E131E412AR

實戰解析實力測驗 T3 普通化學 *131EA02RAE412KT03*

後中西醫 131EA02RAE412KT03

孫彥儒老師 編授
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1. What is the weight of the hydrogen gas produced when 4.86 g of magnesium reacts with 50.0
mL of 2.0 M hydrochloric acid？

(H = 1.0 g/mol ; Mg = 24.3 g/mol)

(A) 0.050 g (B) 0.100 g (C) 0.125 g (D) 0.250 g (E) 0.500 g

2. Adding ammonia (NH3) or chromic acid (HCrO4) to a saturated silver chromate solution

containing solid silver chromate, which of the following statements correctly describes the

effect on the solubility of silver chromate?

(A) Both the them will increase solubility

(B) NH3 will increase solubility ; HCrO4 will decrease

(C) NH3 will increase solubility；HCrO4 has no impact

(D) NH3 will decrease solubility；HCrO4 will increase solubility

(E) Both the them will decrease solubility

3. In the following reaction, the bond energy of AB is twice the bond energy of A2, and the bond

energy of B2 is known to be 419 kJ/mol. What is the bond energy of A-A?

A2 + B2→2AB ΔH = －415 kJ

(A) 417 kJ/mol (B) 1668 kJ/mol (C) 278 kJ/mol (D) 627 kJ/mol (E) 834 kJ/mol
4. How many of following compound has dipole moment μ≠0 ?

NO2 SF6 XeF6 PCl5 BrF5 CO2 XeF2O2

(A) 1 (B) 2 (C) 3 (D) 4 (E) 5

5. Which of follow statement about C60 is incorrect?

(A) Also called [60]fullerene (B) An allotrope of solid carbon

(C) All C with sp2 hybridization (D) Only 1 signal in C-NMR spectrum

(E) A spherical molecule composed of 20 five-membered rings and 12 six-membered rings

6. A gas compound X has diffusion rate to N2 with 1:1.6 (X : N2). And X is a gaseous diatomic
molecule at standard temperature and pressure, what is the highest possible oxidation state of

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 the X atom?

(F=19, Cl=35.5, N=14, O=16, H=1, He=4, Ne=20, Ar=40, Kr=83)

(A) +1 (B) +3 (C) +5 (D) +7 (E) 0

7. In a mixed solution of benzene and toluene, it is observed that the mole fraction of benzene in
the vapor is 0.600. What is the mole fraction of benzene in the solution？(Vapor pressure of

benzene and toluene are 750 torr and 300 torr respectively)

(A) 0.286 (B) 0.375 (C) 0.400 (D) 0.600 (E) 0.625

8. The following reaction has equilibrium constant Kp = 2.3 ×106 in 640K. What is the Kc in the
same temperature？ A(g) + B(g)⇋ 2C(g)

(A) 3.1×104 (B) 4.4×104 (C) 2.3×106 (D) 1.2×108 (E) 1.7×108
9. Among the 0.10 M aqueous solutions of the following five compounds, what is the correct
order of their pH values from low to high?

a.HBO3 b.NaF c.HCOOH d.KCl e.HCN

(HCN: Ka = 6.2×10–10; HF: Ka = 7.2 ×10–4; HCOOH: Ka =1.8×10–4; HBO3: Ka = 5.8×10–10)

(A) c > e > a > d > b (B) c > a > e > d > b (C) a > e > c >d > b

(D) b > d > a >e > c (E) d > a > c > e > b

10. What is the cis:trans ratio in product of the following reaction?

[Co(NH3)5Cl]2+ + Cl－ → [Co(NH3)4Cl2]+ + NH3

(A) 1:1 (B) 1:2 (C) 1:4 (D) 2:1 (E) 4:1

11. Given that A → B + C is zero-order reaction and he rate constant is 4.5 × 10–2 mol/L･s in 25

℃. What is the final concentration of A after 6 seconds if A has an initial concentration 2M?

(ln2=0.693、e-0.18 =0.83)

(A) 0.83 M (B) 1.73 M (C) 0.415 M (D) 2.2 M (E) 0 M

12. The hydrolysis reaction for weak acid HA in 27℃ has ΔH = –8.0 kJ/mol and ΔS = –70 J･

K/mol. What is the ln(Ka) for this HA under this condition？(R=8.0 J/K)

(A) 12 (B) 5.4 (C) 2.54 (D) -5.4 (E) -12

13. Based on data given below, which of the following is the strongest reduction agent?

Cl2 + 2e– → 2Cl－ E˚= 1.36 V

Mg2+ + 2e– → Mg E˚= –2.37 V

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 2H+ + 2e– → H2 E˚= 0.00 V

(A) Mg (B) Mg2+ (C) H2 (D) Cl2 (E) Cl－

14. Considering the MO of O2 and N2, Which of the following statement is(are) correct?

Ⅰ. Both of them are paramagnetic

Ⅱ. Bond energy of O2 is higher than that of N2

Ⅲ. Bond energy of NO is higher than that of N2

Ⅳ. Ionization energy of N2 is lower than that of O2

(A) onlyⅠis correct (B) Ⅰand Ⅱ are correct (C) Ⅰ and Ⅳ are correct

(D) Ⅱ and Ⅳ are correct (E) All of them are incorrect

15. Thin-layer chromatography, TLC, is an analysis method usually used to recognize how many

species exist in solution. Which of the following about TLC is incorrect?

(A) In the development step，solvent in container is called mobile phase

(B) It is better to deposit more sample on the TLC plate for easy observation

(C) The white powder on TLC plate is called stationary phase

(D) Do not touch TLC plate directly with hand, and only use pencil to mark on its surface

(E) Deposit sample is better as small as possible.

16. A certain complex of Cr2+ is octahedral structure. Which of the following statement is

correct?

(A) The complex is diamagnetic regardless of the complex is strong field or weak field

(B) The complex is paramagnetic if it is strong field and diamagnetic for weak field.

(C) The complex is diamagnetic if it is strong field and paramagnetic for weak field.

(D) The complex is paramagnetic regardless of the complex is strong field or weak field

(E) The complex is neither diamagnetic nor paramagnetic.

17. There are two measurement result recorded as 23.68 and 0.112. When adding these two

values, how many significant figures should the result have? And when multiplying, how

many significant figures should the result have? (adding result ; multiplying result)

(A) 3；2 (B) 4；3 (C) 5；4 (D) 5；5 (E) 4；4

18. In the following molecules, how many of them have all their constituent atoms not in the

same plane？

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 H2C=C=CH2、F2O、SO2、NH3、CO2、BeCl2

(A) 2 (B) 3 (C) 4 (D) 5 (E) 6

19. Based on following reactions, reaction enthalpy of (4) is?

(1) 1/2 A → B ΔH = 75 kJ (2) 3 B → 2 C + D ΔH = -125 kJ

(3) E + A→ 2D ΔH = 350 kJ (4) B + D → E + 2 C ΔH = ？

(A) 400 kJ (B) 325 kJ (C) -400 kJ (D) -325 kJ

20. A certain molecule has ground state electron configuration : (σ2s)2(σ2s*)2(π2py)2(π2px)1.

What is the molecule？

(A) Li2+ (B) C2－ (C) Be22+ (D) B2 (E) N23+

21. Use following reactions to calculate standard enthalpy of formation of CuO(s)

2Cu2O(S) ＋ O2(g) → 4CuO(S) ΔH˚＝–288 kJ

Cu2O(S) → Cu(S) ＋ CuO(S) ΔH˚＝ +11 kJ

(A) –288 kJ (B) –155 kJ (C) –310 kJ (D) +155 kJ (E) +11 kJ

22. What will happen if the volume of following system is expanded?

4A (g) + 5O2(g) ⇋ 3B (g) + 6H2O(g) ΔH=100kJ

(A) Temperature raise (B) More NO is produced (C) More O2 is produced

(D) Nothing happens (E) More NH3 is produced

23. Order the boiling point from highest to lowest for (a)KCl、(b) CH3OH、(c)C2H6、(d)Ne、

(e)MgO

(A) a > e > c > b > d (B) e > a > c > b > d (C) a > e > b > c > d

(D) e > a > b > c > d (E) e > a > c > b > d

24. What is the formal charge and oxidation number of N in the stable Lewis structure of NO2?

(A) 0；+4 (B) +1；+4 (C) -1；–4 (D) +1；+1 (E) +1；+5

25. Why transition metals possess color?

(A) transition of conjugated π-electrons (B) transition of d-orbital electrons

(C) transition of p-orbital electrons (D) Transition metals are colorless (E) transition

of s-orbital electrons

26. The following table listed the max wavelength(λmax) absorb for different compound. Which

of the them is yellow-colored?

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 Compound Ⅰ Ⅱ Ⅲ Ⅳ Ⅴ

λmax (nm) 165 305 440 650 790

(A) Ⅰ (B) Ⅱ (C) Ⅲ (D) Ⅳ (E) Ⅴ

27. A certain compound is found to consist of 49.5% C；5.15% H；28.9% N；16.5% O. If the

molar mass of this compound is 194, which of the following is correct? (C: 12；N: 14)

(A) empirical formula is C4H5NO (B) empirical formula is C4H6NO

(C) molecular formula is C8H11N4O2 (D) molecular formula is C9H12N2O

28. There are two isotope for Cu in nature：63Cu and 65Cu. It is known that atomic mass of Cu is

63.5 amu, what is the redundancy of 65Cu?

(A) 70% (B) 63% (C) 90% (D) 50% (E) 30%

29. How many electrons transfer in the following reaction after the coefficient is balanced?

SO32–(aq) + MnO4–(aq)→SO42–(aq) + MnO2(s)

(A) 2 (B) 3 (C) 6 (D) 9 (E) 1

30. The electron configuration of element X is [Ar]3d104s24p2. What is the most possible fluoride

compound of the X?

(A) XF (B) XF3 (C) XF4 (D) XF5 (E) XF6

31. A unknown third-row element has ionization energy as following：IE1 = 578 kJ/mol，IE2 =

1820 kJ/mol，IE3 = 2750 kJ/mol，IE4 = 11600 kJ/mol，IE = 14850 kJ/mol；What is the most

possible element?

(A) Al (B) S (C) P (D) Si (E) Ca

32. A certain gas has density = 1.62 g/L under 300K, 1 atm. Given atomic mass C = 12 g/mol; S

= 32 g/mol; O = 16 g/mol; Ne = 20 g/mol; Ar = 40 g/mol. What is the diffusion rate of He and

X (He:X) ?

(A) 2.2:1 (B) 3.2:1 (C) 2.8:1 (D) 4:1 (E) 1:1

33. H3PO4(aq) has 3 pKa : pKa1: 2.20, pKa2: 7.20, pKa3: 12.40. What is the ratio of

[HPO42-]/[H2PO4-] if solution has pH=6.7 ?

(A) 1:10 (B) 1:7 (C) 1:3 (D) 1:5

34. A sample 25.0 mL of an unknown concentration HF solution is mixed with 25.0 mL of 0.20

M NaOH solution. The pH of the solution is found to be 3.00. What is the approximate

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 concentration of the original HF aqueous solution? (Ka of HF = 7.1×10−4)

(A) 0.12 M (B) 0.24 M (C) 0.36 M (D) 0.48 M

35. The initial rate of gas phase reaction 2NO(g) + 2H2(g) → N2(g) + 2H2O(g) are list as

following table

[NO]0(M) [H2]0(M) Initial rate(M/s)

0.2 0.3 0.0180

0.3 0.45 0.0405

0.4 0.3 0.0720

What is the rate constant of this reaction?

(A) 0.3 (B) 0.45 (C) 1.5 (D) 3

36. A student recorded a reaction with reagent I and found the reaction is a zero-order reaction.

What is the relationship about concentration and time correct?

37. A certain radiative element has 5year-half-life. How long does this element decays to 0.75g

from 25g? (log2=0.301 log3=0.477 log5=0.699)

(A) 5 (B) 10 (C) 25 (D) 125 (E) 625

38. After x time(s) α-decay and y time(s) β-decay, U-238 decays to Pb-206. What is x and y

respectively?

(A) 2,8 (B) 4,6 (C) 6,2 (D) 8,6 (E) 10,2

39. What is the radius if a metal with body-centered cubic and length=600pm ?

√2=1.414 √3=1.73 √5=2.23

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 (A) 3 Å (B) 2.6 Å (C) 2.1 Å (D) 1.4 Å

40. A gas is placed in cylinder with a movable piston and initial volume of 0.255 L. It undergoes

a isobaric process, expanding its volume to 1.45 L against external pressure of 1atm and

absorbing 875 J of heat. What is the change in internal energy of the gas? (1 atm．L = 101.3 J)

(A) 996 J (B) 754 J (C) -754 J (D) -996 J

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 E131E412AR
實戰解析實力測驗 T3 解答 普通化學 *131EA02RAE412KI03*
後中西醫 131EA02RAE412KI03
孫彥儒老師 編授

題號 1 2 3 4 5 6 7 8 9 10
答案 B B C D E D B C A C
題號 11 12 13 14 15 16 17 18 19 20
答案 B D A E B D B A D E
題號 21 22 23 24 25 26 27 28 29 30
答案 B D D B B C A E C C
題號 31 32 33 34 35 36 37 38 39 40
答案 A B C D B B C D B B

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