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Lakshya NEET (2024)

Electrochemistry DPP-05

1. From the electrochemical series, it can be concluded 6. On the basis of the following E° values, the
that: strongest oxidizing agent is:
(1) Zn2+ will liberate H2 from 1 M HCl [Fe(CN)6]4– → [Fe(CN)6]3– + e–1;
(2) Ag metal reacts spontaneously with Zn2+ E° = –0.35 V
(3) Zn metal will liberate H2 from 1 M HCl Fe2+ → Fe3+ + e–; E° = –0.77 V
3+
(4) Ag metal will liberate H2 from 1 M HCl (1) Fe (2) [Fe(CN)6]3–
(3) [Fe(CN)6]4– (4) Fe2+
2. At equilibrium:
(1) E°cell = 0, ∆G° = 0 7. Given:
(2) Ecell = 0, ∆G = 0 (i) Cu2+ + 2e– → Cu; E° = 0.337 V
(3) Both are correct (ii) Cu2+ + e– → Cu+; E° = 0.153 V
(4) None is correct Standard electrode potential (E°) for the reaction,
Cu+ + e– → Cu, will be:
3. Free energy change (∆G) is related to the EMF of (1) 0.52 V (2) 0.90 V
the cell (E) (3) 0.30 V (4) 0.38 V
(1) E = – nF ∆G
(2) ∆G = –nFE 8. A first order reaction takes 40 min for 30%
𝑅𝑇 decomposition. Calculate t1/2
(3) ∆G = – 𝐹 log E
𝑛
𝑛𝐹 (1) 77.7 min (2) 27.2 min
(4) ∆G = – 𝑅𝑇
log E (3) 55.3 min (4) 67.3 min

4. When two half-cells of electrode potential of E1 and

E2 are combined to form a cell of electrode potential 9. A graph plotted between log t50% vs. log conc. is a
E3, then straight line. What conclusion can you draw from
(when n1, n2 and n3 are no. of electrons exchanged in the given graph?
first, second and combined half-cells):
(1) E3 = E2 – E1
E1n1 + E2n2
(2) E3 =
n3
E1n1 − E2n2
(3) E3 =
n32
(4) E3 = E1 + E2 (1) n = 1, t1/2 =
1
Ka
1
5. If the E°cell for a given reaction has a negative value, (2) n = 2, t1/2 =
a
then which of the following gives the correct
0.693
relationships for the values of ∆G° and Keq? (3) n = 1, t1/2 =
k
(1) ∆G° > 0; Keq > 1 (2) ∆G° < 0; Keq > 1
(4) None of these
(3) ∆G° < 0; Keq < 1 (4) ∆G° > 0; Keq < 1
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10. A substance decomposes having rate constant 11. For a zero order reaction
6.8 × 10–2 lit mole–1 sec–1. Calculate half-life if Co (1) t1/2  a (2) t1/2  1/a
was 0.05 M. (3) t1/2  a 2
(4) t1/2  1/a2
(1) 240.0 sec. (2) 298.3 sec.
(3) 294.1 sec. (4) 220.0 sec.
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (3) 7. (1)
2. (2) 8. (1)
3. (2) 9. (3)
4. (2) 10. (3)
5. (4) 11. (1)
6. (1)

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