(SN REACTIONS) CHEMISTRY UT-JEE CPP - HALIDES (: ‘Which of the folowing is correct (assume Sx2): ie 0 Mnf Me ncn ° Mo ° ° ©) tong MM noon fH te te LAID... optically inactive (©) Atotinese In which stop, inversion occurs: Ye Me saws H-G-cr Kos cn-C-H a... 6 3 (ay 1 (BH «C) both (0) None ln which the order written is incorrect: (A) Mel > EtBr >Me,CHCI>Me,CCI — (Sx2 kn) (8) HO" >E10" > E1,CHO” > Et,CO™ (leavabiliy) (C) Me,CCH,| > Me,CCH,Cl > Me,CCH,Br > Me,CCH,F (S12 reactviy) (0) None of these CHD Br at a ° (A)_productis optically inactive () inversion at lower chiral carbon (C)inversion at both the chiral carbon atoms (0) None of these The dielectric constants of the four solvents follows the order S3 << Sz < $= Sz. Among them only S2 and Ss can make hydrogen bonds. Which solvent will be most ‘suitable for Swi reaction? A) Si (8) & (C) Ss ) Ss 99 ; rr r Decreasing order of Su! reactivity of compounds @i>i>m — (B)l>Ml>N (C)il> itl >t (O)iti>t>tl Which substrate on rkn with CH3OH gives dl mix. H CH, cH-g-cH-ci ©) cH-t-cH-cl 4 4 CH,CH, ©) c-¢-cH,-c1 4 ES Correct forthe reaction is HCH, © curpenres B Correct reactivity order(s) for St reaction is/are: (1) Ph-Br-Br (2) Ph-Br > PhCH.Cl (3) ON ‘CHe-I > CHy ‘CHe-T “) A, > Ae A123 (82,4 (0)2,3,4 (C)1,4 Decreasing order of Sx2 rkn with KI in acetone Oa ofa ch, cH -cH & o am cH,-clCH,-O-CH,-cl Ww ) (Ayv>naiv>teml— (@)ll> Vata ll {ivoVe aia (O)Mll>WV>lt> Vo! 10, (A): bridge head halide lke norbory! bromide is inert for Sy1 reaction Br (R): Carbonivis Yon at bridgehead position cannot be formed because planarity is not possible. (A) (A) & (R) are true & (R) explains (A). {B) (A) & (R) are true & (R) does not explain (A). (C)(A)is True, (R) is False (0) (A)is False, (R) is True 114, 1% member is less reactive than 2 (Sw1 Fkn) io c AA 12. In which triplets at least two satisty St (A) weak nucleophile, polar protic solvent, wo step mech. (B)carbonium ion intermediate, heterolysis due to ‘nucleophile, partial racemisation. (C)complete racemisation, polar protic solvent, ‘carbonium ion intermediate. (0) All of these 13, 1 Equnalent NaCN _LEauhalent NECN ay product (is: ate oor o% n wo? a i 4 z a on 7 e wo « 0 EOD @ o Mechanism of Conversion of Ito Il: (A) takes place by Sx1 (B) _ takes ptace by Sx2 (C) takes place by Swi (D) does not take place 15, Rate of Sx2 will be negligible in: Br er Br Br “ Oe oO © Oo ©) O16. 17 18, 19, 20. 21. ‘The greater Sx2 reaction is in each pair is for? ° 24, eo ALe en 0 Lobes “on (Q) (il) HyC-Br + "SH (IV) HC-Br + CHySH MC rare ct om (B47 in ows (3049 (24 0 0m Br « in cron 25. PQrRs PQes (iW vv @u m vow (ci om ov vm or m vow Decreasing nucleophiliciy in polar protic solvent is (WV CHSCHACHO™ (I) CHCH.CH,S™ (Wl) CH,CH,COO- (A) Ml>toll (B) tettist (C) tots (0) stot eee TO OY cn to o wo ay Oy) leaving tendency in Sy reaction is (A) lois il>v @) I>t>iveil (C) WV>i>n>m ° age @ OS Gaon’ Br ‘Time for formation of ethers while ethanolysis in same condition are te, ta, te, te. Which is correct? (A) W 29. ©) (ony,c-crycl + (C)—o > Me Hef optical nature (A) & (8) are cH 7 CO) (A) active, active (B) inactive, inactive (©) active, inactive (0) inacve, active R fw, «|, attained at t= fp and the product is obtained at 1¢ % S-character of attacked carbon at t= tz (0 < tz ‘Ro>Ry (8) Ra>Re>Ry (©) Rr>Ri>Ry (0) Ra>Ro>Ry whee Halides (S, Reactions) (0) V>t>t>1 2. (CPP-CHEMISTRY The order of reactivity for Sut reaction is: 0 m& a CF - & t (Allie to G)M>H>1 Chasm >1 On >1>m o OS a. wre Some OPES (PIs SS] i+ (O)nereactonis possible te ee NEON. product Which is comect? o \) product is optically inactive g (5 contsraton ae ove cial cate i rvenes (C) configuration about both chiral C atoms is inverted (0) None of these Which wil react faster with KWacetone in given pair? CHB CH,CH,6r é “0 ® oO (i) Os-0-F-Cag 8 CHa 3 8 a 8 a AAA BB (CBA AB ‘Which ofthe following statement is incorrect for Sy2? (A) The reaction follows second order kinetics (6) The rate depends upon the [nucleophile] (C) one step reaction through formation of transition state (0) The rate is increased on changing the solvent from Polar aprotic to polar protic {In which of the following pairs first member is tess reactive than second member towards Sut reaction: wh . ot °C» O- Which is not correct about $2? (A) Rate of Sx2.is directly proportional to the dislectic ‘constant of medium, (8) Rate of Si2 is directly proportional to the nature of leaving group. (C) Rate of Sy2 inversely proportional to the steric hindrance present in substrate (base) (eubsrae)FIITIEE at. 3. Identify correct reactivity order for Sy1 reaction Br >i >i Identify correct reactivity order for Sy1 reaction I Br cl 0 CO “i O “CY (iris ti @) (i>ii>i (O)ii>i>i Identity correct reactivity order for Sy1 reaction a OTs ots 0 “ Oy (iri it (i> i> (Qi>it>i (O)ii>i> a Identify correct reactivity order for Sy1 reaction a cl ca “OhiG te oO N’ B (A) i> i> i (8) i> i> (C)i> i> i (O)ii>i>i Identity correct reactivity order for Sy' reaction cl cl cl 0 0) «i Mer Me (i> i> i (B)i>ii>7 (C)i> >i (0) i> i> Ranchi (Lalpur):7th Flocr, Hari Om Towers, Ranchi (SOP, Doranda): Samrii (Opp. Women's College, As Block), Crcular Road, Ranchi, Ph: 0651-2563187/84/69.90 idhi Complex, Ground Floor, Near St. Xavier's School, South Office Para Doranda, Ranchi Jamshedpur : Om Piaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur €FlITIEE ion Qs. deny oie reacty of vce for Sut ert OD ‘i db w d (eyii> i> | 2 fats i (D) ili> Q7. Identify correct reactivity order for Swi reaction ‘Me. Me, 4, Op @ Op ii) (=o Me Me (A) i> ii> ii (B) i> iti>i (C)i>ii> ii (D)ii> i> ii QB. Identify correct reactivity order for Sy1 reaction () Ph—CH,—Br (i) Ph—Br i) Br (aire ii (i> iio (C)i>ii> i (O)ili> i> it Q9. Identify correct reactivity order for S,1 reaction O° \, I 0) © “ oy (iy »o-4 Br Oo (A) i> ii> iii (B) ii > ii > it (C)i>iii>ii (D) iii> i> ii Q10. Identify correct reactivity order for Sy1 reaction. cl a cl eg te “CF (isi (iirisi Q11. Identify correct reactivity order for Sy2 reaction ca cl ca (} CK (ii) Ce (ii) (Ay i> i> i (B)it> i> i (D)ili>i> it Ranchi (Lalpur) 7th Flor, Hari Om Towers, (Opp. Women's College, Arts Block), Cicular Road, Ranchi, Ph : 0851-2563187/28/69/60, Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier's School, South Office Para oranda, Ranchi ‘Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, JamshedpurJEE 12. Identit fy correct reactivity order for S\2 reaction a dhe i cl i> a> it © A-% Wy Hyo—cH~c1 C) i> ii (B)i> i> Oat (0) i> i> i Q13. Identity orect reactivity order for Sx2 reaction ‘O (i) 0 i) é No, (A) i>i> i (8) i>ii>i (C)i> i> i (O)it>i>i Q14. Identity correct reactivity order for S42 reaction Cl ora wa AX" WA (i> i> ii (@)ii> i> i (C) i> ii> ii (O)iii> >i Q16, _dentty corect reactivity order for $y2 reaction cl cl ey ee oe oO soft Ps (Basi i Oi k Orion Ranchi (Lalpur ‘7th Floor, HariOm Towers, (Opp. Women's College, As Block), Circular Road, Ranch, Ph. O86: 2863 18FISSSVLO Ranchi (SOP, Doranda): Samridchi Complex, Ground Floor, Near St. Xavier's School, South Ditice Para Davanda, Ranch ‘Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamanedput nee ee