Electroquímica fuera del

equilibrio
Pulso de Potencial
Arbitrary Potential Pulses
Cottrell Equation

What happens when diffusion limitation is not reached?

Arbitrary Potential Pulses
Arbitrary Potential Pulses
Arbitrary Potential Pulses
Arbitrary Potential Pulses
Sampled Current Voltammetry
Sampled Current Voltammetry (SCV)
Sampled Current Voltammetry (SCV)
Sampled Current Voltammetry (SCV)
Sampled Current Voltammetry (SCV)

Half-wave potential
Sampled Current Voltammetry (SCV)
Spherical electrode Position

Planar electrode
Sampled Current Voltammetry (SCV)
Spherical electrode Position Height
n
Concentration
Area
Planar electrode Diffusion coefficient

Slope
59.1/n @ 25°C
Nernstian Kinetics
Chemical Reversibility
(SCV): Irreversible Systems
Linear Sweep Voltammetry (LSV)
Linear Sweep Voltammetry (LSV)
Linear Sweep Voltammetry (LSV)
Linear Sweep Voltammetry (LSV)
Linear Sweep Voltammetry (LSV)
Linear Sweep Voltammetry (LSV)
Voltamperometría de Barrido Lineal (LSV)
Voltamperometría de Barrido Lineal (LSV)
Linear Sweep Voltammetry (LSV)
Linear Sweep Voltammetry (LSV)

Randles-Sevcik
Linear Sweep Voltammetry (LSV)

Randles-Sevcik
Linear Sweep Voltammetry (LSV)
LSV: Irreversible Reactions
LSV: Capacitance Effect
LSV: Capacitance Effect
LSV: Capacitance Effect
LSV: Capacitance Effect
LSV: Capacitance Effect
LSV: Electrolyte (or Electrode) Resistance
▪ Ohm’s Law
𝐸 = 𝑖𝑅
LSV: Electrolyte (or Electrode) Resistance
▪ Ohm’s Law
𝐸 = 𝑖𝑅

E=ϕdl+iR
LSV: Electrolyte (or Electrode) Resistance

E=ϕdl+iR
Cyclic Voltammetry (CV)
Cyclic Voltammetry (CV)
Cyclic Voltammetry (CV)
Cyclic Voltammetry (CV)
Cyclic Voltammetry (CV)

35 mV
𝐸𝜆 > 𝐸𝑝𝑐 +
𝑛
Cyclic Voltammetry (CV)

35 mV
𝐸𝜆 > 𝐸𝑝𝑐 +
𝑛
Voltamperometría cíclica

35 mV
𝐸𝜆 > 𝐸𝑝𝑐 +
𝑛
Cyclic Voltammetry (CV)

35 mV
𝐸𝜆 > 𝐸𝑝𝑐 +
𝑛
CV: Quasireversible Systems
CV: Quasireversible Systems
Voltamperometría cíclica: Quasi-reversibles
CV: Quasireversible Systems
CV: Multicomponent Systems
CV: Multicomponent Systems
Sistemas Multicomponentes
CV: Multicomponent Systems
CV: Multicomponent Systems
CV: Stepwise Reactions
O + 𝑛1 𝑒 → R1 𝐸10

R 1 + 𝑛2 𝑒 → R 2 𝐸20
CV: Stepwise Reactions
O + 𝑛1 𝑒 → R1 𝐸10

R 1 + 𝑛2 𝑒 → R 2 𝐸20

∆𝐸 0 = 𝐸20 − 𝐸10
CV: Stepwise Reactions
O + 𝑛1 𝑒 → R1 𝐸10

R 1 + 𝑛2 𝑒 → R 2 𝐸20

∆𝐸 0 = 𝐸20 − 𝐸10
UME
CV: Surface Area Estimation
CV: Surface Area Estimation
CV: Surface Area Estimation
CV: Surface Area Estimation
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
Mass Spectrometry
Mass Spectrometry
Mass Spectrometry
Mass Spectrometry de Masas
Mass Spectrometry
Elimination Voltammetry (ELSV)
Elimination Voltammetry (ELSV)
Elimination Voltammetry (ELSV)
Elimination Voltammetry (ELSV)
Elimination Voltammetry (ELSV)
Electrochemical Impedance Spectroscopy (EIS)
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅
Electrochemical Impedance Spectroscopy (EIS)
𝑉 = 𝐼𝑅

Nyquist
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Resistor Capacitor
Electrochemical Impedance Spectroscopy (EIS)
Electrochemical Impedance Spectroscopy (EIS)
Nyquist
Espectoscopía de Impedancia Electroquímica (EIS)
Nyquist
Electrochemical Impedance Spectroscopy (EIS)
Nyquist Bode