Straignt

3. (b) 4. (d) 5. (
1. b) 2. (d)
8. (a) 9. (b) 10. (a
6. (a) 7. (c)
13. (b) 14. (c) 15. (b
11. b) 12. (b)
18. (a) 19. (c) 20. (c)
16. (d) 17. (c)
23. (d) 24. (d) 25. (c)
21. (b) 22. (a)
29. (d) 30. (a)
26. (b) 27. (b) 28. (b)
34. (c) 35. (b)
31. (a) 32. (d) 33. (c)
39. (d) 40. (a)
36. (d) 37. (b) 38. (a)
43. (b) 44. (c) 45. (a)
41. (a) 42. (d)
48. (a) 49. (c) 50. (c)
46 (c) 47. (a)
(d 53. (c) 54. (a) 55. (b)
 Matrix Match Type
1. (a-s), (b-p). (c-9). (d-r) 2. (a-p. q, r, s). (b-p, r, s), (c-q), (d-p)
3. (a-p. s), (b-q. r). (c-q). (d-q) 4. (a-r). (b-p). (c-s). (d-t)
5. (a-). (b-s). (c-p),. (d-q) 6. (a-p. q. s). (b-p, s). (c-p, r). (d-p. q. r, s)

7. (a-p). (b-r), (c-q). (d-s) 8. (a-r). (b-s), (c-p), (d-t)

9. (a-s). (b-t). (c-p). (d-r) 10. (a-s), (b-p), (c-q), (d-r)
11. (a-p). (b-q). (c-r). (d-s) 12. (a-s), (b-r), (c-p), (d-q)
14. (a-q). (b-r). (c-p). (d-s)
13. (a-q). (b-s). (c-p). (d-r)
15. (a-r). (b-p). (c-qg), (d-t)
 SECTION
to thc fomaton of bond
Answer)
nswer)
b) Only positive overlap leads

2.(d) lonic charcter observed100

akrlatc
NH N, NH

hb intolves gy hvbidizalon hence it has " character

(c) O is
not
ossible because the cOvaleney of oxygcn cannot
be equal to four

&. (a)
Carbonate on has no coordinate bond.
. (b) There are sin
( H) bonds in benzene, which are tormed by (spp=s)overlapping
10. (a) 0=
O==0< C=0
Bond energy inereases with bond
order
12 (b) H H

This molecule has two (three centred bonds)

13. (b) lonic
compound dissolves in water, when its
hydration energy is greater than lattice
Cneg
14. (c)Aef and 1C
square planar molecules
are

18.
(a)Cu(H.O) S04 H
Blue itrol has

() clectovalent bond betwcen Cu nd SO; ions

(1)our water molecules ate coordnaied
(1) One watcr nolcule is
h, drugen bonded to SO ions
19. (c) KO has superoxide ion O, s On has 0 e
unpaired electrons
21. (b) Resultant of three polar bonds will be iaimutn in 1, 2,
24. (d) Greater Is the 1onic chataCter. noe s the
3-uichlorobenzen
n water
25. (c) l; and Xel, have y dhybi1dlyition

CIO and PO have sy i,briiation

28. (b) Both ICT e1ae hnea
31. (a) Intramolecular 1 bondmg >
present no-nitroplieho whCh fowers
boilng point while
its
intermolecular 1bonding Is
piesent Inp-ittei teh
ihci eases its boiline pOnt.
 NH; have ntical shape and a lone
Both NF; and
Roth Nt a ofNH pair
moment higher NF due to different clectrons on nitrogen. The
is than
Hbond. B; is a symmetrical molecule It directions of moents of the
dipole
NFand N has zero
an
is
odd electron molecule dipole moment.
NO,

The dimer. N;04. has no unpaired electron.

O O

0
N-N
Fomal charge =total valence clectrons in free atom number of
non-bonding electrons
1/2 number of
6-4-1/2x4 =0
=
bonding electrons
(b) o 10n1e character = Observed dipole moment
Theoretical dipole moment x100
The cal dipole moment of a 100% ionic character
=
exd =(1.6x
10C)x(1.41x 10m)
=
2.256x 10 em
.(d) PCl; has 3-cquitorial and
.(b) SiCl, has pure covalent
2-axial bonds.
bonds.
.(2) NaCI is an ionic compound. Solubility of an ionic compound depends on the value
dielectrie constant of the solvent. of
more is the
Higher the value of dielectrie constant of the solvent
solubility of the ionic compound.
Solvent H,0 CHOH CH,COCH3
Dielectric constant 80 27 21 4.1
9. (d) Xenon has highest boiling point because it involves strongest van der
Waals' force.
ureater is the number of electrons, stronger is the van der Waals' loree.
4.(a) In SF, molecule,
me there are six bond pairs thus sulphur has 12 valence elecurOns.
A (a) The
structur of B,H, is:

Each bosonatomIsin h y b r i d stale. Tach bojon las three orbitals assocaled with e

and on empty
r bilal. Iwo ol Oibitals to cachh boro1 itom onerlap ith
electron cacl
Jo1 jotal igma bonds
hydrogen atoms (teminal) to
bonds. wilhTest oI tlhe louu bu.
overlap
Twohydrogen aloms
orbitals ire involved.
two cnpty
 are:
structures
42. (d) The
bipyramidal
SF
SF d hybridization-trigonal

C F s p hybridization-tetrahedrai
F
F
F

XeF-sp'd* hybridization-octahedral Xe
F F

43. (b) Lattice energy decreases with increase in size of 1ons

Be Mg<Ca
Increasing size

O O O
44. (c) H,S,O,HO-S-S-OH 4-bonds: H,SO; HO- S In-bond:

OH
O O

HS,0 HO S-OH 3n-bonds

45. (a) S+ 2C1, SCT SCl+ 3H,0 H,SO +4HC1

InSO.sulphurhas hybridization
46. (c) Xc has distonted ovtalhedral structure. Nenon in XeF, undergoes sp u hvbridi/ati
hdergoes sp'd'

giving pentagonal bipyrania wiir One

axis Is
occupied by a lone pair.
48. (a) 1,0, is ionic compOund, whicCh
nay be
represented as ldO, P* 310
1. (a-s) (b-p) (c-q) (d-r)
PCI It has trigonal bipyramidal shape with three equitorial and two axial
bonds.

XeF, F Xe F Two axial bonds with three lone

pair of electrons.

SF4 F S F See-saw shape; two axial and two equitorial bonds.

F? F
CIF3> F a
Cl a FT-shaped molecule; two axial and one equitorial bond.
e
F
 (dp)
2. (a-p. q.
r, s)(b p . s)( - 9
C S . Xef),
r,

C>l12. NCO >Al these havelinear

linear .shape.
emmd
CS,b, NCO Involvc syp hybridization

Xe Xenon exists in sp'd hybrid state,

C O , and CS, > Iso-strnuctural lincar molecule involvin
nvolving sp hybridivza
3. (ap.s) (b q. q) (d q)
r) (e /ation
Bond order =2: Paramagnetic molccule having two unpaired
, Bond order - 3: Diamagnetic molecules clectreOs.
0 H Diamagncticmolecule
4. (a-r) (b p) (c s) (d-)
Li (B.O. ): N, (B.O. 3); Be, (B.0. 0);0, (B.O, =2)
5. (a-r)(b ) ( p ) (d q)
HH

H-C-C-H Each carbon has four sigma bonds hence they will be in
sp
HH
hybrid state.
H
= Both carbons have three sigma and a pi bond hence
they will he
H H
in sp hybrid state.
H-=C-I1 -> Both carbons have 20 and 27t bonds hence
they will be in sp
hybrid
state.

H H
>All the six carbons have 3o and It bonds hence
they will
be in sps hybrid state.
H
H
6. (a -p, q. s) (b-p, s) (c-p, r) (d-p, 9, r, s)
H

HN
HC->Covalent, coordinate and ionic bond.

HNC>Covalentand coordinate bond

Covalent bond and iydrogen bond.
H

CuH,O) ] SO4 150-> Tl Is a

conptex conpoun.d; four are
coordinated to Cu" ion and one I1,01s moleeules ol 12
*

hydiogen bonded to So ions,

therefore, possess 1onic, This molecu
covalent, cordnate and ydrogen bond,
 (d-r)
9.(a-)(b ) (-p)
NOS (180°): NO, (134"); NO, (120"): N0, (115")

10.()(b p) (q) (d-r)

F
F F F
Xe Xe:
F F
F
Square planar Distarted octahedral

,O

Xex Xe
o O O
Pyramidal shape Tetrahedral shape

13. (a-q) (b-s) (c-p) (d-r)

120
180 H
CH3
CHC=C-H 108°

H
109.5

5.
(a-r) (b-p) (e-q) (d-1) C
C
C CP
Cl
AIK
,Cl AK C
P C1
CI
DimerC Trigonal bipyrammdat
Tetrahedral Crown shape