AKGECIQAC/QPIO4

AJAY KUMAR GARG ENGINEERING COLLEGE, GHAZIABAD

DEPARTMENT OF APPLIED SCIENCES ANDHUMANITIES
Sessional Test soLUTION
Program: B.Tech. IMCA Somoster: I
Session: 2023-24 Soctlon: S11-820
Subject: ENGG. CHEMISTRY Subject Code:BAS102
Max. Marks: 50 Time: 2 Hours

OBE Remarks:

Q.No 1 2 3 4 5 7 10 11 12
CO No. C01 CO1 CO2 CO2
CO1/ CO2/
CO2 CO1 CO1 CO2 CO2 CO1 CO2
CO1
Bloom's Level L1 L1 L2 L2 L2 L4 L4 L4 L5 L5 L3 L3
(L1 to L6)
Weightage co1: 26.5 Weightage co2: 23.5
*Bloom's Level: L1: Remember, L2: Understand, L3:Apply, L4: Analyze, L5: Evaluate, L6: Create
Note: Answer all the sections with allthe questions
Section-A (2*5=10)
1. Draw a molecular orbitaldiagram of CO also calculate its bond order

of Co is diffeHent from oJhen hetc odi

at omic moleules
Note ;
Diagzam

2p2
eas
2 p4
Bond Order
(Ny-Na)
4(8-2)
2S 4
Bio= 25
-1
T2S
kk
 4610
Atampound having a tomontatonof 19u rosultod ahsorbance value of 0.20 atAmax
nm ueing a 1 em eoll Galoulato ite absorptlvity and molar absorptivity valuos, The
malaoular welglt of the 6ompound is 400.
400

wmol|
4o0
mol (m
20 20 K0o0

GA ompound havingnoleoular formula CiMO whllo studled for lte analysis rosulted ln the
fullowing poako in it spootru:2900-2960om,1710 om and 3600-3060cm. The
ompoundalao yavo offorvea009 wlth NaCO, Buggost the atruoturo ofthe compound.

Jnl eprdal ion

lomuta

HCoo ( Aeelie eid)

compound
*oo , (o4
ofovalion
 Section-B
6. Write a brief note on fullerenes, discussing their (5*5=25)
applications. preparation, properties, and

6 Fullerenes : dn 1996 Nobel Prize for

by wWkroto Ri Cuel & R-Sm
chemcy has been w0n
for
dheir daacoveny in l98s
IRas
foy a new alo tope of Caslbon
StructwHe Fullenernes ate cage dike shuckwe having
forma Csof1o %
Ihe shuckwe of G ruembles a socceu ball ot
made of 20 hexagon 2 perdagand
atom ot the vetce ot each poygen
La and along each pougon edge

Sqndeis By the qraphite vod inaahelium

rsing
phened
Eaporation of c uing veslstiye heak.
when an elechic
eleehic spask is shuck betueen gphite
rod In al he aboe mehod soot is produced
which is maindy Cc black a containssigiticant
amoUnt Scaubon cute compd! knson as
buck inte fleenes.
Propeuiea torm deep magena soution when dissolved is
tendene
It is vey tough 2 theumay stable.
c=c bond lengt 38A°
c-c bond leigth
Tt Can be copessed to lsose 30y. ot its
ApplicatinA volume
formi a eonduator wih akali mealkso)
Can be sed in eleetronic, icro elechone 2
optical devices.
Can be wa a od dabricant
7. What are nanomaterials? Why physical and chemical properties of nanoparticles are
different from bulk materials? Write down a few applications of nanomaterials.

1. Nano mateinla are maleials possexsing pautides sizes

on he oYder of a biliondh of a mete ,manometey.
As the sixe ange, the paicdes will show some uniaue
Propeutie ike quahtum size etteet , swdae eHeet arid
Hhe macTO SCopic -quantum -tunnel efeet de to such
efkct nanopaxticles have diffeuent and chemcal
Propenties. Two principal faetors clse the propeutics
from Bulk
otnanomateuala
mateiala
to
aHe
ditfeu signitianty
Jncaed relalive Suntace area
&uantum effets
Inoreased Relative suae anea : As a panicle decnaeA
in sixe ya geate Praportion of atonu aHe found at
Hhe Swnface ompaued to hose iwde hence nano
Porl icles ne mare Ycactive than dange portides and
Propeties ike dispenaibility, conduetidity, calatytic
behavioun and optial bopeies altex uth it.
Sixe 30 nm >s/. ot its atoms on its swface
Size lonm 20/, ot is aomw ) ) il

Sixe 3 nm >So!, ot its ato u

Quantum feot Quantum confinement is to confine
atic its
he motion ot randomy moving elechon to
maving
motion in speitic enerdy deeds. The quantum confine - he
ot
ment etfeet can be observed onte the diameter
Particde is of the same maqnitude as the wavdength ot
continement is
he elechon wave funtion. uantum
vale of enevgy diHeaence blw
respon sible tor the increase
enengy stata and band gap A enegt
phendhenon tighty velakcd
withlhe optical e&elechdnc properties ot he mcteuals
 Applications of Nanomakcials
nanopauticles have good antibacteual propeutiea
I: Silve used in nnshaments
swHQical , efrigerators
and ae
-Conditiones wattu puifie etc.
2: Gold nano pauticdes ae used iin cataytic grheis
of siliCon nanowires, se
and in he deleetion of tumors,
be
3. Nano diamonds wih protcin moleeuler attaehed can
sed to inortase bone growdh around dental or joints
inplants
Nano crystalline selenide jincsuphide ycadmium
Sulide and lead tellnide ae, JAeplacing cuneat
phespharous for inproved (HOTV) i LCs montors.
5. Caubon nanotibres ave wed to make ithium ion
batteuy elechode hat shw four time he storage
capaty of cwuent Lithium -ion batteues
8. Why bonding
molecular orbitals are more stable than
the stability order of following NO, NO*, NO". antibonding Molecular orbitals.Give
Bonding moleeulan orblas ave more stable han
anibondhg maleculau orbitals it can e undevutood
LCAO medhod
Acc. to wave mehanics he Ao can be ex pressed
wae uncion C) uuhich eptAent he amplitude ot
elecho wares Af
1f two aoic oritala of two atosAB
tu0 atoic
having (A) a(v6wave e chage denity ot aBom Aa BruRe
tivey s hei wave Funcio To Bocsibilitiea ate:
i) t Mos ave formed bu he add'tion of u) ware fune!
of atomic orlitals known as BnO having low eneT
e impats high stability
Ladditive contination
2
Conihetive interteence

") T moleaudaH orbitad is Hormed by he subtraction

wave funetion t Aos knoun.as ABNOs haing
high energy ipos dawen stability
subtacive conbination
PA
2 Desuelive inhofrence

ab
Ordey of NO, No,No
NO

TIs*isas'xasa2-222,
 B-o (Ny-Na)
(l0-5)
25
Not
2

Bo - (lo-4)
= 3
No

Bo = (lo-6)
2
Not No > NO

NoT NO > No
 eloelyn occu in uv- vicible peetnofy
q. Hou) do trans ihms o

wbobeugen
t.

stransi n - transttrans,
tor aidden
motecule,
utuall
transi fion, - u
h t s i hon weal dwensiky Transi fim occesih tlo
n tmnsí ffns wealeiensihy Tra usiion
-allew.

iolatelCovalet,
cuy
ditined as absptoninte
yowephore chacleshe
Curowmo phore.
thal los a
Mepeetie
cyleus,hlu,
ane
Auxoclrome : Tuse
-SH ete.
 NO

Benri

thes male -

than o loenro,

isomeim. hal athe Conlitio to

10. Define C7tilal
achvity
no chhal Carbon atsm
.aie ompeund having
isomei(my hee molecle
Ch5al somsm is a
strutrae tmelas, bul
J, -t Aame mollelan and to eal o the.
dinposall
nm-pe ther
cpral isemesade
TuD tes imag
Lanhomer Nm Supea èmposnll n r Akne
miror
Non
(oo
OH
HO

enomi
 for showiwg ofncal aehvity
eleenl munl b f r 0 in it,

ip) au alt
runtg
Compeunda aviny no chyrad Cas
Ohhally ache
when Cummulatve doulal bond ae the
Alles.:
thn elon cloul becsne bpendilor to eol othe

estually actn

sp. sp sp molecule, having lalbm atom

Spivene; These
Tw
fupedla to cach ottu
hotes
Commgn to ig: loenwe of heotneed
oßhial isomeism
Spianoeibit
H

HOoC H

isomecis m.
Atep
CoDH COoH

KOz rotatin aloo

heslls torm thneel
The tuto isomes Abrain bawwu to ho
tation
Bingle bondo ne the Muie
 Seetim c

detail. Afo ite oy Vaio

plitatio
A sate matten hal ie itamedte betweey the
Aelil Coyctallihe cnol the
Phase s lnm mesomohphic tate or

Tootopie Liqwd, Cmyital

Transittiy mp
pbtno
Potul

Lyotopic LoC.
mo taty
long Cha'n yotepi beyodIsetepic
Aatuntad tutity til cMc Lo
Liytt

(DSmall amounl
Soop O oeuional e small amun

is) Mofecalas torm flanee puhaudi cula to avu mote

-tas to out along dhetr,

SmecbA SheticC
 Ne mabe Lo C. :Thhea ike,
normal o beheriou,
loss ot osittnl odey

Mesogcn
-C=C

Long hais hange oyientnn deu b

Long
ho þositten odes
yiel)
Cholestie L.C, cchal Namate tase bul
imau to nemalie
! i shuetue do
dufind by tance JA.
Prfa Co) Auct Jo n broceln
y hoate by tus t n
is neeessouy to
alony a s
e l e masnete teld.
ratun,
Lyctrepie Lic.
is heale
CMC, Whea Ael Aotuh
Cncewthoto Byond
Concenlhoon,
ol a Liqud Coystal.
e seprate
thea Coliap
Display (2) GLe.
Applicnty,!ci)LcD
d g tumuor,
3, Thumoaphy-
modulotn
S, atmopeu,
6. Eyoonsl ottical and foltenl; la
lleel- hadilrn
Non deotsicn
 Maeule hod vaio

Th nhAni, thee own tn Chorein

Noymal modes Vibraon

T
Ben d
Strchin
clany in laond lenyt
in a end

ymnfe
Assymetic,

Ik inoun vi br

Toishny
 bansdutus depdent
The -patten o
wtol Tlws
minon
clag
tus an
fttern in

Conslueas a proof