2023 Collection of Tests KROK 1 NEW

Ministry of Health of Ukraine
Zaporizhzhia State Medical and Pharmaceutical University

Analytical Chemistry Department
COLLECTION OF TESTS ON ANALYTICAL CHEMISTRY
«KROK 1. PHARMACY»
Collection of tests
for students of the 2-st course
specialty 226 «Pharmacy, industrial pharmacy»
Zaporizhzhia 2023
УДК 546.2-128.4.061(075.8)
Я 45
Approved at the meeting of the Central Methodological Council of ZSMU

(record № __ of «___» _______ 2023 .)
and recommended for use in the educational process
The Manual is composed by:
Doctor of Pharmaceutical Sciences, professor S. O. Vasyuk;

Candidate of Pharmaceutical Sciences A. S. Korzhova;
Candidate of Pharmaceutical Sciences N. O. Nahorna.
Reviewed by:
L. I. Kucherenko - Doctor of Pharmaceutical Sciences, Professor, Head of
the Department of Pharmaceutical, Organic and Bioorganic Chemistry;
A. G. Kaplaushenko - Doctor of Pharmaceutical Sciences, Professor, Head
of the Department of Physicocolloid Chemistry.
Collection of tests on analytical chemistry. «KROK 1.

Я Pharmacy»: Collection of tests for students of the 2-st course
45 specialty 226 «Pharmacy, industrial pharmacy» / composed by. : S.
O. Vasyuk, A. S. Korzhova, N. O. Nahorna. – Zaporizhzhia : ZSMU,
2023. – 162 p.
© Zaporizhzhia State Medical University, 2023
2
CONTENT
Preface……………………………………………………………. 4
Qualitative analysis ……………………………………………. 5
Cations of I-III analytical groups (acid-basic classification) ……. 6
Cations IV-VI analytical groups (acid-basic classification)……... 25
Anions…………………………………………………………..... 47
Quantitative analysis…………………………………………… 64
Acid-base titration ……………………………………………...... 65
Oxidation-reduction titration……………………………………. 81
Precipitating titration gravimetry………………………………… 104
Compleximetric titration…………………………………………. 118
Gravimetry………………………………………………………. 127
Instrumental methods of analysis ……………………………... 131
Optical methods of analysis ……………………………………... 132
Electrochemical methods of analysis ……………………………. 145
Chromatographic methods of analysis…………………………… 156
Recommended literature ………………………………………… 161
3
PREFACE
Analytical chemistry is the science of methods of studying the

qualitative and quantitative composition of substances.
Recently, physico-chemical experimental methods of research,
characterized by speed and high sensitivity, have been widely
implemented - these are chromatography, polarography, potentiometry,
and others.
Analytical chemistry as an academic discipline is based on
knowledge of inorganic chemistry, physics and mathematics and integrates
with organic, pharmaceutical, toxicological, physicocolloid and biological
chemistry; lays the foundations for the study of pharmaceutical and
toxicological chemistry and provides for the formation of skills in the
application of acquired knowledge for the study of special disciplines and
in professional activities.
The collection of analytical chemistry tests "STEP 1. Pharmacy" is
designed for students of the specialty 226 "Pharmacy, industrial
pharmacy" and corresponds to the sample program approved by the
Ministry of Health of Ukraine on April 19, 2017, the educational work
plan approved by the Academic Council of ZDMU (protocol No. 10 of
20.05 .2022.) and the work program of the academic discipline "Analytical
Chemistry" from 2022.
The collection of tests covers all sections of analytical chemistry,
namely "Qualitative analysis", "Quantitative analysis", "Instrumental
methods of analysis", and is designed to prepare students for the integrated
test exam "STEP 1. Pharmacy", which is a test component of the Unified
state qualification exam for holders of a master's degree in the field of
knowledge 22 "Health care".
4
QUALITATIVE ANALYSIS
5
Cations of I-III analytical groups
(acid-basic classification)
1. To detect ammonium cations, a complex mercury compound is used, namely

Nessler's reagent. What is the chemical formula of this compound?
А. K2[HgCl4].
B. [Hg(NH3)2Cl2].
C. K2[Hg(CN)4].
D. K2[HgI4].*
E. [Hg(NH3)4](NO3)2.
2. When adding a dilute solution of hydrochloric acid to the analyzed solution, a

white lime precipitate was formed, completely soluble in ammonia solution. This
is evidence of the presence of ions?
А. Ions of calcium.
В. Ions of sodium.
С. Ions of silver.*
D. Ions of iron (II).
Е. Ions of potassium.
3. When heated, the alkaline solution undergoes a sharp smell and observes the
appearance of a blue color on the red litmus paper moistened with water. What
ions give such an effect?
А. Nitrite ions.
В. Acetate ions.
С. Potassium ions.
D. Ammonium ions.*
Е. Carbonate ions.
4. The dry residue, obtained after evaporation of the analyzed solution, paints the
flame of the burner in yellow, and when viewed through a blue glass - in violet.
Which cations were in the dry residue?
А. Na+, Sr2+.
B. Ca2+, K+.
C. Na+, K+.*
6
D. Na+, Ca2+.
E. Li+, Ba2+.
5. Gypsum water was added to the test solution. After heating the solution is
cloudy. Which of the following cations are present in the solution?
А. Fe3+.
B. Mg2+.
C. Fe2+.
D. Sr2+.*
E. Ca2+.
6. When added to the investigated solution of alkali, a black precipitate falls, and
when heated, gas is formed with a sharp odor. Please indicate which of the
following pairs of cations is in the solution:
А. Plum and ammonium.
В. Sodium and ammonium.
С. Mercury(I) and mercury(II).
D. Potassium and ammonium.
Е. Mercury(I) and ammonium.*
7. In analytical practice, organic dicarboxylic acid is used to detect calcium ions.

This same reaction serves for the qualitative detection of this acid. About which of
the following dicarboxylic acids is mentioned?
А. Adipine (hexandia) acid.
В. Oxalate (etandioic) acid.*
С. Malonov (propanediol) acid.
D. Glutaric (pentanedioic) acid.
Е. Amber (butadiene) acid.
8. In the investigated solution was added a 2 M solution of hydrochloric acid. A

white precipitate has fallen, which became black as a result of treatment with
concentrated ammonia solution. This indicates the presence of the solution:
А. Mercury(I) cations.*
В. Argentum cations.
С. Mercury(II) cations.
7
D. Lead cations.
Е. Bismuth cations.
9. To the study solution was added 1 М solution of sulfuric acid. A white

precipitate has fallen, which dissolves in alkali. This indicates the presence of the
solution:
А. Mercury(I) cations.*
С. Barium cations.
D. Lead cations.*
Е. Calcium cations.
10. In the investigated solution was added potassium iodide solution. A golden-
yellow precipitate was formed, which dissolves in hot water, excess reagent and
acetate acid. This indicates the presence of the solution:
А. Bismuth cations.
С. Mercury(I) cations.
D. Lead cations.*
Е. Mercury(II) cations.
11. The IInd group of cations include Pb2+, Ag+, Hg22+. Choose a group reagent:
А. NH3 solution.
B. HNO3 solution.
C. H2SO4 solution.
D. NaOH solution.
E. HCl solution.*
12. According to the acid-base classification, the III d analytical group of cations
includes Ba2+, Ca2+, Sr2+. What reagent is used to separate these cations from the
cations of other analytical groups?
А. NH4OH solution.
B. HCl solution.
C. Concentrated ammonia solution.
D. NaOH solution.
8
E. H2SO4 solution.*
13. A solution of potassium chromate was added to the test solution. The yellow
precipitate is formed, which is not soluble in acetate acid. This indicates the
presence of the solution:
А. Strontium cations.
В. Barium cations.*
С. Calcium cations.
D. Magnesium cations.
Е. Sodium cations.
14. Identification of the mixture must be carried out, containing cations of the first
analytical group (Li+, NH4+, Na+, K+). Which of these cations is determined by
Nessler's reagent?
А. Sodium.
В. Lithium.
С. Potassium.
D. Ammonia.*
Е. All ions.
15. What cation is in solution if when heated with alkali, gas is released with a
sharp odor?
А. Lead(II).
В. Silver(I).
С. Mercury(I).
D. Mercury(II).
Е. Ammonium.*
includes Ca2+, Sr2+, Ba2+. Specify a group reagent for the cations of this group:
А. Nitric acid.
В. Acetate acid.
С. Sulfuric acid + ethanol.*
D. Oxalic acid.
Е. Hydrochloric acid.
9
17. For the binding of hydrogen ions in the identification of potassium ions with
tartaric acid, use a solution:
А. Ammonia.
В. Sulfuric acid.
С. Sodium acetate.*
D. Sodium hydroxide.
18. Calcium cations are part of some pharmaceuticals drugs. The pharmacopeia
reaction for the detection of calcium cation is the reaction with the solution:
А. Sodium hydroxide.
В. Ammonium oxalate.*
С. Potassium iodide.
D. Sulfuric acid.
Е. Ammonium hydroxide.
19. What based separation of lead (II) chloride from other chlorides II analytical
group?
А. Different solubility in alkali.
В. Different solubility in hydrochloric acid.
С. Different solubility in hot water.*
D. Different solubility in solution of ammonia.
Е. Different solubility in sulfuric acid.
20. Cations of the IIId analytical group (acid-base classification) isolated in a

systematic course of analysis with such of group reagent:
A. 1 М solution of ammonium carbonate.
B. 0,1 М solution of ammonium oxalate.
C. 1 М solution of sulfuric acid in the presence of ethanol.*
D. 1 М solution of potassium chromate.
E. 0,1 М solution of sodium carbonate.
10
21. In the systematic process of analysis for the transfer of sulfates BaSO 4, SrSO4,,
CaSO4 in carbonate, when heated, saturated solution is used use saturated solution
while heating:
A. Na2CO3.*
B. CO2.
C. CaCO3.
D. (NH4)2CO3.
E. MgCO3.
22. What analytical effect is observed when determining the cation of potassium
solution of sodium hexanitrocobaltate (III)?
A. White crystalline precipitate.
B. Black crystalline precipitate.
C. Red crystalline precipitate.
D. Yellow crystalline precipitate.*
E. Yellow color of the solution.
23. By I analytical group of cations for the acid-basic classification of cations:

А. Aluminum, magnesium, zinc.
В. Potassium, barium, bismuth.
С. Calcium, strontium, barium.
D. Silver, lead, nickel.
E. Sodium, potassium, ammonium.*
24. The laboratory needs to identify cation of ammonium. You can use the
solution:
A. Nessler’s reagent.*
B. Potassium chromate.
C. Zincuranylacetate.
D. Chuhayev’s reagent.
E. Sodium sulfate.
25. To test solution added 2 М solution HCl. This formed a white precipitate,
which turned black when treated with ammonia solution. What cation is present in
the solution:
11
A. Hg22+.*
B. Ag+.
C. Pb2+.
D. Ba2+.
E. Mg2+.
26. Which of these reactions is a specific determination of ammonium cations?

A. Reaction with alkali metal hydroxides when heated.*
B. Reaction with potassium hexahydroxyantimony.
C. Reaction with sodium hexanitrocobalate(III).
D. Reaction with potassium tetrahydomercurate(II) in alkaline media.
E. Reaction with sodium hexanitrocobalate(III) in acidic media.
27. To the analyzed solution add the alkali and heat, gas is released, which
changes the color of the red wet litmus paper to blue. This indicates the presence
of the solution:
A. Ammonium ions.*
B. Carbonate ions.
C. Lead cations.
D. Bismuth ions.
E. Chloride ions.
28. The analyzed solution contains calcium chloride and sodium bromide. What
solution was added to the analyzed solution to detect the calcium ion?:
A. Ammonium oxalate.*
B. Barium chloride.
C. Sodium chloride.
D. Potassium iodide.
E. Ammonium acetate.
29. Dry residue obtained after evaporation of the solution analyzed, paints the
colorless flame of the burner in yellow, but when viewed through a blue glass − in
violet. Which cations were in the dry residue?
A. Na+, K+.*
B. Сa2+, K+.
12
C. Na+ , Sr2+.
D. Li+, Ba2+.
E. Na+, Ca2+.
30. The test solution contains potassium and ammonium cations. Specify a reagent
that can detect ammonium cations in this solution.
A. Potassium tetrahydomercurate(II).*
B. Sodium chloride.
C. Sodium acetate.
D. Potassium heksatsianoferate (II).
E. Cincuranylacetate.
31. To the investigated solution was added 1 М solution of sulfate acid. A white
precipitate has fallen, which dissolves in alkali. This indicates the presence of the
solution:
A. Lead cations.*
B. Calcium cations.
C. Barium cations.
D. Silver cations.
E. Mercury cations(І).
32. Cations of the IIId analytical group (acid-basic classification) separated in a

systematic analysis using a group reagent:
A. 1 М solution of sulfuric acid in the presence of ethanol.*
B. Potassium chromate solution.
C. Sodium carbonate solution.
D. Ammonium oxalate solution.
E. Ammonium carbonate solution.
33. In the systematic analysis for the transfering of sulfates ВаSО4, SrSO4, CaSO4
into carbonates are used:
A. Saturated solution Na2CO3, t.*
B. Saturated solution СaCO3, t.
C. Saturated solution (NH4)2CO3, t.
D. Saturated solution MgCO3, t.
13
E. Saturated solution CO2, t.
34. What cation is in the solution, if when heated with alkali allocated gas with a
sharp odor?
A. Ammonium.*
B. Silver(І).
C. Mercury(II).
D. Mercury(I).
E. Lead (ІІ).
35. What cation of the IIId analytical group (acid-basic classification) is in

solution, if by heating with gypsum water after a while the solution becomes
cloudy?
A. Strontium.*
B. Calcium.
C. Magnesium.
D. Lead(ІІ).
E. Mercury(ІІ).
36. After treatment of chloride precipitate cations II groups of hot water to the
solution have acted with a solution of potassium dichromate. A yellow precipitate
formed insoluble in acetic acid but soluble in alkalis. What cations contained the
test solution?
A. Lead(II).*
B. Mercury(II).
C. Barium.
D. Silver(І).
E. Calcium.
37. Calcium cations are part of some pharmaceuticals. The pharmacopoeial

reaction for the detection of calcium cation is the reaction with the solution:
A. Ammonium oxalate.*
B. Hydrochloric acid.
C. Potassium iodide.
D. Ammonium hydroxide.
14
E. Sodium hydroxide.
38. What is the analytical effect to expect from the action of potassium
hexacyanoferat(II) on cations Са2+:
A. Formation of white crystalline precipitate.*
B. The formation of yellow-green crystals.
C. Brown color of the solution.
D. Formation of complex compound of blue color.
E. The formation of gelatinous white precipitate.
39. What analytical effect is observed when determining the potassium cation
solution of sodium hexanitrocobaltate(ІІІ)?
A. Yellow crystalline precipitate.*
B. White crystalline precipitate.
C. Yellow color of the solution.
D. Black crystalline precipitate.
E. Red crystalline precipitate.
40. Indicate the reason for the transfer of cations sulfates of the III d analytical
group (acid-basic classification) in carbonates in the systematic analysis:
A. Insolubility of sulfates in acids and alkalis.*
B. Insolubility of sulfates in water.
C. Solubility of sulfates in water.
D. Solubility of sulfates in acids.
E. Solubility of sulfates in alkalis.
includes:
A. Calcium, strontium, barium. *
B. Aluminum, magnesium, zinc.
C. Potassium, barium, bismuth.
D. Argentum, plumbum, nickel.
E. Zinc, aluminum, chromium.
42. According to the acid-base classification, the II d analytical group of cations
15
includes:
A. Silver, lead, mercury(I).*
B. Calcium, strontium, barium.
C. Aluminum, magnesium, zinc.
D. Zinc, aluminum, chromium.
E. Potassium, barium, bismuth.
43. To the I analytical group cations acid-base classification include cations:

A. Sodium, potassium, ammonium. *
B. Calcium, strontium, barium.
C. Silver, plumbum, nickel.
D. Aluminum, magnesium, zinc.
E. Potassium, barium, bismuth.
44. Why cations of the I st analytical group (acid-base classification) do not have a
group reagent?
A. Most of their salts are soluble in water.*
B. Have similar ionic radii.
C. Have large ionic radii.
D. They have the ability to form soluble alkalis.
E. Relating to biologically active elements.
45. In pharmacopoeial analysis for the detection of sodium ions use:

A. 2-methoxy-2-phenylacetate acid.*
B. 8-oxyquinoline.
C. Diphenylamine.
D. Diacetyldioxime.
E. Tetrafenilborate.
46. In qualitative analysis to detect strontium ions using the gypsum waters.
Gypsum water - is:
A. Saturated aqueous solution СaSO4.*
B. Solution Ca(ОН)2.
C. Saturated solution CO2 in the water.
D. Solution Ba(NO3)2 in the water.
16
E. Solution Ва(ОН)2.
47. In qualitative analysis the typical reaction to cation silver is:

A. The reaction of formation of cheese precipitate AgCl, which dissolves in a
solution of ammonia, again formed by adding НNО3.*
B. The reaction of formation of cheese precipitate АgCl, which is soluble in acids.
C. The reaction of complex formation, which is destroyed by the action of the
solution HNO3.
D. Reaction of formation of a precipitate, which dissolves in a solution of alkali.
E. Reaction of formation of yellow precipitate, which dissolves in excess of
ammonia.
48. What is characterized by the ability of the reagent to give a well-defined

analytical effect when interacting with the test substance?
A. Sensitivity of the reaction. *
B. Selectivity of the reaction.
C. Specificity of the reaction.
D. Selectivity of the reaction.
E. Number of reagents.
49. What is the name of the reaction and the reagents, which allow, under certain
conditions, to determine the data ions in the presence of other ions?
A. Specific. *
B. Selective.
C. Group.
D. Characteristic.
E. General.
50. How to separate PbSO4 from a mixture of cations sulfates III analytical group
at the systematic course of analysis?
A. Sludge treatment 30% solution of ammonium acetate.*
B. Recrystallization of the precipitate.
C. Treatment of the precipitate with concentrated sulfuric acid.
D. Treatment of the precipitate with a solution of acetate acid.
E. Treatment of a precipitate with a solution of ammonia.
17
51. Why is ethanol used together with the group reagent of the III d analytical
group cations?
A. To ensure the completeness of deposition of all cations of this group.*
B. For further dissolution of formed sediments.
C. For fractional deposition of cations.
D. To change the pH of the environment.
E. To prevent complexation.
52. What analytical effect should expect from the effects of potassium
heksatsianoferat(II) on cations Са2+:
A. Formation of white crystalline precipitate.*
B. Formation of yellow-green crystals.
C. Brown color of the solution.
D. Formation of complex compound of blue color.
E. Formation of a white gelatinous precipitate.
53. The test solution contains ammonium and sodium cations. Specify a reagent
that can detect sodium cations in this solution.
A. Zincuranylacetate.*
B. Potassium oxalate.
C. Potassium tetraiodomercury(II).
D. Potassium hydrotartrate.
E. Potassium benzoate.
54. The reaction of the formation of a golden yellow precipitate (reaction of

«golden rain») − this is a reaction:
A. Sedimentation PbI2.*
B. Sedimentation PbCl2.
C. Sedimentation AgI.
D. Sedimentation HgI2.
E. Sedimentation Hg2I2.
55. During precipitation of the IIId analytical group cations (Ca2+, Sr2+, Ba2+) in
order to reduce the solubility of sulfates in the solution are added:
18
A. Ethanol. *
B. Distilled water.
C. Benzen.
D. Chloroform.
E. Amyl ethanol.
56. What analytical effect is accompanied by the reaction of detecting potassium

cations under the influence of sodium hydrotartrate?
A. White crystalline precipitate.*
B. Yellow color of the solution.
C. White amorphous precipitate.
D. Brown precipitate.
E. Yellow precipitate.
57. To the investigated solution, which contains cations of III group, added a
solution of potassium chromate. Fallen yellow precipitate, not soluble in acetate
acid. This indicates the presence of cations in the solution:
A. Strontium.
B. Mercury(І).
C. Calcium.
D. Barium.*
E. Silver(І).
58. What is the analytical effect accompanied by the reaction of determining

potassium cations under the action of sodium hydrotartrate?
A. Yellow precipitate.
B. Brown precipitate.
C. Yellow color of the solution.
D. White amorphous precipitate.
E. White crystalline precipitate.*
59. Volatile compounds of calcium colorless flame painted in a color:

А. Yellow-green.
В. Yellow.
С. Red. *
19
D. Violet.
Е. Green.
60. To the analyzed solution was added solution of 1 M H2SO4 in the presence of
ethanol. A white precipitate formed. Which group of cations are present in the
solution?
А. IV.
В. II.
С. VI.
D. I.
Е. III.*
61. Specialists investigate solutions containing mixtures of cations. Which

solution contains only cations of the IId analytical group?
А. Pb2+, Ag+, Co2+.
В. Hg22+, NH4+, Ag+.
С. Na+, Pb2+, Ni2+.
D. Ag+, Hg22+, Pb2+.*
Е. Na+, Hg22+, NH4+.
62. Which of these reactions is a specific determination of ammonium cations??

A. With alkali metal hydroxides when heated.*
B. With potassium hexahydroxoantimonate.
C. With sodium hexanitrocobalate(III).
D. With potassium tetraiodomercurate(II) in alkaline environment.
E. With sodium hexanitrocobalate(III).
63. Indicate which reagent can detect barium cations in the presence of calcium
and strontium cations:
А. Potassium iodide.
В. Potassium chloride.
С. Potassium nitrate.
Е. Potassium dichromate.*
20
64. The flame of a burner in the presence of salts of an unknown cation is colored
in a carmine-red color. It's a cation?
А. Sodium.
В. Ammonia.
С. Potassium.
D. Strontium.*
Е. Iron.
65. When carrying out the reaction of sodium ions with potassium
hexahydroxoantimonate(V) in a neutral environment a precipitate is formed. What
color is the precipitate indicated??
А. Green.
В. Blue.
С. White.*
D. Yellow.
Е. Red.
66. Chemist-analyst conducts qualitative analysis of the IId analytical group of

cations. For separation of chlorides silver and mercury are use a solution:
В. Potassium chloride.
С. Sodium nitrate.
D. Hydrochloric acid.
Е. Ammonia.*
67. What cations after interact with sodium sulfide form a black precipitate?
А. Calcium and magnesium.
B. Plumbum and silver.*
C. Sodium and potassium.
D. Ammonia and aluminum.
E. Zinc and cadmium.
68. What kind of reagent in the systematic process of analysis can be divided into
chlorides silver and mercury (I) and at the same time detect mercury cations(I)?
А. Hot water.
21
B. The remainder of concentrated hydrochloric acid.
C. Alkali solution.
D. Ammonia solution.*
E. Solution of nitric acid.
69. Which cation colors the flame in violet color?

А. Strontium.
B. Potassium.*
C. Calcium.
D. Sodium.
E. Barium.
70. To determine the qualitative composition of the drug on the investigated

solution have acted 2 М solution НСl. Fallen white precipitate, soluble in aqueous
ammonia solution. What kind of cations indicate this analytical effects:
А. Tin(II).
В. Lead(II).
С. Silver(I).*
D. Mercury(II).
Е. Mercury(I).
71. The analyzed solution contains calcium chloride and sodium bromide. To
determine the calcium ion use:
А. Potassium iodide
В. Ammonium oxalate*
С. Ammonium acetate
D. Sodium chloride
Е. Barium chloride
72. Name the reactions and reagents allow detecting a particular substance or
particular ion in the presence of other substances or ions:
А. Group.
B. General.
C. Specific.*
D. Characteristic.
Е. Selective.
22
73. In order to carry out the silver cations identification, HCl was added to the
solution. Later, the formed solution was followed by adding the solution of
ammonia. Specify which of the below-mentioned compounds are formed in such
case?
A. AgCl
B. [Ag2(NH3)3]Cl
C. [Ag(NH3)3]Cl
D. AgOH
E. [Ag(NH3)2]Cl *
74. In the process of systematic analysis, there is a need to separate PbSO4 from
the mixture of sulfates of the III d analytical group cations. Which of the following
options most towards this end?
A. Processing precipitate with ammonia solution
B. Processing precipitate with acetate acid solution
C. Processing precipitate with concentrated sulfate acid
D. Precipitate recrystallization
E. Processing precipitate with 30% ammonium acetate solution *
75. The researcher while conducting the qualitative analysis that involves sulfates
precipitation of the third analytical group cations (Ca 2+, Sr2+, Ba2+) has to reduce
solubility of sulfates. What substance should be used for this purpose?
A. Chloroform
B. Amyl alcohol
C. Benzene
D. Ethyl alcohol *
E. Distilled wated
76. In the process of systematic analysis it is necessary to separate PbSO4

from the mixture of cation sulfates belonging to the 3rd analytical group. What
approach will be optimal for this purpose?
A. Processing precipitate with ammonia solution
B. Processing precipitate with 30% ammonium acetate solution *
C. Processing precipitate with concentrated sulfate acid
D. Processing precipitate with acetate acid solution
E. Precipitate recrystallization
23
77. Hydrochloric acid (HCl) was added to the solution to be studied. The
precipitate was filtered off and treated with hot water on the filter, and after
cooling, KI was added to the filtrate. What cation is present in the solution if the
resulting precipitate is yellow?
А. Ba2+
В. Hg2+
С. Ca2+
D. Pb2+ *
Е.Ag+
78. In the laboratory, to identify the iodide ions in the solution, a reaction was
carried out with plumbum cations. The resulting precipitate was dissolved by
heating in water, and then the test tube was cooled. What analytical effect was
observed during the reaction?
А. Formation of gold flakes *
B. Formation of a brown precipitate
С. Formation of a blue precipitate
D. Release of gas bubbles
Е. Formation of a white precipitate
79. To determine the qualitative content of a drug, a sample of the analyte

solution was processed with 2M solution of HCl. A white precipitate, soluble in
aqueous ammonia solution, was formed. This analytical effect indicates of the
presence of the following cations:
A. Mercury(II) cations
B. Tin(II) cations
C. Silver(I) cations *
D. Lead(II) cations
E. Mercury(I) cations
24
Cations IV-VI analytical groups
(Acid-basic classification)
1. Indicate which cations are contained in the solution, if with the addition of
dithizone in the presence of alkali there is a pink color of water and chloroform
layers:
А. Sn2+.
B. Cd2+.
C. Cu2+..
D. Zn2+.*
E. Pb2+.
2. In qualitative analysis, acting on the excess of a group reagent (NH 3 solution)

on cations of the VIth analytical group (Cu2+, Co2+, Ni2+, Cd2+, Hg2+) are formed:
А. Ammonia complexes of these metals.*
В. Aquacomplexes of these metals.
С. Hydroxides of these metals.
D. Hydroxydic complexes of these metals.
Е. Basic salts of these metals.
3. With the help of which the reagent is separated cations 4 analytical group from
cations 5 and 6 analytical groups in the analysis of their mixture?
А. Solution NH4OH.
B. Solution Na2S.
C. Solution H2SO4.
D. Dithizone.
E. Solutions NaOH and H2O2.*
4. Ammonium thiocyanate was added to the solution containing cations of the V th

analytical group (acid-base classification). The solution became red. What cations
indicate this analytical effect?
А. Magnesium cations.
В. Iron cations (II).
25
С. Manganese cations(II).
D. Bismuth cations.
Е. Iron cations(III).*
5. With excess reagent can determine which cations of copper (II) in a solution
containing cations of copper (II) and zinc?
А. 2 М solution of chloride acid.
В. 2 М solution of sulfate acid.
С. 6 М solution of potassium hydroxide.
D. 6 М ammonia solution.*
Е. 2 М solution of ammonium carbonate.
6. An excess of 6 M sodium hydroxide solution and 3% hydrogen peroxide

solution was added to the analyzed solution. After heating, the solution turned
yellow. What cations does the solution contain?
А. Tin cations(II).
Б. Cation of lead (II).
С. Aluminum cations.
D. Zinc cations.
Е. Chromium cations(III).*
7. Which cation of the Vth analytical group is in the solution, if after interacting
with tin(II) chloride in an alkaline medium a black precipitate falls?
А. Bismuth(III).*
В. Manganese(II).
С. Stibium(III).
D. Iron(II).
Е. Iron(III).
8. Cations Fe3 + form complex compounds with thiocyanate ions. What is the
analytical effect observed?
А. A precipitate of red color falls.
В. A brown ring is formed.
С. The solution is colored in blue.
D. The solution is colored in red.*
26
Е. «Berlin blue» is formed.
9. Specify the type of reaction used to identify the cation Fe3+:

А. Complex formation.*
В. Sedimentation.
С. Hydrolysis.
D. Neutralization.
Е. Reduction.
10. In qualitative analysis a specific reagent for cations Fe2+ is:

А. K2Na[Co(NO2)6].
B. K3[Fe(CN)6].*
C. K4[Fe(CN)6].
D. NaOH.
E. NH4OH.
11. A characteristic reaction detecting mercury(II) cations is a reaction with

potassium iodide. During reaction is observed:
А. Bright red solution.
В. White precipitate.
С. Dirty green precipitate.
D. Black precipitate.
Е. Bright red precipitate.*
12. According to the values рКа indicate the strongest acid:

А. Lactic acid 3,9.
В. Propionic acid 4,9.
С. п- Methylphenol 10,1.
D. Acetic acid 4,7.
Е. Formate acid 3,7.*
13. What salt corresponds to the expression for calculating the constant of
hydrolysis Кг=Кw/Kb?
A. K2SO4.
B. Na2CO3.
27
C. K3PO4.
D. LiNO3.
E. NH4Cl.*
14. Solvents used in analytical chemistry are classified according to their ability to
attach or deliver protons. Indicate which solvents are ethanol:
А. Protophile.
В. Aprot.
С. Amfіprot.*
D. Protogene and amfiprot.
Е. Protogenic.
15. Medicinal product hydrogen peroxide is determined by reaction with

potassium dichromate in an acidic environment. What is the color of the ether
layer containing chromium oxide-diproxide CrO5:
А. Yellow.
В. Blue.*
С. Crimson.
D. Red.
Е. Green.
16. On the basis of the variables of the instability constants, determine the most
stable complex ion:
A. [Ag(NH3)2]+ Кinst=5,89∙10-8.
B. [Co(NH3)6]2+ Кinst=4,07∙10-5.
C. [Ni(CN)4]2- Кinst=1∙10-22.
D. [Ag(CN)2]- Кinst=1∙10-21.
E. [Fe(CN)6]3- Кinst=1∙10-31.*
17. Qualitative reaction for the determination of compounds Cr(VI) is the

formation of chromium oxide-diproxide, which paints the ether layer in a blue
color. Specify the formula for this chromium compound:
A. CrO.
B. CrO3.
C. Cr2O3.
28
D. CrO5.*
E. NaCrO2.
18. In a qualitative analysis, when the excess of a group reagent (a solution of

sodium hydroxide) on cations of the IV analytical group, the chromium ions (III)
are form:
A. Chromium(III) hydroxide.
B. Chromium(II) oxide.
C. Chromium(III) oxide.
D. Chromium(II) hydroxide.
E. Sodium hexahydroxychromate(III).*
19. To the investigated solution was added concentrated nitric acid and crystalline
plum dioxide. The solution has got a raspberry color. Which cation indicates on
this analytical effect?
A. Iron(III).
B. Bismuth(III).
C. Tin(II).
D. Manganese(II).*
E. Chromium(III).
20. When added to the analyzed solution excess ammonia, it stained in a bright
blue color. This indicates the presence of ions in the solution:
A. Silver.
B. Mercury(II).
C. Copper.*
D. Bismuth.
E. Lead.
21. What cations with a solution of potassium iodide form an orange-red

precipitate, soluble in excess of the reagent to form a colorless solution?
A. Mercury(II).*
B. Lead.
C. Bismuth.
D. Mercury (I).
29
E. Stibium (V).
22. Iron(II) sulfate is a part of the funds used in the treatment of iron deficiency
anemia. Which of the following compounds is reacting FeSO4:
A. HCl.
B. CO2.
C. NaCl.
D. FeCl2.
E. KMnO4.*
23. In a qualitative analysis, with the action of the excess of the group reagent
NaOH on the aluminum ions formed:
А. Sodium hexahydroxoaluminate.*
В. Aluminum hydroxide.
С. Basic salts of aluminum.
D. Aluminum oxide.
E. Sodium metaalyuminat.
24. Specify a compound whose qualitative definition is accompanied by the

appearance of a blue color of the ether layer:
А. Cl2.
В. MnSO4.
С. FeSO4.
D. Na2HPO4.
Е. H2O2.*
25. The division of cations V and VI analytical groups (acid-basic classification)

in the systematic process of analysis carried out under the influence of excess:
А. Concentrated ammonia solution.*
В. Solution of hydrochloric acid.
С. Potassium hydroxide solution.
D. Solution of sulfate acid.
E. Solution of sodium hydroxide.
30
26. The presence of one of the ions d- elements in solutions can be set using
K4[Fe(CN)6]?
A. Fe3+.*
B. Zn2+.
C. Cr3+.
D. Cu2+.
E. Fe2+.
27. Filter paper, impregnated with a solution of cobalt (II) of nitrate and the test
solution after burning, forms a blue ash. This is proof of the presence of ions:
A. Cr3+.
B. Ni2+.
C. Sb3+.
D. Al3+.*
E. Zn2+.
28. An analysis is made of a solution in which there are cations V of the analytical
group (acid-base classification). To the mixture was added a solution of sodium
hydroxostannate − formed a black precipitate, indicating the presence of cation:
A. Fe3+.
B. Fe2+.
C. Sb3+.
D. Mg2+.
E. Bi3+.*
29. To detect ions Co2+ in the presence of Fe3+ for masking the ions Fe 3+ to the
solution is added:
А. Nitrite ions.
В. Sulphate ions.
С. Chloride ions.
D. Fluoride ions.*
E. Bromide ions.
30. What is the general property of compounds of cations Al 3+, Zn2+, Cr3+, Sn2+
combines them into VI analytical group (acid-basic classification)?
31
A. Amphotericity of hydroxides.*
B. Insolubility of salts in water.
C. Good solubility of some salts.
D. Solubility of hydroxides in acids.
E. Solubility of hydroxides in an excess of ammonia solution.
31. In solution there are cations of calcium, barium, aluminum, potassium,

sodium. A small amount of ammonium hydroxide and alizarin solution were
added to the solution. Red precipitate is formed. What is the ion found by this
reaction?
A. Aluminum.*
B. Calcium.
C. Barium.
D. Potassium.
E. Sodium.
32. A characteristic reaction to detect mercury (II) cations is a reaction with

potassium iodide. When carrying out the reaction observed:
A. Bright red precipitate.*
B. Bright red solution.
C. Dirty green precipitate.
E. White precipitate.
33. To the investigated solution was added concentrated nitric acid and crystalline
plum dioxide. The solution has got raspberry color. At the presence of which the
cation indicates this analytical effect:
A. Manganese(II).*
B. Bismuth(III).
C. Iron(III).
D. Chromium(III).
E. Tin(II).
34. To the investigated solution was added a solution of ammonium thiocyanate.

The solution became red. What cation indicates on this analytical effect:
32
A. Iron(III).*
B. Mercury(II).
C. Silver.
D. Mercury(II).
E. Lead(II).
35. When added to the solution analyzed excess ammonia solution was colored in
a bright blue color. This indicates the presence of ions in the solution:
A. Copper.*
B. Silver.
C. Lead.
D. Bismuth.
E. Mercury(II).
36. Specify which ions are in the solution, if heated by with (NH 4)2S2O8 in the
presence of AgNO3 the solution becomes raspberry color?
A. Mn2+.*
B. Fe3+.
C. Fe2+.
D. Co2+.
E. Cu2+.
37. To the investigated solution was added an excess 6 М solution of sodium

hydroxide and 3% hydrogen peroxide solution. By heating the solution turns
yellow. This indicates the presence of the solution:
A. Chromium cations(III).*
B. Tin cations (II).
C. Aluminum cations.
D. Zinc cations.
E. Lead cations.
38. In qualitative analysis under certain conditions, a specific reagent for cations
Fe3+ is K4[Fe(CN)6]. What color precipitate formed?
A. Blue.*
B. White.
33
C. Brown.
D. Red.
E. Black.
39. When analyzing a mixture of the ІVth analytical group cations, Zn2+ can be
determined by a fractional method with a reagent:
A. Dithizone.*
B. Ammonia solution.
C. Alkali.
D. Carbonate of alkali metal.
E. Dimethylglyoxime.
40.What cation of the Vth of the analytical group is in the solution, if under the
influence of the solution of tin(II) chloride in an alkaline medium a black
precipitate was formed?
A. Chromium(III).*
B. Tin(II).
C. Tin(IV).
D. Zinc.
E. Aluminum.
41. What is the cation V of the analytical group (acid-base classification) is in the
solution, if under the influence of the solution of tin(II) chloride in a alkaline
medium a black precipitate was formed?
A. Bismuth(III).*
B. Iron(II).
C. Manganese(II).
D. Antimony(III).
E. Iron(III).
42. In the analyzed cations are a mixture of iron(III) and copper(II). Which group
of reagents can be divided into these cations:
A. Concentrated ammonia solution. *
B. A solution of sodium hydroxide and hydrogen peroxide.
C. Hydrochloric acid solution.
34
D. Sodium hydroxide solution.
E. Sulfate acid solution.
43. In qualitative analysis, under the influence of the excess of a group reagent (a
solution of sodium hydroxide) on cations of the IV th analytical group, the
chromium(III) ions is form:
A. Sodium hexahydroxychromate(III).*
B. Chrome(III) hydroxide.
C. Chrome(III) oxide.
D. Chrome(II) hydroxide.
E. Chrome(II) oxide.
44. In qualitative analysis a specific reagent for cations Fe2+ is:

A. K3[Fe(CN)6].*
B. K2Na[Co(NO2)6].
C. NaOH.
D. K4[Fe(CN)6].
E. NH4OH.
45. What cations with a solution of potassium iodide form an orange-red

precipitate, soluble in excess of the reagent to form a colorless solution?
A. Mercury(II). *
B. Mercury(I).
C. Bismuth.
D. Antimony(V).
E. Lead.
46. The investigated solution of the drug contains cations of magnesium (II) and
aluminum(ІІІ). Which the reagent can be divided into these cations when
analyzing this drug?
A. Alkaline solution.*
B. Hydrogen peroxide in acidic environment.
C. The solution of silver nitrate.
D. Ammonia solution.
E. A solution of hydrochloric acid.
35
47. When adding ammonia buffer solution and sodium hydroxide solution to the
analyzed solution, a white precipitate was formed. This indicates the presence of
ions:
A. Magnesium.*
B. Aluminum.
C. Arsenic(ІІІ).
D. Chromium(ІІІ).
E. Potassium.
48. For the separation of cations of the VI th analytical group from cations of the V th
analytical group (acid-basic classification) use:
A. Excess ammonia solution.*
B. Excess sodium hydroxide solution.
C. Excess solution of sulfate acid.
D. Acetate acid solution.
E. Silver nitrate solution.
49. The most selective reaction for the determination of nickel cations is the
interaction reaction with:
A. Chuhayev’s reagent.*
B. Sodium hydroxide solution.
C. A solution of potassium hydroxide.
D. Sulfate acid solution.
E. Nessler’s reagent.
50. When added to an unknown mixture of a solution of sodium hydroxide and a

solution of hydrogen peroxide, a precipitate formed which disappeared after the
addition of excess of these substances. Which analytical group is present?
A. IV.*
B. V.
C. VI.
D. II.
E. III.
36
51. In an aqueous solution there are cations of the V th analytical group (acid-base
classification). During the dilution of the solution, a white amorphous precipitate
was formed. Which cations easily form hydrolysis products?
A. Cations of bismuth and antimony.*
B. Iron cations(III).
C. Magnesium cations.
D. Manganese cations.
E. Iron cations(II).
52. Indicate which cations are in the solution if when added to it the Chugaev
reagent and the ammonia buffer solution form a red-raspberry precipitate:
A. Nickel cations.*
B. Aluminum cations.
C. Сopper cations.
D. Сobalt cations.
E. Iron cations.
53. What is the purpose of adding hydrogen peroxide (H 2O2) to the group reagent
in the systematic analysis of group IV cations?
A. To form hydroxo- and oxoanions of these elements in higher oxidation stages.*
B. To form the hydroxo- and oxoanions of these elements in low oxidation stages.
C. For a more complete precipitation of cations.
D. For the formation of peroxide compounds of these cations.
E. For the destruction of hydrated complexes.
54. The IVth analytical group of cations according to the acid-base classification
includes cations:
A. Aluminum, zinc, chromium(III), tin(II), tin(IV), arsenic(III), arsenic(V).*
B. Calcium, strontium, barium, potassium, bismuth.
C. Magnesium, calcium, strontium, barium.
D. Arhentumu, lead, nickel, potassium, barium, bismuth.
E. Sodium, potassium, ammonium, silver, lead.
55. The analysis of the IVth analytical group cations (acid-base classification) by
the action of group reagent can separate and identify ions:
37
A. Сr(III).*
B. Аs(III).
C. Zn(II).
D. Sn(IV).
E. Al(III) .
56. The analysis of the IVth analytical group cations (acid-base classification) by
the action group reagent can separate and identify ions:
A. Cu(II).*
B. Co(II).
C. Ni(II).
D. Hg(II).
E. Cd(II).
57. The test mixture contains cations Mg 2+, Ni2+, Со2+. With which reagent can be
found cations Ni2+ in this mixture?
A. Dimethylglyoxime.*
B. Ammonia.
C. 1 nitroso-2-naphthol.
В. Magneson-1.
E. Alizarine.
58. By V analytical group cations include ions Mn 2 +. The qualitative reaction for
these cations is:
A. Oxidation in acidic environment.*
B. Interaction with Fe3 + in acidic environment.
C. Action of alkalies.
D. Action of acid.
E. The formation of insoluble complexes.
59. The group reagent on cations of the IV th analytical group (acid-basic

classification) Со2+, Ni2+, Cd2+, Cu2+, Hg2+ is an excess of concentrated ammonium
hydroxide. What external effect is observed:
A. Formation of water-soluble ammonia complex compounds.*
B. Formation of hydroxides of cations soluble in acids.
38
C. Formation of colored, water insoluble compounds.
D. The formation of hydroxides of cations soluble in alkalis.
E. Formation of hydroxides of cations, insoluble in excess of ammonium
hydroxide.
60. Zinc and aluminum cations are present in the solution. Specify a reagent that
allows you to detect zinc cations in this solution:
A. Solution of potassium hexacyanoferrate(II).*
B. Sodium hydroxide solution.
C. Cobalt nitrate Со(NO3)2.
D. Excess 6 M sodium hydroxide in the presence of hydrogen peroxide.
E. Solution of sulfuric acid.
61. To a solution containing cations of the sixth analytical group (acid-base

classification), a solution of potassium iodide was added. Fallen red precipitate
soluble in excess reagent. What cations are present in the solution:
A. Mercury cation(II).*
B. Nickel cations.
C. Сobalt cations(II).
D. Bismuth cations.
E. Сadmium сations.
62. The IVth analytical group of cations includes Al3+, Sn2+, Sn(IV), As(V), As(III),
Zn2+, Cr3+. Specify the group reagent for the fourth group of cations.
A. Solution NaOH, Н2О2.*
B. Solution HCl.
C. Solution NH3, Н2О2.
D. Solution Н2С2О4.
E. Solution H2SO4, Н2О2.
63. The Vth analytical group of cations includes ions Fe 3+, Fe2+, Mg2+, Mn2+, Bi3+,
Sb(III), Sb(V). Specify a group reagent for the Vth analytical group of cations.
A. Ammonia solution.*
B. Solution H2SO4.
C. Solution Н2S.
39
D. Solution НNO3.
E. Solution HCl.
64. The VIth analytical group of cations include ions Cu 2+, Co2+, Ni2+, Cd2+, Hg2+.
Specify a group reagent for the VIth analytical group of cations.
A. Excess ammonia solution.*
B. Solution H2SO4.
C. Solution NaOH.
D. Excess of the solution КОН.
E. Solution HCl.
65. In qualitative analysis under the influence of an excess of the group regent
(solution NH3) on cations of the VI th analytical group (Cu2+, Co2+, Ni2+, Cd2+, Hg2+)
are formed:
A. Ammonia complexes of metals.*
B. Hydroxides of metals.
C. Basic metal salts.
D. Aquacomplexes of metals.
E. Hydroxycomplexes of metals.
66. Ammonia buffer and 8-oxyquinoline solution were added to the solution of
the Vth analytical group cations. The yellow-green precipitate was formed. What
cations are present in the solution?
A. Bi3+.
B. Fe3+.*
C. Mg2+.
D. Fe2+.
E. Mn2+.
67. What reagent is it possible to separate magnesium cations from other cations
of the V analytical group in a systematic analysis??
A. Alkaline solution.
B. Saturated solution of ammonium chloride.*
C. Excess concentrated ammonia solution.
D. Hydrogen peroxide.
40
E. Nitric acid.
68. Which cations of the IVth analytical group are in the solution, if under the
influence of sodium hydroxide solution a colored precipitate is formed, soluble in
excess of the reagent?
А. Manganese.
В. Bismuth.
С. Lead.
D. Zinc.
Е. Chromium*
69. In chemical-analytical laboratory technician recognize a mixture of cations V

analytical group. When adding thiocyanate ions solution is painted in red. The
presence of which cation shows this analytical effect?
А. Fe3+.*
В. Bi3+.
С. Fe2+.
D. Mg2+.
Е. Mn2+.
70. The fifth analytical group of cations includes ions Mn 2+. The qualitative
reaction for these cations is:
А. The action of acids.
В. The action of alkalis.
С. The formation of insoluble complexes.
D. Interaction with Fe3+ in acidic environment.
Е. Oxidation in acidic environment.*
71. To produce and analyze drugs commonly used buffer solution. Buffer
solutions are used for:
A. Maintaining a certain value of the pH of the solution.*
B. Changes in the pH of the solution.
C. Changes in the constants of ionization of matter.
D. Changes in the ionic strength of the solution.
E. Changes in solubility product of the substance.
41
72. You need to prepare an ammonia buffer solution. To the aqueous solution of
ammonia should be added:
A. Ammonium chloride solution.*
B. Hydrochloric acid solution.
C. Sulfuric acid solution.
D. Potassium chloride solution.
E. Sodium sulfate solution.
73. Buffer solutions are widely used in the analysis for:

A. Providing a certain pH environment.*
B. Coloring of solutions.
C. Formation of complex compounds.
D. Achieving the completeness of deposition of the analytical group of cations.
E. Masking of ions.
74. In conducting analytical reactions, buffer mixtures are widely used. Under
what conditions the buffer capacity of the solution is the maximum?
A. The ratio of the components of the buffer mixture is equimolar.*
B. The concentration of the components of the buffer mixture is 1 М.
C. When adding 100 ml of 1 M solution of acid.
D. When adding 100 ml of 1 M alkaline solution.
E. The total volume of the buffer mixture is 1 liter.
75. To produce and analyze drugs commonly used buffers. Buffer solutions are
used for:
A. Support of a certain value of the pH of the solution.*
B. Changes in the pH of the solution.
C. Changes in the constants of ionization of matter.
D. Changes in the ionic strength of the solution.
E. Changes in solubility product of the substance.
76. Buffer solutions use to maintain a certain pH value buffer solution. Specify a
mixture of substances that is not a buffer:
A. NaOH+NaCl.*
42
B. CH3COOH+CH3COONa.
C. NH4Cl+NH3·H2O.
D. НCOОН+НCOОNа.
E. NaH2PO4+Na2HPO4.
77. The investigated mixture had worked cations KOH solution and dropped white
precipitate dissolved in excess reagent. The action of the solution K 4[Fe(CN)6]
white precipitate was formed. What cation is present in the solution?
A. Са2+.
B. Fe3+.
C. Zn2+.*
D. Сr3+.
E. Ва2+.
78. Which ion when heated with metal zinc in an acidic medium forms gas arsine,
which causes the appearance of yellow-brown spots on paper, soaked salts of
mercury(II)?
A. Nitrate.
B. Sulfate.
C. Arsenate.*
D. Sulfide.
E. Phosphate.
79. The analysis of dry matter always begins with previous tests. The test sample
has a green color. We can conclude the presence in the sample:
А. Manganese(II).
В. Chromium(III).*
С. Barium(II).
D. Iron(III).
Е. Cobalt(II).
80. The analysis of dry matter always begins with previous tests. Investigated
sample of white color. We conclude that there is no compound in the sample:
А. Magnesium(II).
B. Barium(II).
43
C. Aluminum(III).
D. Zinc(II).
E. Chromium(III).*
81. Which of the cations of the IVth analytical group can be opened by a filter-
paper method with alizarin using analytical masking?
А. Zn2+.
B. Cr3+.
C. Sn2+.
D. Sn(IV).
E. Al3+.*
82. Chemists for the identification of zinc cations(II) used a solution of potassium
hexacyanoferrate(II) reagent (pharmacopeia reaction). What color of the
precipitate is formed here?
А. Red.
В. Black.
С. White.*
D. Green.
Е. Yellow.
83. To the solution of cations V of the analytical group was added ammonia buffer
and 8-hydroxyquinolines solution. The yellow-green precipitate was formed.
What are these cations?
А. Ammonium.
В. Manganese.
С. Calcium.
D. Magnesium.*
Е. Iron(II).
84. Ammoniacal buffer and 8-oxyquinoline solution were added into the solution
containing cations of the V analytical group, which resulted in production of a
green-yellow precipitate. What cations were in the solution?
А. Iron(II).
B. Manganese.
44
C. Calcium.
D. Magnesium.*
Е. Ammonium.
85. An analytical chemist performs a qualitative analysis of cations that belong to

the 6th analytical group. If nickel ions are processed with Chugaiev’s reagent
(dimethylglyoxime), a colored substance is produced. What is the color of the
resulting substance?
A. Violet
B. Green
C. Red *
D. Yellow
E. Blue
86. When an unknown mixture of sodium hydroxide (NaOH) and hydrogen

peroxide (H2O2) was added, a precipitate formed and disappeared after adding an
excess of these substances. What does this indicate about the presence of cations
of which analytical group?
А. VI
В. II
С. IV *
D. III
Е. V
87. During a characteristic reaction with sodium sulfide on salts of an unknown

cation, a white precipitate was formed. Identify this cation.
А. Copper
B. Zinc *
С. Mercury
D. Lead
E. Iron
88. What cation of the V analytical group (acid-base classification) is present in

the solution if a black precipitate falls out under the action of tin (II) chloride
solution in an alkaline medium?
45
А. Iron (III)
B. Manganese (II)
С. Iron (II)
D. Antimony (III)
E. Bismuth (III) *
89. An analytical chemist performs a qualitative analysis of cations that belong to

the sixth analytical group. If nickel ions are processed with Chugaiev’s reagent
(dimethylglyoxime), a colored compound is produced. What is the color of the
resulting compound?
A. Green
B. Blue
C. Yellow
D. Red *
E. Violet
90. During the analysis of the cations that belong to the fourth analytical group
(acid-base classification), their processing with a group reagent makes it possible
not only to separate, but also to identify the following ions:
A. Cr(III) ions *
B. As(III) ions
C. Sn(IV) ions
D. Al(III) ions
E. Zn(II) ions
46
Anions
1. With the action of mineral acid on the sample solution bubbles of gas are
allocated, causing turbidity of lime water. This is evidenced by the presence of
ions in solution?
А. Fluoride ions.
В. Nitrite-ions.
С. Carbonate ions.*
D. Permanganate ions.
Е. Nitrate ions.
2. To the dry salt was added a concentrated solution of sulfate acid, and then -
ethanol. After the fire, they observed an emerald-green flame color. What ions
were in the salt?
А. Nitrate ions.
В. Oxalate ions.
С. Thiocyanate ions.
D. Nitrite ions.
Е. Borate ions.*
3. In qualitative analysis, a series of transformations of organic matter are often

carried out to produce a colored product. What transformations should be made
for the qualitative determination of the nitro group in the aromatic nucleus?
А. Reduction, followed by transfer to isonitrile while boiling with chloroform in
an alkaline environment.
В. Reduction, with further diazotization and boiling with water.
С. Reduction followed by acetylation.
D. Reduction with further diazotization and azocompound.*
Е. Reduction followed by methylation to form a secondary amine.
4. In solution contains anions Cl- and Br-. Specify reagent for detection Br-:
А. Bromine water.
В. Barite water.
С. Lime water.
D. Chlorine water.*
47
Е. Gypsum water.
5. To the acidified analyte solution was added chloroform and sodium nitrite
solution. Chloroform layer was reddish-purple. This indicates the presence of the
solution:
А. Iodide ions.*
В. Sulfide ions.
С. Chloride ions.
D. Fluoride ions.
Е. Bromide ions.
6. By acidified with sulfuric acid solution, containing anions of the third analytical
group, added potassium iodide solution. Free iodine is released. What anions are
present in the solution?
А. Nitrite ions.*
В. Nitrate ions.
С. Arsenite ions.
D. Sulfite ions.
Е. Bromide ions.
7. According to the modern classification of anions, the group reagents are barium
nitrate; nitrate silver. What group of anions are anions Cl -, Br-, I-, S2-? Specify the
group reagent for the second group of anions:
А. Solution AgNO3.*
B. Solution NH3.
C. Solution H2SO4.
D. Solution NaOH.
E. Solution Ba(NO3)2.
8. Anaesthesine (ethyl ester p-aminobenzoic acid) - local anesthetic. With the help
of which a reagent can qualitatively prove the presence of an aromatic amino
group in molecule?
А. NaNO2 (HCl).*
B. AgNO3.
C. HNO3 (H2SO4).
48
D. Cu(OH)2.
E. NaHCO3.
9. Which ion is determined by a magnesia mixture (MgCl2+NH3⋅H2O+NH4Cl)?

A. SO42-.
B. HPO42-*.
C. SO32-.
D. CO32-.
E. I-.
10. The group reagent on the first analytical group of anions is barium nitrate.
With which anions it forms a precipitate?
А. Cl-, Br-, OH.
B. NO3-, NO2-, HCOO-.
C. BrO3-, Br-, ClO4-.
D. CH3COO-, S2-, I-.
E. PO43-, CO32-, SO42-*.
11. The analytical effect of the potassium iodide solution on non-colored anion
oxidants in the presence of chloroform is:
А. Change of physical form.
В. Allocation of bubbles of gas.
С. The appearance of the precipitate and its dissolution in excess of the reagent.
D. Sedimentation of white color.
Е. Occurrence of color of free iodine.*
12. Arsenit- and arsenate ions are part of some pharmaceuticals. A

pharmacopoeial reaction to detect said ions is the reaction with the solution:
А. Ammonium hydroxide.
В. Silver(I) nitrate. *
С. Potassium iodide.
Е. Antipyrine.
49
13. When the anions were detected by fractional method, they conducted a
reaction with antipyrine in a sulfuric acid environment – emerald-green color
appeared. What anion led to this analytical effect?
А. Nitrate ion.
В. Fluoride ion.
С. Bromide ion.
D. Nitrite ion.*
Е. Iodide ion.
14. Propose reagents for the detection of nitrite ions in the presence of nitrate ions
contained in the analyzed pharmaceutical preparation:
А. Iron(III) sulfate (concentrated) and potassium bromide.
В. Iron(II) sulfate (dilute) and potassium iodide.
С. Antipyrine and hydrochloric acid.*
D. Iron(II) chloride.
Е. Iron(III) chloride.
15. To identify the nitrate ions, a solution of diphenylamine and concentrated

sulfuric acid was added to the solution. What analytical effect is observed here?
А. Yellow precipitate.
В. Blue precipitate.
С. Blue color of the solution.*
D. White precipitate.
Е. Red color of the solution.
16. Specify the condition under which the oxidation-reduction reaction runs in the
forward direction:
А. Е0оx < Е0red.
В. Е0оx = Е0red.
С. Е0оx > Е0red.*
D. Е0оx < 0.
Е. Е0оx > 0.
17. An analytical feature of the action of potassium iodide solution on non-colored

anion oxidants is:
50
A. Change of physical state.
B. The appearance of brown coloration of free iodine.*
C. Sedimentation of white color.
D. Gas bubbles are allocated.
E. The appearance of the sediment and its dissolution in excess of the reagent.
18. To solution FeSO4 in the presence of concentrated H2SO4 the test solution was
added. The formation of a brown ring indicates the presence in the solution:
A. Carbonate ions.
B. Acetate ions.
C. Nitrate ions.*
D. Oxalate ions.
E. Phosphate ions.
19. In redox reactions of potassium dichromate K 2Cr2O7 is the only oxidant.

Specify the dichromate ion recovery product Cr2O72- in acidic environment:
A. Cr3+.*
B. Cr(OH)3.
C. [Cr(OH)6]3-.
D. Cr2O3.
E. Cr(OH)2.
20. With which of the reagents can be detected phenolic hydroxyl?

A. FeCl3.*
B. [Ag(NH3)2]OH.
C. I2 в KI.
D. NaNO2 (HCl).
E. Cu(OH)2.
21. To the solution acidified with sulfuric acid, containing anions of the third
analytical group, added a solution of potassium iodide. Free iodine is observed.
What anions are present in the solution?
A. Bromide ions.
B. Nitrite ions.*
C. Acetate ions.
51
D. Carbonate ions.
E. Sulphate ions.
22. To solution, containing anions of the second analytical group, added a solution
of silver nitrate. A pale yellow precipitate formed, insoluble in nitric acid and
partially soluble in ammonia solution. What anions are present in the solution?
A. Chloride ions.
B. Sulfide ions.
C. Bromide ions.*
D. Iodide ions.
E. Arsenite ions.
23. The technology of manufacturing drugs widely uses the phenomenon of ion
exchange and adsorption. Which of the ions is selectively adsorbed from the
aqueous solution on the crystal of silver chloride?
А. Ag+.*
B. OH-.
C. H+.
D. Cu2+.
E. NO3-.
24. In oxidation-reduction reactions, potassium permanganate KMnO 4 is the only

oxidant. When the reaction occurs in acidic environment, the raspberry solution is
discolored. Specify the recovery product MnO4- ion in the acidic environment:
A. Mn2+.*
B. MnO2.
C. [Mn(OH)4].
D. [Mn(OH)2].
E. MnO42-.
25. When the anions in the solution were detected by fractional method, conducted
a reaction with antipyrine – emerald-green color of the solution appeared. What
anion led to this analytical effect?
A. Nitrite ion.*
B. Chromate ion.
52
C. Nitrate ion.
D. Bromide ion.
E. Iodide ion.
26. To determine the nitrate anions the diphenylamine was added to the test
solution. What analytical effect is observed here:
A. The solution is blue.*
B. Sediment of yellow color.
C. Blue precipitate.
D. Isolation of brown gas.
E. The appearance of a characteristic smell.
27. The investigated solution of the drug contains anions of iodide, bromide,
chloride and sulfide. Which reagent is a group on these anions (the second
analytical group of anions)?
A. Silver nitrate in 2 М nitric acid.*
B. Barium chloride.
C. Barium nitrate.
D. Group reagent is absent.
E. Silver nitrate in a neutral environment.
28. The solution contains anions Cl- and Br-. What is the reagent for detection Br-:
A. Chlorine water.*
B. Bromine water.
C. Gypsum water.
D. Lime water.
E. Barite water.
29. To the analyzed solution was added chloroform and drops of chlorine water.
Chloroform layer turned orange. This indicates the presence of the solution:
A. Bromide ions.*
B. Iodide ions.
C. Sulfite ions.
D. Sulfate ions.
E. Nitrate ions.
53
30. A solution of sodium arsenate can be distinguished from a solution of arsenite
with the help of the following reagent:
A. Magnesia mixture.*
B. Potassium sulfate.
C. Potassium nitrate.
D. Sodium chloride.
E. Sodium fluoride.
31. When added to the analyzed solution of barium chloride formed a white
precipitate, insoluble in acids and alkalis. This indicates the presence in the
analyzed solution:
A. Sulfate ions.*
B. Chloride ions.
C. Nitrate ions.
D. Permanganate ions.
E. Ion iron(II).
32. To the acidified with sulfuric acid solution, containing anions of the third
analytical group, added potassium iodide solution. Free iodine is observed. What
anions are present in the solution?
A. Nitrite ions.*
B. Carbonate ions.
C. Sulphate ions.
D. Bromide ions.
E. Acetate ions.
33. To a solution containing anions of the second analytical group, a solution of

silver nitrate was added. A black precipitate was formed, insoluble in ammonia
solution, but soluble in heating in dilute nitric acid. What anions are present in the
solution:
A. Sulfide ions.*
B. Iodide ions.
C. Chloride ions.
D. Bromide ions.
54
E. Arsenite ions.
34. To a solution containing anions of the second analytical group, a solution of

silver nitrate was added. A pale yellow precipitate formed, insoluble in nitric acid
and partially soluble in ammonia solution. What anions are present in the solution:
A. Bromide ions.*
B. Iodide ions.
C. Chloride ions.
D. Sulfide ions.
E. Arsenite ions.
35. The analytical effect of the potassium iodide solution on non-colored anion
oxidants in the presence of chloroform is:
A. Appearance of free iodide coloring.*
B. Sedimentation of white color.
C. Change of physical state.
D. Isolation of gas bubbles.
E. The appearance of the precipitate and its dissolution in excess of the reagent.
36. What anions with a solution of silver(І) nitrate form a precipitate, soluble in
12% solution of ammonium carbonate?
A. Chloride ions.*
B. Bromide ions.
C. Sulfide ions.
D. Iodide ions.
E. Thiocyanate ions.
37. What are the anions with the salts of iron(II) in the presence of concentrated
sulfuric acid forming a brown ring?
A. Nitrate ions.*
B. Acetate ions.
C. Bromate ions.
D. Citrate ions.
E. Thiocyanate ions.
55
38. An analysis of the pharmaceutical product revealed anions of 3 analytical
groups. Specify the reagents for the reaction «brown ring»:
A. Iron(ІІ) sulfate (crystalline) і сульфатна кислота (concentrated).*
B. Iron(ІІ) sulfate (solution) and sulfuric acid (diluted).
C. Iron(ІІ) sulfate (solution) and sulfuric acid (concentrated).
D. Iron(ІІІ) sulfate (solution) and sulfuric acid (diluted).
E. Iron(ІІІ) sulfate (solution) and sulfuric acid (concentrated).
39. The investigated solution with a solution of chloride barium formed a white
precipitate not soluble in acids or alkalis. What is the composition of the resulting
precipitate?
A. Barium sulfate.*
B. Barium sulfite.
C. Barium carbonate.
D. Barium oxalate.
E. Barium phosphate.
40. The investigated solution formed a solution of nitrate argentum white cheese
precipitate, soluble in ammonia. Specify the sediment composition.
A. Silver chloride.*
B. Silver bromide.
C. Silver iodide.
D. Silver thiocyanate.
E. Silver sulfide.
41. The pharmacopoeial reaction of determining benzoate ions is the interaction

with the solution:
A. Iron(III) chloride.*
B. Potassium chloride.
C. Resorcinol.
D. Acetic anhydride.
E. Diphenylamine.
42. What substance can determine the presence of chloride ions in drinking water?
A. Silver nitrate.*
56
B. Iodine.
C. Potassium bromate.
E. Ammonia.
43. Pharmacopoeial reaction to phosphate ions is the effect of magnesia mixture.

The result is a white crystalline precipitate МgNH4PO4. The composition of the
magnesia mixture is as follows:
A. MgCl2, NH3·H2O, NH4Cl.*
B. MgCl2, NaOH, NaCl.
C. MnCl2, NH3·H2O, NaCl.
D. MgCl2, MnSO4, NH4Cl.
E. MgCl2, NH4Cl.
44. The first analytical group of anions include anions that form salt insoluble in
water:
A. Barium.*
B. Lead.
C. Ammonia.
D. Bismuth.
E. Mercury.
45. The second analytical group of anions include anions that form insoluble in
nitric acid salt:
A. Silver.*
B. Mercury.
C. Ammonia.
D. Bismuth.
E. Lead.
46. Why the anions of the third analytical group of anions do not have a group
reagent?
A. Most cations form water-soluble salts.*
B. They have large ionic radii.
C. Close ionic radii.
57
D. They have the ability to form soluble acids.
E. Belong to toxic elements.
47. The same analytical effect is observed in the interaction of nitrate and nitrite
ions with:
A. Diphenylamine and concentrated sulfuric acid.*
B. Potassium permanganate.
C. A solution of iodide and potassium iodide.
D. Nitrate solution.
E. A solution of chloride barium.
48. The determination of anions I of the analytical group is carried out under
action:
A. Solution BaCl2 neutral or slightly alkaline environment.*
B. Solution BaCl2 in acidic environment.
C. Solution AgNO3 in acidic environment.
D. Solution mineral acid.
E. Solution alkali.
49. In the analysis of anions I-III analytical groups, a systematic analysis of the
analysis is required in the presence of the general:
A. Sulfate-, sulfit-, tiosulfat- and sulfide-ions.*
B. Sulphate-, acetate-, phosphate-ions.
C. Sulfate-, nitrat-e, chloride-ions.
D. Sulphate-, oxalate-, acetate-ions.
E. Sulfate-, arsenate-, nitrate-ions.
50. The method of treating foreign ions in the analysis is called?

A. Analytical «masking».*
B. Analytical division.
C. Analytical exclusion.
D. Analytical concentration.
E. Analytical coprecipitation.
58
51. The group reagent on the first analytical group of anions is barium nitrate.
Specify the anions of the first group:
A. Cl-, Br-, OH-.
B. PO43-, CO32-, SO42-.*
C. CH3COO-, S2-, I-.
D. NO3-, NO2-, HCOO-.
E. BrO3-, Br-, ClO4-.
52. Nitrite ions in the presence of nitrate ions can be detected using:
A. Crystalline sodium thiosulfate.
B. Crystalline iron(II) sulfate.
C. Diphenylcarbazone.
D. Dimethylglyoxime.
E. Crystal antipyrine in the presence of a dilute HCl.*
53. What reagent is used to separate the precipitate AgCl from AgI?
A. Concentrated solution of potassium chloride.
B. Aqueous ammonia solution. *
C. A solution of sulfuric acid.
D. Diluted nitric acid.
E. Concentrated nitric acid.
54. The solution contains iodide- and chloride-ions. Choose reagent for detection
of iodide ions:
А. Chloride water.*
В. Lime water.
С. Gypsum water.
D. Dihydrogen sulfide.
Е. Barite water.
55. Classification of anions is based on the different solubility of their salts with
anions Ва2+ and Ag+. Anions of the first analytical group form water-soluble salts
with ions:
А. Ва2+ (alkaline or neutral environment).*
В. Ag+ (neutral environment).
59
С. Ag+ (environment ammonia buffer).
D. Ag+ (alkaline environment).
Е. Ag+ (acidic environment).
56. What reagent is used to separate the precipitate AgCl and AgI?
А. Concentrated nitric acid.
В. A solution of sulfuric acid.
С. Concentrated solution of potassium chloride.
D. Aqueous ammonia solution.*
Е. Diluted nitric acid.
57. To the solution containing the anions of the second analytical group, added a
solution of chlorine water and an organic extractant. This formed the violet color
of the organic layer. What anions are present in the solution?
А. Bromide ions.
В. Iodide ions.*
С. Chloride ions.
D. Sulfide ions.
Е. Thiocyanate ions.
58. Specify what value is used to characterize the oxidation-reducing ability of

substances:
A. The value of redox potentials.*
B. The magnitude of the electronegativity of the elements.
C. Number of received and devoted electrons.
D. The magnitude of the degree of oxidation.
E. The number of hydrogen ions involved in the reaction.
59. Choose reagents to detect sulfate-ions in a solution containing carbonate,

sulfate, phosphate-ions:
A. Ba(NO3)2, HCl.*
B. Ba(NO3)2, NaOH.
C. BaCl2, H2O.
D. CaCl2, NH4ОH.
E. AgNO3, HNO3.
60
60. The same analytical effect is observed in interaction NO3- and NO2-- ions from:
A. Diphenylamine and concentrated H2SO4.*
B. Solution KMnO4.
C. Solution I2 in KI.
D. Solution AgNO3.
E. Solution BaCl2.
61. What anions are present in the solution if the reaction with antipyrine in the
presence of concentrated sulfuric acid appears in red color?
А. Nitrate ions.*
В. Carbonate ions.
С. Sulphate ions.
D. Acetate ions.
Е. Oxalate ions.
62. What anions are present in the solution if, as a result of reaction with a
solution of argentum nitrate in nitric acid medium, a black precipitate is formed,
soluble in concentrated nitric acid with heating?
А. Sulfide ions.*
В. Carbonate ions.
С. Sulphate ions.
D. Bromate ions.
Е. Oxalate ions.
63. When conducting a test on anions of unstable acids with characteristic hissing
colorless gas released. Which anion was in solution?
А. Сl-.
B. SiO32-.
C. SO42-.
D. CO32-.*
E. CH3COO-.
64. At carrying out of an express-analysis on a benzoate-ions reaction with a

iron(III) chloride (pharmacopeia’s reaction) is formed:
61
А. Green precipitate.
В. Pink and yellow precipitate.*
С. Red precipitate.
Е. Blue precipitate.
65. Which reagent is used to separate AgCl precipitate from AgI?

А. Dilute nitric acid
B. Concentrated nitric acid
С. Concentrated potassium chloride solution
D. Aqueous solution of ammonia *
Е. Sulfuric acid solution
66. Chloroform and sodium nitrite solution were added to the acidified solution to
be analysed. The chloroform layer turned red-purple. What ions are present in the
solution due to this colouration?
A. Iodide ions *
B. Carbonate ions
С. Fluoride ions
D. Sulphate ions
E. Chloride ions
67. Add chloroform to the solution to be analysed and chlorine water dropwise.
The chloroform layer turns orange. This indicates the presence of the following in
the solution:
A. Iodide ions
B. Bromide ions *
С. Nitrate ions
D. Sulfite ions
E. Sulphate ions
68. An analytical chemist is performing a qualitative analysis of phosphate ions

using a pharmacopoeial reaction that has produced a yellow precipitate. Which
reagent was used?
А. Potassium nitrate
62
B. Potassium chloride
С. Sodium nitrate
D. Silver nitrate *
E. Hydrochloric acid
69. To detect anions in the solution, a fractional reaction with antipyrine was
performed. The solution turned an emerald green colour. Which anion caused this
analytical effect?
A. Iodide ion
B. Nitrate ion
С. Chromate ion
D. Bromide ion
E. Nitrite ion *
63
QUANTITATIVE ANALYSIS
64
Acid-base titration
1. The 0.1 M sodium hydroxide solution used for the quantitative determination of
drugs with acidic properties. Calculate the NaOH mass to prepare 0.5 liters of this
solution:
А. 50 g.
В. 40 g.
С. 30 g.
D. 10 g.
Е. 2 g.*
2. The 0.1 M solution of hydrochloric acid used as a titrant in pharmaceutical

analysis. What amount of this acid can be prepared with 100 ml of 0.5 M HCl
solution?
А. 50 ml.
В. 5000 ml.
С. 500 ml.*
D. 1000 ml.
Е. 200 ml.
3. Specify the primary standard to standardization of titrant (HCl, H 2SO4) by the

acidimetry method:
А. Na2CO3, Na2B4O7.*
B. NaCl, KCl.
C. K2Cr2O7, KMnO4.
D. MgSO4, ZnSO4.
E. NaCl, Na2B4O7.
4. Up to 10,00 sm3 of 0,1000 mol/dm3 hydrochloric acid solution added 12,00 sm3
of 0,1000 mol/dm3 sodium hydroxide solution. Specify color of the solution in the
presence of phenolphthalein:
А. Colorless.
В. Red.
С. Orange-pink.
D. Pompadour.*
65
Е. Yellow.
5. Specify the primary standard to standardization of hydrochloric acid by acid-

base titration method:
А. Zinc sulphate.
В. Oxalic acid.
С. Sodium chloride.
D. Sodium tetraborate. *
Е. Sodium hydroxide.
6. Choose the pair of titrants to determine the CH 3COOH by the back titration
method:
A. NaOH, HCl.*
B. NaOH, AgNO3.
C. NaOH, KOH.
D. HCl, H2SO4.
E. NH4NCS, AgNO3.
7. For the quantitative determination of sodium carbonate in the drug by the acid-
base titration method as indicator used:
А. Murexide.
В. Diphenylamin.
С. Methyl orange. *
D. Methyl blue.
Е. Ferroin.
8. Sodium hydrocarbonate, sodium bromide, ammonium chloride are present in

the mixture. Choose the method for the quantitative determination of sodium
hydrocarbonate in the mixture:
А. Acidimetry.*
В. Complexometry.
С. Alkalimetry.
D. Permanganatometry.
Е. Precipitation titration.
66
9. Quantitative content of КОН and К2СО3 in composite can be determined by
means of the following method:
А. Cannot be titrated.
В. Direct acidimetry with two indicators.*
С. Substitutive acidimetry.
D. Direct acidimetry with phenolphthalein.
Е. Back acidimetry.
10. In the analytical laboratory the chemist should standardize the solution of
sodium hydroxide. Which primary standard solution can be used for this?
А. Acetic acid.
В. Sodium tetraborate.
D. Oxalic acid.*
11. The 0.1 M solution of hydrochloric acid used as a titrant in pharmaceutical
analysis.
What amount of this acid can be prepared with 100 ml of 1 M HCl solution?
А. 200 ml.
В. 50 ml.
С. 1000 ml.*
D 2000 ml.
Е. 5000 ml.
12. Specify a substance that has the same values of molar mass and molar mass of
equivalent:
А. Na2SO4.
B. H3PO4.
C. Al2(SO4)3.
D. HCl.*
E. Mg(OH)2.
13. When selecting pH indicators, the most significant is:

А. Properties of reaction products.
В. Measurement of pH in the process of titration.
67
С. The nature of certain substances.
D. pH of the medium at the equivalence point.*
Е. The nature of the titrant.
14. Choose the pair of standard substances to standardization of acidimetry

method titrants:
А. Sodium carbonate, sodium tetraborate.*
В. Sodium bromide, sodium acetate.
С. Sodium chloride, sodium tetraborate.
D. Sodium sulfate, sodium carbonate.
Е. Sodium oxalate, sodium sulfite.
15. The acidimetry method used for the quantitative determination of

pharmaceutical substances. Titrant of this method is secondary standard solution
of hydrochloride acid. What substance used for established of exact concentration
of hydrochloride acid?
A. Oxalic acid.
B. Potassium dichromate.
C. Sodium tetraborate.*
D. Magnesium sulfate.
E. Sodium thiosulfate.
16. Specify the primary standard to standardization of titrant (NaOH, KOH) by the
alkalimetry method:
A. Acetic and succinate acids.
B. Formic and acetic acids.
C. Sulfanil and salicylic acids.
D. Sulfanil and oxalic acid.
E. Oxalic and succinate acids.*
17. The alkalimetry method used for the quantitative determination of

pharmaceutical substances. Titrant of this method is 0.1 M solution of sodium
hydroxide. What substance used for established of exact concentration of sodium
hydroxide?
A. Sodium thiosulfate.
68
B. Sodium tetraborate.
C. Potassium dichromate.
E. Oxalic acid.*
18. Choose the pair of titrants to determine the ammonium hydroxide by the back
titration method:
A. KOH, NaOH.
B. HCl, NaOH.*
C. H2SO4, K2SO4.
D. HCl, H2SO4.
E. NaOH, KCl.
19. What substance can be determined by acid-base titration and by oxidation-

reduction titration?
А. Ammonium chloride.
В. Calcium nitrate.
С. Sodium hydroxide.
D. Sodium sulfate.
E. Oxalic acid.*
20. What is the method of titrimetric analysis can be carry out to quantitative
determination of sulfate acid by the solution of potassium hydroxide?
А. Acidimetry.
В. Sedimentation.
С. Alkalimetry.*
D. Oxidation-reduction.
E. Complex formation.
21. Which of the following solutions used as working (titrant) in the alkalimetric
method:
A. Potassium hydroxide.*
B. Hydrochloride acid.
C. Oxalic acid.
D. Sodium tetraborate.
69
E. Ammonium hydroxide.
22. In the analytical laboratory the chemist should standardize the solution of
sodium hydroxide. Which primary standard solution can be used for this?
A. Oxalic acid.*
B. Acetic acid.
C. Hydrochloride acid.
E. Sodium chloride.
23. Select the weakest carboxylic acids by the value of pKa:

А. Formic (рКа = 3,7)
B. Butyric (рКа = 4,82)
C. Acetic (рКа = 4,7)
D. Lactic (рКа = 3,9)
E. Propionic (рКа = 4,9)*
24. The acidimetric method used for the quantitative determination of

pharmaceutical substances. Titrant of this method is secondary standard solution
of hydrochloride acid. What substance used for established of exact concentration
of sodium hydroxide?
A. Sodium tetraborate.*
B. Oxalic acid.
D. Sodium thiosulfate.
E. Magnesium sulfate.
25. At the back titration of aqueous solution of acetic acid as indicator used:
A. Phenolphthalein.*
B. Diphenylamine.
D. Eriochrome Black T
E. Murexide.
26. The sample contains sodium hydrocarbonate and sodium chloride. Propose the
70
titrimetric method for the quantitative determination of sodium hydrocarbonate:
A. Acid-base.*
B. Dichromatometry.
C. Cerimetry.
D. Trilonometry.
E. Iodometry.
27. Boric acid (Ka = 5.8 ∙ 10-10) in an aqueous solution in the presence of glycerol
can be determine by the method:
A. Alkalimetry.*
B. Acidimetry.
C. Iodometry.
E. Cerimetry.
28. Choose the chemical utensils that used in the titrimetric analysis methods to
measure the exact volume of the titrant.
A. Burette.*
B. Pipette.
C. Volumetric flask.
D. Measuring cylinder.
Е. Beaker.
30. Choose the chemical utensils that used in the titrimetric analysis
methods to measure the volume of auxiliary reagents.
A. Measuring cylinder.*
B. Volumetric flask.
С. Burette.
D. Pipette.
E. Сone flask.
31. Specify the titration method in which the standard solution of titrant gradually
added to the test solution of the substance to the establishment of the final titration
point:
A. Direct.*
71
В. Back.
C. Indirect.
D. Substitution titration.
E. Precipitation titration.
32. It is necessary to carry out quantitative determination of sodium

hydrocarbonate in the preparation. Which of the methods of titrimetric analysis it
can be determined?
A. Acid-base titration.*
B. Complexometric titration.
C. Precipitation titration.
D. Non-aqueous titration.
E. Oxidation-reduction titration.
33. To select the indicator in the acid-base titration method build a titration curve.
A titration curve is:
A. рН solution as a function of volume of added titrant.*
B. рН solution as a function of concentration of the added titrant solution.
C. рН solution as a function of volume of test solution.
D. Concentration of test solution as a function of рН solution.
E. рН solution as a function of temperature.
34. What is the method of titrimetric analysis can be carry out to quantitative
determination of sulfate acid by the solution of potassium hydroxide?
A. Alkalimetry. *
B. Acidimetry.
C. Oxidation-reduction.
D. Precipitation.
E. Complexometric.
35. Specify the value of the equivalence factor of Na2CO3 at the quantitative
determination according to the reaction: Na2CO3+HCl=NaCl+NaHCO3
A. f=1.*
B. f=1/2.
C. f=2.
72
D. f=1/4.
E. f=4.
36. Choose the pair of titrants to determine the ammonium hydroxide by the back
titration method.
A. НCl, NaOH.*
B. НCl, H2SO4.
C. KOH, NaOH.
D. NaOH, KCl.
E. H2SO4, K2SO4.
37. Specify the primary standard to standardization of hydrochloric acid:

A. Na2CО3.*
B. KMnO4.
C. NaOH.
D. I2.
E. КІ.
38. Choose the appropriate methodical method if the substance is volatile:

A. Back titration.*
B. Direct titration.
C. Substitution titration.
D. Titration with the instrumental fixation of the equivalence point.
E. The method of individual weighting.
39. Choose the appropriate methodical method if the substance reacts with the
titrant stoichiometrically, but slowly:
A. Back titration.*
B. Substitution titration.
C. Direct titration.
D. Titration with the instrumental fixation of the equivalence point.
E. The method of individual weighting.
40. Which solution used to determine the mass fraction of ammonia in the
solution?
73
A. Hydrochloride acid.*
B. Sulfate acid.
C. Potassium permanganate.
D. Iodine.
41. Choose the indicator and the method of titrimetric analysis to determine the
hydrogencarbonate-ions of pharmaceuticals:
A. Methylorange, Acidimetry.*
B. Phenolphthalein, Acidimetry.
C. Methylorange, Alkalimetry.
D. Phenolphthalein, alkalimetry.
E. Murexid, Acidimetry.
42. Which method of titration used if an accurately measured excess of the

auxiliary titrant added to the solution of the test substance:
A. Back titration.*
B. Non-aqueous titration.
C. Direct titration.
D. Substitution titration.
E. Any titration.
43. In the calculation of analysis results through the titre of titrant per test
substance used:
A. Current factor to molar concentration.*
B. Conversion factor.
C. Corrective index.
D. Ratio.
E. Deflexion coefficient.
44. The standard solution of alkali used to determine acidic nature substances.
This method is called:
A. Alkalimetry. *
B. Acidimetry.
C. Complexometric titration.
74
D. Redoximetry.
E. Gravimetry.
45. With the help of which indicators determine the end point of titration in the
method of acid-base titration:
A. рН-indicators.*
B. Adsorption indicators.
C. Redox- indicators.
D. Fluorescent indicators.
E. Metal indicators.
46. The pH value at which the most drastic change in the color of the indicator
occurs called:
A. Titration exponent of indicators.*
B. Indicator constant.
C. Indicator range.
D. Equivalence point.
E. End point of titration.
47. The acid-base titration method determined:

A. Acids, alkalis and salts that are hydrolyzed.*
B. Only strong acids.
C. Only strong alcalis.
D. Only strong acids and weak alkalis.
E. Only salts that are hydrolyzed.
48. Choose pair of substances which determined by the method of back acid-base
titration:
A. NH3∙H2O, CH3COOH.*
B. NaOH, KOH.
C. KOH, K2CO3.
D. NaHCO3, NaOH.
E. Na2CO3, NaCl.
49. The quantitative determination of ammonia carried out by the method:
75
A. Alcalimetry, back titration.*
B. Acidimetry, back titration.
C. Alcalimetry, direct titration.
D. Acidimetry, direct titration.
E. Сomplexometry.
50. The quantitative determination of carbonates and hydrocarbonates carried out

by the method:
A. Direct acidimetry.*
B. Back acidimetry.
C. Direct alcalimetry.
D. Back alcalimetry.
E. Сomplexometry.
51. The medicinal drug contains sodium hydrocarbonate and sodium chloride.
Propose the titrimetric method for the quantitative determination of sodium
hydrocarbonate:
A. Acid-basic titration.*
B. Precipitating titration.
C. Oxidation-reduction titration.
D. Complexometric titration.
E. Coulometric titration.
52. Specify which characteristic in the titrimetric methods of analysis used when
choosing an indicator:
A. Indicator range.*
B. Indicator constant.
C. Titration leap.
D. Titration exponent.
E. Neutralization point.
53. Specify the type of chemical reaction at the titration of acetic acid by solution
of sodium hydroxide:
A. Acid-base.*
B. Oxidation-reduction.
76
C. Electrophilic substitution.
D. Precipitation.
54. Indicators used to determine the final titration point in the acid-base titration
method are:
A. рН indicators.*
B. Redox- indicators.
C. Adsorption indicators.
D. Metal indicators.
E. Fluorescent indicators.
55. Choose the standard solutions (titrants) of the acid-base titration method:
A. NaOH, HCl.*
B. AgNO3, BaCl2.
C. NaNO2, Nа2S2O3.
D. KI, K2Cr2O7.
E. КІ, KMnO4.
56. What are the standard solutions (titrants) used in the acid-base titration
method?
A. KI, K2Cr2O7.
B. KI, KMnO4.
C. NaNO2, Na2S2O3.
D. AgNO3, BaCl2.
E. NaOH, HCl.*
57. Choose indicators to the acidimetric determination of substances in a mixture

of NaOH and Na2CO3:
A. Potassium chromate, ferric ammonium alumina.
A. Diphenylcarbazone, diphenylcarbazide.
B. Eosin, fluorescein.
C. Tropeolin 00, methylene blue.
D. Phenolphthalein, methyl orange.*
77
58. Choose the secondary standard to standardize the solution of sulfate acid:
А. Sodium hydroxide.*
В. Potassium iodide.
D. Argentum nitrate.
Е. Magnesium sulfate.
59. Choose the primary standard to standardize the solution of sulfate acid:
А. Sodium carbonate.*
В. Salicylic acid.
С. Oxalic acid.
D. Arsenic oxide.
Е. Sodium chloride.
60. Titrants of the neutralization method are standard solutions of acids and
alkalis, which are secondary standard solutions. Choose a substance that
standardizes the solution of hydrochloride acid:
А. СaCO3.
B. Na2S2O3.
C. H2C2O4.
D. HNO3.
E. Na2CO3.*
61. To measure the exact volume of the titrant in the titrimetric analysis used:
А. Measuring tube.
В. Burette.*
С. Volumetric flask.
D. Measuring cylinder.
Е. Measuring glasses.
62. When separating cations into analytical groups according to the acid-base
classification, the group reagents are acids and bases. Which acids are used as
group reagents?
А. HNO3, CH3COOH
В. H2CO3
С. HClO4
78
D. HCl, H2SO4 *
Е. H3PO4, H2C2O4
63. Which solution is used to determine the mass and volume fraction of ammonia
in a solution?
А. Potassium permanganate
B. Hydrochloric acid *
С. Sodium hydroxide
D. Iodine
E. Sulfuric acid
64. Which of the following solutions is used as a working solution (titrant) in the
alkalimetric method?
A. Ammonium hydroxide
B. Oxalic acid
C. Hydrochloric acid
D. Potassium hydroxide *
E. Sodium tetraborate
65. What analytical method is used to quantify iodine in solution?

А. Redox titration *
B. Precipitation titration
С. Alkalimetry
D. Acidimetry
E. Complexometry
66. What is used as an indicator in the back titration of an aqueous solution of

acetic acid?
A. Murexide
B. Eriochrome black T
C. Diphenylamine
D. Diphenylcarbazone
E. Phenolphthalein *
67. What solution is used to determine the mass-volume fraction of ammonia in a

solution?
A. Hydrochloric acid solution *
79
B. Sulfuric acid solution
C. Potassium permanganate solution
D. Sodium hydroxide solution
E. Iodine solution
68. What indicator is used, when sodium carbonate is being quantified in the
preparation by means of acid-base titration?
A. Ferroin
B. Murexide
C. Diphenylamine
D. Methylene blue
E. Methyl orange *
80
Oxidation-reduction titration
1. Some oxidation-reduction reactions accompanied by the course of side

induced (bound) reactions, in which one reaction proceeds independently, and the
second only during the course of the first one. What called a substance that
participates in both reactions?
A. Actor.*
B. Inductor.
C. Acceptor.
D. Catalyst.
E. Indicator.
2. Indicate why sodium thiosulfate cannot used in acidic media:

А. It decomposes with the release of sulfur. *
В. Raises hydrolysis.
С. Oxidized to SO42- ion.
D. Slows down hydrolysis.
Е. It leads to the formation of S4O62-.
3. The indicators of bromometry method are azo dyes: methyl orange, methyl red.
Solution discolor in the end point of titration. What is the reason for that?
А. Changes of ionic strength of solution.
В. Precipitation of indicators.
С. Irreversible oxidation of indicators.
D. Changes redox-potentials of indicators.
Е. Bromination of indicators. *
4. Sodium thiosulfate determined by direct iodometric titration. Starch used as

indicator. How to determine the end point of titration?
А. By the appearance of red color.
В. By the white precipitate.
С. By the appearance of blue color. *
D. By the appearance of brown color.
Е. By discoloration of the solution.
81
5. It is necessary periodically monitor the concentration of titrated iodine solution
in potassium iodide. What solution used to standardize it?
А. Hydrochloride acid solution.
В. Sodium thiosulfate solution. *
С. Sodium hydroxide solution.
D. Potassium chloride solution.
Е. Trilon B solution.
6. Which the standard substance used to determine the exact molar concentration
of equivalent of potassium permanganate solution?
А. Sodium nitrite.
В. Arsenous acid anhydride.
С. Sodium oxalate.*
D. Sodium carbonate.
Е. Potassium bromate.
7. Sodium salicylate contains phenolic hydroxyl. Propose the method of

quantitative determination of this salt:
А. Alkalimetry.
В. Mercurimetry.
С. Bromometry. *
D. Argentometry.
Е. Complexometry.
8. Arsenous (III) oxide determined in medicinal preparations by the iodometric

method. Choose the indicator:
А. Starch solution.*
В. Phenolphthalein.
С. Eosin.
D. Murexid.
Е. Tropeolin 00.
9. Determination of the ferrum (II) salts in the presence of Cl --ions by the

permanganatometry method can be carry out if their influence eliminated by the
addition of:
82
А. Acetate buffer solution.
В. Bromate-bromide mixture.
С. Mixture of MnSO4, H3PO4, H2SO4.*
D. Mixture of MgCl2, NH4Cl, NH4OH.
Е. Phosphate buffer solution.
10. Titrated solutions of iodine and sodium thiosulfate used in iodometry. What
substance used to standardize sodium thiosulfate solution?
А. K2Cr2O7.*
B. As2O3.
C. K2CO3.
D. Na2B4O7.
E. NaCl.
11. H2O2 determined by permanganatometry method in a highly acid medium.

Which acid used to create medium in this case?
А. CH3COOH.
B. H2SO4.*
C. HNO3.
D. H3PO4.
E. HCl.
12. Redox-methods used to the quantitative determination of oxidizing and

reducing agents. Which substance can be determine by this method?
А. Potassium chloride.
В. Sodium hydroxide.
С. Hydrogen peroxide.*
D. Magnesium sulfate.
Е. Sodium hydrocarbonate.
13. Which substance used to standardize of KMnO4 solution?

А. Sodium nitrite.
С. Potassium bichromate.
D. Oxalic acid.*
83
Е. Potassium iodide.
14. To standardize of KMnO4 solution as primary standard substance used:

А. Sodium chloride.
С. Potassium bichromate.
D. Oxalic acid.*
Е. Sodium thiosulfate.
15. At the nitritometric determination of primary aromatic amines in the acidic

medium, the product of the reaction is:
А. Nitrozoantipyrine.
В. Azid.
С. Nitrozoamine.
D. Nitrozoarilamin.
Е. Diazonium salt.*
16. The content of potassium dichromate in solution determined by the iodometric

method. Specify the titrant of the iodometric method for the determination of
strong oxidizing agents:
A. Sodium hydroxide.
B. Potassium permanganate.
C. Potassium bromate.
D. Potassium iodide.
E. Sodium thiosulfate.*
17. With the help of which a self-indicator method can determine the quantitative
content of the ferrum (II)?
A. Argentometry.
B. Permanganatometry.*
C. Iodometry.
D. Complexometry.
E. Nitritometry.
18. Choose the indicator to fixation of titration end point in nitritometric method:
84
A. Methyl orange.
B. Starch solution.
C. Methylene blue.
D. Tropaeolin 00 + methylene blue.*
E. Diphenylamin.
19. It is necessary to determine the amount of sodium salicylate in solution. What

method of titrimetric analysis can be used for the quantitative determination of
aromatic compounds?
А. Complexometry.
В. Cerimetry.
С. Bromometry.*
D. Argentometry.
E. Mercurimetry.
20. Propose a redox method for the quantitative determination of the ferrum (II)
salts in a solution containing hydrochloride acid:
А. Nitritometry.
В. Permanganatometry.
С. Iodometry.
D. Ascorbinometry.
E. Dichromatometry.*
21. Specify the standard solutions that used in iodometry for direct and back
titration of reducing agents:
A. I2, KI.
B. KMnO4, KI.
C. I2, Na2S2O3.*
D. K2Cr2O7, Na2S2O3.
E. K2Cr2O7, I2.
22. 0.1 M potassium permanganate solution is titrant of permanganatometric

method. It is prepared as a secondary standard solution and standardized by:
А. Arsenous oxide.*
В. Potassium bichromate.
85
С. Sodium carbonate.
D. Calcium oxide.
E. Sodium chloride.
23. Potassium dichromate solution used to standardize sodium thiosulfate solution.

At this time, carry out:
A. Substitutive titration.*
B. Direct titration in highly acidic medium.
C. Back titration in acidic medium.
D. Back titration in alkaline medium.
E. Direct titration in alkaline medium.
24. The quantitative content of hydrogen peroxide can be determine by a self-

indicator method:
A. Permanganotometry.*
B. Bromatometry.
C. Iodometry.
D. Nitritometry.
E. Argentometry.
25. 0.1 M sodium nitrite solution is titrant of nitritometric method. It is prepared

as a secondary standard solution. The exact concentration of sodium nitrite
established by:
A. Sulfanilic acid. *
B. Hydrochloride acid.
C. Acetate acid.
D. Oxalic acid.
E. Sulfate acid.
26. In the analytical laboratory to determine the chlorine content in water used
method of:
A. Iodometry.*
B. Permanganatometry.
C. Chromatometry.
D. Nitritometry.
86
E. Cerimetry.
27. Specify the type of reaction that occurs when determining the ascorbic acid in
the preparation by iodometric method:
A. Oxidation-reduction.*
B. Acylation.
C. Neutralization.
D. Sedimentation.
28. The sulfanilamide preparations have primary aromatic amino group. Check the
method of quantitative determination of this preparation:
A. Nitritometry.*
B. Iodometry.
C. Dichromatometry.
E. Cerimetry.
29. For quantitative determination of ferrum (II) in pharmaceutical preparations

used self-indicator method
A. Permanganatometry.*
B. Complexometry.
C. Argentometry.
D. Iodometry.
E. Nitritometry.
30. In what medium are most often carried out permanganametometric titration of
ferrum (II)?
A. In sulfate acid.*
B. In alcohol
C. In nitrate acid.
D. In alkaline.
E. In hydrochloride acid.
31. At the bromometric determination of streptocide (primary aromatic amine)
87
applied direct titration by potassium bromate standard solution. The indicator of
this titration is:
A. Methyl orange.*
B. Phenolphthalein.
C. Eriochrom Black T.
D. Ferrum (ІІІ) thiocyanate.
E. Murexide.
32. Back titration used for iodimetric determination of formaldehyde in formalin.

Excess of iodine titrated by standard solution of:
A. Sodium thiosulfate.*
B. Sodium nitrate.
C. Sodium sulfate.
E. Sodium phosphate.
33. Iodometry is one of redoxmetric methods. As a titrant of this method used

solution of:
B. Cerium sulfate.
C. Sodium nitrite.
E. Potassium permanganate.
34. The sulfanilamide preparations have primary aromatic amino group. Check the
method of quantitative determination of this preparation:
A. Nitritometry.*
B. Iodometry.
C. Dichromatometry.
E. Cerimetry.
35. Determination of arsenous (III) oxide in pharmaceutical preparations carried

out by iodometric method. Choose the indicator:
A. Starch solution.*
88
B. Murexid.
C. Tropeolin 00.
D. Eosin.
E. Phenolphthalein.that
36. In the iodometric method, the end point of titration determined using the starch
indicator that added:
A. At the end of the titration.*
B. At the start of the titration.
C. When 50% of the analyzed substance is titrated.
D. At the point of equivalence.
E. In the process of titration.
37. In determining the mass fraction of hydrogen peroxide by the

permanganatometry method, the required pH value of the medium created by:
A. Sulfate acid. *
B. Nitric acid.
C. Acetate acid.
D. Hydrochloride acid.
E. Oxalic acid.
38. Determination of the mass fraction of ascorbic acid by the cerimetry method
carried out in the presence of pheroine, which belongs to:
А. Redox-indicators.*
B. Metal indicators.
C. Fluorescent indicators.
D. Acid-base indicators.
E. Adsorption indicators.
39. Specify a pair of substances that can used to standardize of 0.1 M KMnO 4
solution:
A. Na2C2O4, H2C2O4.*
B. K2CO3, CH3COOH.
C. CH3COOK, H2C2O4.
D. KHC2O4, HCOOH.
89
E. Na2C2O4, CH3COOH.
40. It is necessary to determine the amount of sodium salicylate in solution. What

method of titrimetric analysis can be used for quantitative determination of
aromatic compounds?
A. Bromometry.*
B. Mercurimetry.
C. Cerimetry.
D. Argentometry.
E. Complexometry.
41. Indicate how the end point of titration is determined in the method of
permanganatometry:
A. Upon appearance of the solution color from excess titrant drop.*
B. By the formation of a complex compound of the indicator with titrant.
C. By the formation of a low-soluble compound of the indicator with titrant.
D. By the formation of a low-soluble compound of indicator with analyzed
substance.
E. By the destruction of a complex compound of titrant with analyzed substance.
42. What is the titrimetric method of analysis underlay the quantitative

determination of iodine with sodium thiosulfate solution?
B. Alkalimetry.
C. Acidimetry.
D. Precipitation.
43. Propose the titrimetric method of quantitative analysis of ascorbic acid in the
preparation:
A. Oxidation-reduction. *
B. Complexonometry.
C. Acidimetry.
D. Precipitation.
E. Complexometry.
90
44. For the iodometric determination of oxidising agents as a titrant can used:
A. Working solution Na2S2O3.*
B. Working solution KMnO4.
C. Working solution NaОН.
D. Working solution K2Cr2O7.
E. Working solution КOH.
45. Specify the titrant solution to standardize the iodine monochloride solution:
C. Sodium chloride.
E. Iodine.
46. Choose one of the pairs of methods for the quantitative determination of oxalic
acid:
A. Acid-basic titration, permanganatomometry.*
B. Acid-basic titration, argentometry.
C. Acid-basic titration, trilonometry.
D. Permanganatomometry, mercurometry.
E. Permanganatomometry, mercurimetry.
47. Nitritometric determination of the quantitative content of compounds having a

primary aromatic amine group occurs under conditions:
A. Compliance with all of these conditions.*
B. At temperatures up to 10оС.
C. At adding crystalline KBr (catalyst).
D. In an excess of hydrochloride acid.
E. At slow titration.
48. The substances from which the primary standard solutions of titrants can be
prepared include:
A. К2Cr2О7.*
B. NaOH.
91
C. I2.
D. KMnO4.
E. HCl.
49. What reactions are used in methods of permanganatometry, dichromatometry,

iodometry:
B. Precipitation.
C. Complex formation.
D. Neutralization.
E. Hydrolysis.
50. Check in which method of the oxidation-reduction titration are used external
indicators to fixation of titration end point.
A. Nitritometry.*
C. Iodometry.
D. Cerimetry.
E. Bromatometry.
51. Check in which method of the oxidation-reduction titration is used specific

indicator of starch to fixation of titration end point.
A. Iodometry.*
C. Nitritometry.
D. Cerimetry.
E. Bromatometry.
52. Check in which method of the oxidation-reduction titration are used specific
pH-indicators to fixation of titration end point:
A. Bromatometry. *
C. Nitritometry.
D. Cerimetry.
E. Iodometry.
92
53. How many titrants is the method of iodometric titration?
A. 2.*
B. 1.
C. 3.
D. 4.
E. 5.
54. What substances can be determined by substitution titration in the method of

iodometry:
A. Strong oxidizing agents.*
B. Strong reducing agents.
C. Weak reducing agents.
D. Saturated hydrocarbons.
E. Unsaturated hydrocarbons.
55. Which titrant is used in the bromometric titration method:

A. KBrO3.*
B. KBr.
C. Br2.
D. KBrO4 + KCl.
E. KBrO4.
56. KMnO4 used as a titrant in permanganametry. What is the factor of

equivalence of this compound if titration is carried out in acidic medium:
A. 1/5.*
B. 1/4.
C. 1/2.
D. 1/3.
E. 1.
57. Determination of the end point of the titration in the redox methods is carried
out: self-indicator method, using specific indicators and redox indicators. How
determine the end point of titration in iodometry?
A. With the help of a specific indicator of starch.*
93
B. Self-indicator method.
C. With the help of a specific indicator of ferrum thiocyanate.
D. With the help of the redox-indicator of diphenylamine.
E. With the help of methyl red.
58. Determination of the end point of the titration in the redox methods is carried
out: self-indicator method, using specific indicators and redox indicators. How
determine the end point of titration in permanganatometry?
A. Self-indicator method.*
B. With the help of a specific indicator of ferrum thiocyanate.
C. With the help of a specific indicator of starch.
D. With the help of methyl red.
E. With the help of the redox-indicator of diphenylamine.
59. To determine the mass fraction of ferrum (II) in the Mohr's salt by classical
methods of analysis can used:
A. All these methods.*
C. Dichromatometry.
D. Bromatometry.
E. Cerimetry
.
60. Which standard solution (titrant) is used in the method of permanganatometry?
A. Potassium permanganate solution.*
B. Ferrum (II) sulfate solution.
C. Sodium oxalate solution.
D. Manganese (II) sulphate solution.
E. Potassium manganate solution.
61. The moisture amount of thermally sensitive preparations can be determined:

A. Nonaqueous titration by Fisher's method. *
B. Bromatometry.
C. Permanganatometry.
D. Nitritometry.
E. Iodometry.
94
62. In most times the quantitative content of primary and secondary aromatic
amines in pharmaceutical drugs determined by the method of:
A. Nitritometry.*
B. Cerimetry.
C. Ascorbinometry.
E. Titanometry.
63. Specify the titrimetric method for the quantitative determination of phenol and
phenol based compounds:
A. Bromatometry.*
B. Cerimetry.
C. Nitritometry.
E. Ascorbinometry.
64. What standard solution can used to standardize the solution of I2?
A. Sodium thiosulfate solution.*
B. Potassium iodide solution.
C. Potassium dichromate solution.
D. Potassium permanganate solution.
E. Sodium nitrite solution.
65. What is the titrimetric method of analysis underlying the quantitative

determination of iodine by sodium thiosulfate solution?
B. Alkalimetry.
C. Acidimetry.
D. Precipitation.
66. Choose one of the pairs of methods for the quantitative determination of oxalic
acid:
A. Acid-base titration, permanganatometry.*
95
B. Acid-base titration, argentometry.
C. Acid-base titration, trilonometry.
D. Permanganatometry, mercurometry.
E. Permanganatometry, mercurimetry.
67. At determining of streptocide (aromatic amine) by nitritometry add a catalyst

to increase of reaction rate. Specify a substance that acts as a catalyst:
A. Potassium bromide.*
B. Hydrochloric acid.
C. Pottassim sulfate.
D. Sulphuric acid.
E. Sodium chloride.
68. Choose the appropriate method for determining the active chlorine in
whitewash:
A.Iodometry.*
B. Permanganatometry through the formation of difficult soluble oxalates.
C. Bromatometry through the 8-hydroxyquinolinates.
D. Dichromatometry.
E. Nitritometry.
69. The quantitative determination of iodine carried out by the method:

A. Redox titration.*
B. Alkalimetry.
C. Complex formation.
D. Acidimetry.
E. Precipitation titration.
70. Quantitative content of oxalic acid determined by the method of

permanganatometric titration. How established the equivalence point in this
method?
A. By changing the color of the titrated solution, when extra drop of the working
solution is added.*
B. With the help of the redox indicator of diphenylamine.
C. With the help of the pH indicator.
96
D. With the help of a specific indicator.
E. With the help of an adsorption indicator.
71. In which of the titrimetric methods of analysis are used external and internal
indicators:
A. Nitritometry.*
B. Alkalimetry.
C. Complexonometry.
E. Argentometry.
72. The bromometric titration used for quantitative determination of streptocide.

Solution of potassium bromate is titrant of this method. It can be prepared as:
A. Primary, so and secondary standard solution.*
B. Only primary standard solution.
C. Only secondary standard solution.
D. Solution with the prepared titer.
E. Solution with the set titer.
73. Specify the type of chemical reaction when sodium thiosulfate titrated by
iodine solution?
B. Acid-base.
C. Nucleophilic substitution.
D. Precipitation.
74. What is the standard solution for iodometric determination of reducing agents
(direct titration)?
A. Solution of I2.*
B. Solution of KMnO4.
C. Solution of Na2S2O3.
D. Solution of K2Cr2O7.
E. Solution of КI.
97
75. Determination of the mass fraction of pharmaceutical drugs containing
aromatic amino group carried out by the method of nitritometry. What external
indicator is used in this case?
A. Eosin.
B. Eriochrome Black T.
C. Methylene red.
D. Iodine-starch paper.*
E. Phenolphthalein.
76. Choose the method for quaquantitative determination of hydrogen peroxide in

the presence of preservation agents:
A. Bromatometry.
B. Dichromatometry.
D. Iodometry.*
E. Cerimetry.
77. At determining of streptocide (aromatic amine) by nitritometry, a catalyst to

increase of reaction rate added. Specify a substance that acts as a catalyst:
А. Hydrochloric acid.
В. Sodium chloride.
С. Pottassim sulfate.
D. Potassium bromide.*
Е. Sulphuric acid.
78. In the titrimetric analysis by oxidation-reduction method, to the reaction

system are added indicators that react to change:
A. Redox system potential.*
B. Concentrations of hydroxyl ions.
C. Ionic force of solution;.
D. Degree of ionization of the test substance.
E. Concentrations of hydrogen ions.
79. 0.05 M solution of sodium thiosulfate was prepared. Specify the standard
substance for standardizing this solution:
98
А. AgNO3.
B. K2Cr2O7.*
C. Na2B4O7 · 10H2O.
D. HCl.
E. H2C2O4.
80. Specify the product of sodium thiosulfate oxidation by iodine:

A. S + H2SO4.
B. S + Na2SO4.
C. Na2S + H2SO4.
D. Na2S4O6.*
E. Na2SO4+H2SO4.
81. Choose the indicator for determining ascorbic acid by iodometric method:
А. Starch.*
В. Methyl orange.
С. Fluorescein.
D. Tropeolin 00.
Е. Diphenylcarbazone.
82. Check the internal indicator to fixation of titration end point by nitritometry:
А. Tropeolin 00.*
В. Phenolphthalein.
С. Without indicator.
D. Potassium chromate.
Е. Eosin.
83. Check the external indicator to fixation of titration end point by nitritometry:
А. Iodine-starch paper.*
В. Lacmus.
С. Methylene blue.
D. Eosin.
Е. Murexide.
99
84. Check the method of the oxidation-reduction titration for the detrmination of
novocaine (primary aromatic amine):
А. Iodometry.
В. Nitritometry. *
С. Permanganatometry.
D. Cerimetry
Е. Dichromatometry.
85. Choose indicators to fixing equivalent point in bromatometry:

А. Phenolphthalein.
В. Self-indicator method.
С. Tropeolin 00.
D. Methyl orange.*
Е. Eosin.
86. Determination of the mass fraction of ascorbic acid by the cerimetry method is
carried out in the presence of a redox indicator:
А. Methyl red.
В. Methyl orange.
С. Fluorescein.
D. Ferroin.*
Е. Eosin.
87. Specify the standard solutions which used in permanganatometry for the
quantitative determination of oxidizing agents by the method of back titration:
А. Cerium (IV) sulfate, ferrum (II) sulfate.
В. Potassium iodate, sodium thiosulfate.
С. Potassium bromate, sodium thiosulfate.
D. Potassium dichromate, sodium thiosulfate.
Е. Potassium permanganate, ferrum (II) sulfate.*
88. At determining the oxidizing and reducing agents in the methods of

redoxmetry, the end point of the titration is fixed:
А. Using the instrumental indication.
В. Using redox indicators.
100
С. All listed ways.*
D. Using specific indicators.
Е. Self-indicator method.
89. One of the redoximetry methods is iodometry. As a titrant of the method of

iodometry use solution of:
А. Cerium sulfate.
B. Sodium hydroxide.
C. Sodium nitrite.
D. Potassium permanganate.
Е. Sodium thiosulfate.*
90. Iodometric method of titration used to determine the content of cupper (II)
sulfate. Titrant of this method is:
А. Potassium hydroxide solution.
B. Solution of iodine in solution of potassium iodide.
C. Potassium periodate solution
D. Sodium thiosulfate solution.*
Е. Potassium permanganate solution.
91. A specialist of the analytical laboratory performs direct iodometric

determination of ascorbic acid. What indicator is used in this case?
А. Starch.*
B. Methyl red.
C. Methyl orange.
D. Diphenilamine.
Е. Phenolphthalein.
92. Quantitative content of hydrogen peroxide can be determined by means of the

following self-indicator method:
А. Argentometry.
B. Bromatometry.
C. Nitritometry.
D. Iodometry.
E. Permanganatometry.*
101
93. Permanganatometry is a titrimetric method for the determination of substances
based on oxidation reactions involving permanganate ions. Which of the following
ate the standard solutions that are used according to this method for the
quantitative determination of oxidants by reverse titration method?
A. Potassium dichromate, sodium thiosulfate
B. Potassium bromate, sodium thiosulfate
C. Cerium (IV) sulfate, iron (II) sulfate
D. Potassium iodate, sodium thiosulfate
E. Potassium permanganate, iron (II) sulfate *
94. Which titrant is used in bromatometric titration?

А. KBrO4 + KCl
В. Br2
С. KBrO3 *
D. KBrO4
Е. KBr
95. In which redox titration method does starch use a specific indicator to fix the
titration endpoint?
А. Nitrite titration
B. Iodometry *
C. Cerimetry
D. Permanganatometry
E. Bromatometry
96. What type of reaction occurs during the determination of ascorbic acid in a
preparation by the iodometric method?
А. Precipitation
B. Redox reaction *
С. Neutralisation
D. Acylation
E. Complexation
102
97. Sulfanilamides contain a primary aromatic amino group in their structure.
What method is used for quantitative determination of these compounds?
A. Iodometry
B. Nitritometry *
C. Dichromatometry
D. Permanganatometry
E. Cerimetry
98. In redox titrimetry, the indicators that are added to the reaction system
respond to the changes in the:
A. Ionic strength of the solution
B. Concentration of hydroxyl ions
C. Redox potential of the system *
D. Degree of ionization of the substance being analyzed
E. Concentration of hydrogen ions
103
Precipitating titration
1. Quantitative determination of halogenide-ions by precipitation titration by the

Folgard's method carry out in acidic media. What acid used in this case?
А. Nitric acid.*
В. Hydrochloric acid.
С. Sulphuric acid.
D. Acetic acid.
Е. Nitrous acid.
2. In what case the titration drastic change will be the biggest if silver nitrate
solution is titrated by 0.1 М soluions of potassium iodide, potassium bromide,
potassium chloride, potassium thiocyanate, potassium oxalate (Кs AgI =8,3⋅10-17, Кs
-13 -10 -12 -11
AgBr = 5,3⋅10 , Кs AgCl = 1,78⋅10 , Кs AgSCN = 1,1⋅10 , Кs Ag2C2O4 = 3,5⋅10 )?
А. Potassium chloride.
В. Potassium bromide.
С. Potassium oxalate.
D. Potassium thiocyanate.
Е. Potassium iodide.*
3. Potassium iodide determined by Fajans method. What indicator used for

fixation of the end point of titration?
А. Eosin.*
В. Tropeolin-00.
С. Potassium chromate.
Д. Methyl orange.
Е. Phenolphthalein.
4. Sample solutions contain sodium chloride and one of salts such as below. In
what case determination of chlorides by Mohr's method possible?
А. Na3PO4.
B. Na2C2O4.
C. Na3AsO4.
D. Na2CO3.
E. NaCH3COO.*
104
5. At the titrimetric determination of the substance into the reaction system added
indicators. At mercurimetric titration as an indicator used:
А. Mohr's salt.
В. Eriochrome Black T.
С. Diphenylcarbazide.*
Е. Starch.
6. To 10.20 dm3 0,1000 mol/dm3 of sodium chloride solution added 10.20 dm 3

0,1000 mol/dm3 of silver nitrate solution in presence of potassium chromate. What
color does the precipitate get?
А. Black.
В. Pale yellow.
С. Precipitate remain white.*
D. Reddish brown.
Е. Red.
7. The potassium iodide solution is titrated by standard solution of silver nitrate

(direct titration) using as an indicator:
А. Sodium arsenate.
В. Ammonium iron alum.
С. Potassium chromate.
D. Fluoresceine.*
Е. Potassium iodide.
8. The method of mercurimetry used at determining of chlorides in drinking water.

As a titrant used a solution of:
A. Hg2(NO3)2.
B. HgCl2.
C. Hg(NO3)2.*
D. Hg2Cl2.
E. HgSO4.
105
9. A secondary standard solution of potassium thiocyanate used in the
thiocyanatometry method. It standardized by a standard solution of:
A. Sulphuric acid.
B. Silver nitrate.*
C. Cupper (II) nitrate.
D. Ferum (II) sulfate.
E. Hydrochloric acid.
10. What is the primary standard used to standardize the solution of Hg2(NO3)2?
A. Sodium chloride.*
B. Sodium sulfate.
C. Sodium bromide.
D. Sodium dichromate.
11. Chemist-analyst must determine quantitative content of hydrochloride acid in

the mixture containing nitric acid. What titration method of analysis he can use:
A. Argentometry.*
B. Iodometry.
C. Complexonometry.
D. Acid-base titration.
E. Permanganatometry.
12. Investigated drug contains potassium nitrate and potassium chloride. Propose
the method for quantitative determination of potassium chloride:
A. Argentometry.*
B. Nitritometry.
D. Iodometry.
E. Iodochlorometry.
13. The chemist-analyst applied the Mohr's method to determine the mass fraction
of sodium chloride in a physiological solution. The titrant of this method is:
A. Silver nitrate.*
B. Ammonium thiocyanate.
106
C. Sodium tetraborate.
D. Mercuric (I) nitrate.
E. Mercuric (II) nitrate.
14. To determine the mass fraction of chloride ions in the sample of the kitchen
salt, the solution was prepared and titrated by argentum nitrate solution in the
presence of the potassium chromate indicator. Which method of analysis has been
applied:
A. Mohr's method.*
B. Volhard's method.
C. Fajans method.
D. Mercurometric titration.
E. Trilonometry.
15. Choose the indicator for argentometric determination of chloride ions by the
Mohr's method.
A. Potassium chromate.*
B. Diphenylcarbazone.
C. Eosin.
D. Fluorescein.
E. Methyl red.
16. The Fayans-Khodakov method used to determine the mass fraction of sodium
chloride in the medicinal product. Titration carried out in the presence of the
indicator solution of:
A. Fluorescein.*
B. Methyl red.
C. Potassium chromate.
D. Ammonium ferrum (III) sulfate.
E. Phenolphthalein.
17. The method of mercurometry used for the quantitative determination of

potassium chloride in the preparation. How the indicator applied:
A. Diphenylcarbazone.*
B. Methyl red.
107
C. Phenolphthalein.
D. Fluorescein.
E. Feroin.
18. The method of mercurometry used at the determination of chlorides in water.

As a titrant used the solution of:
A. Hg(NO3)2.
B. Hg2(NO3)2.*
C. HgCl2.
D. HgSO4.
E. Hg2Cl2.
19. For gravimetric determination of sulfate ions as a precipitant used a solution

of:
A. Barium chloride.*
B. Magnesium chloride.
C. Zinc chloride.
D. Silver nitrate.
E. Ferum (II) chloride.
20. The potassium iodide solution is titrated with standard solution of silver nitrate
(direct titration) using as an indicator:
A. Fluorescein.*
B. Methyl orange.
C. Ferrous ammonium sulfate.
D. Starch solution.
E. Tropeolin 00.
21. In the process of titrimetric determination of substances by the method of

mercurometric titration as an indicator can used:
A. Diphenylcarbazide.*
C. Eriochrome Black T.
D. Starch.
E. Tropeolin 00.
108
22. At the argentometric determination of a drug containing KBr by the Mohr’s
method as indicator used:
A. Potassium chromate. *
B. Ferum (III) thiocyanate.
C. Fluorescein.
D. Murexid.
E. Tropeolin 00.
23. To standardize the solution of silver (I) nitrate titrant in the Mohr’s method
used a solution of:
B. Sodium carbonate.
E. Sodium oxalate.
24. Determination of halogenide-ions by the Folgard method should carried out:

A. In nitric acid medium.*
B. In acetic acid medium.
C. In neutral medium.
D. In weak-base medium.
E. In alkaline medium.
25. The analyzed mixture contains the ions Cl -, Br- and I- in equimolar amounts.
The sequence of precipitate formation under argentometric titration will be
determined by:
A. The solubility product of the corresponding silver halide.*
B. The value of redox potentials.
C. The choice of a method of titration - direct or back.
D. The value of anions mobility.
E. The ionic strength of solution.
26. What is the primary standard used to standardize the solution of Hg2(NO3)2:
109
B. Sodium bromide.
C. Sodium sulfate.
E. Sodium dichromate.
27. At determining the sodium chloride by Folgard method used:

A. Back titration, argentometry.*
B. Direct titration, argento.
C. Substitution titration.
D. Back titration, mercurimetry.
E. Direct titration, mercurimetry.
28. Choose the adsorption indicator:

A. Eosin.*
B. Phenolphthalein.
C. Sulphosalicylic acid.
D. Methylorang.
E. Eriochrome black T.
29. Determination of sodium and potassium chloride in medical preparations

carried out by the method:
A. Argentometry, Mohr’s method.*
B. Redox-titration.
C. Alkalimetry.
D. Acidimetry.
E. Complexonometry.
30. Iron-ammonium halons used as indicators:

A. In argentometry, Folgard method.*
B. In argentometry, Mohr’s method.
C. In alkalimetry.
D. In acidimetry.
E. In complexonometry.
31. What indicator used in the Fayans-Khodakov method at determining sodium
110
iodide?
A. Eosin.*
B. Methylorang.
E. Iron-ammonium halons.
32. What working solutions (titrant) used in the method of precipitation titration –
in the Folgard method?
A. AgNO3 and NH4SCN.*
B. H2SO4 and NaOH.
C. Na2S2O3 and K[I3].
D. KMnO4 and KBrO3.
E. HClO4 and KOH.
33. Specify an analysis for determination the total content of CaCl 2 and NaBr in
the solution:
A. Argentometry.*
B. Acidimetry.
C. Complexonometry.
E. Alkalimetry.
34. Specify the conditions necessary for the formation of crystalline precipitates:
A. Slow precipitation from hot diluted solutions.*
B. Rapid precipitation from hot dilute solutions.
C. Slow precipitation from cold dilute solutions.
D. Rapid precipitation from cold dilute solutions.
E. Slow precipitation from cold concentrated solutions.
35. Specify the conditions necessary for the formation of amorphous precipitates:
A. Rapid precipitation from hot concentrated solutions.*
B. Slow precipitation from hot concentrated solutions.
C. Slow precipitation from cold concentrated solutions.
D. Rapid precipitation from cold concentrated solutions.
E. Rapid precipitation from hot dilute solutions.
111
36. Specify the method based on the reactions of precipitation of
halogenides in the form of insoluble mercury salts (I).
A. Mercurometry.*
B. Argentometry.
C. Rhodanometry.
D. Mercurimetry.
E. Trilonometry.
37. Specify the analytical effect which observed when fixing the end point of
titration in the Folgard method:
A. Colour stain of solution in red.*
B. Formation of a red precipitation.
C. Colour stain of solution in yellow.
D. Formation of a brown precipitation.
E. Formation of a yellow precipitation.
38. In determining the silver content by the precipitation titrimetric method used
method of:
A. Folgard.*
B. Mohr’s.
C. Gay Lussac.
D. Fayans-Khodakov.
E. Nessler.
39. In determining the quantitative content of sodium chloride in injectable

solutions using the method of:
A. Argentometry.*
B. Complexonometry.
C. Iodometry.
D. Cerimetry.
E. Acid-base titration.
40. To determine the mass fraction of silver nitrate in the medicinal product used
the Folgard direct titration. Titration carried out in the presence of the indicator
112
solution of:
A. Ammonium ferrous (III) sulfate.*
C. Fluorescein.
D. Diphenylcarbazone.
E. Eosin.
41. To determine the mass fraction of sodium chloride in the physiological

solution using the Mohr’s method. Titration carried out in the presence of the
B. Fluorescein.
C. Ammonium ferrous (III) sulfate.
E. Ferroin.
42. Halide ions in medicinal preparations determined by the titration method,

which based on the reaction of:
A. Precipitation.*
C. Substitution.
D. Acid-base.
43. Specify the analytical effect that observed when fixing the end point of
titration in the Mohr’s method?
A. The formation of brick-red color precipitation.*
B. Coloring the solution in red.
C. Coloring the solution in yellow.
D. The formation of white color precipitation.
E. The formation of yellow color precipitation.
44. Specialist used the Mohr’s method for the quantitative determination of
chloride ions in the drug. The end point of titration was fixed by the formation of a
brick-red precipitate formed by such a compound of:
113
А. Potassium dichromate.
В. Potassium chromate.
С. Potassium chloride.
D. Silver chromate.*
Е. Silver chloride.
45. The Folgard direct titration used to determine the mass fraction of silver
nitrate in the medicinal product. Titration carried out in the presence of the
А. Iron ammonium alum (ammonium ferrum (III) sulfate). *
В. Fluorescein.
С. Eosin.
Е. Diphenylcarbazone.
46. A 0.1 M solution of silver nitrate was prepared. Specify the standard substance
for standardizing this solution:
А. Sodium tetraborate.
В. Potassium chloride.*
С. Sodium benzoate.
D. Oxalic acid.
Е. Sodium hydroxide.
47. In the preparation of mercurimetry titrant - a mercury (II) solution - to

suppress its hydrolysis, add such an acid:
А. Hydrochloride.
В. Sulfate.
С. Phosphate.
D. Acetate.
Е. Nitric.*
48. What reaction used in argentometric titration?

А. Precipitation.*
В. Complex formation.
С. Oxidation.
114
D. Neutralization.
Е. Reduction.
49. Specify the substance that used as the primary standard for standardization of
titrated silver nitrate solution in argentometry:
А. Potassium dichromate.
В. Sodium chloride.*
С. Ferum (II) sulfate.
D. Oxalic acid.
Е. Sodium carbonate.
50. Fix the end point of the titration in the Folgard method carried out with the
help of:
А. рН-indicators.
В. Adsorption indicators.
С. Metallochrome indicators.*
D. Self-indicatore titration.
Е. Redox indicators.
51. Potassium chromate is a precipitation indicator and is used to fix the end point
of titration in the method of:
А. Complexonometry.
В. Argentometry.*
С. Cerimetry.
Е. Iodomerty.
52. What anions can be determined by the Mohr’s method?

А. Formate nitrite.
B. Nitrate and acetate.
C. Chloride and bromide.*
D. Iodide and thiocyanate.
E. Chromate and manganate.
115
53. The Fajans-Khodakov method is used to determine the mass fraction of
sodium chloride (NaCl) in a drug. What indicator is used in the titration by this
method?
А. Phenolphthalein
B. Methyl red
С. Ferric ammonium (III) phosphate
D. Fluorescein *
E. Potassium chromate
54. What standard solution is used to standardise the secondary solution of

potassium thiocyanate used in the thiocyanatometric method?
А. Copper (II) nitrate
B. Sulfuric acid
С. Hydrochloric acid
D. Argentum nitrate *
E. Ferric (II) sulphate
55. Which indicator is used in the titrimetric determination of substances by the

mercurimetric titration method?
А. Potassium chromate
B. Diphenylcarbazide *
С. Eryochrome black T
D. Starch
E. Tropeolin 00
56. The Mohr method was used for the quantitative determination of chloride ions
in the drug product. The end point of the titration was recorded by the formation
of a brick red precipitate. What compound was it formed by?
А. Potassium dichromate
B. Potassium chloride
С. Potassium chromate
D. Silver chloride
E. Silver chromate *
116
57. What is the name of the method of quantitative analysis based on the reactions
of formation of complex compounds of halide ions with Hg2+ salts?
А. Alkalimetry
B. Mercurimetry *
С. Acidimetry
D. Argentometry
E. Complexometry
117
Compleximetric titration
1. What cations can be determined by trilonometry in acid medium?

A. Ni2+.
B. Mg2+.
C. Fe3+.*
D. Al3+.
E. Cu2+.
2. What method of analysis should be chosen for determination of total hardness

of running water?
А. Acidimetric.
В. Nitritometric.
С. Trilonometric.*
D. Argentometric.
Е. Iodimetric.
3. Disodium salt of ethylenediaminotetraacetic acid solution (trilon B) is used for

trilonometric determination of many inorganic drugs containing metals that forms
stable chelates with metal cations. To what kind of ligands trilon B is belong?
А. Polydentate.*
В. Monodentate.
С. Didentate.
D. Bidentate.
Е. Tridentate.
4. What reactions underlie of trilonometric determination of the total water

hardness?
А. Hydrolysis.
В. Oxidation-reduction.
С. Acid-base interaction.
D Complex formation.*
Е. Precipitate.
118
5. Magnesium sulphate content in the medicinal drugs determined by
complexometric method. Choose the indicator for fixation of the end point of
titration?
А. Chromogen black.*
В. Methyl orange.
С. Diphenylcarbazone.
D. Phenolphthalein.
Е. Eosin
6. One molecule of trilon B interreacts with only one metal ion (regardless of
metal valency) in the method of trilonometry. Determine the equivalent factor f of
the salts at determining them by this method:
A. f=1.*
B. f=1/3.
C. f = 1/5.
D. f=2.
E. f=1/2.
7. What substance solution used as a titrant in the method of complexometry?

А. Sulphuric acid.
В. Trilon B.*
С. Argentum (I) nitrate.
D. Potassium dichromate.
Е. Sodium thiosulfate.
8. The total hardness of water determined by direct titration with the standard
solution of trilon B in the presence of indicator:
А. Sodium nitroprusside solution.
В. Fluorescein.
С. Diphenylcarbazone.
D. Eriochrome Black T.*
Е. Potassium chromate.
9. Quantitative content of calcium chloride determined by the method of direct

trilonometry. Choose the indicator for fixation of the end point of titration:
119
A. Phenolphthalein.
B. Methyl red.
C. Eriochrome Black T.*
D. Eosin.
E. Starch.
10. By the method of direct complexometry determined the concentration of:

A. Metal cations.*
B. Anions of strong acids.
C. Anions of weak acids.
D. Hydroxide ions.
E. Hydrogen-ions.
11. The quantitative content of calcium chloride in the pharmaceutical preparation

determined by direct complexometric titration. Choose the indicator to fixation of
the end point of the titration:
A. Eriochrome Black T.*
B. Starch.
C. Fluorescein.
E. Eosin.
12. What method of analysis can be used to determine the aluminium content in
the alumag (maalox) drug by the method of indirect titration?
A. Complexonometry.*
B. Dichromatometry.
C. Argentometry.
D. Mercurometry.
E. Iodometry.
13. To standardize the titrated solution of trilon B used a standard solution of:
A. Zinc sulfate.*
C. Sodium chloride.
D. Potassium dichromate.
120
E. Oxalic acid.
14. For the quantitative determination of magnesium sulfate in solution can used
the method of:
B. Nitritometry.
C. Argentometry.
D. Thiocyanatometry.
E. Acidimetry.
15. The titrant of the complexonometry method - the solution of trilon B - forms
with cations of metals, regardless of their valency, complex compounds in the
molar ratio:
A. 1:1.*
B. 1:3.
C. 1:2.
D. 2:1.
E. 3:1.
16. Choose the titrimetric method for quantitative determination of magnesium

sulfate in a solution for injection:
B. Cerimetry.
C. Acid-base titration.
D. Iodochlorometry.
E. Nitritometry.
17. The precipitation carried out with a solution of barium chloride at the
gravimetric determination of the mass fraction of sulfate ions in the magnesium
sulfate drug. A precipitated form of barium sulfate should washed out:
A. Dilute solution of sulfate acid.*
B. Distilled water.
C. Barium chloride solution.
D. Sodium sulfate solution.
E. Hydrochloride acid solution.
121
18. Trilonometric titration used for the determination of drugs containing
magnesium and calcium cations. Specify type of chemical reaction in this case:
A. Complex formation.*
D. Alkylation.
E. Precipitation.
19. Solution of trilon B was prepared. Specify the standard substance for
standardizing this solution:
A. Metal zinc.*
C. Sodium hydroxide.
D. Oxalic acid.
E. Potassium dichromate.
20. A solution, which contains potassium chloride and magnesium chloride taken
for the study. What titrimetric method can used for determine the amount of
magnesium chloride in the mixture?
A. Method of complexonometry.*
B. Method of argentometry.
C. Method of mercurometry.
D. Method of permanganatometry.
E. Method of iodometry.
21. The laboratory assistant uses the erichrom black T indicator for determining
the total hardness of the water. Specify which method used to determine:
B. Argentometry.
D. Bromatometry.
E. Chromatometry.
22. For the quantitative determination of medicinal preparations, containing
122
alkaline earth and heavy metals used the method of:
C. Acidimetry.
D. Mercurometry.
E. Alkalimetry
23. Quantitative determination of bismuth in the drug carried out by the method
of:
B. Iodometry.
C. Mercurimetry.
E. Argentometry.
24. The method of direct complexonometry used for determination of the

concentration of:
А. Metal cations.*
В. Anions of strong acids.
С. Anions of weak acids.
D. Hydroxide ions.
Е. Hydrogen-ions.
25. The content of magnesium sulfate in the drug determined by the method of
complexonometric titration. Suggest the indicator to fixation the end point of the
titration:
A. Chromogen black.*
B. Phenolphthalein.
C. Methyl orange.
E. Eosin.
26. Specify the type of chemical reaction in the titrimetric determination of the
total hardness of water:
A. Complex formation.*
123
B. Acid-base.
D. Precipitation.
E. Oxidation-reduction.
27. Zinc sulfate solution taken for analysis. Propose a titrimetric method for
quantitative determination of ZnSO4 in solution:
A. Mercurometry.
B. Complexonometry.*
C. Argentometry.
D. Iodometry.
E. Permanganatometry.
28. The method of direct complexonometry used for determination of the

concentration of:
A. Metal cations.*
B. Anions of strong acids.
C. Anions of weak acids.
D. Hydroxide ions.
E. Hydrogen-ions.
29. What buffer solution is used to determine the total hardness of water by the
complexonometric method:
А. Ammoniac.*
В. Phthalate.
С. Сarbonated.
D. Phosphate.
Е. Formate.
30. Indicate the primary standard that used to standardize the trilon B solution in
the method of complexonometric titration:
А. Magnesium sulfate.*
В. Potassium dichromate.
С. Salicylic acid.
D. Oxalic acid.
Е. Sodium carbonate.
124
31. Standardization of the titrated solution of trilon B is carried out with metal
zinc. What indicator used in this case?
А. Iron ammonium alum.
В. Xylenol orange.*
С. Methyl red.
D. Phenolphthalein.
Е. Methyl orange.
32. A solution containing cations of calcium and magnesium is titrated with a

solution of trilon B. In what medium is the complexometric titration of these
cations carried out?
А. In a neutral medium.
В. In an ammonium buffer solution.*
С. In an acetate buffer solution.
D. In a formate buffer solution.
Е. In acid medium.
33. To determining calcium cations with a murexide indicator (for pH> 12) add
compound of:
В. Urotropin.
С. Acetate buffer solution.
Е. Ammonium buffer solution.*
34. In the laboratories of different profiles, for determination the total hardness of
drinking water used the method of:
А. Acidimetry.
B. Oxidimetry.
С. Alkalimetry.
D. Complexonometry.*
Е. Precipitation.
35. Determine the concentration by indirect complexometry:
125
А. Hydrogen ions
B. Anions of weak acids
С. Hydroxide ions
D. Strong acid anions
E. Metal cations *
36. What method should be used for the quantitative determination of magnesium
sulfate in solution?
A. Acidimetry
B. Nitritometry
C. Thiocyanometry
D. Argentometry
E. Complexonometry *
37. Complexometric determination of the total hardness of water is carried out

with metallochromic indicators. What indicator can be used in this case?
A. Eriochrome black T *
B. Phenolphthalein
S. Potassium chromate
D. Methyl red
E. Fluorescein
126
Gravimetry
1. Calcium content in salts determined by gravimetric method. It precipitated in

the form of calcium oxalate. The precipitate washed, dried and calcined, which
causes it to become calcium oxide. What reagent used for precipitate of calcium
ions?
А. Sodium oxalate.
В. Potassium oxalate.
С. Magnesium oxalate.
D. Lithium oxalate.
Е. Ammonium oxalate.*
2. The gravimetric determination of moisture in pharmaceutical preparations

carried out by the method:
А. Indirect sublimation.*
В. Precipitation.
С. Selection.
D. Direct sublimation.
Е. Selection and indirect sublimation.
3. The gravimetric determination of carbonate ions in the contaminated

preparation carried out by the method:
А. Direct sublimation.*
В. Precipitation.
С. Indirect sublimation.
D. Selection.
Е. Selection and indirect sublimation.
4. A gravimetric method used to determine the mass fraction of aluminium in the

medicinal product. Solution of ammonium hydroxide used as a precipitant. The
gravimetric form in this case is:
A. Aluminium oxide.*
B. Aluminium hydroxide.
C. Ammonium chloride.
D. Ammonium nitrate.
127
E. Aluminium carbonate.
5. The gravimetric determination of moisture in pharmaceutical preparations is

carried out by the method::
A. Indirect sublimation.*
B. Selection.
C. Precipitation.
E. Selection and indirect sublimation.
6. The analysis of sodium sulfate crystallohydrate performed gravimetrically by

precipitating the sulfate ions with a solution of barium chloride. After maturation
the barium sulfate precipitate washed by decantation using as a washing liquid:
A. Dilute solution of sulfate acid.*
B. Distilled water.
C. Barium chloride solution.
D. Sodium sulfate solution.
E. Ammonium sulfate solution.
7. A gravimetric method used to determine the mass fraction of calcium in the

drug. Solution of ammonium oxalate used as a precipitant. The gravimetric form
in this case is:
A. Calcium oxide.*
B. Anhydrous calcium oxalate.
C. Monohydrate of calcium oxalate.
D. Calcium carbonate.
E. Calcium hydroxide.
8. Choose the precipitator for gravimetric determination of calcium salts:

A. (NH4)2C2O4.*
B. K2C2O4.
C. Na2C2O4.
D. Na2CO3.
E. K2CO3
128
9. The gravimetric determination of moisture in the pharmaceutical preparations
carried out by the method of:
А. Selection and indirect sublimation.
В. Direct sublimation.
С. Precipitation.
D. Selection.
Е. Indirect sublimation.*
10. A gravimetric deposition method used to determine the mass fraction of

barium ions in the drug. The gravimetric form in this case is:
А. Barium sulfite.
В. Barium sulfide.
С. Barium oxide.
D. Barium sulfate.*
Е. Barium hydroxide.
11. The gravimetric determination of moisture in the pharmaceutical preparations

carried out by the method of:
A. Indirect sublimation.*
B. Selection and indirect sublimation.
C. Selection.
E. Precipitation.
12. The mass fraction of sulfate ions in magnesium sulfate determined by

gravimetric method. Deposition carried out by:
А. BaCl2.*
B. AgNO3.
C. ZnCl2.
D. HCl.
E. CuBr2.
13. Gravimetric deposition method used to determine the magnesium content.

Choose precipitated and gravimetric forms:
А. MgNH4PO4, Mg2P2O7.*
129
B. MgNH4PO4, MgO.
C. Mg(OH)2, Mg2P2O7.
D. MgNH4PO4, Mg(OH)2.
E. Mg(OH)2, MgO.
14. The gravimetric method was used to determine the mass fraction of aluminium
in the drug product. Ammonium hydroxide solution was used as a precipitant.
Determine which compound is the gravimetric form.
А. Aluminium hydroxide
B. Ammonium sodium
С. Ammonium chloride
D. Aluminium carbonate
E. Aluminium oxide *
130
INSTRUMENTAL METHODS OF ANALYSIS
131
Optical analysis methods
1. The photoelectrocolorimetric method of analysis allows for determination the

concentration of:
A. Color solution.*
B. Cloudy solution.
C. Optically active substance.
D. Water-white solution.
E. Any solution.
2. The Bouguer-Lambert-Beer's law is a basic of molecular absorption analysis.

According to this law the optical density of the solution is:
A. Directly proportional to the optical path length and concentration of the
substance.*
B. Directly proportional to the optical path length and absorbance.
C. Inversely proportional to the optical path length and concentration of the
substance.
D. Directly proportional to the concentration and inversely proportional to the
optical path length.
E. Directly proportional to the concentration and inversely proportional to
absorbance.
3. Potassium dichromate solution taken for analysis. Which of the physico-

chemical methods of analysis used by a chemist to determine its concentration:
A. Spectrophotometric.*
B. Fluorimetric.
C. Polarimetric.
D. Coulonometric.
E. Conductometric titration.
4. Refractometric method of analysis used for identification of medicinal drug.

Refractometric method of analysis based on the relationship between:
A. Refraction index and concentration of substance in the solution.*
B. Electrical conductance of solution and this concentration.
C. Concentration of substance in the solution and these angles of rotation.
132
D. Concentration of substance in the solution and these optical densities.
E. Intensity of light absorption by solution and this concentration.
5. The quantitative determination of copper salts by photometric method carried

out according to calibration graph, which are drawed in coordinates:
A. Optical density - concentration.*
B. Optical density - temperature.
C. Optical density - optical path length.
D. Intensity of light absorption - wavelength.
E. Optical density - wavelength.
6. Choose the reagent for detection and photometric determination of Fe (II) and
Fe (III) cations:
A. Sulphosalicylic acid.*
B. Oxalic acid
C. Aminobenzoic acid
D. Phenylacetic acid.
E. Chloracetic acid.
7. For quantitative determination of glucose by polarimetric method measure:

A. Angle of rotation of polarized light beam.*
B. Index of light refraction.
C. Absorption index of polarized light beam by solution.
D. Dispersion of light beam by solution.
E. Optical density of solution.
8. Concentration of ethanol in some drugs and tinctures determined by

refractometric methods. For this purpose determined:
A. Index of solution refraction.*
B. Angle of rotation of polarized light plane.
C. Angle of total internal reflection of light beam.
D. Angle of light beam incidence.
E. Angle of light beam refraction.
9. The molar absorption coefficient is the optical density of the solution at the
133
optical path length of 1 cm and the concentration is equal to:
A. 1 mol/l.*
B. 0,1 mol/l.
C. 1%.
D. 1g/ml.
E. 1 g/l.
10. One of the most common instrumental methods of analysis is photometry,

based on measurement:
A. Optical density.*
B. Index of refraction.
C. Angle of rotation.
D. Wavelength.
E. Intensity of fluorescence.
11. Angle of rotation of polarization plane of optically active organic substances is

determined by:
A. Polarimeter.*
B. Refractometer.
C. Conductometer.
D. Spectrophotometer.
E. Potentiometer.
12. Sensibility of photometric reactions determined by value of molar light

absorbtion index that depend from:
A. Type of substance.*
B. Concentration of solution.
C. Density of solution.
D. Value of absorbtion layer.
E. Intensity of impinging light.
13. For determining the degree of purity of glucose solutions by polarimetric

method, calculate the value of:
A. Angle of specific rotation of polarization plane.*
B. Angle of rotation of polarization plane.
134
C. Absolute refraction index.
D. Relative refraction index.
E. Specific index of light absorbtion.
14. Results of determination of solutions concentration by refractometric method

of analysis is possible to determine if value of such quantities known:
A. n, n0, F.*
B. n, F.
C. n, n0.
D. n0, F.
E. n.
15. The concentration of ethanol in pharmaceutical practice determined by the

method of:
A. Refractometry.*
B. Iodometry.
C. Polarimetry.
D. Photometry.
E. Alkalimetry.
16. For the choice of analytical wavelength in the method of photometry, create
plot of dependence:
A. Optical density (A) from wavelength (lambda). *
B. Optical density (A) from concentration of solution (С).
C. Optical density (A) from temperature (t0) .
D. Wavelength (lambda) from temperature (t0).
E. Wavelength (lambda) from concentration (С).
17. The concentration of potassium permanganate in solution determined by

photometric analysis. What value measure in this case?
B. Angle of rotation of polarization plane.
C. Refraction index.
D. Half-wave potential.
E. Indicator electrode potential.
135
18. For simultaneous elimination of the influence of foreign substances,
concentration and concentration determination used:
A. Extraction-photometric method.*
B. Differential spectrophotometry.
C. Polarimetry.
D. Fluorimetry.
E. Refractometry.
19. Analysis of copper salts carried out by photometric method. Quantitative

content determined by the calibration graph:
А. Optical density as a function of concentration.*
B. Optical density as a function of path length.
C. Optical density as a function of wavelength.
D. Intensity of light absorption as a function of wavelength.
E. Intensity of light absorption as a function of path length.
20. Specify the method that based on measuring the angle of rotation of the plane
of polarization of the polarized light by the solution of the optically active
substance:
A. Polarimetry.*
B. Refractometry.
C. Interferometry.
D. Photocolorimetry.
E. Spectrophotometry.
21. Refractometric method of analysis is based on:

A. Measurement of refraction index of the analyzed substance.*
B. Measurement of the plane of rotation of a plane of a polarized light beam
passing through an optically active substance.
C. Measurement of the ratio of the speed of light propagation in the solution to the
light vacuum velocity.
D. Measurement of optical activity of a substance.
E. Measurement of the ratio of the speed of light propagation in the solution to the
speed of light propagation in the air.
136
22. For photocolorimetric determination of the mass fraction of potassium
dichromate, a graded graph constructed in coordinates:
A. Optical density - concentration.*
B. Refraction index - concentration.
C. Fluorescence intensity - concentration.
D. The angle of rotation of the polarization plane - concentration.
E. The intensity of the incident light - concentration.
23. What is the physico-chemical method of analysis can used for the quantitative
determination of potassium permanganate solution?
A. Photometry.*
B. Polarimetry.
C. Fluorimetry.
D. Turbidimetry.
E. Nephelometry.
24. The photometric reaction with sulphosalicylic acid conducted for quantitative
determination of Fe3+-ions. What value measure in this case:
B. Specific rotation.
C. Refraction index.
D. Wavelength.
E. Potential half-wave.
25. In the photometric analysis, a series of 6-8 standard solutions prepared for:
A. Construction of calibration graph.*
B. Estimates of the method of determination.
C. Simplification of the method of determination.
D. Choose cuvet.
E. Choose a light filter.
26. Absorption of light obeys the law:

A. Bouguer-Lambert-Beer.*
B. Nernst.
137
C. Geirovsky-Ilkovich.
D. Langmuir.
E. Mendeleyev-Clapeyron.
27. In methods of atomic absorption spectroscopy are used:

A. Monochromatic radiation.*
B. Polychromatic radiation.
C. Reflected light.
D. Refracted beam of light.
E. Diffuse radiation.
28. Nephelometry and turbidimetry are used to analyze a drug substance if it is in

the form of:
A. Suspensions.*
B. Colored solution.
C. Colorless solution.
D. True solution.
E. Colloidal solution.
29. The photoelectrocolorimetric method of analysis allows determining the

concentration of:
A. Colored solution.*
B. Muddy solution.
C. Optically active substance.
D. Colorless solution.
E. Any solution.
30. Potassium dichromate solution taken for analysis. One of the physico-chemical
methods of analysis used for its quantitative determination:
A. Spectrophotometric.*
B. Fluorometric.
C. Polarimetric.
D. Coulometric.
E. Turbidimetric.
138
31. One of the common instrumental methods of analysis is photometry that based
on measurement of:
B. Refraction index.
C. Angle of rotation.
D. Wavelengths.
E. Fluorescence intensity.
32. The angle of rotation of the plane of polarization of optically active organic
substances measured with the help of:
A. Polarimeter.*
B. Refractometer.
C. Conductometer.
D. Spectrophotometer.
E. Potentiometer.
33. A specific characteristic of substances - the light absorption curve used for the
identification of substances in a quantitative analysis. The light absorption curve is
a graphical dependence:
А. Optical density of the solution from the wavelength of incident light.*
B. Optical density of the solution from the concentration of the colored substance.
C. The intensity color of the solution from the thickness of the absorbing layer.
D. Optical density from the thickness of the absorbing layer.
E. The intensity of the light flux coming from the solution from the thickness of
the absorbing layer.
34. Absorption optical methods of analysis based on usage:

A. Combined light absorption law of Bouguer-Lambert-Beer.*
B. Hess's law.
C. Faraday's law.
D. Kohlrausch's law.
E. Law of Lomel-Stokes.
35. Specify which solution can be photocolorimetric determine by self-absorption:

139
B. Potassium chloride.
C. Potassium sulfate.
D. Potassium nitrate.
E. Potassium phosphate.
36. Physico-chemical methods used for the quantitative determination of

medicinal substances. Which of the following methods based on determining the
optical density of the solution?
A. Potentiometry.
B. Polarography.
C. Spectrophotometry.*
D. Electrogravimetry.
E. Coulometry.
37. Specify which solution can be photocolorimetric determine by self-absorption:

A. Potassium phosphate.
B. Potassium sulfate.
C. Potassium nitrate.
D. Potassium chromate.*
E. Potassium chloride.
38. The mixture of glucose and potassium bromide solution taken for analysis.
The concentration of glucose necessary to determine. Which of the physico-
chemical methods should be used?
А. Potentiometric.
В. Polarimetric.*
С. Amperometric.
D. Fluorimetric.
Е. Conductometric.
39. The quantitative content of ascorbic acid in solution as an optically active

substance can determined by the method of polarimetry. What value measured in
this method?
А. Refraction index.
В. Fluorescence intensity.
140
С. Electromotive force.
D. Potential halfwave.
Е. Rotation angle.*
40. Specify the optimal express method for the quantitative determination of 20%
MgSO4 solution:
А. Polarimetry.
В. Photometry.
С. Polarography.
Д. Conductometry.
Е. Refractometry.*
41. An important analytical characteristic of a substance is its spectrum of

absorption in the ultraviolet (UV) region of the spectrum. The appearance of the
spectrum of absorption of a substance in the UV region of the spectrum is due to
of:
А. The atoms ionization of substance.
В. The rotational motion of a molecule in space.
С. Electronic transitions in a substance molecule.*
D. Moving motions of atoms that formed a covalent bond.
Е. Conformational transformations of a molecule.
42. It is known that the test solution contains about 10 -6 mol/l of potassium ions.
What optical method can used to determine the exact concentration of potassium
ions?
А. Fire emission photometry.*
В. Refractometry.
С. Photocolorimetry.
D. Fluorimetry.
Е. Polarimetry.
43. The polarimetric method of analysis used to determine the degree of purity of
glucose and ascorbic acid. Polarimetric method of analysis based on:
А. Measurement of the angle of rotation of the polarized plane of polarized light
passing through an optically active substance.*
141
В. Measurement of optical activity of a substance.
С. Measurement of the ratio of the speed of light propagation in the solution to the
speed of light propagation in the air.
D. Measurement of the ratio of the velocity of light propagation in the solution to
the velocity of light propagation in a vacuum.
Е. Measurement of the index of refraction of the analyzed substance.
44. The light absorption curve build for the choice of the analytical wavelength in
photometric measurements. The light absorption curve is:
А. Graph of the dependence of the optical density of the solution on the
wavelength of the incident light.*
В. Graph of the dependence of the optical density of the solution on the
concentration of the colored solution.
С. Graph of the dependence of the intensity of the light flux on the thickness of
the absorbing layer.
D. Graph of the dependence of the optical density of the solution on the thickness
of the absorbing layer.
Е. Graph of the dependence of the optical density of the solution on the
concentration of the solution.
45. For quantitative determination of glucose by polarimetric method measured:

А. The plane of rotation of the polarized beam of light.*
В. Dispersion of light beam solution.
С. Refractive index of light.
D. Degree of absorption by a solution of a polarized light beam.
Е. Optical density of the solution.
46. For choosing a compound for photometric determination, the advantage given
by the one whose molar absorption coefficient is higher. What does the magnitude
of the molar absorption coefficient depend on?
А. Optical path length of the test substance.
В. Density of the test substance solution.
С. Intensity of absorption of incident light by the test solution.
D. Nature of the test substance.*
Е. Concentration of the test substance.
142
47. The photometric reaction with sulphosalicylic acid conducted for quantitative
determination of Fe3+-ions. What value measure in this case:
А. Wavelength.
В. Optical density.*
С. Potential half-wave.
D. Refraction index.
Е. Specific rotation.
48. The concentration of copper sulfate in solution determined by photometric

method. What value measure in this case?
А. Optical density.*
В. Refractive index.
С. Potential half-wave.
D. Strength of current.
Е. Rotation angle.
49. The method of refractometry based on measurement of:

А. Refractive index.*
В. Specific heat capacity.
С. Transmission.
D. Specific electrical conductivity.
Е. Optical density.
50. Polarimetry is used to identify compounds containing an asymmetric carbon

atom. Which of the following compounds can be identified by this method?
А. Potassium iodide
B. Sodium chloride
С. Calcium nitrate
D. Glucose *
E. Copper sulphate
51. The Bouguer-Lambert-Beer law is the basis of molecular absorption analysis.

According to this law, the optical density of a solution
143
А. Inversely proportional to the thickness of the layer and the concentration of the
substance
B. Directly proportional to the thickness of the layer and the concentration of the
substance *
С. Directly proportional to concentration, inversely proportional to layer thickness
D. Directly proportional to the concentration and inversely proportional to the
absorption of monochromatic light
E. Directly proportional to the layer thickness and monochromatic light absorption
52. In which coordinates is a calibration graph used for the photometric

determination of copper salts plotted?
А. Optical density - wavelength
B. Optical density - thickness of the liquid layer
С. Light absorption intensity - wavelength
D. Optical density – concentration *
E. Optical density - temperature
53. For the quantitative determination of Fe3+ ions, a photometric reaction

with sulfosalicylic acid was performed. What value is measured for the
photometric determination of the resulting solution?
А. Specific rotation
B. Optical density *
С. The wavelength of the wave
D. Half-wave potential
E. Refraction
54. Which physical and chemical method of analysis should be used to determine
the concentration of a solution of potassium dichromate?
А. Fluorometric
B. Coulometric
С. Spectrophotometric *
D. Polarimetric
E. Conductometric titration
144
Electrochemical methods of analysis
1. To what type is the electrode, compiled according to the scheme Au3+/Au?

A. Ion-selective electrodes.
B. Electrodes of the III-rd generation.
C. Redox electrodes.
D. Electrodes of the I kind. *
E. Electrodes of the II kind.
2. For quantitative determination of potassium hydroxide the method of

potentiometric titration is chosen. The point of equivalence in this method is
determined by a sharp change:
А. Tension.
Б. Diffuse current.
С. Intensity of fluorescence.
D. Electromotive force. *
Е. Current strength.
3. Which indicator electrode is used for dichromatometric determination of the

content FeSO4 in a solution with a potentiometric fixation point of equivalence:
A. Hinhydron.
B. Silver/silver chloride.
C. Silver.
D. Platinum.*
E. Glass.
4. Potentiometric determination method рН, as the most universal, entered in the

State Pharmacopoeia of Ukraine. Which of the electrodes is used as a comparison
electrode?
A. Glass.
B. Gydrogen.
C. Quinhydrone.
D. Saturated calomel.*
E. Zinc.
145
5. One of the electrochemical methods of analysis is potentiometry. Potentiometry
- a method of analysis based on the measurement (determination):
A. Potential of indicator electrode.*
B. Potential of a diffusive layer.
C. Zeta-potential.
D. Oxidation-reduction potential.
E. Potential electrode reference.
6. For the identification of medicinal products polarographic method is

determined:
A. Potential half-wave.*
B. Deposition potential.
C. Potential of decomposition.
D. Boundary diffusion current.
E. Residual current.
7. For a potentiometric determination in a solution containing ammonia and

sodium hydroxide, a suitable indicator electrode:
A. Glass.*
B. Platinum.
C. Silver.
D. Silver-silver chloride.
E. Zinc.
8. Концентрацію ацетатної кислоти в аналізованому розчині визначають

методом потенціометричного титрування. Виберіть індикаторний електрод:
A. Glass.*
B. Zinc.
C. Silver-silver chloride.
D. Mercury.
E. Calomel.
9. Specify the physico-chemical method of analysis, based on measuring the

electrical conductivity of the investigated solutions.
146
A. Conductometry.*
B. Coulometry.
C. Potentiometry.
D. Polarography.
E. Amperometry.
10. Polarography - simultaneously qualitative and quantitative analysis method.

What is a quantitative characteristic in this method?
A. The magnitude of the boundary diffuse current.*
B. Electrode potential.
C. Potential half-wave.
D. Solution resistance.
E. Electromotive force.
11. Potentiometric titration is used in cases where it is not possible to use visual
indicators. In the course of this titration is measured:
A. Potential of indicator electrodes.*
B. Potential of reference electrodes.
C. Potential of oxidation-reducing system.
D. Potential of a diffusive layer.
E. Zeta-potential.
12. One of the electrochemical methods of analysis is polarography. During the

polarographic analysis, the test substance is identified by:
A. Potential half-wave.*
B. A value of electromotive force.
C. The height of the polarographic wave.
D. The position of the polarographic wave.
E. The width of the polarographic wave.
13. Specify the comparison electrode that can be used in the potentiometric study
of the drug substance.:
А. Silver-silver chloride. *
B. Glass.
C. Hinhydron.
147
D. Stibial.
E. Zinc.
14. From which depends the height of the polarographic wave?

А. Concentrations of the reducing ion.*
B. The composition of the electrolyte.
C. Characteristics of the capillary.
D. Radius of the capillary.
E. The length of the capillary.
15. Coulometry is based on measuring the amount of electricity consumed by the

electrode reaction. Indicate which law is the basis of the coulometric
determination of substances:
A. Faraday.*
B. Coulomb.
C. Newton.
D. Stokes.
E. Bouguer-Lambert-Beer.
16. Specify the method of titration using a pair of electrodes "glass-chloro-silver",

which can be used to determine the components of the drug substance.
A. Potentiometric.*
B. Coulometric.
C. Conductometric.
D. Amperometric.
E. Polarographic.
17. At potentiometric titration of the investigated solution near the point of

equivalence, a sharp change of magnitude:
A. Potential.*
B. Current strength.
C. Diffusion current.
D. Resistance.
E. Fluorescence intensity.
148
18. Specify the method of quantitative analysis, based on measuring the amount of
electricity spent on conducting the electrochemical reaction:
A. Coulometry.*
B. Amperometry.
C. Polarography.
D. Conductometry.
E. Potentiometry.
19. One of the electrochemical methods of analysis is polarography. The amount

of matter in the investigated system during the polarographic analysis is
determined:
A. The height of the polarographic wave.*
B. A value of electromotive force.
C. Strength of current.
D. The position of the polarographic wave.
E. The width of the polarographic wave.
20. Specify the physico-chemical method of analysis, based on measuring the

electrical conductivity of the investigated solutions as a result of the chemical
reaction.
A. Conductometry.*
B. Coulometry.
C. Potentiometry.
D. Polarography.
E. Amperometry.
21. Specify a method based on measuring the amount of electricity consumed by

the electrolysis of a certain amount of substance:
A. Coulometry.*
B. Amperometry.
C. Potentiometry.
D. Polarography.
E. Conductometry.
22. Choose a pair of electrodes for the potentiometric determination of the pH of
149
the solution:
A. Glass-chloro-silver. *
B. Calomel-chloro-silver.
C. Hinhydron-stibial.
D. Mercury-chloro-silver.
E. Glass-stibial.
23. For quantitative determination of iron(III) sulfate by the method of

potentiometric titration as indicator electrode used:
A. Platinum electrode.*
B. Silver-silver chloride electrode.
C. Quinhydrone electrode.
D. Stibial electrode.
E. Glass electrode.
24. Specify which parameter is measured with conductometric titration of

electrolyte solutions:
A. Conductivity.*
B. Electromotive force.
C. Viscosity of the solution.
D. Acidity of the environment.
E. Concentration of the solution.
25. Amperometric titration is used to analyze some pharmaceutical products. The

amperometric titration method is based on:
A. Determination of the equivalence points by a sharp change in the diffusion
current in the titration process.*
B. Measurement of the potential difference between electrodes in the titration
process.
C. Measuring the voltage in the cell during titration.
D. Ion exchange between the analyzed solution and cation exchange.
E. Ion exchange between the analyzed solution and anion exchange.
26. Choose an indicator electrode for the quantitative determination of acetic acid
by potentiometric titration:
150
A. Glass.*
B. Silver-silver chloride.
C. Silver.
D. Platinum.
E. Calomel.
27. When conducting permanganametometric determination of potassium iodide,

the point of equivalence was determined potentiometrically. Which electrode used
as indicator?
А. Platinum.*
В. Glass.
С. Hydrogenous.
Е. Mercury.
28. For quantitative determination of potassium hydroxide the method of

potentiometric titration is chosen. The point of equivalence in this method is
determined by a sharp change:
А. Tension.
Б. Diffuse current.
С. Fluorescence intensity.
D. Electromotive force.*
Е. Current strength.
29. The concentration of iron(II) sulfate is determined by the potentiometric

titration method: titanium is a standard solution of cerium(IV) sulfate. Select the
required pair of electrodes for titration:
А. Hydrogenous, silver-silver chloride.
В. Glass, silver-silver chloride.
С. Silver, zinc.
D. Platinum, silver-silver chloride.*
Е. Glass, calomel.
151
30. In the study of medicinal substances, a potentiometric method for determining
pH is used. Which of the electrodes can be used as an indicator when measuring
the pH of the solution?
А. Copper.
В. Glass.*
С. Calomel.
Е. Zinc.
31. With dichromatometric determination of the content FeSO 4 in a solution with a

potentiometric fixation of the point of equivalence as an indicator electrode, use:
А. Platinum.*
В. Silver.
С. Glass.
Е. Quinhydrone.
32. In electrochemical analysis, widely used electrodes of various designs.

Electrodes of the first kind belong:
А. Quinhydrone.
В. Calomel standard.
С. Silver-silver chloride standard.
D. Hydrogen gas.*
Е. Glass.
33. Potentiometric method for determining pH as the most universal, entered into
the State Pharmacopoeia of Ukraine. With the help of which of the pairs of
electrodes can determine the pH?
А. Hydrogen-quinhydrone.
В. Calomel-silver-silver chloride.
С. Glass-hydrogen.
D. Glass-calomel. *
E. Glass-quinhydrone.
152
34. Specify an indicator electrode for conducting potentiometric oxidation-
reduction titration:
А. Mercury.
В. Glass.
С. Hydrogen.
D. Quinhydrone.
Е. Platinum.*
35. Which electrode should be used as an indicator for potentiometric titration of

hydrochloric acid with a solution of potassium hydroxide?
А. Glass. *
В. Silver.
С. Zinc.
Е. Platinum.
36. Select a pair of electrodes for potentiometric titration of potassium iodide

solution:
А. Platinum, silver-silver chloride. *
В. Glass, silver-silver chloride.
С. Glass, calomel.
D. Hydrogen, silver-silver chloride.
Е. Quinhydrone, calomel.
37. The physico-chemical method of research, based on the measurement of the

EMF  is:
А. Potentiometry.*
В. Photocolorimetry.
С. Chromatography.
D. Refractometry.
Е. Polarimetry.
38. With direct conductometric determination of the concentration of a substance

in the analyzed solution are determined by the results of measurements:
А. Specific heat capacity.
153
В. Specific electrical conductivity.*
С. Transmission.
D. Refractive index.
E. Optical density.
39. When conductometric titration of acids HCl and CH3COOH 0,1 М solution
NaOH measured:
А. Potential difference.
В. pH environment.
С. Conductivity of the solution.*
D. Angle of rotation of plane of polarization.
Е. Refractive index.
40. What type of electrodes belongs chlorine silver-silver chloride electrode?

А. Oxidation-reducing.
В. To the second kind.*
С. To the first kind.
D. Gas.
Е. Ion-selective.
41. How according to the Pharmacopoeia is pH determined?

А. Indicator.
В. Potentiometry.*
С. Spectrophotometry.
D. Polarography.
Е. Conductometry.
42. Acetic acid concentration in a solution being analyzed can be determined by

means of potentiometric titration. Specify the indicator electrode:
A. Silver chloride
B. Mercury
C. Calomel
D. Glass *
E. Zinc
154
43. Glass electrodes are often used in pharmaceutical analysis. What type of
electrode is it?
А. First type
B. Ion selective *
С. Redox complex
D. Redox simple
E. Of the second kind
44. What reference electrode can be used in the potentiometric analysis of a

medicinal substance?
A. Antimony electrode
B. Glass electrode
C. Zinc electrode
D. Silver chloride electrode *
E. Quinhydrone electrode
45. What physico-chemical method is used to determine the pH of solutions

for injections?
A. Amperometry
B. Potentiometry *
C. Electrolysis
D. Conductometry
E. Polarography
155
Chromatographic methods of analysis
1. The chemical laboratory received a drug that is a mixture of glucose and

mannose. To identify these substances in the mixture can be used method:
A. Chromatography in a thin layer of sorbent.*
B. Polarimetry.
C. Spectrophotometry.
D. Polarography.
E. Amperometric titration.
2. For quantitative determination of ethanol gas chromatography method was

used. What parameter is measured?
A. Height or area of the chromatographic peak.*
B. Retention time.
C. Volume content.
D. The width of the chromatographic peak.
E. The half-width of the chromatographic peak.
3. Specify the method of chromatographic analysis when ion exchangers are used
as sorbent.
A. Ion exchange.*
B. Gas.
C. Paper.
D. Thin layer.
E. Gel filtration.
4. For identification of medicinal product by thin-layer chromatography use

parameter:
A. Rf.*
B. n.
C. E, mV.
D. I, A.
E. Kr.
156
5. Chromatographic methods of analysis are distinguished by the mechanism of
interaction of sorbent and sorbate. Select the appropriate separation mechanism
for ion exchange chromatography:
A. On different ability of substances to ion exchange.*
B. The difference in adsorption of substances is a solid sorbent.
C. On different solubility of divisible substances in a stationary phase.
D. On the formation of different dissolved soluble precipitates.
Е. On different solubility of distributed substances in a moving phase.
6. In the gas-liquid chromatography, the substances analyzed are injected into the
carrier gas stream, which must meet the requirements.:
A. Inertia in relation to the stationary phase and the analyzed substances.*
B. High thermal conductivity.
C. High molecular weight.
D. Speed on the column.
E. Affinity to the stationary phase.
7. When chromatography of novocaine in a thin layer of sorbent after the

discovery of the plate, a spot was obtained, the distance to which from the starting
line of 3 cm, and the distance of the solvent front  10 cm. What is the value of Rf
novocaine?
A. 0,3.*
B. 0,4.
C. 0,5.
D. 0,6.
E. 0,7.
8. Chromatographic methods are classified according to the mechanism of the

separation process. What type of chromatography include a method of gas-liquid
chromatography?
A. Partition.*
B. Adsorption
C. Ion exchange.
D. Gel chromatography.
E. Affinity.
157
9. The separation of substances in the method of gas-liquid chromatography
occurs due to different velocity of substances in the column. What is a moving
phase in this analysis method?
A. Gas carrier.*
B. Solid carrier.
C. Liquid phases.
D. Water.
E. Organic solvent.
10. In a quantitative analysis, an ion-exchange chromatography method is used.

Specify the process underlying the ion-exchange chromatography method?
A. Revolving stoichiometric ion exchange.*
B. Adsorption of ions on the surface in accordance with the Panethan-Fayans rule.
C. Oxidation-reducing process.
D. Reactions of the formation and dissolution of sediments.
E. Formation of intracompound compounds.
11. At the heart of the quantitative analysis in the gas chromatography is the
dependence:
А. Height of the chromatographic peak or its area from the concentration of the
substance.*
B. Time of concentration from substance concentration.
C. Containment volume from concentration of substance.
D. Width of chromatographic peak from concentration.
E. Height, equivalent to the theoretical plate, from the amount of substance.
12. There is a mixture of mannose and fructose. With which method of analysis,
they can be identified?
А. Refractometry.
В. Polarographies.
С. Conductometry.
D. Potentiometry.
Е. Chromatography.*
158
13. Specify the method of chromatographic analysis, in which, when studying the
components of the drug substance as a sorbent use ion exchangers:
А. Gel filtration chromatography.
В. Gas chromatography.
С. Ion exchange chromatography.*
D. Paper chromatography.
Е. Thin layer chromatography.
14. The separation of substances using the method of gas-liquid chromatography

occurs due to different rate of substances in the column. What is a moving phase?
А. Solid carrier.
В. Organic solvent.
С. Water.
D. Liquid phases.
Е. Gas carrier. *
15. In the chromatography method, the separation of substances is based:

A. The ability to divide between a moving and stationary phase.*
B. The ability to divide between two moving phases.
C. The ability to divide between two stationary phases.
D. On the ability to dissolve.
E. On the ability to precipitate.
16. In gas-liquid chromatography, the substances to be analysed are introduced

into a carrier gas stream that must meet the requirements:
А. High thermal conductivity
B. Inertness in relation to the stationary phase and the substance to be analysed *
С. Movement speeds in the column
D. Affinity for the stationary phase
E. Large molecular weight
17. Chromatographic methods of analysis differ in the mechanism of interaction

between sorbent and sorbate. What is the basis of the separation mechanism for
ion-exchange chromatography?
159
А. Formation of coordination compounds of different stability in the phase or on
the surface of the sorbent
B. On the different ability of a substance to ion exchange *
С. The difference in adsorption of substances by a solid sorbent
D. The formation of precipitates that differ in the solubility of the substances to be
separated with the sorbent
E. On the different solubility of the substances to be separated in the stationary
phase
18. The chemical laboratory received a drug that is a mixture of glucose and
mannose. The method can be used to identify these substances in the mixture:
A. Chromatography in a thin layer of sorbent.*
B. Polarimetry.
C. Spectrophotometry.
D. Polarographies.
E. Amperometric titration.
160
Recommended literature
General literature
1. Analytical chemistry : textbook [the textbook for students of
higher schools]/ I. S. Grytsenko, V. V. Bolotov, L. Yu. Klimenko et al.;
edited by I. S. Grytsenko. – Kharkiv: NUPh: Golden Pages, 2019. – 600 p.
2. Analytical chemistry: textbook for students of higher
educational institutions / V. Bolotov et al. Kh.: NUPh, 2014. 320 с.
3. Analytical chemistry. Qualitative and quantitative analysis :
lecture notes / V. Bolotov et al. Vinnytsia: New book, 2011. 424 c.
4. Vasiuk S. O., Korzhova A. S. Workshop on analytical
chemistry: workshop for students of specialty "Pharmacy, industrial
pharmacy". Zaporizhzhia : ZSMU, 2020. 96 с.
5. Analytical chemistry: textbook for students of Pharmacy and
Biotechnology/ N. K. Fedushchak et al. Vinnytsia: Nova Kniga, 2012.
640 с.
Additional literature
1. British Pharmacopeia. – Vol. 1–4. – London: The Stationary
Office, 2009. – 10952.
2. United States Pharmacopeia 36. – USP Convention Inc. –
Rockville, 2013. – 5640.
3. Foundations of Analytical Chemistry. A Teaching–Learning
Approach : textbook / ed. M. V. Cases, Á. I. López-Lorente, Á. López-
Jiménez. – Switzerland : Springer, 2018. – 487 p. : ill. - DOI 10.1007/978-
3-319-62872-1.
4. Qualitative analysis. Acid-basic titration. Section 1. Theory and
analysis of cations of I-III analytical groups. Basic topic 1. Theory and
analysis of cations of IV-VI analytical groups. Basic topic 2. Theory and
analysis of anions and compounds of unknown composition. Basic topic 3.
Manual for students of the 2-nd course of the Pharmaceutical Faculty
speciality 226 «Pharmacy, Industrial Pharmacy». – S. O. Vasyuk, A. S.
Korzhova, A. O. Donchenko. – Zaporizhzhia, 2021 – 131 p.
161
5. Qualitative analysis. Acid-basic titration. Section 1. Acid-base
titration and its application in chemical and pharmaceutical analysis. Basic
topic 4. Manual for students of the 2-nd course of the Pharmaceutical
Faculty speciality 226 «Pharmacy, Industrial Pharmacy». – S. O. Vasyuk,
A. S. Korzhova, N. O. Nagorna, K. P. Miedviedieva. – Zaporizhzhia, 2021
– 110 p.
6. Quantitative analysis. Instrumental methods of analysis.
Section 2. Oxidation-reduction titration and its application in the analysis
of chemical compounds and medicines. Basic topic 1. Manual for students
of the 2-st course of the Pharmaceutical Faculty specialty 226 «Pharmacy,
Industrial Pharmacy». – S. O. Vasyuk, A. S. Korzhova, K. P.
Miedviedieva. – Zaporizhzhia, 2021 – 66 p.
7. Quantitative analysis. Instrumental methods of analysis.
Section 2. Precipitation titration, compleximetric titration. Gravimetric
analysis. Application of methods in the analysis of chemical compounds
and medicines. Basic topic 2. Manual for students of the 2-st course of the
Pharmaceutical Faculty specialty 226 «Pharmacy, Industrial Pharmacy». –
S. O. Vasyuk, A. S. Korzhova, N. O. Nahorna. – Zaporizhzhia, 2021 –
75 p.
8. Physical methods of analysis. Manual for students of the 1-st
course of the Pharmaceutical Faculty speciality 226 «Pharmacy, Industrial
Pharmacy». – S. O. Vasyuk, A. S. Korzhova, O. R. Maletska. –
Zaporizhzhia, 2021 – 46 p.
162

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Ministry of Health of Ukraine

Zaporizhzhia State Medical and Pharmaceutical University

COLLECTION OF TESTS ON ANALYTICAL CHEMISTRY

Approved at the meeting of the Central Methodological Council of ZSMU

The Manual is composed by:

Doctor of Pharmaceutical Sciences, professor S. O. Vasyuk;

Collection of tests on analytical chemistry. «KROK 1.

© Zaporizhzhia State Medical University, 2023

Analytical chemistry is the science of methods of studying the

1. To detect ammonium cations, a complex mercury compound is used, namely

2. When adding a dilute solution of hydrochloric acid to the analyzed solution, a

7. In analytical practice, organic dicarboxylic acid is used to detect calcium ions.

8. In the investigated solution was added a 2 M solution of hydrochloric acid. A

9. To the study solution was added 1 М solution of sulfuric acid. A white

20. Cations of the IIId analytical group (acid-base classification) isolated in a

23. By I analytical group of cations for the acid-basic classification of cations:

26. Which of these reactions is a specific determination of ammonium cations?

32. Cations of the IIId analytical group (acid-basic classification) separated in a

35. What cation of the IIId analytical group (acid-basic classification) is in

37. Calcium cations are part of some pharmaceuticals. The pharmacopoeial

42. According to the acid-base classification, the II d analytical group of cations

43. To the I analytical group cations acid-base classification include cations:

45. In pharmacopoeial analysis for the detection of sodium ions use:

47. In qualitative analysis the typical reaction to cation silver is:

48. What is characterized by the ability of the reagent to give a well-defined

54. The reaction of the formation of a golden yellow precipitate (reaction of

56. What analytical effect is accompanied by the reaction of detecting potassium

58. What is the analytical effect accompanied by the reaction of determining

59. Volatile compounds of calcium colorless flame painted in a color:

61. Specialists investigate solutions containing mixtures of cations. Which

62. Which of these reactions is a specific determination of ammonium cations??

66. Chemist-analyst conducts qualitative analysis of the IId analytical group of

69. Which cation colors the flame in violet color?

70. To determine the qualitative composition of the drug on the investigated

76. In the process of systematic analysis it is necessary to separate PbSO4

79. To determine the qualitative content of a drug, a sample of the analyte

2. In qualitative analysis, acting on the excess of a group reagent (NH 3 solution)

4. Ammonium thiocyanate was added to the solution containing cations of the V th

6. An excess of 6 M sodium hydroxide solution and 3% hydrogen peroxide

9. Specify the type of reaction used to identify the cation Fe3+:

10. In qualitative analysis a specific reagent for cations Fe2+ is:

11. A characteristic reaction detecting mercury(II) cations is a reaction with

12. According to the values рКа indicate the strongest acid:

15. Medicinal product hydrogen peroxide is determined by reaction with

17. Qualitative reaction for the determination of compounds Cr(VI) is the

18. In a qualitative analysis, when the excess of a group reagent (a solution of

21. What cations with a solution of potassium iodide form an orange-red

24. Specify a compound whose qualitative definition is accompanied by the

25. The division of cations V and VI analytical groups (acid-basic classification)

31. In solution there are cations of calcium, barium, aluminum, potassium,

32. A characteristic reaction to detect mercury (II) cations is a reaction with

34. To the investigated solution was added a solution of ammonium thiocyanate.

37. To the investigated solution was added an excess 6 М solution of sodium

44. In qualitative analysis a specific reagent for cations Fe2+ is:

45. What cations with a solution of potassium iodide form an orange-red

50. When added to an unknown mixture of a solution of sodium hydroxide and a

59. The group reagent on cations of the IV th analytical group (acid-basic

61. To a solution containing cations of the sixth analytical group (acid-base

69. In chemical-analytical laboratory technician recognize a mixture of cations V

73. Buffer solutions are widely used in the analysis for:

85. An analytical chemist performs a qualitative analysis of cations that belong to

86. When an unknown mixture of sodium hydroxide (NaOH) and hydrogen

87. During a characteristic reaction with sodium sulfide on salts of an unknown