Key/Solutions

QAQ A Q A
1 A 7 CD 13 2
2 D 8 ABD 14 4
3 B 9 AB 15 25
4 B 10 AC 16 11
5 C 11 B 17 Range : 66 - 67
6 D 12 B 18 3

Q1)
Let the units of ferrous oxide in a unit cell = n,
molecular weight of ferrous oxide FeO = 72 grams/mol
72 × n
=
weight of n units 6 . 023 × 10 23
Volume of one unit = a3 = 125 ✕ 10-24
wt. of cell 72 × n
= , 4.09 =
volume 6.023 × 10 23 × 125 × 10−24
Density
3079.2 × 10−1
n= 72
= 42.7 × 10−1 = 4.27 ≈ 4

Q4)
For rock salt structure, Zef f = 4

6.023
M = 6.023Yu = Y kg
1000

4 × 6.023
1000
× 10−3 × Y
3
Density = 6.023 × 10 23 × (2Y 1/3 × 10−9)

= 408
= 5kgm−3
Given: Observed density = 20kgm−3
Calculated density = 5kgm−3
The observed density is higher than the calculated density, hence, the solid must have non-
stoichiometric defect.
 Q6)
Oxide ions are arranged in C.C.P array. Thus oxide ions are 4
Tetrahedral holes = 8, Octahedral holes = 4
1 1 1
Cobalt atoms = 8 × = 1 (since cobalt atoms occupy th of tetrahedral voids 4 × = 2
8 8 2
( Cobalt atoms also occupy half the octahedral voids )
Thus total cobalt atoms per unit cell = 1 + 2 = 3
Formula = Co3O4

Q10)
Fe3O4 has inverse spinel structure the tetrahedral voids are occupied by 50% of trivalent atoms and
octahedral voids are occupied by 50% of divalent atoms as well as trivalent atoms. The oxide ions
are present at all the corner positions.

Q13)
Z × (Mo /NA) 4 × (31.25 / (1.67 × 10−24 ))
(ideal) = = = 1.67 grams/cc
a3 (500 × 10−10 )3
BUT! (actual) = 1.6075 grams/cc
Difference due to the defect = 1.67-1.6075 = 0.0625 grams/cc
= 0.0625 ✕ 103 grams/ Litre
= 62.5 grams/ Litre
62.5
=
31.25
= 2 mole

Q14) ZnS, AgCl, AgBr, AgI

Q15)
Since the centre of an FCC unit cell is an octahedral void, Ti4+ ion is present in the octahedral void.
Total number of octahedral voids per FCC unit cell is 4. Since only one of the voids is captured we
1
have × 100 % = 25 % occupancy.
4

Q17)
For one litre crystal, m initial − mBremoved + mCadded = mfinal
2
or, 4800 − x × 30 + 1 × 15 = 4795 ⇒ x =
3
x
∴ Percentage of C-atoms which replaced B-atoms = × 100 = 67%
1

Q18)
Only the graph of 2C + O2 → 2CO, has a downward slope, so the graphs having a downward slope
except the mentioned one are wrongly represented.
𝟈
𝟈
STD XI F1 Date: 5 May 2024

Indefinite Integral Key and Solution

19 20 21 22 23 24 25 26 27
A D C D B C AB BC AD
28 29 30 31 32 33 34 35 36
BC A BC 7 2 2 2 7 4

19. Solutions
20.
21.

22.

23.
24.

25.

26.
27.
28.

29.
30.

31.

32.
33.
34.

35.

36.

37.
 M. Prakash Institute
Answer Key:

Q37 Q38 Q39 Q40 Q41 Q42 Q43 Q44 Q45 Q46
A B A B A D A,B,C,D B,C,D C A,B,C
Q47 Q48 Q49 Q50 Q51 Q52 Q53 Q54
A,B,C,D B,D 28.00 9.00 1.03 1.00 0.12 5.00

Solutions:

37

38
𝑣 = 𝜔√𝐴 − 𝑥 and 𝑎 = −𝜔 𝑥 give 𝑣 = 𝜔 𝐴 −

39

40

41

42
43

44

45
46
1 𝑘
𝑓=
2𝜋 𝜇
Initial deformation of spring is . If 𝑥 and 𝑥 are displacements in center of
mass frame,
𝑥 +𝑥 = and 𝑚 𝑥 = 𝑚 𝑥
47 -
48

49

50

51
52 Use phasor diagram.
53 Blocks get detached when spring becomes undeformed. Later only 𝑚
performs SHM.
1 1
× 100 × 0.2 = (9 + 16)𝑣
2 2
1 1
× 9 × 𝑣 = × 100 × 𝐴
2 2

54