Appendix E ANSWERS

This section includes answers to section questions and questions in Chapter and
Unit Reviews that require calculation.

Unit 1 Organic Chemistry 9. False Activity 3.4.2 The Hydrogen 19. (b)
Chapter 1 Organic Compounds 10. True Line Spectrum and the Bohr 10. (d)
11. (d) Theory
Section 1.3 Questions Unit 2 Self-Quiz
12. (e) (a) 410 nm, 434 nm, 486 nm, and
5. 17% greater 1. False
13. (b) 655 nm
2. True
Section 1.6 Questions 14. (e) (b) 656 nm
3. True
10. 0.003 mol/L 15. (d) For H ni = 4, nf = 2, wave-
4. True
16. (c) length = 486 nm
Lab Exercise 1.3.1: 5. False
17. (c) For H ni = 5, nf = 2, wave-
Preparation of Ethyne 6. False
18. (d) length = 434 nm
(c) 0.050 mol Ca(OH)2 7. True
19. (d) For H ni = 6, nf = 2, wave-
(d) 1.30 g 8. False
20. (a) length = 410 nm
(e) 47.2% 9. True
21. (c)
22. (d) Chapter 3 Self-Quiz 10. True
Chapter 1 Self-Quiz 1. False 11. False
23. (c)
1. False 2. False 12. True
24. (b)
2. False 3. False 13. False
25. (e)
3. True 4. True 14. False
26. (e)
4. False 5. True 15. True
5. True Unit 1 Review 6. False 16. True
6. (b) 28. theoretical yield: 47.6 g; per- 7. False 17. True
7. (b) cent yield: 73.9% 8. True 18. False
8. (a) 9. True 19. True
9. (e) Unit 2 Structure and Properties 20. (e)
10. True
10. (b) Are You Ready? 21. (b)
11. False
11. (c) 6. hydrogen atom: 1,1,0 22. (c)
12. (b)
12. (e) sodium atom: 11, 11, 0 23. (a)
13. (d)
13. (c) chlorine atom: 17, 17, 0 24. (a)
14. (a)
14. (e) hydrogen ion: 1, 0, 1+ 25. (a)
15. (c)
15. (c) sodium ion: 11, 10, 1+ 26. (c)
16. (c)
chloride ion: 17, 18, 1– 27. (d)
17. (b)
Chapter 1 Review
Chapter 3 Atomic Theories 18. (e) 28. (b)
15. (b) 87.0%
Section 3.3 Questions 19. (d) 29. (d)
Chapter 2 Polymers – Plastics, 6. (a) 3.6 ! 10–19 J 30. (b)
Chapter Review 31. (e)
Nylons, and Food (b) 3.6 ! 10–19 J
16. (a) 2 32. (a)
7. (a) UV: 9.9 ! 10–19 J; IR:
Chapter 2 Self-Quiz (b) 8 33. (b)
2.2 ! 10–19 J
1. False (c) 18 34. (c)
(b) 4.5:1
2. True. (d) 32 35. (e)
3. True. Section 3.4 Questions 36. (c)
Chapter 4 Chemical Bonding
4. False 13. (a) 485 nm. 37. (b)
Chapter 4 Self-Quiz
5. False (b) 6.19 ! 1014 Hz 38. (c)
1. False
6. (d) (c) 4.1 ! 10–19 J 39. (a)
2. True
7. (d) (d) 654 nm; 4.59 ! 1014 Hz; 40. (d)
3. False
8. (b) 3.0 ! 10–19 J
4. False Unit 2 Review
9. (e) (e) 1.1 ! 10–19 J
5. False 34. (b) 7.8%
10. (c)
Section 3.6 Questions 6. False 43. red – 4.29 ! 1014 Hz; blue –
11. (d)
1. (a) 2 7. True 7.50 ! 1014 Hz
12 (b)
(b) 8 8. False 44. highest – 4.97 ! 10–19 J; low-
13. (b)
(c) 18 9. False est – 2.84 ! 10–19 J
14. (e)
(d) 32 10. True 46. UV – 6.63 ! 10–19 J; orange –
15. (c)
2. (a) 1; 2 11. (e) 3.32 ! 10–19 J
Unit I Self-Quiz (b) 3; 6 12. (b)
1. False (c) 5; 10 13. (d) Unit 3 Energy Changes and
2. True (d) 7; 14 14. (a) Rates of Reaction
3. False 15. (c) Are You Ready?
4. False 16. (e) 4. (c) 12540 J or 12 kJ
5. False 17. (c) 8. (b) 2.5 mol NaHCO3/min
6. True 18. (a) (c) 10 mol
7. False (d) 2.5 mol CO2/min
8. False

816 Appendix E NEL

 Appendix E

Chapter 5 Thermochemistry 14. –264 kJ 3. False 7. (a) 26

Section 5.2 Questions 15. –388.3 kJ/mol 4. True (b) 0.28
1. (a) 7.8 MJ 16. (c) – 55 kJ 5. False (c) 0.52 or –1.7
(b) 2.08 MJ (d) +19 kJ 6. True
Chapter 7 Chemical Systems in
2. 12°C 18. (a) –44 kJ 7. True
Equilibrium
3. 1.50 g (b) –285.5 kJ/mol 8. False
Section 7.1 Questions
4. 242 kJ (c) – 1.7 ! 109 kJ 9. False
(d) ∆Hcondenstion: 0.4 cm; 3. (a) 2.00 mol
10. True
Section 5.3 Questions ∆H°f(H O ): 3 cm; 11. (b) (b) 70.0%
4. (a) –11.0 MJ/mol 2 (l) 4. (a) [C2H4] = 2.50 mol/L;
∆Hfusion: 1000 km 12. (c)
(d) 17% [Br2] = 1.00 mol/L;
13. (e)
Chapter 6 Chemical Kinetics [C2H4Br2] = 1.50 mol/L
Section 5.4 Questions 14. (a)
Section 6.1 Questions (c) 60.0%
1. (b) –247.5 kJ 15. (e)
1. (a) 1.2 mol/(L•s) 7. (a) 0.0 mol HI; 8.0 mol I2;
2. –78.5 kJ 16. (c)
(b) 2.5 mol/(L•s) 12.0 mol H2
3. 492 kJ 17. (b)
(c) 1.2 mol/(L•s) (b) 14 mol HI
4. (b) Experiment 1:–20.9 kJ; 18. (d)
(d) 2.5 mol/(L•s) (c) 88%
Experiment 2: –34.3 kJ; 19. (b)
8. [PCl5] = 0.90 mol/L;
Experiment 3: –56.0 kJ/mol Section 6.3 Questions 20. (e)
[Cl2] = 0.10 mol/L
(c) 1.4 % 2. (a) 1 with respect to Cl2(g); 2 21. (b)
9. (a) [CO] = 0.0600 mol/L;
with respect to NO(g) 22. (a)
Section 5.5 Questions [CH3OH] = 0.0400 mol/L
(b) ! 2 23. (c)
(b) 40.0%
2. (a) 100.7 kJ
(b) –1411 kJ
(c) ! 9
(d) 3.0 L/(mol• s)
24.
25.
(c)
(e)
E
(c) –5640 kJ (e) 8.2(5) ! 10"4 mol/(L•s) 26. (c) Section 7.2 Questions
3. (b) –96.6 kJ 3. (b) 0.495 a 27. (b)
4. (a) –1.79 MJ/mol acetone 28. (d) 2. 49.70
(c) 2.5 g
(b) –1.5 MJ/mol acetone 29. (c) 3. 0.46
4. (a) 0.039 g
(c) 16% 30. (d) 4. 3.9 ! 10–4 mol/L
Section 6.4 Questions 6. (c) 0.200 mol
Lab Exercise 5.5.1 Testing 3. (a) 60 kJ Unit 3 Review (d) 0.800 mol HBr
Enthalpies of Formation (b) –35 kJ 1. 340 kJ (e) 0.400 mol H2, 0.400 mol
(a) – 726 kJ 2. 657 kJ Br2
(b) –597 kJ/mol Lab Exercise 6.1.1
3. (a) –5.57 kJ/mol (f) 0.200 mol/L
(c) 18% (c) (i) 0.4 mol/(Lmin)
5. (c) 44.6 kJ (g) 4.00
(ii) 0.075 mol/(Lmin)
6. –2572.4 kJ
Chapter 5 Self-Quiz (d) (i) 0.41 mol/(Lmin) Section 7.5 Questions
7. (b) –3536.3 kJ
1. False (ii) 0.075 mol/(Lmin) 2. 1.5
(c) 982 kJ
2. False 3. (a) [HBr] = 0.78 mol/L;
Chapter 6 Self-Quiz 9. (b) 0.130 mol/L
3. True [H2] = [Br2] = 0.011 mol/L
1. False 11. (b) 0.80; 1.30; 1.80; 2.20
4. False (b) 0.39 mol HBr, 0.055 mol
2. True (c) (i) 0.092 mol/(L•h)
5. True H2, 0.055 mol Br2
3. False (ii) 0.18 mol/(L•h)
6. True (c) 78%
4. True (iii) 0.046 mol/(L•h)
7. False 4. [H2] = 0.010 mol/L; [I2] =
5. True (d) 0.14 mol/(L•h);
8. True 0.31 mol/L; [HI] = 0.38
6. False 0.058 mol/(L•h)
9. False mol/L
7. True 14. (b) 2.0 ! 10"2 mol/(L•s) for
10. True 5. [NO2] = 1.66 mol/L
8. True [O2(g)]; 1.2 ! 10"2 mol/(L•s)
11. (c) 6. (a) [HCl] = 0.38 mol/L;
9. False for [CO2(g)]
12. (b) [H2] = [Cl2] = 1.81 mol/L
10. False 20. (a) –1.96 MJ/mol
13. (e) (b) 0.285 mol HCl; 1.36 mol
11. (b) 21. (a) –104 kJ/mol
14. (c) H2; 1.36 mol Cl2
12. (e) 22. (a) –125.7 kJ/mol
15. (c) (c) 9.50%
13. (d) 27. (b) efficient –5470 kJ;
16. (c) 7. [CO] = [Cl2] = 0.25 mol/L
14. (c) non-efficient –3942 kJ
17. (d) 8. [PCl5] = 0.199 mol/L; [Cl2]
15. (a) (c) 28%
18. (a) = [PCl3] = 0.480 mol/L
16. (b) (d) 3.7 ! 102 g
Chapter 5 Review 17. (d) (e) 6.1 ! 102 g Section 7.6 Questions
2. 1.10 J/(g•°C) 18. (b) 4. 1.0 ! 10–5 mol/L
Unit 4 Chemical Systems and
4. 170 kJ 5. 1.4 ! 10–5 g/100 mL
Chapter 6 Review Equilibrium
5. 547 g 6. 2.0 ! 10–3 mol/L
3. 80 mL/s Are You Ready?
9. (c) –253.9 kJ 7. 1.0 ! 10–2
5. (a) 1.47 mL/s (page 420)
10. 206 kJ 8. 3.4 ! 10–11
7. (c) 18 L2/(mol2•s) 2. (b) 0.1 mol MgCl2
11. 25.7 g 9. 1.7 ! 10–4 g
(d) 0.65 mol/(L•s) (c) 0.4 mol/L
12. –117 kJ 10 (a) 6.0 ! 10–4
8. (b) 6.25% 4. –1923.7 kJ/mol
13. (a) 382.8 kJ/mol NH3 (b) 2.8 ! 10–11
5. (b) 0.027 mol/L
(b) 2.25 ! 104 kJ Unit 3 Self-Quiz (c) 5.6 ! 10–9
6. (g) 15.00 mL NaOH
(c) 6.25 m2 1. False 11. 8.5 ! 10–7 mol/L
(h) 7
2. True
(j) 1.0 ! 10–7 mol/L

NEL Answers 817

 12. (a) 1.4 ! 10–3 mol 10. (b) atropine 11.25; mor- Unit 4 Self-Quiz 24. –7.7 kJ
(b) 1.4 ! 10–2 mol/L phine 10.45; erythromycin 1. False 25. –801.2 kJ
(c) 1.2 ! 10–5 10.90 2. True 26. 348 K
13. (a) 2.5 ! 10–3 mol 11. 7.7 ! 10–10 3. True 29. 40:1
(b) 5.0 ! 10–3 mol 12. 1.4 ! 10–11 4. False 30. [H+(aq)] = 2 ! 10–3 mol/L;
[OH" –12 mol/L
(c) 5.0 ! 10–2 mol/L 13. 10.27 5. False (aq)] = 5 ! 10
(d) 2.5 ! 10–3 15 (b) NH3 1.7 ! 10–5; HS– 9.1 6. False 31. 3.5 ! 10–6
! 10–8; SO42– 1.0 ! 10–12 7. True 34. 4.27
Section 7.7 Questions 16. 1.6 ! 10–6 8. True 38. (b) 12.58
11. (a) –207.5 kJ 17. 11.124 9. False 43. (a) 7.000
(b) +803.8 kJ 18. 8.46 10. False (b) 1.000
12. 300°C 21. (a) 4.2 ! 10–10 11. False (c) 1.477
13. (b) #H° = –176.2 kJ; #S° = 23. (a) 3.20 12. False (e) 7.000
–284.8 J/K•mol ; #G° = 13. False (f) 12.301
–91.3 kJ Section 8.4 Questions
14. False 44. (a) 1.000
14. (a) –1314.4 kJ 7. (a) 2.600
15. True (b) 1.477
19. (a) 387 K (b) 4.025
16. True (c) 3.601
(c) 10.450
Chapter 7 Self-Quiz 17. False (d) 4.602
9. (a) (i) 5.206
1. False 18. False (e) 9.400
(ii) 8.883
2. True 19. False (f) 12.046
(iii) 4.283
3. False 20. True 52. 0.62 decrease
10. 12.25
4. True 21. False 53. (a) 8.0 ! 10–4 mol
5. False Section 8.5 Questions 22. True (b) 0.016 mol/L
6. False 9. 61 increase 23. (b) (c) 0.032 mol/L
7. False 24. (b) (d) 0.016 mol/L
Chapter 8 Self-Quiz 25. (e) (f) 1.6 ! 10–5
8. True
1. False 26. (b) 54. (a) 1.740 ! 10–4 mol
9. True
2. False 27. (b) (b) 0.38 g
10. True
3. True 28. (c) (c) 84 %
11. (e)
4. True 29. (b) 55. (a) 0.185 mol/L
12. (a)
5. False 30. (e) 58. (a) pOH = 0.0969; pH =
13. (c)
6. False 31. (c) 13.903
14. (b)
7. False 32. (c) 62. (a) 7.1 ! 10–5 mol/L
15. (d)
8. False 33. (d) (b) 350
16. (a)
9. True 34. (c) 64. (a) 7.1 ! 10–5 mol/L
17. (a)
10. (b) 35. (e) (b) 352
18. (a)
11. (b) 36. (c)
19. (c) Unit 5 Electrochemistry
12. (e) 37. (b)
20. (e) Chapter 9 Electric Cells
13. (a) 38. (b)
Chapter 7 Review 14. (b) 39. (d) Section 9.2 Questions
10. (b) 2.9 ! 10–3 mol/L 15. (c) 40. (d) 7. 75.5 mmol/L
15. (a) [H2] = 1.46 mol/L; 16. (e) 41. (e)
[Br2] = 1.46 mol/L; [HBr] = 17. (a) Section 9.5 Questions
5.07 mol/L 18. (b) Unit 4 Review 6. +0.48 V
(b) [H2] = 2.20 mol/L; [Br2] 19. (a) 1. 3.58 ! 10–3 7. (a) +1.10 V
= 2.20 mol/L; [HBr] = 2. 1.7 ! 10–3 (b) +1.37
Chapter 8 Review 6. (a) 1.3 ! 10–5 mol/L
2.61 mol/L 8. –0.28 V
1. 0.372 (b) 1.2 ! 10–8 mol/L
(c) [H2] = 3.00 mol/L; [Br2]
2. (a) pH = 0.0161; pOH = 8. 7.91 mol/L Chapter 9 Self-Quiz
= 1.00 mol/L; [HBr] =
13.984 10. (a) [H2] = [CO2] = 0.044 1. True
6.00 mol/L
4. [H+(aq)] = [F"
(aq)] = mol/L; [H2O] = [CO] = 2. False
17. 1.61 ! 10–10
3.6 ! 10–2 0.056 mol/L 3. True
18. 4.8 ! 10–5 mol/L
5. [H+(aq)] = 4.0 ! 10–8; pH = (b) 1.6 4. False
Chapter 8 Acid–Base 7.40 11. (a) [PCl5] = 0.040 mol/L; 5. False
Equilibrium 6. pH = 2.421; pOH = 11.579 [PCl3] = [Cl2] = 0.26 mol/L 6. True
7. (a) 2.644 (b) 1.7 7. False
Section 8.1 Questions 8. (b) [H+(aq)] = 7.9 ! 10–6; 8. True
12. [H2] = [I2] = 0.0221 mol/L;
4. 0.018 g pH = 5.10 9. True
[HI] = 0.156 mol/L
Section 8.2 Questions 9. 1.3 ! 10–10 13. [NH3] = 0.14 mol/L; [N2] = 10. (a)
2. 11.23 14. 0.537 mol/L 0.032 mol/L; [H2] = 0.097 11. (d)
3. 6 ! 10–3% 15. (a) 5.27 mol/L 12. (c)
4. 6.3 ! 10–5 (b) 11.12 14. 0.375 mol/L 13. (a)
5. 7 ! 10–4 (c) 9.26 15. 3.255 ! 10–3 mol/L 14. (b)
6. 4.65 (e) 5.27 16. 8.4 ! 10–3 mol/L 15. (d)
(f) 1.70 17. 0.029 mol/L 16. (c)
25. 1.79 17. (e)
18. (b)

818 Appendix E NEL

 Appendix E

Chapter 9 Review 16. 20.1 min

17. 1.03 kmol/h
Appendix D (b) 1.28 mol/L
(c) 0.640 mol/L
14. (a) +0.71 V
Chemistry 11 Review
(b) +0.62 V 18. (a) 1.8 A 8. 4.98 ! 10"3 mol
Unit 2 Quantities in Chemical
15. (a) +0.48 V (b) 2% 9. 4.69 g
Reactions
(b) +0.48 V 10. 0.348 mol/L
Unit 5 Self-Quiz 1. (a) 28.02 g/mol
(c) +1.77 V 11. 24.2 mL
1. True (b) 114.26 g/mol
16. (b) +0.14 V 12. (a) 1.00 ! 103 g
2. False (c) 32.00 g/mol
18. +1.54 V (b) 55.5 mol
3. False (d) 182.71 g/mol
22. (c) +0.47 V (c) 55.5 mol/L
4. True. (e) 187.42 g/mol
25. (a) +0.23 V 14. (c) 0.381 g
5. False (f) 285.75 g/mol
15. (b) 0.11 mol/L
Chapter 10 Electrolytic Cells 6. True (g) 4.00 g/mol
17. (a) 2
Section 10.1 Questions 7. True (h) 80.06 g/mol
(b) 10.35
5. (a) ∆E° = –0.50 V 8. False (i) 17.04 g/mol
(c) 2.26
(b) ∆E° = –0.03 V 9. True (j) 36.46 g/mol
(d) 9.14
(c) ∆E° = –0.47 V 10. False 2. (a) 6 mol
18. (a) 1.0 ! 10"5 mol/L
6. (a) 0.43 V 11. False (b) Fe: 2 mol; N: 3 mol; O: 9
(b) 8 ! 10"3 mol/L
(b) 0.29 V 12. True mol
(c) 1.6 ! 10"10 mol/L
7. (a) –1.30 V 13. False (c) K: 9 mol; Cr 9 mol; O:
(d) 1.0 ! 10"7 mol/L
14. True 31.5 mol
Section 10.3 Questions 22. 0.146 mol/L
15. True (d) 3 mol
1. 2.80 mmol 23. 0.0105 mol/L
16. True (e) N: 10 mo; H: 40 mol; S: 5
2. 0.58 Mg or 0.58 t
3. 82.8 min
17. False mol; O: 20 mol
24.
25.
0.0775 mol/L
0.112 mol/L
E
18. False 3. (a) 146 g
4. 52.8 kA 26. 32.4 mL
19. (b) (b) 45.0 g
5. (a) 1.63 Mg or 1.63 t 27. 0.180 mol/L
20. (e) (c) 216 mg
(b) 4.76 Mg or 4.76 t 21. (c) (d) 126 g Unit 4 Gases and Atmospheric
6. 0.174 mol/L 22. (c) (e) 0.803 g Chemistry
7. 24.42 g 23. (d) 4. (a) 0.555 mol 1. 2.39 L
Chapter 10 Self-Quiz 24. (e) (b) 14.7 mol 2. 1.78 L
1. True 25. (b) (c) 1.43 ! 10"5 mol 3. 180 kPa
2. False 26. (d) (d) 5.94 ! 10"6 mol 4. 3.25 L
3. False 27. (a) (e) 16.6 mol 5. 6.98 L
4. True 28. (d) 5. (a) H: 2.06%; S: 32.69%; O: 6. 82.6 L
5. True 29. (e) 65.25% 7. 186 kPa
6. True 30. (b) (b) Ag: 63.498%; N 8.247%; 8. 0.092 mol
7. False 31. (c) O: 28.26% 9. 2660 L
8. (e) 32. (a) (c) N: 35.00%; H: 5.05%; O: 10. 27.96 g/mol
9. (a) 33. (c) 59.96% 11. 1.3 g
10. (b) 34. (d) 10. (a) 7.5 mol 12. (a) 25.0 L
11. (d) 35. (a) (b) 12.5 mol (b) 50.0 L
12. (b) 36. (b) 11. (b) 5.144 g 13. 95.6 kPa
13. (e) (c) 2.04 g 14. 0.732 g
Unit 5 Review 12. (b) 250.3 g.
14. (c) 15. (b) 981 L
3. (a) –2 (c) 189.0 g
15. (a) (b) +4 Unit 5 Hydrocarbons and
16. (d) 13. (c) 14.4 g
(c) +6 (d) 15.8 g Energy
Chapter 10 Review (d) +4 15. (d) 132.9 g 7. 376 kJ
4. (a) 1.22 V (e) 0 16. (a) 945 g. 8. 1.06 ! 103 kJ
(b) 0.80 V 4. (a) Sn +4; Co 0; Sn 2+; Co +2 (b) 762.3 g 9. (b) 2.3 kJ/g
(c) 0.00 V (b) Fe +3; Zn 0; Fe +2; Zn +2 17. (a) 8.82 g. (c) 140 kJ/mol
5. (a) 1.90 V (c) Cl 0; I "1; Cl "1; I 0 (b) 1.44 g 10. (b) 728 kJ/mol
(b) 1.23 V (d) C +3; O "2; Mn +7; O 18. (a) 25.98 g
(c) 1.51 V "2; H +1; C +4; O "2; (b) 68.98%
6. (b) 1.23 V Mn +2; H +1; O "2 19. (a) 0.259 g
10. (b) 2.19 V (e) Cl 0; S +4; O "2; O "2; (b) 73%
11. (c) 0.889 g H +1; Cl "1; S +6; O "2
12. Al: 0.629 g; Ni: 2.05 g; H +1, O "2 Unit 3 Solutions and Solubility
Ag: 7.54 g 2. (a) 0.696 mol/L
13. (a) 7.42 ! 103 s (b) 2.00 mol/L
(b) 4.05 ! 103 s (c) 0.664 mol/L
(c) 4.34 ! 103 s 3. 0.25 L
14. (a) 1.99 V 4. 6.4 g
(b) 590 s 5. 119 g
15. 2.98 kA 6. 0.390 mol/L
7. (a) 0.640 mol/L

NEL Answers 819