CHAPTER

1 Some Basic Concepts

of Chemistry
1. The number of moles of hydrogen (a) 3.5 g (b) 7g (c) 14g (d) 28 g

molecules required to produce 20 moles of (2015)

ammonia through Haber's process is 7. If Avogadro number Nas is changed from
(a) 40 (b) 10 (c) 20 (d) 30 6.022 x 10 mol to 6.022 x 10 mol,
(NEET 2019) this would change
carbon
2. The density of 2 M aqueous solution of (a) the mass of one mole of
to each
NaOH is 1.28 g/cm'. The molality of the (b) the ratio of chemical species
solution is [Given that molecular mass of other in a balanced equation
NaOH 40 g mol] (c) the ratio of elements to each other in a

(a) 1.20 m (b) 1.56 m compound

(c) 1.67 m (d) 1.32 m (d) the definition of mass in units of gramns.
(Odisha NEET 2019) (2015)
A mixture of 2.3 g formic acid and 4.5 g
8. The number of water molecules is
3.
oxalic acid is treated with conc. H,SO maximum in
is passed
The evolved gaseous mixture (a) 1.8 gram of water
of the
through KOH pellets. Weight (in g) (6) 18 gram of water
will be
remaining product at STP (c) 18 moles of water
(a) 1.4 (b) 3.0 (c) 2.8 (d) 4.4 (d) 18 molecules of water: (2015)
(NEET 2018)
9. A mixture of gases contains H, and O
molecules of
is number of What is the
4. In which case
gases in the ratio of 1:4 (w/w).
water maximum? molar ratio of the two gases in the mixture?
18 mL of water
(b) 0.18 g of water 1:4 (d) 4:1
(a) (a) 16:1 (b) 2:1 (c)
at 1 atm and
(c) 0.00224 L of water vapours (2015, Cancelled)
273 K
(NEET 2018) 10. Equal masses of H,» O, and methane
(d) L0 mol of water
X and Ycombine to
have been taken in a container of volume
5. Suppose the elements V at. temperature 27 °C in identical
and X,Y2. When
form two compounds XY, conditions. The ratio of the volumes of
10 g and 0.05 mole
0.1 mole of XY, weighs gases H: 0, methanewould be
the atomic weights of
of X,Y, weighs 9g. (a) 8:16:1 (b) 16:8:1
X and Y are (d) 8:1:2 (2014)
(b) 60, 40 (c) 16:1:2
(a) 40, 30
(c) 20, 30
(d) 30, 20 11. When 22.4 litres of H2(o is mixed with
(NEET-II 2016) 11.2 litres of Clzioeach at S.T.P, the moles
formed of HCl formed is equal to
6. What is the mass of the precipitate
AgNO, is (a) 1 mol of HCl (b) 2 mol of HCl
when 50 mL of 16.9%
solution of
solution? (c) 0.5 mol ofHCl (d) 1.5 mol of HC
mixed with 50 mL of 5.8% NaCl
(Ag=107.8, N=14, O=16, Na =23, Cl=35.5) (2014)
2 MtG NEET-AIPMT Chapterwise Solutions Chemistry
12. 1.0gof magnesium is burnt with 0.56 g O, in (a) 3 mol (b) 4 mol
a closed vessel. Which reactant is left in excess (c) 1 mol (d) 2 mol
(2009)
and how much? (At. wt. Mg 24, 0 16) = =
19. What volume of oxygen gas (O,)
(a) Mg. 0.16 g (b) 0,,0.16g measured
at 0°C and 1 atm, is needed to
) Mg. 0.44g (d) O, 0.28 g burn
(2014)
completely 1 L of propane gas (C,H)
measured under the same conditions?
13. 6.02x 10 molecules of
urea are present in (a) 5L (b) 10 L (c) 7L (d) 6 L
100 mL of its solution. The concentration
of solution is (2008)
20. How many moles of lead (II) chloride will
(a) 0.001 M b) 0.1 M
be formed from a reaction between 6.5 of
(c) 0.02 MM (d) 0.01 M g
PbO and 3.2 g HCI?
(NEET 2013) (a) 0.011 (b) 0.029
14. In an
experiment it showed that 10 mL (c) 0.044 (d) 0.333 (2008)
of 0.05 M solution of chloride
required21. An
10 mlL of 0.1 M solution of organic compound contains carbon,
AgNO, which
of the following will be the formula of the hydrogen and oxygen. Its elemental analysis
gave C, 38.71% and H, 9.67%. The empirical
chloride (X stands for the symbol of the
formula of the compound would be
element other than chlorine)?
(a) CHO (b) CHO
(a) X,Cl (b) XCl,
(c) XCl (d) X,CI
(c) CH,O (d) CH,O (2008)
22. An element, X has the
(Karnataka NEET 2013) following isotopic
15. Which has the maximum number of composition:
molecules among the following?
200y: 90% 199X:8.0%% 202X: 2.0%
The weighted average atomic mass of the
(a) 44 g CO, (b) 48 g O,
(c) 8gH, (d) 64 g S0
naturally occurring element X is closest to
(a) 201 amu (b) 202 amu
(Mains 2011) (c) 199 amu (d) 200 amu (2007)
16. The number of atoms in 0.1 mol of a
23. The maximum number of molecules is
triatomic gas is (N =6.02 x 105 moll)
present in
(a) 6.026 x 102 (b) 1.806 x 1023
(a) 15 Lof H, gas at STP
(c) 3.600x 1023 (d) 1.800x 1022
(b) 5 L of N, gas at STP
(2010) (c) 0.5 gof H, gas
17. 25.3 g of sodium carbonate, Na,CO, is (d) 10 gof O, gas. (2004)
dissolved in enough water to make 250 mL
24. Which has maximum molecules?
of solution. If sodium carbonate dissociates
completely, molar concentration of sodium (a) 7gNg (b) 2 gH
ion, Na* and carbonate ions, COg are (c) 16g NO, (d) 16 gO, (2002)
respectively 25. Percentage of Se in peroxidase anhydrous
(Molar mass of Na,CO, = 106 g mol) enzyme is 0.5% by weight (at. wt. = 78.4)
(a) 0.955 M and 1.910M then minimum molecular weight of
(b) 1.910 M and 0.955 M peroxidase anhydrous enzyme is
(c) 1.90 M and 1.910 M (a) 1.568 x 104 (b) 1.568 x 10*
(d) 0.477 M and 0.477 M (2010) (c) 15.68 (d) 2.136 x 10*
18. 10 g of hydrogen and 64 of (2001)
g oxygen were
filled in a steel vessel and exploded. Amount 26. Molarity of liquid HCl, if density ot
of water produced in this reaction will be solution is 1.17 g/cc is
Some Basic Concepts of Chemistry 3
(a) 36.5 (b) 18.25 34. 0.24 g of a volatile gas, upon vaporisation,
(c) 32.05 (d) 42.10 (2001) gives 45 mL vapour at NTP. What will
be the vapour density of the substance?
27. Specific volume of cylindrical virus particle is (Density of H, = 0.089 g/L)
6.02 x 102 cc/g whose radius and length are
7Å and 10 respectively. IfN, = 6.02 x 10*", (a) 95.93 (b) 59.93
find molecular weight of virus. (c) 95.39 (d) 5.993 (1996)
(a) 15.4 kg/mol (b) 1.54 x 10* kg/mol 35. The amount of zinc required to produce
(c) 3.08x 10 kg/mol (d) 3.08 x 10" kg/mol 224 mL of H, at STP on treatment with
(2001) dilute H,SO, will be
28. Volume of CO, obtained by the complete (a) 65 g (b) 0.065g
decomposition of 9.85 g of BaCO, is (c) 0.65 g (d) 6.5 g (1996)
(a) 2.24 L (b) 1.12 L
36. The dimensions of pressure are the same as
(c) 0.84 L (d) 0.56 L (2000)
that of
29. Oxidation numbers of A, B, C are +2, +5 (a) force per unit volume
and 2 respectively. Possible formula of (b) energy per unit volume
compound is (c) force
(a) A(BC,) (b) A,(BC)2 (d) energy. (1995)
(c) A,(BC)2 (d) A,(B,C), (2000)
37. The number of moles of oxygen in one litre
30. The number of atoms in 4.25 g of NH, is
of air containing 21% oxygen by volume,
approximately under standard conditions, is
(a) 4 x 1023 (b) 2x 103
(a) 0.0093 mol (b) 2.10 mol
(c) 1x 1023 (d) 6x 1023 (1999)
31. Given the numbers: 161 cm, 0.161l cm,
()0.186mol (d) 0.21 mol. (1995)
38. The total number of valence electrons in
0.0161 cm. The number of significant
figures for the three numbers is 4.2 g of ion is (NA is the Avogadro's
N,
(a) 3,3 and 4 respectively number)
(b) 3, 4 and 4 respectively (a) 2.1 NA (b) 4.2 NA
(c) 3,4 and 5 respectively (c) 1.6 NAa (d) 3.2 N (1994)
(d) 3,3 and 3 respectively. (1998) 39. A 5 molar solution of H,SO, is diluted
32. Haemoglobin contains 0.334% of iron from 1 litre to a volume of 10 litres, the
by weight. The molecular weight of normality of the solution will be
haemoglobin is approximately 67200. The (a) 1N (b) 0.1 N
Iumber of iron atoms (Atomic weight (c) 5N (d) 0.5 N (1991)
of Fe is 56) present in one molecule of
40. The number of gram molecules of oxygen
haemoglobin is in 6.02 x 10 CO molecules is
(a) 4 (6) 6 (c) 3 (d) 2
(a) 10 gmolecules (6) 5g molecules
(1998) (c) 1gmolecules (d) 0.5gmolecules.
33. In the reaction,
(1990)
4NH3+502 4NO+6H,0
when 1 mole of ammonia and 1 mole of O, 41. Boron has two stable isotopes, B(19%)
are made to
and 'B(81%). Calculate average at. wt. of
react to completion: boron in the periodic table.
(a) all the oxygen will be consumed
(b) 1.0 mole of NO will be produced (a) 10.8 (b) 10.2 (c) 11.2 (d) 10.0
(c) 1.0 mole of H,O is produced (1990)
(d) all the ammonia will be consumed. 42. The molecular weight of 0, and SO
(1998) are 32 and 64 respectively. At 15°C and
 wtG NEET-AIPMT Chapterwise Solutions
Chemisto
150 mmHg pressure, one litre ofO, contains 46. The number of oxygen atoms in 4.4
N molecules. The number of molecules in g of
CO, is
two litres of SO, under the same conditions (a) 1.2x 1023 (b) 6 x 1022
of temperature and pressure will be (c) 6x 1023 (d) 12 x 105 (1989
(a) N/2 (b) N (c) 2N (d) 4N
47. At S.T.P. the density of CCI4
(1990) vapour in g/
will be nearest to
43. A metal oxide has the formula Z,0,. It can
(a) 6.87 (b) 3.42
be reduced by hydrogen to give free metal (c) 10.26 (d) 4.57
and water. 0.1596 g of the metal oxide (1988)
requires 6 mg of hydrogen for complete 48. One litre hard water contains 12.00
mg
reduction. The atomic weight of the metal is Mg*. Milli-equivalents of washing soda
(a) 27.9 (b) 159.6 (c) 79.8 (d) 55.8 required to remove its hardness is
(1989) (a) 1 (b) 12.16
(c) 1x 103 (d) 12.16 x 10
44. Ratio of C, and Cy of a gas X is 1.4. The
number of atoms of the gas 'X present in (1988)
11.2 litres of it at NTP will be 49. 1 cc N,O at NTP contains
(a) 6.02 x 1023 (b) 1.2x 1023
(c) 3.01 x 1023 (d) 2.01 x 1023 (a) 8 x10 atoms
224
(1989) 2 molecules
45. What is the weight of oxygen
required 22400
for the complete combustion of 2.8 kg of
ethylene? (c) x105 electrons
(a) 2.8 kgs (b) 6.4 kg
(c) 9.6 kg (d) 96 kg (1989) (d) all of the above. (1988)
ANSWER KEY
1. (d) 2. (c) 3. (c) 4. (a) 5. (a) 6. (b) 7. (a) 8. (c)
9. (d) 10. (c) 11. (a) 12. (a) 13. (d) 14. (b) 15. (c) 16. (b)
17. (b) 18. (b) 19. (a) 20. (b) 21. (c) 22. (d) 23. (a) 24. (b)
25. (a) 26. (c) 27. (a) 28. (b) 29. (b) 30. (d) 31. (d) 32. (a)
33. (a) 34. (b) 35. (c) 36. (b) 37. (a) 38. 39.
(c) (a) 40. (b)
41. (a) 42. (c) 43. (d) 44. (a) 45. (c) 46. (a) 47. (a) 48. (a)
49. (d)
EXPLANATIONS
1. (d): Haber's process, N, + 3H,>2NH, Mass of solution =
dx V= 1280 g
2 moles of
NH, are formed by 3 moles of H2
20 moles of will be formed by
Mass ofsolute = n x Molar mass 2x 40 =808
NH,
30 moles of H. Mass of solvent (1280 80) g= 1200 g
=
2. (c): Density 1.28 g/cc,
=
Number of moles of solute = 80 2
Conc. of solution = 2 M 40
Molar mass
of NaOH 40 g mol = 2x1000
Volume of solution 1 L= 1000 mL
=
Molality=1200 1200
=1.67 m
Some Basic Concepts of Chemistry
3. (c) HCOOHehydrating agent Co + H,O The reaction can be represented as:
.3
conc. H,S04 AgNO,+ NaCl- AgC+ NaNO,
Initial 8.45/170 2.9/58.5 0
mole = 0.049 = 0.049
1
n,= 0 Final moles 0 0 0.049 0.049
0 20
Mass of AgCI precipitated = 0.049 x 143.3
conc. H,s, co CO,
H,C,O + +
H,O0 7.02 7g
0
7. (a): Mass of 1 mol (6.022 x 1023 atoms) of
20
1 carbon = 12 g
n,=0
20 20 20 If Avogadro number is changed to 6.022 x 1020
Gaseous mixture
atoms then mass of 1 mol of carbon
H.O absorbed by H,SO.
(containing CO and CO,) when passed through 12x6.022x1020
= 12x10 g
KOH pellets, CO, gets absorbed. 6.022 x1023
(c): 1.8 gram of water =6.023x103 x1.8
1
Moles of CO left (unabsorbed)=+ = 8.
20 20 10 18
= 6.023 x 10 molecules
Mass of CO=moles x molar mass = x 28=2.8g
10 18 gram of water = 6.023 x 10 molecules
4 (a): (a) Mass ofwater =Vxd=18x1 =18g 18 moles ofwater 18 x 6.023 x 1023 molecules
18.
Molecules of water = mole x N=NA =NA 9. (d): Number of moles of H =
18
(6) Molecules of water = mole x N, = NN, Number ofmoles of O, =
18 32
1 4
=
102 NA Hence, molar ratio=
0.00224
(c) =10
Moles of water= 22.4 10. (c): According to Avogadros hypothesis,
Molecules of water = mole x N^ = 10 NA ratio of the volumes of gases will be equal to the
(d) Molecules of water = mole x N= 10° N ratio of their no. of moles.
5. (a): Let atomic weight of element X is x Mass
So, no. of moles =
and that of element Y is y. Mol. masSs
W W w
For XY» n 1 ,32 CH 16
10
Mol. wt.
0.1= .>x+2y= =100 ..i) o r 16:1:2.
x+2y 0.1 So,theratiois
W
For X,Y,, n= Mol. wt. 11. (a): l mole = 22.4 litres at S.T.P.
9 9 H, 22.4
4 11.2 = 0.5 mol
422.4 =1 mol; a22.4
0.05 A7 3x+2yn180.(i)
3x +2y 0.05
On solving equations (i) and (i), we get y = 30 Reaction is as,
X+ 2(30) = 1 0 0 x = 100 6 0 4 0 Ha + C 2HC
Initial I mol 0.5 mol
6. (b): 16.9% solution
of AgNO, means 16.9 g Final (1-0.5) (0.5-0.5) 2x0.5
of AgNO, in 100 mL of solution. = 0.5 mol = 0 mol mol
16.9 g of AgNO, in 100 ml solution =8.45 g of mole of HC
Here, Cl, is limiting reagent. So, 1
AgNO, in 50 mL solution. is formed.
Similarly, 5.8 g of NaCl in 100 mL solution
12. (a): nMe==0.0416moles
2.9 gof NaCl in 50 mL solution.
 wtG NEET-AIPMT
Chapterwise Solutions Chemistry
0.56 20. (b): PbO +2HCI
no 32=0.0175 mole
>
PbCl, +H,O
6.5 3.2
mol mo
The balanced equation is 224 36.5
=
0.029 mol 0.087 mol
Mg O MgO
=
2 Formation of moles of lead (1I) chloride
Initial 0.0416 mole 0.0175 mole depends upon the n0. of moles of PbO which
Final (0.0416-2 x0.0175) 0
= 0.0066 mole
2 x 0.0175 acts as a
limiting factor here. So, no. of moles of
PbCl, formed will be equal to the no. of moles
Here, O, is limiting reagent. of PbO i.e. 0.029.
Mass of Mg left in excess 0.0066 x 24 =0.16 g
=
21. (c):
13. (d): Moles urea=6.02 x=0.001
of Element % Atomic Mole Simple
6.02 x1023 mass ratio
Concentration of solution= 0.001
x10001000 =0.01 M
100 C 38.71 12 38.71
0.
12
3.22 3.22
3.22
14. (b): Millimoles of solution of chloride
0.05 x 10 = 0.5
9.67
Millimoles of AgNO, solution = 10 x 0.1 = 1 H 9.67 9.67 9.67 =3
3.22
So, the millimoles of AgNO, are double than
the chloride solution. 3.22
XCl,+ 2AgNO,>2AgCl+X(NO,),
O 51.62 16
51.623.2222
16
15. (c):8 g H, has 4 moles while the others Hence, empirical formula of the compound
has 1 mole each. would be CH,O.
16. (b): No. of atoms = N^ x No. of moles x 3 22. (d): Average isotopic mass of X
= 6.023 x 10 x 0.1 x 3 = 1.806 x 1023
200x90 +199 x8+202 x2
17. (b): Given thatmolarmass of Na,CO =106g 90+8+2
25.3 x1000 18000+1592+ 404
..
Molarity ofsolution = = 0.955 M =199.96 a.m.u. * 200 a.m.u.
106x250 100
NaCO,2Na* +COj
23. (a) At STP, 22.4L = 6.023 x 102 molecules
Na] = 2[Na,CO] = 2x0.955 = 1.910 M
c o ] = [Na,CO,] = 0.955 M
H6.023X10
15 LH,=
22.4
X15-4.033x1023
18. (b): H, +
1/20,>H,O
I mol
28
0.5 mol
16g
1 mol
18 g
5LN
6.023x10 x51.344x10
22.4
10g of H, = 5 mol and 64 g of O, = 2 mol
2gH =6.023 x 1023
I n this reaction, oxygen is the limiting
reagent so amount of H,O produced depends 5.023x104 x0.5
0 . 5 g H, = 1.505 x1023
on that of
O. 2
Since 0.5 mol of O, gives 1 mol H,O 32 g O, 6.023 x 1023
2 mol of
O, will give 4 mol H,O x10x1o
6.023x
19. (a): CH +50,3CO, +4H,O 10 g of O, =
32
-=1.882x1023
vol. 5 vol. 3 vol. 4 vol.
According to the above equation 24. (b): Number of molecules = moles x N
l vol. or 1 litre of
propane requires to 5 vol.
Molecules of N, = NA = 0.5 NA
or litre of O, to burn completely.
5
Some Basic Concepts of Chemistry 1
Molecules of H, =2N 30. (d): No. of molecules in 4.25g NH,
16 4.4 x 6.023
Molecules of NO, = = 0.35 N = x 1023 =2.5 x 6.023x 104
46 17
16
Molecules of O, = = 0.5 N Number of atoms in 4.25 g NH,
32 = 4x 2.5 x 6.023 x 1022 = 6.023 x 1023
2gH, (1g mole H,) contains maximum
31. (d): Zeros placed left to the number are
molecules.
never significant, therefore the no. of significant
25. (a): In peroxidase anhydrous enzyme figures for the numbers.
0.59% Se is present means, 0.5 g Se is present in 161 cm = 0.161 cm and 0.0161 cm are same, i.e.,3
100 g of enzyme. In a molecule of enzyme one 32. (a): Quantity of iron in one molecule
Se atom must be present. Hence, 78.4 g Se will
67200
100 x 0.334 =
224.45 amu
be present in x 78.4 = 1.568 x 10 100
100
0.5
No. of iron atoms in one molecule of haemoglobin
26. (c): Density = 1.17 g/cc.
224.45
1 cc. solution contains 1.17 g of HCl 4
56
1.17x1000 32.05
Molarity36.5x1
27. (a): Specific volume (vol. of 1 g) of
33. (a): 4NHs(+502(4NO(%+ 61,»
4 mole 5 mole 4 mole 6 mole
cylindrical virus particle = 6.02 x 10 cc/g 5
1 mole of NH, requires == 1.25 mole of
Radius ofvirus, r = 7 Ä = 7x 10 cm
Volume of virus = t 1 oxygen while 1 mole of O, requires =
0.8 mole of NH
x(7 x103 x10x10*= 154 10-2
=
x cc
Volume Therefore, all oxygen will be consumed.
wt. of virus
one
particESpecific volume 34. (b): Weight of gas = 0.24 g
Volume ofgas = 45 mL =0.045 litre and density
154x1023
6.02x102 8
of H = 0.089
weight of 45 mL of H, density x = volume
Molecular wt. of virus = wt. of N^ particles = 0.089 x 0.045 4.005 x
10 g
154x10-23 Therefore, vapour density
40x6.02x10g/mol
6.02 x102 Weight of certain volume of substance
Weight of same volume of hydrogen
= 15400 g/mol =15.4 kg/mol
28. (b): BaCO, BaO+ CO 0.24
= 59.93
197.34 g 22.4 L at N.T.P.
4.005x 10
9.85 8 22.4 9.85
197.34 35. (c): Zn + H,SO, > ZnSO, + H,
= 1.118 L 22400 mL
65 g
9.85 g BacO, will produce 1.118L CO, at Since 65 g of zinc reacts to liberate 22400 ml of
N.T.P. on the complete decomposition. at STP, therefore amount of zinc needed
to
H,
29. (b): In A,(BC,). (+2) x 3 + 2[+5 +4(-2)] produce 224 ml of H, at STP
+ 6 +2(-3) = 0 65 x 224=0.65 g
Hence, in the compound A,(BC)2 the 22400
Oxidation no. of 'A, 'B and 'C are +2, +5 and Force
-2 respectively. 36. (b): Pressure =
Area
 8 wbG NEET-AIPMT
Chapterwise Solutions Chemistry
MLT2 44. (a): Here, C,/Cy
Therefore, dimensions of pressure =
=
shows that 14, which
the gas is diatomic.
2 22.4 Lat NTP 6.02x
= MIL 'T 2
11.2 Lat NTP 3.01 x
102 molecules
=
and dimensions of energy per unit volume Since gas is diatomic.
10 molecules
=
Energy MIT-2= 11.2 Lat NTP 6.02 x
MLIT2 10 atom=
Volume 15. (c): CH, + 30, - 2C0, +2H,o
37. (a) Volume of oxygen in one litre of air 28 g 96 g
For complete combustion
21
x1000 210 m 2.8 kg of C,H, requires
100
Therefore, no. ofmol=
210
22400
= 0.0093 mol 968x2.8
28 g kg ofO2 =x2.8
28
96
x10°g
38. (c) Each nitrogen atom has 5 valence
electrons, therefore total number of electrons in
9.6 x
103g= 9.6 kg of O,
46. (a): 1 mol of CO,
N ion is 16. Since the molecular mass of N, is = 44 g of CO,
42, therefore total number of electrons in 4.2 g 4.4g CO%=0.1 mol C0, =6x 10molecules
4.2. [Since, 1 mole CO, =6x 10 molecules
of N ion =
x16xN =1.6 NA =
2x6x 10 atoms of O =1.2 x 10 atoms of O
42
39.
47. (a) : Weight of 1 mol CCl, vapour
(a): 5M H,SO, =10 NH,SO 12 +4
=
x 35.5 =
154g
N,V =N,V10x 1 =N, x 10 »
N, =1N 154
40. (b): Avogadro's No., N = 6.02 x 1023 Density of CCl, vapour =22.48L
molecules
6.875 g L
6.02 x
10 CO molecules 10 moles CO
=
48. (a): Mg* + Na,CO, > MgCO, + 2Na"
= 10 g atoms of O 5 g molecules of O
=
1g eq 1geq.
41. (a): Average atomic mass 1g eq. of Mg*" = 12g of Mg* =12000 mg
19x10+81X1110.81
100
Now, 1000 millieq. of Na, CO, = 12000 mg of Mg*
1 millieq. of Na,C0, 12 mg of Mg* =
42. (): If1 gas Lofone contains Nmolecules, 49. (d): As we know,
2L of any gas under the same conditions will 2400 cc of N,Ocontain 6.02 x 10molecules
contain 2 N molecules. 1 cc ofN,O contain 6.02x103 molecules
43. (d): Z,0, +3H,2Z+3H,0 22400
Valency of metal in Z,0, =3
Since in N,O molecule there are 3 atoms
0.1596 g of Z,O, react with 6 mg of H.
[1 mg = 0.001 g = 10g 1 1 cc
N,0=3*6.02x1045
atoms
22400
1gofH, react with= 0.1596 26.6gofZ,O,
0.006 1 8x1022
atoms
Eq.wt. of Z,0, 26.6 =
224
Now, Eq. wt. of Z + Eq. wt. of O = Eq. wt. of No. of electrons in a molecule of
Z+8 26.6
E q . wt. of Z = 26.6 - 8 18.6
N,O 7 +7+8 2 2
=
6.02 x1023
At. wt. ofZ = 18.6 x 3 = 55.8 x22 electrons
.
Hence, no. ofelectrons=
22400
Atomic wt.
Eq. wt. = 1.32
Valency of metal X105 electrons
224