Drill 4 ( Sem 1) 2018 5. Which of the following statement(s) concerning ideal gases is ( are ) correct?

I A significant volume is occupied by gas molecules compared to the

Section A volume of the container which holds them.
1. Given that the reaction : 2 S + 3 O2 2 SO3 II Collision between gas molecules are perfectly elastic.
If you started with 5.0 moles of sulphur and you obtained 351 g of III There are no attractive or repulsive forces between the molecules.
sulphur trioxide, what is your percentage yield?
A 44 % B 88 % C 93 % D 100 % A Only I is correct B I and II are correct
C II and III are correct D None of these is correct

2. Which of the following molecules is non-polar?

A CH2Cl2 B NH3 C SO3 D POCl3 6. For K2Cr2O7, choose the correct oxidation state of Cr and its dn
configuration.

Oxidation number of Cr dn
3. The atomic spectrum of hydrogen in a spectrometer shows a series of lines. A +4 d4
These lines are formed as a result of B +4 d2
A excitation of orbital electrons C +6 d0
B hydrogen atoms accepting electrons D +6 d5
C hydrogen atoms forming molecules.
D electrons undergoing pairing.
7. Based on the valence shell electron pair repulsion theory, what is the
shape of I3 - ?
4. In which of the following pairs do the central atoms NOT have the same A T- shape B linear
hybridization? C V-shaped D Trigonal planar
A SO2 and CO2 B NH3 and H2O
C NCl3 and PCl3 D H2S and HF
8. Which of the following Groups of elements react to form crystals of high
solubility in water?
A Group 1 and Group 17 B Group 2 and Group 16
C Group 13 and Group 16 D Group 14 and Group 17
9. Element X with proton number 50. Which of the following shows the 12. The reaction between A and B is given to be
right order for the removal of electrons from its orbitals to form X4+ ion? 2A + 2B 2 AB
Frist Second Third Fourth The mechanism of the reaction is as shown below:
A 4d 4d 5s 5s 2A A2
B 5p 5p 5s 5d A2 + B AB + A● slow step
C 5p 5p 5s 5s A● + B AB
D 5s 5s 5p 5p
Which of the following statements is true?
A Doubling the concentration of A doubles the rate of reaction.
10. Given that 250 cm3 of gaseous hydrocarbon is completely oxidized by 750 B Doubling the concentration of A and B increase the rate of reaction by 8
cm3 of oxygen, what is the volume of carbon dioxide liberated? times.
( All volume are measured at same temperature and pressure) C The overall rate order is 2.
A 500 cm3 B 250 cm3 D The rate equation is rate = k [A2][B]
C 1000 cm3 D 1500 cm3

13. At 60oC and a total pressure of 1 atm, dinitrogen tetroxide is 50%

11. The acid dissociation constant for propanoic acid is 1.35 x 10-5 mol dm-3 at dissociated into nitrogen dioxide.
298 K. The pH of 0.100 mol dm-3 of this acid is 2.93. Which of the following Calculate the equilibrium constant, Kp at this temperature.
statement is true of this acid if it is diluted. A 18 B 2
A The pH value is 3.93. C 12.5 D 1.33
B The acid becomes weaker.
C The degree of dissociation of the acid increases.
D The acid dissociation constant of this acid decreases.
 14. The reaction 2A + B + C D + E follows the rate law: Section B
2
Rate = k [A] [B]
If the concentration of A is halved, the concentration of B is tripled and
the concentration of C is doubled, what factor is the rate of reaction changed by? 16. The isotopic masses of some elements are shown in the table below:
A 4.5 B 3.0 C 1.5 D 0.75 Isotope Relative isotopic mass
1
H 1.0078
12
C 12.000
14
N 14.0031
16
15. Samples of hydrofluoric acid, HF and hydrochloric acid, HCl with same O 15.9949
concentration are diluted at constant temperature. Which of the following
graph best describe the variation of pH of the solution with dilution?
(a) High resolution mass spectrometers are included on planetary space
probes. Such a probe recorded gases with masses of 27.0109 and
31.0421.
Identity these two gases , which contain elements from the group
shown in the table :

Group Mass Identity of gas

A 27.0109

B 31.0421

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(b) It is possible to identify that given compound contains either chlorine from
the presence of M and (M+2) peaks in the mass spectrum of the compound.
State what species causes the (M+2) peaks in each of the following compounds.
C2 H5 Cl

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(c) State the differences in relative heights of M and (M+2) peaks in the mass
spectra of chlorine containing compound in (b)

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(d) Potassium was discovered and named in 1807 by the British chemist Sir
Humphrey Davy. The mass spectrum of a sample of potassium is shown below. 17. (a) Show the Lewis structure of ammonia and water molecule.

92

8 [2]

(c) Ammonia is a weak base. On mixing with water, ammonia forms an

(i) Use this mass spectrum to complete the table below alkaline solution.
Isotope % Proton Neutrons electrons (i) Write a balanced equation of this reaction.
composition
39
K
41
K [1]
[2]
(ii) A new bond is formed during this reaction. Name the type new bond
(ii) Calculate the relative atomic mass of potassium. formed and explain how this bond is formed.

[2]

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(d) A 15.3 kg sample of ammonia gas was compressed at 800K into a cylinder
of volume 300 dm3 .
Calculate the pressure in the cylinder assuming that the ammonia remained as a
gas.

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Section C. 19. (a) The kinetics of the reaction

18. 2NO (g) + Cl2 (g) 2 NOCl (g) ∆H = - 33 kJ mol-1

. (a) Explain the following Is second order with respect to NO and first order with respect to Cl2. The
activation energy of the reaction is + 6.7 kJ mol-1.
(i) The vapour pressure of a liquid will decrease when a non-volatile
solute is added. (i) Write the rate equation for the reaction.
(ii) Sketch an energy profile for the reaction showing all the relevant
(ii) carbon dioxide gas can be made to liquefy by pressurising the gas. energy changes.
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(b) Mixture of hexane ( C6H14) and heptanes ( C7H16) behave as ideal solution. (b) Consider the reaction at 55oC.

(i) Why do mixtures of hexane and heptanes behave ideally? (CH3)3CBr (aq) + OH- (aq) (CH3)3COH (aq) + Br- (aq)

(ii) Calculate the vapour pressure of a solution of 60.0 g of hexane and 45.0 g of A series of experiment is run with the following results:
heptanes at 293 K.
Experiment [(CH3)3CBr] mol [OH-] mol dm-3 Rate mol dm-3 s-1
dm-3
(iii) Sketch a labeled vapour pressure –composition diagram of the hexane-
1 0.50 0.050 5.0 x 10--3
heptane system at 293 K showing
2 1.0 0.050 1.0 x 10-2
(I) The vapour pressure – liquid composition relationship and 3 1.0 0.10 1.0 x 10-2
(II) The vapour pressure – vapour composition relationship.
(i) Find the order of the reaction with respect to (CH3)3CBr and OH-
[ At 293 K, vapour pressures of pure hexane and pure heptanes are 658 Pa and
(ii) Write the rate equation of this reaction.
471 Pa respectively ]
(iii) What is the effect of concentration of OH- on the rate of reaction?
(III) State the composition of the distillation if a solution containing Explain your answer.
equal molar of mixture of hexane and heptanes is fractional [8]
distilled.
(c) Below 550oC , the reaction NO2 (g) + CO (g) NO (g) + CO2 (g)
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obeys the rate law: rate = k [NO2]2. Suggest mechanism for this reaction.

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