
4 sec 2x dx 2
2I =  (1 + e

x 6
= 2
)(cos x + sin x ) ( 4 + tan 2x )
6
0
2
−
2

2
sec 2 2x dx dt
 I = 4 put tan2x = t sec 2 2x dx =
6 4 + tan 2x
2
2
 
dt   t 
= 2 = 2  tan−1    = 
0 4+t 2
  2  0
n
n2
Sol7. S = Lt 
n →
r =1 (n 2
)
+ r 2 (n + r )
 1 x −1 
1 1
dx
= (
0
2
= 
)
−
1 + x (1 + x ) 0  1 + x 1 + x
2  dx

 1
+ n2
8 4
Equation of tangent at P ( x, y ) is Y − y =
dy
Sol8. ( X − x)
dx
dx dy dx
A/q, 2x − y =02 =
dy y x
 2 ny = nx + nc
y 2 = xc
It passes through (3, 3), c = 3
 y 2 = 3x  Length of latus rectum = 3
x2 y2 (acos , 2sin )
Sol9. + =1
a2 4
1
  =  a (1 + cos  )  4sin 
2 (a, 0)
2a (1+ cos ) sin 
d 1
 = 0,  cos  = −1,
d 2

max =6 3 a= 4
3
e =
2
1  1
1
Sol10.  = 4   0 1 = 4
2
0  1
  = 8
NJEETS-2024 - FT - 7 -PCM -30
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(, − ), ( −, ) ( )
and  2 ,  are collinear,
 − 1
 −  1 = 0   = −64
2  1
Sol11. f ( x ) = x7 − 7x − 2
f ' ( x ) = 7x6 − 7  f ' ( x ) = 0, x = 1
 f (1) =  0 and f ( −1)  0
Hence number of real roots of f ( x ) = 0 are 3.
Sol12. –3  2x3 – 5 < 11 as x  [1, 2)

Discontinuous at x = –2, –1, 0, ......, 10
    1
Sol13. cos  x +  cos  − x  = cos2 2x
 3   3  4
 1
 cos2 x − sin2 = cos2 2x
3 4
3
 4cos x − 4  = cos2 2x
2
4
 2 (1+ cos2x ) − 3 = cos2 2x
 cos2 2x − 2cos2x + 1 = 0  cos2x = 1
x = −3, − 2, − , 0, , 2, 3
 total number of solution = 7.
1
Sol14. S.D. =
3
î ˆj kˆ
b1  b2 = 2 3  = î (15 − 4 ) + ˆj (  − 10 ) + kˆ ( 5 )
1 4 5
( −î − 2jˆ − 2kˆ )  (15 − 4 ) î + ( − 10) ˆj + 5kˆ = 1

(15 − 4 ) + (  − 10 )
2 2
+ 25 3
  = 16
Sol15. Let P ( x,y,z ) be any point on plane P1 then

( x + 4) + ( y − 2) + ( z − 1) = ( x − 2) + ( y + 2) + ( z − 3 )
2 2 2 2 2 2
 3x − 2y + z + 1 = 0 ………(i)
and 2x + y + 3z − 1 = 0 ……….(ii)
6−2+3 
 cos  = =
14 3
Sol16. ( )
a + b + 2 a  b = 2,   ( 0,  )
2
squaring on both sides, we get  =
3
where  is angle between â and b̂ .
Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -31
2 aˆ  bˆ = 3 = aˆ − bˆ , S1 is correct.
and projection of â on â + bˆ =
(
aˆ  aˆ + bˆ ) =1
â + bˆ 2
so (S2) is correct.
   3 
Sol17. Let x3 =    ,
2  4 4 
 y = tan−1 ( sec  − tan )
 1 − sin  
= tan−1  
 cos  
   x3
y = −  y = −
4 2 4 2
dy −3x 2 d2 y
 =  2 = −3x
dx 2 dx
d2
y 3  3
 x 2 2 − 6y + = 0  x 2 y11 − 6y + =0
dx 2 2
Sol18. given statement is

( A  C) → B then its negation is ( A  C) → B
or ~ − ( A  C)  B  ( A  C)  ( ~ B ) or ( ~ B )  ( A  C )
dx x2
Sol19. − =
dy xy − x2 y2 − 1
dy xy − x 2 y 2 − 1
 =
dx x2
dy dv
Let xy = v  x +y=
dx dx

dv
−y =
(
v2 − v + 1 y )
dx v
dv
=
(
v2 − v + 1+ v y

)vdv v
= ydx = dx
dx v 1+ v 2
x
dv dx
 =  tan−1 v = nx + c
1+ v2 x

 tan−1 ( xy ) = nx +
4

Put x = 1, y = 1  tan−1 = c  c =
4

 tan−1 ( xy ) = nx +
4
 
xy = tan  nx + 
 4
   tan1 + 1
( )
e y ( e ) = tan 1 +  =
 4  1 − tan1
Sol20. f ( x ) = 4x3 − 36x2 + 36x + 48

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -32
(
f' ( x ) = 12 x 2 − 6x + 3 )
For increasing f' ( x )  0
x2 − 6x + 3  0  D  0
 1
362 − 12  0    0, 
 3
1
 =
3
4
f ( x ) = x3 − 12x 2 + 36x + 48
3
1 1
 f (1) + f ( −1) = 73 − 1 = 72
2 2
PART – C
Circle  z − 3  1  ( x − 3) + y  1
2 2
Sol1.
and line z ( 4 + 3i ) + z ( 4 − 3i )  24
4
 4 x − 3 y  12  slope = tan  =
3
12 4
 + i  = + i
5 5
25 ( +  ) = 80
Sol2. S = 1 + 3 + 32 + 33 + .... + 32021
32022 − 1 1 1011
= =  a − 1
2 2
1 1
= 91011 − 1 = 100k + 10110 − 1 − 1
2 2
= 50k1 + 4
Remainder = 4
Sol3. Required area
2  y2 
=   4 − y −  dy
−4
 2 
2
 y 2 y3 
=  4y − −  = 18 sq units.
 2 6 −4
Sol4. The common chord of the given circles is
6x + 14 y + l +m = 0 (1)
Since x2 + y2 +4x + 22 y + l =0 biscets the circumference of the circle
x2 +y2 – 2x + 8y – m = 0, (1) paases through the centre of the second circle i.e. ( 1, -4) .
Therefore, 6 – 56 + l + m = 0  l + m = 50 .
x2 y 2
Sol5. − =1
a2 1
2
Length of latus rectum =
a
x2 y 2
and + =1
4 3

Rankers Academy JEE
NJEETS-2024 - FT - 7 -PCM -33
6
length of latus rectum = =3
2
2 2
= 3 a =
a 3
 9   3   13 1 
12 ( eH2 + eH2 ) = 12 1 +  + 1 −   = 12  + 
 4   4   4 4
14
= 12  = 42
4


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B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

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Useful Data Chemistry:

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(A) E1 =  / 0 , E2 =  / 20 (B) E1 = 2 / 0 , E2 =  / 0

Q9. Match List – I with List – II.

Q11. If wattles current flows in the AC circuit, then the circuit is :

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Q3. The total current supplied to the circuit is shown in

space for rough work

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3. The exothermic formation of CIF3 is represented by the equation:

6. The set representing the correct order of ionic radius is :

7. The molecular shapes of SF4 , CF4 and XeF4 are

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10. For which of the following molecule significant   0?

(a) (b) (c) (d)

(A) (B) (C) (D)

14. In the following sequence of reactions,

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The major product C would be:

17. The lanthanide contraction is responsible for the fact that

19. The molecules having smallest bond angle is

20. In Fe ( CO )5 , the Fe – C bond possesses

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5. The Gibbs energy for the decomposition of Al2O3 at 500C is as follows:

pace for rough work

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Section – III (Mathematics)

Q4. Let x,y  0 . If x 3 y 2 = 215 , then the least value of 3x + 2y is

Q6. The value of the integral

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Q11. The number of distinct real roots of the equation x7 − 7x − 2 = 0 is

Q12. Number of points of discontinuity of f(x) = [2x2 – 5] in [1, 2), is equal to

Q13. The number of solutions of the equation

x −1 y − 2 z − 3 x−2 y−4 z−5 1

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Q18. Consider the following statements :

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Q2. The remainder on dividing 1 + 3 + 32 + 33 + .... + 32021 by 50 is………..

space for rough work

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Section – III (Mathematics)

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HINTS & SOLUTIONS

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Sol6. Let, Rain drop moving with terminal Fb

Sol8. (Independent of distance) 2

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Sol9. Based on theory

Sol10. for  R2 Area → ‘ I ’ current Direction of current

Sol11. Purely inductive circuit

Sol14. Velocity of light in medium 2

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F.B.D of chain lying on the table.

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Batch :___ Date of Examination :