DPP No.

06
TARGET : JEE-2024 Max. Time : 50 Min.

DPP No. : 06 (JEE-MAIN)

SCQ (Only one correct) :
1. CH3 COO D
I II III
Among these groups, which of the following orders is correct for the magnitude of their +I effect ?
(A) I > II > III (B) III > II > I (C) II > I > III (D) III > I > II
Ans. (C)
Sol. Order of +I effect —COO– > –CH3 > –D

2. In which of the following species, incorrect direction of Inductive effect is shown ?

N=O CHO O
(A) (B) (C) (D) CH3 CH2MgBr
O
Ans. (A)
Sol. Case A has incorrect direction of I-effect.

3. Maximum –I effect is exerted by the group

(A) C6H5 (B) –OCH3 (C) –Cl (D) –NH2
Ans. (C)
Sol. Maximum – I effect – Cl.

4. Which order of I effect is incorrect.

 
(A)  N(CH3 )3   S(CH 3 ) 2 [ I] (B) OCH 3   OH [  I]

(C)  F  Cl [  I] (D) CH3   O [ I]
Ans. (D)
Sol. It is experimental fact of order of inductive effect.

5.  NO 2  Cl I
I II III
Which of these groups has –I effect ?
(A) I (B) II (C) III (D) All of these
Ans. (D)
Sol. –NO2, –Cl and –I these all are –I groups.

6. Maximum –I effect is exerted by the group ?

(A) C6H5 (B) –OCH3 (C) –Cl (D) –NO2
Ans. (D)
Sol. –NO2 group has maximum – I effect.

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7. In which of the following compounds the direction of Inductive-effect is not correct ?
CH = CH2
MgBr COOH
COONa
(A) (B) (C) (D)
OH NaO
C CH
Ans. (C)
CH = CH2

Sol.

C CH

8. Which of the following case has correct direction of I effect ?

O–H
ONa
CHO
(A) (B) (C) (D) CH3CH 2 Li
CH3
COOK
Ans. (D)
Sol. Carbon is more electro negative than lithium.

9. Which of the following statement is incorrect for the inductive effect ?

(A) It is a permanent effect (B) It transmits through sigma electrons
(C) It is represented by   (D) It is represented by or
Ans. (C)
Sol. Inductive effect is paramanent effect, which is applicable only on sigma bond.

–CH2–CH2–O –O –CH2–O
10.
I II III
Among these groups, which of the following orders is correct for the magnitude of their +I effect ?
(A) I > II > III (B) I > III > II (C) II > I > III (D) II > III > I
Ans. (D)
Sol. –O– > –CH2–O– > –CH2–CH2–O– . This is order of +I effect. Which is decrease on increase distance.

11. Which of the following statement is CORRECT regarding the inductive effect?
(A) electron-donating inductive effect(+I effect) is generally more powerful than electron-withdrawing
inductive effect (–I effect)
(B) it implies the shifting of  electrons from more electronegative atom to the lesser electronegative atom
in a molecule
(C) it implies the shifting of  electrons from less electronegative atom to the more electronegative atom
in a molecule
(D) it increases with increase in distance.
Ans. (C)
Sol. Inductive effect is applicable only on sigma bond and more electro negative atom / group withodraw
sigma bond electron.

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12. Resonance structure of the molecule does not have
(A) Higher energy than their hybrid structure (B) Identical arrangement of atoms
(C) The same number of paired electrons (D)Always equal contribution to the resonance hybrid.
Ans. (D)
Sol. Different resonating structure give unequal contribution to resonance hybrid and more stable resonating
structure give more contribution to the resonance hybrid.

13. A compound (C5 H8) gives white ppt. with ammonical AgNO3 and on reduction followed by monochlorination
it gives 4 structrual monochloro products. What is the possible structure of compound ?
(A) CH3CH2 – CH2 – CH = CH2 (B) CH3 – CH2 – C  CH
(C) (CH3)2 CH – C  CH (D) CH2 = CH – CH2 – CH = CH2
Ans. (C)
C5H8 ; DU = 2
Terminal alkyne can give positive tollen’s test (ammonical AgNO3).

14. Acetaldehyde and Acetone can be distinguish by :

(A) 2,4–DNP (B) I2/NaOH (C) Lucas reagent (D) Ammonical AgNO3
Ans. (D)
Sol. Acetaldehyde give positive Tollen (Ammonical AgNO3) but ketones are not

15. Acetaldehyde and Propyne can be distinguish by :

(A) NaHCO3 (B) I2/NaOH (C) Lucas reagent (D) neutral FeCl3
Ans. (B)
Sol. Acetaldehyde and Propyne can be distinguish by Iodoform test.

16. and are :

(A) Identical isomer (B) Positional isomer

(C) Functional isomer (D) Chain isomer
Ans. (C)

17. Which common name is wrong ?

(A) (Asprin)

(B) Acetophenone

(C) Picric Acid

(D) Benzyl alcohol

Ans. (A)

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18. How many carboxylic acid structure isomers are possible with C5H10O2 ?
(A) 3 (B) 4 (C) 5 (D) 8
Ans. (B)

H 2 (1 eq.) Cl 2
19. (P) C7 H12  Ni
 (Q)C7 H14 
hv
5–Monochloro structural products
Identify the structure of P

(A) (B) (C) (D)

Ans. (A)

H 2 (1 eq.) Cl2
Sol.  Ni
 
hv
(5–Monochloro structural products)

20. An alkene on ozonolysis gives only one product (Z). Z on reaction with Fehling solution give red precipitate
of Cu2O. Alkene will be ?
(A) Ph–CH=CH–Ph (B) (CH3)2C=C(CH3)
(C) CH3–CH=C(CH3)2 (D) CH3–CH=CH–CH3
Ans. (D)

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