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YAKEEN 3.0
Organic Chemistry Topper Assigment

1. Which of the following diseases is not correctly 7. Among the following, the reaction that proceeds
matched with the vitamins mentioned with it? through an electrophilic substitution is
(1) Vitamin B2 - Cracking of lips Cu 2 Cl 2
(1) N 2–Cl Cl + N 2
(2) Vitamin C-Bone deformities
(3) Vitamin D-Osteomalacia AlCl3
(2) + Cl 2 Cl + HCl
(4) Vitamin A -Night blindnesss
Cl Cl
2. Deficiency of vitamin B1 causes the disease UV light
(3) + Cl 2 Cl Cl
(1) Cheilosis
(2) Sterility Cl Cl
(3) Convulsions Heat
(4) CH 2OH + HCl CH2Cl + H 2O
(4) Beri-Beri

3. α-D- glucose and β-D- glucose differ from each other 8. Which of the following undergoes hydrolysis most
due to the difference in one of the carbon atoms, with easily?
respect to its Cl Cl
(1) Number of -OH groups (1) (2)
NO 2
(2) Configuration
NO2
(3) Conformation
Cl Cl
(4) Size of hemiacetal ring (3) (4)
NO2 NO2 NO2 NO2
4. In acidic & alkaline solution amino acids exists as a–
(1) Positive ion & negative ion respectively
9. This question contains, Statement-I (assertion) and
(2) Negative ion & positive ions respectively Statement-II (reason). Select correct option
(3) Neutral in both medium Statement-I: Neopentane forms only one
(4) None of these monochlorinated product.
Statement-II: Neopentane has four identical methyl
5. In DNA, the complimentary bases are group attached to a quaternary carbon.
(1) Adenine and thymine; guanine and uracil (1) Statement-I is True, Statement-II is True;
(2) Adenine and guanine; thymine and cytosine Statement-II is a correct explanation for
(3) Uracil and adenine; cytosine and guanine Statement-I
(4) Adenine and thymine; guanine and cytosine (2) Statement-I is True, Statement-II is True;
Statement-II is NOT a correct explanation for
Statement-I
6. If a native protein is subjected to physical or chemical (3) Statement-I is True, Statement-II is False.
treatment which may disrupt its various forms
(4) Statement-I is False, Statement-II is True.
without affecting its primary structure, are called
(1) Inactive protein
10. When ethyl chloride and n-propyl chloride undergoes
(2) Denatured protein
wurtz reaction which is not obtained
(3) Both of these
(1) n-butane (2) n-pentane
(4) None of these
(3) n-hexane (4) isobutane
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11. In an SN1 reaction, the configuration of the product 17. Correct order of reactivity of CH3CHO, C2H5COCH3
undergoes: and CH3COCH3 with HCN is:
(1) Inversion (1) CH3CHO > CH3COCH3 > CH3COC2H5
(2) Racemization
(3) Retention (2) C2H5COCH3 > CH3COCH3 > CH3CHO
(4) None of these (3) CH3COCH3 > CH3CHO > C2H5COCH3
(4) CH3COCH3 > C2H5COCH3 > CH3CHO
12. Which of the following is used as a solvent in the
Friedel-Crafts reaction:
18. A mixture of benzoic acid and phenol may be
(1) Toluene
(2) Nitrobenzene separate by treatment with
(3) Benzene (1) NaHCO3 (2) NaOH
(4) Aniline (3) NH3 solution (4) KOH

13. The final product of the following reaction sequence CH2OH

is(are) O LiAlH 4
19. Product.
H OH
CH2OH
In the given reaction the product is.
(1) An optically inactive mixture of two compounds
(2) An optically active mixture of two compounds
Br Br (3) An optically inactive mixture of three
compounds
(1) (2) (4) An optically active mixture of three compounds
Br
Br 20. Correct reactivity order towards nucleophilic
Br Br
addition is
Br Br Br Br
(3) (4) O O

Br
(a) (b)
OCH3
14. Which one of the following is the strongest base in NO 2
aqueous medium? O O
(1) (C2H5)3N (2) C2H5NH2
(3) NH3 (4) (C2H5)2NH (c) (d)
CH3
(1) b > a > d > c (2) a > b > d > c
15. Amines are basic in character because they have (3) b > d > c > a (4) b > d > a > c
(1) A lone pair of electrons on the nitrogen atom
(2) A hydroxyl group in the molecule 21. 3-Butenoic acid (for But-3-enoic acid) is represented
(3) Replaceable hydrogen atom as
(4) Saturated C atom O O

(1) OH (2) OH
16. C3H9N cannot represent O
(1) 1° amine (2) 2° amine
(3) OH (4) None of these
(3) 3° amine (4) Quaternary salt
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22. Arrange the following in the acidic strength order: 30. Which of the following is most stable?
(a) NO2CH2COOH (b) NC–CH2COOH (1) 2, 3-Dimethyl-2-butene
(c) CCl3COOH (d) CHCl2COOH (2) 2-Butene
(1) a > b > c > d (2) c > d > a > b (3) 2-Methyl-l-butene
(3) b > a > d > c (4) c > a > b > d
(4) 1-Butene
23. What does this exhibit?
H 3C H 31. Halogenation of benzene in presence of AlCl3 (anhy.)
C=C H is
H 3C C
H 3C COOH (1) Nucleophilic substitution
(1) Tautomerism (2) Nucleophilic addition
(2) Optical isomerism (3) Electrophilic substitution
(3) Geometrical isomerism
(4) Free radical substitution
(4) Geometrical and optical isomerism

24. Which of the following is not an electrophile? 32. Acetic acid on heating with urea gives:
 (1) Acetamide, carbon dioxide and ammonia
(1) CH3 (2) AlCl3 (2) Ammonium carbonate and carbon
  
(3) Ammonium acetate, acetamide and carbon
(3) SiF4 (4) (CH3 ) 4 N  O H

  dioxide
(4) None of the above
25. In allene (C3H4), the type(s) of hybridisation of the
carbon atoms is (are) 33. Oxalic acid on treatment with cone. H2SO4 gives:
(1) sp and sp3 (2) sp and sp2 (1) CO + H2O2
2
(3) only sp (4) sp2 and sp3 (2) HCOOH + CO2
(3) H2O + CO + CO2
26. Due to the presence of an unpaired electron, free
radicals are (4) HCOOH + CO2 + O2
(1) Chemically inactive
(2) Chemically reactive 34. The compound A, B and C in the reaction sequence
(3) Cations CH3CH 2 OH 
PBr3
A 
alc. KOH
 B 
Br2
C
A
(4) Anions
(1) C2H5Br, CH3CH2OH, CH3CHBr2.
27. The correct order of reactivity of alkene towards an (2) C2H5Br, CH ≡ CH, CH2 = CHBr
electrophile is mentioned in (3) C2H5Br, CH2 = CH2, CH2Br–CH2Br
(1) CH2 = CH – Cl > CH2 = CH – OCH3 (4) C2H5Br, CH3CH2OH, BrCH2–CH2Br
(2) CH2 = CHCl < CH2 = CCl2
(3) CH2 = CH2 > CH3 – CH = CH2 35. Consider the following compounds:
(4) CH2 = CH – OCH3 > CH2 = CH – CH2 – OH
(i)
28. Which one is most stable?
(1) Cyclopropane (2) Cyclobutane (ii)
(3) Cyclopentane (4) Cyclohexane

29. Which of the following give positive Tollens test? (iii)

(1) CH3–CH3 (2) CH2=CH2
(3) CH ≡ CH (4) (iv)
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The correct order of reactivity towards hydrolysis is:-

(1) (i) > (ii) > (iii) > (iv)
(2) (iv) > (ii) > (i) > (iii)
(3) (ii) > (iv) > (i) > (iii)
(4) (ii) > (iv) > (iii) > (i)
36. In a set of reaction, ethyl benzene yielded a product
D.
38.
The compound with the above configuration is
called:
(1) (2S, 3S) – 2 – chloro – 3 – hydroxypentane
(2) (2S, 3R) – 2 – chloro – 3 – hydroxypentane
(3) (2R, 3R) – 2 – chloro – 3 – hydroxypentane
(4) (2R, 3S) – 2 – chloro – 3 – hydroxypentane

39. Chlorobenzene reacts with Mg in dry ether to give a

compound (A) which further reacts with ethanol to
yield:
‘D’ would be:- (1) Phenol (2) Benzene
(3) Ethyl benzene (4) Phenyl ether

(1) 40. Which of the following can be used as the halide

component for Friedel-Crafts reaction?
(1) Chlorobenzene (2) Bromobenzene
(3) Chloroethene (4) Isopropyl chloride
(2)
41. Assertion: The formula of propanenitrile is C3H7CN
Reason: Number of carbon atoms in propanenitrile
is 4.
(1) Both Assertion and Reason are true and the
(3) Reason is the correct explanation of the
Assertion.
(2) Both Assertion and Reason are true but the
Reason is not the correct explanation of the
Assertion.
(3) Assertion is true statement but Reason is false.
(4) Both Assertion and Reason are false statements.
(4)
42. Assertion: The IUPAC name for is
propanone.
37. Which of the following compound are meso forms? Reason: The prefix oxo is used for > C = O group.
(1) Both Assertion and Reason are true and the
Reason is the correct explanation of the
Assertion.
(2) Both Assertion and Reason are true but the
Reason is not the correct explanation of the
Assertion.
(1) 1 only (2) 3 only (3) Assertion is true statement but Reason is false.
(3) 1 and 2 (4) 2 and 3 (4) Both Assertion and Reason are false statements.

43. Assertion: Diastereomers are not mirror image of
each other.
Reason: Diastereomers may be optically active.
(1) Both assertion and reason are correct and reason
is a correct explanation for assertion
(2) Both assertion and reason are correct and reason
is not a correct explanation for assertion
(3) Assertion is correct, Reason is incorrect
(4) Both assertion and reason are incorrect
44. Assertion: Halogen is deactivating group due to –I
effect.
Reason: Halogen is ortho-para directing due to + M
effect.
(1) Both (A) and (R) are wrong statements.
(2) Both (A) and (R) are correct statements and (R)
is correct explanation of (A).
(3) Both (A) and (R) are correct statements but (R)
is not the correct explanation of (A).
(4) (A) is a correct statement but (R) is a wrong
statement.
45. Assertion: Wurtz reaction is used for the preparation
of symmetrical alkanes
Reason: Wurtz reaction occurs by the reaction of
alkyl halides with sodium metal.
(1) Both (A) and (R) are wrong statements.
(2) Both (A) and (R) are correct statements and (R)
is correct explanation of (A).
(3) Both (A) and (R) are correct statements but (R)
is not the correct explanation of (A).
(4) (A) is a correct statement but (R) is a wrong
statement.
46. Given below are two statements:
Statement-I: Maltose has two α-D-glucose units
linked at C1 and C4 and is a reducing sugar.
Statement-II: Maltose has two monosaccharide
units.
α-D-glucose and β-D-glucose linked at C1 and C6 and
it is a non-reducing sugar.
In the light of the above statements, choose the
correct answer from the options given below.
(1) Both Statement-I and Statement-II are true.
(2) Both Statement-I and Statement-II are false.
(3) Statement-I is true but Statement-II is false.
(4) Statement-I is false but Statement-II is true.
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47. Statement I: Water insoluble component of starch is
Amylopectin.
Statement II: In cellulose, D-glucose units are
joined by α-1, 4-glycosidic linkage.
(1) Both statement I and II are correct.
(2) Statement I is correct but statement II is
incorrect.
(3) Statement I is incorrect but statement II is
correct.
(4) Both statement I and II are incorrect
48. Statement-I: With HI, anisole gives methyl phenyl
oxonium ion as intermediate.
Statement-II: The attack of I– on methyl phenyl
oxonium ion produces methanol and phenyl iodide.
(1) Statement-I is correct, statement-II is also
correct.
(2) Statement-I is correct, statement-II is incorrect.
(3) Statcmcnt-I is incorrect, statement-II is correct.
(4) Both statements-I and II are incorrect.
49. Statement-I: Ethers behave as bases in the presence
of mineral acids.
Statement-II: Ethers have lone pairs of electrons on
oxygen.
(1) Both Statement I and Statement II are true.
(2) Statement I is true but Statement II is false.
(3) Statement I is false but Statement II is true.
(4) Both Statement I and Statement II are False.
50. Statement-I: Best method for the conversion of
ethanol to ethanal is by passing ethanol vapours over
Cu at 578 K.
Statement-II: Oxidation of ethanol with acidic
KMnO4 gives ethanal as product.
(1) Both statement I and II are correct
(2) Statement I is correct but statement II is
incorrect
(3) Statement I is incorrect but statement II is
correct
(4) Both statement I and II are incorrect
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Answer Key
1. (2) 11. (2) 21. (1) 31. (3) 41. (4)
2. (4) 12. (2) 22. (1) 32. (1) 42. (2)
3. (2) 13. (2) 23. (2) 33. (3) 43. (2)
4. (1) 14. (4) 24. (4) 34. (3) 44. (3)
5. (4) 15. (1) 25. (2) 35. (3) 45. (3)
6. (2) 16. (4) 26. (2) 36. (1) 46. (3)
7. (2) 17. (1) 27. (4) 37. (2) 47. (2)
8. (4) 18. (1) 28. (4) 38. (1) 48. (2)
9. (1) 19. (2) 29. (3) 39. (2) 49. (1)
10. (4) 20. (3) 30. (1) 40. (4) 50. (2)

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