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Basic Occupational Safety and Health

CONTROL MEASURES FOR OSH HAZARDS Abrasive blasting rooms require 60–100 cfm
ft−2 of floor for downdraft exhaust.
To understand the nature of these hazards, the
occupational health professional must understand • Dust control on abrasive blasting equipment
not only the toxicology of industrial materials but depends to a large degree on the integrity of
also the manufacturing technology that defines how the enclosure.
contaminants are released from the process, the
physical form of the contaminants, and the route of • All units should be inspected periodically,
exposure. including baffle plates at air inlets, gaskets
around doors and windows, gloves and sleeves
Physical stresses including noise, vibration, heat, on cabinets, gaskets at hose inlets, and the
and ionizing and nonionizing radiation must also be major structural seams of the enclosure.
evaluated.
Twelve specific unit operations representing both
large employment and potential health hazards to ACID AND ALKALI CLEANING OF METALS
the worker have been chosen for discussion in this • After the removal of major soils and oils by
chapter; these unit operations occur in many degreasing, metal parts are often treated in acid
different industrial settings. and alkaline baths to condition the parts for
electroplating or other finishes. The principal
hazard in this series of operations is exposure to
acid and alkaline mist released by heating, air
ABRASIVE BLASTING agitation, gassing from electrolytic operation, or
• Abrasive blasting is practiced in a number of cross‐contamination between tanks.
occupational settings, including bridge and •
building construction, shipbuilding and repair, 1. Alkaline Immersion Cleaning
foundries, and metal finishing in a variety of 2. Acid Pickling and Bright Dip
industries. 3. Salt Bath

• The process is used in heavy industry as an


initial cleaning step to remove surface coatings DEGREASING
and scale, rust, or fused sand in preparation for • The principal application of degreasing
finishing operations. technology has been in the metalworking
• Abrasive blasting is used in intermediate industry for the removal of machining oils,
finishing operations to remove flashing, tooling grease, drawing oils, chips, and other soils from
marks, or burrs from cast, welded, or machined metal parts. The technology has expanded
fabrications and to provide a matte finish to greatly prompted by advances in both
enhance bonding of paint or other coatings. degreasing equipment and solvents.

1. Cold Degreasing
 APPLICATION AND HAZARDS 2. Vapor Degreasing

Blasting operations may be performed either in a


variety of enclosures or in open‐air operations such  Types of Vapor-Phase Degreasers and Solvents
as bridge and ship construction. The most obvious o The simplest form of vapor‐phase
health hazard of abrasive blasting operations is degreaser, utilizes only the vapor for
airborne dust contamination. cleaning. The straight vapor‐cycle degreaser
• The minimum exhaust volumes, based on seals is not effective on small, light work because
and curtains in good condition, include 20 air the part reaches the temperature of the
changes per minute for cabinets with a vapor before the condensing action has
minimum of 500 fpm through all baffled inlets. cleaned the part. Also, the straight vapor
cycle does not remove insoluble surface
soils.
o The vapor‐spray cycle degreaser is studies have identified a series of health effects
frequently used. The part to be cleaned is in electroplaters ranging from dermatitis to
first placed in the vapor zone as in the elevated mortality for a series of cancers.
straight vapor‐cycle degreaser.
 Air Contaminants
o A portion of the vapor is condensed by a
cooling coil and fills a liquid solvent o The principal source of air contamination in
reservoir. This warm liquid solvent is electroplating operations is the re- lease of the
pumped to a spray lance, which can be used bath electrolyte to the air by the gassing of the
to direct the solvent on the part, washing bath.
off surface oils and cooling the part, thereby
permitting final cleaning by vapor  CONTROL MEASURES
condensation. • Proprietary bath additives are available to
o A third degreaser design has two reduce the surface tension of the electrolyte
compartments, one with warm liquid and therefore reduce misting. Another additive
solvent and a second compartment with a provides a thick foam that traps the mist
vapor zone. released from the bath. This agent is best used
for tanks that operate continuously. In addition
 CONTROL MEASURES to the proper design and installation of good
• The vapor level in the degreaser is controlled by local exhaust ventilation, one must provide
a nest of water‐fed condensing coils located on adequate replacement air, backflow dampers
the inside perimeter of the tank. on any combustion devices to prevent carbon
monoxide contamination of the work- place,
• In addition, a water jacket positioned on the and suitable air cleaning.
outside of the tank keeps the freeboard cool.
The vertical distance between the lowest point
at which vapors can escape from the degreaser GRINDING, POLISHING, AND BUFFING
machine and the highest normal vapor level is  Processes and Materials
called the freeboard. o Nondimensional application of grinding
• The freeboard should be at least 15 in. and not techniques includes cutoff operations in
less than one‐half to three‐fifths the width of foundries, rough grinding of forgings and
the machine. castings, and grinding out major surface
imperfections in metal fabrications.
• The effluent water from the coils and water Grinding is frequently done with wheels and
jacket should be regulated to 32–49 °C (90–120 disks of various geometries made up of
°F); a temperature indicator or control is selected abrasives in different bonding
desirable. structural matrices.

ELECTROPLATING  EXPOSURES AND CONTROL MEASURES


• The hazard potential from grinding, polishing,
• A number of epidemiologic studies have and buffing operations depends on the specific
identified a series of health effects in operation, the workpiece metal and its surface
electroplaters ranging from dermatitis to coating, and the type of abrasive system in use.
elevated mortality for a series of cancers. A NIOSH‐sponsored study of the ventilation re-
• Metal, plastic, and rubber parts are plated to quirements for grinding, polishing, and buffing
prevent rusting and corrosion, for appearance, operations showed that the major source of
to reduce electrical contact resistance, to airborne particles in grinding and polishing is
provide electrical insulation as a base for the workpiece, whereas the abrasive and the
soldering operations, and to improve wheel textile material represent the principal
wearability. The common plating metals include sources of contamination in buffing (NIOSH
cadmium, chromium, copper, gold, nickel, 1975a).
silver, and zinc. A number of epidemiologic
METAL MACHINING Electrical Discharge Machining (EDM)
• The fabrication of metal parts is done with a o A spark‐gap technique is the basis for the
variety of machine tools, the most common of EDM procedure, which is a popular
which are the lathe, drill press, miller, shaper, machining technique for large precise work
planer, and surface grinder. The occupational such as die sinking or the drilling of small
health hazards from these operations are holes in complex parts. In one system, a
similar; so they are grouped together under graphite tool is machined to the precise size
conventional machining. and shape of the hole to be cut. The
workpiece (anode) and the tool (cathode)
 Conventional Metal Machining
are immersed in a dielectric oil bath and
• The major machining operations of turning, powered by a low‐voltage DC power supply.
milling, and drilling utilize cutting tools that
shear metal from the workpiece as either HEAT TREATING
the workpiece or the tool rotates. A thin • A range of heat treating methods for metal
running coil is formed that normally breaks alloys is available to improve the strength,
at the tool to form small chips. Extremes of impact resistance, hardness, durability, and
temperature and pressure occur at the corrosion resistance of the workpiece
interface between the cutting tool and the (American Society for Metals 1982). Int he most
work. To cool this point, provide an common procedures, metals are hardened by
interface lubricant, and help flush away the heating the workpiece to a high temperature
chips, a coolant or cutting oil is directed on with subsequent rapid cooling. Softening
the cutting tool in a solid stream (flood) or a processes normally involve only heating or
mist. heating with low cooling.

 Health Effects 1. Surface Hardening
• Cutting fluids present two potential health 2. Annealing
problems: extensive skin contact with the 3. Quenching
cutting fluids and the inhalation of
respirable oil mist.
 HAZARD POTENTIAL
 CONTROL MEASURES
• The principal problems in heat treating
• An excellent pamphlet on lubricating and operations are due to the special furnace
coolant oils prepared by Esso out- lines environments, especially carbon monoxide, and
procedures to minimize exposure to cutting the special hazards from handling bath
fluids (Esso Petroleum Company1979). materials.
 Types of Metal Machining • Venting rods need to be inserted in baths
before shutdown and reheating to release gases
Electrochemical Machining (ECM)
when the bath is again brought up to
o The electrochemical machining (ECM) temperature. If this is not done and gas is
process utilizes a DC electrolytic bath occluded in the bath, explosions or blowouts
operating at low‐voltage and high current may occur.
density. The workpiece is the anode; and • Parts must be clean and dry before immersion
the cutting tool, or cathode, is machined to in baths for residual grease, paint, and oil may
reflect the geometry of the hole to be cut in cause explosions. Where sprinkler systems are
the workpiece. used, canopies should be erected above all oil,
o Because the ECM method is fast, produces salt, and metal baths to prevent water from
an excellent surface finish, does not cascading into them.
produce burrs, and produces little tool
wear, it is widely used for cutting irregular‐ • Dilution ventilation for fugitive emissions as well
shaped holes in hard, tough metals. as local exhaust ventilation for baths is often
provided, but specific standards have not been  HAZARDS AND CONTROLS
developed.
• A major hazard common to all techniques is the
• The physical hazards for employees include heat potential exposure to toxic metal fumes. If the
stress from furnace processes and noise from vapor pressure of the metal at the application
mechanical equipment and combustion air. temperature is high, this will be reflected in
Personal protective equipment may include high air concentrations of metal fume. If a toxic
goggles, face shields, heavy gloves and metal is sprayed, air samples should be taken to
gauntlets, reflective clothing, and protective define the worker exposure. The operator
screens should also wear a positive‐pressure air‐-
supplied respirator while metallizing with toxic
metals. One must also consider the exposure of
NONDESTRUCTIVE TESTING other workers in the area, because systems
• With the increase in manufacturing with 50% overspray obviously represent a
technology in the last decade of the significant source of general contamination.
twentieth century, a need has developed
for in‐plant inspection techniques. The most  Paint
common procedures now in use in the • The term paint is commonly used to identify a
metalworking industries are discussed in range of organic coatings including paints,
this section. varnishes, enamels, and lacquers. Conventional
• Radiography is used principally in industry paint is an inorganic pigment dispersed in a
for the examination of metal fabrications vehicle consisting of a binder and a solvent with
such as weldments, castings, and forgings in selected fillers and additives. The conventional
a variety of settings. Specially designed varnish is a nonpigmented product based on oil
shielded cabinets may be located in and natural resin in a solvent that dries first by
manufacturing areas for in process the evaporation of the solvent and then by the
examination of parts. Large components oxidati
may be transported to shielded rooms for • Water‐based paints may require ventilation
examination. Radiography may be only when spray application is utilized on of the
performed in open shop areas, on resin binder.
construction sites, on board ships, and
along pipelines.  CONTROLS
• • Flow application of solvent‐based paints
1. X‐ray Sources requires local exhaust ventilation depending on
2. Gamma Ray Sources the application technique.
• The usual ventilation control for spray
METAL THERMAL SPRAYING
application of solvent‐based paints is a spray
• A practical technique for spraying molten metal booth, room, or tunnel provided with some
was invented in the 1920s and has found type of paint spray mist arrestor before the
application for applying metals, ceramics, and effluent is exhausted outdoors. The degree of
plastic powder to workpieces for corrosion control of paint mist and solvent varies with the
protection, to build up worn or corroded parts, application method, that is, whether it is air
to improve wear resistance, to reduce atomization, airless, or electrostatic painting.
production costs, and as a decorative surface.
In industrial spray painting of parts, the simple
• Different Spraying Methods
instructions contained in several state codes on
1. Combustion Spraying spray painting should be observed:
2. Thermal Arc Spraying • Do not spray toward a person.
• Automate spray booth operations where
3. Plasma Method
possible to reduce exposure.
4. Detonation Method
• Maintain 2‐ft clearance between the sides of fluxes should be evaluated under conditions of
the booth and large flat surfaces to be sprayed. use to determine worker exposure.
• Keep the distance between the nozzle and the • Controls on brazing operations must obviously
part to be sprayed to less than 12 in. be based on the identification of the
• Do not position work so that the operator is composition of the filler rod.
between the exhaust and the spray gun or disk. • Local ventilation control is necessary in
• Locate the drying room so that air does not pass operations where toxic metal fumes may be
over drying objects to exhaust food past the generated from the brazing components or
breathing zone of the operator. from parts plated with cadmium or other toxic
metals. In the use of common fluxes, one
SOLDERING should minimize skin contact owing to their
• Soft soldering is the joining of metal by surface corrosiveness and provide exhaust ventilation
adhesion without melting the base metal. This to control airborne thermal degradation
technique uses a filler metal (solder) with a products released during the brazing operation.
melting point less than 316 °C (600 °F); hard
solder is used in the range of 316–427 °C (600– WELDING
800 °F). These temperature ranges differentiate • Welding is a process for joining metals in which
soldering from brazing, which utilizes a filler coalescence is produced by heating the metals
metal with a melting point greater than 427 °C to a suitable temperature.
(800 °F). • Over a dozen welding procedures are
commonly encountered in industry.
BRAZING • The source of this respirable metal fume is the
• Brazing techniques are widely used in the base metal, the metal coating on the workpiece,
manufacture of refrigerators, electronics, the electrode, and the fluxing agents associated
jewelry, and aerospace components to join both with the particular welding system.
similar and dissimilar metals. • A range of gases and vapors including carbon
• Although the final joint looks similar to a soft monoxide, ozone, and nitrogen dioxide may be
solder bond, it is much stronger, and the joint generated depending on the welding process.
requires little finish. The wavelength and intensity of the
• Brazing is defined as a technique for joining electromagnetic radiation emitted from the arc
metals that are heated above 430 °C (800 °F), depends on the welding procedure, inerting gas,
whereas soldering is conducted below 430 °C. and base metal.
• The temperature of the operation is of major
importance because it determines the vapor
pressure of the metals that are heated and
therefore the concentration of metal fumes to
which the operator is exposed (Handy and
Harman 1985).

 CONTROL MEASURES FOR SOLDERING AND


BRAZING
• The fluxes may represent the most significant
hazard from soldering. The conventional pure
rosin fluxes are not difficult to handle, but
highly activated fluxes warrant special handling
instruction. A range of alcohols, including
methanol, ethanol, and isopropyl alcohol, are
used as volatile vehicles for fluxes. The special

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