Sarthak MHT-CET Crash Course 2.

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CHEMISTRY DPP – 01
Chemical Thermodynamics & Energetics
1. The work done when the system (gas) expands or 7. The energy stored in a substance is called as
contracts against the external opposing force is called _______energy
work (A) kinetic (B) Gibbs
(A) pressure-volume (C) internal (D) external
(B) pressure-temperature
(C) volume-temperature 8. The first law of thermodynamics states that
(D) pressure (A) the total internal energy of an isolated system
decreases when the system changes from an
2. If one mole of a gas occupying y dm3 volume is initial state to final state
expanded against a constant external pressure of one (B) the energy of the universe increases
bar to a volume of x dm3 the work done by the system (C) the total energy of a system and surroundings
is________ remains constant when the system changes from
(A) –Pext (x + y) (C) –Pcxt (x–y) an initial state to final state
(B) –Pext (x/y) (D) –Pext /(x - y) (D) All of these

3. For free expansion of as in vacuum, work done is 9. In an isobaric process, _______the increase in
_____ internal energy is _______
(A) Positive (A) equal to the heat absorbed
(B) negative (B) equal to zero
(C) positive or negative (C) equal to the work done
(D) zero (D) equal to the sum of the heat absorbed and work
done
4. One Joule is equal to _____
(A) 1 Pa m3 (B) 4.184 Pa m3 10. In an isobaric process, ________
(C) 10 Pa m3 (D) 105 Pa m3 (A) QP = 0
(B) QP = U
5. The maximum work is obtained from the change (C) QP = U + Pext V
which is thermodynamically (D) QP = U – Pext V
(A) irreversible (B) reversible
(C) adiabatic (D) isochoric 11. The sum of the internal energy of the system and the
energy that arises due to its pressure- volume work is
6. Which of the following is the expression for the called of the system
maximum work? (A) internal energy (B) enthalpy
(A) W = –Pext v (C) entropy (D) free energy
P
(B) W = –2.303n RT log10 1
P2 12. Enthalpy (H) is equal to _______
P2 (A) internal energy (U)
(C) W = –2.303 n RTlog10 (B) product of pressure (P) and volume (V) of gas
P1
(C) internal energy (U) + PV
P2
(D) W = 2.303n RT log10 (D) work (W) done by a system
P1
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13. Statement 1: Density is an intensive property. 19. When heat is released during the reaction, it is
Statement 2: The ratio of two extensive properties is denoted as _______ and when work is done on
an intensive property. system by the surroundings, it is denoted as _____.
Choose the CORRECT option. (A) positive; positive
(A) Both the statements are false. (B) negative; negative
(B) Both the statements are true. (C) positive; negative
(C) Statement 1 is true, but statement 2 is false. (D) negative; positive
(D) Statement 1 is false, but statement 2 is true.
20. Which of the following statement is CORRECT?
14. Heat capacity and specific heat are (A) The work done on the system by the
(A) extensive properties surroundings is negative.
(B) intensive properties (B) The work done by the system on the
(C) intensive and extensive properties respectively surroundings is positive.
(D) extensive and intensive properties respectively (C) The heat absorbed by the system from the
surroundings is positive.
15. Which of the following is a state function as well as (D) The heat absorbed by the surroundings from the
intensive property? system is positive
(A) Heat capacity (B) Internal energy
(C) Temperature (D) Volume 21. One mole of an ideal gas expands isothermally at
300 K from 1 dm³ to 11 dm³ at constant pressure of
16. A system is said to be in thermodynamic equilibrium
1 bar. The work done during this change is _____ J.
when, ……………
(A) –1000 (B) –10000
(A) the temperature of the system is non- uniform
(C) –100 (D) –10
and different from the temperature of the
surroundings
22. Two moles of an ideal gas is expanded isothermally
(B) the mechanical properties are non- uniform
from a volume of 300 cm3 to 2500 cm3 at 300 K
throughout the system
against a pressure of 2 bar. The work done in joules
(C) the state functions of the system do not change
is
with time
(A) –440
(D) only pressure of the reaction is at equilibrium
(B) –44.0
(C) –4.40
17. Which of the following is INCORRECT regarding
(D) 0.440
thermodynamic processes?
(A) reversible change is a change in which the
23. The constant external pressure required to compress
pressure remains constant.
1 mole of an ideal gas from 23 dm3 to 8 dm3 when
(B) An adiabatic change is a change in which the
work obtained is 9.09 kJ at 27 °C is
system is completely isolated in the thermal
(A) 60.6 bar
sense.
(B) 6.60 bar
(C) In an isochoric process, the volume of the
(C) 0.606 bar
system remains constant.
(D) 6.06 bar
(D) In a reversible process, the driving and opposing
forces differ by an infinitesimal amount
24. 3 moles of an ideal gas is compressed from 30 dm³ to
20 dm³ against a constant pressure 3.039 bar. The
18. Identify the INCORRECT statement.
work done in calories is of (1 J=0.239 cal)
(A) In mechanics, work done by a body is the
(A) + 30.39 cal
product of force and displacement.
(B) +72.63 cal
(B) In the reaction between NH3(g) and HCl(g)
(C) +726.3 cal
carried out in a cylinder equipped with
(D) + 303.9 cal
frictionless movable piston, as the reaction
proceeds the piston moves down.
25. Two moles of an ideal gas expand spontaneously into
(C) Pressure is defined as force per unit volume.
a vacuum. The work done is Joule
(D) In the decomposition of H2O2(l) carried out in a
(A) 2 (B) 4
cylinder equipped with frictionless movable
(C) zero (D) infinite
piston, the gas produced pushes the piston
upwards.
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26. The heat of a chemical reaction is given by the 31. Which of the following is NOT in the standard state
following expression, at 1 bar pressure and 25oC ?
(A)  r H =  H products −  H reactants (A) C2 H5OH(t) (C) CO 2( g)
(B) CaCO 3( s)
(B)  r H =  H products +  H reactants
(D) H2 O(g)

(C)  r H =  H reactants −  H products 32. Which of the following is the CORRECT

(D)  r H = − H products −  H reactants representation of thermochemical equation?
(A) CH4 + 2O2 → CO2 + 2H2O, r H = −890 kJ

27. An exothermic reaction is one in which the reacting
substances ___________.
(A) have more energy than the products
(B) have less energy than the products
(C) are at a higher temperature than the products
(D) are at a lower temperature than the products
(B) CH4( g) + 2O2( g) → CO2( g) + 2H2O( ) ,
r H = −890 kJ
(C) CH4( g) + O2( g) → CO2( g) + H2O(l) ,
r H = −890 kJ
(D) CH4( g) + 2O2( g) → CO2( g) + 2H2O(l)

28. Study the following two reactions: 33. Enthalpy change for the following reaction at 1 bar
CH4( g) + 2O2( g) → CO2( g) + 2H2O(g) ; 1 1
(i) pressure and 25oC, H 2( g) + Cl2( g) → HCl(g) is
2 2
H = −890.4 kJ called
(ii) 2HgO(s) → 2Hg(l) + O2( g) ; (A) enthalpy of combustion
H = +181.6 kJ (B) enthalpy of vaporization
Which of the following statements is CORRECT? (C) enthalpy of formation
(A) Both reactions are exothermic. (D) enthalpy of fusion
(B) Both reactions are endothermic.
34. The CORRECT equation for standard enthalpy of
(C) Reaction (i) is endothermic and
formation of CO is __________.
(ii) isexothermic.
(A) C(s) + O2 → 2CO(g)
(D) Reaction (i) is exothermic and
1
(ii) isendothermic. (B) C + O 2 → CO
2
(C) 2C(s) + O2( g) → 2CO(g)
29. Combustion of carbon is
(A) an endothermic change 1
(D) C(s) + O 2( g) → CO(g)
(B) an exothermic change 2
(C) a process where no heat change occurs
(D) a process accompanied by no chemical changes 35. Which of the following reactions represents standard
enthalpy of formation of AgCl} ?
+ −
(A) Ag (aq) + Cl(aq) → AgCl(s)
30. Conversion of oxygen to ozone represented by the
equation 3O2 → 2O3 is an endothermic reaction. 1
(B) AgCl(s) → Ag (s) + Cl2( g)
Enthalpy change H accompanying the reaction 2
(A) is negative (C) Ag(s) + AuCl(s) → AgCl(s) + Au (s)
(B) is positive 1
(D) Ag (s) + Cl2( g) → AgCl(s)
(C) is zero 2
(D) is either negative or zero
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36. The enthalpies of the elements are assumed to be 38. The enthalpy change for the formation of 3.6 kg of
(A) zero at 298 K and 1 bar water is ___________.
1
(B) one at 298 K and 1 bar H 2( g) + O 2( g) → H 2 O(f ) ; H = −284.5 kJ mol−1
(C) zero at all temperatures and pressures 2
(A) 284.5 kJ (B) –284.5 kJ
(D) zero at 273 K and 1 bar (C) –5690 kJ (D) –56900 kJ

37. If f H(X), f H(Y), f H(R) and f H(S) denote the 39. The enthalpy change (H) for the reaction
enthalpies of formation of X, Y, R and S respectively, 2CO + O2 → 2CO2 ; H = −135kcal is called
the enthalpy of reaction; X + Y → R + S is given by (A) heat of formation
(A) f H(X) + f H(Y) (B) heat of reaction
(B) f H(R) + f H(S) (C) heat of combustion
(C) f H(X) + f H(Y) − f H(R) − f H(S) (D) heat of solution
(D) f H(S) + f H(R) − f H(X) − f H(Y)
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Answer Key
1. (A) 11. (B) 21. (A) 31. (D)

2. (B) 12. (C) 22. (A) 32. (B)

3. (D) 13. (B) 23. (D) 33. (C)

4. (A) 14. (D) 24. (C) 34. (D)

5. (B) 15. (C) 25. (C) 35. (D)

6. (B) 16. (C) 26. (A) 36. (A)

7. (C) 17. (A) 27. (A) 37. (D)

8. (C) 18. (C) 28. (D) 38. (D)

9. (A) 19. (D) 29. (B) 39. (B)

10. (C) 20. (C) 30. (B)

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