(Set-B) SR Adv (2020 P1) (R-T) Ex. Dt. 22-05-2023 - Q.P

1- B
INTERNAL TEST
IIT - JEE
SECOND YEAR 2021-23
RESHUFFLING TEST
2020 P1
Time: 3 hours Maximum Marks: 198
INSTRUCTIONS: Dated: 22 MAY 2023
Instructions to the Candidates

GENERAL: Question paper format & Marking Scheme:
I. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has
3 sections.
II. Section I contains SIX (06) multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out of which only one is correct.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
III. Section II contains SIX (06) questions. Each question has FOUR options ONE OR MORE THAN
ONE of these four option(s) is(are) correct answer(s).
Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
IV. Section III contains SIX (06) questions. The answer to each of the questions is a NUMERICAL
VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value
has more than two decimal places, truncate/round-off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.
NAME:
ENROLLMENT NO.:
KUKATPALLY CENTRE: # 22-97, Plot No.1, Opp. Patel Kunta Huda Park, Vijaynagar Colony, Hyderabad - 500 072. Ph.: 040-64601123
MIYAPUR CENTRE: Above Sai Motors Maruthi Showroom, Allwyn X Road, Miyapur, Hyderabad.
2- SECOND YEAR RESHUFFLING TEST ADV (2020 P1) EX. DT. 22-05-2023 (SET-B)
Section-III Bubbling samples
Ans. 1.25 Ans. 5
Ans. 19 Ans. 0.33
Ans. 30.27 Ans. – 127.30
Ans. 1021.65 Ans. 40025.01
SECTION–1 (Maximum Marks: 18)

Single Correct Choice Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, Out of which ONLY ONE is correct.
1. The figure shows a hexagonal arrangement of six particles each of mass m. The side of hexagon is a.
Each particle rotate with uniform angular velocity about the centre of mass of the system in the same
horizontal plane under the action of net gravitation force.
A B
7GM 2
(A) work done to disassemble the system is
2a
C
9GM 2 F
(B) work done to disassemble the system is
2a F
E D
8GM 2
(C) work done to disassemble the system is
a
11GM 2
(D) work done to disassemble the system is approximately
2a
2. The figure shows a small disc whose center is attached to an elastic thread of area of cross section A
and natural length l0 where 2  l0  2.01 m. The coefficient of friction for x > 0 is  = 0.8 and for x <
0 is very high. The disc is given a velocity v0 = 6 m/s towards the smooth wall such that it attains
immediate rolling(no slipping) and collides with the wall. The collision is perfectly elastic. If mass of
disc is m and youngs modulus for thread material is Y then maximum elongation in the thread is
smooth
0
v0
x=0
2.0 m
3ml0 3ml0 3ml0 3ml0

(A) 2 (B) 5 (C) 3 (D) 6
2 AY 2 AY 2 AY 2 AY
A
mA = mB = mC = 2kg
3. Consider the situation given. When system is released B
Neglect friction
from rest, block B moves vertically downwards by 1 m. 1m
every where
The displacement of block C till the instant block B makes vertical downward displacement of 1 m is
2 4 1
(A) zero (B) m in left direction (C) m in left direction (D) m in left direction
3 3 3
4. The figure shows an elevator in which a vessel of height h0 is kept. elevator

The vessel is filled with an ideal fluid upto the brim. At time = 10.00
am, a small hole is punctured on the vessel side and at same
2
moment the elevator starts accelerating upwards at 10 m/s . If area
h0
of cross section of hole is a << A (area of cross section of vessel) ground
2
then the maximum range on the ground is (g = 10 m/s )
Ah0  2  1 
(A) 
a  2 
 (B)
2Ah0
a
(C)
2 Ah0
a
 2 1  (D)
2 Ah0
a
 3 1 
0
5. A small block of mass m is kept on a smooth inclined plane of angle 30 ,
a0
placed in an elevator going upward, with acceleration a0. Electric field E
+ –
exists between the vertical sides of the wall of the elevator. The charge on + –
the block is +q. The time taken by the block to come to the lowest point of + –
+ –
inclined plane starting from top is : (Take the surface to be smooth) + –
m – h
+ +q
+ 300 –
+ –
     
 2h   2h   8h   2h 
(A)   (B)   (C)   (D)  
qE   g  qE   qE  2 
  g  a0     g  a0   3    g  a0    m  h
2
 
 m   m     
6. A rod of length ‘  ’ is placed along x-axis. One of its ends is at the

origin. The rod has a non uniform charge density  = ax, a being a
positive constant and x is distance from origin. Electric potential at
P as shown in the figure is
1     1    
(A) a   bloge  1    (B) a   b  1   
40   b  40   b 
1     1    
(C) a   bloge  1   (D) a   b 1  
40   2b  40   b 

Multiple Correct Choice Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, Out of which ONE OR MORE is/are correct.
7. Two non–conducting solid spheres of radii R and 2R, having uniform volume charge densities 1 and
2 respectively, touch each other. The net electric field at a distance 2R from the centre of the smaller

sphere, along the line joining the centres of the spheres, is zero. The ratio 1 can be
2
32 32
(A) 4 (B) – (C) (D) – 4
25 25
8. A uniform solid sphere of mass m and radius R is kept on the rough 37
1 J
horizontal surface with co–efficient of friction   as shown in the
3
figure. An impulse of J = mV0 is applied at the topmost point of the
sphere at an angle 37 with horizontal shown in figure. rough
2 3  3 4
(Assuming J >> mg dt, g = 10 ms , tan 37 = )  sin37o  , cos37o  
4  5 5
9V0
(A) the angular velocity just after impulse is applied
7R
3V0
(B) velocity of centre of mass just after impulse is applied is
5
(C) velocity of centre of mass just after impulse is applied is V0
3V0
(D)  
2R
9. Two identical rings of same thermal conductivity K and radius R are joined as
shown in figure. The points P and Q are maintained at constant temperatures
2T and T respectively. If area of cross section of the wire used for rings is A,
the heat current between P & Q is
3KAT KAT
(A) (B)
8R 4R
3KAT 3KAT
(C) (D)
2R 4R
10. The figure shows a hemispherical track whose radius of curvature is R. A B
The inner surface of the track is rough (coefficient of friction is ). An R

external agent pulls the block with a constant speed v along the interior

from point A to point B the work done by the external agent in the
process is
2 2
(A) 2 mgR (B) mv + mgR (C) mv + 2mgR (D) none of these
11. Fig shows a long non-conducting, massless rod of length L, pivoted

at its centre and balanced with a weight W at a distance x from the
left end. At the left end and right end of the rod are attached small
identical conducting spheres with positive charges q and 2q
respectively. A distance h directly beneath each of these spheres
is a fixed sphere with positive charge Q. Which of following is/are
correct? (neglect mass of small sphere and induced charge)
 QqL L
(A) when the rod is horizontal and balanced then x    .
 80 wh
2
2
(B) when the rod exerts no vertical force on the bearing then h  3qQ / 40 w
5L
(C) when the rod is horizontal and balanced and reaction on bearing is zero then x 
6
2L
(D) when the rod is horizontal and balanced and reaction on bearing is zero then x 
3
12. A gas undergoing an adiabatic process. At a certain stage A, the values V

of volume and temperature = (V0, T0). From the details given in the graph,
find the value of CV.  A(T0, V0)
2RT0 tan 
(A) (B) R tan 
V0
RT0 tan  RT0 tan  T
(C) (D)
2V0 V0

Numerical Value Type
This section contains 6 questions. The answer to each of the questions is a Numerical value.
For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
13. A capillary tube of radius 1 mm is kept vertical with the lower end in water. The height of water raised
h
in the capillary is ‘h’. If the length of the capillary tube is above the water surface then the angle 
3
made by the water surface in the capillary with the wall is tan   2 K . Find K .
14. In the figure shown mass of both, the spherical body and block is
m . Moment of inertia of the spherical body about centre of mass is R
2
2mR . The spherical body rolls on the horizontal surface. There is
2R
no slipping at any surface in contact. The ratio of kinetic energy of
the spherical body to that of block is given by ……
15. A fixed sphere of radius R and uniform mass density d has a cavity of radius
R/2 as shown in figure. The centre of the solid sphere was at C while that
of the cavity is O. A liquid of density d/2 is filled in the cavity. The
gravitational force exerted by the liquid on solid sphere is given by
GR 4 d2 .a , where value of a is
(Take 2  9.86 )
16. A non conducting ring of mass m and radius R is placed on a rough surface so that the plane of the
ring is perpendicular to surface. Two point charges  q and  q are fixed at highest point and lowest
point of ring respectively. A time t  0 uniform electric field E0 in horizontal direction and parallel to
the plane of the ring is switched on. The maximum value of coefficient of friction below which the ring
kEo q
will not slip is found to be . Find k .
mg
T
17. The efficiency of the thermodynamic cycle for 1 mole of monoatomic 2T 0 A
B
ideal gas is (in percent) (ln 2=0.693)
T0
C
v0 2v0 V
18. 1 gm of steam at 100C is injected into a vessel containing 1 gm of ice at 0C. The resultant mixture is
mixed with 2 gm of water at 11C, in an open container allowing the steam to escape. The final
temperature of mixture will be in C. (Lf = 80 cal/gm, Lv = 540 cal/gm, specific heat of water = 1
cal/gm/C, thermal capacity of vessel and open container is negligible)

19. Identify the reagent I and II respectively in the following sequence:


Borax 
I
 H3BO3   B2 O3 
II
 Boron
(A) Acid, Al (B) Acid, C (C) Acid, Mg (D) Acid, Fe
Hg OAc  / THF H O

20. X 
2
NaBH / OH
2
 C7H14 O  optically inactive 
4
X is
(A) (B) (C) (D)
21. The percentage yield of ammonia as a function of time in the reaction

N2(g) +3H2(g)  2NH3(g), ∆H<0 at (P,T1) is given below
If this reaction conducted at(P,T2) with T2> T1 The percentage yield of ammonia as a function of time
is represented by:
(A) (B)
(C) (D)
o
22. In a photoelectric experiment, radiation of 623 A strike a metal surface. The Kinetic energy of the
–19
photoelectrons is 6.4  10 Joule. What is the stopping potential of the metal is volt unit?
(A) 3 (B) 4 (C) 5 (D) 6
23. Arrange the following compounds in decreasing order of reactivity towards a common electrophilic
substitution reaction?
CH2CONH2 COCH2NH2 CONHCH3 NHCOCH3
(I) (II) (III) (IV)
(A) I > IV > II > III (B) IV > I > II > III (C) IV > I > III > II (D) I > IV > III > II
24. OH (a) CH2OH (b)
OH (c)
OH (d)
Arrange the hydrogen atoms (a, b, c and d) in the above compound in decreasing order of acidic
strength?
(A) a > d > c > b (B) a > d > b > c (C) a > b >c > d (D) a > b > d > c

25. Which of the following are aromatic?
H
N
N
(A) (B) (C) (D)
N N N
O
H 
B
26. For the following compounds the correct statement(s) with respect to nucleophilic substitution
reactions is(are)
Br Br
(I) (II)
(III) Br (IV) Br
(A) I and II follow SN2 mechanism

(B) I and III follow SN1 mechanism
(C) The order of reactivity of I, III, IV towards SN2 is I > IV > III
(D) Compound IV undergoes inversion of configuration
27. A gas obeys P(V - b) = RT. Which of the following is/are correct about this gas?
R
(A) Isochoric curves have slope =
V b
Pb
(B) For the gas compressibility factor = 1 
RT
R
(C) Isobaric curves have slope and intercept ‘b’
P
(D) The attractive forces are overcome by repulsive forces
28. Which of the following is correct for critical temperature?

(A) It is highest temperature at which liquid and vapor can co-exist
(B) Beyond the critical temperature there is no distinction between two phases and gas cannot be
liquefied by compression
(C) At critical temperature the gas and the liquid phases have the different critical densities
(D) At critical temperature, the surface tension of the system is zero
29. To check the principle of multiple proportions, a series of pure binary compounds PmQn  were
analysed and their composition is tabulated below. The correct option(s) is/are
Compound Weight % of ‘P’ Weight % of Q
1 50 50
2 44.4 55.6
3 40 60
(A) If empirical formula of compound 3 is P3Q 4 , then the empirical formula of compound 2 is P3Q5
(B) If empirical formula of compound 3 is P3Q2 and atomic weight of element P is 20, then atomic
weight of Q is 45
(C) If atomic weight of P and Q are 70 and 35 respectively, then the empirical formula of compound 1
is PQ2
(D) If empirical formula of compound 2 is PQ then the empirical formula of the compound 1 is P5Q 4
30. For the reaction

   ClO3  H2SO 4  Cl  HSO4   2
(A) Stoichiometric coefficient of HSO4 is 5 (B) H2 O is one of the product
(C) Sulphur is reduced (D) Iodide is oxidised

31. The total number of nodal planes possessed by the following molecules or ions is/are
 *2s , dz2 , px, dxy,  *2px
32. When one mole of A(g) is introduced in a closed vessel of one litre capacity maintained at constant
temperature, the following equilibrium is established
A  g  B g  C g ; KC1
C g  D g  B g ; KC2
KC1 Ceq 2
The total pressure of equilibrium is twice the initial pressure. Find if 
KC2  A eq 1
10 - SECOND YEAR RESHUFFLING TEST ADV (2020 P1) EX. DT. 22-05-2023 (SET-B)
33. How many maximum number of electrons of an atom will have the following set of quantum numbers?
n = 4, l = 0, 1, m = 0, +1 and s =  1/2
34.
How many hyperconjugation structure(s) is/are possible for the above species?
35. 

In the reaction: C  s   CO2  g 
 2 CO  g  , the equilibrium pressure is 6 atm. If 50%(mole) of
CO2 reacts then KP of the reaction in atm unit is:
3
36. Out of the following, how many molecules have sp hybridization of central atom:
H2O, NH3, H2O2, CH4, SO3, SO2, CO2, PCl5, PCl3, POCl3, XeF2

37. Let A and B are two non-singular 3  3 matrices such that A  B  2I and A 1  B1  3I then
det  AB  is equal to
27 8
(A) 8 (B) 27 (C) (D)
8 27
38. Consider the equation 3cot 2 x   cot x  3  0 , x   0,2    . Then which of the following
CORRECT
(A) Sum of the solutions of the equation  3 if 7
(B) Sum of the solutions of the equation  5 if 9
(C) Sum of the solutions of the equation  4 if   8
(D) Sum of the solutions of the equation  6 if   10
39. If 2a  3b  4c  k , then the value of ‘k’ for which the line ax  by  c  1 always passes through a
fixed point is
(A) 1 (B) 2 (C) 4 (D) 3
 2 1 2023
40. If M    then M is equal to
  1 0 
 2024 2023   2025 2024   2024 2023   2025 2024 
(A)   (B)   (C)   (D)  
 2021 2022   2022 2023   2023 2022  2024 2023 
41. Let f  x   x3  x  1 and let g  x  be its inverse function, then equation of the tangent to y  g  x  at
x  3 is
(A) x  4y  1  0 (B) x  4y  1  0 (C) 4x  y  1  0 (D) 4x  y  1  0
42. The locus of the midpoints of the perpendiculars drawn from points on the line x  y  1  0 to the line
2x  y  1  0 is
(A) 5x  2y  2  0 (B) 2x  5y  5  0 (C) 4x  7y  7  0 (D) 7x  4y  4  0

43. Let f  x   x  1,g1  x   x 3  x  1 and h  x   g  f  x   . Then which of the following are CORRECT
h x 1
(A) h1  3   30 (B) lim 
x 0 x 4
h 1
 x   h 1
1
(C) lim 4 (D) h  2   1
x 1 x 1
n
n
 2k   2k  
44. Let f  n    cos 
k 1
7 
and g  n    cos 
k 1
7 
 then which of the following are CORRECT
(A) f  3   g  3  (B) 2f  3   f  6  (C) f  8   g  8  (D) 2g  3   g  6 
45. Let f : 0,2  3,5 is an ONTO function such that f '  x   0 and f ''  x   0 then which of the
following are CORRECT
(A) f  0   f  2   8 (B) f 1  4
f  x f  x
(C) , x   0,2 is an increasing function (D) ,  x   0,2 is a decreasing function
x x
 x  2k, 2k  x  2k  1
46. Let f  x    where k   . Then which of the following are CORRECT
 2k  2  x, 2k  1  x  2k  2
(A) f  x  is continuous  x  R
(B) f  x  is periodic function with period 1
(C) f  x  is symmetric with respect to line x  1
(D) f  x  is an even function
47. Consider two functions f and g from N  N defined as
 x, x 
f x  
1  f  x  1 , otherwise
 x, x 
g x   
 2  f  
x  1 , otherwise
Then which of the following are CORRECT
(A) f  2023   47 (B) g  2023   49 (C) g is onto (D) f is one-one
4
 1   b   b   b   b 
48. If  x   1  a0   a1x  1    a2 x 2  22    a3 x 3  33    a 4 x 4  44  then which of the following
 x   x  x   x   x 
are CORRECT
(A) a0  19 (B) a1  16 (C) b3  4 (D) b2  8

x 2n1  ax 2  bx
49. Let f  x   lim . If f  x  is continuous  x   , then the value of 3a  4b is
n 1  x 2n
x 1 y  2 z  3
50. The shortest distance between a variable line and the line   lies along the points
2 3 4
A  3,5,7  and B  2,3,4  . Then the locus of the point on the variable line is x  ay  bz  c then
a  b  c is
51. If L1 is the line of intersection of the planes x  y  2z  8  0 , 3x  2y  z  4  0 and L 2 is

x  2 y 1 z 1
  . If P is the plane containing L1 and L 2 which intersects the coordinates axes at
1 2 1
A, B, C respectively, then volume of tetrahedron OABC (O is origin) is ______
   
2
52. If a  b  c b   c  2a  c  a  3b   k a b c  then k is equal to
   
53. Let a,b,c be three vectors satisfying a  2b  b  c where b  c  2 and a  4 . Then the sum of
possible values of a  b  c is
   2 n 
54. 
The value of tan  cot 1  2
n k 3


 n 1  k 1 

(Set-B) SR Adv (2020 P1) (R-T) Ex. Dt. 22-05-2023 - Q.P

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1- B

Instructions to the Candidates

Section-III Bubbling samples

Ans. 1.25 Ans. 5

Ans. 19 Ans. 0.33

Ans. 30.27 Ans. – 127.30

Ans. 1021.65 Ans. 40025.01

SECTION–1 (Maximum Marks: 18)

3ml0 3ml0 3ml0 3ml0

4. The figure shows an elevator in which a vessel of height h0 is kept. elevator

6. A rod of length ‘  ’ is placed along x-axis. One of its ends is at the

SECTION–2 (Maximum Marks: 24)

10. The figure shows a hemispherical track whose radius of curvature is R. A B

The inner surface of the track is rough (coefficient of friction is ). An R

11. Fig shows a long non-conducting, massless rod of length L, pivoted

12. A gas undergoing an adiabatic process. At a certain stage A, the values V

SECTION–3 (Maximum Marks: 24)

SECTION–1 (Maximum Marks: 18)

19. Identify the reagent I and II respectively in the following sequence:

Hg OAc  / THF H O

(A) (B) (C) (D)

21. The percentage yield of ammonia as a function of time in the reaction

(I) (II) (III) (IV)

24. OH (a) CH2OH (b)

SECTION–2 (Maximum Marks: 24)

25. Which of the following are aromatic?

(A) I and II follow SN2 mechanism

28. Which of the following is correct for critical temperature?

30. For the reaction

SECTION–3 (Maximum Marks: 24)

SECTION–1 (Maximum Marks: 18)

SECTION–2 (Maximum Marks: 24)

(A) f  3   g  3  (B) 2f  3   f  6  (C) f  8   g  8  (D) 2g  3   g  6 

47. Consider two functions f and g from N  N defined as

SECTION–3 (Maximum Marks: 24)

51. If L1 is the line of intersection of the planes x  y  2z  8  0 , 3x  2y  z  4  0 and L 2 is

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