Assignment

SECTION - A
Objective Type Questions (One option is correct)
Equilibrium and Factors Affecting
Equilibrium Constant
1. In which of the following does the reaction go almost to completion?

(1) ; K = 104

(2) ; K = 10−3

(3) ;K=1

(4) ; K = 10−1

2. At constant pressure, the addition of argon in Haber's process

(1) Reduces the formation of ammonia from N2 and H2
(2) Increases the formation of ammonia from N2 and H2
(3) Does not affect the equilibrium of the reaction in which ammonia is formed from N2 and H2
(4) Reduces the dissociation of ammonia
3. Consider the general hypothetical reaction

If the concentration of C at equilibrium is doubled, then after the equilibrium is re-established, the
concentration of B will be
(1) Twice of its original value
(2) Half of its original value

(3) times of original value

(4) times the original value

4. Pure NH3 is placed in a vessel at a temperature where its dissociation is appreciable. At equilibrium
(1) Kp does not change significantly with pressure
(2) Concentration of N2 does not change with pressure
(3) Concentration of NH3 does not change with pressure
(4) Kp changes with pressure but α does not change
5. Which of the following relation holds true for an equilibrium reaction, if its reaction quotient (Q) = 1?
(1) ∆G = 0 (2) ∆G° = 0 (3) ∆G > ∆G° (4) ∆G = ∆G°
6. For the equilibrium

The relation between Kp and Kc at 25°C and at 100°C are

(1) Kp = Kc, Kp = Kc
(2) Kp= Kc(RT)−1, Kp = Kc
(3) Kp= Kc(RT), Kp= Kc(RT)
(4) Kp = Kc(RT), Kp = Kc
7. What is the vapour density of mixture of PCI5 at 250°C when it has dissociated to the extent of
80%?
(1) 58 (2) 41.7 (3) 52.25 (4) 83.6

8. The equilibrum constant (Kp) for the reaction, at 1000

K is 3 5 atm−1
What would be the partial pressure of oxygen gas, if the equilibrium is found to have equal moles
of SO2 and SO3?
(1) 0.35 atm (2) 3.5 atm (3) 2.85 atm (4) 0.285 atm

9. For the equilibrium which of the following statements is true?

(1) The pressure changes do not effect the equilibrium

(2) More of ice melts, if pressure on the system is increased
(3) More of liquid freezes, if pressure on the system is increased
(4) Less of ice melts, if pressure on the system is increased

10. For the equilibrium , the molar mass at equilibrium was observed to be
60, then the degree of dissociation of SO3 would be
(1) 0.33 (2) 0.66 (3) 0.25 (4) 0.50
Ionic Equilibrium of Acid and Base
11. Conjugate acid of PO4−3 is
(1) H3PO4 (2) H3PO4− (3) HPO4−2 (4) HPO3−
−4 −6 −10
12. The dissociation constant of monobasic acids A, B and C are 10 , 10 and 10 respectively.
The concentration of each monobasic acid is 0.1 M. Which of the following has been arranged in
increasing order of pH?
(1) C < B < A (2) A < B < C (3) B < C < A (4) B < A < C
13. Among the following, which causes the greatest change in pH on addition to 50 ml of 0.2 M oxalic
acid solution?
(1) Addition of 25 ml of 0.02 M oxalic acid
(2) Addition of 25 ml of 1 M NaOH solution
(3) Addition of 2 ml of 0.02 M NH4OH solution
(4) Addition of 50 ml of 0.2 M acetic acid solution
14. What will be the H+ concentration in a solution prepared by mixing 50.0 ml of 0.20 M NaCI, 25 ml
of 0.10 M NaOH and 25.0 ml of 0.30 M HCI?
(1) 0.5 M (2) 0.05 M (3) 0.02 M (4) 0.10 M
15. To 250.0 ml of M/50 H2SO4, 4.0 g of solid NaOH is added and the resulting solution is diluted to
1.0 L. The pH of the resulting solution is
(1) 12.0 (2) 11.25 (3) 11.95 (4) 12.95
16. One mole of N2O4(g) at 300 K is kept in a closed container under one atmosphere. It is heated to
600 K when 20% by mass of N2O4(g) decomposes to NO2(g). The resultant pressure is
(1) 1.2 atm (2) 2.4 atm (3) 2.0 atm (4) 1.0 atm
17. If an aqueous solution at 25°C, has twice as many OH− as pure water, its pOH will be
(1) 6.7 (2) 7.3 (3) 7 (4) 6.98
Hydrolysis of Salt, Salt Hydrolysis
and Solubility Product
18. When a solution of benzoic acid was titrated with NaOH, the pH of the solution when half of the
acid neutralized was 4.2. Dissociation constant of the acid is
(1) 6.31 x 10−5 (2) 3.2 x 10−5 (3) 8.7 x 10−8 (4) 6.42 x 10−4
19. Solubility of AgCI in water, 0.01 M CaCI2, 0.01 M NaCI and 0.05 M AgNO3 are S1, S2, S3 and S4
respectively, then,
(1) S1 < S2 < S3 < S4 (2) S1 > S3 > S2 > S4 (3) S1 > S2 = S3 > S4 (4) S1 > S3 > S4 > S2
20. pH of Ba(OH)2 solution is 12. Its solubility product is
(1) 10−6 M3 (2) 4 x 10−6 M3 (3) 5 x 10−7 M3 (4) 5 x 10−6 M3
21. Solubility product constants (Ksp) of salts of types MX, MX2 and M3X at temperature 'T' are 4.0 x
10−8, 3.2 x 10−14 and 2.7 x 10−15, respectively. Solubilities (mol dm−3) of the salts at temperature 'T'
are in the order [IIT-JEE 2008]
(1) MX > MX2 > M3X (2) M3X > MX2 > MX (3) MX2 > M3X > MX (4) MX > M3X > MX2
−12
22. The Ksp of Ag2CrO4 is 1.1 x 10 at 298 K. The solubility (in mol/L) of Ag2CrO4 in a 0.1 M AgNO3
solution is [JEE(Advanced)-2013]
(1) 1.1 x 10−11 (2)1.1 x 10−10 (3) 1.1 x 10−12 (4) 1.1 x 10−9

SECTION - B
Objective Type Questions (More than one options are correct)

1. The following reaction attains equilibrium at high temperature

The concentration of NO(g) is affected by

(1) Increasing the nitrogen concentration
(2) Decreasing the hydrogen concentration
(3) Compressing the reaction mixture
(4) Addition of catalyst

2. For the reaction , the forward reaction at constant temperature is

favoured by
(1) Introducing an inert gas at constant volume
(2) Introducing Cl2(g) at constant volume
(3) Increasing the volume of the container
 (4) Introducing PCI5 at constant volume
3. If concentration of two acids are same, their relative strengths can be compared by

(1) (2) (3) (4)

4. Which of the following solutions will have no effect on pH on dilution?

(1) 0.1 M NH4OH + 0.1 M NH4CI
(2) 0.5 M H2CO3 + 0.5 M NaHCO3
(3) 1 M CH3COONH4
(4) 0.1 M CH3COONa
5. Which of the following is correct about the equilibrium?
(1) Catalyst has no effect on equilibrium state
(2) Keq changes with temperature
(3) Value of Keq changes by increasing concentration of equilibrium
(4) ∆G = 0
6. Which of the following statements are correct?
(1) The pH of 1.0 x 10−8 M solution of HCI is 8
(2) The conjugate base of H2PO4− is HPO4−2
(3) Auto-protolysis constant of water increases with temperature
(4) When a solution of weak monoprotic acid is titrated against a strong base, then, at half
neutralization point

7. Equal volumes of following solutions are mixed. In which case the pH of resulting solution will be
average value of pH of two solutions?
(1) pH = 2 (HCI) and pH = 12 (NaOH)
(2) pH = 2 (HCI) and pH = 4 (HCI)
(3) pH = 2 (HCN) and pH = 12 (NaOH) (Ka of HCN = 10−10)
(4) pH = 5 (CH3COOH) and pH = 9 (NH3) (aq) (Ka CH3COOH = KbNH4OH)

8. A weak base (BOH) with Kb = 10−5 is titrated with a strong acid HCI, at th of the equivalence point,
pH of the solution is
(1) 5 + log3 (2) 5 − log3 (3) 9 − log 3 (4) 8.523
9. 0.1 molar CH3COOH is titrated with 0.1 molar NaOH solution. What would be the difference in pH
between and stages of neutralization of acid?

(1) 2 log (2) 2 log 3 (3) 0.9542 (4) 0.3010

10. Which of the following solution will have pH close to 7?

(1) 100 ml of HCI + 100 ml of NaOH

(2) 1 M solution of CH3COONH4 (Ka = Kb)

(3) 100ml of H2SO4 + 100 ml of NaOH
 (4) 100 ml of HCI + 100 ml of Ca(OH)2

−12
11. 2.5 mL of M weak monoacidic base (Kb = 1 x 10 at 25°C) is titrated with M HCI in water at
25°C.
The concentration of H+ at equivalence point is (Kw = 1 x 10−14 at 25°C) [IIT-JEE2008]
−13 −7 −2
(1) 3.7 x 10 M (2) 3.2 x 10 M (3) 3.2 x 10 M (4) 2.7 x 10−2 M
12. Aqueous solutions of HNO3, KOH, CH3COOH, and CH3COONa of identical concentrations are
provided. The pair(s) of solutions which form a buffer upon mixing is(are) [IIT-JEE 2010]
(1) HNO3 and CH3COOH
(2) KOH and CH3COONa
(3) HNO3 and CH3COONa
(4) CH3COOH and CH3COONa
13. The thermal dissociation equilibrium of CaCO3(s) is studied under different conditions
[JEE(Advanced)-2013]

For this equilibrium, the correct statement(s) is(are)

(1) ∆H is dependent on T
(2) K is independent of the initial amount of CaCO3
(3) K is dependent on the pressure of CO2 at a given T
(4) ∆H is independent of catalyst, if any
14. For a reaction taking place in a container in equilibrium with its surroundings, the effect of
temperature on its equilibrium constant K in terms of change in entropy is described by
[JEE(Advanced)-2017]
(1) With increase in temperature, the value of K for exothermic reaction decreases because
favourable change in entropy of the surroundings decreases
(2) With increase in temperature, the value of K for exothermic reaction decreases because the
entropy change of the system is positive
(3) With increase in temperature, the value of K for endothermic reaction increases because the
entropy change of the system is negative
(4) With increase in temperature, the value of K for endothermic reaction increases because
unfavourable change in entropy of the surroundings decreases

15. For a reaction, , the plots of [A] and [P] with time at temperatures T1 and T2 are given
below.

If T2 > T1, the correct statement(s) is (are)

θ and θ
(Assume ∆H ∆S are independent of temperature and ratio of InK at T1 to InK at T2 is greater
than T2/T1. Here H, S, G and K are enthalpy, entropy, Gibbs energy and equilibrium constant,
respectively.) [JEE(Advanced)-2018]
 θ θ θ θ θ θ θ θ
(1) ∆H < 0, ∆S < 0 (2) ∆G < 0, ∆H > 0 (3) ∆G < 0, ∆S < 0 (4) ∆G < 0, ∆S > 0

SECTION - C
Linked Comprehension Type Questions

This section contains 5 paragraphs. Based upon each paragraph, some multiple choice questions
have to be answered. Each question has 4 choices (1), (2), (3) and (4), out of which ONLY ONE is
correct
Comprehension-I
Degree of dissociation : (α)
α are the number of moles which are dissociating from 1 mole of given reactants and gas density
measurements can be used to determine the degree of dissociation. Let us take a general case where
one molecule of a substance A splits up into n molecules of A(g) on heating i.e.,

Total number of Moles = a − aα + naα

= [1 + (n - 1)α] a
Observed molecular weight or molar mass of the mixture.

Choose the correct answer :

1. A sample of mixture A(g), B(g) and C(g) under equilibrium has a mean molecular weight (observed)
of 80.
The equilibrium is

Find the degree of dissociation α for A(g)

(1) 0.25 (2) 0.5 (3) 0.75 (4) 0.8
2. If the total mass of the mixture in question (1) is 300 gm, then moles of C(g) present are

(1) (2) (3) (4)

Comprehension-II
Pure water is neutral in nature [H+] = [OH−]. When this condition is disturbed by changing the
concentration of H+ or OH−, the neutral solution changes to acidic {[H+] > [OH−]} or basic {[H+] <
−
[OH ]}. This change occurs during salt hydrolysis. pH of salt solution can be calculated using the
following relation
(i) Salt of weak acid and strong base
 (ii) Salt of weak base and strong acid

(iii) For Salt of weak base and strong acid

The pH of buffer can be calculated using the following formula

Answer the following questions when

pKa = 4.7447
pKb = 4.7447
pKw=14
Choose the correct answer :
1. When 50 ml of 0.1 M NH4OH is added to 50 ml of 0.05 M HCI solution, the pH is nearly
(1) 1.60 (2) 12.40 (3) 4.75 (4) 9.25
2. When 50 ml of 0.1 M NaOH is added to 50 ml of 0.1 M CH3COOH solution, the pH will be
(1) 4.7447 (2) 9.2553 (3) 8.7218 (4) 1.6020
3. 1 mole of CH3COOH is dissolved in water to form 1 litre aqueous solution. The pH of resulting
solution will be
(1) 9.2253 (2) 2.3723 (3) 14 (4) 7
Comprehension - III
+
pH is the negative logarithm of H .
+
pH = − log[H ]
HCI → H+ + Cl−

Kw = [H+] [OH−]
Kw depend on the temperature. With rise in temperature Kw increases.
At 298 K, pH of pure water = 7
Choose the correct answer :
1. At 373 K, pH of the pure water is
(1) 7 (2) > 7 (3) < 7 (4) Cannot be stated
 + −1
2. The concentration of H in 10 M HCI given by

(1) 10−1 + 10−8 (2) (3) 10−1 (4) 10−1 − 10−7

3. The pH at first equivalence of H3PO4 vs NaOH titration at 298 K will be

(1) 7 (2) > 7 (3) < 7 (4) Depend on the concentration of titrant
Comprehension - IV
When 100 mL of 1.0 M HCI was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant
pressure, a temperature increase of 5.7 °C was measured for the beaker and its contents (Expt.1).
Because the enthalpy of neutralization of a strong acid with a strong base is a constant (−57.0 kJ
mol−1), this experiment could be used to measure the calorimeter constant. In a second experiment
(Expt. 2), 100 mL of 2.0 M acetic acid (Ka = 2.0 x 10−5) was mixed with 100 mL of 1.0 M NaOH (under
identical conditions to Expt.1) where a temperature rise of 5.6 °C was measured. (Consider heat
capacity of all solutions as 4.2 J g−1 K−1 and density of all solutions as 1.0 g mL−1)
[JEE(Advanced)-2015]
Choose the correct answer :
1. Enthalpy of dissociation (in kJ mol−1) of acetic acid obtained from the Expt.2 is
(1) 1.0 (2) 10.0 (3) 24.5 (4) 51.4
2. The pH of the solution after Expt. 2 is
(1) 2.8 (2) 4.7 (3) 5.0 (4) 7.0
Comprehension - V
Thermal decomposition of gaseous X2 to gaseous x at 298 K takes place according to the following
equation:

The standard reaction Gibbs energy, ∆rG°, of this reaction is positive. At the start of the reaction, there
is one mole of X2 and no X. As the reaction proceeds, the number of moles of X formed is given by β.
Thus, βequilibrium is the number of moles of X formed at equilibrium. The reaction is carried out at a
constant total pressure of 2 bar. Consider the gases to behave ideally. (Given : R = 0.083 L bar K−1
mol−1)
[JEE(Advanced)-2016]
Choose the correct answer :
1. The equilibrium constant Kp for this reaction at 298 K, in terms of βequilibrium, is

(1) (2) (3) (4)

2. The Incorrect statement among the following, for this reaction, is

(1) Decrease in the total pressure will result in formation of more moles of gaseous X
(2) At the start of the reaction, dissociation of gaseous X2 takes place spontaneously
(3) βequilibrium = 0.7
(4) Kc < 1
 SECTION - D

Assertion-Reason Type Questions

This section contains 13 questions. Each question contains STATEMENT-1 (Assertion) and
STATEMENT-2 (Reason). Each question has 4 choices (1), (2), (3) and (4) out of which ONLY ONE
is correct.
(1) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1
(2) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(3) Statement-1 is True, Statement-2 is False
(4) Statement-1 is False, Statement-2 is True
1. STATEMENT-1 : For a given reaction at fixed temperatures, equilibrium constants Kp and Kc are
related as Kp = Kc(RT)∆n.
and
STATEMENT-2 : ∆n = No. of moles of products - No. of moles of reactants.
2. STATEMENT-1 : Equilibrium constant does not depend upon concentration of various reactants,
presence of catalyst, direction from which equilibrium is reached
and
STATEMENTS-2 : Equilibrium constant is only dependent upon the temperature
3. STATEMENT-1 : The pKa of weak acid becomes equal to pH of the solution at the mid point of its
titration.
and
STATEMENT-2 : The molar concentration of proton aceptor and Proton donor becomes equal at
mid point of a weak acid.
4. STATEMENT-1 : When a small amount of strong acid is added to a buffer solution, its pH value
does not change significantly.
and
STATEMENT-2: Buffer action of the buffer solution resist the change in pH when small amount of
acid is added to it.
5. STATEMENT-1 : pH of water decreases with increase in temperature.
and
STATEMENT-2 : Kw of water decreases with increase in temperature.
6. STATEMENT-1 : It is difficult to distinguish between the strengths of the strong acids like HCI,
HNO3, HCIO4 etc. in dilute aqueous solution.
and
STATEMENT-2 : In dilute aqueous solution, all strong acids donate a proton to water and are
essentially 100% ionised to produce a solution containing H3O+ ions plus the anions of strong acid.
7. STATEMENT-1 : Solubility of BaSO4 in 0.1 M Na2SO4 is 10−9 M hence its Ksp is 10−18.
and
STATEMENT-2 : In aqueous solution, solubility product of BaSO4 = S2. (Where S is solubility of
BaSO4).
8. STATEMENT-1 : , for given equilibrium Kp = pCO2.
and
STATEMENT-2 : If we add CaCO3, equilibrium will shift in forward direction.

9. STATEMENT-1 : For , vapour pressure is P atm then Kp is equal to vapour

pressure.
and
STATEMENT-2 : Kp can be changed by adding mere H2O vapour from out side.

10. STATEMENT-1 : For a hypothetical equilibrium, , Kp is always greater

than Kc.
and
STATEMENT-2 : Relation of Kp and Kc will be Kp = Kc (RT)∆ng.
11. STATEMENT-1 : Buffer capacity is maximum when concentration of salt is equal concentration of
acid.
and

STATEMENT-2 : pH of the buffer is given by .

12. STATEMENT-1 : HCI is a strong acid and true electrolyte.

and
STATEMENT-2 : Liquid HCI is bad conductor of electricity.
13. STATEMENT-1 : For every chemical reaction at equilibrium, standard Gibbs energy of reaction is
zero.
and
STATEMENT-2 : At constant temperature and pressure, chemical reactions are spontaneous in
the direction of decreasing Gibbs energy. [IIT-JEE 2008]

SECTION - E

Matrix-Match Type Questions

This section contains 4 questions. Each question contains statements given in two columns
which have to be matched. The statements in Column-I are labelled A, B, C and D, while the
statements in Column-ll are labelled p, q, r, s and t. Any given statement in Column-I can have
correct matching with One OR More statement(s) in Column-ll.
1. Match Column-I with Column-ll.
Column-I Column-ll
(A) (p) ∆ng > 0
(B) (q) Kp < KC
(C) (r) Kp not defined
(D) (s) Kp > Kc

(assume temperature = 25°C)

2. Match Column I with Column II
Column-I Column-ll
(A) 25 ml of 0.1 M NaOH + 50 ml of 0.1 M (p) Basic buffer
CH3COOH
(B) 25 ml of 0.1 M NaOH + 25 ml of 0.1 M HCI (q) Acidic buffer
(C) 25 ml of 0.1 M HCI + 50 ml of 0.1 M NH4OH (r) pH > 7
(D) 25 ml of 0.1 M NH4OH + 25 ml of 0.1 M (s) pH = 7
CH3COOH
Given (Ka = Kb)
3. Match the following
Column 1 Column II
(A) NaH2PO4 + Na2HPO4 (p) Buffer system

(B) 100 ml Aniline + 100 ml H2SO4 (q) pH < 7

(C) 100ml CH3COOH + 100ml NaOH (r) pH changes on dilution

(D) 100 ml H2C2O4 + 100 ml KOH (s) Salt hydrolysis occurs

(t) pH > 7

4. Dilution processes or different aqueous solutions, with water, are given in Column I. The effects of
dilution of the solutions on [H+] are given in Column II.
(Note: Degree of dissociation (α) of weak acid and weak base is << 1; degree of hydrolysis of salt
<<1; [H+] represents the concentration of H+ ions) [JEE(Advanced)-2018]
Column I Column II
(A) (10 mL of 0.1 M NaOH + 20 mL of 0.1 M (p) the value of [H+] does not change on dilution
acetic acid) diluted to 60 mL
(B) (20 mL of 0.1 M NaOH + 20 mL of 0.1 M (q) the value of [H+] changes to half of its initial value
acetic acid) diluted to 80 mL on dilution
(C) (20 mL of 0.1 M HCI + 20 mL of 0.1 M (r) the value of [H+] changes to two times of its initial
ammonia solution) diluted to 80 mL value on dilution
+
(D) 10 mL saturated solution of Ni(OH)2 in (s) the value of [H ] changes to times of its initial
equilibrium with excess solid Ni(OH)2 is value on dilution
diluted to 20 mL (solid Ni(OH)2 is still
present after dilution).
(t) the value of [H+] changes to times of its initial
value on dilution
Match each process given in Column I with one or more effect(s) in Column II. The correct option is
(1) A(s); B(q); C(r); D(p)
(2) A(s); B(r); C(q); D(r)
(3) A(p); B(s); C(t); D(r)
(4) A(p); B(t); C(s); D(p)
 SECTION - F

Integer Answer Type Questions

This section contains 10 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. For example, if the correct answers to question numbers X, Y and Z (say) are 6, 0
and 9, respectively, then the correct darkening of bubbles will look like the following :

1. Equal volulmes of solution with pH = 6 and pH = 8 are mixed. What will be the pH of resulting
mixture?

2. In Homogeneous gaseous equilibrium, . Initial concentration of M is equal to that of

N. If equilibrium concentrations of M and P are equal then what will be the value of Kc?
3. Ka for a monobasic organic acid is 2 x 10−5. What is pH of 0.2 M aqueous solution of its salt formed
with KOH?

4. For equilibrium , equilibrium pressure is 3 atm. What will be

the value of Kp?
5. Find the pH of a buffer solution having equal volumes of 0.2 M NH4OH and 0.2 M NH4CI
(Kp for base = 1.0 x 10−5).
6. The dissociation constant of a substituted benzoic acid at 25°C is 1.0 x 10−4. The pH of a 0.01 M
solution of its sodium salt is [IIT-JEE 2009]
7. Amongst the following, the total number of compounds whose aqueous solution turns red litmus
paper blue is [IIT-JEE-2010]
KCN K2SO4 (NH4)2C2O4 NaCI Zn(NO3)2
FeCI3 K2CO3 NH4NO3 LiCN
8. In 1 L saturated solution of AgCI [KSP(AgCI) = 1.6 x 10−10], 0.1 mol of CuCI [KSP(CuCI) = 1.0 x 10−6]
is added. The resultant concentration of Ag+ in the solution is 1.6 x 10−x. The value of "x" is.
[IIT-JEE 2011]
9. MX2 dissociates into M2+ and X− ions in an aqueous solution, with a degree of dissociation (α) of
0.5. The ratio of the observed depression of freezing point of the aqueous solution to the value of
the depression of freezing point in the absence of ionic dissociation is [JEE(Advanced)-2014]
10. The solubility of a salt of weak acid (AB) at pH 3 is Y x 10−3 mol L−1. The value of Y is ___. (Given
−10
that the value of solubility product of AB (Ksp) = 2 x 10 and the value of ionization constant of HB
−8
(Ka) = 1 x 10 ) [JEE(Advanced)-2018]

SECTION - G

Multiple True-False Type Questions

Identify the correct combination of true (T) and false (F) of the given three statements.
1. STATEMENT-1 : pH of water at 25°C is less than the pH at 4°C.
STATEMENT-2 : Water is more acidic at 25°C than at 4°C.
STATEMENT-3 : Water is neutral at all temperatures
(1) T F T (2) F F T (3) F T T (4) T T F
2. STATEMENT-1 : Autoprotolysis constant of water increases with the increase in temperature.
STATEMENT-2 : When a solution of a weak monobasic acid is titrated with a strong base, at half
neutralization point pH = pKa + 1.
−8
STATEMENT-3 The pH of 10 M HCI is 8.
(1) F F T (2) T F F (3) F T T (4) T T T
3. STATEMENT-1 : Net reaction can occur only if a system is in equilibrium.
STATEMENT-2 : All reaction tends to be in a state of equilibrium.
STATEMENT-3 : At equilibrium, ∆G is zero.
(1) T T F (2) F T T (3) T T T (4) F T F
4. STATEMENT-1 : Catalyst change the activation energy.
STATEMENT-2 : Catalyst can change equilibrium.
STATEMENT-3 : Kp is temperature dependent.
(1) T F T (2) F T T (3) F F T (4) T T T

SECTION - H

Aakash Challengers Questions

1. The exact concentration of H+ ion in 10−3 molar HCl aq. solution at 298 K is

(1) 10−3 + 10−7 (2) (3) (4) 10−3

2. In ammonia formation process, due to increase in pressure, equilibrium will shift in

(1) Forward direction
(2) Backward direction
(3) No effect
(4) May be forward or in backward direction
3. 4 mole of N2O4 is taken in container of unit volume at any temperature. After some time, equilibrium
is attained and vapour density of mixture is 34.5. The value of ∆G will be
(1) Zero (2) 9.2 kcal (3) 50 kcal (4) Data is insufficient to calculate
4. Which of the following pH curve represent the titration of weak acid and strong base (dotted line
show equivalence point)?
 (1) (2)

(3) (4)

Which of the following equilibrium will shift in forward direction on increasing pressure?

(1) (2)

(3) (4) Both (2) & (3)

6. The equilibrium constant of given reaction will be

(1) (2) (3) (4)

7. Ammonium hydrogen sulphide dissociated according to the equation:

If observed pressure of the mixture is 1.12 atm at 106°C, what is the equilibrium constant Kp of the
reaction?
8. The density of an equilibrium mixture of N2O4 and NO2 at 1 atm and 348 K is 1.84 g/dm3. Calculate
the equilibrium constant Kp of the reaction.

9. 15 g sample of BaO2 is heated to 794°C in a closed evacuated vessel of 5 litre capacity. How many
g of peroxide are converted to BaO(s)?

10. Calculate the pH at equivalence point of the titration between 0.1 M CH3COOH (25 ml) with 0.05
M NaOH. Ka for CH3COOH = 1.8 x 10−5.
11. Calculate change in phi of 1 L buffer solution containing 0.10 Mole each of NH3 and NH4CI upon
addition of
(i) 0.02 mole of dissolved gaseous HCI.
(ii) 0.02 mole of dissolved NaOH. (Assuming volume to be constant). Kb(NH3) = 1.8 x 10−5
12. Two solid compounds A and B dissociate into gaseous products at 20°C as

(i)

(ii)
 At 20°C, pressure over excess solid A is 50 mm and that over excess solid B is 68 mm of Hg. Find
(a) The dissociation constant of A and B.
(b) Relative number of moles of Aʹ and Bʹ in the vapour phase over a mixture of solid A and B at
20°C.
(c) Show that the total pressure of gas over the solid mixture would be 84.4 mm of Hg.
−5 3 −3
13. The solubility product of Ca(OH)2 at 25°C is 4.42 x 10 mole litre . A 500 ml of saturated
solution of Ca(OH2) is mixed with equal volume of 0.4 M NaOH solution. How much Ca(OH)2 in
milligrams is precipitated?
14. The pH of blood stream is maintained by a proper balance of H2CO3 and NaHCO3 concentrations.
What volume of 5 M NaHCO3 solution, should be mixed with 10 ml sample of blood, which is 2 M
in H2CO3 in order to maintain a pH of 7.4? Ka for H2CO3 in blood is = 7.8 x 10−7.
15. The solubility product of BaSO4 and BaCrO4 at 25°C are 1 x 10−10 and 2.4 x 10−10 respectively.
Calculate the simultaneous solubilities of BaSO4 and BaCrO4.
 ASSIGNMENT
Section A : Objective Type Questions (Only one answer)
1. (1) 2. (1) 3. (4) 4. (1) 5. (4) 6. (4) 7. (1) 8. (4) 9. (2) 10. (2) 11. (3) 12. (2) 13. (2) 14. (2) 15. (4)
16. (2) 17. (1) 18. (1) 19. (2) 20. (3) 21. (4) 22. (2)
Section B : Objective Type Questions (More than one answer)
1. (1, 2, 3) 2. (3, 4) 3. (1, 3, 4) 4. (1, 2, 3) 5. (1, 2, 4) 6. (2, 3) 7. (1, 4) 8. (3, 4) 9. (2, 3) 10. (1, 2) 11.
(4) 12. (3, 4) 13. (1, 2, 4) 14. (1, 2, 4) 15. (1, 3)
Section C : Linked Comprehension Type Questions
Comprehension-I
1. (1) 2. (3)
Comprehension-II
1. (4) 2. (3) 3. (2)
Comprehension-Ill
1. (3) 2. (3) 3. (3)
Comprehension-IV
1. (1) 2. (2)
Comprehension-V
1. (2) 2. (3)
Section D : Assertion-Reason Type Questions
1. (3) 2. (2) 3. (1) 4. (1) 5. (3) 6. (1) 7. (4) 8. (3) 9. (3) 10. (4) 11. (2) 12. (4) 13. (4)
Section E : Matrix Match Type Questions
1. A(q), B(p, s), C(p, s), D(r)
2. A(q), B(s), C(p, r), D(s)
3. A(p, q, s), B(q, r, s), C(r, s, t), D(r, s, t)
4. (4)
Section F : Integer Answer Type Questions
1. 7 2. 8 3. 9 4. 4 5. 9 6. 8 7. 3 8. 7 9. 2 10. 4.47
Section G : Multiple True-False Type Questions
1. (1) 2. (2) 3. (3) 4. (1)
Section H : Aakash Challengers Questions
1. (2) 2. (1) 3. (1) 4. (2) 5. (4) 6. (1)
7. Kp = 0.3136 atm2 8. 5.14 atm 9. 9.633 g 10. pH = 8.63
11. (i) ∆pH = 0.1761 unit (ii) ∆pH = 0.1761 unit
2
12. (a) KA = 625 (mm) of Hg
KB = 1156 (mm)2 of Hg
(b) nAʹ = 14.81 and nBʹ = 27.38

or
13. 758.2 mg 14. V = 78.37 ml 15.