TARGET CH E M IST RY

JEE - 2023
CLASS : 11TH DPP-- (Stability of Intermediates) DATE 11/03/2022
SUBJECTIVE QUESTIONS
1. Which of the following carbocation can undergo rearrangement :

(a) (b) (c) (d)

(e) (f) (g) (h)

(i) (j) (k) (l) (n)

2. Stability order of following carbocations is :

CH3 CH3
|  |
(I) CH3 – O – CH2 CH2  CH  CH2 (II) CH3 – O – CH2 CH2  C  CH3


CH3 CH3
 |  |
(III) CH3 – O – CH2 CH  CH  CH3 (IV) CH3 – O – C H CH2  CH  CH3
3. Arrange the following carbocations in decreasing order of their stability :

(I) (II) (CH3CH2)2 (III) (CH3CH2)3 (IV)

OBJECTIVE QUESTIONS
1. What is NOT-True for inductive effect but True 3. Decreasing order of potential energy of the
for Resonance effect (During their functioning) folowing cations is :
(Inductive effect) (Resonance effect)
(A) electron pair is delocalised -electron pair
delocalized
(B) electron pair is localized -electron pair is
localized
(I) (II)
(C) Bond angle does not change -electron pair is
localized
(D) Hybridisation of atoms changes -electron pair is
localized
2. The most unlikely representation of resonance (III)
structures of p-nitrophenoxide ion is:
(A) II > I > III (B) I > II > III
(C) III > II > I (D) II > III > I

(A) (B) (C) (D)

Sanshiksha Head Office: 2nd Floor,Zameer Compound,Above SBI city branch,Canal Road ,Raebareli. Ph.7705002074/75 [1]

Academy Branches :
Conatct Nos.
Lalganj
95-1111-7777
/
/
NTPC Unchahaar Campus
9305160331 /
/ Orai
91-25-26-27-28
4. Least contributing resonating structure of
nitroethene is :

(A) (B)

(C) (D)

5. The least and most stable resonating structure (A) x > w > y > z (B) z > y > w > x
respectively are : (C) x > z > y > w (D) y > z > w > x
10. Correct dipole moment order is :
(1) (2)
CH2  CH  Cl CH3  CH2  Cl
(p) (q)
(3) (4)
CH2  CH  CN
(A) 2, 1 (B) 2, 3 (r )
(C) 3, 1 (D) 1, 2
6. In which case the -bond pair and  bond pair of (A) r > q > p (B) r > p > q
electrons both are attracted in the same direc- (C) q > r > p (D) p > r > q
tion, (towards same atom.) : 11. Which of the following is most stable carbocation ?
 
(A) H2C = CH — Cl (B) CH3 – CH2 – NH2 (A) CH – C H (B) C H – CH Cl
3 2 2 2
(C) H2C = CH – CH = O (D) H2C = CH – OCH3
 
7. Hyperconjugation is possible in : (C) C H – CH – Cl (D) C H – CCl
2 2 2 3
12. The most stable carbocation is :

(A) (B) (A) (B)

(C) (D)
(C) (D)

13. Arrange the following carbanions in decreasing

order of stability :
8. Stability of -bond in following alkenes in the
increasing order is :
CH3–CH = CH – CH3

(A) III > II > IV > I (B) III > II > I > IV
(C) III > I > II > IV (D) II > III > I > IV
14. Give the stability order of following radicals :
(I) (II)
(III) (IV)
(I) (II)
(A) I < III < IV < II (B) I < II < III < IV
(C) IV < III < II < I (D) II < III < IV < I
9. The decreasing order of electron density on the (III) (IV)
ring is :
(A) III > IV > II > I (B) IV > III > II > I
(C) I > II > III > IV (D) IV > II > III > I

ANSWER KEY
1. (A) 2. (C) 3. (A) 4. (C) 5. (C)
6. (C) 7. (A) 8. (A) 9. (B) 10. (A)
11. (A) 12. (D) 13. (B) 14. (B)

Sanshiksha Head Office: 2nd Floor,Zameer Compound,Above SBI city branch,Canal Road ,Raebareli. Ph.7705002074/75 [2]

Academy Branches :
Conatct Nos.
Lalganj
95-1111-7777
/
/
NTPC Unchahaar Campus
9305160331 /
/ Orai
91-25-26-27-28