Single Correct Questions

Q-1: Consider permanent polarisations in the ground state of molecule

and also time variable effects in saturated and unsaturated molecules.
The incorrect statement is :

Time variable effects will not be reflected in the physical

A
properties of the compounds concerned.

Permanent polarisations in ground state are manifested

B in the physical properties of saturated and unsaturated
compounds.

C X-ray crystallography shows that two oxygen atoms are

distinguishable from each other, in acetate ion, the two
carbon oxygen bond distances being the same.

D Time variable effects should be looked upon as

polarisabilities rather than as polarisations.
Q-2:Match the Column I and II.

Column - I Column - II Column - I Column - II

(A) (p) 180 kJ/mol (C) (r) 21 kJ/mol

A a – q; b – r; c – s; d – p

B a – r; b – q; c – s; d – p

C a – p; b – r; c – s; d – q
(B) (q) 88.3 kJ/mol (D) (s) Negative
barrier D a – s; b – r; c – q; d – p
Q-3: Consider the following reaction involving two acids shown below : formic acid and HF.

Which of the following statements about this reaction are true ?

(A) Formic acid is the strongest Bronsted acid in the reaction
(B) HF is the strongest Bronsted acid in the reaction
(C) KF is the strongest Bronsted base in the reaction
(D) KO2CH is the strongest Bronsted base in the reaction
(E) The equilibrium favours the reactants
(F) The equilibrium favours the products
(G) Formic acid has a weaker conjugate base
(H) HF has a weaker conjugate base

A A, D and F B B, D, and H

C A, C, and H D B, D, E and H
Q-4: Several factors (steric, electronic, orbital interactions etc.) can affect
the inversion barrier of an amine. In the given pair which data is correctly
placed?

A B

C D All of these
Q-5: State whether the following statements are true or false.
Give your reason.
(a) A compound with the S configuration is the (-)
enantiomer.
(b) An achiral compound can have chiral centers.
(c) An optically inactive substance must be achiral.
(d) In chemical reactions the change from an S reactant to an
R product always signals an inversion of configuration.
(e) When an achiral molecule reacts to give a chiral molecule
the product is always racemic.

A FTFFF

B TFTTF

C TTTFT

D FFTFT
Q-6: Find sum of stereoisomer of following compound.

A 512 B 412

C 822 D 712
Q-7:

A (A) = 6.87D, (B) = 4.11D

B (A) = 4.11 D , (B) = 6.87 D

C (A) = 4.11 D , (B) = 4.11 D

D (A) = 6.87 D, (B) = 6.87 D

Q-8: For the series of bases shown below, the correct order of basicity from
strongest to weakest :

A d>b>c>a

B b>d>c>a

C d>b>a>c

D a>b>c>d
Q-9: With respect to the compounds I-V, choose the incorrect
statement(s).

A The acidity of compound I is due to delocalization in the conjugate

base.

B The conjugate base of compound IV is aromatic.

C Compound II becomes more acidic, when it has a -NO2 substituent.

D The acidity of compounds follows the order I > IV > V > II > III.
Q-10: In each of the following sections four compounds are listed.
(Decreasing order of acidic strength, 1 is strongest & 4 is weakest).

A 1 4 2 3

B 3 4 1 2

C 1 4 3 2

D 2 4 1 3
Multiple Correct Questions
Q-11: In 3-methyl-2-cyclohexenone which hydrogen can undergo deuterium
exchange when it reacts with CH3O⊝ /CH3OD ?

A H1

B H4

C H3, H2

D H5, H3
Q-12: Consider the following four compounds I, II, III, and IV.

Choose the correct statement(s)

A The order of basicity is II > I > III > IV

B The magnitude of pKb difference between I and II is more than that

between III and IV.

C
Resonance effect is more in III than in IV.

D Steric effect makes compound IV more basic than III.

Q-13: Identify the pairs in which either both the molecules show same interaction
with plane polarised light or they are not mirror images of each other ?

A B

C D
Q-14: Which of the following is/are statement:

A N-Methylethanamine exists as non isolable racemic mixture

B N-Methylethanamine react with excess of DCl and give configurational enantiomer.

C Two conformational isomers of butane have equal energy (degenerate) and

they are chiral.

D Penta-2, 3-diene exist in optically active isomeric forms

Q-15: Which of the following statement(s) is/are true about the
following compound?

A (I) and (II) are identical

B (I) and (III) are geometrical diastereomers

C (I) and (II) are structural isomers

D (II) and (III) are structural isomers

Integer Type Questions
Q-16: Among the given molecules, calculate the number of aromatic compounds ?

(a) (b) (c) (d)

(e) (f) (g)

(h) (i) (j) (k)

Q-17: Find the sum of total number of stereoisomer for each
compound:
Q-18: The maximum number of possible isomers (including
stereoisomers) which may be formed on monobromination of
1-methylcyclohex-1-ene using Br2 and UV light is____.
Q-19: Identify the number of species which are more acidic than (ii) .