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5 DDB 1 e 26
5 DDB 1 e 26
5 DDB 1 e 26
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : For professional use only
Use of the substance/mixture : Liquid Organo-Mineral Fertilizer
GHS07
Signal word (CLP) : Warning
Contains : 2-methylisothiazol-3(2H)-one
Hazard statements (CLP) : H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
Precautionary statements (CLP) : P261 - Avoid breathing vapours.
P264 - Wash hands, forearms and face thoroughly after handling.
P280 - Wear protective gloves.
P302+P352 - IF ON SKIN: Wash with plenty of water.
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
3.1. Substances
Not applicable
3.2. Mixtures
hydrogen sulphide CAS-No.: 7783-06-4 < 0.01 Flam. Gas 1A, H220
substance with a Community workplace exposure limit EC-No.: 231-977-3 Press. Gas (Comp.), H280
EC Index-No.: 016-001-00-4 Acute Tox. 2 (Inhalation), H330
Aquatic Acute 1, H400 (M=10)
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
ethanediol (107-21-1)
EU - Indicative Occupational Exposure Limit (IOEL)
Remark Skin
sulfur (7704-34-9)
PNEC (Oral)
PNEC (Water)
PNEC (STP)
PNEC (Water)
PNEC (Sediment)
PNEC (Soil)
ethanediol (107-21-1)
DNEL/DMEL (Workers)
PNEC (Water)
PNEC (STP)
Eye protection:
Safety glasses. Safety goggles with side protection against splashes (UNE-EN 166:2002)
Hand protection:
Standard EN 374 - Protective gloves against chemicals.
Respiratory protection:
No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. In case of inadequate
ventilation wear respiratory protection.
10.1. Reactivity
The product is stable at normal handling and storage conditions.
sulfur (7704-34-9)
LD50 oral rat > 2000 mg/kg bodyweight
ethanediol (107-21-1)
LD50 dermal rabbit 10600 mg/kg
2-methylisothiazol-3(2H)-one (2682-20-4)
pH 2.58
2-methylisothiazol-3(2H)-one (2682-20-4)
pH 2.58
sulfur (7704-34-9)
NOAEL (oral, rat) 1000 mg/kg bodyweight (90 days)
sulfur (7704-34-9)
NOAEL, subchronic, oral, rat, systemic 1000 mg/kg bw/day
ethanediol (107-21-1)
STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met.)
12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Hazardous to the aquatic environment, short–term : Not classified (Based on available data, the classification criteria are not met.)
(acute)
Hazardous to the aquatic environment, long–term : Not classified (Based on available data, the classification criteria are not met.)
(chronic)
ethanediol (107-21-1)
LC50 - Fish [1] 54700 mg/l 96 h
TRIUMPHALIS
Persistence and degradability Once sulfur is released into the environment, is rapidly oxidized by bacteria, other
microorganisms or spontaneously by the presence of oxygen, to become organic sulfur
compounds. Sulfur is incorporated to the food chain by the action of the microorganism
present In water and soil, through oxidation and reduction reactions allowing the
assimilation of these compounds by higher plants and animals.
sulfur (7704-34-9)
Persistence and degradability Not established.
TRIUMPHALIS
Bioaccumulative potential Sulfur has, generally, a lifecycle and a mobility similar to nitrogen's, characteristic of those
nutrients essential for cellular life development. It is not solubilized in water.
ethanediol (107-21-1)
Partition coefficient n-octanol/water (Log Pow) -1.36
TRIUMPHALIS
PBT: not yet assessed
Overland transport
Not regulated
Transport by sea
Not regulated
Air transport
Not regulated
Rail transport
Not regulated
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
3(b) TRIUMPHALIS ; Substances or mixtures fulfilling the criteria for any of the following hazard classes or
ethanediol categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6,
3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other
than narcotic effects, 3.9 and 3.10
40. hydrogen sulphide Substances classified as flammable gases category 1 or 2, flammable liquids categories 1,
2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with
water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or
pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to
Regulation (EC) No 1272/2008 or not.
Indication of changes
Section Changed item Change Comments
Supersedes Modified
Indication of changes
Section Changed item Change Comments
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006. SDS EU format according to COMMISSION
REGULATION (EU) 2020/878.
Other information : Refer to the safety data sheet before handling or disposing.
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Skin Irrit. 2 H315 Calculation method
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.