Sri Chaitanya IIT Academy, India 02-12-2023_Jr.

Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 02-12-2023
Time: 09:00 AM to 12:00 PM CTM-12 Max. Marks: 300

KEY SHEET
PHYSICS

1) 2 2) 1 3) 2 4) 2 5) 1
6) 3 7) 1 8) 1 9) 2 10) 1
11) 2 12) 1 13) 1 14) 3 15) 3
16) 3 17) 2 18) 3 19) 1 20) 3
21) 4 22) 30 23) 220 24) 326 25) 7
26) 52 27) 16 28) 3 29) 49 30) 1

CHEMISTRY

31) 1 32) 1 33) 3 34) 1 35) 2

36) 4 37) 4 38) 2 39) 3 40) 1
41) 1 42) 3 43) 4 44) 3 45) 2
46) 2 47) 3 48) 3 49) 3 50) 3
51) 6 52) 1 53) 3 54) 6 55) 4
56) 2 57) 6 58) 2 59) 2 60) 5

MATHEMATICS

61) 4 62) 2 63) 4 64) 1 65) 4

66) 1 67) 3 68) 3 69) 1 70) 2
71) 4 72) 4 73) 3 74) 2 75) 1
76) 3 77) 1 78) 4 79) 4 80) 2
81) 7 82) 1 83) 0 84) 2 85) 3
86) 3 87) 5 88) 1 89) 6 90) 8

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
SOLUTIONS
PHYSICS
1. f 0  fC  2
 1 1  V
V    2 or  8
 2L 4L  L
In the second case,
V V 7V 7
f 0'  f c'     8  7
L 8 L 8L 8
2. Conceptual
3. Equation of Reynolds number
4. Conceptual
5. Conceptual
6. For 1st reading of oscillator
f A   514  2  Hz
f A  516 Hz or 512 Hz
For 2nd reading of oscillator
f A   510  6  Hz
f A  516 Hz or 504 Hz
A has a frequency 516 Hz .
V51
7. n  4

V51
 n  4 ..................  i 

V16
and  n  1 ..................  ii 

V16
 n 1

Dividing Eq. (ii) by Eq (i)
V51 n  4

V16 n  1
As v T
273  51 n  4
 
273  16 n  1
324 n  4 18 n  4
or  or 
289 n  1 17 n  1
n  50 Hz

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8.

1 T 1 T 1 T
n  f 0 ........ 1 n1  n2 
2l  21 u , 2 2 u
l l
l1   l , l2   l
2 2
n  n1  n2 and l 2 can be neglected
dx T T
9. V  
dt m m0   x
  
m0   x dx  T dt
10 t
 
m0   x dx  T  dt
0 0
10. Conceptual
2
I  A  A2 
11. n  n1  n2 and max   1 
I min i  A1  A2 
12. n A  nB  8
V V
Also n A  , nB 
4  0.32  4  0.33
V V
 8
4  0.32  4  0.33 
V  338 m s
V 338
 nA    264 Hz
4  0.32 4  0.32
nB  n A  8  256 Hz
13. Conceptual
I power
14. I  10log , I
I0 4 r 2
 dU
15. F and sin   
dx
2
1  y 
16. P.E  T     dx; K  9
2  x 

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
vs 2 T 320 1 50 1
17.    
4 LP 2lS  4  0.8 0.5  50
1
Mass of string, m   lS   0.5  0.01 kg  10 g
50
v v
18. n1  and n2  given l1  32 cm ,
4l1 2l2
l2  66 cm and n1  n2  8 heat s
19. Conceptual
20. f  500 Hz , v  300 ms 1
v 300 3
   m
f 500 5

Resonating length l 
 2n  1 v
4f

l
 2n  1  300  1m
4  500
23
n  3.83
6
Since only odd harmonics are possible there will be only two resonant lengths.
1 T
21. N
2l m
T T
22. M1  0
,M2 
g sin 30 g
23. Frequency of first fork = n. Frequency of 56th fork = 2n
 n   56  1 4  2n
 n  220  2n
n  220 Hz
24. Conceptual
25. Conceptual
26. In ten forks, there are nine intervals
n2  n1  9  4 (Also given n2  2n1 )
2n1  n1  36
n1  36 Hz
so n2  2n1  72 Hz T5  n1   5  1  4
V  RT
27. n  ,V 
4l M
28. Tensile stress  Y  tensile strain

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
 dy 
 Y  
 dx 
 dy 
Max tensile stress  Y   
 dx max

320  100
320 
2  48  2e 
2  48  2e   100
2e  50  48
2e  2
e 1
v 320  100
nclosed  
4  l  e  4  48  1
8  103
=
49
8000
29. =
49
 N is 49
1 1 f 2 1
30.   1  , power =  2 A2 $
2 2 f2 1 2
A W 1
P1  P2  W1 A1  W2 A2  1  2 
A2 W1 2
A 1
Pressure = BAK  1 1 
A2 2 1

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
CHEMISTRY
31. CH 3 group is more electron pumping than other alkyl groups due to hyper
conjugation. If it is directly connected to benzene ring.
32. PhCOCH 3 (Acetophenone)
33. Orientation effect at para to bulky electron pumping group.
34. Orientation effect of halogen


 Re arrangement

35.
36. Friedel craft alkylation gives poly substitution products
37. Common ion effect decreases the ionization of weak acid
38. HNO3 act as base
39. Arenium ion is non-aromatic
40.  I effect of halogen dominates +M effect

CF3 CF3
Br

41. is more stable than
Br Br
Br / h
* 
2
or 
 *
42. *
43. C   lone pair under conjugation no reaction

44. AC 
4 trap H from   complex
45. Nitrobenzene is inert towards friedel craft reaction and can be used as a solvent
46.   complex is carbocation
47. EAS occure at para position to existing methylgroup by the formation of 30
carbocation
2 NaNH CH C  C H C 
48. HC  CH  
2 C2 Na2 
3  NaC  C  CH 3 
2 5  H 5C2  C  C  CH 3
49. SO3 is neutral electrophile
50. CH 3 is more electron pumping group than C  CH 3 3 , when they connected to aryl
or unsaturated system due to hyper conjugation
51. Except the salts of strong acid is strong base
52. At 900 C : k w  10 12 ; p H  6 (Nutral) P H  6  acidic  ; P H  6 (Basic)
53. Terminal alkynes have acidic hydrogen

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
O O
|| ||
54.  N  C  R, OCH 3 , O  C  R
|
H
H
2

Pd

 Chiral   Achiral 
55.

H
2

Pd

 Chiral   Achiral 

 Achiral   Achiral 
Meso

 Chiral   Achiral 

 Chiral   Achiral 

 Chiral   Chiral 

56. Nitronium ion NO2 ; hybridization of N is sp, two hybride orbitals

57. 6th position is para position is electron pumping group N
58. Halogens are ring deactivating but o,p-directing.

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s

59.
H 3C H

3H

2
Pd
60.
DU  5

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
MATHEMATICS

1 x2
 x3  f  x   x3  f  x 
61. l  lim 1   if A  ,
x 0  x  x

A

 
2 lim 2
1A A x
then l  lim 1  A  e x 0 x
x0

A x3  f  x   f  x 
lim  lim  lim 1  3 
x 0 x 2 x 0 x3 x 0  x 
f  x
Now, 1  lim  7, Given
x 0 x3
f  x
lim 6
x0 x3
62. Let S  x 2  y 2  2  0, P   2, 2 

 S1  22  22  2  6  0
 P lies outside the circle
2
PA  PB   PT   S1  6       i 
PB
given  3         ii 
PA

From Rqs. (i) and (ii), we get

PA  2, PB  3 2
 AB  PB  PA  2 2  Diameter of circle
Hence, chord AB passes through the centre  0,0  , y  x

63. Let S  x 2  y 2  2 x  4 y    0
for interval point P  2,8 ,

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
4  64  4  32    0
   96
and x-intercept  2 1    and y-intercept  2 4           i 
given 2 1     0     1         ii 
and 2 4     0     4         iii 
from Eqs. (i), (ii) and (iii), we get
 
  x ' x  x  '  x 
64. F '  x   f    f    g   g  
 2 2  2   2 
Here, g  x   f '  x  & g '  x   f ''  x    f  x 
 x  x  x  x
So, F '  x   f   g    f   g    0
2 2 2 2
 F  x  is constant function
So, F 10   5

65. Let S  x, y   x 2  y 2  2 gx  2 fy  c  0
 S  x, 2   0
2
 x 2  4  2 gx  4 f  c   x  1
 g  1,3  4 f  c  0       i 
and S 1, y   0  1  y 2  2 g  2 fy  c   y  0  y  2 
 f  1,1  2 g  c  0          ii 
From Eqs. (i) and (ii), we get
g  1, f  1, c  1
 Equation of required circle is
x2  y2  2x  2 y  1  0
66. Since, x 2  y 2  25 and x and y are integers, the possible values of x and
y   0, 1, 2, 3, 4  . Thus, x and y can be chosen in 9  9  81 ways. However, we
have to exclude cases  3, 4  ,  4,3 and  4, 4  i.e. 3  4  12 cases. Hence, the number
of permissible values

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  2 1   2 
67.    5  5
 4 4 
2
  2  1     20  100
 2 2  2  119  0
1  239 1  239
  
2 2
  7.2    8.2
   7, 6, 5,......, 7,8
68. Let MN be the diameter of the circle whose equation is
4 y  x  7       i 

and coordinates of A and B are  3, 4  and  5, 4  respectively.

Equation of perpendicular bisector of AB is  L  1, 4  
1
y4  x  1  slope of AB  0 
0
 x  1         ii 
Solving Eqs. (i) and (ii), we get the coordinates of the centre of the circle as 1, 2 

 OL  1  12   4  2 2  2
 BC  2OL  4 units
AB  8 unit
 Area of rectangle ABCD  4  8  32 sq units.

69.  ACB 
3
2
 AOB 
3

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
 AOM  BOM 
3
Let mid-point of chord AB is  x1 , y1 

OM   x1  2 2   y1  32
 In AOM , cos  
3 OA 5
2
5 2 2
or     x1  2    y1  3
2
25
  x12  y12  4 x1  6 y1  13
4
4 x12  4 y12  16 x1  24 y1  27  0
27
 Locus of mid-point is x 2  y 2  4 x  6 y  0
4
2 2
  x  2    y  3  6.26
70. Values of parameter ‘a’
1 dy 1
Given curve is: xy  1  y   
x dx x 2
 slope of normal  x 2  0  As x  0 

 Slope of given line 


log 2 1  5a  a 2  0
5
 
 log 2 1  5a  a 2  0  1  5a  a 2  1

 a 2  5a  0
Hence, a   0,5 

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71.

Let a be the length of each sides of an equilateral triangle ABC. Then r the radius of the
1
in circle =   AP (the altitude, median and the angle bisector of angle)
 3
1 2 a2 a
r  a  
3 4 2 3
a2 a2
Area of the square PQRS inscribed in this circle  PQ 2  OQ 2  2r 2  2  
43 6
72. Equation circle passing through 1,0  0,1 and  0,0  is x 2  y 2  x  y  0
Hence, the correct answer is 4
73.

a2 b2 a 2  b2
r  
4 4 2

74.

A  x1  ay1  lies on x 2  y 2  a 2

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2
  x1  a   y12  a 2
2 2
Locus in x  y  2ax  0
Hence the correct answer is 2
75. Equation of line 1  m  x  7 
mx  y  1  7 m  0
r
Perpendicular distance from  0,0  
2
p
r
2
2
or  7m  1  25 1  m2  
49m2  14m  24  0
 m1m2  1
76. When d is maximum, A and B coincide to each other and coincide with Q  5,3 the
other end of the diameter through P 1,1 .

So secant AB coincides with tangent at Q  5,3 .
Its equation is 5 x  3 y  3  x  5   2  y  3  8  0 , i.e., 2 x  y  13  0
77. Conceptual
78. Conceptual
79. f '  x   x2  x  1  0
f  x  is increasing then check the local minima of g  x  .
g '  x   x3  6 x 2  11x  6; g ''  x   3x 2  12 x  11
g '  x    x  1 x  2  x  3
g ''  2   0  g '' 1  0
g ''  3  0
So, local minima at x  1 and x  3
80. Since  x 2  2 x  7 takes maximum value 8 at x  1 , so f  x  take maximum value at
xX
If lim f  x   f 1
x 1

 a2  4  5  a   3,3
81. After rationalize, we get

lim
 a  2  x3   3  c  x 2   b  3  x   2  d  4
x  4 3 2 4 3 2
x  ax  3x  bx  2  x  2 x  cx  3x  d

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
x
Since, limit is finite, so degree of N must be 2
So, a  2  0  a  2

lim
 3  c  x 2   b  3 x   2  d  4
n 4 3 2 4 3 2
x  ax  3x  bx  2  x  2 x  cx  3x  d

lim
 3  c    b  3 x   2  d  x2
4
n  a 3 b 2 2 c 3 d
1  2  3  4  1  2  3  4
x x x x x x x x
3 c
 4  c5
2
82. The given line is a diameter.
 Required area = Area of semicircle
1 
   1 
2 2
  1
 x 
83. g  x  f  
 f  f  x   

'

 g  x  f 
x '
  f  f  x   0 f f  x  f  x 

 ' '
  
 f  f  x     f  f  x  
2
 

 f 1 1 f ' 1  f ' 1 
 g  x  f    
' 
' 1    
1 
  f 1  2 

 1 1 
So, g 1  f 1 
' ' 0
 f 12 

84. Radius  51 , perpendicular distance of the chord

78  5  4
7 x  y  4  0 from centre   50
50
So, length of the chord  2  51  50  2
2 2
85. The equation of the circle is  x  1   y  1  1

 x 2  y 2  2 x  2 y  1  0        1
Let the equation of the variable straight line be y  mx         2 

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s

 
Solving (1) and (2), we get 1  m 2 x 2  2 x 1  m   1  0

8m
 Length of DE 
1  m2

1
Area of DEB , A  DE  Dis tan ce of B from DE
2
1 8m 1 2m 2m
 A2      A
4 1  m2 1  m2
  1  m2
2
1  m2

dA 1  3m 2 1
 0  m
dm

m 1 m 2 2
 3

d2A 1
 0, if m 
d 2m 3
1
 Area is maximum from m 
3
1
86. y  3 x  3 but f '  0   
3
2x
lim
x 0 2 xf '
 x2   40xf '  4x2   56 xf '  7 x2 
1 1 1
    k 3
f '  0   20 f '  0   28 f '  0  9 f ' 0  1
9  
 3
1.6 4
87.   0.4t  0.4 x  x
x tx
 0.4t  0.6 x  2t  3 x
2dt 3dx
 
dT dT

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s
3dx
 2  30  
dT

dx
  20  k
dT
k
5
4
88. Reflection of H about BC lies on circumcircle.
Let, P   h, k  we have

 h  1 5

 k  2 5

6 17 4 
 P , 
2 1 5  5 5
2 2
 17  4  305 61
 CP    2     4    units
 5  5  25 5
89. We have, f  x   2 x3  3  2  P  x 2  12 Px  1x 16  P 2  

Now, f '  x   6 x 2   2  P  x  2 P 
x2
 f  x  0
'
xP
As, f  x  has exactly one local maxima and one local minima
so, P  2       1

Also, 16  P 2  0  P 2  16  0
  P  4  P  4   0   4  P  4         2 
 The possible integral values of P are 3, 2, 1,0,1,3
 The total number of integral values of pare 6.
90. Length of chord AB  2 x 2  d 2
2
 n  8  n2
 2 4  2
 2  2

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 Sri Chaitanya IIT Academy, India 02-12-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-12_Key & Sol’s


4 8  n2   2 8  n2
AB 2 
2
   if n  1, 2 
Re q  2  8  1   8  4    k  14  8  22
4k 4  22
  8
11 11

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