Total No. of Questions : 9] SEAT No.

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P-3920 [Total No. of Pages : 4

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ENGINEERING CHEMISTRY

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(2019 Pattern) (Semester - I/II) (107009)
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Time : 2½ Hours] [Max. Marks : 70
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Instructions to the candidates :

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1) Question No. 1 is compulsory.

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2) Solve any one of Q.2 or Q3, Q4 or Q5, Q6 or Q7, Q8 or Q.9.

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3) Neat diagrams must be drawn wherever necessary.

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4) Figures to the right indicate full marks.
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5) Use of logarithmic tables slide rule, Mollier charts, electronic pocket calculator
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and steam tables is allowed.
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6) Assume suitable data, if necessary.

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Q1) Multiple Choice Questions :

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i) Electroluminiscent polymers are used in : [1]

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a) Solar cell technology b) Digital display

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c) LED d) All of above

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ii) Properties of polymer composite depends on : [1]
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a) colour of particle b) monomer

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c) size of particle d) none of the above

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iii) Which of following industries have prominant applications for quantum

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dots? [1]
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a) Electronic b) Agriculture
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c) Medical d) None
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iv) In ______ max shift to higher side.

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[1]
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a) hyperchromic effect
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b) hypochromic effect
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c) bathochromic shift
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d) blue shift
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 v) Following is the most important characteristic of a good fuel. [1]

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a) high heat value b) bright light

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c) high sound d) colourful smoke

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vi) Following is not a prominant application of UV spectroscopy. [1]

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a) Study of reaction kinetics

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b) Detection of functional group

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c) Quantitative analysis

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d) Qualitative analysis

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vii) The possible number of fundamental modes of vibrations in case of CO2
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molecule is [1]
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a) 2 b) 3
c) 4 d) 5
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viii) In the process of tinning : [1]

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a) Zn is coated on Fe
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b) Sn is coated on Fe
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c) Sn is coated on Zn
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d) Fe is coated on Zn
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ix) Ideal pilling Bed worth ratio for effective protection of metal against
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corrosion is [1]
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a) PBR < 1
b) PBR  1
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c) PBR > 2
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d) PBR > 2.5

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x) Sacrificial anode is [1]

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a) anodic protection method

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b) cathodic protection method
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c) an example of metal cladding

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d) an example of powder coating

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Q2) a) What are conductive polymer? Give types of conducting polymers.

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Explain doping with reactions and give any two applications of conducting
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polymers. [6]
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b) Give classification and any four applications of SWCNT. [5]

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c) Give structure, any three properties and any three applications of

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polycarbonate. [4]
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Q3) a) Explain with diagram the structure of graphene. Give three properties and

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three applications of it. [6]

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b) What is biodegradable polymer? Give three factors affecting

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biodegradation process of a polymer. Give any two applications of

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biodegradable polymer. [5]

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c) What are quantum dots? Give any two types of quantum dots. Write any

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two applications of Q.D.S. [4]

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Q4) a) Explain steam reforming of coke and methane with reaction conditions
for industrial production of hydrogen. Give process of CO2 removal.[6]
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b) Explain fractional distillation process with diagram for petroleum crude.
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Give composition, boiling temperature range and use of any one fraction.

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c) Exactly 2.500 gram was weighed into silica crucible. After heating for
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one hour at 110ºC the residue weighed 2.415 gram. The crucible next
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was covered with vented lid and strongly heated for exactly seven minutes
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at 950  20ºC. The residue weighed 1.528 gram. The crucible was then
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heated without the cover, until a constant weight was obtained. The last
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residue was found to weight 0.245 gram. Calculate % moisture, % volatile

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matter, % ash and % Fixed carbon. [4]

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Q5) a) Give construction with figure and working of Bomb calorimeter. Write

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corrected formula to find out Gross calorific value of a coal using Bomb
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calorimeter. [6]
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b) What is ‘Power Alcohol’? Give procedure for preparation of ethanol

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with reactions. Give any two advantages of Power alcohol. [5]

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c) Observations in the Boy’s Gas calorimeter experiments are given below;

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find GCV and NCV of fuel. [4]

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Volume of gas burnt at STP = 0.08m3

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Mass of cooling water used = 29.5 kg

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Rise in temperature of circulatting water = 9.1ºC

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Mass of steam condensed = 0.04 kg

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Q6) a) Explain with diagram the possible electronic transitions those may occur

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in organic molecule on absorption of UV-radiations. Also state forbidden

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electronic transitions. [6]

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b) Explain conditions for IR radiation absorption by organic molecule.

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Describe any three applications of IR spectroscopy. [5]

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c) Give statement and mathematical expression of Lambert-Beer’s Law.[4]

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Q7) a) With the help of diagram explain construction of IR spectrometer.
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Describe different components of IR spectrometer. [6]

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b) Give any five applications of UV-visible spectroscopy. [5]

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c) Explain bending vibrations observed in IR spectroscopy. [4]

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Q8) a) Explain hydrogen evolution and oxygen absorption mechanisms of wet
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corrosion with diagram and reactions. [6]
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b) Explain any five factors responsible for corrosion of metals. [5]
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c) What is galvanisation? Explain process with diagram. [4]

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Q9) a) Explain types of oxide films with corrosion reactions for metals, Na, Al,
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Ag, Mo. [6]

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b) Explain process of electroplatting with the help of neat labeled diagram.

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Give any four applications of electroplatting. [5]
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c) Distinguish between anodic and cathodic coatings. [4]

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